WO2005054838B1 - Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity - Google Patents
Method for controlling electrodeposition of an entity and devices incorporating the immobilized entityInfo
- Publication number
- WO2005054838B1 WO2005054838B1 PCT/US2004/039470 US2004039470W WO2005054838B1 WO 2005054838 B1 WO2005054838 B1 WO 2005054838B1 US 2004039470 W US2004039470 W US 2004039470W WO 2005054838 B1 WO2005054838 B1 WO 2005054838B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrodes
- deposition
- entity
- deposition entity
- range
- Prior art date
Links
- 238000004070 electrodeposition Methods 0.000 title claims abstract 4
- 108090000623 proteins and genes Proteins 0.000 claims abstract 5
- 102000004169 proteins and genes Human genes 0.000 claims abstract 5
- 230000005012 migration Effects 0.000 claims abstract 4
- 108090000790 Enzymes Proteins 0.000 claims abstract 3
- 102000004190 Enzymes Human genes 0.000 claims abstract 3
- 239000000725 suspension Substances 0.000 claims abstract 3
- 108010034715 Light-Harvesting Protein Complexes Proteins 0.000 claims abstract 2
- 239000000758 substrate Substances 0.000 claims abstract 2
- 238000003306 harvesting Methods 0.000 claims 6
- -1 cofactors Substances 0.000 claims 3
- 108030002048 EC 1.10.3.9 Proteins 0.000 claims 2
- 108030005866 EC 1.97.1.12 Proteins 0.000 claims 2
- 241000894006 Bacteria Species 0.000 claims 1
- 229940088597 Hormone Drugs 0.000 claims 1
- 102000004856 Lectins Human genes 0.000 claims 1
- 108090001090 Lectins Proteins 0.000 claims 1
- 229920000272 Oligonucleotide Polymers 0.000 claims 1
- 229940067631 Phospholipids Drugs 0.000 claims 1
- 241000700605 Viruses Species 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- 230000000692 anti-sense Effects 0.000 claims 1
- 102000004965 antibodies Human genes 0.000 claims 1
- 108090001123 antibodies Proteins 0.000 claims 1
- 239000000427 antigen Substances 0.000 claims 1
- 102000038129 antigens Human genes 0.000 claims 1
- 108091007172 antigens Proteins 0.000 claims 1
- 235000020639 clam Nutrition 0.000 claims 1
- 239000003814 drug Substances 0.000 claims 1
- 229940079593 drugs Drugs 0.000 claims 1
- 239000005556 hormone Substances 0.000 claims 1
- 239000002523 lectin Substances 0.000 claims 1
- 150000002632 lipids Chemical class 0.000 claims 1
- 239000002502 liposome Substances 0.000 claims 1
- 239000002773 nucleotide Substances 0.000 claims 1
- 125000003729 nucleotide group Chemical group 0.000 claims 1
- 150000003904 phospholipids Chemical class 0.000 claims 1
- 102000004196 processed proteins & peptides Human genes 0.000 claims 1
- 108090000765 processed proteins & peptides Proteins 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 235000000346 sugar Nutrition 0.000 claims 1
- 150000008163 sugars Chemical class 0.000 claims 1
- 229920000160 (ribonucleotides)n+m Polymers 0.000 abstract 1
- 229920003013 deoxyribonucleic acid Polymers 0.000 abstract 1
Abstract
The present invention relates to a method and system for controlling electrodeposition of a deposition entity in which a solution or suspension of the deposition entity is provided between a pair of superposed electrodes at a predetermined concentration. A potential is applied to the electrodes sufficient to cause migration of the deposition entity to one of the electrodes and deposition of a controlled thickness of the deposition entity. The distance between the electrodes and voltage applied can be controlled to provide migration of the deposition entity. The method and system provide controlled immobilization of deposition entities such as proteins, enzymes, light harvesting complexes, DNA, RNA, PNA onto a substrate without loss of function. In one embodiment, the system can be used on a nanoscale. Additionally, devices can be formed by the method of the present invention.
Claims
1. A method for controlling electrodeposition of a deposition entity comprising the steps of: preparing a solution or suspension of said deposition entity at a predetermined concentration; providing said solution to a vicinity between a pair of electrodes, said pair of electrodes being in a superposed relation at a predetermined distance between one another; and applying a predetermined potential across said two electrodes sufficient to cause migration of said deposition entity to one of said electrodes and deposition of said deposition entity on said one of said electrodes.
