WO2005040326A1 - Method of cleaning - Google Patents
Method of cleaning Download PDFInfo
- Publication number
- WO2005040326A1 WO2005040326A1 PCT/GB2004/003979 GB2004003979W WO2005040326A1 WO 2005040326 A1 WO2005040326 A1 WO 2005040326A1 GB 2004003979 W GB2004003979 W GB 2004003979W WO 2005040326 A1 WO2005040326 A1 WO 2005040326A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foam
- acid
- cleaning
- fabric
- water
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000006260 foam Substances 0.000 claims abstract description 74
- 239000000203 mixture Substances 0.000 claims abstract description 60
- 238000009472 formulation Methods 0.000 claims abstract description 26
- 239000004744 fabric Substances 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 229920003023 plastic Polymers 0.000 claims description 33
- 239000004033 plastic Substances 0.000 claims description 33
- 230000001413 cellular effect Effects 0.000 claims description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 238000005273 aeration Methods 0.000 claims description 7
- 239000003599 detergent Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 8
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract description 6
- 229940045872 sodium percarbonate Drugs 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- -1 sodium percarbonate Chemical compound 0.000 description 60
- 229920005646 polycarboxylate Polymers 0.000 description 19
- 229940123150 Chelating agent Drugs 0.000 description 18
- 239000002738 chelating agent Substances 0.000 description 18
- 239000002253 acid Substances 0.000 description 17
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 125000000217 alkyl group Chemical group 0.000 description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
- 239000002736 nonionic surfactant Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- 235000021317 phosphate Nutrition 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000009471 action Effects 0.000 description 7
- 150000001340 alkali metals Chemical class 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 150000001860 citric acid derivatives Chemical class 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 150000003138 primary alcohols Chemical class 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000006071 cream Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229940071089 sarcosinate Drugs 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 4
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 4
- 150000002978 peroxides Chemical group 0.000 description 4
- 150000004965 peroxy acids Chemical class 0.000 description 4
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Natural products NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000004904 UV filter Substances 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 2
- UURYKQHCLJWXEU-UHFFFAOYSA-N 2-(2-hydroxypropanoyloxy)butanedioic acid Chemical class CC(O)C(=O)OC(C(O)=O)CC(O)=O UURYKQHCLJWXEU-UHFFFAOYSA-N 0.000 description 2
- CQWXKASOCUAEOW-UHFFFAOYSA-N 2-[2-(carboxymethoxy)ethoxy]acetic acid Chemical compound OC(=O)COCCOCC(O)=O CQWXKASOCUAEOW-UHFFFAOYSA-N 0.000 description 2
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CKLJMWTZIZZHCS-UHFFFAOYSA-N Aspartic acid Chemical class OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical class OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
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- 235000010447 xylitol Nutrition 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 description 1
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 1
- JUAGNSFMKLTCCT-UHFFFAOYSA-N 2-aminoacetic acid;carbonic acid Chemical compound OC(O)=O.NCC(O)=O JUAGNSFMKLTCCT-UHFFFAOYSA-N 0.000 description 1
- XPTYFQIWAFDDML-UHFFFAOYSA-N 2-aminoacetic acid;ethanol Chemical class CCO.NCC(O)=O.NCC(O)=O XPTYFQIWAFDDML-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- CJAZCKUGLFWINJ-UHFFFAOYSA-N 3,4-dihydroxybenzene-1,2-disulfonic acid Chemical class OC1=CC=C(S(O)(=O)=O)C(S(O)(=O)=O)=C1O CJAZCKUGLFWINJ-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- ORWQBKPSGDRPPA-UHFFFAOYSA-N 3-[2-[ethyl(methyl)amino]ethyl]-1h-indol-4-ol Chemical compound C1=CC(O)=C2C(CCN(C)CC)=CNC2=C1 ORWQBKPSGDRPPA-UHFFFAOYSA-N 0.000 description 1
- LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- YKROIAMLMVENMW-UHFFFAOYSA-N CCC(=O)ON(OC(=O)CC)CCN(OC(=O)CC)OC(=O)CC Chemical class CCC(=O)ON(OC(=O)CC)CCN(OC(=O)CC)OC(=O)CC YKROIAMLMVENMW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XXAXVMUWHZHZMJ-UHFFFAOYSA-N Chymopapain Chemical compound OC1=CC(S(O)(=O)=O)=CC(S(O)(=O)=O)=C1O XXAXVMUWHZHZMJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- BCXBKOQDEOJNRH-UHFFFAOYSA-N NOP(O)=O Chemical class NOP(O)=O BCXBKOQDEOJNRH-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical class [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000011128 aluminium sulphate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- ACWQSLXTIYNAJO-UHFFFAOYSA-N azanium;nonyl sulfate Chemical compound [NH4+].CCCCCCCCCOS([O-])(=O)=O ACWQSLXTIYNAJO-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 235000015116 cappuccino Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical group 0.000 description 1
- CSMFSDCPJHNZRY-UHFFFAOYSA-N decyl hydrogen sulfate Chemical compound CCCCCCCCCCOS(O)(=O)=O CSMFSDCPJHNZRY-UHFFFAOYSA-N 0.000 description 1
- CNTVAYPTVYVIFS-UHFFFAOYSA-N decyl octyl sulfate Chemical compound CCCCCCCCCCOS(=O)(=O)OCCCCCCCC CNTVAYPTVYVIFS-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NNCAWEWCFVZOGF-UHFFFAOYSA-N mepiquat Chemical compound C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 description 1
- 125000000007 metacrylic acid group Chemical group 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- ASHGTUMKRVIOLH-UHFFFAOYSA-L potassium;sodium;hydrogen phosphate Chemical compound [Na+].[K+].OP([O-])([O-])=O ASHGTUMKRVIOLH-UHFFFAOYSA-L 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- XZTJQQLJJCXOLP-UHFFFAOYSA-M sodium;decyl sulfate Chemical compound [Na+].CCCCCCCCCCOS([O-])(=O)=O XZTJQQLJJCXOLP-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- C11D2111/42—
Definitions
- the invention relates to method of treating soft surfaces by the production of a stable foam from a solution of a cleaning formulation and applying the stable foam to the fabric, the invention includes the cleaning formulation itself comprising a source of hydrogen peroxide, such as sodium percarbonate, and at least one surfactant .
