WO2005031900A2 - Separateur bipolaire pour assemblage de piles a combustible - Google Patents

Separateur bipolaire pour assemblage de piles a combustible Download PDF

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Publication number
WO2005031900A2
WO2005031900A2 PCT/EP2004/010930 EP2004010930W WO2005031900A2 WO 2005031900 A2 WO2005031900 A2 WO 2005031900A2 EP 2004010930 W EP2004010930 W EP 2004010930W WO 2005031900 A2 WO2005031900 A2 WO 2005031900A2
Authority
WO
WIPO (PCT)
Prior art keywords
separator
sheets
cathode
fluid passage
anode
Prior art date
Application number
PCT/EP2004/010930
Other languages
English (en)
Other versions
WO2005031900A3 (fr
Inventor
Antonino Toro
Original Assignee
Nuvera Fuel Cells Europe S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nuvera Fuel Cells Europe S.R.L. filed Critical Nuvera Fuel Cells Europe S.R.L.
Priority to KR1020067006438A priority Critical patent/KR101119479B1/ko
Priority to BRPI0414962-9A priority patent/BRPI0414962A/pt
Priority to US10/572,534 priority patent/US7794895B2/en
Priority to CA2538961A priority patent/CA2538961C/fr
Priority to ES04765713.5T priority patent/ES2673944T3/es
Priority to EP04765713.5A priority patent/EP1668725B1/fr
Priority to JP2006530056A priority patent/JP5208418B2/ja
Publication of WO2005031900A2 publication Critical patent/WO2005031900A2/fr
Publication of WO2005031900A3 publication Critical patent/WO2005031900A3/fr

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0223—Composites
    • H01M8/0228—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H01M8/0254—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form corrugated or undulated
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267—Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0297—Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029—Heat exchange using liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023—Porous and characterised by the material
    • H01M8/0232—Metals or alloys
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12479—Porous [e.g., foamed, spongy, cracked, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y10T428/24686—Pleats or otherwise parallel adjacent folds

