WO2004056560A1

WO2004056560A1 - Method and device for producing a multi-ply printed web of flexible material, such as paper and nonwoven, and multi-ply material produced by the method

Info

Publication number: WO2004056560A1
Application number: PCT/SE2003/001987
Authority: WO
Inventors: Anders Andersson; Anna MÅNSSON; Eva-Li SAARVÄLI; Wolfgang Hof; Ferdinand Hein
Original assignee: Sca Hygiene Products Ab
Priority date: 2002-12-19
Filing date: 2003-12-17
Publication date: 2004-07-08
Also published as: MXPA05006400A; SE0203847D0; CN1729097A; BR0317551A; AU2003288843A1; AU2003288843A2; PL376005A1; EP1575767A1; CO5580810A2; RU2005122657A

Abstract

Method for producing a multi-ply web (17) of flexible material, such as paper and nonwoven material, comprising at least one first (1) and one second ply (8) which are interconnected by gluing in a plurality of discrete glue sites (13). The web is printed with at least one printing pattern (18;19) which is in register with the glue pattern (12). The multiply web is produced by bringing a first ply (1) in contact with a patterned glue transfer roll (5), transferring glue to the first ply in a glue pattern, a second ply (8) is brought in contact with the glue applied side of the first ply (1) in a press nip between a patterned lamination roll (10) and an impression roll (7), the glue transfer roll (5) and the lamination roll (10) being in register with each other and having corresponding patterns. At least one of the plies is printed by a printing roll (15;16) carrying a colorant, a skin care agent or other functional chemical in a selected pattern, said printing is performed in register with the glue transfer while the first and/or second web shaped flexible materials are residing on said impression roll (7).

Description

Method and device for producing a multi-ply printed web of flexible material, such as paper and nonwoven, and multi-ply material produced by the method

Technical field

The present invention refers to a method for producing a multi-ply web of flexible material, such as paper and nonwoven material, by means of gluing the plies. Especially it refers to production of tissue products such as toilet and kitchen paper, paper towels, hand towels, napkins, handkerchiefs, wiping material and the like. The invention further refers to a multi-ply web of flexible material, such as paper and nonwoven, comprising at least a first and a second ply, which are interconnected by means of gluing in spots.

Background of the invention It is very common to laminate two or more tissue plies in order to produce the final tissue product. Herewith a more flexible and softer tissue product is obtained as compared to if one single ply with a corresponding thickness and basis weight had been produced as for the laminated product. The absorbent capacity and the bulk are moreover improved.

The lamination of two or more tissue plies is often made by means of gluing. A mechanical embossing of the plies is also often performed before they are glued together. It is further known to laminate two plies only by means of a mechanical embossing, at which a mechanical joining of the plies occurs in the embossing sites.

Through for example EP-A-796 727 it is known to first emboss two paper plies in a three dimensional structure with alternating raised and recessed portions, after which glue is applied to one of the plies and the two plies are joined in a press nip between two embossing rolls, so that the raised portions of the respective plies are glued to each other. A similar embossing procedure is shown in EP-A-738 588, according to which the glue also has a colouring effect.

In WO 95/08671 there is enclosed an example of so called nested embossing, in which the two individually embossed plies are combined and joined with the raised portions of one ply nesting into the recessed portions of the opposite ply. Through US-A-5,443,889 there is known a procedure for laminating two paper plies, which are fed over a pattern roll each, said pattern rolls having alternating raised and recessed portions and where glue is applied to one ply while this is led over the roll. The two paper plies are then glued together in a nip between the two pattern rolls, which are in register with each other so that a joining and compression of the paper plies occurs in a pattern corresponding to the raised portions of the pattern rolls.

A drawback that occurs in connection with embossing a paper web where this is compressed in spots, is that a considerable strength reduction occurs in the embossing sites, which effects the strength properties of the entire paper product. Strength reductions of up to 70% of an embossed paper as compared to a corresponding unembossed paper are not unusual.

