WO2005028565A1 - Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form - Google Patents
Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form Download PDFInfo
- Publication number
- WO2005028565A1 WO2005028565A1 PCT/EP2004/009752 EP2004009752W WO2005028565A1 WO 2005028565 A1 WO2005028565 A1 WO 2005028565A1 EP 2004009752 W EP2004009752 W EP 2004009752W WO 2005028565 A1 WO2005028565 A1 WO 2005028565A1
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- WO
- WIPO (PCT)
- Prior art keywords
- oxygen
- zinc oxide
- zinc
- aggregates
- gas
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/04—Compounds of zinc
- C09C1/043—Zinc oxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/02—Oxides; Hydroxides
- C01G9/03—Processes of production using dry methods, e.g. vapour phase processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
Definitions
- the invention relates to a zinc oxide powder, its preparation and use.
- Zinc oxide powders are used in inks, surface coatings, in resins and fibres.
- An important sector is the use of zinc oxide powders in the cosmetic field, especially as a constituent of sun protection formulations.
- the zinc compounds used as starting material in wet-chemical processes are those which can be converted into zinc oxide by means of heat, such as, for example, zinc hydroxide, zinc oxalate or zinc carbonate.
- the wet-chemical method usually has the disadvantage that the zinc oxide particles produced agglomerate to form larger units, which are undesirable especially in cosmetic applications.
- the process which is usually carried out as a batch process, comprises filtering, drying and, optionally, grinding the particles and is relatively cost-intensive.
- Gas-phase processes or pyrogenic processes permit a more inexpensive process. They include the French and American processes, according to which zinc oxide can be produced on a large scale. In both processes, oxidation of zinc vapour is carried out. Disadvantages of these processes are the formation of large aggregates of primary particles and a low BET surface area.
- the prior art describes various possibilities for gas-phase synthesis with the aim of achieving a higher BET surface area, better transparency and higher UV protection. Ultimately, a common feature of all these attempts is the oxidation of zinc vapour.
- JP 56-120518 describes the oxidation of zinc vapour using air or oxygen, with the formation of non-aggregated, needle-like zinc oxide particles. Such particles can often be incorporated into sun protection formulations only with difficulty.
- US 6,335,002 describes the oxidation of zinc vapour using air or oxygen. By varying the process parameters, primary particles of zinc oxide which are largely isotropic in form and have a low degree of aggregation should be formed. In the examples according to the invention of US 6,335,002, the aggregate diameters are from 0.47 to 0.55 ⁇ m.
- the zinc oxide powder has a BET surface area of from 10 to 200 m 2 /g and a tamped density of from 4 to 40 ml/g.
- the oxidation of the zinc vapour is carried out in an atmosphere of an oxidising gas which contains oxygen and steam.
- an atmosphere can also be produced by burning an oxygen-containing gas with hydrogen or propane, an excess of oxygen being used.
- Zinc vapour and the oxygen/steam mixture are injected separately by means of nozzles into a reactor, in which the oxidation takes place.
- the prior art demonstrates the keen interest in zinc oxide, especially in its use as UV protection in sun protection formulations .
- the object of the invention is to provide a zinc oxide powder which avoids the disadvantages of the prior art. In particular, it should exhibit high transparency while providing good UV protection. It should also be readily incorporable into dispersions.
- a further object is to provide a process for the preparation of zinc oxide powder.
- the invention provides a pyrogenically prepared zinc oxide powder having a BET surface area of from 10 to 200 m 2 /g, characterised in that it is in the form of aggregates, the aggregates being composed of particles having different morphologies, and 0-10 % of the aggregates being in a circular form, 30-50 % of the aggregates being in an ellipsoidal form, 30-50 % of the aggregates being in a linear form, 20-30 % of the aggregates being in a branched form.
- particles are understood as being the particles formed primarily in the pyrogenic preparation process. They join together during the reaction, with the formation of sintering surfaces, to form aggregates. It is important that the aggregates are composed of particles having different morphologies. According to the definition, an aggregate is composed of particles which are the same or approximately the same, the primary particles (DIN 53206) .
- the zinc oxide powder according to the invention contains aggregates which consist of particles having different morphologies, and are therefore not designated primary particles. Morphology is understood as meaning both isotropic and anisotropic particles. There may be, for example, spherical or largely spherical particles, bulb-like particles, rod-shaped particles or needle-shaped particles. It is important that the aggregates consist of different particles, and the particles are joined together by sintering surfaces.