Definitions

  • the present invention relates to a bipolar separation element between fuel cells, in particular polymer membrane fuel cells, laminated in a stack in a filter press configuration.
  • fuel cells are electrochemical generators converting the chemical energy of the reaction between a fuel and an oxidant to electrical energy, producing water as a by-product.
  • the polymer membrane type is the one which operates at the lowest temperature, typically 70-100°C, providing sensible advantages in terms of easiness and safety of operation, of material stability and especially of quickness in start-up and in reaching the final regime operating conditions.
  • the main problems which have slowed the industrial diffusion of this technology one of the most significant lies in the fact the energy produced by a single cell is obtained as direct current of relatively high intensity versus a very limited voltage (in any case lower than 1 V, and typically comprised between 0.5 and 0.8 V).
  • the constructive complexity of polymer membrane fuel cells is imposed by the multiplicity of functions required to make the reactions of fuel oxidation and oxidant reduction proceed with a high efficiency.
  • a critical factor is given by the ion-exchange membrane acting as the solid electrolyte and which must provide for transporting the electrical current as a flow of ions; in particular, the protons generated by the oxidation of the fuel, that in the most common of cases consists of hydrogen, either pure or in admixture, have to cross the membrane thickness and be transported to the cathode side where they are consumed by the reaction with the oxidant, generally consisting of oxygen, also pure or in admixture.
  • the ion-exchange membranes currently available on the market consist of a polymeric backbone, often perfluorinated for the sake of chemical stability, whereto anionic functional groups are attached, capable of bonding protons albeit to a sufficiently weak extent to allow the migration thereof under the effect of the electric field generated by the reactants.
  • anionic functional groups capable of bonding protons albeit to a sufficiently weak extent to allow the migration thereof under the effect of the electric field generated by the reactants.
  • the most recent technological solutions provide the use of metallic materials with reduced thickness and more favourable mechanical characteristics. They are for instance configured as described in US patent 5,578,388, providing the supply of previously humidified reactants to the two compartments, anodic and cathodic, of a stack of cells delimited by preferably metallic bipolar plates, coupled to frame-shaped planar gaskets suitable for housing an adequate current collector also acting as distributing chamber, besides ensuring the electrical continuity between the plate itself and the so-called electrochemical package; the latter consists of an ion-exchange membrane-gas diffusion electrode assembly.
  • the current collector is a metallic reticulated element, which favours the delocalisation of the electrical contact and the distribution of the correspondent gas flow along the whole surface of the membrane-electrode assembly.
  • the heat withdrawal is typically achieved through the circulation of water or other thermostatting fluid inside a serpentine embedded within the thickness of the metallic plate; this nevertheless entails the use of rather thick and heavy plates, expensive to manufacture since they are obtained by a delicate moulding operation.
  • stack configurations alternating, within the same lamination, fuel cells to thermostatting cells crossed by water or other cooling fluid capable of exchanging heat through the walls of the metallic plates delimiting the various cells have been proposed.
  • the invention consists of a bipolar separator delimited by a cathode sheet and an anode sheet, at least one of which provided with fluid passage holes, wherein said sheets are welded or metallurgically bonded through a conductive corrugated element so as to delimit a cooling fluid passage section.
  • the invention consists of a stack of fuel cells disposed in a filter-press arrangement and separated by an integrated conductive element performing, in the different embodiments, one or more functions among which the thermal regulation of the cell, the distribution and the humidification of the reactants without resorting to additional thermostatting cells.
  • the separator of the invention is delimited by two conductive sheets, at least one of which is provided with fluid passage holes, respectively suitable for acting as cathode and anode sheet in a filter-press type bipolar arrangement.
  • the two conductive sheets are mutually welded or otherwise secured through an interposed conductive element, whose geometry is of the corrugated type in order to determine, in a preferred embodiment, the formation of channels for the passage of a thermostatting fluid, preferably water in the liquid state.
  • corrugated element in this context it is intended a generic element, for instance obtained from a planar sheet, with an undulated or otherwise shaped profile so as to form projections and depressions; said projections and depressions are welded or otherwise secured alternatively to one or the other sheet delimiting the separator.
  • the corrugated element has the dual purpose of mechanically adjoining the anode and cathode sheets and of ensuring the electrical continuity between the same.
  • the corrugated element may be present just on a peripheral part of the separator, for instance in correspondence of two opposed sides, or it may be disposed along the whole surface of the sheets.
  • the corrugated conductive element advantageously delimits channels which can be used for the circulation of a cooling fluid, preferably liquid water.
  • the internal part may be advantageously filled with a reticulated material suitable for being employed for the circulation of a cooling fluid.
  • the reticulated material metallic foams or meshes, expanded sheets, sintered porous materials may be advantageously used, also in mutual combination or juxtaposition; however, other types of reticulated materials may be employed without departing from the scope of the invention.
  • one or both of the sheets delimiting the separator are provided with fluid passage holes; by fluid passage hole in this context it is intended a through opening of any shape or profile, obtained on the main surface of the corresponding sheet, suitable for being crossed by a liquid or a gas.
  • both of the sheets are provided with holes, preferably disposed along a peripheral region, in communication with a gas feeding duct; such holes can thus be employed to supply a gaseous reactant to the adjacent fuel cell, in a similar way as disclosed in PCT/EP 03/01207.
  • Equivalent holes, in communication with a discharge duct are preferably used for discharging exhaust reactants and reaction products.
  • fluid passage holes preferably in the form of calibrated orifices, are present in the internal part of the main surface of the separator, in correspondence of the cooling fluid passage section.
  • This embodiment is particularly advantageous, especially in case the cooling fluid is liquid water, since the controlled passage of a portion of said cooling water from the inside of the separator to the outside, toward one or both the adjacent fuel cells, determines the humidification of one or both reactants, moreover contributing to the heat withdrawal by evaporation, in a similar manner as described in PCT/EP03/06327.
  • the present invention thus exhibits the same advantageous features of the findings of PCT/EP 03/01207 and PCT/EP03/06327, making use however of an integrated separator directly interposed between the fuel cells, which replaces the thermostatting cells and the relative components to be individually assembled, simplifying the hydraulic sealing system by eliminating the relative gaskets and facilitating the assembly procedure to a radical extent.
  • the separator of the invention may be also provided externally with current collectors and/or gaskets, welded or otherwise secured on one or preferably both of the cathode and anode sheets.
  • the fuel cell stack of figure 1 is configured in accordance with the most widespread teaching of the prior art, and comprises a juxtaposition of laminated single fuel cells (100), delimited by separators (1) in form of bipolar sheets, which enclose an electrochemical package (2) consisting of an ion-exchange membrane activated on the two faces with a catalyst or by an ion-exchange membrane/gas diffusion electrode assembly, as known in the art.
  • the electrochemical package (2) divides the cell into two compartments, cathodic and anodic.
  • the electrical continuity between the separators (1) and the electrochemical package (2) is ensured by the interposition of an appropriate current collector (3), which in the illustrated case is for instance a reticulated conductive material also acting as a gas distributor.
  • the hydraulic sealing of the cells is ensured by suitable gaskets (4), usually plane gaskets.
  • Each of the cells (100) is fed with a gaseous reactant, fuel and oxidant, in the respective anodic and cathodic compartments, by means of suitable ducts not shown in the figure, as known in the art of filter-press type module design.
  • the discharge of the exhausts and of the reaction products is likewise carried out by means of a collecting duct.
  • a design of this kind does not provide the integrated humidification of the reactants, which must be carried out externally, while the cell thermal regulation is typically carried out with serpentines, also not shown, embedded in the sheets acting as separators (1).
  • thermostatting cells could have been intercalated to the fuel cells (100), delimited by the same separators (1) and internally crossed by a liquid coolant; in this case, the assembly and the hydraulic sealing would have obviously been complicated by the addition of the specified components.
  • FIG. 2 shows two possible embodiments of the separator (1) of the invention; in both cases, the separator is delimited by sheets (5), one cathodic and one anodic, joined by means of a corrugated element (8) secured by weld spots (6, 9) or other forms of metallurgical bonding; in the case illustrated on the left hand side of the figure, the corrugated element (8) joins the cathode and anode sheets (5) along the whole surface delimiting a serpentine channel which may be advantageously crossed by a cooling fluid supplied from an appropriately connected circuit, not shown.
  • the corrugated element is present only on a peripheral part of the separator (1), typically outside the cell's active area, while within the recess delimited by the two sheets (5) in the internal part, a reticulated element (10) is present, which can be crossed by a cooling fluid supplied from an appropriately connected circuit, not shown.
  • the separator is therefore capable of providing for the thermal regulation of the adjacent fuel cells.
  • suitable holes (7) which can be employed for feeding gaseous reactants coming from gas feed ducts, not shown, in communication with said peripheral region, to the respective adjacent fuel cells.
  • the separator (1) of the invention performs the function of gas distributor to the cells, allowing to obtain a compact design taking advantage of what would otherwise be a dead zone.
  • the constitutive elements of the separators (1) in figure 1 are evidently not reported in scale; the feed (7) and discharge holes (11), for example, are usually tiny, and have been magnified in the figure with respect to the typical situation in order to explain their function with better clarity.
  • the communication holes between the inside and the outside of the separator (1) also comprise calibrated orifices (7') which serve to allow a controlled passage of cooling water toward the adjacent fuel cells: in this case, the separator (1) performs also the function of humidifying the reactants of the adjacent cells; the heat withdrawal from said cells is moreover incremented by the evaporation of part of the water passing through the orifices (7') inside the same cells.
  • Figure 3 shows two embodiments equivalent to those of figure 2, further comprising the integration of the current collectors (3) and of the gaskets (4) of the fuel cells (100).
  • the current collectors (3) may be integrated to the separator (1) of the invention by welding, also of the spot type, by soldering or other metallurgical bonding;
  • the gaskets (4) may be integrated by moulding, gluing or by other systems known to those skilled in the art.
  • the integrated bipolar separator (1) may comprise the current collectors (3) and not the gaskets (4) or vice versa, or again it may comprise one or both of those elements on both sides or on one side only.
  • the invention may be practised making other variations or modifications to the cited examples.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)