- the invention includes a device for a preparation of the stable foam.
- the stable foam can be used for direct treatment of stains on soft surfaces (fabric or carpet) and it is prepared by mixing a solution of a cleaning formulation, preferably in combination with aerating, for, preferably, less than 5, 4, 3, 2 minutes: preferably the foam is formed quickly, in less than 1 minute, between 5 and 50, 10 and 40 seconds from mixing with water.
- the cleaning formulation is a solid, such as a granular, compacted or powder composition, ideally the cleaning formulation is granular or powder, to aid dissolution in water.
- warm water is used (greater than 25, 30, 40 or 50°C, ideally less than 80, 70, 60, 50°C) .
- a method of cleaning stains on a soft surface comprising mixing (preferably dissolving) a solid, preferably a powder, cleaning formulation in water, the formulation comprising a source of active oxygen and at least one surfactant with water to form a stable foam and applying the foam directly onto the stained soft surface.
- a further feature of the invention includes a device for the aeration of aqueous surfactant mixtures comprising a cellular plastic attached to a rigid support surface the opposition face of the rigid support surface being attached to a handle.
- a further feature of the invention includes a kit for treating stain on soft surfaces comprising a solid, preferably a powder, stain cleaning composition comprising a source of active oxygen and at least one surfactant and a device for the mixing/ aerating of the cleaning composition to form a stable foam for application onto the stain.
- a kit for treating stain on soft surfaces comprising a solid, preferably a powder, stain cleaning composition comprising a source of active oxygen and at least one surfactant and a device for the mixing/ aerating of the cleaning composition to form a stable foam for application onto the stain.
- Further optional subsequent steps include one or more of the following; a) rubbing the stained soft surface; b) cleaning the fabric in a fabric washing machine, with or without the addition of a fabric detergent; c) rinsing with water the stable foam formulation from the soft surface.
- the time period between applying the stable foam and any of the subsequent steps is at least 10, 20, 30, 40, 50, 60 seconds, ideally more than 1 , 2 , or 3 minutes, advisably the stable foam is not left for more than 10, 9, 8, 7, 6, 5, or 4 minutes.
- stable we mean that the foam retains at least 80%, 90% or 95% of its volume for 2 minutes after its formation.
- the foam is prepared by dissolving 15 grams of solid composition into 100 ml of water at 40°C.
- the stable foam may be prepared by any suitable mixing device or aeration device to incorporate air into the cleaning formulation solution.
- the ?????? device offers particular advantages in ensuring that all of the solid composition is dissolved prior to application.
- a cleaning solution containing a foaming surfactant is necessary for preparing the stable foam.
- the inclusion of the cleaning formulation of a source of active oxygen provides for oxygen to be evolved during dissolution further providing a rapid development of the stable foam.
- a container is also ideally required where the stable foam is prepared.
- the stable foam is prepared by the use of cellular plastic.
- Cellular plastics are those with a density of between 1 and 500 kg/m 3 preferably between 20 and 80 kg/m 3 and with an average pore diameter of at least 0.1 mm, preferably at least 0.4 mm.
- the cellular plastic has a porosity of >50%, >60%, >70% or >80%.
- the "porosity" according to the embodiment is obtained by measuring with a dry automatic densimeter an apparent volume and a true volume of the cellular pastic material, and calculated in accordance with the following equation.
- Porosity % (apparent volume-true volume) /apparent volumexlOO
- the "average pore diameter” is a value measured in accordance with ASTM (Designation: D4404-84) and is specifically a value determined by the measurement of the diameter of pores in accordance with a mercury penetration process using a mercury porosimeter manufactured by Porous Material , Inc .
- Suitable cellular plastics are those readily available for example from Euro foam, Miarka and Menshen and are made by any table water-insoluble plastic such as cellulose, polyurethane, polyester, polyether, or blends thereof .
- the cellular plastic is attached to a handle so that the user does not need to get their hands wet.
- the device comprising the cellular plastic is plunged into the cleaning formulation containing solution and pressed several times such that the liquid is aerated to form the stable foam when the formulation is squeezed through the cellular plastic.
- the device can be moved up and down pushing it against the bottom of a suitable container, until the cleaning formulation is transformed into the stable foam.
- the time necessary to create the foam with a suitable cellular plastic is quite low, between 10 and 60 seconds, typically below 2 minutes.
- the solution is pumped by each up and down movement through the pores of the cellular plastic to form the stable foam.
- the liquid excess can be squeezed out from the cellular plastic component.
- the cellular plastic can be then dipped into the foam and applied onto the surface to be treated.
- the device can also be used to rub the surface with the cellular plastic component. During the rubbing action the cleaning foam can more easily penetrate the stain that can in addition be adsorbed by the cellular plastic.
- a rinsing step might be necessary or eventually in the case of fabric, a normal wash can be done in a fabric washing machine .
- the device consists of at least two components, a handle 2 and cellular plastic 1, attached to the handle by a glue or a heat seal .
