WO2005007704A1 - Improvements to centrifugation of rubber latex - Google Patents
Improvements to centrifugation of rubber latex Download PDFInfo
- Publication number
- WO2005007704A1 WO2005007704A1 PCT/SG2003/000172 SG0300172W WO2005007704A1 WO 2005007704 A1 WO2005007704 A1 WO 2005007704A1 SG 0300172 W SG0300172 W SG 0300172W WO 2005007704 A1 WO2005007704 A1 WO 2005007704A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- latex
- drc
- centrifugation
- clustering
- creaming
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C1/00—Treatment of rubber latex
- C08C1/02—Chemical or physical treatment of rubber latex before or during concentration
- C08C1/075—Concentrating
- C08C1/08—Concentrating with the aid of creaming agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C1/00—Treatment of rubber latex
- C08C1/02—Chemical or physical treatment of rubber latex before or during concentration
- C08C1/075—Concentrating
- C08C1/10—Concentrating by centrifugation
Definitions
- This invention is or relates to a process for improving the efficiency of centrifugation of natural rubber (NR) latex.
- the invention relates to a process of increasing the efficiency of separation of NR latex cream by centrifugation.
- Natural rubber latex formulations in concentrated liquid form are extensively used to make foam rubber products, dipped goods such as gloves, extruded threads, balloons, bladders and in a whole host of applications.
- the consumption of natural rubber latex concentrates the world over amounts to about 900,000 tonnes dry rubber content (DRC) in the year 2000 and is increasing.
- DRC dry rubber content
- centrifugation process for concentration of natural rubber latex is very well known and widely practiced in all NR producing countries.
- the most efficient operation gives a separation efficiency of about 85 - 89% with the centrifuged cream component having about 60% DRC and the skim component at about 3 to 5% DRC. Improvements that have been effected through the years to impact on the efficiency and costs of centrifugation relate to machines used rather than the process itself.
- Creaming agents such as alginates, tamarind seed powder, polyvinyl alcohol, etc. are admixed with natural rubber field latex and allowed to cream up by standing through a period of several weeks.
- the aqueous serum phase is run off leaving the cream phase, which is stabilised appropriately with ammonia.
- the creaming process separates most of the latex rubber particles with no skim fraction, i.e. achieving a 97% to 98% separation efficiency. While the creaming process can attain a DRC of around 65%, the resultant latex concentrate has high viscosity.
- the latter i.e. the creaming process
- the creaming process has as a result all but disappeared from commercial operations .
- the process according to the present invention comprises effecting the clustering of latex particles in the natural rubber latex which is to be separated by centrifugation.
- the clustering of the latex particles is effected prior to centrifuging the latex.
- the clustering of the latex particles is achieved by adding a latex creaming agent.
- the creaming agent is chosen from any one of the following: alginates, tamarind seed powder, and polyvinyl alcohol.
- the concentration of creaming agents added is in the range of 0.3% to 0.7% of DRC. Higher concentrations may be used without any particular advantage .
- the input field latex is diluted to a lower DRC and/or a detergent is added.
- the essence of our invention is to effect latex particle clustering prior to centrifugation.
- the clustering of latex particles must be achieved without destabilising the latex.
- Latex particle clustering can be achieved by adding creaming agents .
- the clustering of latex particles is achieved within hours of the addition of the creaming agent and centrifugation subsequently enables the clustered small particles to join the larger particles to appear in the concentrate.
- the limitation of separation is only dictated by the increasing viscosity of the concentrate at DRC's higher than 60%.
- a compromise can be achieved by attaining centrifugation efficiency in excess of 95% and accepting some rubber in the skim fraction which can be as low as 1 to 2%.
- the process of the present invention uses commercially available creaming agents at concentrations used and acceptable to the industry and centrifuged in any commercially available machines and used by the industry.
- Field latex at DRC's ranging from 25-35% is a moniated to 0.3% and a creaming agent at the concentration of 0.5 to 0.7 on DRC is added. Higher concentrations can be tolerated but provide no particular advantage.
- the latex is allowed to stand for 2-24 hours and then centrifuged in the usual manner.
- the separation of cream and skim with the former ammoniated to 0.7%, is highly efficient and the table below provides the comparison between the conventional centrifuging and creaming process and our novel process .
- the process can be further enhanced and improved by adjustments of DRC of input latex, refinement of creaming agents, addition of soaps etc.
- the essence of our invention is the prior clustering of latex particles before mechanical centrifugation.
