WO2004060587A1 - Method and apparatus for processing solid organic waste - Google Patents

Method and apparatus for processing solid organic waste Download PDF

Info

Publication number
WO2004060587A1
WO2004060587A1 PCT/GB2003/005687 GB0305687W WO2004060587A1 WO 2004060587 A1 WO2004060587 A1 WO 2004060587A1 GB 0305687 W GB0305687 W GB 0305687W WO 2004060587 A1 WO2004060587 A1 WO 2004060587A1
Authority
WO
WIPO (PCT)
Prior art keywords
waste
solid organic
organic waste
weight
treated
Prior art date
Application number
PCT/GB2003/005687
Other languages
French (fr)
Inventor
Peter Hood
Original Assignee
International Waste Industries Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Waste Industries Limited filed Critical International Waste Industries Limited
Priority to AU2003295162A priority Critical patent/AU2003295162A1/en
Priority to PCT/GB2004/003157 priority patent/WO2005063946A1/en
Publication of WO2004060587A1 publication Critical patent/WO2004060587A1/en
Priority to GB0605977A priority patent/GB2431155B/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/40Treatment of liquids or slurries
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/303Burning pyrogases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • F23G2206/203Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/50208Biologic treatment before burning, e.g. biogas generation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Definitions

  • the present invention relates to methods and apparatus for processing solid organic waste, for example municipal waste or agricultural waste.
  • the waste may be processed to provide fuel or a multi purpose pure organic compost.
  • a drying step has been required to reduce the moisture level to below 30% by weight. Once the moisture level has been reduced to this level, further bacterial activity ceases so that the product becomes stable and can be stored.
  • the drying step has typically required heated or forced draught-drying apparatus which has been expensive to run.
  • the present inventor has set out to overcome the problems of the prior art.
  • the present inventor has particularly sought to provide a method of processing organic waste in which an expensive drying apparatus is not required.
  • the inventor has further set out to provide a process and apparatus for processing municipal waste which has a very variable moisture level and physical composition, so that a relatively homogeneous product can be produced.
  • an alternative method of thermal decomposition of waste involves a pyrolysis step, in which the waste material is heated to a temperature of about 800°C, whereby a mixture of combustible gases is produced and the solid material is reduced to a largely carbonaceous char.
  • the char can be subsequently gasified either insitu or in a separate step, for example using steam, to generate further combustible gases.
  • the combustible gases from the pyrolysis and gasification process can be burnt at high temperature under controlled conditions for production of heat. This heat can be used to provide power and to run the process.
  • the present inventor has discovered that solid organic waste can be treated by anaerobic digestion whilst being agitated, to provide a good quality raw material which is suitable for subsequent processing to provide a fuel or compost product and which has an average moisture level not exceeding 45% by weight and preferably not exceeding 35% by weight. Subsequent drying of this material to an average moisture content of below 30% by weight can be carried out relatively easily. It is found that both the calorific value and the nutrient content of waste treated in this way remains high so that it is suitable as a replacement fuel or compost.
  • the present invention provides a method of treating solid organic waste, comprising treating the waste by anaerobic digestion, the solid waste being agitated during digestion, the waste having an average moisture level after treatment not exceeding 45% by weight and preferably not exceeding 35% by weight.
  • the inventor has also discovered that the input of solid organic waste can be controlled so that a relatively homogeneous product with a moisture level not exceeding 45% by weight, and preferably not exceeding 35% by weight, can be obtained.
  • the present invention also provides an apparatus for treating solid organic waste, comprising an anaerobic digestion vessel, means for agitating the solid organic waste in the vessel, and drying means following the digestion vessel and means for controlling the input of solid organic waste to the vessel so that moisture level of waste after treatment does not exceed 45% by weight and preferably does not exceed 35% by weight.
  • the input of waste is controlled by mixing solid orgamc waste with a controlled amount of other waste, for example commercial waste, which has a moisture level not exceeding 30% by weight.
  • other waste for example commercial waste, which has a moisture level not exceeding 30% by weight.
  • variations in the physical composition (for example calorific content) and moisture level of the solid organic waste can be smoothed out, so that a product formed from treated waste from different areas or different time periods can be relatively homogeneous.
  • homogeneity is required in parameters such as ash content, calorific value, moisture level and density.
  • homogeneity in parameters such as moisture level, density and nutrient content is required.
  • 'digestion' is used herein to indicate the bacterial breakdown of at least some of the organic matter to produce heat. This breakdown is accompanied by changes in the physical nature of the waste.
  • the substantially anaerobic digestion process should be carried out using the thermophyllic phase, which normally occurs in the temperature range 60°C - 75°C, most preferably around 63°C - 70°C. In this phase, very rapid digestion occurs with the production of heat. It is found that the reaction in the thermophyllic phase is much quicker than the commonly used mesophyllic phase which occurs in the range 30°C - 38°C. Accordingly, rapid treatment of the waste can take place. However, if the temperature rises above 75°C, there is a danger that the bacteria will be destroyed.
  • thermophyllic phase results in the natural generation of heat which breaks down the solid organic waste to produce a material which is suitable for processing to provide a fuel or compost.
  • the reaction will almost always provide sufficient heat to maintain itself without provision of supplementary heat.
  • the material may be placed in a sealed container with no supply of additional air during the reaction.
  • the waste should be agitated while it is being digested. Agitation may take place by any suitable means, but it is particularly preferred that the digestion takes place in a rotating anaerobic drum.
  • the drum may be rotated at any suitable rate, and suitably completes one revolution in a time range of 1 minute to 10 minutes, preferably 2-5 minutes, most preferably about 3 minutes.
  • the drum preferably comprises a substantially parallel sided circular section cylinder.
  • the axis of the cylinder may be inclined to the horizontal, for example at an angle in the range 3° - 10° most preferably 5° - 8°, to provide gravitational flow through the drum.
  • drum Any suitable size of drum may be provided, depending upon the rate of consumption of organic waste. It has been found that, for a processing rate of about 250-500 tonnes per day, a drum of diameter in the range 3.5 - 8m, preferably 4-6m most preferably around 5.5m should be used. The length should be in the range from 4 to 8 times the diameter, most preferably about 6 times the diameter.
  • the drum may be used of any suitable material, for example steel.
  • a rotary digester has the advantage that it is mechanically simple. There are relatively few problems of blocking and very few moving parts, which reduces the risk of breakdown.
  • the drum is substantially completely filled with waste, being preferably at least 75% full by volume. This leads to increased attrition, rapid heat generation and also to efficient use of plant .
  • Residence time in the anaerobic digestion process is suitably in the range 18-60 hours, more preferably around 24 to 48 hours, most preferably around 36 hours
  • the gas space over the material will accordingly increase.
  • the gas space will comprise air and carbon dioxide, and is saturated with water vapour.
  • Aerobic digestion does also occur at a low level in early stages in the process.
  • the rate of aerobic digestion increases at later stages in the process when the material is less dense and less moist.
  • the waste material should be discharged from the anaerobic digester at a stage at which the treated waste material is sufficiently digested and sufficiently dry. This typically occurs after a period of about 48 hours. By restricting residence time to 48 hours or less, additional loss of carbon can be reduced.
  • some parameters of the solid organic waste fed to the digestion step are preferably controlled.
  • the solid organic waste is preferably treated in a first process before anaerobic digestion to remove particles of size in excess of 60mm, more preferably 50mm.
  • This process may comprise a first step in which very large objects are removed, for example by hand and a second step in which the remaining material is treated to reduce its particle size, for example by shredding.
  • the person skilled in the art will be able to obtain suitable shredding apparatus.
  • the second parameter which may be controlled is the moisture content of at least some of the organic solid waste fed to the anaerobic digestion step.
  • the moisture level of this part of the waste is suitably in the range 40-75%, more preferably 60-70%, most preferably around 60% by weight.
  • Waste having a moisture level in the range 50-80%, preferably in the range 65%-75% by weight can also be used All moisture levels quoted herein are % by weight. They are average values, being averaged for quantities of at least 100kg of waste.
  • Moisture levels of solid waste may be measured by measuring the moisture level of air or gas over the waste at a fixed temperature and in equilibrium with it.
  • waste having a moisture level in the range in the range 40-75 %by weight may be mixed with waste having a lower moisture level, but it has been found that the anaerobic digestion process will proceed effectively, if sufficient waste having the higher moisture level is present. It has been found to be acceptable if the average moisture level of all waste fed in to the digestion step is in the range 50-60% by weight and preferably 53-57% by weight.
  • process water is preferably added.
  • This process water is preferably waste water from water treatment, most preferably dewatered sewage sludge. This material has a high nitrogen content and acts as a catalyst for the anaerobic reaction.
  • control of the moisture level can be obtained by blending solid organic waste with other waste of a lower average moisture level. It is found that domestic waste typically has a moisture level in excess of 60% by weight. Agricultural waste may have a moisture level in excess of 75% by weight and sometimes 80% by weight, particularly in tropical or sub-tropical countries for crops such as bananas and pineapples. Finally, commercial waste from offices and factories is typically much drier, having a moisture level in the range 20% - 30% by weight.
