WO2004096703A3 - Ammonia oxidation process - Google Patents

Ammonia oxidation process Download PDF

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Publication number
WO2004096703A3
WO2004096703A3 PCT/GB2004/001785 GB2004001785W WO2004096703A3 WO 2004096703 A3 WO2004096703 A3 WO 2004096703A3 GB 2004001785 W GB2004001785 W GB 2004001785W WO 2004096703 A3 WO2004096703 A3 WO 2004096703A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
decomposition
nitrous oxide
ammonia
contacted
Prior art date
Application number
PCT/GB2004/001785
Other languages
French (fr)
Other versions
WO2004096703A8 (en
WO2004096703A2 (en
Inventor
Sean Alexander Axon
Duncan Roy Coupland
James Richard Foy
John Ridland
Ian Carmichael Wishart
Original Assignee
Johnson Matthey Plc
Sean Alexander Axon
Duncan Roy Coupland
James Richard Foy
John Ridland
Ian Carmichael Wishart
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey Plc, Sean Alexander Axon, Duncan Roy Coupland, James Richard Foy, John Ridland, Ian Carmichael Wishart filed Critical Johnson Matthey Plc
Priority to BRPI0409944-3A priority Critical patent/BRPI0409944A/en
Priority to EP04729673A priority patent/EP1633677A2/en
Priority to JP2006506185A priority patent/JP2006525216A/en
Publication of WO2004096703A2 publication Critical patent/WO2004096703A2/en
Publication of WO2004096703A3 publication Critical patent/WO2004096703A3/en
Publication of WO2004096703A8 publication Critical patent/WO2004096703A8/en
Priority to NO20054967A priority patent/NO20054967L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24—Nitric oxide (NO)
    • C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J35/19—
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24—Nitric oxide (NO)
    • C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/265—Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208—Preparation in gaseous phase
    • C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • C01C3/0216—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)

Abstract

A process for the oxidation of ammonia, including the Andrussow process is described, wherein a mixture comprising air and ammonia is contacted with a precious metal ammonia oxidation catalyst and the resultant gas mixture contacted with a catalyst effective for the decomposition of nitrous oxide, characterised in that prior to contacting the gas mixture with the catalyst effective for the decomposition of nitrous oxide, the gas mixture is contacted with a guard material. The guard material protects the nitrous oxide decomposition catalyst from deposition of precious metal and/or catalyst poisoning. In a preferred embodiment the catalyst effective for the decomposition of nitrous oxide also functions as an ammonia oxidation catalyst.
PCT/GB2004/001785 2003-04-29 2004-04-27 Ammonia oxidation process WO2004096703A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0409944-3A BRPI0409944A (en) 2003-04-29 2004-04-27 process for ammonia oxidation, catalyst assembly and its uses
EP04729673A EP1633677A2 (en) 2003-04-29 2004-04-27 Ammonia oxidation process
JP2006506185A JP2006525216A (en) 2003-04-29 2004-04-27 Ammonia oxidation method
NO20054967A NO20054967L (en) 2003-04-29 2005-10-26 Ammonia oxidation process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0309747 2003-04-29
GB0309747.4 2003-04-29

Publications (3)

Publication Number Publication Date
WO2004096703A2 WO2004096703A2 (en) 2004-11-11
WO2004096703A3 true WO2004096703A3 (en) 2005-01-20
WO2004096703A8 WO2004096703A8 (en) 2005-03-17

Family

ID=27741488

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2004/001785 WO2004096703A2 (en) 2003-04-29 2004-04-27 Ammonia oxidation process

Country Status (12)

Country Link
EP (1) EP1633677A2 (en)
JP (1) JP2006525216A (en)
KR (1) KR20060017503A (en)
CN (1) CN100363252C (en)
BR (1) BRPI0409944A (en)
CO (1) CO5660283A2 (en)
GB (1) GB0315643D0 (en)
IL (1) IL171472A (en)
NO (1) NO20054967L (en)
TW (2) TWI346087B (en)
WO (1) WO2004096703A2 (en)
ZA (2) ZA200508788B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0416982D0 (en) * 2004-07-30 2004-09-01 Johnson Matthey Plc Oxidation process
RU2397810C2 (en) * 2006-03-10 2010-08-27 Умикоре Аг Унд Ко. Кг Catalyst and method of decomposing dinitrogen monoxide and method and device for producing nitric acid
PL2145663T3 (en) * 2008-07-16 2011-04-29 Umicore Ag & Co Kg Catalyst for converting nitrous oxide and its application in industrial nitric acid production
GB0819094D0 (en) * 2008-10-20 2008-11-26 Johnson Matthey Plc Catalyst containment unit
US8524185B2 (en) 2008-11-03 2013-09-03 Basf Corporation Integrated SCR and AMOx catalyst systems
GB201002378D0 (en) * 2010-02-12 2010-03-31 Johnson Matthey Plc Catalyst structures
IT1401698B1 (en) 2010-09-13 2013-08-02 Sued Chemie Catalysts Italia CATALYST FOR THE DECOMPOSITION OF DANGEROUS PROSTOSIS.
DE102012106732A1 (en) 2012-07-24 2014-01-30 Heraeus Materials Technology Gmbh & Co. Kg catalyst
NO335207B1 (en) * 2013-01-28 2014-10-20 Yara Int Asa Catalytically active component of catalyst, catalyst and use thereof.
NO20130145A1 (en) * 2013-01-28 2014-07-29 Yara Int Asa An ammonia oxidation catalyst for the preparation of nitric acid based on metal dipped yttrium
GB2536530B (en) 2014-12-19 2019-07-17 Johnson Matthey Plc Catalyst manufacturing method
FI20146177A (en) * 2014-12-31 2016-07-01 Teknologian Tutkimuskeskus Vtt Oy Process for the preparation of catalytic nano coating
EP3056267A1 (en) * 2015-02-12 2016-08-17 Umicore AG & Co. KG Catalyst gauze and installation for the catalytic oxidation of ammunia
CZ201750A3 (en) * 2017-01-30 2018-03-07 Ústav fyzikální chemie J. Heyrovského AV ČR, v. v. i. A method of production of catalysts of a perovskite structure, catalysts perovskite structure and their use for high temperature decomposition of N2O

