WO2004074296A3 - Phosphazeniumsalz-mischungen enthaltend hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium und polyaminophospazenium-salze - Google Patents

Phosphazeniumsalz-mischungen enthaltend hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium und polyaminophospazenium-salze Download PDF

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Publication number
WO2004074296A3
WO2004074296A3 PCT/EP2004/001253 EP2004001253W WO2004074296A3 WO 2004074296 A3 WO2004074296 A3 WO 2004074296A3 EP 2004001253 W EP2004001253 W EP 2004001253W WO 2004074296 A3 WO2004074296 A3 WO 2004074296A3
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WIPO (PCT)
Prior art keywords
carbon atoms
amino
independent
formula
represent
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PCT/EP2004/001253
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English (en)
French (fr)
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WO2004074296A2 (de
Inventor
Thomas Wessel
Daniel Decker
Thomas Sommer
Hagen Huenig
Reinhard Schwesinger
Original Assignee
Clariant Gmbh
Thomas Wessel
Daniel Decker
Thomas Sommer
Hagen Huenig
Reinhard Schwesinger
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Clariant Gmbh, Thomas Wessel, Daniel Decker, Thomas Sommer, Hagen Huenig, Reinhard Schwesinger filed Critical Clariant Gmbh
Priority to EP04709990A priority Critical patent/EP1597220A2/de
Priority to JP2006501803A priority patent/JP2006518273A/ja
Priority to US10/546,502 priority patent/US20060241300A1/en
Publication of WO2004074296A2 publication Critical patent/WO2004074296A2/de
Publication of WO2004074296A3 publication Critical patent/WO2004074296A3/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0264—Phosphorus acid amides
    • B01J31/0265—Phosphazenes, oligomers thereof or the corresponding phosphazenium salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/208—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being MX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mischungen enthaltend 5 bis 99,5 Gew.-% einer Verbindung der Formel (I), 95 bis 0,5 Gew.-% einer Verbindung der Formel (II) und höchstens 10 Gew.-% einer oder mehrerer Verbindungen der allgemeinen Formel (III a), worin A1 bis A32 unabhängig voneinander, gleich oder verschieden sind und für ein geradkettiges oder verzweigtes Alkyl oder Alkenyl mit 1 bis 12 Kohlenstoffatomen, Cycloalkyl mit 4 bis 8 Kohlenstoffatomen, ein Aryl mit 6 bis 12 Kohlenstoffatomen, ein Aralkyl mit 7 bis 12 Kohlenstoffatomen stehen, oder A1-A2, A3-A4, A5-A6 usw. bis A31-A32 unabhängig voneinander, gleich oder verschieden sind und direkt oder über O oder N-A33 miteinander zu einem Ring mit 3 bis 7 Ringgliedern verbunden sind, A33 für ein Alkyl mit 1 bis 4 Kohlenstoffatomen steht, wobei X1 und/oder X2 und/oder X3 unabhängig voneinander Reste der Formel (III b), oder die Reste X1 und/oder X2 und/oder X3 ebenfalls für ein geradkettiges oder verzweigtes Alkyl oder Alkenyl mit 1 bis 12 Kohlenstoffatomen, Cycloalkyl mit 4 bis 8 Kohlenstoffatomen, für ein Aryl mit 6 bis 12 Kohlenstoffatomen, ein Aralkyl mit 7 bis 12 Kohlenstoffatomen stehen, oder jeweils die Reste, die sich an einem identisch gebundenen Stickstoffatomen befinden, z.B. A1 und A2, A3 und A4, A5 und A6 usw. bis A31 und A32 unabhängig voneinander, gleich oder verschieden sind und direkt oder über O oder N-A33 miteinander zu einem Ring mit 3 bis 7 Ringgliedern verbunden sind und A33 für ein Alkyl mit 1 bis 4 Kohlenstoffatomen steht und B- für einen einwertigen organischen oder anorganischen Säurerest oder das Äquivalent eines mehrwertigen Säurerests steht. Die Mischungen eignen sich als Katalysatoren und Co-Katalysatoren für Phasentransferreaktionen, nucleophile Substitutionsreaktionen oder Halogen-Fluor-Austauschreaktionen.
PCT/EP2004/001253 2003-02-21 2004-02-11 Phosphazeniumsalz-mischungen enthaltend hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium und polyaminophospazenium-salze WO2004074296A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP04709990A EP1597220A2 (de) 2003-02-21 2004-02-11 Phosphazeniumsalz-mischungen enthaltend hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium und polyaminophospazenium-salze
JP2006501803A JP2006518273A (ja) 2003-02-21 2004-02-11 ヘキサキス（アミノ）ジホスファゼニウム、テトラキス（アミノ）−ホスホニウムおよびポリアミノホスファゼニウム塩を含むホスファゼニウム塩混合物
US10/546,502 US20060241300A1 (en) 2003-02-21 2004-02-11 Phosphazenium salt mixtures containing hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium and polyaminophosphazenium salts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10307558.5 2003-02-21
DE10307558A DE10307558A1 (de) 2003-02-21 2003-02-21 Phosphazeniumsalz-Mischungen enthaltend Hexakis(amino)diphosphazenium Tetrakis(amino)-phosphonium und Polyaminophosphazenium-Salze

