WO2005069389A1 - Gallium nitride-based iii-v group compound semiconductor device and method of manufacturing the same - Google Patents

Gallium nitride-based iii-v group compound semiconductor device and method of manufacturing the same Download PDF

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Publication number
WO2005069389A1
WO2005069389A1 PCT/KR2005/000150 KR2005000150W WO2005069389A1 WO 2005069389 A1 WO2005069389 A1 WO 2005069389A1 KR 2005000150 W KR2005000150 W KR 2005000150W WO 2005069389 A1 WO2005069389 A1 WO 2005069389A1
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Prior art keywords
layer
metal layer
ohmic electrode
gallium nitride
diffusion barrier
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PCT/KR2005/000150
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French (fr)
Inventor
Jong-Lam Lee
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Seoul Opto-Device Co., Ltd.
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Application filed by Seoul Opto-Device Co., Ltd. filed Critical Seoul Opto-Device Co., Ltd.
Priority to EP05721806.7A priority Critical patent/EP1709695B1/en
Priority to US10/597,200 priority patent/US7859109B2/en
Priority to JP2006549141A priority patent/JP5227517B2/en
Publication of WO2005069389A1 publication Critical patent/WO2005069389A1/en
Priority to US12/952,928 priority patent/US8323999B2/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/40—Materials therefor
    • H01L33/405—Reflective materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G65/00—Loading or unloading
    • B65G65/30—Methods or devices for filling or emptying bunkers, hoppers, tanks, or like containers, of interest apart from their use in particular chemical or physical processes or their application in particular machines, e.g. not covered by a single other subclass
    • B65G65/34—Emptying devices
    • B65G65/36—Devices for emptying from the top
    • B65G65/38—Mechanical devices
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28575—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising AIIIBV compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G2201/00—Indexing codes relating to handling devices, e.g. conveyors, characterised by the type of product or load being conveyed or handled
    • B65G2201/04—Bulk
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G2207/00—Indexing codes relating to constructional details, configuration and additional features of a handling device, e.g. Conveyors
    • B65G2207/48—Wear protection or indication features
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G2814/00—Indexing codes relating to loading or unloading articles or bulk materials
    • B65G2814/03—Loading or unloading means
    • B65G2814/0301—General arrangements
    • B65G2814/0326—General arrangements for moving bulk material upwards or horizontally
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/26—Materials of the light emitting region
    • H01L33/30—Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table
    • H01L33/32—Materials of the light emitting region containing only elements of Group III and Group V of the Periodic Table containing nitrogen

Definitions

  • GaN LEDs gallium nitride-based semiconductor
  • active research has been done on high-power GaN LEDs.
  • a GaN LED film layer is grown on a sapphire substrate that is an insulator, the associated LED device has a horizontal structure.
  • the conventional LED device has disadvantageously a high operation voltage and a low light output because current spreading resistance increases during a high power operation thereof.
  • the conventional LED device has also disadvantageously poor thermal stability because heat generated during the operation thereof cannot be efficiently dissipated from the sapphire substrate.
  • a flip-chip packaging method has been proposed to implement a high-power GaN LED. Since light emits upwards through the sapphire substrate from an active layer of the GaN LED having a flip-chip structure, a thick p-type ohmic electrode can be substituted for a transparent electrode, so that the current spreading resistance can be reduced. At this time, a material constituting the p-type ohmic electrode should have low absorbance and high reflectance.
  • an object of the present invention is to provide a gallium nitride-based III-V group compound semiconductor device and a method of manufacturing the same capable of improving performance of the device by forming an ohmic electrode having good thermal stability, improved contact resistivity, and highly-maximized reflectance.
  • a gallium nitride-based ⁇ i-V group compound semiconductor device comprising a gallium nitride-based semiconductor layer and an ohmic electrode layer formed on the gallium nitride-based semiconductor layer.
  • the ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
  • the ohmic electrode layer may further comprise at least one bonding metal layer.
  • the ohmic electrode layer may be formed by sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer, and the bonding metal layer.
  • the contact metal layer may comprise at least one of Ni, Ir, Pt, Pd, Au, Ti, Ru, W, Ta, V, Co, Os, Re, and Rh.
  • the reflective metal layer may comprise at least one of Al and Ag.