In Swedish patent application no. 0200590-8 there is disclosed a method for producing a multi-ply paper or nonwoven material, by means of gluing the plies wherein a glue transfer roll and a lamination roll are driven in register. The glue transfer roll and the lamination roll have corresponding patterns of protuberances so that the plies are glued together in a pattern corresponding to the configuration of the protuberances.

Printing of tissue paper with a colorant is often made for aesthetical reasons. The printing pattern could be any pattern including more or less continuous lines, line segments, dots, trademarks, logotypes, symbols, fantasy characters etc. In a multiply web material printing is usually made on the outside of the multiply web, but may also be on the inner side of one ply, wherein it is visible through the ply.

Object and most important features of the invention

The object of the present invention is to provide a method for producing a printed multi-ply web of flexible material, such as paper and nonwoven material, wherein at least two plies of flexible material are laminated together by gluing and which provides a high flexibility in creating printing patterns and combinations of printing patterns and/or combinations of glue patterns and printing patterns.

This has according to the invention been provided by a method, comprising the steps of bringing a patterned glue transfer roll, having a pattern of protuberances, in contact with a glue application device, transferring glue to a first web shaped flexible material in a glue pattern corresponding to the configuration of the protuberances, a second web shaped flexible material being brought in contact with the glue applied side of said first web shaped flexible material in a press nip between a patterned lamination roll and an impression roll, said lamination roll having a pattern of protuberances corresponding to said glue pattern, the glue transfer roll and the lamination roll being in register with each other, so that the first and second web shaped flexible materials are combined and glued together in a pattern corresponding to the configuration of the protuberances, wherein the first web shaped flexible material and/or the second web shaped flexible material is printed by a printing roll carrying a colorant, a surfactant, a skin care agent or other functional chemical in a selected pattern, said printing is performed in register with the glue transfer while the first and/or second web shaped flexible materials are residing on said impression roll.

In one embodiment the first web shaped flexible material is printed before it is laminated to the second web shaped flexible material, wherein the printed pattern is printed on the inside of the first web shaped flexible material, i.e. the side facing the second web shaped flexible material. According to one aspect of this embodiment two or more patterns are printed in subsequent steps on said first web shaped flexible material before it is laminated to the second web shaped flexible material, said patterns being printed in register with each other and with the glue pattern.

In a further embodiment the second web shaped flexible material is printed after or simultaneously with lamination to the first web shaped flexible material, wherein the printed pattern is printed on the outside of the second first web shaped flexible material. According to one aspect of this embodiment two or more patterns are printed in subsequent steps on said second web shaped flexible material after or simultaneously with lamination to the first web shaped flexible material, said patterns being printed in register with each other and with the glue pattern.

According to one embodiment at least two printing stations are provided, wherein at least one first printing station prints at least one first pattern on the first web shaped flexible material before it is laminated to the second web shaped flexible material, and at least one printing station prints at least one second pattern on the second web shaped flexible material after or simultaneously with lamination to the first web shaped flexible material. In one embodiment the glue is a coloured glue, wherein said coloured glue pattern will appear as a printed pattern. At least one printing pattern can be the same as and printed on the next web shaped flexible material just on top of the coloured glue pattern. The at least one printing pattern and said glue pattern may be of different colours, wherein a "two-sided product" will be provided. The coloured glue pattern and the printing pattern(s) may further be different.

According to further embodiments at least two different printing patterns are provided.

In one embodiment of the invention at least one of the plies before lamination with the opposite ply is exerted to a three-dimensional patterning.

In a further embodiment the multi-ply web is embossed after lamination.

The size of each glue site should amount to between 0.15 and 150, preferably between 0.5 and 100 mm², more preferably between 1 and 15 mm². The number of glue sites per area unit should amount to between 25 and 350000, preferably between 300 and 180000 and more preferably between 800 and 50000 glue sites per m². It is pointed out that the glue sites may be regularly distributed over the area of the web shaped material, but they may also be irregularly distributed, for example arranged in groups spaced apart.

The term sites in this respect refers to any shape of the glue sites, such as small points, lines, figures, letters, fantasy patterns or any desired shape. The invention further refers to a multi-ply web of flexible material, such a paper and nonwoven, comprising at least one first and one second ply which are interconnected by gluing in a plurality of discrete glue sites, wherein the web is printed with at least one printing pattern which is in register with the glue pattern and wherein the printing pattern and the glue pattern are either overlapping or non-overlapping.

