WO2005042671A1 - Process and system for removing contaminants from a natural gas stream - Google Patents
Process and system for removing contaminants from a natural gas stream Download PDFInfo
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- WO2005042671A1 WO2005042671A1 PCT/EP2004/052690 EP2004052690W WO2005042671A1 WO 2005042671 A1 WO2005042671 A1 WO 2005042671A1 EP 2004052690 W EP2004052690 W EP 2004052690W WO 2005042671 A1 WO2005042671 A1 WO 2005042671A1
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- gas stream
- gas
- adsorbent bed
- contaminants
- temperature
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G5/00—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas
- C10G5/02—Recovery of liquid hydrocarbon mixtures from gases, e.g. natural gas with solid adsorbents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
- B01D5/0033—Other features
- B01D5/0054—General arrangements, e.g. flow sheets
Definitions
- the invention relates to a process for removing water and hydrocarbons from a natural gas stream.
- natural gas is applied to gas produced from underground accumulations of widely varying composition.
- the main constituent of natural gas is methane.
- natural gas Apart from methane, natural gas generally includes other hydrocarbons, nitrogen, carbon dioxide, sometimes a small proportion of hydrogen sulphide, and often water.
- Hydrocarbon constituents include ethane (C ) , propane (C3), butane (C4), pentane(C5), hexane(Cg), heptane (C7), etc. Hydrocarbons having 5 or more carbon atoms are generally referred to as C5+.
- the invention relates in particular to the removal of contaminants by partial condensation followed by gas/liquid separation, and contaminants that can be removed in this way are also sometimes referred to as condensables .
- the lighter constituents, C]_ up to and including C4 are in gaseous phase at atmospheric temperatures and pressures.
- the heavier constituents, C5+ are in gaseous phase when at elevated temperatures during production from the subsurface and in liquid phase when the gas mixture has cooled down. Natural gas containing such heavier constituents is known as "wet gas" as distinct from dry gas containing none or only a small proportion of liquid hydrocarbons.
- the removal of contaminants, in particular water and hydrocarbons, from natural gas streams is important to prevent problems that can occur during their transportation.
- the pressure loss which is inevitable in pipeline systems, causes liquids to be formed as a result of condensation of water and/or hydrocarbons. Slugs of these liquids can cause problems, such as plugging of pipelines and distribution systems.
- liquid water can accelerate corrosion.
- a useful parameter for indicating the water content of any gas is in terms of the dewpoint.
- the dewpoint is generally defined as the temperature to which a gas must be cooled (at constant water content) in order for it to become saturated with respect to water vapour (i.e. attain equilibrium with liquid water) .
- the cricondenbar highest pressure at a given temperature at which a vapour-liquid equilibrium is present
- cricondentherm highest temperature at a given pressure at which a vapour-liquid equilibrium is present
- the adsorbent is once again cooled to its initial temperature.
- This reversion of the adsorption process is called regeneration. Therefore in total three adsorption beds are provided in the known process, one of them being in adsorption mode, one of them being regenerated by passing a slipstream of the untreated natural gas stream at an elevated temperature over the bed so that adsorbed contaminants are removed from the bed, and one of them being cooled by the slipstream after the bed was regenerated.
- the slipstream is first passed through the bed to be cooled, then heated, and passed through the bed to be regenerated.
- the slipstream takes up contaminants that are removed from the adsorbent bed in regeneration mode.
- the contaminated slipstream is then passed through an air and water cooler, so that contaminants that condense at the temperature of water (above hydrate formation temperature) can be separated off as a liquid in a separator.
- the flash gas is recycled to the natural gas stream to be treated, upstream of adsorption bed in adsorption mode.
- a problem in the use of adsorbent beds to remove water and/or hydrocarbons from a natural gas stream is that it is not always possible to achieve a sufficiently low cricondentherm of the resulting purified gas stream from the bed in adsorption mode. Therefore, there is a need for a process enabling the removal of contaminants, typically both water and hydrocarbons, from the natural gas, to achieve a certain desired cricondentherm.
- the process of the invention allows an advantageous and efficient treatment of the part of the natural gas stream (first gas stream) that is used for regeneration. Regenerating the first adsorbent bed results in an increase in contaminants content of the second gas stream leaving the bed as compared to the first gas stream entering the bed. Although in this way the adsorbent bed can be regenerated, the regeneration gas now is of (far) worse quality than the original natural gas stream. This is a problem since it is generally desired to recycle the regeneration gas stream to an adsorbent bed in adsorption mode.