  • the diffusion barrier layer may comprise at least one of Ru, Ir, Re, Rh, Os, V, Ta, W, ITO (Indium Tin Oxide), IZO (Indium Zinc oxide), RuO , VO , MgO, IrO , 2 2 2 ReO , RhO , OsO , Ta O , and WO .
  • the bonding metal layer may comprise first and 2 2 2 2 3 2 second bonding metal layers, said first bonding metal layer comprising at least one of Ni, Cr, Ti, Pd, Ru, Ir, Rh, Re, Os, V, and Ta, said second bonding metal layer comprising at least one of Au, Pd, and Pt.
  • a method of manufacturing a gallium nitride-based III-V group compound semiconductor device comprises steps of: forming a gallium nitride-based semiconductor layer having a PN contact structure on a substrate; and forming an ohmic electrode layer on the semiconductor layer.
  • the ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
  • the step of forming the ohmic electrode layer may comprise steps of: sequentially laminating the contact metal layer, the reflective metal layer, and the diffusion barrier layer on the semiconductor layer; performing a thermal treatment process; and forming a bonding metal layer on the diffusion barrier layer.
  • the step of forming the ohmic electrode layer comprises steps of: sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer and bonding metal layer on the semiconductor layer; and performing a thermal treatment process.
  • the thermal treatment process may be a rapid thermal annealing process performed under an atmosphere of 5 to 100% oxygen at a temperature of 100 to 700 °C for 10 to 100 seconds. Description of Drawings
  • FIG. 1 is a schematic cross-sectional view showing a p-type ohmic electrode of a gallium nitride-based compound semiconductor layer according to an embodiment of the present invention
  • Fig. 2 is a graph showing current versus voltage of ohmic electrodes according to the present invention under different thermal treatment atmospheres
  • Fig. 3 is a graph showing contact resistivity of the ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode with respect to thermal treatment temperature;
  • Fig. 4 is a graph showing reflectance of the ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
  • FIG. 5 is a graph showing depth profiles of an ohmic electrode according to the present invention, wherein the depth profiles are measured by using a secondary ion- mass spectros ⁇ opy (SIMS) with respect to thermal treatment conditions;
  • SIMS secondary ion- mass spectros ⁇ opy
  • Fig. 6 is a graph showing operation voltage and light output of flip-chip light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
  • Fig. 7 is a graph showing operation voltage of vertical-structure light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
  • Fig. 8 is a graph showing light output of the vertical-structure light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
  • Fig. 9 is a photograph of the vertical-structure LED. Best Mode
  • the ohmic electrode layer includes a reflective metal layer made of Ag, a diffusion barrier layer made of Ru, a first bonding metal layer made of Ni, and a second bonding metal layer made of Au.
  • FIG. 1 is a schematic cross-sectional view showing a configuration of an ohmic electrode of a gallium nitride-based compound semiconductor layer according to an embodiment of the present invention.
  • an n-type GaN layer 12, an active layer 13, and a p-type GaN layer 14 are sequentially formed on a substrate 11. Then, a multi-layered ohmic electrode layer is formed by sequentially depositing contact metal/Ag/Ru/Ni/Au metal layers 15 to 19 on the p-type GaN layer 14.
  • the ohmic electrode layer has a total thickness of 300 to 23,000 ?, and more preferably, 2,000 to 5,000 ?.
  • the contact metal layer 15 has a thickness of 5 to 500 ?, and more preferably, 200 ? or less.
  • the contact metal layer 15 may be formed as a multi-layered thin film.
  • the Ag layer 16 has a thickness of 100 to 9,000 ?, and more preferably, 1,000 to 2,000 ?.
  • the Ru layer 17 has a thickness of 50 to 1,000 ?, and more preferably, 100 to 800 ?.
  • the Ni layer 18 has a thickness of 100 to 3,000 ?, and more preferably, 1,000 ? or less.
  • the Au layer 19 has a thickness of 100 to 9,000 ?, and more preferably, 1,000 ? or less.
  • the thickness of the contact metal layer 15 is selected within the aforementioned range in order to control absorbance of light.
  • the contact metal layer 15 is made of one of Ni, Ir, Pt, Pd, Au, Ti, Ru, W, Ta, V, Co, Os, Re, and Rh.
  • the contact metal layer 15 may be formed by alternately laminating two different metals of the above-listed metals.