In one embodiment at least one printing pattern is printed on the inner side of at least one ply and is visible from the outside of the multiply product.

In one embodiment at least one printing pattern is printed on the outside of at least one ply. According to a further embodiment at least one printing pattern is printed on the inner side of at least one ply and at least one printing pattern is printed on the outside of at least one ply.

Further features of the invention are disclosed in the following description and in the claims.

Description of drawings

The invention will in the following be closer described with reference to some embodiments shown in the accompanying drawings.

Fig. 1 shows a schematic side view of a first embodiment of a device for performing the method according to the invention.

Fig. 2 shows a schematic side view of a second embodiment of a device for performing the method according to the invention. Fig. 3 is a plan view of one embodiment of a multiply web according to the invention.

Fig. 4 is a plan view of a further embodiment of a multiply web according to the invention.

Description of an embodiment

Fig. 1 shows a device for producing a two-ply material, of e g paper, especially tissue paper. A first paper web 1 is fed over a roll 2 and an impression roll 7. While residing on the impression roll 7 the first paper web 1 is printed by a printing roll 15 carrying a colorant, a surfactant, a skin care agent or other functional chemical, in a selected pattern. The printing unit may be a flexographic printing device or any optional printing device adapted to print on paper or nonwoven. The first paper web is then fed towards a glue application station. This comprises a glue chamber 3 from which glue is applied on a glue roll 4. The glue roll 4 is in contact with a first patterned glue transfer roll 5, which along its periphery is provided with a pattern of protuberances 6. The glue roll 4 is only contacting the tops of the protuberances 6, so that glue is applied only thereon. The paper web 1 is passed into a press nip between the glue transfer roll 5 and the centrally placed impression roll 7. Glue will thus be applied to the first paper web 1 in a pattern corresponding to the configuration of the tops of the protuberances 6. The printing roll 15 is driven in register with the glue transfer roll 5. The printing pattern is in register with and preferably not overlapping with the glue pattern. The term "in register with" generally refers to that two or more patterns are applied with fixed relationship to each other, and are either overlapping or non- overlapping. The term "overlapping" includes that the patterns are located just above each other or are only partly covering each other.

The pressure in the press nip between the glue transfer roll 5 and the impression roll 9 is low and only sufficiently high to accomplish a transfer of glue to the paper web 1. According to one aspect of the invention no or only a slight deformation of the paper web takes place, i e no distinct impression of the protuberances 6 of the glue transfer roll 5 into the paper web will occur.

A second paper web 8 is fed over a roll 9 and into a press nip between a patterned lamination roll 10 and the centrally placed impression roll 7. The lamination roll 10 has a three dimensional pattern of protuberances 11 corresponding to the pattern of the protuberances 6 on the glue transfer roll 5. The term "corresponding to" in this respect means that the protuberances 11 either have the same shape and size of the effective surface area as the protuberances 6 of the glue transfer roll 5, the same shape but a larger effective surface area than the protuberances 6 of the glue transfer roll 5 so as to extend outside the outer circumference of the glue sites provided by the glue transfer roll 5, or a different shape and a larger effective surface area than the protuberances 6 of the glue transfer roll 5. For example a glue pattern 12 provided by the first pattern roll 5 may be in the form of groups of three dots 13 arranged in a triangular pattern as shown in Fig. 1 and 2, wherein the protuberances 11 of the lamination roll 10 may either be exactly the same as or slightly larger than the glue pattern, or may for example be in the form of a triangle 14 covering the three dots. In all these cases the relative positions of the patterns on the glue transfer roll 5 and the lamination roll 10 are in correspondence with each other.

The glue transfer rolls 5 and the lamination roll 10 are driven in register with each other so that the first and second paper webs 1 and 8 are pressed and glued together in a pattern corresponding to the configuration of the glue pattern provided by the glue transfer roll 5.