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SG2003/000172 WO2005007704A1 (en) | 2003-07-21 | 2003-07-21 | Improvements to centrifugation of rubber latex |
AU2003256222A AU2003256222A1 (en) | 2003-07-21 | 2003-07-21 | Improvements to centrifugation of rubber latex |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SG2003/000172 WO2005007704A1 (en) | 2003-07-21 | 2003-07-21 | Improvements to centrifugation of rubber latex |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005007704A1 true WO2005007704A1 (en) | 2005-01-27 |
Family
ID=34075276
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SG2003/000172 WO2005007704A1 (en) | 2003-07-21 | 2003-07-21 | Improvements to centrifugation of rubber latex |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU2003256222A1 (en) |
WO (1) | WO2005007704A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013055202A1 (en) * | 2011-10-11 | 2013-04-18 | Sime Darby Malaysia Berhad | A method of recovering rubber from skim natural rubber latex |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL47691C (en) * | ||||
US1754535A (en) * | 1927-12-28 | 1930-04-15 | Rubber Latex Res Corp | Purifying and concentrating latex |
US1777045A (en) * | 1925-07-02 | 1930-09-30 | Naugatuck Chem Co | Method of treating rubber latex and product obtained thereby |
US1816018A (en) * | 1923-03-10 | 1931-07-28 | Us Rubber Co | Concentration of latex by centrifugal action |
GB415133A (en) * | 1933-02-23 | 1934-08-23 | Rubber Res Inst Of Malaya | Improvements relating to the treatment of rubber latex |
GB490781A (en) * | 1937-04-10 | 1938-08-22 | Algemeene Vereeniging Van Rubb | Process for preparing a concentrated rubber dispersion from rubberlatex |
US2161731A (en) * | 1937-04-10 | 1939-06-06 | Algemeene Vereeniging Van Rubb | Process for preparing a concentrated rubber dispersion from latex and product |
US2371560A (en) * | 1940-05-07 | 1945-03-13 | Bie Godfried Johan Van Der | Method of concentrating latex |
US2423766A (en) * | 1941-02-13 | 1947-07-08 | Dow Chemical Co | Creaming latexes |
GB690451A (en) * | 1950-04-06 | 1953-04-22 | Separator Ab | Method of concentrating latex by creaming and centrifugal separation |
-
2003
- 2003-07-21 WO PCT/SG2003/000172 patent/WO2005007704A1/en active Application Filing
- 2003-07-21 AU AU2003256222A patent/AU2003256222A1/en not_active Abandoned
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL47691C (en) * | ||||
US1816018A (en) * | 1923-03-10 | 1931-07-28 | Us Rubber Co | Concentration of latex by centrifugal action |
US1777045A (en) * | 1925-07-02 | 1930-09-30 | Naugatuck Chem Co | Method of treating rubber latex and product obtained thereby |
US1754535A (en) * | 1927-12-28 | 1930-04-15 | Rubber Latex Res Corp | Purifying and concentrating latex |
GB415133A (en) * | 1933-02-23 | 1934-08-23 | Rubber Res Inst Of Malaya | Improvements relating to the treatment of rubber latex |
GB490781A (en) * | 1937-04-10 | 1938-08-22 | Algemeene Vereeniging Van Rubb | Process for preparing a concentrated rubber dispersion from rubberlatex |
US2161731A (en) * | 1937-04-10 | 1939-06-06 | Algemeene Vereeniging Van Rubb | Process for preparing a concentrated rubber dispersion from latex and product |
US2371560A (en) * | 1940-05-07 | 1945-03-13 | Bie Godfried Johan Van Der | Method of concentrating latex |
US2423766A (en) * | 1941-02-13 | 1947-07-08 | Dow Chemical Co | Creaming latexes |
GB690451A (en) * | 1950-04-06 | 1953-04-22 | Separator Ab | Method of concentrating latex by creaming and centrifugal separation |
Non-Patent Citations (1)
Title |
---|
FALCONER FLINT C.: "The chemistry and technology of rubber latex", 1938, CHAPMAN & HALL, LTD., LONDON, article "Chapter V: The preservation, shipping and concentration of latex", pages: 195 - 215 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013055202A1 (en) * | 2011-10-11 | 2013-04-18 | Sime Darby Malaysia Berhad | A method of recovering rubber from skim natural rubber latex |
CN103917564A (en) * | 2011-10-11 | 2014-07-09 | 森达美马来西亚有限公司 | A method of recovering rubber from skim natural rubber latex |
Also Published As
Publication number | Publication date |
---|---|
AU2003256222A1 (en) | 2005-02-04 |
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