  • the contact metal layer 15 is formed by laminating Ni, Ir, and Pt layers.
  • a method of forming the multi-layered ohmic electrode layer is as follows. Firstly, the n-type GaN layer 12, the active layer 13, and the p-type GaN layer 14 are sequentially formed on a sapphire substrate 11. Next, the p-type GaN layer 14 is subject to a mesa-etching process using inductively coupled plasma (TCP), a surface treatment process, a lithography process, a metal thin film deposition process, and a lift-off process, so that a metal electrode pattern is obtained.
  • TCP inductively coupled plasma
  • the ohmic electrode is subject to a rapid thermal annealing process under an atmosphere of 5% or more oxygen at a temperature of 100 to 700 °C for 10 or more seconds. That is, the rapid thermal annealing process is preferably performed under an atmosphere of 5 to 100 % oxygen at a temperature of 100 to 700 °C for about 10 to 100 seconds.
  • the electrical properties of the ohmic electrode are measured, so that contact resistivity thereof is calculated.
  • the gallium nitride-based III-V group compound semiconductor is preferably at least one selected from a group of GaN, InGaN, AlGaN, and AlInGaN.
  • the substrate is preferably one of a sapphire substrate, a silicon carbide (SiC) substrate, a silicon (Si) substrate, a zinc oxide (ZnO) substrate, a gallium arsenide (GaAs) substrate, and a gallium phosphate (GaP) substrate.
  • the substrate is more preferably the sapphire substrate.
  • a low contact resistivity of 7x10-5 ⁇ cm is obtained by performing a thermal treatment process at a temperature of 500 °C. It should be noted that, during a high temperature thermal treatment process, the contact resistivity of the Me/Ag/Ru/Ni/Au ohmic electrode relatively slowly increases, whereas the contact resistivity of the conventional Ni/Au electrode rapidly increases.
  • the multi-layered p-type ohmic electrode according to the present invention has good thermal stability.
  • Fig. 4 is a graph showing reflectance of Me/Ag Me/Ag/Ru, Me/Ag/Ru/Ni/Au ohmic electrodes according to the present invention and the conventional Ni/Au p-type ohmic electrode with respect to wavelength of light.
  • the reflectance of the Me/Ag and Me/Ag/Ru ohmic electrodes is 75%, but the reflectance of the Me/Ag/Ru/Ni/Au ohmic electrode is 90%, which is very high.
  • the reflectance of the conventional Ni/Au ohmic electrode is 50%. Accordingly, it can be understood that the Me/Ag/Ru/Ni/Au p-type ohmic electrode according to the present invention is very suitable for a high- reflectance electrode of a flip-chip LED.
  • Fig. 5 is a graph showing depth profiles of an Ir/Ag/Ru/Ni/Au ohmic electrode manufactured by performing a thermal treatment process at a temperature of 500 °C for two minutes, wherein the depth profiles are obtained by using a secondary ion- mass spectros ⁇ opy (SIMS).
  • SIMS secondary ion- mass spectros ⁇ opy
  • the Ag layer performs its inherent role as a reflective layer. Accordingly, it is possible to obtain high reflectance and good thermal stability by using the ohmic electrode according to the present invention.
  • Fig. 6 is a graph showing operation voltage and light output of (300 ⁇ m x 300 ⁇ m) InGaN flip-chip LEDs manufactured by using an Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention and a conventional Ni/Au p-type ohmic electrode.
  • a figure that schematically shows a method of measuring light outputs of the LEDs is inserted in Fig. 6.
  • the operation voltage of the LED decreases from 3.73 V to 3.65 V, and the light output of the LED greatly increases from 16 a.u. to 31 a.u.
  • the high-reflectance Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention improves the properties of the gallium nitride-based III-V group compound semiconductor LED device.
  • Figs. 7 and 8 are graphs showing operation voltage and light output of (300 ⁇ m x 300 ⁇ m) InGaN vertical-structure LEDs manufactured by using an Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention and a conventional Ni/Au p-type ohmic electrode, respectively.
  • a cross-sectional view of the vertical-structure LED is inserted.
  • Fig. 9 shows a photograph of the vertical-structure LED.
  • the Me/ Ag/Ru/Ni/Au ohmic electrode it is possible to implement a gallium nitride-based III-V group compound semiconductor device having high reliability.