- this problem is solved by cooling the regeneration gas in an air and water cooler, so as to condense part of the contaminants into a liquid phase, and by separating the liquid phase from the regeneration gas .
- Applicant has found that the quality of the regeneration gas stream obtained in this way is, at best, comparable to the quality of the original natural gas stream, in terms of the cricondentherm of the streams, and in terms of the water and hydrocarbon constituents contributing to the criconderterm.
- applicant has realized that it is beneficial to purify the regeneration gas further, by performing a second gas/liquid separation step wherein further contaminants are condensed into a liquid and separated off phase so that a lean gas is obtained. In this way actually a better quality of the regeneration gas can be obtained than the original natural gas stream.
- the regeneration gas is first enriched in contaminants, and then contaminants are removed so that overall the contaminants level is decreased.
- another part of the natural gas stream is contacted with a second adsorbent bed in adsorption mode, to obtain a purified gas stream.
- a purified gas stream can be obtained that is of better quality than what is obtainable with the known process, due to the better quality of the lean gas that is recycled from regeneration. It has been found that this is a very efficient way to improve the quality of the purified gas, just sufficiently to obtain required specifications in many practical situations, without having to modify other parts of the process such as the absorption step.
- the lean gas stream has a cricondentherm lower than that of the natural gas stream, preferably at least 10 °C lower, more preferably at least 15 °C lower, most preferably at least 20 °C lower.
- the lean gas stream suitably has a cricondentherm below 10 °C, preferably below 6 °C, more preferably below 0 °C, most preferably below -5 °C.
- the purified gas stream obtained from the second adsorbent bed suitably has a cricondentherm below 10 °C, preferably below 6 °C, more preferably below 0 °C, most preferably below -5 °C, or even below -10 °C.
- the cooling in step (b) is suitably done against a temperature above water freezing temperature, in particular using a water cooler.
- the temperature of the second adsorbent bed is suitably at ambient temperature, such as between 5 and 45 °C, preferably between 20 and 30 °C.
- the temperature of the first adsorbent bed is suitably between 200 and 350 °C, preferably between 250 and 325 °C, more preferably between 275 and 310 °C such as 280 or 300 °C.
- Step (c) comprises cooling the third gas stream to a temperature that is below a temperature at which contaminants in the third gas stream will begin to condense into a second liquid phase, and separating the second liquid phase from the third gas stream.
- the third gas stream is cooled to a temperature below the cooling temperature in step (b) , preferably to a temperature below water freezing temperature (0 °C) , more preferably to a temperature below -5 °C.
- the second gas/liquid separation in step (c) is effected by means of an accelerated velocity inertia separator.
- Such a separator creates a fluid stream flowing at accelerated velocity and causes said fluid stream to cool to a temperature at which water and hydrocarbons will condense into a second liquid water/hydrocarbon phase.
- the accelerated velocity inertia separator is advantageously a supersonic inertia separator and the fluid stream flows at supersonic velocity.
- a swirling motion can suitably be induced to the fluid stream flowing at supersonic velocity, thereby causing the contaminants, in particular water and hydrocarbons, to flow to a radially outer section of a collecting zone in the stream.
- Such a separator is advantageous as it is very efficient to remove contaminants that influence the cricondentherm, in particular water and hydrocarbons.
- Such a separator is as such known from US patent specification No.
- Step (a) comprises suitably heating the first gas stream in a heating zone to obtain a heated first gas stream; and contacting the heated first gas stream with the first adsorbent bed in regeneration mode. Heating of the adsorbent bed to elevated temperature is in this way effected by the regeneration gas.
- the first gas stream can be passed through a third adsorbent bed in cooling mode, prior to being contacted with the first adsorbent bed.
- the invention further provides a system for removing contaminants from a natural gas stream, the system comprising: a first adsorption bed arranged to receive part of the natural gas stream as a first gas stream, and provided with a means for heating the first adsorbent bed, which first adsorption bed has an outlet for a second gas stream a cooler for cooling the second gas stream; a first gas/liquid separator for separating the cooled second gas stream into a first liquid phase and a third gas stream; and a second gas/liquid separator for separating the third gas stream into a second liquid phase and a lean gas stream.