It is preferred that one centrally impression roll 7 is used for both the glue transfer roll 5 and the lamination roll 10, as is shown in Fig. 1. However it would of course also be possible to use two separate impression rolls and to synchronize them so that they are driven in register.

Also in this second press nip the pressure should be sufficiently high to provide a gluing together of the two paper webs 1 and 8. The pressure in the second press nip should preferably not be higher than to cause only slight compacting impressions just opposite the glue sites in the second ply 8 facing the lamination roll 10.

The opposite external surface of said multi-ply web, i e the surface facing the central impression roll 7 will substantially maintain its structure unaffected by the lamination process with no compacting impressions in the material opposite the glue sites.

The pattern on the glue transfer roll 5 can be optional, but should be chosen so that glue is applied to the paper web 1 in an amount corresponding to between 0.03 and 9%, preferably between 0.1 and 6% of the total surface area of the paper web 1. In the present case the glue sites 13 are sparsely distributed over substantially the entire area of the laminated product. It is with the method according to the invention possible to provide a very distinct positioning of the glue sites 13, wherein a very small amount of glue is needed. This means advantages with respect to softness, drapability, absorption etc. The number of glue sites 13 per area unit should amount to between 25 and 350000 glue sites per m², preferably between 300 and 180000 glue sites per m² and more preferably between 800 and 50000 glue sites per m². The size of each glue site 13 should amount to between 0.15 and 150mm², preferably between 0.5 and 100mm² and more preferably between 1 and 15 mm².

In the case of large glue sites 13 screened patterns can be used, which means that each glue pattern unit is built up of a plurality of small screen dots. The size of the glue site in this case is defined as the circumscribed area of the combination of screen dots forming a glue pattern unit.

Preferred glues are the ones commonly used for paper, such as carboxy methyl cellulose (CMC), polyvinyl alcohol (PVOH), ethylene vinyl acetate (EVA), polyvinyl acetate (PVAc), ethylene acrylic acid, vinyl acetate acrylic acid, styrene acrylic acid, polyurethane, polyvinylidene chloride, starch, chemically modified starch, dextrine, water soluble polymers such as latexes and milky colloids in which natural or synthetic rubber or plastic is suspended in water. In case the material webs are of other material than paper glues suited for these materials are of course chosen.

It is preferred that glues having a relatively high dry content are used, since this enables a distinct positioning of the glue sites.

Coloured glues may also be used, which give a visual effect and therewith a patterning effect to the material.

The printing pattern provided by the printing roll 15 will appear on the inside of the laminated multiply product, and will be visible through the plies, in case the printing pattern is a coloured pattern.

In case the printing pattern is a surfactant, a skin care agent or other functional chemical it may be of advantage to have the chemical substance on the inside of the laminated product, so that it is protected during the converting process and before use and becomes active only after wetting of the paper.

A second printing roll 16 is arranged after the lamination roll 10 for printing on the outside of the second web shaped material 8. This second printing unit may also be a flexographic printing device or any optional printing device adapted to print a colorant, a surfactant, a skin care agent or other functional chemical on paper or nonwoven. The second web shaped flexible material 8 is printed while residing on the central impression roll 7 and the printing roll 16 is driven in register with the glue transfer roll 5, the lamination roll 10 and the first printing roll 15. The second printing pattern is printed on the outside of the second web shaped material 8 and may or may not overlap with the glue pattern and/or the first printing pattern. It may further be printed on top of the glue pattern. In case the printing pattern is a surfactant, a skin care agent or other functional chemical it may for some applications be advantageous to have the active substance on the outside of the laminated product, so that it is active also without wetting the product.

In alternative embodiments of the invention only one printing roll is provided, wherein either the first or the second printing roll 15 or 16 is eliminated. In further embodiments two or more printing rolls may be provided, which print two or more patterns in subsequent steps on said first web shaped flexible material 1 before it is laminated to the second web shaped flexible material 8. Said patterns are printed in register with each other. In still further embodiments two or more printing rolls may be provided, which print in subsequent steps on said second web shaped flexible material 8 after lamination to the first web shaped flexible material 1, said patterns being printed in register with each. The lamination roll 10 may further act as a printing roll carrying a colorant, a skin care agent or other functional chemical in a selected pattern, which is printed on the outside of the laminated product. This is shown in the embodiment of Fig. 2.