  • the diffusion barrier layer is interposed between the lower contact and reflective metal layers and the bonding metal layer, so that an ohmic electrode layer having low contact resistivity and improved reflectance can be obtained.
  • the bonding metal layer is formed after the contact and reflective metal layers are formed.
  • the bonding metal layer is diffused into a lower layer, so that the properties of the lower contact and reflective metal layers are deteriorated.
  • the reflective metal layer and the diffusion barrier layer are sequentially formed, and then, an oxygen-atmosphere thermal treatment process is performed.
  • a layer for protecting the lower metal layer can be obtained. That is, in a case where the diffusion barrier layer is made of Ru, the Ru is deposited on the reflective metal layer, and the oxygen-atmosphere thermal treatment process is performed, so that the Ru is oxidized into RuO . As a result, it is possible to effectively protect the 2 reflective metal layer.

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Abstract

The present invention relates to a gallium nitride-based compound semiconductor device and a method of manufacturing the same. According to the present invention, there is provided a gallium nitride-based II-V group compound semiconductor device comprising a gallium nitride-based semiconductor layer and an ohmic eletrode layer formed on the gallium nitride-based semiconductor layer. The ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.

Description

Description GALLIUM NITRIDE-BASED III-V GROUP COMPOUND
SEMICONDUCTOR DEVICE AND METHOD OF MANUFACTURING THE SAME Technical Field
[1] The present invention relates to a gallium nitride-based compound semiconductor device and a method of manufacturing the same, and more particularly, to a gallium nitride-based III-V group compound semiconductor device having an Me (= Ir, Ni, Pt)/Ag/Ru/Ni/Au ohmic electrode having low contact resistivity, high reflectance, and good thermal stability and a method of manufacturing the same. Background Art
[2] Recently, light emitting diodes (LEDs) using a gallium nitride-based semiconductor (hereinafter, referred to as GaN LEDs) have been expected to be substituted for conventional light sources such as incandescent lamps, fluorescent lamps, and mercury lamps. Therefore, active research has been done on high-power GaN LEDs. In general, since a GaN LED film layer is grown on a sapphire substrate that is an insulator, the associated LED device has a horizontal structure. As a result, the conventional LED device has disadvantageously a high operation voltage and a low light output because current spreading resistance increases during a high power operation thereof. In addition, the conventional LED device has also disadvantageously poor thermal stability because heat generated during the operation thereof cannot be efficiently dissipated from the sapphire substrate. [3] In order to solve the aforementioned problems, a flip-chip packaging method has been proposed to implement a high-power GaN LED. Since light emits upwards through the sapphire substrate from an active layer of the GaN LED having a flip-chip structure, a thick p-type ohmic electrode can be substituted for a transparent electrode, so that the current spreading resistance can be reduced. At this time, a material constituting the p-type ohmic electrode should have low absorbance and high reflectance. Since metals such as Ag and Al having a reflectance of 90% or more have a low work function, these metals are not suitable for contact metals of the p-type GaN ohmic electrode. On the other hand, with respect to an InGaN LED device, research has rarely been done on a high-reflectance p-type ohmic electrode in comparison to a conventional p-type transparent electrode. [4] A recent research shows that, an Ni/Au transparent electrode on which Al and Ag reflective layers are deposited can have a reflectance of 70 % or more in a blue light range (see Appl. Phys. Lett. vol. 83, p. 311 (2003)). Ifcwever, there is a problem in that properties of the electrodes drastically deteriorate at a temperature of 100 °C or more. Disclosure of Invention Technical Problem
[5] The present invention is conceived to solve the aforementioned problems in the prior art. Accordingly, an object of the present invention is to provide a gallium nitride-based III-V group compound semiconductor device and a method of manufacturing the same capable of improving performance of the device by forming an ohmic electrode having good thermal stability, improved contact resistivity, and highly-maximized reflectance. Technical Solution
[6] According to an aspect of the present invention for achieving the objects, there is provided a gallium nitride-based πi-V group compound semiconductor device. The semiconductor device comprises a gallium nitride-based semiconductor layer and an ohmic electrode layer formed on the gallium nitride-based semiconductor layer. The ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
