WO2004111448A1 - Superheating method in a geothermal plant - Google Patents

Superheating method in a geothermal plant Download PDF

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Publication number
WO2004111448A1
WO2004111448A1 PCT/IT2004/000315 IT2004000315W WO2004111448A1 WO 2004111448 A1 WO2004111448 A1 WO 2004111448A1 IT 2004000315 W IT2004000315 W IT 2004000315W WO 2004111448 A1 WO2004111448 A1 WO 2004111448A1
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Prior art keywords
plant
superheating
fluid
geothermal
motive fluid
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PCT/IT2004/000315
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French (fr)
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WO2004111448B1 (en
Inventor
Fabio Neri
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Fabio Neri
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F03MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
    • F03GSPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
    • F03G7/00Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for
    • F03G7/04Mechanical-power-producing mechanisms, not otherwise provided for or using energy sources not otherwise provided for using pressure differences or thermal differences occurring in nature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/10Geothermal energy

Definitions

  • the invention refers to a process for heating and finds application in the field of conversion of the thermal energy of geothermal fluids to mechanical and/or electric power.
  • the invention refers, in addition, to a plant for implementing such a process.
  • Geothermal fluids of endogenous origin used for generating electric power, are made by a mixture of steam and non-condensable gas or by pressurised saturated or sub-cooled water with dissolved solids and non-condensable gas.
  • the steam is saturated or slightly super heated and may be directly used as motive fluid of a turbo generator unit, of various typology, which generates electric power.
  • the endogenous fluid is initially flashed, in one or more stages, in order to produce saturated steam, which may directly feed a turbo generator unit.
  • the heat content of the endogenous fluid is transferred to a secondary fluid, which feeds the electric power plant.
  • Geothermal fluid FE produced by one or more geothermal wells, feeds normally a unit SE that produces the motive fluid FM of the power plant
  • the unit SE belongs to various typologies: if the endogenous fluid is steam with entrained solids then SE is used to remove the solids or SE may be a washing apparatus for eventually neutralising the chlorides contained in the fluid. This unit operates as a separator of the liquid phase if the fluid is a mixture of steam and liquid water.
  • SE carries out the separating process in one or two flashing steps in order to generate a vapour phase at one or two pressure levels.
  • the geothermal plant CE adopts a consolidated technology: its simpler scheme includes a steam turbine, with a single inlet and without bleeding, that drives an electric generator.
  • the outlet of the steam turbine is connected to a steam condenser whose pressure is kept below the atmospheric value and whose temperature is that corresponding to the saturation value for the fluid. Since the fluid features a certain amount of non-condensable gases, these gases must be exhausted from the condenser with the help of special compressors. If the gas content in the fluid is above 10-15 % wt., it could be convenient to adopt a conversion process without steam condenser and the fluid is discharged from the turbine directly to the atmosphere.
  • geothermal power plants in operation exploit the heat content of the endogenous geothermal fluid and do not use, for the generation of the electric power, other forms of chemical energy.
  • the process which is the object of this invention, consists in superheating of the motive fluid of the geothermal power plant, by means of a renewable source of energy, before the fluid enters the plant itself.
  • a renewable source of energy is here intended any solid, liquid or gaseous material having a non -fossil origin and featuring a chemical energy that can be converted into thermal energy.
  • the invention may apply to new geothermal power plants but also to existing power plants when this is allowed by their operative conditions and their characteristics.
  • the main advantage of this invention is that the same plant can generate electric power by means of two renewable energy sources (i.e. the geothermal fluid and one of the renewable above mentioned), having an overall efficiency equivalent to that of two distinguished plants each fed by only one renewable source, with an investment much lower than that required by two separated plants.
  • two renewable energy sources i.e. the geothermal fluid and one of the renewable above mentioned
  • Fossil Superheat Hybrid System is similar to the invention here claimed and represented in Figure 2, but it is different for the following substantial differences: a) the process of the invention here claimed does not require modification of the thermal cycle of the power plant, but it is applicable to existing plants or to new plants without modifications of the thermal cycle.
  • the process FSHS entails a substantial modification of the cycle of the geothermal plant by adoption of special materials that can operate up to 540 0 C in an environment containing hydrogen sulphide.
  • the ratio between the power generated by the plant with superheating and the power generated without superheating is greater than or equal to 1.4 in the process FSHS, while in the process here proposed the maximum value is 1.3. In the year 1994 Louis J.