2. The method of claim 1 wherein the predetermined concentration of said deposition entity is in the range of about 10 μg/ml to about 1 mg/ml and a volume of said solution is in the range of about 1 mm3 to about 100 mm3.
3. The method of claim 2 wherein the distance between said pair of electrodes is in a range of about 10 ran to about 5.0 mm.
4. The method of claim 3 wherein the predetermined potential is in the range of about 1 V/cm to about 1,000 V/cra.
5. The method of claim I wherein a monolayer of said deposition entity is deposited on said one of said electrodes.
6. The method of claim 1 wherein a layer of said deposition entity having a thickness in the range of about 5 nm to about 10 nm is deposited on said one of said electrodes.
7. The method of claim 1 wherein said deposition entity is selected from the group consisting of proteins, peptides, enzymes, enzyme substrates, cofactors, drugs, lectins, sugars, oligonucleotides, DNA7 RNA7 PNA, viruses, bacteria phages, antisense, antigens, haptens, antibodies, amino acids and their derivatives, hormones, lipids, phospholipids, glycolipids, liposomes, nucleotides and light harvesting complexes.
8. The method of claim 1 wherein the deposition entity is selected from the group consisting of proteins, Photosystem I1 Photosystem π, Light Harvesting Complex 1 and Light Harvesting Complex 2.
9 9. The method of claim 1 wherein one of said electrodes are transparent and said deposition entity is selected from the group consisting of proteins, Photosystem I, Photosystem II, Light Harvesting Complex 1 and Light Harvesting Complex 2.
10. The method of claim 1 wherein said solution is provided within a retainer housing positioned between said pair of electrodes.
11 - A device formed by the method of claim 1.
12. The device of claim 11 wherein said deposition entity is selected from the group consisting of proteins, Photosystem I, Photosystem II, Light Harvesting Complex 1 and Light Harvesting Complex 2 and the device is a solid state photosensitive device.
13. The device of claim 12 wherein the device is a photovoltaic device.
14. The device of claim 1 J wherein the device is a biosensor.
15. The device of claim 11 wherein the device is a memory device.
16. An apparatus for electrodeposition of a deposition entity comprising: two electrodes in superimposed relationship; retainer means between said two electrodes for receiving a solution or suspension of said deposition entity; means for applying a potential across said two electrodes sufficient to cause migration of said deposition entity to one of said two electrodes and deposition of said deposition entity on said one of said two electrodes.
17. The apparatus of claim 16 wherein the predetermined concentration of said deposition entity is in the range of about 10 μg/ml to about 1 mg/ml and a volume of said solution is in the range of about 1 mm3 to about 100 mm3
18. The apparatus of claim 16 wherein the distance between said pair of electrodes is in a range of about 10 nm to about 5.0 mm.
19. The apparatus of clam 16 wherein the predetermined potential is in the range of about
1 V/cm to about 1,000 V/cm.
20. The apparatus of claim 16 wherein a monolayer of said deposition entity is deposited on said one of said electrodes.
21. The apparatus of claim 16 wherein a layer of said deposition entity having a thickness in the range of about 5 nm to about 10 nm is deposited on said one of said electrodes.