Thus it is understood that the invention provides a plurality of possibilities to create coloured printing patterns, combinations of different, coloured printing patterns, patterns of different kinds of functional chemicals, such as surfactants, skin treating agents etc. and combinations of coloured printing patterns and patterns of functional chemicals. In case a coloured glue is used, the glue pattern also contributes to the patterning effect of the product.

Fig. 3 shows an example of a multiply web 17 made with a device according to the device shown in Fig. 1. The glue pattern 12 is in the form of groups of three dots 13 arranged in a triangular configuration. The glue pattern may be coloured or colourless, so that it either does or does not form part of the patterning effect of the multiply web. A first printed pattern 18 in the form of a figurative pattern is printed on the inside of the multiply web and visible through the plies. It is preferred that said first printed pattern 18 looks good from both sides of the multiply web. A second printed figurative pattern 19 in the form of a logotype is provided on the outside of the multiply web.

Fig. 2 shows a modified embodiment of a device for making a multi-ply product according to the invention. The first paper web 1 is printed by a printing roll 15, carrying a colorant, a skin care agent or other functional chemical in selected pattern. In a next step glue is transferred to the first paper web 1 by a glue transfer roll 5 transferring glue to the web 1 in a selected glue pattern. The second paper web 8 is laminated to the first paper web by the lamination roll 10 having a pattern of protuberances corresponding to the glue pattern and driven in register with the glue transfer roll 5. The lamination roll 10 in this embodiment is also acting as a printing roll, such as a flexographic printing device or any optional printing device adapted to print on paper or nonwoven. Thus the combined printing/lamination roll 10 prints a printing pattern on the outside of the laminated multi-ply product 17. In the embodiment shown this printing pattern is identical to and printed on the second paper web 8 on top of the glue pattern on the first paper web 1 provided by the glue transfer roll 5. It is also understood that the printing pattern provided by the combined printing/lamination roll 10 may be different from the glue pattern as described in connection with the embodiment of Fig. 1 as long as it covers the glue pattern and thus provides a lamination of the plies.

In case a coloured glue is used for providing the glue pattern, the glue pattern will also form a visible printing pattern which can be seen from the outside of the multiply product. Further if different colours are used for the coloured glue and for the identical printing pattern provided by the combined printing/lamination roll 10 respectively, the latter being applied on the outside of the multiply product, a "two- sided" product will be provided. This means that the product will look different from different sides, since from one side more or less only the coloured glue pattern 20 will be visible, while from the opposite side more or less only the identical printing pattern 21 will be visible. This is illustrated in Fig. 4. The first printing pattern provided by the first printing roll 15, for example a decorative figure, is denoted 18.

A two-sided product may be desirable in cases where the opposite sides of the product have different properties, for example one soft, smooth and absorbent side and one side for example having a more rough surface adapted for cleaning and/or a surface having a three-dimensional structure suited for wiping viscous fluids.

The paper webs 1 and 8 that are laminated can be either smooth but also have a three-dimensional structure provided earlier in the process, for example during forming, dewatering and/or drying of the paper web. A three-dimensional structure may also be provided by embossing the dry paper webs before lamination. The method according to the invention is very lenient to such a pattern, so that this is maintained substantially intact throughout the laminating process. The paper webs 1 and 8 laminated together may be of the same or different type. For example, as explained above, a two-sided product may be provided where different sides of the multiply product have different properties.

Another important advantage of the invention is that the paper substantially maintains its strength properties through the process, which in many other lamination processes, in which an embossing and deformation of the paper webs occur in connection with lamination, are decreased. Because of the substantially smooth structure of the laminated multiply product this can be converted into dense rolls or folded products, which means space- and cost saving.

The laminated multiply product may also if desired, due to the strong ply bonding provided by the glue spots, be embossed after the lamination process, thereby creating a softer material. Preferably a relatively dense embossing pattern having a relatively small embossing depth is used, for example a so called "micro quilted" embossing pattern, so as to not disturb the appearance of the printed pattern. It is also possible to use a macro embossing pattern.