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774069A (en) * 1985-06-28 1988-09-27 Johnson Matthey Public Limited Company Process for the manufacture of nitric oxide
EP0611041A1 (en) * 1993-02-09 1994-08-17 Johnson Matthey Public Limited Company Catchment device for platinum recovery
US5478549A (en) * 1994-12-15 1995-12-26 E. I. Du Pont De Nemours And Company Production of nitric oxide
WO1998028073A1 (en) * 1996-12-20 1998-07-02 Imperial Chemical Industries Plc Ammonia oxidation catalyst
WO1999007638A1 (en) * 1997-08-12 1999-02-18 L. & C. Steinmüller Gmbh Method for producing nitric acid and device for carrying out said method
WO1999055621A1 (en) * 1998-04-27 1999-11-04 Basf Aktiengesellschaft Method for the catalytic decomposition of n2o
WO1999064352A1 (en) * 1998-06-09 1999-12-16 Imperial Chemical Industries Plc Catalytic process for the oxidation of ammonia and catalyst assembly
WO2000013789A1 (en) * 1998-09-09 2000-03-16 Porzellanwerk Kloster Veilsdorf Gmbh Ceramic catalyst for selectively decomposing n2o and a method for the production thereof
WO2001011094A1 (en) * 1999-08-10 2001-02-15 Engelhard Corporation Recovery of precious metal
WO2001051415A1 (en) * 2000-01-14 2001-07-19 Krupp Uhde Gmbh Removal of laughing gas in nitric acid production
WO2001087771A1 (en) * 2000-05-15 2001-11-22 W.C. Heraeus Gmbh & Co. Kg Method and device for the reduction of nitrogen protoxide
WO2003011448A1 (en) * 2001-07-27 2003-02-13 Johnson Matthey Plc Catalyst or sorbent beds

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2145935C1 (en) * 1999-08-11 2000-02-27 Институт катализа им.Г.К.Борескова СО РАН Method of ammonia conversion

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4774069A (en) * 1985-06-28 1988-09-27 Johnson Matthey Public Limited Company Process for the manufacture of nitric oxide
EP0611041A1 (en) * 1993-02-09 1994-08-17 Johnson Matthey Public Limited Company Catchment device for platinum recovery
US5478549A (en) * 1994-12-15 1995-12-26 E. I. Du Pont De Nemours And Company Production of nitric oxide
WO1998028073A1 (en) * 1996-12-20 1998-07-02 Imperial Chemical Industries Plc Ammonia oxidation catalyst
EP0946290A1 (en) * 1996-12-20 1999-10-06 Imperial Chemical Industries Plc Ammonia oxidation catalyst
WO1999007638A1 (en) * 1997-08-12 1999-02-18 L. & C. Steinmüller Gmbh Method for producing nitric acid and device for carrying out said method
WO1999055621A1 (en) * 1998-04-27 1999-11-04 Basf Aktiengesellschaft Method for the catalytic decomposition of n2o
WO1999064352A1 (en) * 1998-06-09 1999-12-16 Imperial Chemical Industries Plc Catalytic process for the oxidation of ammonia and catalyst assembly
WO2000013789A1 (en) * 1998-09-09 2000-03-16 Porzellanwerk Kloster Veilsdorf Gmbh Ceramic catalyst for selectively decomposing n2o and a method for the production thereof
WO2001011094A1 (en) * 1999-08-10 2001-02-15 Engelhard Corporation Recovery of precious metal
WO2001051415A1 (en) * 2000-01-14 2001-07-19 Krupp Uhde Gmbh Removal of laughing gas in nitric acid production
WO2001087771A1 (en) * 2000-05-15 2001-11-22 W.C. Heraeus Gmbh & Co. Kg Method and device for the reduction of nitrogen protoxide
WO2003011448A1 (en) * 2001-07-27 2003-02-13 Johnson Matthey Plc Catalyst or sorbent beds

Also Published As

Publication number Publication date
CO5660283A2 (en) 2006-07-31
EP1633677A2 (en) 2006-03-15
TW200513435A (en) 2005-04-16
TW200502162A (en) 2005-01-16
NO20054967L (en) 2005-11-23
IL171472A (en) 2011-01-31
CN100363252C (en) 2008-01-23
CN1780789A (en) 2006-05-31
WO2004096703A8 (en) 2005-03-17
BRPI0409944A (en) 2006-04-25
NO20054967D0 (en) 2005-10-26
TWI346087B (en) 2011-08-01
ZA200508783B (en) 2006-07-26
ZA200508788B (en) 2006-08-30
KR20060017503A (en) 2006-02-23
JP2006525216A (en) 2006-11-09
GB0315643D0 (en) 2003-08-13
WO2004096703A2 (en) 2004-11-11

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