10
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002549835A CA2549835A1 (en) | 2003-11-26 | 2004-11-24 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity |
| EP04812067A EP1706521A2 (en) | 2003-11-26 | 2004-11-24 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity |
| JP2006541690A JP2007512439A (en) | 2003-11-26 | 2004-11-24 | Method for controlling the electrodeposition of objects and devices incorporating immobilized objects |
| MXPA06005996A MXPA06005996A (en) | 2003-11-26 | 2004-11-24 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity. |
| BRPI0416429-6A BRPI0416429A (en) | 2003-11-26 | 2004-11-24 | electrodeposition control method of an entity and device incorporating the fixed entity |
| AU2004294552A AU2004294552A1 (en) | 2003-11-26 | 2004-11-24 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/722,740 | 2003-11-26 | ||
| US10/722,740 US20050109622A1 (en) | 2003-11-26 | 2003-11-26 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO2005054838A2 WO2005054838A2 (en) | 2005-06-16 |
| WO2005054838A3 WO2005054838A3 (en) | 2006-01-12 |
| WO2005054838B1 true WO2005054838B1 (en) | 2006-03-16 |
Family
ID=34592054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2004/039470 WO2005054838A2 (en) | 2003-11-26 | 2004-11-24 | Method for controlling electrodeposition of an entity and devices incorporating the immobilized entity |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20050109622A1 (en) |
| EP (1) | EP1706521A2 (en) |
| JP (1) | JP2007512439A (en) |
| KR (1) | KR20060096463A (en) |
| CN (1) | CN1902340A (en) |
| AU (1) | AU2004294552A1 (en) |
| BR (1) | BRPI0416429A (en) |
| CA (1) | CA2549835A1 (en) |
| MX (1) | MXPA06005996A (en) |
| TW (1) | TW200525151A (en) |
| WO (1) | WO2005054838A2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050239184A1 (en) * | 2004-04-23 | 2005-10-27 | Reiko Ohara | Electric driven protein immobilizing module and method |
| WO2010119443A1 (en) * | 2009-04-13 | 2010-10-21 | Yissum Research Development Company Of The Hebrew University Of Jerusalem, Ltd. | Process for electrochemical coating of conductive surfaces by organic nanoparticles |
| US10092207B1 (en) | 2016-05-15 | 2018-10-09 | Biolinq, Inc. | Tissue-penetrating electrochemical sensor featuring a co-electrodeposited thin film comprised of polymer and bio-recognition element |
| CN106868572B (en) * | 2017-04-25 | 2019-07-09 | 广东工业大学 | A kind of electrophoresis auxiliary micro-nano particle fusion self assembly surface modifying apparatus |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5569298A (en) * | 1978-11-17 | 1980-05-24 | Kureha Chem Ind Co Ltd | Electrodeposition method of protein |
| JP2600069B2 (en) * | 1985-09-14 | 1997-04-16 | 工業技術院長 | Light sensor |
| JPH0383999A (en) * | 1989-08-28 | 1991-04-09 | Hitachi Ltd | Preparation of oriented protein film, artificial structure comprising the same film and its use |
| US5107104A (en) * | 1989-10-18 | 1992-04-21 | Fuji Photo Film Co., Ltd. | Photoelectric transducer having photosensitive chromoprotein film, i.e. bacteriorhodopsin |
| US5166063A (en) * | 1990-06-29 | 1992-11-24 | Eli Lilly And Company | Immobolization of biomolecules by enhanced electrophoretic precipitation |
| US5346789A (en) * | 1991-12-06 | 1994-09-13 | Cornell Research Foundation, Inc. | Oriented biological material for optical information storage and processing |
| US5855753A (en) * | 1996-11-26 | 1999-01-05 | The Trustees Of Princeton University | Method for electrohydrodynamically assembling patterned colloidal structures |
| US6406921B1 (en) * | 1998-07-14 | 2002-06-18 | Zyomyx, Incorporated | Protein arrays for high-throughput screening |
| US6340421B1 (en) * | 2000-05-16 | 2002-01-22 | Minimed Inc. | Microelectrogravimetric method for plating a biosensor |
| JP4434013B2 (en) * | 2002-05-07 | 2010-03-17 | ユニバーシティ オブ サザン カリフォルニア | Method and apparatus for measuring the quality of a deposit during a plating process using conformable contact mask plating |
-
2003
- 2003-11-26 US US10/722,740 patent/US20050109622A1/en not_active Abandoned
-
2004
- 2004-11-24 CA CA002549835A patent/CA2549835A1/en not_active Abandoned
- 2004-11-24 AU AU2004294552A patent/AU2004294552A1/en not_active Abandoned
- 2004-11-24 EP EP04812067A patent/EP1706521A2/en not_active Withdrawn
- 2004-11-24 CN CNA2004800391550A patent/CN1902340A/en active Pending
- 2004-11-24 KR KR1020067012495A patent/KR20060096463A/en not_active Application Discontinuation
- 2004-11-24 WO PCT/US2004/039470 patent/WO2005054838A2/en active Application Filing
- 2004-11-24 JP JP2006541690A patent/JP2007512439A/en active Pending
- 2004-11-24 BR BRPI0416429-6A patent/BRPI0416429A/en not_active IP Right Cessation
- 2004-11-24 MX MXPA06005996A patent/MXPA06005996A/en unknown
- 2004-11-25 TW TW093136320A patent/TW200525151A/en unknown
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