  • the moisture level of waste fed to the digester may be manipulated by altering the mixing ratios of different types of waste. It is required that at least part of the waste fed to the digester has a moisture level in the range 50% - 80% by weight, preferably 50- 75% by weight in order to promote the faster thermophyllic reaction. However, part of the waste fed to the digester may comprise a relatively dry commercial waste. The heat generated by the digestion of the moist waste is sufficient to treat the whole of the waste fed to the digester. However, during the agitation process, the commercial and domestic waste are slowly mixed together reducing the overall moisture content of the mixture, so that at the end of the processing, the moisture level does not exceed 45 % by weight and preferably does not exceed 35% by weight.
  • Solid waste with higher moisture level may be blended with solid waste with lower moisture level in blending apparatus in a controlled manner.
  • the relative quantities of different types of waste can be controlled so that the desired average moisture level is obtained as explained above.
  • the blending step also allows absorbent material such as paper and paper based material (which is particularly common in commercial waste) to be blended intimately with the moist waste (such as domestic waste).
  • absorbent material such as paper and paper based material (which is particularly common in commercial waste) to be blended intimately with the moist waste (such as domestic waste).
  • the absorbent material absorbs liquid rich in bacteria, providing a substrate for the bacteria to grow on and allowing the bacteria to be spread throughout the waste being processed. This promotes reaction and mixing, leading to an improved digestion. Further, the wetting of the paper helps it to be broken down.
  • the relative quantities of different types of waste fed can be controlled using automatic weigh feeders.
  • a further parameter which may be manipulated is the pH of the organic waste. This is suitably in the range 6.0-8.5, preferably 6.3-7.3, most preferably around 6.8..
  • the density of the organic waste fed to the anaerobic digestion process is suitably not too low.
  • the density is not less than 45 Og per litre, preferably not less than 750g per litre.
  • the blending step is particularly useful here.
  • Domestic waste can have a relatively high density.
  • the average density can be controlled by admixing a suitable quantity of commercial waste, which has a comparatively low density.
  • the solid organic waste may be subjected to various types of treatment before the anaerobic digestion process.
  • the previous steps include any or all of the following:
  • the process can be carried out on a stationary surface, such as a picking floor.
  • the solid organic waste may be loaded onto a moving surface such as a conveyor and passed through a picking station in which mechanical or manual picking of the material takes place.
  • the organic solid waste may be mechanically screened to select particles with size in a given range.
  • the given range may be from 10mm to 50mm. Material less than 10mm in size comprises dust, dirt and stones and is rejected.
  • the solid organic waste may be treated to at least two screening processes in succession, each removing progressively smaller fractions of particles. Material removed in the screening process as being too large may be shredded to reduce its average size. Material which is classified by the screen as being of acceptable size and, where applicable, shredded material can then be fed to the anaerobic digestion step.
  • Blending Domestic and commercial waste may be blended in a blending mixer before being fed to the anaerobic digestion process. This is particularly important step. Where least domestic waste and commercial waste are received for treatment, they are preferably processed separately. It is found that commercial waste can be treated before the anaerobic digestion process in a picking stage to remove oversized objects followed by a shredding stage only. By keeping the different types of waste separate, accurate control of quality of solid waste fed to the anaerobic digestion step can be obtained.
  • the treated material may be subjected to a number of steps after the anaerobic digestion process. These steps may include any of the following:
  • the material may be screened to remove particles in excess of a given size. For example, particles in excess of 50mm may be rejected. They may be subsequently shredded to reduce their size, returned to the anaerobic digester or simply rejected.
  • Relatively small metal particles such as iron or aluminium may have passed through the system. They can be removed, for example by a magnetic or electromagnetic remover in a subsequent step. Metal particles removed f om the system may then pass to a suitable recycling process.
  • the material is subjected to a drying step.
  • the moisture level does not exceed 45% by weight, preferably not exceeding 35% by weight, after the digestion step, the subsequent drying can be carried out relatively simply.
  • a forced draught of air may be provided during or after the unloading phase from the anaerobic digestion process.
  • the treated material will still be at high temperature (for example in the range 50-60°C) and a lot of moisture can be removed simply by forcing air over it.
  • a further drying step may comprise laying the material out on a drying floor. In this step, material is laid out at a thickness of not more than 20cm over a relatively large area for a suitable period of time, during which the moisture level drops.
  • the material may be agitated, for example by turning using mechanical or manual apparatus such as a power shovel.
  • the material may be turned at intervals of for example of 2-4 hours preferably around 3 hours.
  • the moisture level drops to below 30% by weight after which no further biological decomposition occurs.
  • the material is left on a drying floor for a period in the range 18-48 hours, preferably 24- 36 hours, more preferably around 24 hours.
  • Waste heat from other process equipment may be used to dry the material.
  • the material In order to convert the treated material to fuel, the material may be classified according to size and subsequently densified to provide pellets of suitable size which can be subsequently stored or packed for use. During this stage, further drying of the material may occur, due to heat generation caused by friction and due to further exposure to air.
  • the moisture level of the treated material is in the range 33-38% by weight.
  • the material is to be converted into compost, it can simply be bagged after treatment.
  • the moisture level of solid, organic waste during processing may be as follows. Domestic waste with a high organic content and moisture level above 60% can be mixed with commercial waste having a moisture level of 20% or below in a suitable ratio to provides a blend having an average moisture level in the range 50-60%) by weight.
  • the average moisture level may drop to around 45-50% by weight, preferably 35-40% by weight.
  • the waste which still has a high residual heat level may be dried by a forced draught as described above, so that the moisture level drops to the range 40-45% by weight, preferably 35-40% by weight.
  • the waste may then be further dried on a drying floor as described above, so that the moisture level drops to below 30% by weight.
  • the method and apparatus of the invention can be used to produce a product which is suitable for subsequent storage, transportation or sale.
  • the method of the invention can provide a fuel, referred to as Green Coal, which has a calorific value in the order of 3500 Kcals/g which is about half that of industrial coal.
  • the material has an ash content of less than 20% by weight and has the additional advantage that it will contain relatively low levels of sulphur and chlorine, so reducing pollution due to acid rain from gases of combustion.
  • fuel produced at different times or with waste from different locations can be relatively homogeneous in terms of: 1.
  • Calorific value - suitably in the range 3000-4000 Kcal/g,
  • Density - suitably in the range 270-350g/l more preferably around 300g/l
  • This fuel can be used either on its own or as a supplementary fuel.
  • the material can be used as a multi purpose organic compost having a relatively high nutrient content.
  • the apparatus and method of the invention may alternatively form a part of a plant or system.
  • the apparatus and method of the invention can be used to supply fuel in a plant or system.
  • the material may be fed directly to a combustion chamber for generating heat or power.
  • the apparatus and method of the invention can be used to supply a feed to a pyrolysis process, as described below.
  • the treated material may be fed directly from the digestion vessel to the plant or system or it may be treated by any suitable steps such as grading, metal separation, drying, palletising or bagging as appropriate.
  • an electrical power supply system comprising apparatus according to the invention for feeding material to the combustion chamber of a boiler for providing steam for power plant.
  • a cement producing apparatus comprising a cement kiln and an apparatus according to the invention for supplying fuel to the cement kiln.
  • the present invention provides a method of treating solid organic waste, comprising treating the waste by bacteriological digestion and subsequently subjecting the waste to heating at a temperature which is sufficiently high to substantially pyrolyse the digested waste anaerobically.
  • the pyrolysed material may be used as a fuel in its own right. However, in a preferred embodiment, the pyrolysed material may be fed to a gasification process in which combustible gases are produced by introduction of a gasifying agent. This will normally require the pyrolysed material to be at a high temperature and the gasification process preferably occurs directly after the pyrolysis process.
  • the pyrolysis process and gasification process may be carried out in separate zones, for example as described in WO97/15641 and WO97/15640, or in a common zone, for example as shown in GB2301659.
  • the gasifying agent comprises air, steam or water vapour.
  • Suitable apparatus may also be obtained from Metso Corporation, or from the Allis Chalmers Corporation.
  • the bacteriological digestion may be aerobic or anaerobic. Preferably, it is anaerobic
  • thermopyhilic phase which normally occurs in the temperature range 60°C - 75°C as described above in relation to the first aspect of the invention.
  • the digestion takes place in a sealed container, for example a rotating drum. Preferred aspects of the drum are as set out above for the first aspect of the invention.
  • the solid organic waste is digested in a manner which allows its moisture level to be controlled.
  • the solid organic waste is digested by a method according to the first aspect of the invention.
  • an apparatus according to the first aspect of the invention is used.
  • the preferred features of the first aspect of the invention described above apply to the second aspect of the invention.
  • the treated material from the anaerobic digestion process is suitably fed directly to the apparatus for pyrolysis.
  • Any suitable feed means may be used for delivering the treated waste from the anaerobic digestion process to the pyrolysis apparatus.