- the BET surface area of the powder according to the invention may be from 20 to 60 m 2 /g.
- the aggregates of the zinc oxide powder according to the invention are in circular, ellipsoidal, linear and branched forms.
- Figures la-c show typical forms of ellipsoidal, linear and branched aggregates of the zinc oxide powder according to the invention.
- Figure 2 shows a TEM image of the powder according to the invention
- Figures 3a-d show a linear, branched, ellipsoidal and circular aggregate, respectively, of that powder .
- the zinc oxide powder according to the invention may also have a tamped density, determined according to DIN ISO 787/11, of at least 150 g/1.
- a tamped density of from 250 to 350 g/1 may be particularly preferred.
- the zinc oxide powder according to the invention may consist of aggregates that have a mean projected aggregate surface area of less than 10,000 nm 2 , an equivalent circle diameter (ECD) of less than 100 nm and a mean circumference of less than 600 nm. These values can be obtained by image analysis of approximately from 1000 to 2000 aggregates from TEM images.
- zinc oxide powders having a mean projected aggregate surface area of from 2000 to 8000 nm 2 , an equivalent circle diameter (ECD) of from 25 to 80 nm and a mean circumference of from 200 to 550 nm.
- ECD equivalent circle diameter
- the zinc oxide powder according to the invention may contain not more than 20 ppm of lead, not more than 3 ppm of arsenic, not more than 15 ppm of cadmium, not more than 200 ppm of iron, not more than 1 ppm of antimony and not more than 1 ppm of mercury, in each case based on zinc oxide .
- the invention further provides a process for the preparation of the zinc oxide powder according to the invention, which process is characterised in that - a starting mixture containing zinc vapour, a combustible gas and the reaction products from the oxidation of the combustible gas with an oxygen- containing gas is reacted in a flame with an oxygen-containing gas in an oxidation zone, the hot reaction mixture is cooled in a quenching zone and the solid material is separated from the gas stream, the amount of oxygen in the oxidation zone being greater than the amount necessary for the complete oxidation of the combustible gas and the zinc vapour.
- the manner in which the zinc vapour is provided is not limited.
- zinc powder or another zinc compound that yields zinc when subjected to heat treatment can be vaporised in a vaporiser and fed by means of a stream of inert gas into the apparatus containing the starting mixture.
- the starting mixture also contains a combustible gas, which may be hydrogen, methane, ethane or propane or a mixture thereof, hydrogen being preferred.
- a combustible gas which may be hydrogen, methane, ethane or propane or a mixture thereof, hydrogen being preferred.
- steam and/or carbon dioxide the reaction products from the combustion of the combustible gas.
- the starting mixture may preferably contain steam.
- the mixture of zinc vapour, combustible gas and steam or steam/carbon dioxide, and also other inert gases, for example nitrogen, is transferred to an oxidation zone, where it reacts in a flame with an oxygen-containing gas in an oxidation zone.
- the amount of oxygen in the oxidation zone is greater than the amount necessary for the complete oxidation of the combustible gas and the zinc vapour.
- the oxidation of the combustible gas for example hydrogen
- the oxidation of the zinc vapour according to Eq. 2 take place in parallel.
- FIG. 4 shows the sequence of the process according to the invention in diagrammatic form.
- A starting mixture
- B oxidation zone
- C quenching zone
- D separation of solid material
- 1 zinc vapour
- 2 combustible gas
- 3 water or water/carbon dioxide
- 4 oxidising air
- 5 quenching air.
- water is formed in the oxidation of the combustible gas in the oxidation zone, the presence of water and/or carbon dioxide in the starting mixture has been found to be essential for the formation of the zinc oxide particles according to the invention. Water is preferred. Water and/or carbon dioxide can result, for example, from the oxidation of a combustible gas using oxygen.
- the molar ratio of water to zinc vapour may preferably be from 15:1 to 35:1 and particularly preferably from 20:1 to 30:1.
- the molar ratio of combustible gas to zinc vapour in the starting mixture is from 5:1 to 25:1.
- a ratio of from 10:1 to 20:1 is particularly advantageous .
- the molar ratio of oxygen to combustible gas may be from 3:1 to 20:1.
- a ratio of from 6:1 to 15:1 may be particularly advantageous .
- the molar ratio of oxygen to zinc vapour may be from 5:1 to 30:1.
- a ratio of from 10:1 to 20:1 may be particularly advantageous.
- the temperature of the starting mixture may be from 920°C to 1250°C.