- the system suitably further comprises a second adsorbent bed arranged to receive another part of the natural gas stream at a temperature at which contaminants are adsorbed, and having an outlet for a purified gas stream.
- the second adsorbent bed can in particular be arranged to receive the lean gas stream together with the other part of the natural gas stream.
- the first gas/liquid separator suitably comprises a cooler condensing liquid at a temperature above the freezing point of water, such as a water and/or air cooler, and wherein the second gas/liquid separator is arranged to separate contaminants that condense at a temperature lower than 0 °C.
- the second gas/liquid separator can advantageously be an accelerated velocity inertia separator, preferably a supersonic inertia separator.
- the second gas/liquid separator can also comprise a refrigerator.
- the process and system according to the invention allows, in addition to the removal of water, the removal of hydrocarbons from the feed gas stream, resulting in a lower cricondentherm compared to the feed gas stream.
- the extent of removal of water and hydrocarbons from the feed gas stream can be steered, thereby creating a fourth (lean) gas stream with a desired cricondentherm, even in cases where the composition of the feed gas stream is such that a lowering of the cricondentherm to a sufficiently low level could not have been achieved using other techniques such as the process using only adsorption.
- the composition of the natural gas stream can vary.
- the natural gas stream comprises water in concentrations in the range of from 0.01 to 4 mol%, preferably from 0.05 to 2 mol%.
- C3 and C4 hydrocarbons in the feed gas stream is typically in the range of from 0.4 to 4 mol%, in particular from 1.0 to 3 mol%.
- concentration of C5+ hydrocarbons in the feed gas stream is typically in the range of from 0.05 to 5 mol%, in particular from 0.1 to 3 mol%, based on the feed gas stream.
- Contacting part of the natural gas stream is contacted as a first gas stream at an elevated temperature with a first adsorbent bed in regeneration mode, to remove contaminants present on the first adsorbent bed.
- the elevated temperature is suitably provided by heating the part of the feed gas stream in a heating zone to obtain a heated first gas stream.
- the part of the feed gas stream heated in a heating zone is in the range of from 10 to 60%, preferably from 20 to 50%, more preferably 30% or less of the total feed gas stream.
- heating temperatures in the heating zone are in the range of from 150 to 450 °C, preferably from 200 to 400 °C, or from 250 to 350 °C.
- the heated first gas stream is contacted with a first adsorbent bed, the first adsorbent bed being in the regeneration mode, to obtain a second gas stream.
- Adsorption of components from a gas mixture through solid adsorbents is a thermal exothermic process. This process can be reverted by applying heat to the adsorbent and adsorbate phase.
- the adsorbed components will leave the adsorbent internal surface and pores.
- the adsorbent is once again cooled to its initial temperature. This reversion of the adsorption process is called regeneration.
- Reference herein to the first adsorption bed being in regeneration mode is to the first adsorption bed, comprising adsorbed contaminants, predominantly water and/or hydrocarbons, being subjected to conditions which will cause the adsorbed components to leave the adsorbent internal surface and pores and to be transferred to the heated gas stream.
- the first adsorbent bed at least part of the adsorbed components are transferred from the first adsorbent bed to the heated first gas stream to obtain a second gas stream.
- the temperature at which the first adsorbent bed is subjected via the heated regeneration stream is in the range of from 200 to 350 °C, more preferably from 250 to 330 °C, to enable the regeneration of the adsorbent without causing thermal instability of the adsorbent.
- the second gas stream obtained after step (b) is typically enriched in contaminants, typically in water and in C5+ hydrocarbons, compared to the heated first gas stream.
- the amount of water in the second gas stream is in the range of from 1.1 to 20 times, more typically from 2 to 10 times the amount of water in the total heated gas stream.
- the amount of C5+ hydrocarbons in the second gas stream is in the range of from 1.5 to 25 times, in particular from 3 to 15 times the amount of water in the total heated gas stream.
- the pressure of the second gas stream is lower than the pressure of the heated first gas stream, typically 1 to 10 bar lower.
- the second gas stream is cooled to a temperature such that at least some water and some hydrocarbons will begin to condense into a first liquid water/hydrocarbon phase.