- the handle (1) can be formed for example by one piece or two identical stick parts attached together through a screwing system. Each stick has a diameter from 1 mm to 6 cm, preferably from 3 mm to 12 mm and it may have a cavity running through the centre to reduce weight and material costs.
- the wall thickness of the handle (1) is from 0.1 mm up to 1 mm, preferably between 0.1 mm to 0.5 mm.
- the handle length may range from 1 cm up to 25 cm, preferably from 3 cm to 15 cm.
- the handle can be made of wood, metal or plastic.
- a plastic material and more preferred plastic materials are polyethylene, polypropylene, polystyrene, or PET.
- the handle is attached to a support (2) that is a disk with a diameter from 1 cm to 30 cm, preferably from 3 cm to 10 cm. The thickness can range from 0.1 mm up to 12 cm, preferably from 0.5 to 10 mm.
- the support (2) can be made of wood, metal or plastic.
- plastic material and more preferred are polyethylene, polypropylene, polystyrene, or PET.
- the cellular plastic (3) can be any shape but is preferably cylindrical shape.
- the diameter can range from 1 cm to 20 cm, preferably from 3 cm to 10 cm.
- the height can range from 0.1 mm up to 50 mm, preferably from 1 to 10 mm.
- the cellular plastic can be made of synthetic materials as polyurethane, polyester, polyether, or a blend thereof or natural cellulose.
- the support (2) can be attached to the handle (1) by heat sealing, with a glue or with any screw system type.
- the cellular plastic (3) is attached to the support (2) by heat sealing or with a glue.
- the cleaning formulation contains oleoyl sarcosinate (preferably as a sodium salt) , a source of active oxygen, such as sodium percarbonate, and pre erably at least one other surf ctant .
- oleoyl sarcosinate preferably as a sodium salt
- a source of active oxygen such as sodium percarbonate
- oleoyl sarcosinate especially where the composition is applied directly onto the stain.
- the above surfactant types can be used in combination with other surfactants, such as alcohol ethoxylates and alkyl sulphates .
- a combination of alkyl naphthalene sulfonates and oleoyl sarcosinates provide improved stain removal efficacy for laundry detergent products .
- the alkyl naphthalene sulfonates and oleoyl sarcosinate surfactant combination of the present invention can be also used in combination with a source of active oxygen, such as sodium percarbonate, and bleach activators, such as TAED.
- Other ingredients that can be used include polymers, chelating agents, fillers, solvents, enzymes, fragrances and other minor components such as preservatives, dyes, thickeners and antifoaming agents.
- Actives present in the detergent formulations of this invention include an one or more of the following: a) Anionic and/or nonionic surfactant, preferably an oleoyl sarcosinate and/or an alkyl naphthalene sulfonate and/or an alkyl sulphate each at an overall level of 0.1 to 30%wt, preferably 0.5 to 20%wt, and ideally 1 to l0%wt. b) Source of active oxygen, such as sodium percarbonate, preferably at a range of 0.1 to 80%wt, preferably from 10 to 70%wt, and ideally 30 to 60%wt.
- Anionic and/or nonionic surfactant preferably an oleoyl sarcosinate and/or an alkyl naphthalene sulfonate and/or an alkyl sulphate each at an overall level of 0.1 to 30%wt, preferably 0.5 to 20%wt, and ideally 1 to l0%wt.
- Builder such as polymers or chelating agents, preferably at a range of 0.1 to 80%wt, preferably from 1 to 60%wt, and ideally from 10 to 50%wt.
- Bleach activator such as TAED, preferably at a level of 0.1 to 8%wt, preferably from 0.2 to 7%wt.
- Superwetting agent preferably at a level from 0.01 to 10%wt.
- Filler such as sodium sulfate, preferably to 100% formula composition.
- the soft surface is a fabric, ideally clothing.
- the composition is particularly effective on coloured fabric, especially cotton, providing for ? colour sa e bleaching composition.
- Alkyl sulphate surfactants for use herein are those according to the formula R 2 S0M wherein R 2 represents a saturated or unsaturated alkyl group containing from 9 to 30 carbon atoms, preferably from 9 to 18 carbon atoms, more preferably from 9 to 14, even more preferably from 9 to 12 and most preferably 10.
- the alkyl group can be in straight or branched configuration, and preferably in straight configuration.
- M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium, calcium, magnesium) or ammonium or substituted ammonium cations.
- substituted ammonium cations include methyl-, dimethyl-, trimethylammonium and quaternary ammonium cations, such as tetramethylammonium, dimethyl piperidinium and cations derived from alkanolamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof.
- Suitable examples are sodium, potassium, ammonium nonyl sulphate, decyl sulphate, dodecyl sulphate and/or octyl decyl sulphate.
- sodium decyl sulphate is commercially available from ALLBRIGHT & WILLSON under the name EMPICOL 0137 ® .
- Alkyl naphthalene sulfonate anionic surfactants are described in the formula below:
- R is a straight chain or branched alkyl chain having from about 1 to about 25 carbon atoms, saturated or unsaturated, and the longest linear portion of the alkyl chain is 15 carbon atoms or less on the average
- M is a cation capable of washing the compound more water soluble than the free acid especially preferred is an alkali metal (such as sodium or magnesium) , or ammonium or substituted ammonium preferred cation.
- Oleoyl sarcosinates are described below: O I I R- CH 2 CH 2 -C -NH(R 1 )CH 2 -C -00 M I I o
- R and R 1 is a straight chain or branched alkyl chain having from 1 to about 30 carbon atoms, saturated or unsaturated, and the longest average linear portion of the alkyl chain is 15 carbon atoms or less
- M is a cation capable of making the compound more water soluble especially than the free acid, especially preferred is an alkali metal (such as sodium, potassium or magnesium) , or ammonium or substituted ammonium cation
- NRx and x is from 0 to about 4.