  • the Blaize's process features a few of similarities with the process here proposed but is substantially different for the following reasons: a) The Blaize's process is conceived for exploiting the heat contained in the hot and dry rocks of the terrestrial crust by means of thermal exchange between the rocks and pressurised water, pumped from surface to depth trough suitable injection wells and withdrawn at temperature of 350 0 C by means of appropriate production wells.
  • the process, according the invention here claimed, is applicable to geothermal fluids of endogenous origin and not to exogenous fluids injected into deep rocks from the hearth surface with the purpose of extracting the heat stored in them.
  • the temperature of the fluid is assumed equal to 350 0 C at the head of the production wells.
  • the heat stored in the fluid is exploited by means of a battery of heat exchangers that generates saturated steam.
  • This steam is first superheated by the use of fossil fuel, and then it feeds a closed loop electric power plant based on the Rankine cycle.
  • the geothermal fluid is endogenous, it does not exchange heat with other fluids and it feeds directly, after one or two stage of flashing, the geothermal power plant that adopts an open cycle.
  • the temperature of the saturated steam, before superheating, is about 350 0 C in the Baize's process, while in the process of this invention the temperature is about 350 0 C downstream the superheating process.
  • the power plant can be operated even if the equipment performing the superheating, i.e. the superheater is not operating, in the Blaize's process any outage to the superheater causes the outage of the power plant.
  • the process of this invention has been conceived for using a renewable fuel and the invention provides advantages only with such a typology of fuel and not, for instance, if natural gas or coal would be used for superheating the fluid.
  • the process and the plant of this invention are represented in the schemes of
  • FIG. 1 Figure 2 and Figure 3 and include following equipment and/or systems and/or components:
  • SE - Eventual apparatus for processing the endogenous fluid may be: i) A separator of solid particles or an apparatus for washing the fluid if it is in vapour phase, ii) A single or double flash reactor with phase separator if the fluid is mainly in liquid phase, iii) A simple centrifugal separator of the liquid phase, if the fluid is mainly in vapour phase
  • BM - Renewable fuel as defined above in this document, i.e. biomass or RDF (Refused Derived Fuel) or others.
  • SH - Superheater apparatus, which increases the temperature of the motive fluid.
  • FM Motive fluid of the geothermal plant.
  • CE Geothermal power plant.
  • the geothermal fluid FE feeds normally a unit SE.
  • This unit described above, generates a flow of gaseous material, which is the motive fluid of the plant and generates also a flow SL of liquid or solid material.
  • the motive fluid FM produced by the unit SE enters the superheater SH, which is a device that increases the temperature of the motive fluid FM.
  • the superheater increases the fluid temperature up to the maximum value allowed by the geothermal plant, which is about 400 0 C, or up to a lower value considered more appropriate.
  • the increase of temperature occurs by using the heat content of a renewable fuel, as for instance biomass or RDF (Refuse Derived Fuel), represented in the schemes of Figure 2 and Figure 3 by stream BM.
  • the superheater may adopt various technologies as direct combustion of renewable fuels or combustion of an intermediate liquid or gaseous product, which comes from the thermal conversion of the fuel.
  • the motive fluid, exiting the superheater, features an enthalpy higher than that at the inlet and feeds the geothermal power plant CE.
  • the condenser operates at the pressure of 0,08 bar; in such a condition the plant may generate a net power of 15 MWe.
  • MX - Gathering device of motive fluid FM The plant configuration shown in Figure 3 allows the geothermal plant to operate with (V1 open and VO closed) or without (VO open and V1 closed) superheating. As a consequence the plant can be operated at base load during any shut down of superheater.
  • the superheater based on direct fuel combustion, is fed by biomass with a heat content of 15 thermal MWh. In such a condition the superheating allows to generate electric power with a marginal efficiency of about 25 %.
  • the advantage of the process here proposed is that the investment required for converting the biomass to electric power is much lower than that necessary for the construction of a power plant fuelled only by biomass.
  • the superheater may be built adopting also technologies different from the direct combustion and in particular could be based on combustion of a synthesis gas derived from thermal conversion of the primary renewable fuel.
  • the process of superheating may be applied to existing power plants when their effective electric load becomes, as a consequence of the natural flow rate decline during operation, much lower than the nominal maximum load.
  • the process can find also application in geothermal plants of novel construction. From a functional point of view the superheating process is situated upstream the heat conversion process of the motive fluid to power, while from the point of plant lay out view, the superheating unit is separated from the power plant and may be located also at a great distance.