  • an interim storage means for example in the form of a feed hopper may be provided. It is preferred that there is a first delivery means for receiving treated organic waste from the anaerobic digestion process and feeding it into the interim storage means and a second feed apparatus for feeding the stored treated solid waste from the interim storage means to the pyrolysis apparatus.
  • the second feed means is preferably operated substantially continuously.
  • the first and second feed apparatus may comprise any suitable means, for example conveyor belts or screw feeders.
  • Figure 1 is a schematic process diagram of steps involved in the process of the present invention before the rotary anaerobic digester.
  • Figure 2 is a schematic process diagram showing the steps involved in feeding the rotary anaerobic digester and drying the material.
  • Figure 3 is a schematic process diagram showing further steps in the procedure.
  • Figure 4 is a schematic process diagram showing a further embodiment of the present invention.
  • Figure 1 shows the steps involved in an embodiment of a process according to the first aspect of the present invention for manufacturing fuel from solid organic waste.
  • two sources of waste 101 and 102 are identified.
  • Source 101 comprises a source of domestic waste, which typically has an average moisture in the range 35-60% by weight.
  • Source 102 comprises a source of commercial waste which may have moisture averaging around 20% by weight.
  • waste from the sources 101 102 is delivered to a reception and picking floor.
  • waste supplies from the two sources 101 and 102 are kept separate.
  • waste is manually picked over to identify objects which are not suitable for further processing, for example, metal, large plastic objects, etc.
  • the rejected objects are collected at 104 and disposed of separately, for example by tipping or by recycling if appropriate.
  • the dotted line in step 103 indicates separation of the solid waste from the two sources.
  • domestic waste which has been manually picked over is then fed at 105 onto a feed conveyor 106 using a loading hopper arrangement. Further manual sorting of the solid waste can take place whilst the waste is on the feed conveyor 106 for example by personnel standing on both sides of the conveyor.
  • the rejected waste can be disposed of in step 104 as described above.
  • the feed conveyor 106 feeds the sorted waste to a rotary screen separator apparatus 107.
  • a first rotary screen separator 108 particles of size less than 50mm are passed and allowed to fall onto a conveyor 109 for subsequent feeding to the rotary anaerobic digester as will be described further below in figure 2.
  • Material screened out by the rotary screen separator 108 is then screened in a further rotary screen separator 109 which passes objects of size less than 100mm. Objects of size less than 100mm are then fed to a domestic waste shredder 110 which reduces their size to below 50mm and greater than 10mm. Thereafter, the shredded waste is passed onto to the conveyor 109.
  • Objects of size greater than 100mm are fed onto an "oversize conveyor 112" for further processing.
  • the waste products on the conveyor 109 which will comprise unmixed domestic and commercial waste are blended together in a blender 115. Further, paper and paper based material in the commercial waste absorbs moisture in the domestic waste which is rich in bacteria, thus spreading the bacteria throughout the material and providing a substrate to promote bacterial action.
  • the blended waste is fed from the mixer 115 intermittently to the anaerobic digester 116.
  • the anaerobic digester comprises a cylindrical steel vessel of diameter 5.5mm and length 33m which is mounted with its axis at an angle of approximately 7° degrees to the horizontal with waste being fed in at the loading end 117. Waste is fed into the loading 117 end at intervals of approximately 24 hours, and is simultaneously discharged . Except when loading and unloading, the rotary anaerobic digester is sealed to prevent access of air so that conditions may remain substantially anaerobic inside the anaerobic digester.
  • the digester is normally rotated at a rate of approximately one revolution every 3 minutes.
  • the rate of rotation is increased to 1 rpm to help feed material down the digester.
  • the waste inside the rotary anaerobic digester is gently agitated.
  • the digester is mounted at an angle to the horizontal, the waste slowly feeds downwards from the loading end 117 to the unloading end 118.
  • a mixture of domestic and commercial waste which has been pre-treated is fed from the mixer 115 into the loading end 117 of the rotary anaerobic digester.
  • the average moisture level of the solid waste fed into the loading end 117 of the rotary anaerobic digester 116 can be controlled.
  • the temperature inside the rotary anaerobic digester is maintained at a temperature in the range 65-75°C, most preferably around 68-70°C.
  • auxiliary heating means this is not normally required, as the moist solid waste fed into the digester undergoes a thermophyllic anaerobic reaction which leads to the generation of sufficient heat to maintain the temperature at the desired level.
  • the screening and shredding apparatus can be used to ensure that the waste fed into the rotary anaerobic digester does not have a particle size greater than 50mm. Further, by controlling the relative quantities of commercial and domestic waste fed into the rotary anaerobic digester using the blending system, the overall moisture level of at least part of the load can be maintained at the high level leading to a high rate of reaction. Further whilst the waste is on the conveyor or picking floor, it can be tested to ensure that its pH is the correct range and suitable additives can be added to correct the pH in a manner known to the person skilled in the art if necessary. Further, the shredders can be operated to ensure that the density of the waste material does not fall below 750gm per litre. It has been found that if the solid waste fed into the rotary anaerobic digester meets the following parameters, a high rate of anaerobic digestion can be obtained:
  • moisture content between 50 and 70%, ideally 60% by weight.
  • the rotary anaerobic digester is operated so that waste has residence time of approximately 24 hours inside the digester.
  • digested waste is unloaded at the unload end 118 where it is sieved.
  • Digested waste with a particle size less than 50mm is collected at 119. This material is suitable for formation of fuel pellets as will be described further below.
  • Treated waste with a particle size in excess of 50mm is collected at 120 and rejected.
  • a grid inside the digester, over the final 1 metre length, for passing objects of size less than 50mm is provided, to reject oversize material.
  • step 121 the sieved treated solid waste is treated in a metal separation stage, for separating out metals such as iron and aluminium
  • a metal separation stage for separating out metals such as iron and aluminium
  • electromagnetic or magnetic apparatus can be used to separate various materials which can be collected at 122 for suitable recycling.
  • the treated waste from which metal has been received can be spread on a stockpile / drying floor 123.
  • Treated waste collected at the unloading end 118 has a moisture level of not more than 35%) by weight and preferably not more than 35% by weight.
  • a certain amount of the moisture in the treated solid waste material goes into the gas over the material in the rotary anaerobic digester.
  • a certain amount of the moisture is driven off for example by a forced draught fan at the unloading stage 118 when the anaerobic digester is opened the waste sieved.
  • the moisture level of the treated waste loaded onto the drying floor is typically in the range 30-35% by weight and the material will still be at a temperature in the range 50- 60°C from the drum.
  • the material is fed into a layer not more than 20cm thick, where it is allowed to dry by natural evaporative drying and mechanical turning. As a result, the moisture level drops to a level of less than 30% by weight. At this stage, further bacterial decomposition of the material ceases and the product becomes stable and storable.
  • a process according to figures 1-3 was operated with a feed a comprising 75000 tons per annum of mixed municipal waste.
  • the average moisture level of waste input to the rotary anaerobic digester was 60% by weight, with some batches having higher moisture level and some batches having lower moisture level.
  • Treated waste collected from the rotary anaerobic digester, after unloading and fan drying had a moisture level of about 35% by weight.
  • GREEN COAL From an input of 75,000 tonnes of combined waste materials, 50,000 tonnes of GREEN COAL can be produced, having a calorific value equivalent to 25,000 tonnes of fuel oil.
  • the graded and pelletised product was found to have constant thermal characteristics and to be suitable for use as a supplementary fuel, going by the description of GREEN COAL. It had a minimum calorific value of 3500Kcals/g. It had an ash content of less than 20% by weight and very small quantities of sulphur and chlorine.
  • Figure 4 shows a schematic process diagram of a second embodiment of the present invention.
  • the embodiment of Figure 4 will employ the system as shown in Figure 1 for the pre- treatment of solid waste material and digestion in a rotary anaerobic digester 116 as shown in Figure 2.
  • the embodiment of Figure 4 is different to that of Figures 2 and 3 in that a different system is employed downstream of the anaerobic digester.
  • the treated material is fed into a gravity hopper 118 for storage of material.
  • the stored material is fed from the gravity hopper 134 by a screw feeder 135 into a pyrolysis chamber 136 in which the solid waste material is transported by a screw while being heated to a temperature in excess of 800°C, sufficient to cause pyrolysis of the treated waste material.
  • a mixture of combustible gases is produced at 139.
  • the solid material is reduced to a char, largely comprising carbon and ash.
  • the char may, in some embodiments, be used as a fuel. However in the process shown in Figure 4, the char is fed into a gasification chamber 138, where it is maintained at a temperature in excess of 800°C and treated with steam so that a mixture of carbon monoxide and hydrogen are generated at 140. As a result, the char is converted to a non-combustible ash 141 which is subsequently disposed of, suitably by landfill.
  • the combustible gases from the pyrolysis chamber 139 and the producer gas 140 from the gasification chamber 138 are burnt at high temperature in a combustion chamber 142. As a result, exhaust gas is produced.
  • the exhaust gas has a very low content of pollutants in particular, NO x gases, because of the combustion conditions.
  • the combustion of the gases 139 and 140 is used to produce steam, some of which is fed at 144 into the gasification chamber and the remainder of which is fed at 143 into a steam turbine power plant 145 for the generation of electricity.
  • Electricity from the power plant can be distributed at 146 for running the entire apparatus of the embodiment of Figure 4.
  • Power can also be delivered at 147 to consumers, via the National grid for example.
  • the pyrolysis and gasification apparatus is shown schematically only. It is suitably as described for example in WO97/15640 or WO97/15641. Alternatively, the gasification and pyrolysis chambers maybe combined, for example as shown GB2301659.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