- Preferred total level of surfactant is in the range from 0.01 to 50% wt, ideally 0.1 to 30% wt and preferably 0.5 to 10% w . Additional nonionic and anionic surfactants can be used.
- the nonionic surfactant is preferably a surfactant having a formula RO (CH2CH20) nH wherein R is a mixture of linear, even carbon-number hydrocarbon chains ranging from C12H25 to C16H33 and n represents the number of repeating units and is a number of from about 1 to about 12.
- R is a mixture of linear, even carbon-number hydrocarbon chains ranging from C12H25 to C16H33 and n represents the number of repeating units and is a number of from about 1 to about 12.
- examples of other non-ionic surfactants include higher aliphatic primary alcohol containing about twelve to about 16 carbon atoms which are condensed with about three to thirteen moles of ethylene oxide.
- nonionic surfactants include primary alcohol ethoxylates (available under the Neodol tradename from Shell Co.), such as Cll alkanol condensed with 9 moles of ethylene oxide (Neodol 1-9) , C12-13 alkanol condensed with 6.5 moles ethylene oxide (Neodol 23-6.5), C12-13 alkanol with 9 moles of ethylene oxide (Neodol 23-9) , C12-15 alkanol condensed with 7 or 3 moles ethylene oxide (Neodol 25-7 or Neodol 25-3) , C14-15 alkanol condensed with 13 moles ethylene oxide (Neodol 45-13), C9-11 linear ethoxylated alcohol, averaging 2.5 moles of ethylene oxide per mole of alcohol (Neodol 91- 2.5), and the like.
- Neodol tradename available under the Neodol tradename from Shell Co.
- nonionic surfactants suitable for use in the present invention include ethylene oxide condensate products of secondary aliphatic alcohols containing 11 to 18 carbon atoms in a straight or branched chain configuration condensed with 5 to 30 moles of ethylene oxide.
- examples of commercially available non-ionic detergents of the foregoing type are Cll-15 secondary alkanol condensed with either 9 moles of ethylene oxide (Tergitol 15-S-9) or 12 moles of ethylene oxide (Tergitol 15-S-12) marketed by Union Carbide, a subsidiary of Dow Chemical .
- Octylphenoxy polyethoxyethanol type nonionic surfactants for example, Triton X-100, as well as amine oxides can also be used as a nonionic surfactant in the present invention.
- linear primary alcohol ethoxylates are available under the Tomadol tradename such as, for example, Tomadol 1-7, a Cll linear primary alcohol ethoxylate with 7 moles EO; Tomadol 25-7, a C12-C15 linear primary alcohol ethoxylate with 7 moles EO;
- Tomadol 45-7 a C14-C15 linear primary alcohol ethoxylate with 7 moles EO; and Tomadol 91-6, a C9-C11 linear alcohol ethoxylate with 6 moles EO.
- Other nonionic surfactants are amine oxides, alkyl amide oxide surfactants.
- Preferred anionic surfactants are frequently provided as alkali metal salts, ammonium salts, amine salts, aminoalcohol salts or magnesium salts.
- sulfate or sulfonate compounds including: alkyl benzene sulfates, alkyl sulfates, alkyl ether sulfates, alkylamidoether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamide sulfonates, alkylarylsulfonates, olefinsulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfosuccinamate, alkyl sulfoacetates, alkyl phosphates, alkyl ether phosphates, acyl sarcosinates, acyl isethionates, and N-acyl taurates
- a super wetting agent is capable of reducing the surface tension in water at values below 25 mN/m, in the range between 18 and 25 mN/m at concentrations of 0.0001-l%wt, preferably between 0.001 and 0.1%wt.
- Preferred levels in the cleaning composition are between 0.01 and 10%wt.
- super wetting agents of this invention are silicone glycol copolymers and flurosurfactants.
- the silicone glycol copolymers are described by the following formula:
- X, Y, m and n are each a whole number ranging from 0 to 25, provided that X or Y is at least 1.
- X is between 0-10 and y, m and n are each preferably between 0-5.
- R and R' are straight chain or branched alkyl chain having from about 1 to about 25 carbon atoms, saturated or unsaturated, and the longest linear portion of the alkyl chain is 15 carbon atoms or less on the average.
- the fluorinated surfactant is described in the following formulae : F(CF 2 ) n -CH 2 CH 2 -S-CH 2 CH 2 -COOM
- n, m and x are integers having a value from 0 to 15; preferred values are between 1 and 12.
- M is a cation which makes the compound water soluble especially an alkali metal such as sodium or magnesium, ammonium or substituted ammonium cation.
- Suitable level of oxygen bleaches is in the range from 0.01 to 80% wt, preferred level is between 10 and 70% wt, ideally 30 to 60% wt .
- active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
- the active oxygen sources according to the present invention increase the ability of the compositions to remove oxidisable stains, to destroy malodorous molecules and to kill germs.
- the concentration of available oxygen can be determined by methods known in the art, such as the iodimetric method, the permanganometric method and the cerimetric method. Said methods and the criteria for the choice of the appropriate method are described for example in "Hydrogen Peroxide", W. C. Schumo, C. N. Satterfield and R. L. Wentworth, Reinhold Publishing Corporation, New York, 1955 and "Organic Peroxides", Daniel Swern, Editor Wiley Int. Science, 1970.