- zinc vapour can be obtained in a reductive vaporisation zone by vaporising zinc powder by means of a stream of inert gas in a centrally arranged pipe by means of a flame arranged around the centrally disposed pipe, which flame is generated by reaction of a combustible gas and an oxygen-containing gas, the combustible gas being present in a stoichiometric excess relative to the oxygen content of the oxygen-containing gas.
- the centrally arranged pipe is so adjusted that contact with the flame is avoided.
- a reductive vaporisation zone within the scope of the invention is understood as being a zone in which there prevails an atmosphere that is deficient in oxygen. This prevents the zinc powder from being oxidised even before the vaporisation.
- the molar ratio of combustible gas to the oxygen content of the oxygen-containing gas in the reductive vaporisation zone may preferably be from 1.5:1 to 3.5:1 and particularly preferably from 2:1 to 2.5:1.
- the invention provides a further process for the preparation of the zinc oxide powder according to the invention, which process is characterised in that zinc powder is vaporised inside a reactor and oxidised to zinc oxide, wherein in a reductive vaporisation zone, zinc powder is metered with the aid of a stream of inert gas into a centrally arranged pipe which projects into the vaporisation zone of the reactor, is vaporised by means of an externally arranged flame which is generated by reaction of a combustible gas with an oxygen-containing gas, - the combustible gas and the oxygen-containing gas being supplied in pipes arranged concentrically around the central pipe, and the centrally arranged pipe being longer than the pipes arranged concentrically around it, and - the combustible gas being present in a stoichi
- Figure 5 shows the apparatus for carrying out this process in diagrammatic form.
- A reductive vaporisation zone
- B oxidation zone
- C quenching zone
- 1 zinc powder + inert gas
- 2 combustible gas, preferably hydrogen
- 3 air
- 4 oxidising air
- 5 quenching air.
- the process according to the invention can preferably be carried out in such a manner that the molar ratio of combustible gas to the oxygen content of the oxygen- containing gas in the reductive vaporisation zone is from 1.5:1 to 3.5:1. This ratio may particularly preferably be from 2:1 to 2.5:1.
- the molar ratio of oxygen to combustible gas on entry into the oxidation zone may be preferably from 3:1 to 20:1 and particularly preferably from 6:1 to 15:1.
- the molar ratio of oxygen to zinc vapour on entry into the oxidation zone may be from 5:1 to 30:1.
- a ratio of from 10:1 to 20:1 may be particularly advantageous.
- High purity is understood as meaning a purity of at least 99 %, in the case of special requirements a purity of at least 99.9 %.
- lead not more than 20 ppm
- arsenic not more than 3 ppm
- cadmium not more than 15 ppm
- iron not more than 200 ppm
- antimony not more than 1 ppm
- mercury not more than 1 ppm
- the temperature of the mixture to be oxidised on entering the oxidation zone is preferably from 920°C to 1250°C.
- the temperature in the quenching zone immediately before the addition of the quenching air may preferably be from 600°C to 850°C, and the rate of cooling in the quenching zone may be from 1000 Kelvin/second to 50,000 Kelvin/second.
- the invention relates also to the use of the zinc oxide powder according to the invention as a constituent of sun protection compositions for protection against UV radiation, as a vulcanisation aid, in plastics and surface coatings as a UV absorber, as a crosslinking agent or catalyst in the curing or polymerisation of plastics or plastics monomers, in synthetic resins, in pharmaceutical and cosmetic preparations as an antifungal or antibacterial additive, in the preparation of ceramics, as a catalyst or catalyst support .
- the BET surface area is determined according to DIN 66131.
- the TEM images are obtained using a Hitachi TEM device, type H-75000-2.
- a Hitachi TEM device type H-75000-2.
- CCD camera of the TEM device By means of the CCD camera of the TEM device and subsequent image analysis, approximately from 1000 to 2000 aggregates are evaluated.
- the parameters are defined in accordance with ASTM 3849-89. Analysis of the form of the aggregates according to circular, ellipsoidal, linear and branched is carried out according to Herd et al . , Rubber, Chem. Technol. 66 (1993) 491.
- the tamped density is determined according to DIN ISO 787/11.
- Example 1 is carried out in a reactor according to Figure 4.
- Zinc powder (510 g/h) is conveyed by means of a stream of nitrogen (4.2 Nm 3 /h) into a reductive vaporisation zone in which a hydrogen/air flame (hydrogen: 4.0 Nm 3 /h, air: 8.0 Nm 3 /h) is burning. The zinc powder is thereby vaporised.