Abstract

La présente invention se rapporte à un séparateur bipolaire destiné à des assemblages de piles à combustible à membrane polymère, qui est défini par deux feuilles dotées de trous de passage de fluide, qui sont reliées par l'intermédiaire d'un élément ondulé et possèdent une section permettant le passage d'un liquide de thermostatisation. Ainsi, l'invention permet un retrait de chaleur des piles adjacentes, ainsi que l'humidification et la distribution des gaz, à l'aide d'une pièce intégrée unique, et par là même une simplification de l'ensemble et de l'étanchéisation hydraulique de l'assemblage.
PCT/EP2004/010930 2003-10-01 2004-09-30 Separateur bipolaire pour assemblage de piles a combustible WO2005031900A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1020067006438A KR101119479B1 (ko) 2003-10-01 2004-09-30 연료 전지 스택용 양극성 분리기
BRPI0414962-9A BRPI0414962A (pt) 2003-10-01 2004-09-30 separador bipolar para bateria de células a combustìvel
US10/572,534 US7794895B2 (en) 2003-10-01 2004-09-30 Bipolar separator for fuel cell stack
CA2538961A CA2538961C (fr) 2003-10-01 2004-09-30 Separateur bipolaire pour assemblage de piles a combustible
ES04765713.5T ES2673944T3 (es) 2003-10-01 2004-09-30 Separador bipolar para apilamiento de pilas de combustible
EP04765713.5A EP1668725B1 (fr) 2003-10-01 2004-09-30 Separateur bipolaire pour assemblage de piles a combustible
JP2006530056A JP5208418B2 (ja) 2003-10-01 2004-09-30 燃料電池積重ね体用の二極セパレータ

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI2003A001881 2003-10-01
IT001881A ITMI20031881A1 (it) 2003-10-01 2003-10-01 Separatore bipolare per batteria di celle a combustibile.

Publications (2)

Publication Number Publication Date
WO2005031900A2 true WO2005031900A2 (fr) 2005-04-07
WO2005031900A3 WO2005031900A3 (fr) 2005-10-27

Family

ID=34385816

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2004/010930 WO2005031900A2 (fr) 2003-10-01 2004-09-30 Separateur bipolaire pour assemblage de piles a combustible

Country Status (10)

Country Link
US (1) US7794895B2 (fr)
EP (1) EP1668725B1 (fr)
JP (1) JP5208418B2 (fr)
KR (1) KR101119479B1 (fr)
CN (1) CN1860633A (fr)
BR (1) BRPI0414962A (fr)
CA (1) CA2538961C (fr)
ES (1) ES2673944T3 (fr)
IT (1) ITMI20031881A1 (fr)
WO (1) WO2005031900A2 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007026737A (ja) * 2005-07-13 2007-02-01 Toyota Motor Corp 燃料電池及び燃料電池製造方法
EP1791201A1 (fr) * 2005-11-28 2007-05-30 Behr GmbH & Co. KG Plaque bipolaire
WO2007090819A1 (fr) 2006-02-06 2007-08-16 Nuvera Fuel Cells Europe Srl Empilement de piles a combustible
WO2008095533A1 (fr) * 2007-02-06 2008-08-14 Nuvera Fuel Cells Europe Srl Unite bipolaire pour pile a combustible pourvue de collecteurs de courant poreux
WO2009157981A1 (fr) * 2008-06-23 2009-12-30 Blanchet Scott C Pile à combustible présentant des limites de transfert de masse réduites
EP2169752A1 (fr) * 2007-06-15 2010-03-31 Toyota Jidosha Kabushiki Kaisha Pile à combustible
DE102014219164A1 (de) 2014-09-23 2016-03-24 Volkswagen Aktiengesellschaft Brennstoffzellenstapel mit integriertem Befeuchter sowie Fahrzeug mit einem solchen

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Publication number Priority date Publication date Assignee Title
ITMI20051738A1 (it) * 2005-09-20 2007-03-21 De Nora Elettrodi S P A Anodo discreto per la protezione catodica del calcestruzzo armato
JP5068052B2 (ja) * 2006-09-29 2012-11-07 昭和電工株式会社 燃料電池用セパレータ、燃料電池用セルおよび燃料電池用セルユニット、ならびに燃料電池用セパレータおよび燃料電池用セルユニットの製造方法
US9614232B2 (en) * 2007-12-28 2017-04-04 Altergy Systems Modular unit fuel cell assembly
DE102008028358A1 (de) 2008-06-10 2009-12-17 Igs Development Gmbh Separatorplatte und Verfahren zum Herstellen einer Separatorplatte
US8889314B2 (en) * 2009-01-13 2014-11-18 GM Global Technology Operations LLC Bipolar plate for a fuel cell stack
KR101491372B1 (ko) * 2013-12-17 2015-02-06 현대자동차주식회사 연료 전지 분리판 및 이를 포함하는 연료 전지 스택
US10297841B2 (en) * 2015-03-31 2019-05-21 Honda Motor Co., Ltd. Fuel cell and production apparatus for the fuel cell
KR102248990B1 (ko) * 2021-02-04 2021-05-07 주식회사 유한정밀 연료전지차용 금속분리판 제조방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3589942A (en) * 1966-12-22 1971-06-29 Cons Natural Gas Svc Bipolar collector plates
US4279731A (en) * 1979-11-29 1981-07-21 Oronzio Denora Impianti Elettrichimici S.P.A. Novel electrolyzer
US5578388A (en) * 1993-04-30 1996-11-26 De Nora Permelec S.P.A. Electrochemical cell provided with ion exchange membranes and bipolar metal plates
WO2000070698A1 (fr) * 1999-05-18 2000-11-23 Nevera Fuel Cells Europe S.R.L. Dispositif d'humidification pour piles a combustible a membrane polymere
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EP2169752A1 (fr) * 2007-06-15 2010-03-31 Toyota Jidosha Kabushiki Kaisha Pile à combustible
EP2169752A4 (fr) * 2007-06-15 2011-02-09 Toyota Motor Co Ltd Pile à combustible
WO2009157981A1 (fr) * 2008-06-23 2009-12-30 Blanchet Scott C Pile à combustible présentant des limites de transfert de masse réduites
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WO2005031900A3 (fr) 2005-10-27
CA2538961A1 (fr) 2005-04-07
JP5208418B2 (ja) 2013-06-12
ITMI20031881A1 (it) 2005-04-02
US7794895B2 (en) 2010-09-14
BRPI0414962A (pt) 2006-11-07
JP2007507838A (ja) 2007-03-29
EP1668725B1 (fr) 2018-04-04
CN1860633A (zh) 2006-11-08
EP1668725A2 (fr) 2006-06-14
KR20060090698A (ko) 2006-08-14
CA2538961C (fr) 2012-08-14
US20060263667A1 (en) 2006-11-23
ES2673944T3 (es) 2018-06-26
KR101119479B1 (ko) 2012-03-16

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