- Suitable organic and inorganic peroxides for use in the compositions according to the present invention include diacyl and dialkyl peroxides such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide, persulphuric acid and mixtures thereof .
- Suitable preformed peroxyacids for use in the compositions according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalatic acid, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof.
- Peroxygen bleaching actives useful for this invention are: percarbonates, perborates, peroxides, peroxyhydrates, persulfates.
- Preferred compound is sodium percarbonate and especially the coated grades that have better stability.
- the percarbonate can be coated with silicates, borates, waxes, sodium sulfate, sodium carbonate and surfactants cleaning at room temperature .
- Bleach activators :
- compositions may additionally comprise from 0% to 30%wt, preferably from 2% to 20%wt of peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide product peroxyacids .
- peracid precursors suitable for use in the present invention can be found among the classes of anhydrides, amides, imides and esters such as acetyl triethyl citrate (ATC) described for instance in EP 91 87 0207, tetra acetyl ethylene diamine (TAED) , succinic or maleic anhydrides .
- the detergent composition comprises contains at least one builders or a combination of them from 0.01 to 80% wt, preferably from 0.1 to 50% wt .
- builders are described below: - the parent acids of the monomeric or oligomeric polycarboxylate chelating agents or mixtures therefore with their salts, e.g. citric acid or citrate/citric acid mixtures are also contemplated as useful builder components .
- - borate builders, as well as builders containing borate-forming materials than can produce borate under detergent storage or wash conditions can also be used.
- - iminosuccinic acid metal salts - polyaspartic acid metal salts. - ethylene dia ino tetra acetic acid and salt forms.
- phosphate buiders are the alkali metal tripolyphosphates, sodium potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate sodium polymeta/phosphate in which the degree of polymerisation ranges from 6 to 21, and salts of phytic acid.
- water- soluble phosphate builders are the alkali metal tripolyphosphates, sodium potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from 6 to 21, and salts of phytic acid.
- Such polymers include the polycarboxylates containing two carboxy groups include the water-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates .
- Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivates such as the carboxymethloxysuccinates described in GB-A-1,379,241, lactoxysuccinates described in GB-A- 1,389,732, and aminosuccinates described in NL-A-7205873 , and the oxypolycarboxylate materials such as 2-oxa-l,l,3- propane tricarboxylates described in GB-A-1, 387, 447.
- Polycarboxylate containing four carboxy groups include oxydisuccinates disclosed in GB-A-1, 261, 829, 1, 1, 2,2-ethane tetracarboxylates, 1, 1, 3 , 3-propane tetracarboxylates and 1, 1, 2 , 3-propane tetracarobyxlates.
- Polycarboxylates contining sulfo substituents include the sulfosuccinate derivatives disclosed in GB-A-1, 398 , 421, GB-A-1, 398, 422 and US-A-3 , 936448 , and the sulfonated pyrolsed citrates described in GB-A-1, 439, 000.
- Alicylic and heterocyclic polycarboxylates include cyclopentane-cis, cis, cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2,3,4,5, 6-hexane - hexacarboxylates and carboxymethyl derivates of polyhydric alcohols such as s.orbitol, mannitol and xylitol.
- Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in GB-A-1, 425, 343.
- the preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates.
- Suitable polymer water-soluble compounds include the water soluble monomeric polycarboxylates, or their acid forms, homo or copolymeric polycarboxylic acids or their salts in which the polycarboxylic acid comprises at least two caroxylic radicals separated from each other by not more than two carbon atoms, carbonates, bicarbonates, borates, phosphates, and mixtures of any of thereof.
- the carboxylate or polycarboxylate builder can be monomeric or oligomeric in type although monomeric polycarboxylates are generally preferred for reasons of cost and performance .
- Suitable carboxylates containing one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof.
- Polycarboxylates containing two carboxy groups include the water-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates.
- Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivates such as the carboxymethloxysuccinates described in GB-A-1, 379, 241, lactoxysuccinates described in GB-A-1, 389, 732 , and aminosuccinates described in NL-A-7205873 , and the oxypolycarboxylate materials such as 2-oxa-l, 1, 3-propane tricarboxylates described in GB-A-1, 387, 447.
- succinate derivates such as the carboxymethloxysuccinates described in GB-A-1, 379, 241, lactoxysuccinates described in GB-A-1, 389, 732 , and aminosuccinates described in NL-A-7205873 , and the oxypolycarboxylate materials such as 2-oxa-l, 1, 3-propane
- Polycarboxylate containing four carboxy groups include oxydisuccinates disclosed in GB-A-1, 261, 829, 1,1,2,2- ethane tetracarboxylates, 1 , 1 , 3 , 3-propane tetracarboxylates and 1 , 1 , 2 , 3-propane tetracarobyxlates.
- Polycarboxylates confining sulfo suibstituents include the sulfosuccinate derivatives disclosed in GB-A- 1,398,421, GB-A-1, 398, 422 and US-A-3 , 936448 , and the sulfonated pyrolsed citrates described in GB-A-1, 439, 000.
- Alicylic and heterocyclic polycarboxylates include cyclopentane-cis,cis, cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2 , 3 , 4, 5, 6-hexane - hexacarboxylates and carboxymethyl derivates of polyhydric alcohols such as sorbitol, mannitol and xylitol.
- Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phthalic acid derivatives disclosed in GB-A-1, 425, 343. Of the above, the preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates.
- More preferred polymers are homo-polymers, copolymers and multiple polymers of acrylic, flourinated acrylic, sulfonated styrene, maleic anhydride, metacrylic, iso-butylene, styrene and ester monomers.