- a hydrogen/air flame hydrogen: 4.0 Nm 3 /h, air: 8.0 Nm 3 /h
- the reaction mixture comprising zinc vapour, hydrogen, nitrogen and water flows into the oxidation zone, into which 20 Nm 3 /h of air is added.
- the temperature Tl before addition of the oxidising air is 956°C. Then 10 Nm 3 /h of quenching air are added. The temperature T2 before addition of the quenching air is 648°C. The resulting zinc oxide powder is separated from the gas stream by filtration.
- Example 2 to 4 are carried out analogously to Example 1.
- the process parameters are to be found in Table 1.
- Example 5 (comparison example) :
- Zinc powder 250 g/h is conveyed by means of a stream of nitrogen (1.5 Nm 3 /h) into a vaporisation zone in which a hydrogen/air flame (hydrogen: 4.25 Nm 3 /h, air: 8.40 Nm 3 /h) is burning. The zinc powder is thereby vaporised.
- a hydrogen/air flame hydrogen: 4.25 Nm 3 /h, air: 8.40 Nm 3 /h
- the reaction mixture comprising zinc vapour, hydrogen, nitrogen and water is then cooled to a temperature of 850°C in a nucleation zone by the metered addition of 1 Nm 3 /h of nitrogen. 5 m 3 /h of oxidising air and 34 Nm 3 /h of quenching air are then added, the reaction temperature falling to values of less than 400°C.
- the resulting zinc oxide powder is separated from the gas stream by filtration.
- Example 5 is to be found in the patent application having the application number DE 10212680 of 22.03.2002.
- Example 6 is a commercially available zinc oxide powder from Nanophase, NanoTek® Zinc Oxide 99+%.
- Table 2 shows that the powders according to the invention of Examples 1 to 4 exhibit the claimed distribution of the aggregate forms into circular, linear, branched and ellipsoidal forms.
- the powders of Comparison Examples 5 and 6 do not exhibit this distribution.
- the equivalent circle diameter (ECD) of the powders according to the invention of Examples 1 to 4 is less than 100 nm, the mean aggregate circumference is less than 600 nm and the mean aggregate surface area is less than 7500 nm 2 .
- Figures 3a-d show a linear, branched, ellipsoidal and circular aggregate, respectively, of the powder of Example 3.
- the powder according to the invention can readily be incorporated into sun protection formulations. It exhibits high transparency and high UV protection.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cosmetics (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04764712A EP1664208B1 (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form |
AU2004274149A AU2004274149B2 (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form |
DE200460009944 DE602004009944T2 (en) | 2003-09-22 | 2004-09-02 | ZINC OXIDE POWDER AGGREGATES IN CIRCULAR, ELLIPSOIDER, LINEAR AND BRANCHED SHAPES |
JP2006527293A JP4490427B2 (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder agglomerates present in the form of circles, ellipses, lines and branches |
US10/572,936 US7371337B2 (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form |
CA 2539455 CA2539455C (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10343728.2 | 2003-09-22 | ||
DE2003143728 DE10343728A1 (en) | 2003-09-22 | 2003-09-22 | zinc oxide powder |
Publications (1)
Publication Number | Publication Date |
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WO2005028565A1 true WO2005028565A1 (en) | 2005-03-31 |
Family
ID=34352977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/009752 WO2005028565A1 (en) | 2003-09-22 | 2004-09-02 | Zinc oxide powder aggregates present in circular, ellipsoidal, linear and branched form |
Country Status (11)
Country | Link |
---|---|
US (1) | US7371337B2 (en) |
EP (1) | EP1664208B1 (en) |
JP (1) | JP4490427B2 (en) |
CN (1) | CN100480338C (en) |
AT (1) | ATE377631T1 (en) |
AU (1) | AU2004274149B2 (en) |
CA (1) | CA2539455C (en) |
DE (2) | DE10343728A1 (en) |
ES (1) | ES2295908T3 (en) |
TW (1) | TWI281459B (en) |
WO (1) | WO2005028565A1 (en) |
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EP1757664A2 (en) | 2005-08-25 | 2007-02-28 | Degussa AG | Paste of nanoscale powder and dispersant |