In order to provide a method and apparatus for processing solid organic waste to produce a fuel or organic compost, the waste material is treated in a rotary anaerobic digester (116), where it is digested in the thermophyllic phase at a temperature in the range 60 - 75 °C, to produce a treated material having a moisture level not exceeding 45 % by weight and preferably not exceeding 35 % by weight. The treated material can be subsequently dried on a drying floor (123) to provide a stable product. Waste having a high moisture level, such as domestic waste can be blended in a blender (115) with waste having a lower moisture level, such as commercial waste, to provide control of the properties of the waste being treated and of the product obtained. The treated solid organic waste from the anaerobic digester may also be pyrolised and, optionally, subsequently gasified.

Description

METHODS AND APPARATUS FOR PROCESSING SOLID ORGANIC WASTE
The present invention relates to methods and apparatus for processing solid organic waste, for example municipal waste or agricultural waste. The waste may be processed to provide fuel or a multi purpose pure organic compost.
The disposal of municipal and agricultural waste presently provides a major problem. A medium sized city may produce in the region of hundreds of thousands of tonnes of waste a year. Whereas in the past it has been the practice to dump this waste in landfill sites, this is becoming less favoured, as the availability of suitable sites for landfill is decreasing.
At the same time, there is concern over the rate of consumption of fossil fuels. These fuels are not replaceable and in some cases present pollution problems due to a high sulphur content. There is a corresponding interest in finding a source of low pollution fuel which does not deplete fossil fuel stocks.
There is a wide interest in the use of organic material as compost for horticultural purposes. In the past, materials such as coir have been used, which has a relatively low nutrient content. Peat has also been used, but there is now concern that natural peat bogs are being dangerously depleted by this use.
Accordingly, there is an interest in recycling municipal and agricultural waste to produce either a fuel material for replacement of fossil fuels or organic compost for horticultural purposes. A number of processes have been proposed in which agricultural or municipal waste is composted in a specially design apparatus so that it is treated by aerobic digestion. Examples of each process are described for example in GB 1551020 and WO83/02779. Although these can be effective, there is a problem that the aerobic digestion can lead to loss of carbon content and consequently lowering of calorific value of the resulting material. Further processes have been proposed in which waste is subjected in a first step to aerobic digestion and subsequently to anaerobic digestion to improve the quality of the product, for example as in GB2208645. Aerobic digestion has also been found to require long digestion times, sometimes of the order of weeks.
Where an anaerobic digestion process has been used, it has taken place in large static tanks which has given rise to problems of disposal of leachate and a relatively large hold up volume requiring specially constructed tanks.
Further, in all processes in which organic waste is digested aerobically or anaerobically, a drying step has been required to reduce the moisture level to below 30% by weight. Once the moisture level has been reduced to this level, further bacterial activity ceases so that the product becomes stable and can be stored. However, the drying step has typically required heated or forced draught-drying apparatus which has been expensive to run.
The present inventor has set out to overcome the problems of the prior art. The present inventor has particularly sought to provide a method of processing organic waste in which an expensive drying apparatus is not required. The inventor has further set out to provide a process and apparatus for processing municipal waste which has a very variable moisture level and physical composition, so that a relatively homogeneous product can be produced.
An alternative approach to the disposal of waste uses incineration, in which the waste is heated to a very high temperature to oxidise it. However, the plant required for the incineration is complex and expensive. There are problems in the operation of the plant due to the uneven nature of the waste being collected and the high moisture content which is often encountered. There can be problems with generation of pollutants particularly NOx.
For this reason, an alternative method of thermal decomposition of waste involves a pyrolysis step, in which the waste material is heated to a temperature of about 800°C, whereby a mixture of combustible gases is produced and the solid material is reduced to a largely carbonaceous char. The char can be subsequently gasified either insitu or in a separate step, for example using steam, to generate further combustible gases. The combustible gases from the pyrolysis and gasification process can be burnt at high temperature under controlled conditions for production of heat. This heat can be used to provide power and to run the process. Generation of pollutants is effectively controlled because the degradation of the waste occurs at a temperature below that at which NOx gases are produced and the combustion of the gases can be conducted under controlled conditions which reduce the generation of such gases. However, there are problems with the control of such processes where the composition and water content of the waste being processed are not uniform from time to time. A drying step can be used, but this adds complexity.
The present inventor has discovered that solid organic waste can be treated by anaerobic digestion whilst being agitated, to provide a good quality raw material which is suitable for subsequent processing to provide a fuel or compost product and which has an average moisture level not exceeding 45% by weight and preferably not exceeding 35% by weight. Subsequent drying of this material to an average moisture content of below 30% by weight can be carried out relatively easily. It is found that both the calorific value and the nutrient content of waste treated in this way remains high so that it is suitable as a replacement fuel or compost.
Accordingly, in a first aspect, the present invention provides a method of treating solid organic waste, comprising treating the waste by anaerobic digestion, the solid waste being agitated during digestion, the waste having an average moisture level after treatment not exceeding 45% by weight and preferably not exceeding 35% by weight.
The inventor has also discovered that the input of solid organic waste can be controlled so that a relatively homogeneous product with a moisture level not exceeding 45% by weight, and preferably not exceeding 35% by weight, can be obtained.
Accordingly, in a first aspect, the present invention also provides an apparatus for treating solid organic waste, comprising an anaerobic digestion vessel, means for agitating the solid organic waste in the vessel, and drying means following the digestion vessel and means for controlling the input of solid organic waste to the vessel so that moisture level of waste after treatment does not exceed 45% by weight and preferably does not exceed 35% by weight.
In a particularly preferred embodiment, the input of waste is controlled by mixing solid orgamc waste with a controlled amount of other waste, for example commercial waste, which has a moisture level not exceeding 30% by weight. In this way, variations in the physical composition (for example calorific content) and moisture level of the solid organic waste (typically domestic waste, but also possibly agricultural waste) can be smoothed out, so that a product formed from treated waste from different areas or different time periods can be relatively homogeneous. For a fuel, homogeneity is required in parameters such as ash content, calorific value, moisture level and density. For an organic compost, homogeneity in parameters such as moisture level, density and nutrient content is required.
Preferred features of the first aspect of the invention will be described further below.
The term 'digestion' is used herein to indicate the bacterial breakdown of at least some of the organic matter to produce heat. This breakdown is accompanied by changes in the physical nature of the waste.
The substantially anaerobic digestion process should be carried out using the thermophyllic phase, which normally occurs in the temperature range 60°C - 75°C, most preferably around 63°C - 70°C. In this phase, very rapid digestion occurs with the production of heat. It is found that the reaction in the thermophyllic phase is much quicker than the commonly used mesophyllic phase which occurs in the range 30°C - 38°C. Accordingly, rapid treatment of the waste can take place. However, if the temperature rises above 75°C, there is a danger that the bacteria will be destroyed.
The reaction in the thermophyllic phase results in the natural generation of heat which breaks down the solid organic waste to produce a material which is suitable for processing to provide a fuel or compost. The reaction will almost always provide sufficient heat to maintain itself without provision of supplementary heat. In order to allow the anaerobic digestion to take place, the material may be placed in a sealed container with no supply of additional air during the reaction.
According to the first aspect of the invention, the waste should be agitated while it is being digested. Agitation may take place by any suitable means, but it is particularly preferred that the digestion takes place in a rotating anaerobic drum.
The drum may be rotated at any suitable rate, and suitably completes one revolution in a time range of 1 minute to 10 minutes, preferably 2-5 minutes, most preferably about 3 minutes.
The drum preferably comprises a substantially parallel sided circular section cylinder. The axis of the cylinder may be inclined to the horizontal, for example at an angle in the range 3° - 10° most preferably 5° - 8°, to provide gravitational flow through the drum.
Any suitable size of drum may be provided, depending upon the rate of consumption of organic waste. It has been found that, for a processing rate of about 250-500 tonnes per day, a drum of diameter in the range 3.5 - 8m, preferably 4-6m most preferably around 5.5m should be used. The length should be in the range from 4 to 8 times the diameter, most preferably about 6 times the diameter.
The drum may be used of any suitable material, for example steel.
A rotary digester has the advantage that it is mechanically simple. There are relatively few problems of blocking and very few moving parts, which reduces the risk of breakdown.
The agitation caused by the rotation leads to attrition of the solid waste, further contributing to its breakdown. Preferably, the drum is substantially completely filled with waste, being preferably at least 75% full by volume. This leads to increased attrition, rapid heat generation and also to efficient use of plant . Residence time in the anaerobic digestion process is suitably in the range 18-60 hours, more preferably around 24 to 48 hours, most preferably around 36 hours
During processing, it is found that the volume of the material may decrease by as much as 25%. The gas space over the material will accordingly increase. The gas space will comprise air and carbon dioxide, and is saturated with water vapour.
Aerobic digestion does also occur at a low level in early stages in the process. The rate of aerobic digestion increases at later stages in the process when the material is less dense and less moist. The waste material should be discharged from the anaerobic digester at a stage at which the treated waste material is sufficiently digested and sufficiently dry. This typically occurs after a period of about 48 hours. By restricting residence time to 48 hours or less, additional loss of carbon can be reduced.
In order to promote the anaerobic digestion process, some parameters of the solid organic waste fed to the digestion step are preferably controlled.
In the first place, the solid organic waste is preferably treated in a first process before anaerobic digestion to remove particles of size in excess of 60mm, more preferably 50mm. This process may comprise a first step in which very large objects are removed, for example by hand and a second step in which the remaining material is treated to reduce its particle size, for example by shredding. The person skilled in the art will be able to obtain suitable shredding apparatus.
The second parameter which may be controlled is the moisture content of at least some of the organic solid waste fed to the anaerobic digestion step. The moisture level of this part of the waste is suitably in the range 40-75%, more preferably 60-70%, most preferably around 60% by weight. Waste having a moisture level in the range 50-80%, preferably in the range 65%-75% by weight can also be used All moisture levels quoted herein are % by weight. They are average values, being averaged for quantities of at least 100kg of waste. Moisture levels of solid waste may be measured by measuring the moisture level of air or gas over the waste at a fixed temperature and in equilibrium with it. As will be described further below, waste having a moisture level in the range in the range 40-75 %by weight may be mixed with waste having a lower moisture level, but it has been found that the anaerobic digestion process will proceed effectively, if sufficient waste having the higher moisture level is present. It has been found to be acceptable if the average moisture level of all waste fed in to the digestion step is in the range 50-60% by weight and preferably 53-57% by weight.
Alternatively, if the delivered waste is low in organic content so that the moisture level is not sufficient to support anaerobic digestion, process water is preferably added. This process water is preferably waste water from water treatment, most preferably dewatered sewage sludge. This material has a high nitrogen content and acts as a catalyst for the anaerobic reaction.