- these polymers are Acusol supplied from Rohm & Haas, Syntran supplied from Interpolymer and Versa and Alcosperse series supplied from Alco Chemical, a National Starch & Chemical Company.
- bicarbonate and carbonate builders are the alkaline earth and the alkali metal carbonates, including sodium and calcium carbonate and sesqui- carbonate and mixtures thereof .
- carbonate type builders are the metal carboxy glycine and metal glycine carbonate.
- builders are compounds that sequester metal ions associated with the hardness of water, e.g. calcium and magnesium
- chelating agents are compounds that sequester transition metal ions capable of catalysing the degradtaion of oxygen bleach systems.
- certain compounds may have the ability to do perform both functions.
- Suitable chelating agents to be used herein include chelating agents selected from the group of phosphonate chelating agents, amino carboxylate chelating agents, polyfunctionally-substituted aromatic chelating agents, and further chelating agents like glycine, salicylic acid, aspartic acid, glutamic acid, malonic acid, or mixtures thereof. Chelating agents when used, are typically present herein in amounts ranging from 0.01% to 50%wt of the total composition and preferably from 0.05% to 10%wt.
- Suitable phosphonate chelating agents to be used herein may include ethydronic acid as well as amino phosphonate compounds, including amino alkylene poly (alkylene phosphonate) , alkali metal ethane 1-hydroxy diphosphonates, nitrilo trimethylene phosphonates, ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates .
- the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
- Preferred phosphonate chelating agents to be used herein ar-e diethylene triamine penta methylene phosphonates.
- Such phosphonate chelating agents are commercially available from Monsanto under the trade name DEQUEST TM.
- Polyfunctionally-substituted aromatic chelating agents may also be useful in the compositions herein. See U.S. patent 3,812,044, issued May 21, 1974, to Connor et al .
- Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1, 2-dihydroxy -3,5- disulfobenzene .
- a preferred biodegradable chelating- agent for use herein is ethylene diamine N,N' -disuccinic acid, or alkali metal, or alkaline earth, ammonium or substitutes ammonium salts thereof or mixtures thereof .
- Ethylenediamine N,N' -disuccinic acids, especially the (S,S) isomer have been extensively described in US patent 4, 704, 233, November 3, 1987, to Hartman and Perkins.
- Ethylenediamine N,N' -disuccinic acids is, for instance, commercially available under the tradename ssEDDS TM from Palmer Research Laboratories .
- Suitable amino carboxylates to be used herein include ethylene diamine tetra acetates, diethylene triamine pentaacetates, diethylene triamine pentaacetate (DTPA) ,N- hydroxyethylethylenediamine triacetates, nitrilotri- acetates, ethylenediamine tetrapropionates, triethylenetetraaminehexa-acetates, ethanol-diglycines, propylene diamine tetracetic acid (PDTA) and methyl glycine diacetic acid (MGDA) , both in their acid form, or in their alkali metal, ammonium, and substituted ammonium salt forms.
- PDTA propylene diamine tetracetic acid
- MGDA methyl glycine diacetic acid
- Particularly suitable amino carboxylates to be used herein are diethylene triamine penta acetic acid, propylene diamine tetracetic acid (PDTA) which is, for instance, commercially available from BASF under the trade name Trilon FS TM and methyl glycine di-acetic acid (MGDA) .
- PDTA propylene diamine tetracetic acid
- MGDA methyl glycine di-acetic acid
- Fillers useful for the present invention are sodium chloride, bentonite, zeolites, citrates, talc and metal sulfate salts as sodium, calcium and aluminium sulfates. They can be used at a level from 0.01 to 60%wt, preferably between 0.1 to 30%wt.
- Solvents can be used at levels of 0.01 to 50%wt, preferred level is between 0.1-5%wt.
- the solvent constituent may include one or more alcohol, glycol, acetate, ether acetate, glycerol, polyethylene glycol with molecular weight ranging from 200 to 10000, silicones or glycol ethers.
- Exemplary alcohols useful in the compositions of the invention include C2-C8 primary and secondary alcohols which may be straight chained or branched, preferably pentanol and hexanol .
- Preferred solvents for the invention are glycol ethers and examples include those glycol ethers having the general structure.
- Preferred solvents for the invention are glycol ethers and examples include those glycol ethers having the general structure R a -0- [CH 2 - CH(R) - (CH 2 ) -0] n -H, wherein Ra is C ⁇ - 20 alkyl or alkenyl, or a cyclic alkane group of at least 6 carbon atoms, which may be fully or partially unsaturated or aromatic; n is an integer from 1 to 10, preferably from 1 to 5; each R is selected from H or CH 3; and a is the integer 0 or 1.
- Specific and preferred solvents are selected from propylene glycol methyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether, propylene glycol n-propyl ether, ethylene glycol n-butyl ether, diethylene glycol n-butyl ether, diethylene glycol methyl ether, propylene glycol, ethylene glycol, isopropanol, ethanol, methanol, diethylene glycol monoethyl ether acetate, and particularly useful are, propylene glycol phenyl ether, ethylene glycol hexyl ether and diethylene glycol hexyl ether.
- fragrance selected from a list consisting fragrance, anticaking agent (such as sodium xylene sulfonate and magnesium sulfate) , dye, enzyme are present at levels of up to 5%wt preferably less then l%wt.
- anticaking agent such as sodium xylene sulfonate and magnesium sulfate
- the device has been compared with other foam making equipment in terms of time for foam preparation, foam consistency and convenience.
- the gadget efficacy in foam application onto the stain and cleaning performance have been showed against no gadget usage .
- the foam has been prepared by dissolving in warm water Oxi Action Max powder, which contains foaming surfactants . About 15 grams of powder has been used with 100 ml of warm water. The solution can be prepared in a 300-500 ml open container.
- the different devices are compared for preparing the foam.
- the reference is the spoon that can be used as 5 mixing/aerating device.
- the devices are rated in terms of timing necessary to prepare the foam, consistency of the foam, convenience in preparing the foam and cost:
- the stain removal evaluation of standard soils has been done considering Y, the reflectance value has been used for performance evaluation.
- the X Y Z scale has been used with a spectrophotometer with the UV-filter at 460 nm.
- Y 100 means a complete stain removal. 0 Standard prepared stains have been used for the test .
- the cellular plastic device described for preparing the foam was compared to the simple mixing with the spoon, with a hand propeller system, with a 'cappuccino cream maker' , with a shaker and with a battery powered 10 mixer. In all cases 15 grams of Oxi Action Max powder has been dissolved in 100 ml of warm water, prior to using the devices .
- the cellular plastic device cleaning performance has 15 been compared to just applying the foam onto the stain with a spoon and then rinsing.
- Foams were prepared by dissolving 15 g in 100 ml of warm water, using Ex 1 and Ref from 1 to 5 gadgets.
- Multi-use can be used for foam preparation, application onto the stain and for cleaning through scrubbing.
- the cellular sponge gadget is a manual system that has been rated as the more convenient among the different manual tools, it is very effective in preparing the foam, short time and good foam consistency.
- the cellular 10 plastic device is in addition quite cheap and it can be used also for foam application onto the stain and for improving the cleaning performance .
- Results for stain removal 15
- the cellular plastic device of the present invention was been used to prepare the foam by dissolving 15 g of Vanish Oxi Action Max in 100 ml of water and compared to the use of the spoon. In both cases two grams of the foam 20 were applied onto each standard soiled swatch. In the case of the cellular plastic device 3 scrubbing back and forwards have been conducted on each swatch. Then the foam was left for 10 minutes before rinsing with cold water. After 10 minutes of the foam action all samples 25 were rinsed. For each device /stain for replicates were performed and the values reported in the table below are the average.
- the stable foam is prepared by dissolving the cleaning formulation , from 1 to 50 grams in 100 ml of water, preferably between 10 and 30 grams into 100ml of water.
- the stable foam is formed due to the source of active oxygen evolving oxygen within a surfactant .
- the stain removal evaluation of standard soils has been done considering Y, the reflectance value has been used for performance evaluation.
- the X Y Z scale has been used 15 with a spectrophotometer with the UV-filter at 460 nm.
- Standard prepared stains have been used for the test .
- 20 Standard stains (aged stain) 20 Standard stains (aged stain) :
- ⁇ E 0 means no colour damage and in general the lower the value the lower the colour damage .
- the foams described in this invention were prepared by using powder formulations easily produced by mixing in a suitable container the ingredients.
- the foam was prepared by dissolving 15 grams of the cleaning formulation of this invention in 100 ml of warm water (40°C) and mixing for 3 minutes. The foam was applied for 10 minutes before rinsing with cold water (20°C) .
- Product available on the market, Oxy Magic from Dr. Beckmann and Oxiclean new from Orange glo were used as references. These two products have been tested with the same procedure even if it was not possible to make a stable foam, but only a solution or a slightly foaming solution.
- Foams were prepared by using Ex 1, 2 and 3, for all dissolving 15 g and 30 grams in 100 ml of warm water and 5 mixing for 3 minutes .
- the formulation of present invention have been used as a 10 foam by dissolving 15 g in 100 ml of water and applying 2 ml of the foam onto each stain. After 10 minutes of contact with the foam all samples were rinsed. The reference products were used at the same dosage. Four replicates were made and the values reported in the table 15 below is the average .
- Oxiclean powder has been used as a reference. Three replicates have been considered for each product/colour type and the values reported in the table below are averages .
- Ref 1 Oxiclean from Orange glo. * foam made with 15 grams of Ex2 in 100 ml water 1 0 ** foam made with 30 grams of Ex2 in 100 ml water
- a value of delta E below 3.0 can be considered as no colour damage .