Three or more paper plies may of course be laminated with the method described above. Two or more glue stations may therefore be provided, which are driven in register and/or two or more plies may enter the first and/or further press nips.

Different kind of paper with different properties with respect to absorption capacity, basis weight, manufacturing technique, fiber composition, chemical additives may be used in the different plies.

The method is further suitable to use for paper plies having holes therein, since the main part of the holes will be intact throughout the lamination process and not be filled with glue, which normally is the case when gluing the plies together.

Claims

1. Method for producing a multi-ply web (17) of flexible material, such as paper and nonwoven material, by means of gluing the plies, bringing a patterned glue transfer roll (5), having a pattern of protuberances (6), in contact with a glue application device (4), transferring glue to a first web shaped flexible material (1) in a glue pattern corresponding to the configuration of the protuberances (6), a second web shaped flexible material (8) being brought in contact with the glue applied side of said first web shaped flexible material (1) in a press nip between a patterned lamination roll (10) and an impression roll (7), said lamination roll (10) having a pattern of protuberances (11) corresponding to said glue pattern, the glue transfer roll (5) and the lamination roll (10) being in register with each other, so that the first and second web shaped flexible materials (1,8) are combined and glued together in a pattern corresponding to the configuration of the protuberances (6) of the glue transfer roll (5), cha racterized i n that the first web shaped flexible material (1) and/or the second web shaped flexible material (8) is printed by a printing roll (10; 15; 16) carrying a colorant, a surfactant, a skin care agent or other functional chemical in a selected pattern, said printing is performed in register with the glue transfer while the first and/or second web shaped flexible materials are residing on said impression roll (7).

2. Method as claimed in claim 1, characterized in that said first web shaped flexible material (1) is printed before it is laminated to the second web shaped flexible material (8), wherein the printed pattern is printed on the inner side of the first web shaped flexible material (1), i.e. the side facing the second web shaped flexible material (8).

3. Method as claimed in claim 2, cha racterized i n that two or more patterns are printed in subsequent steps on said first web shaped flexible material (1) before it is laminated to the second web shaped flexible material (8), said patterns being printed in register with each other and with the glue pattern.

4. Method as claimed in claim 1, cha racterized in that said second web shaped flexible material (8) is printed after or simultaneously with the lamination to the first web shaped flexible material (1), wherein the printed pattern is printed on the outside of the second web shaped flexible material (8).

5. Method as claimed in claim 4, characterized in that two or more patterns are printed in subsequent steps on said second web shaped flexible material (8) after or simultaneously with the lamination to the first web shaped flexible material (1), said patterns being printed in register with each other and with the glue pattern.

6. Method as claimed in any of claims 2-5, characterized i n that at least two printing stations are provided, wherein at least one first printing station (15) prints at least one first pattern (18) on the first web shaped flexible material (1) before it is laminated to the second web shaped flexible material (8), and at least one second printing station (16; 10) prints at least one second pattern (19;

21) on the second web shaped flexible material after lamination to the first web shaped flexible material (1).

7. Method as claimed in claim 6, cha racterized in that one of said printing stations (15; 16; 10) prints a pattern of a colorant and the other of said printing stations (15; 16; 10) prints a pattern of a surfactant, skin care agent or other functional chemical.

8. Method as claimed in any of the preceding claims, cha racterized in that the glue is a coloured glue, wherein said coloured glue pattern will appear as a printed pattern.

9. Method as claimed in claim 8, cha racterized i n that a printing pattern (21) is the same as and printed on the next web shaped flexible material just on top of a coloured glue pattern (20) on the underlying web.

10. Method as claimed in claim 9, cha racterized i n that said printing pattern (21) and said glue pattern (20) are of different colour.

11. Method as claimed in claim 6, cha racterized i n that the two printing patterns (18; 19) are different.

12. Method as claimed in claim 8, cha racterized i n that the coloured glue pattern and the printing pattern(s) are different.