- the cooling temperature can be adjusted and depends on the temperature of the second gas stream.
- cooling is done by means of an air and/or water cooler, and cooling temperatures are typical air or water temperatures, in particular above the freezing point of water, such as above the freeing the range of from 0 to + 10 °C.
- cooling temperatures are typical air or water temperatures, in particular above the freezing point of water, such as above the freeing the range of from 0 to + 10 °C.
- the first liquid water/hydrocarbon phase comprises water and C5+ as the principal components.
- the liquid water/hydrocarbon phase comprises between 5 and 90 wt% water, more preferably between 10 and 80 wt%, most preferably between 15 and 50 wt%, based on the total water/hydrocarbon phase.
- the first liquid water/hydrocarbon phase is separated from the second gas stream and discharged to create a third gas stream depleted of contaminants.
- the separation can for example be achieved using a gas/liquid separator, in particular a high pressure separation vessel.
- the third gas stream typically comprises water in the range of from 0.01 to 1 mol%, in particular from 0.05 to 5 mol%, more in particular 0.1 to 2 mol%, based on the third gas stream.
- the third gas stream is enriched in hydrocarbon contaminants.
- the third gas stream comprises C2+ hydrocarbon contaminants in the range of from 0.5 to 5 mol%, based on the total third gas stream.
- the third gas stream is suitably cooled to a temperature that is below a temperature at which water and hydrocarbons that are still present after the first separation step, will begin to condense into a second water/hydrocarbon phase.
- the cooling in step (c) is achieved by leading the third gas stream through a conduit of an accelerated velocity inertia separator, thereby creating a fluid stream flowing at accelerated velocity. This fluid stream is then caused to cool to a temperature that is below a temperature at which water and hydrocarbons will begin to condense into a second liquid water/hydr ⁇ carbon phase.
- this embodiment is especially suitable in cases where the feed gas stream, and hence the third gas stream, has a relatively high pressure compared to the required pressure of the fourth gas stream (lean gas stream) .
- the pressure of the third gas stream is in the range of from 80 to 150 bar, preferably from 90 to 140 bar, the use of an accelerated velocity inertia separator is preferred.
- references herein to an accelerated velocity inertia separator is to an apparatus wherein a fluid stream is induced to flow at accelerated velocity through a conduit, so as to decrease the temperature of the fluid in the conduit to below a temperature at which a selected component will condense into a second liquid water/hydrocarbon phase.
- the accelerated velocity inertia separator is a supersonic inertia separator wherein the velocity in the radially outer section and in the central part of the stream is supersonic. Suitable supersonic velocity inertia separators are described in
- the supersonic inertia separator causes the fluid stream to flow at supersonic velocity. This causes a rapid expansion, resulting in cooling of a compressible fluid stream. The cooling results in condensation of vapours to the extent that such cooling brings the temperature of the stream to a temperature below a point where components will condense to form a separate second water/hydrocarbon phase.
- the conduit is provided with swirl imparting means to impart a swirling motion to the stream of fluid flowing at accelerated velocity.
- a swirling motion is induced to the stream of fluid flowing at supersonic velocity, thereby causing the water and hydrocarbons to flow to a radially outer section of the regenerated gas stream.
- a wing placed in the supersonic flow region imparts the swirling motion.
- Reference herein to the supersonic flow region is to the part of the conduit of the supersonic velocity inertia separator wherein the fluid stream flows at supersonic velocity.
- a shock wave is created in the stream that is upstream of the radially outer section and downstream of the location where the swirling motion has been imparted.
- the shock wave is created by inducing the stream of fluid to flow through a diffuser.
- a diffuser may be a diverging volume, or a converging and a diverging volume. It was found that the separation efficiency is significantly improved if collection of the condensed particles takes place after the shock wave, i.e.
- the second gas/liquid separation step includes cooling by means of refrigeration.
- This embodiment is especially suitable in cases where the pressure of the feed gas stream, and hence also the pressure of the third gas stream, is relatively low compared to the required pressure of the fourth gas stream.
- the pressure of the third gas stream is in the range of from 10 to 100 bar, preferably from 30 to 80 bar, refrigeration as cooling means in step (e) is advantageous.
- methanol is preferably added in the refrigeration step.