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WO2004074296A2 WO2004074296A2 (de) 2004-09-02
WO2004074296A3 true WO2004074296A3 (de) 2005-03-03

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PCT/EP2004/001253 WO2004074296A2 (de) 2003-02-21 2004-02-11 Phosphazeniumsalz-mischungen enthaltend hexakis(amino)diphosphazenium, tetrakis(amino)-phosphonium und polyaminophospazenium-salze

Country Status (5)

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US (1) US20060241300A1 (de)
EP (1) EP1597220A2 (de)
JP (1) JP2006518273A (de)
DE (1) DE10307558A1 (de)
WO (1) WO2004074296A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060069291A1 (en) * 2004-09-24 2006-03-30 General Electric Company Phosphazenium salt phase transfer catalysts
HUE039602T2 (hu) 2014-02-18 2019-01-28 Covestro Deutschland Ag Eljárás izocianátok módosítására N-P-N-szekvenciájú katalizátorok alkalmazásával

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998032532A1 (de) * 1997-01-23 1998-07-30 Aventis Research & Technologies Gmbh & Co Kg Amidophosphoniumsalz enthaltender katalysator für halex-reaktionen
EP1070724A1 (de) * 1999-07-23 2001-01-24 Clariant GmbH Tetrakis(pyrrolidino/piperidino)phosphoniumsalze enthaltende Mischungen
EP1070723A1 (de) * 1999-07-23 2001-01-24 Clariant GmbH Aminophosphoniumverbindungen
EP1266904A1 (de) * 2001-06-15 2002-12-18 Bayer Ag Verbessertes Verfahren zur Herstellung kernfluorierter Aromaten
EP1275630A1 (de) * 2000-04-20 2003-01-15 Mitsui Chemicals, Inc. Verfahren zur herstellung substituierter aromatischer verbindungen

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US5824827A (en) * 1996-11-22 1998-10-20 Albemarle Corporation Halogen exchange reactions
US6322502B1 (en) * 1996-12-30 2001-11-27 Imd Soft Ltd. Medical information system
WO1999047598A1 (en) * 1998-03-16 1999-09-23 The Dow Chemical Company Polyolefin nanocomposites
JP3370972B2 (ja) * 2000-06-20 2003-01-27 川崎重工業株式会社 流動層セメントクリンカ焼成装置における気密排出装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998032532A1 (de) * 1997-01-23 1998-07-30 Aventis Research & Technologies Gmbh & Co Kg Amidophosphoniumsalz enthaltender katalysator für halex-reaktionen
EP1070724A1 (de) * 1999-07-23 2001-01-24 Clariant GmbH Tetrakis(pyrrolidino/piperidino)phosphoniumsalze enthaltende Mischungen
EP1070723A1 (de) * 1999-07-23 2001-01-24 Clariant GmbH Aminophosphoniumverbindungen
EP1275630A1 (de) * 2000-04-20 2003-01-15 Mitsui Chemicals, Inc. Verfahren zur herstellung substituierter aromatischer verbindungen
EP1266904A1 (de) * 2001-06-15 2002-12-18 Bayer Ag Verbessertes Verfahren zur Herstellung kernfluorierter Aromaten

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SCHWESINGER R ET AL: "EXTREMELY STRONG, UNCHARGED AUXILIARY BASES; MONOMERIC AND POLYMER-SUPPORTED POLYAMINOPHOSPHAZENES (P2-P5)", LIEBIGS ANNALEN: ORGANIC AND BIOORGANIC CHEMISTRY, VCH PUBLISHERS, US, 1996, pages 1055 - 1081, XP000910164, ISSN: 0947-3440 *
SCHWESINGER, REINHARD ET AL: "Stable phosphazenium ions in the synthesis - easily obtainable extremely reactive naked fluoride salt", ANGEW. CHEM., INT. ED. ENGL., ISSN 0570-0833, vol. 30, no. 10, 1991, pages 1372 - 1375, XP002312715 *

Also Published As

Publication number Publication date
US20060241300A1 (en) 2006-10-26
EP1597220A2 (de) 2005-11-23
WO2004074296A2 (de) 2004-09-02
JP2006518273A (ja) 2006-08-10
DE10307558A1 (de) 2004-09-02

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