As mentioned above, it is particularly preferred feature of the first aspect of the present invention that control of the moisture level can be obtained by blending solid organic waste with other waste of a lower average moisture level. It is found that domestic waste typically has a moisture level in excess of 60% by weight. Agricultural waste may have a moisture level in excess of 75% by weight and sometimes 80% by weight, particularly in tropical or sub-tropical countries for crops such as bananas and pineapples. Finally, commercial waste from offices and factories is typically much drier, having a moisture level in the range 20% - 30% by weight.
The moisture level of waste fed to the digester may be manipulated by altering the mixing ratios of different types of waste. It is required that at least part of the waste fed to the digester has a moisture level in the range 50% - 80% by weight, preferably 50- 75% by weight in order to promote the faster thermophyllic reaction. However, part of the waste fed to the digester may comprise a relatively dry commercial waste. The heat generated by the digestion of the moist waste is sufficient to treat the whole of the waste fed to the digester. However, during the agitation process, the commercial and domestic waste are slowly mixed together reducing the overall moisture content of the mixture, so that at the end of the processing, the moisture level does not exceed 45 % by weight and preferably does not exceed 35% by weight.
Solid waste with higher moisture level may be blended with solid waste with lower moisture level in blending apparatus in a controlled manner. The relative quantities of different types of waste can be controlled so that the desired average moisture level is obtained as explained above.
The blending step also allows absorbent material such as paper and paper based material (which is particularly common in commercial waste) to be blended intimately with the moist waste (such as domestic waste). The absorbent material absorbs liquid rich in bacteria, providing a substrate for the bacteria to grow on and allowing the bacteria to be spread throughout the waste being processed. This promotes reaction and mixing, leading to an improved digestion. Further, the wetting of the paper helps it to be broken down.
In processing solid organic waste it is particularly important to produce a product which is substantially homogeneous, at least at the scale of mm or above. The blending step helps to improve the homogeneity of the product.
However, although blending takes place, it is found that the moisture level remains concentrated in local areas of the waste, where it is sufficiently high to allow the thermophyllic reaction to commence and proceed very rapidly.
The relative quantities of different types of waste fed can be controlled using automatic weigh feeders.
A further parameter which may be manipulated is the pH of the organic waste. This is suitably in the range 6.0-8.5, preferably 6.3-7.3, most preferably around 6.8..
It has been further found that the density of the organic waste fed to the anaerobic digestion process is suitably not too low. Preferably, the density is not less than 45 Og per litre, preferably not less than 750g per litre. Again, the blending step is particularly useful here. Domestic waste can have a relatively high density. The average density can be controlled by admixing a suitable quantity of commercial waste, which has a comparatively low density.
Preliminary Treatment
As described above, the solid organic waste may be subjected to various types of treatment before the anaerobic digestion process. Preferably, the previous steps include any or all of the following:
1. Picking
Initial treatment to remove objects which are not combustible, such as stone, concrete, metal, old tyres etc. Objects having a size in excess of 100mm or more may also be removed The process can be carried out on a stationary surface, such as a picking floor. Alternatively or additionally, the solid organic waste may be loaded onto a moving surface such as a conveyor and passed through a picking station in which mechanical or manual picking of the material takes place.
2. Screening
The organic solid waste may be mechanically screened to select particles with size in a given range. The given range may be from 10mm to 50mm. Material less than 10mm in size comprises dust, dirt and stones and is rejected. The solid organic waste may be treated to at least two screening processes in succession, each removing progressively smaller fractions of particles. Material removed in the screening process as being too large may be shredded to reduce its average size. Material which is classified by the screen as being of acceptable size and, where applicable, shredded material can then be fed to the anaerobic digestion step.
3. Blending Domestic and commercial waste may be blended in a blending mixer before being fed to the anaerobic digestion process. This is particularly important step. Where least domestic waste and commercial waste are received for treatment, they are preferably processed separately. It is found that commercial waste can be treated before the anaerobic digestion process in a picking stage to remove oversized objects followed by a shredding stage only. By keeping the different types of waste separate, accurate control of quality of solid waste fed to the anaerobic digestion step can be obtained.
Subsequent Treatment
The treated material may be subjected to a number of steps after the anaerobic digestion process. These steps may include any of the following:
1. Grading
The material may be screened to remove particles in excess of a given size. For example, particles in excess of 50mm may be rejected. They may be subsequently shredded to reduce their size, returned to the anaerobic digester or simply rejected.
2. Metal Separation
Relatively small metal particles such as iron or aluminium may have passed through the system. They can be removed, for example by a magnetic or electromagnetic remover in a subsequent step. Metal particles removed f om the system may then pass to a suitable recycling process.
3. Drying
Suitably, after treatment in the anaerobic digestion process, the material is subjected to a drying step. However, with the first aspect of the present invention, because the moisture level does not exceed 45% by weight, preferably not exceeding 35% by weight, after the digestion step, the subsequent drying can be carried out relatively simply.
For example, in a first stage, a forced draught of air may be provided during or after the unloading phase from the anaerobic digestion process. During this stage, the treated material will still be at high temperature (for example in the range 50-60°C) and a lot of moisture can be removed simply by forcing air over it. A further drying step may comprise laying the material out on a drying floor. In this step, material is laid out at a thickness of not more than 20cm over a relatively large area for a suitable period of time, during which the moisture level drops. The material may be agitated, for example by turning using mechanical or manual apparatus such as a power shovel. The material may be turned at intervals of for example of 2-4 hours preferably around 3 hours. Preferably, during this stage, the moisture level drops to below 30% by weight after which no further biological decomposition occurs. Suitably, the material is left on a drying floor for a period in the range 18-48 hours, preferably 24- 36 hours, more preferably around 24 hours.
It is also found that further drying may take place during subsequent processing, due to the mechanical input of energy.
Waste heat from other process equipment, for example from furnaces, may be used to dry the material.
4. Pelletising
In order to convert the treated material to fuel, the material may be classified according to size and subsequently densified to provide pellets of suitable size which can be subsequently stored or packed for use. During this stage, further drying of the material may occur, due to heat generation caused by friction and due to further exposure to air. Preferably, in order for palletising to proceed well, the moisture level of the treated material is in the range 33-38% by weight.
5. Bagging
Where the material is to be converted into compost, it can simply be bagged after treatment.
By way of example, the moisture level of solid, organic waste during processing may be as follows. Domestic waste with a high organic content and moisture level above 60% can be mixed with commercial waste having a moisture level of 20% or below in a suitable ratio to provides a blend having an average moisture level in the range 50-60%) by weight.
During anaerobic digestion, a part of the moisture is absorbed by the gas and air above the material being processed. The average moisture level may drop to around 45-50% by weight, preferably 35-40% by weight..
During emptying of the digester, the waste which still has a high residual heat level, may be dried by a forced draught as described above, so that the moisture level drops to the range 40-45% by weight, preferably 35-40% by weight.
The waste may then be further dried on a drying floor as described above, so that the moisture level drops to below 30% by weight.
It has been found that the process of the first aspect of the present invention for treating domestic waste can allow up to 85% by weight of delivered waste to be recycled. The remaining 15% by weight has to be rejected and disposed of by conventional means.
Further use of treated material
The method and apparatus of the invention can be used to produce a product which is suitable for subsequent storage, transportation or sale.
It has been found that the method of the invention can provide a fuel, referred to as Green Coal, which has a calorific value in the order of 3500 Kcals/g which is about half that of industrial coal. The material has an ash content of less than 20% by weight and has the additional advantage that it will contain relatively low levels of sulphur and chlorine, so reducing pollution due to acid rain from gases of combustion.
By blending different sources of waste material, fuel produced at different times or with waste from different locations can be relatively homogeneous in terms of: 1. Calorific value - suitably in the range 3000-4000 Kcal/g,
2. Density - suitably in the range 270-350g/l more preferably around 300g/l
3. Moisture level - below 30% by weight and preferably around 20% by weight.
This fuel can be used either on its own or as a supplementary fuel.
Alternatively, the material can be used as a multi purpose organic compost having a relatively high nutrient content.
The apparatus and method of the invention may alternatively form a part of a plant or system. The apparatus and method of the invention can be used to supply fuel in a plant or system. For example, the material may be fed directly to a combustion chamber for generating heat or power. The apparatus and method of the invention can be used to supply a feed to a pyrolysis process, as described below.
The treated material may be fed directly from the digestion vessel to the plant or system or it may be treated by any suitable steps such as grading, metal separation, drying, palletising or bagging as appropriate.
In a particularly preferred embodiment, there is provided an electrical power supply system comprising apparatus according to the invention for feeding material to the combustion chamber of a boiler for providing steam for power plant. In an alternative embodiment, there is provided a cement producing apparatus comprising a cement kiln and an apparatus according to the invention for supplying fuel to the cement kiln.
In this embodiment, complete heat transfer from the fuel to the cement producing materials is obtained as they are mixed together in the kiln. The ash from burning the material of the present invention, is absorbed into the cement material. Waste heat from the kiln can be used to dry the treated waste from the present invention or to provide power for operating the process. The present inventor has further realised that solid organic waste fed to a pyrolysis process can be initially treated by a digestion step, to make the solid organic waste more uniform and more suitable for use in the pyrolysis process. Accordingly, in a second aspect, the present invention provides a method of treating solid organic waste, comprising treating the waste by bacteriological digestion and subsequently subjecting the waste to heating at a temperature which is sufficiently high to substantially pyrolyse the digested waste anaerobically.
The pyrolysed material may be used as a fuel in its own right. However, in a preferred embodiment, the pyrolysed material may be fed to a gasification process in which combustible gases are produced by introduction of a gasifying agent. This will normally require the pyrolysed material to be at a high temperature and the gasification process preferably occurs directly after the pyrolysis process.
The pyrolysis process and gasification process may be carried out in separate zones, for example as described in WO97/15641 and WO97/15640, or in a common zone, for example as shown in GB2301659.
Suitably, the gasifying agent comprises air, steam or water vapour.
Preferred methods and apparatus for the pyrolysis and gasification processes are disclosed in GB2301659, WO97/15640, WO97/15641 and WO01/96501.
Suitable apparatus may also be obtained from Metso Corporation, or from the Allis Chalmers Corporation.
The bacteriological digestion may be aerobic or anaerobic. Preferably, it is anaerobic
Suitably, it is carried out using the thermopyhilic phase, which normally occurs in the temperature range 60°C - 75°C as described above in relation to the first aspect of the invention. Suitably, the digestion takes place in a sealed container, for example a rotating drum. Preferred aspects of the drum are as set out above for the first aspect of the invention. Preferably, the solid organic waste is digested in a manner which allows its moisture level to be controlled.
It is particularly preferred that the solid organic waste is digested by a method according to the first aspect of the invention. Suitably, an apparatus according to the first aspect of the invention is used. The preferred features of the first aspect of the invention described above apply to the second aspect of the invention.