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE602004008492T DE602004008492T2 (en) | 2003-10-07 | 2004-09-16 | CLEANING PROCESS |
MXPA06003969A MXPA06003969A (en) | 2003-10-07 | 2004-09-16 | Method of cleaning. |
AU2004284267A AU2004284267B2 (en) | 2003-10-07 | 2004-09-16 | Method of cleaning |
EP04768525A EP1670890B1 (en) | 2003-10-07 | 2004-09-16 | Method of cleaning |
BRPI0415071-6A BRPI0415071B1 (en) | 2003-10-07 | 2004-09-16 | CLEANING METHOD |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0323394.7 | 2003-10-07 | ||
GB0323394A GB0323394D0 (en) | 2003-10-07 | 2003-10-07 | Method of removing fabric stains |
GB0409178.1 | 2004-04-24 | ||
GB0409178A GB2413336A (en) | 2004-04-24 | 2004-04-24 | Method of cleaning using a foam and an aeration device |
Publications (1)
Publication Number | Publication Date |
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WO2005040326A1 true WO2005040326A1 (en) | 2005-05-06 |
Family
ID=34525041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/GB2004/003979 WO2005040326A1 (en) | 2003-10-07 | 2004-09-16 | Method of cleaning |
Country Status (8)
Country | Link |
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EP (1) | EP1670890B1 (en) |
AT (1) | ATE371012T1 (en) |
AU (1) | AU2004284267B2 (en) |
BR (1) | BRPI0415071B1 (en) |
DE (1) | DE602004008492T2 (en) |
ES (1) | ES2288269T3 (en) |
MX (1) | MXPA06003969A (en) |
WO (1) | WO2005040326A1 (en) |
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GB201310507D0 (en) * | 2013-06-13 | 2013-07-24 | Reckitt Benckiser Brands Ltd | Product |
EP3535449A1 (en) | 2016-11-01 | 2019-09-11 | Koninklijke Philips N.V. | Portable stain removal device |
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GB1418889A (en) * | 1972-12-20 | 1975-12-24 | Martin P | Paint applicators |
US4106153A (en) * | 1975-07-15 | 1978-08-15 | Lemelson Jerome H | Cleaning appliance |
US4232420A (en) * | 1979-04-23 | 1980-11-11 | Sam Schuster | Scouring pad handle |
GB2183461A (en) * | 1985-12-02 | 1987-06-10 | Willson Co Ltd | Wax applicator |
US5718622A (en) * | 1995-01-05 | 1998-02-17 | Jones; Jason Robert | Abrasive holder |
US5855217A (en) * | 1996-10-26 | 1999-01-05 | Diversey Lever, Inc. | Process and device for cleaning surfaces which are heavily soiled with grease, starch and/or proteins, especially in the food processing industry |
US5866524A (en) * | 1994-03-30 | 1999-02-02 | Procter & Gamble Company | Foamed cleaning compositions and method of treating textile fabrics |
US6023810A (en) * | 1998-07-28 | 2000-02-15 | Gessert; Roy E. | Grill cleaning apparatus incorporating detachable handle and holder for removable scouring pad |
WO2000037183A1 (en) * | 1998-12-21 | 2000-06-29 | Wagner Spray Tech Corporation | Foam backing for sponge pad paint applicators |
US20020001636A1 (en) * | 2000-06-30 | 2002-01-03 | Greg Holloway | Surface texture applicator |
US6371675B1 (en) * | 2000-12-20 | 2002-04-16 | Becton, Dickinson And Company | Skin disinfectant applicator |
US6403547B1 (en) * | 1998-10-30 | 2002-06-11 | The Procter & Gamble Company | Process of cleaning carpets with a composition comprising peroxygen bleach |
US20020076258A1 (en) * | 2000-12-20 | 2002-06-20 | Crosby Cynthia T. | Skin disinfectant applicator |
-
2004
- 2004-09-16 DE DE602004008492T patent/DE602004008492T2/en active Active
- 2004-09-16 EP EP04768525A patent/EP1670890B1/en active Active
- 2004-09-16 MX MXPA06003969A patent/MXPA06003969A/en active IP Right Grant
- 2004-09-16 AT AT04768525T patent/ATE371012T1/en not_active IP Right Cessation
- 2004-09-16 BR BRPI0415071-6A patent/BRPI0415071B1/en active IP Right Grant
- 2004-09-16 WO PCT/GB2004/003979 patent/WO2005040326A1/en active IP Right Grant
- 2004-09-16 AU AU2004284267A patent/AU2004284267B2/en active Active
- 2004-09-16 ES ES04768525T patent/ES2288269T3/en active Active
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1418889A (en) * | 1972-12-20 | 1975-12-24 | Martin P | Paint applicators |
US4106153A (en) * | 1975-07-15 | 1978-08-15 | Lemelson Jerome H | Cleaning appliance |
US4232420A (en) * | 1979-04-23 | 1980-11-11 | Sam Schuster | Scouring pad handle |
GB2183461A (en) * | 1985-12-02 | 1987-06-10 | Willson Co Ltd | Wax applicator |
US5866524A (en) * | 1994-03-30 | 1999-02-02 | Procter & Gamble Company | Foamed cleaning compositions and method of treating textile fabrics |
US5718622A (en) * | 1995-01-05 | 1998-02-17 | Jones; Jason Robert | Abrasive holder |
US5855217A (en) * | 1996-10-26 | 1999-01-05 | Diversey Lever, Inc. | Process and device for cleaning surfaces which are heavily soiled with grease, starch and/or proteins, especially in the food processing industry |
US6023810A (en) * | 1998-07-28 | 2000-02-15 | Gessert; Roy E. | Grill cleaning apparatus incorporating detachable handle and holder for removable scouring pad |
US6403547B1 (en) * | 1998-10-30 | 2002-06-11 | The Procter & Gamble Company | Process of cleaning carpets with a composition comprising peroxygen bleach |
WO2000037183A1 (en) * | 1998-12-21 | 2000-06-29 | Wagner Spray Tech Corporation | Foam backing for sponge pad paint applicators |
US20020001636A1 (en) * | 2000-06-30 | 2002-01-03 | Greg Holloway | Surface texture applicator |
US6371675B1 (en) * | 2000-12-20 | 2002-04-16 | Becton, Dickinson And Company | Skin disinfectant applicator |
US20020076258A1 (en) * | 2000-12-20 | 2002-06-20 | Crosby Cynthia T. | Skin disinfectant applicator |
Also Published As
Publication number | Publication date |
---|---|
AU2004284267B2 (en) | 2010-02-04 |
ATE371012T1 (en) | 2007-09-15 |
DE602004008492D1 (en) | 2007-10-04 |
EP1670890B1 (en) | 2007-08-22 |
MXPA06003969A (en) | 2006-06-27 |
BRPI0415071B1 (en) | 2014-12-30 |
BRPI0415071A (en) | 2006-11-28 |
ES2288269T3 (en) | 2008-01-01 |
AU2004284267A1 (en) | 2005-05-06 |
EP1670890A1 (en) | 2006-06-21 |
DE602004008492T2 (en) | 2008-05-15 |
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