JP2007161580A (en) * | 2005-12-16 | 2007-06-28 | Degussa Gmbh | Method for producing zinc oxide powder |
WO2007144243A1 (en) * | 2006-06-13 | 2007-12-21 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
WO2007144237A2 (en) * | 2006-06-13 | 2007-12-21 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
JP2009545509A (en) * | 2006-08-17 | 2009-12-24 | エボニック デグサ ゲーエムベーハー | Silica coated zinc oxide particles obtained by flame pyrolysis method |
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KR100628841B1 (en) * | 2001-11-13 | 2006-09-29 | 데구사 아게 | Curable bonded assemblies capable of being dissociated |
DE10212680A1 (en) * | 2002-03-22 | 2003-10-09 | Degussa | Nanoscale zinc oxide, process for its production and use |
DE10343728A1 (en) | 2003-09-22 | 2005-04-21 | Degussa | zinc oxide powder |
DE10353995A1 (en) | 2003-11-19 | 2005-06-09 | Degussa Ag | Nanoscale, crystalline silicon powder |
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DE10343728A1 (en) | 2003-09-22 | 2005-04-21 | Degussa | zinc oxide powder |
DE102004003675A1 (en) | 2004-01-24 | 2005-08-11 | Degussa Ag | Dispersion and coating preparation containing nanoscale zinc oxide |
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2003
- 2003-09-22 DE DE2003143728 patent/DE10343728A1/en not_active Withdrawn
-
2004
- 2004-09-02 ES ES04764712T patent/ES2295908T3/en active Active
- 2004-09-02 CA CA 2539455 patent/CA2539455C/en not_active Expired - Fee Related
- 2004-09-02 EP EP04764712A patent/EP1664208B1/en not_active Not-in-force
- 2004-09-02 DE DE200460009944 patent/DE602004009944T2/en active Active
- 2004-09-02 CN CNB2004800274735A patent/CN100480338C/en not_active Expired - Fee Related
- 2004-09-02 JP JP2006527293A patent/JP4490427B2/en not_active Expired - Fee Related
- 2004-09-02 US US10/572,936 patent/US7371337B2/en not_active Expired - Fee Related
- 2004-09-02 AT AT04764712T patent/ATE377631T1/en not_active IP Right Cessation
- 2004-09-02 WO PCT/EP2004/009752 patent/WO2005028565A1/en active IP Right Grant
- 2004-09-02 AU AU2004274149A patent/AU2004274149B2/en not_active Ceased
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US6335002B1 (en) * | 1999-02-23 | 2002-01-01 | Showa Denko Kabushiki Kaisha | Ultrafine particulate zinc oxide, production thereof and cosmetic material using the same |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1757664A2 (en) | 2005-08-25 | 2007-02-28 | Degussa AG | Paste of nanoscale powder and dispersant |
JP2007161580A (en) * | 2005-12-16 | 2007-06-28 | Degussa Gmbh | Method for producing zinc oxide powder |
JP4571932B2 (en) * | 2005-12-16 | 2010-10-27 | エボニック デグサ ゲーエムベーハー | Production method of zinc oxide powder |
WO2007144243A1 (en) * | 2006-06-13 | 2007-12-21 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
WO2007144237A2 (en) * | 2006-06-13 | 2007-12-21 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
WO2007144237A3 (en) * | 2006-06-13 | 2008-10-30 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
US8048398B2 (en) | 2006-06-13 | 2011-11-01 | Evonik Degussa Gmbh | Process for preparing mixed metal oxide powders |
JP2009545509A (en) * | 2006-08-17 | 2009-12-24 | エボニック デグサ ゲーエムベーハー | Silica coated zinc oxide particles obtained by flame pyrolysis method |
Also Published As
Publication number | Publication date |
---|---|
TWI281459B (en) | 2007-05-21 |
AU2004274149B2 (en) | 2009-10-29 |
TW200526525A (en) | 2005-08-16 |
ATE377631T1 (en) | 2007-11-15 |
CN1856549A (en) | 2006-11-01 |
EP1664208A1 (en) | 2006-06-07 |
US20070037699A1 (en) | 2007-02-15 |
CN100480338C (en) | 2009-04-22 |
US7371337B2 (en) | 2008-05-13 |
DE10343728A1 (en) | 2005-04-21 |
AU2004274149A1 (en) | 2005-03-31 |
JP4490427B2 (en) | 2010-06-23 |
CA2539455A1 (en) | 2005-03-31 |
DE602004009944T2 (en) | 2008-08-28 |
JP2007505818A (en) | 2007-03-15 |
DE602004009944D1 (en) | 2007-12-20 |
ES2295908T3 (en) | 2008-04-16 |
CA2539455C (en) | 2009-04-28 |
EP1664208B1 (en) | 2007-11-07 |
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