However, instead of the optional treatments of grading, metal separation, drying, pelletising and bagging described above subsequent to the anaerobic digestion process, the treated material from the anaerobic digestion process is suitably fed directly to the apparatus for pyrolysis. Any suitable feed means may be used for delivering the treated waste from the anaerobic digestion process to the pyrolysis apparatus.
As the anaerobic digestion process is typically carried out in a batch wise fashion, whereas the pyrolysis process typically requires a continuous feed of material, an interim storage means, for example in the form of a feed hopper may be provided. It is preferred that there is a first delivery means for receiving treated organic waste from the anaerobic digestion process and feeding it into the interim storage means and a second feed apparatus for feeding the stored treated solid waste from the interim storage means to the pyrolysis apparatus. The second feed means is preferably operated substantially continuously. The first and second feed apparatus may comprise any suitable means, for example conveyor belts or screw feeders.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a schematic process diagram of steps involved in the process of the present invention before the rotary anaerobic digester.
Figure 2 is a schematic process diagram showing the steps involved in feeding the rotary anaerobic digester and drying the material. Figure 3 is a schematic process diagram showing further steps in the procedure.
Figure 4 is a schematic process diagram showing a further embodiment of the present invention.
DETAILED DESCRIPTION OF THE DRAWINGS
Figures 1, 2, and 3 from a continuous process diagram which has been divided into three sections for convenience of illustration.
Figure 1 shows the steps involved in an embodiment of a process according to the first aspect of the present invention for manufacturing fuel from solid organic waste. In this embodiment, two sources of waste 101 and 102 are identified. Source 101 comprises a source of domestic waste, which typically has an average moisture in the range 35-60% by weight. Source 102 comprises a source of commercial waste which may have moisture averaging around 20% by weight.
At 103, waste from the sources 101 102 is delivered to a reception and picking floor. On the reception and picking floor, waste supplies from the two sources 101 and 102 are kept separate. On the picking floor, waste is manually picked over to identify objects which are not suitable for further processing, for example, metal, large plastic objects, etc. The rejected objects are collected at 104 and disposed of separately, for example by tipping or by recycling if appropriate.
The dotted line in step 103 indicates separation of the solid waste from the two sources.
On the left hand side of figure 1, domestic waste which has been manually picked over is then fed at 105 onto a feed conveyor 106 using a loading hopper arrangement. Further manual sorting of the solid waste can take place whilst the waste is on the feed conveyor 106 for example by personnel standing on both sides of the conveyor. The rejected waste can be disposed of in step 104 as described above. The feed conveyor 106 feeds the sorted waste to a rotary screen separator apparatus 107. In a first rotary screen separator 108, particles of size less than 50mm are passed and allowed to fall onto a conveyor 109 for subsequent feeding to the rotary anaerobic digester as will be described further below in figure 2. Material screened out by the rotary screen separator 108 is then screened in a further rotary screen separator 109 which passes objects of size less than 100mm. Objects of size less than 100mm are then fed to a domestic waste shredder 110 which reduces their size to below 50mm and greater than 10mm. Thereafter, the shredded waste is passed onto to the conveyor 109.
Objects of size greater than 100mm are fed onto an "oversize conveyor 112" for further processing.
Returning to the reception floor 103, commercial waste which has been sorted is directed to a commercial waste conveyor 113. Whilst this is on the conveyor, the waste may be subject to further hand picking by personnel located adjacent to the conveyor. Material from the over size conveyor 112 and commercial waste from the commercial waste conveyor 113 are combined and together fed into a commercial waste shredder 114 of suitable design which shreds the waste so that it has a particle size not greater than 50mm.
In Figure 2, the waste products on the conveyor 109, which will comprise unmixed domestic and commercial waste are blended together in a blender 115. Further, paper and paper based material in the commercial waste absorbs moisture in the domestic waste which is rich in bacteria, thus spreading the bacteria throughout the material and providing a substrate to promote bacterial action.
The blended waste is fed from the mixer 115 intermittently to the anaerobic digester 116. The anaerobic digester comprises a cylindrical steel vessel of diameter 5.5mm and length 33m which is mounted with its axis at an angle of approximately 7° degrees to the horizontal with waste being fed in at the loading end 117. Waste is fed into the loading 117 end at intervals of approximately 24 hours, and is simultaneously discharged . Except when loading and unloading, the rotary anaerobic digester is sealed to prevent access of air so that conditions may remain substantially anaerobic inside the anaerobic digester. The digester is normally rotated at a rate of approximately one revolution every 3 minutes. During loading and unloading, the rate of rotation is increased to 1 rpm to help feed material down the digester. As a result, the waste inside the rotary anaerobic digester is gently agitated. Also, as the digester is mounted at an angle to the horizontal, the waste slowly feeds downwards from the loading end 117 to the unloading end 118.
During the loading phase, as mentioned above, a mixture of domestic and commercial waste which has been pre-treated is fed from the mixer 115 into the loading end 117 of the rotary anaerobic digester. By controlling the rate of feed of treated domestic waste on the conveyor 109 and treated commercial waste on the conveyor 113, the average moisture level of the solid waste fed into the loading end 117 of the rotary anaerobic digester 116 can be controlled.
The temperature inside the rotary anaerobic digester is maintained at a temperature in the range 65-75°C, most preferably around 68-70°C. Although it is possible to provide auxiliary heating means, this is not normally required, as the moist solid waste fed into the digester undergoes a thermophyllic anaerobic reaction which leads to the generation of sufficient heat to maintain the temperature at the desired level.
It can be seen that the screening and shredding apparatus can be used to ensure that the waste fed into the rotary anaerobic digester does not have a particle size greater than 50mm. Further, by controlling the relative quantities of commercial and domestic waste fed into the rotary anaerobic digester using the blending system, the overall moisture level of at least part of the load can be maintained at the high level leading to a high rate of reaction. Further whilst the waste is on the conveyor or picking floor, it can be tested to ensure that its pH is the correct range and suitable additives can be added to correct the pH in a manner known to the person skilled in the art if necessary. Further, the shredders can be operated to ensure that the density of the waste material does not fall below 750gm per litre. It has been found that if the solid waste fed into the rotary anaerobic digester meets the following parameters, a high rate of anaerobic digestion can be obtained:
1. less than 50mm in size
2. moisture content between 50 and 70%, ideally 60% by weight.
3. pH between 6.5 and 8.0
4. density not less than 750gm per litre.
The rotary anaerobic digester is operated so that waste has residence time of approximately 24 hours inside the digester. During an appropriate unloading phase, digested waste is unloaded at the unload end 118 where it is sieved. Digested waste with a particle size less than 50mm is collected at 119. This material is suitable for formation of fuel pellets as will be described further below. Treated waste with a particle size in excess of 50mm is collected at 120 and rejected. A grid inside the digester, over the final 1 metre length, for passing objects of size less than 50mm is provided, to reject oversize material.
In step 121, the sieved treated solid waste is treated in a metal separation stage, for separating out metals such as iron and aluminium In a manner known in the art, electromagnetic or magnetic apparatus can be used to separate various materials which can be collected at 122 for suitable recycling.
The treated waste from which metal has been received can be spread on a stockpile / drying floor 123.
Treated waste collected at the unloading end 118 has a moisture level of not more than 35%) by weight and preferably not more than 35% by weight. A certain amount of the moisture in the treated solid waste material goes into the gas over the material in the rotary anaerobic digester. A certain amount of the moisture is driven off for example by a forced draught fan at the unloading stage 118 when the anaerobic digester is opened the waste sieved.
The moisture level of the treated waste loaded onto the drying floor is typically in the range 30-35% by weight and the material will still be at a temperature in the range 50- 60°C from the drum. The material is fed into a layer not more than 20cm thick, where it is allowed to dry by natural evaporative drying and mechanical turning. As a result, the moisture level drops to a level of less than 30% by weight. At this stage, further bacterial decomposition of the material ceases and the product becomes stable and storable.
In Figure 3, dried treated waste from the stock pile 123 is loaded onto a feed conveyor 124 where it is fed to a classifier 125 for separating treated waste which is of too large a diameter. Particles of size in excess of 50mm are rejected and collected at 126. Particles of size less than 50mm are collected in a hopper 127 from whence they are fed to a feed stock transfer conveyor 128 which transfers the treated waste to densifiers 129 and 130. The densifiers compress and pelletise the waste and further reduce the moisture level. Over spill from the conveyor 128 is collected at 132 and returned to the conveyor 134. Pelletised treated waste is collected on a conveyor 131 and delivered to a stockpile or bagging stage at 133.
EXAMPLE
A process according to figures 1-3 was operated with a feed a comprising 75000 tons per annum of mixed municipal waste. The average moisture level of waste input to the rotary anaerobic digester was 60% by weight, with some batches having higher moisture level and some batches having lower moisture level.
Treated waste collected from the rotary anaerobic digester, after unloading and fan drying had a moisture level of about 35% by weight.
After 24 hours residence on the drying floor 123, the moisture level had dropped to below 30% by weight and the product was stable.
From an input of 75,000 tonnes of combined waste materials, 50,000 tonnes of GREEN COAL can be produced, having a calorific value equivalent to 25,000 tonnes of fuel oil. The graded and pelletised product was found to have constant thermal characteristics and to be suitable for use as a supplementary fuel, going by the description of GREEN COAL. It had a minimum calorific value of 3500Kcals/g. It had an ash content of less than 20% by weight and very small quantities of sulphur and chlorine.
Figure 4 shows a schematic process diagram of a second embodiment of the present invention.
The embodiment of Figure 4 will employ the system as shown in Figure 1 for the pre- treatment of solid waste material and digestion in a rotary anaerobic digester 116 as shown in Figure 2. However, the embodiment of Figure 4 is different to that of Figures 2 and 3 in that a different system is employed downstream of the anaerobic digester. At the output end 118 of the rotary anaerobic digester, the treated material is fed into a gravity hopper 118 for storage of material. The stored material is fed from the gravity hopper 134 by a screw feeder 135 into a pyrolysis chamber 136 in which the solid waste material is transported by a screw while being heated to a temperature in excess of 800°C, sufficient to cause pyrolysis of the treated waste material. As a result, a mixture of combustible gases is produced at 139. The solid material is reduced to a char, largely comprising carbon and ash.
The char may, in some embodiments, be used as a fuel. However in the process shown in Figure 4,the char is fed into a gasification chamber 138, where it is maintained at a temperature in excess of 800°C and treated with steam so that a mixture of carbon monoxide and hydrogen are generated at 140. As a result, the char is converted to a non-combustible ash 141 which is subsequently disposed of, suitably by landfill.
The combustible gases from the pyrolysis chamber 139 and the producer gas 140 from the gasification chamber 138 are burnt at high temperature in a combustion chamber 142. As a result, exhaust gas is produced. The exhaust gas has a very low content of pollutants in particular, NOx gases, because of the combustion conditions.
The combustion of the gases 139 and 140 is used to produce steam, some of which is fed at 144 into the gasification chamber and the remainder of which is fed at 143 into a steam turbine power plant 145 for the generation of electricity. Electricity from the power plant can be distributed at 146 for running the entire apparatus of the embodiment of Figure 4. Power can also be delivered at 147 to consumers, via the National grid for example.
The pyrolysis and gasification apparatus is shown schematically only. It is suitably as described for example in WO97/15640 or WO97/15641. Alternatively, the gasification and pyrolysis chambers maybe combined, for example as shown GB2301659.