13. Method as claimed in any of the preceding claims, cha racterized i n that the size of each glue site (13) amounts to between 0.15 and 150 mm², preferably between 0.5 and 100 mm² and more preferably between 1 and 15 mm².

14. Method as claimed in any of the preceding claims, cha racterized in that the number of glue sites (13) per unit area amounts to between 25 per m²to 150 per cm², preferably between 300 per m²to 50 per cm² and more preferably between 800 per m²to 20 per cm².

15. Method as claimed in any of the preceding claims, cha racterized in that the pattern configuration of the glue transfer roll (5) is chosen so that glue is applied to said first ply (1) in glue sites (13) covering an area corresponding to between 0.03 and 9%, preferably between 0.1 and 6%, of the total area of the first web shaped flexible material (1) and sparsely distributed over substantially the entire area of the first web shaped flexible material (1).

16. Method as claimed in any of the preceding claims, characterized i n that at least one of the plies (1; 8) before lamination with the opposite ply is exerted to a three dimensional patterning provided on the ply while wet, during drying of the wet ply and/or in dry state.

17. Method as claimed in any of the preceding claims, characterized i n that the multi-ply web after lamination is embossed.

18. Method as claimed in any of the preceding claims, characterized in that any of said web shaped flexible materials (1; 8) comprises one or more plies of flexible material.

19. Multi-ply web (17) of flexible material, such a paper and nonwoven, comprising at least one first (1) and one second ply (8) which are interconnected by gluing in a plurality of discrete glue sites (13), cha racterized in that the web is printed with at least one printing pattern (18,19; 21,22) comprised of a colorant, a surfactant, a skin care agent or other functional chemical, said printing pattern is in register with the glue pattern (12; 20).

20. Multi-ply web as claimed in claim 19, cha racterized in that at least one printing pattern (18; 22) is printed on the inner side of at least one ply (1).

21. Multi-ply web as claimed in claim 19, cha racterized i n that at least one printing pattern (18; 22) is printed on the inner side of at least one ply (8) and is visible from the outside of the multi-ply web.

22. Multi-ply web as claimed in 20 and 21, cha racterized i n that at least one printing pattern (18; 22) is printed on the inner side of at least one ply (1) and at least one printing pattern (19; 21) is printed on the outer side of at least one ply (8).

23. Multi-ply web as claimed in any of claims 19-22, cha racterized in that the glue in the glue sites (13) is coloured and thus appears as a printed pattern which is visible from the outer side of the multi-ply web.

24. Multi-ply web as claimed in claim 23, cha racterized i n that the coloured glue pattern (20) and at least one printing pattern (21) are the same and are located just opposite each other.

25. Multi-ply web as claimed in claim 24, characterized i n that the coloured glue pattern (20) and the at least one printing pattern (21) comprises a colorant of a different colour as compared to the glue pattern, so that the multi-ply web will have a two-sided appearance with different colours appearing on opposite sides.

26. Multi-ply web as claimed in claim 22, cha racterized i n that the two printing patterns (18; 19; 21; 22) are different.

27. Method as claimed in claim 23 or 24, cha racterized i n that the coloured glue pattern and the printing pattern(s) are different.

28. Multi-ply web as claimed in any of claim 19-27, cha racterized in that the first and second plies (1; 8) have different properties.

29. Multi-ply web as claimed in any of claims 19-28, cha racterized i n that the glue sites (13) take up a total area of between 0.03 and 9%, preferably between 0.1 and 6%, of the total surface area of the respective ply (1;8).

30. Multi-ply web as claimed in any of claims 19-29, cha racterized in that the size of each glue site (13) amounts to between 0.15 and 150 mm², preferably between 0.5 and 100mm² and more preferably between 1 and 15 mm²

31. Multi-ply web as claimed in any of claims 19-30, characterized in that at least one of the plies (1;8) has a three-dimensional pattern provided before joining with the opposite ply.

32. Multi-ply web as claimed in any of claims 19-31, characterized i n that the multi-ply web is embossed.

33. Multi-ply web as claimed in any of claims 19-32, characterized in that at least one of the plies (1;8) has holes therein.