[7] The ohmic electrode layer may further comprise at least one bonding metal layer. The ohmic electrode layer may be formed by sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer, and the bonding metal layer. The contact metal layer may comprise at least one of Ni, Ir, Pt, Pd, Au, Ti, Ru, W, Ta, V, Co, Os, Re, and Rh. The reflective metal layer may comprise at least one of Al and Ag. The diffusion barrier layer may comprise at least one of Ru, Ir, Re, Rh, Os, V, Ta, W, ITO (Indium Tin Oxide), IZO (Indium Zinc oxide), RuO , VO , MgO, IrO , 2 2 2 ReO , RhO , OsO , Ta O , and WO . The bonding metal layer may comprise first and 2 2 2 2 3 2 second bonding metal layers, said first bonding metal layer comprising at least one of Ni, Cr, Ti, Pd, Ru, Ir, Rh, Re, Os, V, and Ta, said second bonding metal layer comprising at least one of Au, Pd, and Pt. [8] According to another aspect of the present invention for achieving the objects, there is provided a method of manufacturing a gallium nitride-based III-V group compound semiconductor device. The method comprises steps of: forming a gallium nitride-based semiconductor layer having a PN contact structure on a substrate; and forming an ohmic electrode layer on the semiconductor layer. The ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
[9] The step of forming the ohmic electrode layer may comprise steps of: sequentially laminating the contact metal layer, the reflective metal layer, and the diffusion barrier layer on the semiconductor layer; performing a thermal treatment process; and forming a bonding metal layer on the diffusion barrier layer. The step of forming the ohmic electrode layer comprises steps of: sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer and bonding metal layer on the semiconductor layer; and performing a thermal treatment process. The thermal treatment process may be a rapid thermal annealing process performed under an atmosphere of 5 to 100% oxygen at a temperature of 100 to 700 °C for 10 to 100 seconds. Description of Drawings
[10] The above and other features and advantages of the present invention will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which:
[11] Fig. 1 is a schematic cross-sectional view showing a p-type ohmic electrode of a gallium nitride-based compound semiconductor layer according to an embodiment of the present invention;
[12] Fig. 2 is a graph showing current versus voltage of ohmic electrodes according to the present invention under different thermal treatment atmospheres;
[13] Fig. 3 is a graph showing contact resistivity of the ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode with respect to thermal treatment temperature;
[14] Fig. 4 is a graph showing reflectance of the ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
[15] Fig. 5 is a graph showing depth profiles of an ohmic electrode according to the present invention, wherein the depth profiles are measured by using a secondary ion- mass spectrosαopy (SIMS) with respect to thermal treatment conditions;
[16] Fig. 6 is a graph showing operation voltage and light output of flip-chip light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
[17] Fig. 7 is a graph showing operation voltage of vertical-structure light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode;
[18] Fig. 8 is a graph showing light output of the vertical-structure light emitting diodes manufactured by using an ohmic electrode according to the present invention and a conventional Ni/Au ohmic electrode; and
[19] Fig. 9 is a photograph of the vertical-structure LED. Best Mode
[20] Hereinafter, a gallium nitride-based compound semiconductor device comprising an ohmic electrode layer and a method of manufacturing the same will be described with reference to the accompanying drawings. The ohmic electrode layer includes a reflective metal layer made of Ag, a diffusion barrier layer made of Ru, a first bonding metal layer made of Ni, and a second bonding metal layer made of Au.
[21] Fig. 1 is a schematic cross-sectional view showing a configuration of an ohmic electrode of a gallium nitride-based compound semiconductor layer according to an embodiment of the present invention.
[22] Referring to Fig. 1, an n-type GaN layer 12, an active layer 13, and a p-type GaN layer 14 are sequentially formed on a substrate 11. Then, a multi-layered ohmic electrode layer is formed by sequentially depositing contact metal/Ag/Ru/Ni/Au metal layers 15 to 19 on the p-type GaN layer 14. The ohmic electrode layer has a total thickness of 300 to 23,000 ?, and more preferably, 2,000 to 5,000 ?. The contact metal layer 15 has a thickness of 5 to 500 ?, and more preferably, 200 ? or less. In addition, the contact metal layer 15 may be formed as a multi-layered thin film. The Ag layer 16 has a thickness of 100 to 9,000 ?, and more preferably, 1,000 to 2,000 ?. The Ru layer 17 has a thickness of 50 to 1,000 ?, and more preferably, 100 to 800 ?. The Ni layer 18 has a thickness of 100 to 3,000 ?, and more preferably, 1,000 ? or less. The Au layer 19 has a thickness of 100 to 9,000 ?, and more preferably, 1,000 ? or less. The thickness of the contact metal layer 15 is selected within the aforementioned range in order to control absorbance of light.
[23] The contact metal layer 15 is made of one of Ni, Ir, Pt, Pd, Au, Ti, Ru, W, Ta, V, Co, Os, Re, and Rh. Alternatively, the contact metal layer 15 may be formed by alternately laminating two different metals of the above-listed metals. Preferably, the contact metal layer 15 is formed by laminating Ni, Ir, and Pt layers.
[24] A method of forming the multi-layered ohmic electrode layer is as follows. Firstly, the n-type GaN layer 12, the active layer 13, and the p-type GaN layer 14 are sequentially formed on a sapphire substrate 11. Next, the p-type GaN layer 14 is subject to a mesa-etching process using inductively coupled plasma (TCP), a surface treatment process, a lithography process, a metal thin film deposition process, and a lift-off process, so that a metal electrode pattern is obtained. The surface treatment process for the p-type GaN layer 14 is performed by immersing the p-type GaN layer 14 in aqua regia (HCl:HNO3 =3:1) for ten minutes, cleaning the resultant product with de-ionized water, and drying the resultant product with nitrogen.
[25] Before the metal layer is deposited, another surface treatment process is performed with a solution of HC1 and de-ionized water (1 : 1) for one minute. Then, in an e-beam evaporator, metal (Me = Ir, Ni, Pt)/Ag/Ru/Ni/Au layers 15 to 19 are sequentially deposited to form an ohmic electrode. Next, the ohmic electrode is subject to a rapid thermal annealing process under an atmosphere of 5% or more oxygen at a temperature of 100 to 700 °C for 10 or more seconds. That is, the rapid thermal annealing process is preferably performed under an atmosphere of 5 to 100 % oxygen at a temperature of 100 to 700 °C for about 10 to 100 seconds. Next, the electrical properties of the ohmic electrode are measured, so that contact resistivity thereof is calculated.
[26] More preferably, the contact metal (Me = Ir, Ni, Pt), Ag, and Ru layers 15 to 17 are sequentially deposited on the p-type GaN layer 14. Then, the resultant product is subject to a thermal treatment process under an oxygen atmosphere. Since the Ru layer 17 serves as a diffusion barrier layer formed on the Ag layer 16 which serves as a r eflecrrve layer, it is possible to prevent diffusion and oxidation of Ag in the Ag layer 16 during the thermal treatment process. Next, the Ni and Au layers 18 and 19 are sequentially deposited on the Ru layer 17, so that the ohmic electrode can be obtained.
[27] Alternatively, an ohmic electrode having a condensed structure may be obtained by sequentially forming the contact metal (Me = Ir, Ni, Pt), Ag, Ru, Ni, and Au layers 15 to 19 and performing a thermal treatment process on the resultant product under an oxygen atmosphere. After the ohmic electrode is formed, a pattern for the ohmic electrode may be formed on the p-type GaN layer 14. In addition, the ohmic electrode may be formed on the n-type nitride layer.
[28] The gallium nitride-based III-V group compound semiconductor is preferably at least one selected from a group of GaN, InGaN, AlGaN, and AlInGaN. The substrate is preferably one of a sapphire substrate, a silicon carbide (SiC) substrate, a silicon (Si) substrate, a zinc oxide (ZnO) substrate, a gallium arsenide (GaAs) substrate, and a gallium phosphate (GaP) substrate. The substrate is more preferably the sapphire substrate.
[29] Fig. 2 is a graph showing current versus voltage of Me (= Ir, Ni, Pt)/Ag/Ru/Ni/Au p-type ohmic electrodes manufactured by performing thermal treatment processes for two minutes at a temperature of 500 °C under different atmospheres of oxygen and nitrogen. In comparison to the nitrogen-atmosphere thermal treatment process, the oxygen-atmosphere thermal treatment process results in the ohmic property of the improved current- voltage properties. [30] Fig. 3 is a graph showing changes of contact resistivities of the Me (= Ir, Ni, Pt)/Ag/Ru/Ni/Au ohmic electrode according to the present invention and a conventional Ni(200 ?)/Au(1000 ?) ohmic electrode with respect to oxygen-atmosphere thermal treatment temperature. 2
[31] As shown in the figure, a low contact resistivity of 7x10-5 Ωcm is obtained by performing a thermal treatment process at a temperature of 500 °C. It should be noted that, during a high temperature thermal treatment process, the contact resistivity of the Me/Ag/Ru/Ni/Au ohmic electrode relatively slowly increases, whereas the contact resistivity of the conventional Ni/Au electrode rapidly increases.
[32] Accordingly, it can be understood that the multi-layered p-type ohmic electrode according to the present invention has good thermal stability.
[33] Fig. 4 is a graph showing reflectance of Me/Ag Me/Ag/Ru, Me/Ag/Ru/Ni/Au ohmic electrodes according to the present invention and the conventional Ni/Au p-type ohmic electrode with respect to wavelength of light. As shown in the figure, at a wavelength of 470 mm, the reflectance of the Me/Ag and Me/Ag/Ru ohmic electrodes is 75%, but the reflectance of the Me/Ag/Ru/Ni/Au ohmic electrode is 90%, which is very high. In addition, it should be noted that the reflectance of the conventional Ni/Au ohmic electrode is 50%. Accordingly, it can be understood that the Me/Ag/Ru/Ni/Au p-type ohmic electrode according to the present invention is very suitable for a high- reflectance electrode of a flip-chip LED.
[34] Fig. 5 is a graph showing depth profiles of an Ir/Ag/Ru/Ni/Au ohmic electrode manufactured by performing a thermal treatment process at a temperature of 500 °C for two minutes, wherein the depth profiles are obtained by using a secondary ion- mass spectrosαopy (SIMS).
[35] In comparison to the nitrogen-atmosphere thermal treatment process, external diffusion of Ga greatly increases by the oxygen-atmosphere thermal treatment process. Therefore, it can be understood that a larger number of Ga- vacancies are generated at an interface between GaN and metal layers after the oxygen-atmosphere thermal treatment process. The Ga-vacanάes serve as acceptors for generating holes, so that the contact resistivity can be further lowered after the oxygen-atmosphere thermal treatment process. Even though the nitrogen- and oxygen-atmosphere thermal treatment processes are performed, the external diffusion of Ag does not occur in a surface of the Ag layer. Therefore, it can be understood that the Ru layer serves as a diffusion barrier layer for preventing external diffusion of Ag. In addition, after oxygen-atmosphere thermal treatment process, AgO is not generated. Therefore, it can be understood that the Ag layer performs its inherent role as a reflective layer. Accordingly, it is possible to obtain high reflectance and good thermal stability by using the ohmic electrode according to the present invention.
[36] Fig. 6 is a graph showing operation voltage and light output of (300 μm x 300 μm) InGaN flip-chip LEDs manufactured by using an Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention and a conventional Ni/Au p-type ohmic electrode. For reference, a figure that schematically shows a method of measuring light outputs of the LEDs is inserted in Fig. 6. At an applied current of 20 mA, the operation voltage of the LED decreases from 3.73 V to 3.65 V, and the light output of the LED greatly increases from 16 a.u. to 31 a.u. Accordingly, in comparison to the conventional Ni/Au ohmic electrode, the high-reflectance Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention improves the properties of the gallium nitride-based III-V group compound semiconductor LED device.
[37] Figs. 7 and 8 are graphs showing operation voltage and light output of (300 μm x 300 μm) InGaN vertical-structure LEDs manufactured by using an Me/Ag/Ru/Ni/Au ohmic electrode according to the present invention and a conventional Ni/Au p-type ohmic electrode, respectively. In Fig. 7, a cross-sectional view of the vertical-structure LED is inserted. Fig. 9 shows a photograph of the vertical-structure LED.
[38] As shown in Figs. 7 and 8, at an applied current of 20 mA, the operation voltage of the LED using the high-reflectance Me/Ag/Ru/Ni/Au ohmic electrode decreases by about 0.1 V, and the light output of the LED increases by about 30 %.
[39] According to the present invention, after an oxygen-atmosphere thermal treatment process, an Me (= Ir, Ni, Pt)/Ag/Ru/Ni/Au ohmic electrodes has low contact resistivity, high thermal stability, and a high reflectance up to about 90%. By employing the Me/ Ag/Ru/Ni/Au ohmic electrode, it is possible to implement a gallium nitride-based III-V group compound semiconductor device having high reliability.
[40] The scope of the present invention is not limited to the embodiment described and illustrated above but is defined by the appended claims. It will be apparent that those sϋlled in the art can make various modifications and changes thereto within the scope of the invention defined by the claims. Therefore, the true scope of the present invention should be defined by the technical spirit of the appended claims. Industrial Applicability [41] As described above, the diffusion barrier layer is interposed between the lower contact and reflective metal layers and the bonding metal layer, so that an ohmic electrode layer having low contact resistivity and improved reflectance can be obtained. In this case, the bonding metal layer is formed after the contact and reflective metal layers are formed. H)wever, if a predetermined thermal treatment process is performed, the bonding metal layer is diffused into a lower layer, so that the properties of the lower contact and reflective metal layers are deteriorated. In order to solve the problem, the reflective metal layer and the diffusion barrier layer are sequentially formed, and then, an oxygen-atmosphere thermal treatment process is performed. As a result, a layer for protecting the lower metal layer can be obtained. That is, in a case where the diffusion barrier layer is made of Ru, the Ru is deposited on the reflective metal layer, and the oxygen-atmosphere thermal treatment process is performed, so that the Ru is oxidized into RuO . As a result, it is possible to effectively protect the 2 reflective metal layer.

Claims

Claims
[1] 1. A gallium nitride-based III-V group compound semiconductor device comprising: a gallium nitride-based semiconductor layer; and an ohmic electrode layer formed on the gallium nitride-based semiconductor layer, wherein the ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
[2] 2. The semiconductor device according to claim 1, wherein the ohmic electrode layer further comprises at least one bonding metal layer.
[3] 3. The semiconductor device according to claim 2, wherein the ohmic electrode layer is formed by sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer, and the bonding metal layer.
[4] 4. The semiconductor according to any one of claims 1 to 3, wherein the contact metal layer comprises at least one of Ni, Ir, Pt, Pd, Au, Ti, Ru, W, Ta, V, Co, Os, Re, and Rh.
[5] 5. The semiconductor according to any one of claims 1 to 3, wherein the reflective metal layer comprises at least one of Al and Ag.
[6] 6. The semiconductor according to any one of claims 1 to 3, wherein the diffusion barrier layer comprises at least one of Ru, Ir, Re, Rh, Os, V, Ta, W, ITO (Indium Tin Oxide), IZO (Indium Zinc oxide), RuO , VO , MgO, IrO , ReO 2 2 2 , RhO , OsO , Ta O , and WO . 2 2 2 2 3 2
[7] 7. The semiconductor according to claim 2 or 3, wherein the bonding metal layer comprises first and second bonding metal layers, said first bonding metal layer comprising at least one of Ni, Cr, Ti, Pd, Ru, Ir, Rh, Re, Os, V, and Ta, said second bonding metal layer comprising at least one of Au, Pd, and Pt.
[8] 8. A method of manufacturing a gallium nitride-based III-V group compound semiconductor device, comprising steps of: forming a gallium nitride-based semiconductor layer having a PN contact structure on a substrate; and forming an ohmic electrode layer on the semiconductor layer, wherein the ohmic electrode layer comprises a contact metal layer, a reflective metal layer, and a diffusion barrier layer.
[9] 9. The method of according to claim 8, wherein the step of forming the ohmic electrode layer comprises steps of: sequentially laminating the contact metal layer, the reflective metal layer, and the diffusion barrier layer on the semiconductor layer; performing a thermal treatment process; and forming a bonding metal layer on the diffusion barrier layer. [10] 10. The method of according to claim 8, wherein the step of forming the ohmic electrode layer comprises steps of: sequentially laminating the contact metal layer, the reflective metal layer, the diffusion barrier layer and bonding metal layer on the semiconductor layer; and performing a thermal treatment process. [11] 11. The method of according to any one of claims 8 to 10, wherein the thermal treatment process is a rapid thermal annealing process performed under an atmosphere of 5 to 100% oxygen at a temperature of 100 to 700 °C for 10 to 100 seconds.
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