Claims

CLAIMS:
1. A method of treating solid organic waste, comprising treating the waste by anaerobic digestion, the solid waste being agitated during digestion, the waste having an average moisture level after treatment not exceeding 45% by weight and preferably not exceeding 35% by weight.
2. The method of Claim 1, wherein the solid organic waste is treated in a rotary anaerobic digester.
3. The method of Claim 2, wherein the rotary anaerobic digester is rotated at a rate of one revolution in a period ranging from 1 minute to 10 minutes, preferably 2 to 5 minutes.
4. The method of any preceding claim, further comprising the step of mixing the solid organic waste with other solid waste of average moisture level less than 30% by weight before digestion.
5. The method of claim 4, wherein the relative quantities by weight of the solid organic waste and the other waste are controlled.
6. The method of Claim 5, wherein the solid organic waste and the other solid waste are mixed so that the overall average moisture level is in the range 50- 60% by weight, preferably 45-60 % by weight.
7. The method of any preceding Claim, wherein the treated solid organic waste is processed to form fuel.
8. The method of any of Claims 1 to 6, wherein the treated solid organic waste is processed to form compost.
9. The method of any preceding claim, wherein, before treatment, the solid organic waste has a moisture level in the range 45-75% by weight, more preferably 60-65% by weight, a pH in the range 6.0 to 8.5, a density of not less than 450g/l and a particle size not exceeding 50mm.
10. Apparatus for treating solid organic waste, comprising an anaerobic digestion vessel, means for agitating the solid organic waste in the vessel, and drying means following the digestion vessel and means for controlling the input of solid organic waste to the vessel so that moisture level of waste after treatment does not exceed 45% by weight, preferably not exceeding 35% by weight.
11. Apparatus according to Claim 10, further comprising a supply of solid organic waste and a supply of other waste having an average moisture level of not more than 30% by weight and means for mixing the solid organic waste and the other waste before it is fed to the digestion vessel.
12. Apparatus according to Claim 11, further comprising control means for controlling the relative quantities by weight of the solid organic waste and the other waste mixed together.
13. The method of treating solid organic waste, comprising treating the waste by bacteriological digestion and subsequently treating the treated waste in a pyrolysis process.
14. A method according to Claim 13, wherein after the pyrolysis process, the pyrolysed waste is treated in a gasification process
15. A method according to claim 13 or 14, wherein the bacteriological treatment is anaerobic digestion.
16. A method according to claim 13, 14 or 15, wherein the solid organic waste is treated by method of any of claims 1, to 6 or 9.
17. Apparatus for treating solid organic waste, comprising a bacteriological digestion vessel, means for feeding bacteriologically digested solid organic waste from the bacteriological digestion vessel to means for pyrolysing the treated solid organic waste.
18. An apparatus according to Claim 17, further comprising means for gasifying the pyrolysed solid organic waste.
19. An apparatus according to claim 16, wherein the solid organic waste is treated in an apparatus according to any of claims 10-12.
20. A method of treating solid organic waste, substantially as herein described with reference to the accompanying drawings.
21. Apparatus for treating solid organic waste substantially as herein described with reference to the accompanying drawings.
PCT/GB2003/005687 2003-01-07 2003-12-31 Method and apparatus for processing solid organic waste WO2004060587A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU2003295162A AU2003295162A1 (en) 2003-01-07 2003-12-31 Method and apparatus for processing solid organic waste
PCT/GB2004/003157 WO2005063946A1 (en) 2003-12-31 2004-07-22 Method and apparatus for processing mixed organic waste
GB0605977A GB2431155B (en) 2003-12-31 2006-03-24 Method and apparatus for processing mixed organic waste

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0300309.2 2003-01-07
GB0300309A GB0300309D0 (en) 2003-01-07 2003-01-07 Method and apparatus for processing solid organic waste

Publications (1)

Publication Number Publication Date
WO2004060587A1 true WO2004060587A1 (en) 2004-07-22

Family

ID=9950775

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2003/005687 WO2004060587A1 (en) 2003-01-07 2003-12-31 Method and apparatus for processing solid organic waste

Country Status (3)