- the second liquid water/hydrocarbon phase is separated from the third gas stream and discharged, to create a fourth gas stream.
- the second liquid water/ hydrocarbon phase is enriched in C2+ components.
- the second liquid water/hydrocarbon phase is suitably separated in a first outlet stream from a radially outer section of the third gas stream.
- the remaining fourth gas stream is collected in a second outlet stream from a central part of the third gas stream.
- the fourth gas stream obtained after step (f) comprises between 0.001 and 4 mol% of total components selected from the group of C2, C3 and C4, more typically between 0.01 and 3 mol%, most typically between 0.5 and 2 mol%, based on the total fourth gas stream.
- the process further comprises the step of contacting another part of the feed gas stream with a second adsorbent bed to remove in particular water and C5+ hydrocarbons.
- the resulting purified gas stream exiting the second adsorbent bed is typically depleted of water and of hydrocarbons with respect to the natural gas feed stream.
- the pressure of the other part of the feed gas stream is adjusted prior to being contacted with the second adsorbent bed, in order to conform to the operating pressure of the adsorbent bed.
- Typical operating pressures of the second adsorbent bed are between 40 and 120 bar, preferably between 70 to 100 bar.
- temperatures in the second adsorbent bed are in the range of from 5 to 50 °C, more preferably from 15 to 40 °C, most preferably from 20 to 30 °C. This enables sufficient removal of water and/or hydrocarbon contaminates without the need for excessive heating.
- In the adsorbent bed generally two zones, an equilibrium zone and a mass transfer zone, can be distinguished.
- the amount of adsorbed material of a component is in equilibrium with the partial pressure of the component in the feed.
- the adsorbent is actively adsorbing the component from the gas stream.
- Suitable adsorbents in the first and in the second adsorbent bed are solids having a microscopic structure.
- the internal surface of such adsorbents is preferably between 100 and 2000 m2/g, more preferably between 500 and 1500 m 2 /g.
- the nature of the internal surface of the adsorbent in the adsorbent bed is such that water and C5+ hydrocarbons are adsorbed.
- the internal surface of the adsorbent is polar.
- Suitable adsorbent materials include materials based on silica, silica gel, alumina or silica-alumina. Zeolite type adsorbents are preferred. Generally, in the adsorbent bed water is preferentially adsorbed over hydrocarbons. C5+ hydrocarbons, hydrocarbons having 5 or more carbon atoms, will generally be preferentially adsorbed over lighter hydrocarbons such as C2, C3 or C4. Typically, water is adsorbed to the extent that the resulting concentrations are in the range of from 0.001 to 0.5 mol%, in particular from 0.01 to 0.4 mol%, more in particular 0.05 to 0.2 mol%.
- C5+ hydrocarbons are adsorbed to the extent that the resulting concentrations are in the range of from 0.01 to 1 mol%, in particular from 0.05 to 0.5 mol%.
- the first and second adsorbent bed can alternatively be either in the adsorbent mode or in the regenerating mode, or optionally in a cooling mode. Although the preferred embodiment is described for two adsorbent beds, other embodiments wherein more than two adsorbent beds are used are comprised in the invention.
- the process further comprises the step of contacting the fourth (lean) gas stream with the second adsorbent bed to further remove water and C5+ hydrocarbons from the fourth gas stream, thereby obtaining a purified gas stream exiting the second adsorbent bed.
- the pressure of the fourth gas stream is adjusted prior to being contacted with the second adsorbent bed, for example using a compressor, in order to conform to the operating pressure of the adsorbent bed. More preferably, the pressure of the fourth gas stream is increased to a value of between 50% and 100% of the pressure of the feed gas stream, most preferably to a value of between 60% and 90% of the pressure of the feed gas stream.
- the purified gas stream exiting the second adsorbent bed is further depleted of water and/or hydrocarbons and has a lower cricondenther than the feed stream.
- C3, C4, C5+ hydrocarbons and water and having a starting pressure of 120 bara is led via line 1 to a valve (2) to decrease the pressure.
- the part of the feed gas stream with a decreased pressure is led via line (3) to a second adsorbent bed (4) comprising solid adsorbent material.
- water and 05+ hydrocarbons are adsorbed to create a purified gas stream depleted of water and C5+ hydrocarbons which is discharged from the first adsorbent bed via line (5) .
- Another part of the feed gas stream is led via line (6) to a heating zone (7) where it is heated.
- the heated first gas stream is led via line (8) to a first adsorbent bed (9), the first adsorbent bed being in the regeneration mode, to create a second gas stream enriched in contaminants, in particular water and C5+ hydrocarbons.
- This second gas stream is led via line (10) to a cooling unit (11) which can be a water cooler, where it is cooled to a temperature such that water and hydrocarbons condense into a first liquid water/hydrocarbon phase.
- the cooled gas stream comprising the first liquid water/hydrocarbon phase is led via line (12) to a gas/liquid separator (13) where the first liquid water/hydrocarbon phase is separated and led from the gas/liquid separator via line (14) .
- the resulting third gas stream is led from the gas/liquid separator to a further gas/liquid separator step via line (15) .
- Reference numeral (16) can for example be an accelerated velocity inertia separator, or refrigerator together with a gas/liquid separation means.
- the third gas stream is caused to cool to a temperature that is below a temperature/pressure at which water and hydrocarbons condense into a second liquid water/ hydrocarbon phase, the hydrocarbons in the water/ hydrocarbon phase mostly comprising C3+ components.
- the second liquid water/hydrocarbon phase is separated from the fluid stream and is led from the cooling device via line (17) .
- Example 1 (Comparative example) In the comparative example use is made of a line-up as shown in Figure 1, but without the separator means 16 and compressor 19. Part of a feed natural gas stream having a composition as shown in Table 1 is contacted with a second adsorbent bed, the second adsorbent bed being in the adsorbing mode. The pressure of the feed gas stream is 80 bara.
- the temperature of the feed gas is 25 °C. Another part (for example 30%) of the feed gas stream is heated to obtain a first heated gas stream.
- the heated first gas stream is contacted with a first adsorbent bed, the first adsorbent bed being in the regeneration mode, to create a second gas stream enriched in water and C5+ hydrocarbons.
- the second gas stream is cooled to a temperature such that water and hydrocarbons condense into a first liquid water/hydrocarbon phase.
- the first liquid water/hydrocarbon phase is separated.
- the composition of the resulting gas stream is given in Table 1.
- the resulting gas stream that is recycled from regeneration is of lower quality than the feed gas, in particular the methane content is lower, and C5-C7 and water content are higher.
- Table 1 Composition of gas streams in example 1 (in mol%) .
- Example 2 A feed gas having a composition as shown in Table 2 is subjected to a process based on example 1, but now according to the present invention as described in figure 1, the cooling device (16) being an accelerated inertia separator.
- the resulting composition of the 2 nd , 3 rd and 4 th (lean) gas stream are given in Table 2.
- Table 2 Composition of gas streams in example 2 (in mol%) .
- Example 3 A feed gas having a composition as shown in Table 3 is subjected to a process as described in figure 1, the cooling device (16) being a refrigerator, run at 80 bar and -7 °C.
- the resulting composition of the 2 nd , 3 rd and 4 th (lean) gas stream are given in Table 3.
- Table 3 Composition of gas streams in example 3 (in mol%) .
- Example 4 A feed gas having a composition as shown in Table 4 is subjected to a process as described in figure 1, the cooling device (16) being a refrigerator, run at 80 bar and -7 °C. Methanol was added in sufficient quantities to prevent hydrate formation. The resulting composition of the 2 nd , 3 rd and 4 th gas stream are given in Table 4.
- the cricondentherm of the resulting fourth (lean) gas stream for examples 2 to 4 are given in Table 5.
- the cricondentherm of the resulting gas stream (comparable with the fourth gas stream in the process according to the invention) is given. From Table 5 it is clear that all processes according to the invention (examples 2,3 and 4) result in a (fourth) gas stream having a lower cricondentherm compared to the gas stream obtained after a process according to the comparative example.
- Table 5 Cricondentherm (in °C) of the fourth gas stream (in the case of example 1: of the resulting gas stream) .
Abstract
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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EP04791326A EP1678276A1 (en) | 2003-10-30 | 2004-10-28 | Process and system for removing contaminants from a natural gas stream |
CA002543539A CA2543539A1 (en) | 2003-10-30 | 2004-10-28 | Process and system for removing contaminants from a natural gas stream |
US10/577,200 US20070267328A1 (en) | 2003-10-30 | 2004-10-28 | Process and System for Removing Contaminants from a Natural Gas Stream |
AU2004285080A AU2004285080B2 (en) | 2003-10-30 | 2004-10-28 | Process and system for removing contaminants from a natural gas stream |
NO20062436A NO20062436L (en) | 2003-10-30 | 2006-05-29 | Method and system for removing contaminants from a natural gas stream |
Applications Claiming Priority (2)
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EP03024785 | 2003-10-30 | ||
EP03024785.2 | 2003-10-30 |
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WO2005042671A1 true WO2005042671A1 (en) | 2005-05-12 |
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US (1) | US20070267328A1 (en) |
EP (1) | EP1678276A1 (en) |
AU (1) | AU2004285080B2 (en) |
CA (1) | CA2543539A1 (en) |
NO (1) | NO20062436L (en) |
WO (1) | WO2005042671A1 (en) |
Cited By (4)
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WO2014021900A1 (en) * | 2012-08-03 | 2014-02-06 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
WO2014022510A3 (en) * | 2012-08-03 | 2014-07-03 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
US9631864B2 (en) | 2012-08-03 | 2017-04-25 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
RU2640050C1 (en) * | 2017-02-02 | 2017-12-26 | Публичное акционерное общество криогенного машиностроения (ПАО "Криогенмаш") | Method for removing heavy hydrocarbons when liquefying natural gas and device for its implementation |
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WO2014081649A1 (en) * | 2012-11-21 | 2014-05-30 | Uop Llc | Supersonic gas separation and adsorption processes for natural gas dehydration systems |
DE102014005935A1 (en) * | 2014-04-24 | 2015-10-29 | Linde Aktiengesellschaft | Process for separating heavy hydrocarbons |
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- 2004-10-28 EP EP04791326A patent/EP1678276A1/en not_active Withdrawn
- 2004-10-28 WO PCT/EP2004/052690 patent/WO2005042671A1/en active Application Filing
- 2004-10-28 CA CA002543539A patent/CA2543539A1/en not_active Abandoned
- 2004-10-28 AU AU2004285080A patent/AU2004285080B2/en not_active Ceased
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2006
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US3378992A (en) * | 1964-07-17 | 1968-04-23 | Continental Oil Co | Gas treating process utilizing overlapping adsorption phases |
DE19840409C1 (en) * | 1998-09-04 | 2000-01-20 | Fraunhofer Ges Forschung | Dehumidification of gas by condensation |
WO2000023757A1 (en) * | 1998-10-16 | 2000-04-27 | Translang Technologies Ltd. | Vortex tube for liquefaction and separation of components in a gas mixture |
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Cited By (8)
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WO2014021900A1 (en) * | 2012-08-03 | 2014-02-06 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
WO2014022510A3 (en) * | 2012-08-03 | 2014-07-03 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
CN104685036A (en) * | 2012-08-03 | 2015-06-03 | 气体产品与化学公司 | Heavy hydrocarbon removal from a natural gas stream |
AU2013296552B2 (en) * | 2012-08-03 | 2016-09-15 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
RU2599582C2 (en) * | 2012-08-03 | 2016-10-10 | Эр Продактс Энд Кемикалз, Инк. | Removal of heavy hydrocarbons from natural gas flow |
US9631864B2 (en) | 2012-08-03 | 2017-04-25 | Air Products And Chemicals, Inc. | Heavy hydrocarbon removal from a natural gas stream |
CN104685036B (en) * | 2012-08-03 | 2017-07-11 | 气体产品与化学公司 | Heavy hydrocarbon is removed from natural gas flow |
RU2640050C1 (en) * | 2017-02-02 | 2017-12-26 | Публичное акционерное общество криогенного машиностроения (ПАО "Криогенмаш") | Method for removing heavy hydrocarbons when liquefying natural gas and device for its implementation |
Also Published As
Publication number | Publication date |
---|---|
CA2543539A1 (en) | 2005-05-12 |
AU2004285080A1 (en) | 2005-05-12 |
US20070267328A1 (en) | 2007-11-22 |
EP1678276A1 (en) | 2006-07-12 |
NO20062436L (en) | 2006-05-29 |
AU2004285080B2 (en) | 2008-04-24 |
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