Abstract

The present invention is a process for increasing the power generated by a geothermal power plant, which adopts a steam cycle. The proposed process consists in superheating the motive fluid of the plant up to a maximum temperature of 400°C. the superheating is carried out introducing suitable equipment upstream the power plant by means of chemical energy of a renewable fuel like biomass or similar. The plant itself does not require important modifications. The process as well the plant for superheating the motive fluid is claimed.

Description

SUPERHEATING METHOD IN A GEOTHERMAL PLANT
DESCRIPTION
Technical Field
The invention refers to a process for heating and finds application in the field of conversion of the thermal energy of geothermal fluids to mechanical and/or electric power.
The invention refers, in addition, to a plant for implementing such a process.
Background Art
Geothermal fluids of endogenous origin, used for generating electric power, are made by a mixture of steam and non-condensable gas or by pressurised saturated or sub-cooled water with dissolved solids and non-condensable gas.
In the first case the steam is saturated or slightly super heated and may be directly used as motive fluid of a turbo generator unit, of various typology, which generates electric power.
In the second case the endogenous fluid is initially flashed, in one or more stages, in order to produce saturated steam, which may directly feed a turbo generator unit.
Sometimes the heat content of the endogenous fluid is transferred to a secondary fluid, which feeds the electric power plant.
The process scheme of a geothermal plant, normally adopted, is represented in
Figure 1. Geothermal fluid FE, produced by one or more geothermal wells, feeds normally a unit SE that produces the motive fluid FM of the power plant
CE.
The unit SE belongs to various typologies: if the endogenous fluid is steam with entrained solids then SE is used to remove the solids or SE may be a washing apparatus for eventually neutralising the chlorides contained in the fluid. This unit operates as a separator of the liquid phase if the fluid is a mixture of steam and liquid water.
If FE is mainly liquid then SE carries out the separating process in one or two flashing steps in order to generate a vapour phase at one or two pressure levels.
The geothermal plant CE adopts a consolidated technology: its simpler scheme includes a steam turbine, with a single inlet and without bleeding, that drives an electric generator.
Usually the outlet of the steam turbine is connected to a steam condenser whose pressure is kept below the atmospheric value and whose temperature is that corresponding to the saturation value for the fluid. Since the fluid features a certain amount of non-condensable gases, these gases must be exhausted from the condenser with the help of special compressors. If the gas content in the fluid is above 10-15 % wt., it could be convenient to adopt a conversion process without steam condenser and the fluid is discharged from the turbine directly to the atmosphere.
The rate of the motive fluid of a geothermal plant undergoes a slow or rapid decline, which entails a temporal decline of the generated power. It comes out that during the life of the plant the steam turbine will operate at a rate lower than the nominal (see: N. Gennai, G. Sestini: Studio sulle cause del declino della portata di vapore endogeno nel tempo. Ricerche di Termotecnica, Vol.14. 1964;
G. Neri: Flow rate Decline and Pressure Transients in the Larderello
Geothermal Field. Prod 3° Workshop on Geothermal Energy. Stanford
University, Stanford 1988; M.A. Grant, IA Donaldson, P. F. Bixley: Geothermal
Reservoir Engineering, Academic Press 1982).
The geothermal power plants in operation exploit the heat content of the endogenous geothermal fluid and do not use, for the generation of the electric power, other forms of chemical energy.
Disclosure of Invention
The process, which is the object of this invention, consists in superheating of the motive fluid of the geothermal power plant, by means of a renewable source of energy, before the fluid enters the plant itself. For renewable source of energy is here intended any solid, liquid or gaseous material having a non -fossil origin and featuring a chemical energy that can be converted into thermal energy.
The invention may apply to new geothermal power plants but also to existing power plants when this is allowed by their operative conditions and their characteristics.
The main advantage of this invention is that the same plant can generate electric power by means of two renewable energy sources (i.e. the geothermal fluid and one of the renewable above mentioned), having an overall efficiency equivalent to that of two distinguished plants each fed by only one renewable source, with an investment much lower than that required by two separated plants.
The idea of using geothermal energy, together with a fossil fuel in the same plant for generating electric power is not new. Such idea has been investigated by R. Di Pippo and others in the years between 1978 and 1981 and is the basis of a few of process schemes having in common, with the process here proposed, only the concept of super heating (see J. Kestin, R. DiPippo, H. E.
Khalifa: Hybrid Geothermal-Fossil Power Plant, Mechanical Engineering Vol.
100, Pag. 28-35, Dec 1978).
The known process named Fossil Superheat Hybrid System (FSHS) is similar to the invention here claimed and represented in Figure 2, but it is different for the following substantial differences: a) the process of the invention here claimed does not require modification of the thermal cycle of the power plant, but it is applicable to existing plants or to new plants without modifications of the thermal cycle. The process FSHS entails a substantial modification of the cycle of the geothermal plant by adoption of special materials that can operate up to 540 0C in an environment containing hydrogen sulphide. b) the ratio between the power generated by the plant with superheating and the power generated without superheating is greater than or equal to 1.4 in the process FSHS, while in the process here proposed the maximum value is 1.3. In the year 1994 Louis J. Blaize obtained in the United States of America the patent n. 5,311 ,741 with reference to a process named "Hybrid Electric Power Generation". The Blaize's process features a few of similarities with the process here proposed but is substantially different for the following reasons: a) The Blaize's process is conceived for exploiting the heat contained in the hot and dry rocks of the terrestrial crust by means of thermal exchange between the rocks and pressurised water, pumped from surface to depth trough suitable injection wells and withdrawn at temperature of 350 0C by means of appropriate production wells. The process, according the invention here claimed, is applicable to geothermal fluids of endogenous origin and not to exogenous fluids injected into deep rocks from the hearth surface with the purpose of extracting the heat stored in them. Moreover this concept never found application at yet. b) In the Blaize's process the temperature of the fluid is assumed equal to 350 0C at the head of the production wells. The heat stored in the fluid is exploited by means of a battery of heat exchangers that generates saturated steam. This steam is first superheated by the use of fossil fuel, and then it feeds a closed loop electric power plant based on the Rankine cycle. In the process of this invention the geothermal fluid is endogenous, it does not exchange heat with other fluids and it feeds directly, after one or two stage of flashing, the geothermal power plant that adopts an open cycle. The temperature of the saturated steam, before superheating, is about 350 0C in the Baize's process, while in the process of this invention the temperature is about 350 0C downstream the superheating process. c) According to the process of this invention the power plant can be operated even if the equipment performing the superheating, i.e. the superheater is not operating, in the Blaize's process any outage to the superheater causes the outage of the power plant. d) The process of this invention has been conceived for using a renewable fuel and the invention provides advantages only with such a typology of fuel and not, for instance, if natural gas or coal would be used for superheating the fluid. The process and the plant of this invention are represented in the schemes of
Figure 2 and Figure 3 and include following equipment and/or systems and/or components:
FE - Geothermal fluid of endogenous origin
SE - Eventual apparatus for processing the endogenous fluid. According to the nature and to the composition of fluid the apparatus may be: i) A separator of solid particles or an apparatus for washing the fluid if it is in vapour phase, ii) A single or double flash reactor with phase separator if the fluid is mainly in liquid phase, iii) A simple centrifugal separator of the liquid phase, if the fluid is mainly in vapour phase
SL - Liquid phase from unit SE
BM - Renewable fuel, as defined above in this document, i.e. biomass or RDF (Refused Derived Fuel) or others.
SH - Superheater: apparatus, which increases the temperature of the motive fluid.
FM - Motive fluid of the geothermal plant. CE - Geothermal power plant.
Mode for Carrying out the Invention
In the process represented in Figure 2 the geothermal fluid FE, of endogenous origin, feeds normally a unit SE. This unit, described above, generates a flow of gaseous material, which is the motive fluid of the plant and generates also a flow SL of liquid or solid material. The motive fluid FM, produced by the unit SE enters the superheater SH, which is a device that increases the temperature of the motive fluid FM.
The superheater increases the fluid temperature up to the maximum value allowed by the geothermal plant, which is about 400 0C, or up to a lower value considered more appropriate. The increase of temperature occurs by using the heat content of a renewable fuel, as for instance biomass or RDF (Refuse Derived Fuel), represented in the schemes of Figure 2 and Figure 3 by stream BM. The superheater may adopt various technologies as direct combustion of renewable fuels or combustion of an intermediate liquid or gaseous product, which comes from the thermal conversion of the fuel.
The motive fluid, exiting the superheater, features an enthalpy higher than that at the inlet and feeds the geothermal power plant CE.
Lets consider a geothermal fluid with following characteristics:
Nature of fluid Mixture of slightly super-heated steam and inert gas
Flow rate of fluid 30 kg/s
Pressure of fluid 6,5 bar
Temperature of fluid 170 0C
Gas content 3% by weight
Gas composition Carbon dioxide
The fluid feeds a geothermal plant equipped by:
i) a condensing turbine ii) direct contact condenser iii) battery of centrifugal inter-cooled compressors for gas extraction from condenser iv) evaporative cooling towers
The condenser operates at the pressure of 0,08 bar; in such a condition the plant may generate a net power of 15 MWe.
Superheating the motive fluid up to the temperature of 370 0C, prior of its expansion through the steam turbine, allows an increase of the electric power generated up to about 19 MWe. The superheating may be carried out according to the scheme of Figure 3. In such a scheme appear the following devices:
VO, V1 - On-Off valves
SP - Device diverting the direction of motive fluid FM
MX - Gathering device of motive fluid FM. The plant configuration shown in Figure 3 allows the geothermal plant to operate with (V1 open and VO closed) or without (VO open and V1 closed) superheating. As a consequence the plant can be operated at base load during any shut down of superheater.
The superheater, based on direct fuel combustion, is fed by biomass with a heat content of 15 thermal MWh. In such a condition the superheating allows to generate electric power with a marginal efficiency of about 25 %. The advantage of the process here proposed is that the investment required for converting the biomass to electric power is much lower than that necessary for the construction of a power plant fuelled only by biomass. The superheater may be built adopting also technologies different from the direct combustion and in particular could be based on combustion of a synthesis gas derived from thermal conversion of the primary renewable fuel.
The process of superheating may be applied to existing power plants when their effective electric load becomes, as a consequence of the natural flow rate decline during operation, much lower than the nominal maximum load. The process can find also application in geothermal plants of novel construction. From a functional point of view the superheating process is situated upstream the heat conversion process of the motive fluid to power, while from the point of plant lay out view, the superheating unit is separated from the power plant and may be located also at a great distance.

Claims

.
1 Process for superheating the motive fluid of a geothermal power plant characterised by a maximum temperature after superheating preferably lower or equal to 400 0C and characterised by the use of a renewable energy source.
2 Process according claim 1 characterised by the fact that it is applied to existing power plant.
3 Process according claims 1 and 2 characterised by the fact that, for the superheating, is used a renewable energy source made by biomass, fuel derived from refused or similar.
4 Plant for implementing the process, according to one or more of the previous claims 1 , 2 and 3, characterised by the adoption of a superheating system SH that is fed with a renewable energy source and that increases the temperature of the motive fluid FM of the geothermal power plant CE.
PCT/IT2004/000315 2003-06-16 2004-05-28 Superheating method in a geothermal plant WO2004111448A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITPI2003A000048 2003-06-16
ITPI20030048 ITPI20030048A1 (en) 2003-06-16 2003-06-16 FLUID OVERHEATING PROCESS AND PLANT

Publications (2)

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WO2004111448A1 true WO2004111448A1 (en) 2004-12-23
WO2004111448B1 WO2004111448B1 (en) 2005-02-03

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR20080100375A (en) * 2008-06-02 2010-01-27 Εστια Συμβουλοι Και Μηχανικοι Α.Ε. Combined cycle for the production of electric energy and heat from solar energy and biomass combustion.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950949A (en) * 1974-03-26 1976-04-20 Energy Technology Incorporated Method of converting low-grade heat energy to useful mechanical power
US5311741A (en) * 1992-10-09 1994-05-17 Blaize Louis J Hybrid electric power generation
WO2001044658A1 (en) * 1999-12-17 2001-06-21 The Ohio State University Heat engine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950949A (en) * 1974-03-26 1976-04-20 Energy Technology Incorporated Method of converting low-grade heat energy to useful mechanical power
US5311741A (en) * 1992-10-09 1994-05-17 Blaize Louis J Hybrid electric power generation
WO2001044658A1 (en) * 1999-12-17 2001-06-21 The Ohio State University Heat engine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR20080100375A (en) * 2008-06-02 2010-01-27 Εστια Συμβουλοι Και Μηχανικοι Α.Ε. Combined cycle for the production of electric energy and heat from solar energy and biomass combustion.

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WO2004111448B1 (en) 2005-02-03

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