Country Link
AU (1) AU2003295162A1 (en)
GB (1) GB0300309D0 (en)
WO (1) WO2004060587A1 (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2423079A (en) * 2005-06-29 2006-08-16 Tetronics Ltd Combined gasification and plasma treatment of waste
WO2007000607A1 (en) * 2005-06-29 2007-01-04 Tetronics Limited Waste treatment process and apparatus
ES2273594A1 (en) * 2005-09-05 2007-05-01 Francisco Angulo Lafuente Fuels production from organic waste comprises e.g. household waste comminution and wetting, for yeast and bacteria based methane and oils extraction
WO2008040396A1 (en) * 2006-10-06 2008-04-10 Pearse O'kane Renewable energy recovery from msw and other wastes
WO2009034217A1 (en) 2007-09-11 2009-03-19 Francisco Angulo Lafuente Method for treating organic matter and obtaining and refining fuels from said matter
DE102007056353A1 (en) * 2007-11-16 2009-05-20 Jürgen Heinrich Method for waste treatment, particularly domestic, commercial and industrial waste, involves subjecting waste of recycling material, where electrical energy is generated by thermal recycling of high calorific residual fraction of waste
US7955839B2 (en) 2006-06-23 2011-06-07 Recology Inc. Systems and methods for converting organic waste materials into useful products
US7985577B2 (en) 2003-04-30 2011-07-26 Recology, Inc. Systems and processes for treatment of organic waste materials with a biomixer
WO2013110186A1 (en) * 2012-01-23 2013-08-01 Anaergia Inc. Syngas biomethanation process and anaerobic digestion system
US8667914B2 (en) 2010-05-07 2014-03-11 Advanced Plasma Power Limited Waste treatment
US8809038B1 (en) 2003-04-30 2014-08-19 Recology Inc. Process for treatment of organic waste materials
US8877468B2 (en) 2010-09-24 2014-11-04 Anaergia Inc. Method for converting biomass to methane or ethanol
US8957275B2 (en) 2010-03-19 2015-02-17 Advanced Plasma Power Limited Waste treatment
CZ305015B6 (en) * 2013-07-22 2015-03-25 Az Eco Energy, Spol. S R.O. Reactor for pyrolysis (thermal decomposition) of solid bulk organic waste, particularly sewage sludge and sludge from a biogas station
WO2016074990A1 (en) * 2014-11-14 2016-05-19 Huber Se Digestion and gasification of sludge occurring in a wastewater-treatment plant
US9868964B2 (en) 2015-02-06 2018-01-16 Anaergia Inc. Solid waste treatment with conversion to gas and anaerobic digestion
US9879285B2 (en) 2015-07-20 2018-01-30 Anaergia Inc. Production of biogas from organic materials
US11123778B2 (en) 2016-03-18 2021-09-21 Anaergia Inc. Solid waste processing with pyrolysis of cellulosic waste
US11286507B2 (en) 2013-07-11 2022-03-29 Anaergia Inc. Anaerobic digestion and pyrolysis system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1983002779A1 (en) * 1982-02-15 1983-08-18 Peter Hood Method for the production of a fuel from waste
US4420320A (en) * 1979-09-27 1983-12-13 Industrie-Werke Karlsruhe Augsburg Aktiengesellschaft Method of biologically drying waste material
US4826573A (en) * 1986-12-24 1989-05-02 Iris M. P. Van Der Heyden Method for processing substantially solid organic material
US4935035A (en) * 1987-11-11 1990-06-19 Helmut Kloimstein Process of producing dried wood chips
DE4103715A1 (en) * 1990-02-12 1991-07-11 Annerose Kutzer Plant for treating household and industrial waste - has bunker for supplying waste, fermentation reactor, carbonisation drum and second fermentation reactor
WO2001079123A1 (en) * 2000-04-19 2001-10-25 Daub, Roman Method for conditioning biogenic solid substances

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4420320A (en) * 1979-09-27 1983-12-13 Industrie-Werke Karlsruhe Augsburg Aktiengesellschaft Method of biologically drying waste material
WO1983002779A1 (en) * 1982-02-15 1983-08-18 Peter Hood Method for the production of a fuel from waste
US4826573A (en) * 1986-12-24 1989-05-02 Iris M. P. Van Der Heyden Method for processing substantially solid organic material
US4935035A (en) * 1987-11-11 1990-06-19 Helmut Kloimstein Process of producing dried wood chips
DE4103715A1 (en) * 1990-02-12 1991-07-11 Annerose Kutzer Plant for treating household and industrial waste - has bunker for supplying waste, fermentation reactor, carbonisation drum and second fermentation reactor
WO2001079123A1 (en) * 2000-04-19 2001-10-25 Daub, Roman Method for conditioning biogenic solid substances

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8809038B1 (en) 2003-04-30 2014-08-19 Recology Inc. Process for treatment of organic waste materials
US7985577B2 (en) 2003-04-30 2011-07-26 Recology, Inc. Systems and processes for treatment of organic waste materials with a biomixer
EP2264367A3 (en) * 2005-06-29 2017-11-22 Advanced Plasma Power Limited Waste treatment process and apparatus
GB2423079B (en) * 2005-06-29 2008-11-12 Tetronics Ltd Waste treatment process and apparatus
EP2026003A3 (en) * 2005-06-29 2017-09-20 Advanced Plasma Power Limited Waste treatment process and apparatus
RU2554970C2 (en) * 2005-06-29 2015-07-10 Эдванст Плазма Пауэр Лимитед Method and device for processing of wastes
US7658155B2 (en) 2005-06-29 2010-02-09 Advanced Plasma Power Limited Waste treatment process and apparatus
GB2423079A (en) * 2005-06-29 2006-08-16 Tetronics Ltd Combined gasification and plasma treatment of waste
WO2007000607A1 (en) * 2005-06-29 2007-01-04 Tetronics Limited Waste treatment process and apparatus
US8109218B2 (en) 2005-06-29 2012-02-07 Advanced Plasma Power Limited Waste treatment process and apparatus
US8438983B2 (en) 2005-06-29 2013-05-14 Advanced Plasma Power Limited Waste treatment process and apparatus
US8443741B2 (en) 2005-06-29 2013-05-21 Advanced Plasma Power Limited Waste treatment process and apparatus
ES2273594A1 (en) * 2005-09-05 2007-05-01 Francisco Angulo Lafuente Fuels production from organic waste comprises e.g. household waste comminution and wetting, for yeast and bacteria based methane and oils extraction
US7955839B2 (en) 2006-06-23 2011-06-07 Recology Inc. Systems and methods for converting organic waste materials into useful products
WO2008040396A1 (en) * 2006-10-06 2008-04-10 Pearse O'kane Renewable energy recovery from msw and other wastes
WO2009034217A1 (en) 2007-09-11 2009-03-19 Francisco Angulo Lafuente Method for treating organic matter and obtaining and refining fuels from said matter
DE102007056353A1 (en) * 2007-11-16 2009-05-20 Jürgen Heinrich Method for waste treatment, particularly domestic, commercial and industrial waste, involves subjecting waste of recycling material, where electrical energy is generated by thermal recycling of high calorific residual fraction of waste
US8957275B2 (en) 2010-03-19 2015-02-17 Advanced Plasma Power Limited Waste treatment
US8667914B2 (en) 2010-05-07 2014-03-11 Advanced Plasma Power Limited Waste treatment
US8877468B2 (en) 2010-09-24 2014-11-04 Anaergia Inc. Method for converting biomass to methane or ethanol
US8993288B2 (en) 2010-09-24 2015-03-31 Anaergia Inc. Method for converting biomass to methane
US9416374B2 (en) 2010-09-24 2016-08-16 Anaergia Inc. Method for treating lignocellulose-bearing materials
US20130203144A1 (en) * 2012-01-23 2013-08-08 Anaergia Inc. Syngas biomethanation process and anaerobic digestion system
US9284203B2 (en) 2012-01-23 2016-03-15 Anaergia Inc. Syngas biomethanation process and anaerobic digestion system
US9567247B2 (en) 2012-01-23 2017-02-14 Anaergia Inc. Syngas biomethanation process and anaerobic digestion system
WO2013110186A1 (en) * 2012-01-23 2013-08-01 Anaergia Inc. Syngas biomethanation process and anaerobic digestion system
US11286507B2 (en) 2013-07-11 2022-03-29 Anaergia Inc. Anaerobic digestion and pyrolysis system
CZ305015B6 (en) * 2013-07-22 2015-03-25 Az Eco Energy, Spol. S R.O. Reactor for pyrolysis (thermal decomposition) of solid bulk organic waste, particularly sewage sludge and sludge from a biogas station
WO2016074990A1 (en) * 2014-11-14 2016-05-19 Huber Se Digestion and gasification of sludge occurring in a wastewater-treatment plant
US9868964B2 (en) 2015-02-06 2018-01-16 Anaergia Inc. Solid waste treatment with conversion to gas and anaerobic digestion
US9879285B2 (en) 2015-07-20 2018-01-30 Anaergia Inc. Production of biogas from organic materials
US11123778B2 (en) 2016-03-18 2021-09-21 Anaergia Inc. Solid waste processing with pyrolysis of cellulosic waste

Also Published As

Publication number Publication date
AU2003295162A1 (en) 2004-07-29
GB0300309D0 (en) 2003-02-05

Similar Documents

Publication Publication Date Title
WO2004060587A1 (en) Method and apparatus for processing solid organic waste
US4203376A (en) Treatment of waste
CA1108403A (en) Fuel from composting solid organic wastes
CA2478642C (en) Conversion of municipal solid waste to high fuel value
US4255129A (en) Apparatus and method for processing organic materials into more useful states
KR101024447B1 (en) Production of refuse derived fuel with biomass using microbial materials
WO2005063946A1 (en) Method and apparatus for processing mixed organic waste
US5556445A (en) Steam treatment of municipal solid waste
US20120324785A1 (en) Pyrolysis of Biomass
US20060280669A1 (en) Waste conversion process
GB2423079A (en) Combined gasification and plasma treatment of waste
KR101876555B1 (en) Solid fuel using paper sludge and coffee sludge and manufacturing method thereof
US20140069798A1 (en) Process and device for devolatizing feedstock
CN107008735A (en) A kind of Combustion Properties of Municipal Solid Waste gasification process
KR101999650B1 (en) Hybrid Sludge Fuel, Manufacturing Method and System of Fuel Production thereof
Stępień et al. Organic waste torrefaction–a review: reactor systems, and the biochar properties
KR100998800B1 (en) The method for manufacturing a mixing solid fuel from municipal waste and landfilled waste by calorimetry
EP0566419B1 (en) Method of making refuse derived fuels
KR100384068B1 (en) Method of making fertilizer using food trash
CN111282951A (en) Landfill stale refuse treatment system and method
JP2006088044A (en) Sludge carbonized matter and carbonization method of sludge
EP1364916A1 (en) Method of anaerobic digestion of organic and non organic waste to produce premium compost or recycled fuel
Park et al. Characteristics of Fuel Pellets Made by Mixing Paper Sludge and Forest Byproducts
US20240191151A1 (en) Method for providing raw material for an industrial process
AU2003208132A1 (en) Waste management

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP