WO2004035441A1 - Method for producing logs of web material and rewinding machine implementing said method - Google Patents
Method for producing logs of web material and rewinding machine implementing said method Download PDFInfo
- Publication number
- WO2004035441A1 WO2004035441A1 PCT/IT2003/000624 IT0300624W WO2004035441A1 WO 2004035441 A1 WO2004035441 A1 WO 2004035441A1 IT 0300624 W IT0300624 W IT 0300624W WO 2004035441 A1 WO2004035441 A1 WO 2004035441A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- winding
- web material
- core
- glue
- log
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H19/00—Changing the web roll
- B65H19/22—Changing the web roll in winding mechanisms or in connection with winding operations
- B65H19/28—Attaching the leading end of the web to the replacement web-roll core or spindle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H19/00—Changing the web roll
- B65H19/22—Changing the web roll in winding mechanisms or in connection with winding operations
- B65H19/2238—The web roll being driven by a winding mechanism of the nip or tangential drive type
- B65H19/2269—Cradle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H19/00—Changing the web roll
- B65H19/22—Changing the web roll in winding mechanisms or in connection with winding operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H19/00—Changing the web roll
- B65H19/22—Changing the web roll in winding mechanisms or in connection with winding operations
- B65H19/28—Attaching the leading end of the web to the replacement web-roll core or spindle
- B65H19/283—Attaching the leading end of the web to the replacement web-roll core or spindle by applying adhesive to the core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H19/00—Changing the web roll
- B65H19/22—Changing the web roll in winding mechanisms or in connection with winding operations
- B65H19/29—Securing the trailing end of the wound web to the web roll
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2301/00—Handling processes for sheets or webs
- B65H2301/40—Type of handling process
- B65H2301/41—Winding, unwinding
- B65H2301/414—Winding
- B65H2301/41419—Starting winding process
- B65H2301/41424—Starting winding process involving use of glue
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2301/00—Handling processes for sheets or webs
- B65H2301/40—Type of handling process
- B65H2301/41—Winding, unwinding
- B65H2301/417—Handling or changing web rolls
- B65H2301/418—Changing web roll
- B65H2301/4181—Core or mandrel supply
- B65H2301/41812—Core or mandrel supply by conveyor belt or chain running in closed loop
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2301/00—Handling processes for sheets or webs
- B65H2301/40—Type of handling process
- B65H2301/41—Winding, unwinding
- B65H2301/417—Handling or changing web rolls
- B65H2301/418—Changing web roll
- B65H2301/4181—Core or mandrel supply
- B65H2301/41814—Core or mandrel supply by container storing cores and feeding through wedge-shaped slot or elongated channel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2408/00—Specific machines
- B65H2408/20—Specific machines for handling web(s)
- B65H2408/23—Winding machines
- B65H2408/235—Cradles
Definitions
- the present invention relates to a method for producing logs of web material, for example rolls of toilet tissue, kitchen towels or the like.
- the invention also relates to a rewinding or winding machine for forming logs destined to produce small rolls of wound web material.
- a web material is unwound from one or more parent reels of large diameter, coming directly from the paper mill, and predetermined quantities of web material are rewound on tubular winding cores to obtain logs of a length equivalent to the length of the parent reel but with a minor diameter, equivalent to the diameter of the final product. These logs are subsequently cut crosswise to their axis to produce rolls or small rolls of web material destined to be packaged and distributed.
- the initial free end of the web material must be glued to adhere to the external surface of the log and thereby allow subsequent handling, without the risk of accidentally unwinding the web material.
- the rewinding machines currently used wind the logs, which are then conveyed to a gluing unit that glues the final free end of the web material.
- the individual logs are partially unwound and positioned to apply the glue to the unwound free end or to a portion of the cylindrical surface of the log that is subsequently covered with the final free end of the material by rewinding it.
- gluing units to seal the final end of a web material forming a log are described in US-A-5242525, EP-A-0481929, US-A-3393105, US-A-3553055, EP-A-0699168.
- rewinding machines of the so called peripheral type are preferably used, in which the log being formed is made to rotate through contact with a plurality of motor-driven winding rollers, a plurality of belts or with combined systems of belts and rollers. Examples of rewinding machines of this type are described in WO-A-9421545, US-A-4487377, GB-B-2150536 and others.
- US-A-4487377 describes a method that makes the use of a gluing unit downstream of the rewinding machine unnecessary.
- the web material is cut upon termination of winding a log and the final end of the web material of the completed log is glued after cutting by transferring to it a glue previously dis- tributed in annular strips on the tubular winding core introduced into the winding area.
- the glue applied to the tubular core also serves to start winding the new log.
- This system makes it possible to eliminate the gluer, although it requires a particular configuration of the rewinding machine, with a cutting blade disposed so as to cooperate cyclically with the winding roller. With a layout of this type it is not possible to attain the performances currently required of these machines in terms of production speed and production flexibility.
- WO-A-9732804 describes a rewinding machine with a gluing unit incorporated. Nonetheless, owing to the design and layout of the gluing unit, this rewinding machine is only capable of reaching relatively low winding speeds. Moreover, even if the winding elements and the gluing elements are incorporated in the same machine, it still has a gluing unit which is separated in respect of to the elements to wind the web material on the previously glued tubular cores.
- WO-0164563 describes a rewinder wherein, upon termination of winding a log, a first glue is applied to the web material to seal the free end of the formed log. A second glue is applied to the new winding core before it is introduced into the machine.
- the object of the present invention is to provide a method for producing logs of wound web material, that makes it possible to glue the final end of the rolls or logs, without requiring a gluing unit downstream of the rewinding machine or incorporated in it, and which makes it possible to obtain a high level of precision in applying the glue to the web material to seal it.
- a further object of the present invention is to provide a method that makes it possible to attain high performances in terms of pro- duction flexibility.
- a further object of the present invention is to produce a rewinding machine that makes it possible, reaching adequate production speeds, to avoid the use of a gluing unit downstream of the rewinding machine, performing the operations to glue the final end of the log formed inside the rewinding machine, without requiring spe- cific gluing elements.
- the invention is based on a method per se known and described in US-A- 4487377. This method includes the following phases:
- the glue is transferred from the winding core to the web material before the web material is severed to produce the final free end of the completed log and the initial free end of the new log to be wound.
- the method is characterized by:
- the glue may be applied to the tubular winding cores in annular bands. Nonetheless, according to a preferred embodiment of the invention, the glue is applied along at least a longitudinal band, i.e. parallel to the axis of the tubular winding core.
- This longitudinal band may be suitably broken to prevent the glue applied from soiling the mechanical elements of the rewinding machine.
- this surface may be designed in the form of a comb, i.e. with an arrangement of elements parallel to and spaced apart from one another.
- the longitudinal band of glue applied to the core will be broken in areas corresponding to the position in which the core comes into contact with these supporting elements forming the rolling surface.
- two longitudinal bands are ap- plied to the core, one destined to be transferred to the final free end of the completed log to seal it and the other destined to secure the initial free end of the web material to the new core.
- the two bands may be formed by glues with different characteristics, optimized for the two different functions.
- the tubular core is introduced into the channel formed by the winding element and by the rolling surface in an angular position, such that the longitudinal band of glue applied to the tubular core is far from the contact area of the core with the web material fed around the winding element.
- the tubular core starts to roll in the channel in contact with the web material fed around the winding element and the rolling surface for a sufficiently wide angle before the band of glue comes into contact with the web material.
- the web material may be tensioned through acceleration of a winding roller downstream of the area in which the tubular core is introduced, to prepare the web material for subsequent severing. Severing is obtained by exceeding the limit of tensile strength of the web material at the level of a perforation line provided on it.
- This sev- ering occurs when the core is rolled for an angle greater than the one required to bring the longitudinal band of glue into contact a first time with the web material to deposit a fraction of the glue on the web material.
- Severing takes place along a perforation line located between the band of glue transferred to the web material and the i core, before the band of glue on the core comes into contact for a second time with the web material.
- the glue transferred to the web material is extremely near the line along which the web material is severed. Acceleration of the winding roller to obtain tensioning can also start after the glue has been transferred to the web material. The moment in which tensioning starts depends on the gradient of acceleration and on the characteristics of resistance and elasticity of the web material.
- the invention also relates to a peripheral rewinding machine of the automatic and continuous type, i.e. in which the web material is fed continuously at an essentially constant speed and the logs formed are automatically unloaded to be replaced by new tubular winding cores. More specifically, the invention relates to a peripheral rewinding machine of this type comprising:
- introduction of the winding core and operation of the means to sever the web material are coordinated so that the web material is severed in an area upstream, in respect of the direction of feed of the web material, of an area in which said winding core transferred part of the glue applied to it to the web material.
- Figures 1 to 6 schematically show the. principal elements of the rewinding machine in an operating sequence in the exchange phase, wherein the finished log is unloaded, a new winding core is introduced and winding of a new log starts;
- Figures7 and 8 show two alternative embodiments of the invention.
- Detailed description of the preferred embodiment of the invention Figure 1 shows the principal elements of the rewinding machine, the description of which shall be restricted to the description required to understand the present invention.
- the rewinding machine indicated as a whole with 1, comprises a first winding roller 1, rotating around an axis 1A, a second winding roller 3, rotating around a second axis 3 A parallel to the axis 1A, and a third winding roller 5, rotating around an axis 5 A parallel to the axes 1 A and 3 A and moving around an axis 7 of oscillation, around which oscillating arms 9 to support the winding roller 5 are supported.
- the three winding rollers 1, 3 and 5 define a winding cradle 11 inside which, in the position shown in Figure 1, a first log LI of web material is found in the final wind- ing phase.
- a nip 6 is defined between the winding rollers 1 and 3 through which the web material N passes and is wound around to form the log LI.
- the web material N is fed around the first winding roller 1 and, before reaching it, through a perforator unit 13 that perforates the web material N along perforation lines equidistant and substan- tially orthogonal to the direction of feed of the web material. In this way the web material N wound on the log LI is divided into sheets that can be separated individually by being torn by the final user.
- the rolling surface 15 is formed by a series of strips parallel to and spaced apart from one another, one of which is shown in the drawing and indicated with 17, the others being superimposed on it.
- the strips 17 terminate with a narrow portion that is introduced into annular channels 3B of the second winding roller 3.
- the layout is analogous to the one described in WO-A-9421545, the content of which may be referred to for greater de- tails concerning the construction of these rolling surfaces.
- the rolling surface 15 forms, with the external cylindrical surface of the winding roller 1, a channel 19 to introduce the tubular winding cores.
- the channel 19 extends from an inlet area 21 to the nip 6 between the winding rollers 1 and 3. It has a height, in a radial direction, equal to or slightly below the diameter of the tubular winding cores, which must be sequentially introduced into the winding area in the manner described below.
- the tubular winding cores are taken to the inlet 21 of the channel 19 by a conveyor 23 comprising two or more flexible elements parallel with one another and equipped with pushers 25 that collect each single tubular winding core A (Al, A2, A3, A4) from a hopper above 27.
- a glue dispenser indicated as a whole with 29, comprising a tank of glue 31, inside which a moving gluing element 33 oscillating around an axis 35 orthogonal to the plane of the figure is immersed.
- the gluing element 33 alternatively adopts a first position (shown with a dashed line in Figure 1), wherein it is immersed in the glue contained in the tank 31, and a raised position, shown with a solid line in Figure 1, wherein it touches the tubular winding core in the lowest position in the core unloading channel under the hopper 27, that is core A4 in the figure.
- the gluing element 33 has a rim; equipped with an upward facing groove if needed, on which the glue is collected to be applied along a corresponding longitudinal band on each single core unloaded from the hopper 27 onto the conveyor 23 below, before being transferred with a movement according to the arrow fA towards the winding area. It must be understood that other conveying and gluing systems may be used to convey the tubular winding cores an4 to apply glue to them, preferably along longitudinal lines, that is parallel to the axis of said cores.
- tubular winding cores A2 and A3 are already equipped with a longitudinal band of glue, indicated with C.
- This band may be broken in positions corresponding to the positions in which the strips 17 are disposed, so that the longitudinal edge of the gluing element 33 has a series of breaks distributed appropriately along its extension.
- the tubular winding core A2 is in proximity to the inlet 21 of the channel 19 and is held there by an elastic strip 37. It will be introduced at an appropriate moment into the channel 19 and will start to roll on the rolling surface 15 through the effect of contact with the web material N fed around the winding roller 1. Introduction is ob- - o -
- the rewinding machine summarily described hereinbefore operates as fol- lows.
- Figure 1 shows a roll or log LI in the terminal phase of winding onto a tubular winding core Al.
- the tubular winding core A2 equipped with the band of glue C, is at the inlet 21 of the channel ready to be introduced into the winding area.
- the web material N advances according to the arrow fN from the perforator 13 to the winding roller 1 until reaching the winding cradle 11 where it is wound around the log L 1.
- Figure 2 shows the phase to introduce the tubular core A2 into the channel 19. It is forced into the channel to come into contact with the web material N, pressing it against the cylindrical surface of the first winding roller 1, and with the rolling sur- face 15. Upstream of the contact point between the web material and the tubular core A2 the position of the perforation line P along which the web material will be severed in the manner described below is shown.
- the log LI continues to be wound in the winding cradle 11.
- Introduction of the core is suitably synchronized with the position of the perforation line along which the web material must subsequently be sev- ered.
- the longitudinal band of glue C is again in a position more or less diametrically opposite in relation to the contact area between the tubular winding core A2 and the web material N fed around the winding core 1.
- the portion of glue transferred from the tubular winding core A2 to an area of the web material N is indicated with Cl.
- the third winding roller 5 as been accelerated and, if necessary, the second winding roller 3 has been decelerated. Consequently, the log LI in the completion phase starts to move away from the first winding roller 1 and gets ready to be unloaded onto an unloading surface 12. Acceleration of the upper moving winding roller 5 also causes tensioning of the web material N in the area between the log LI and the point in which the material is pinched between the winding roller 1 and the tubular winding core A2. This occurs because the speed at which the web material N is fed to the winding roller 1 and the peripheral speed of the latter remain constant, while the speed of the contact point between the log LI and the winding roller 5 increases.
- This perforation line is disposed between the log LI and the point in which the web material is pinched between the tubular winding core A2 and the first winding roller 1.
- the position of this perforation line may be adequately and precisely controlled in a per se known way.
- Figure '5 shows a moment successive to severing the web material N.
- This severing produces a free tail end Lf, which will finish winding around the log LI, and a free leading end Li which will start winding around the new tubular winding core A2.
- the free tail end Lf is produced in close proximity to the band Cl of glue that the tubular core A2 has transferred to the web material N wound around the log LI.
- the free leading end Li will start to wind around the tubular core A2 through the web material being secured to the tubular core by the residual glue of the longitudinal band of glue C.
- Figure 6 shows a subsequent phase of the winding cycle, wherein the completed log LI is unloaded onto the unloading surface 12, while the tubular winding core A2 is in the winding cradle 11 and a certain quantity of web material has started to be wound around it to form the initial part of a new log indicated with L2.
- the winding roller 5 with moving axis After oscillating upwards to allow unloading of the completed log LI, the winding roller 5 with moving axis returns to the low position and is once again in contact with the new log L2 being formed.
- the conveyor 23 has advanced by one step to take the tubular winding core A3 to the position previously occupied by the tubular winding core A2 ( Figure 1).
- the peripheral speed of the winding rollers 3 and 5 has returned to the nominal value more or less equivalent to the peripheral speed of the winding roller 1. In this position the machine is ready to start a new exchange cycle when the log L2 is completed and the winding core A3 will be introduced into the feed channel 19 in the same way described hereinbefore.
- the figures described hereinbefore show an example of embodiment wherein a single longitudinal band of glue is applied to the tubular core.
- the quantity of glue C is sufficient to wet the free tail end of the formed log and the free leading end destined to be secured to the new tubular core.
- two longitudinal bands of glue may be applied to the same core in two different angular positions, one destined to glue the free tail end of the completed log and the other to secure the free leading end to the new core.
- two different glues may be used for the two bands, taking into consideration the different gluing requirements. While the final free end of the log requires light gluing, the initial free end must adhere efficiently and rapidly to the new core.
- Figure 7 shows a first embodiment of the machine that allows two bands of glue to be applied in two different angular positions using different glues.
- two gluing elements 33 A and 33B are provided immersed in two separate tanks containing two different glues.
- the core When the core is in the gluing position, it receives two bands Cc and C T of glue of different qualities in different angular positions.
- the glue Cc is destined to glue the free tail end or tail edge of the completed log, while the glue CT is destined to glue the free leading end to the new core.
- each core Before each core is introduced into the channel 19 formed between the roller 1 and the rolling surface 15 it is made to rotate through more or less 180°, for exam- pie by a belt 34 disposed in a suitable position along the core introduction path. In this way, as shown schematically in Figure 7, the core is fed into the channel 19 in an angular position that brings the core and the web material into contact in the portion of cylindrical surface lying between the bands C T e Cc.
- the band of glue Cc first touches the web material N and - li ⁇
- the glue is transferred to an area adjacent to the line along which the material is severed, but downstream of said line.
- the core continues to roll and the material is severed as described hereinbefore, but the free leading end that must be secured to the core A is glued by the band of glue C T that touches the web material after severing and after the core has rotated for slightly less than one complete turn.
- Figure 8 shows an embodiment modified in relation to the one in Figure 7 and wherein the tubular core is not rotated through 180° after the glue is applied.
- the reciprocal position of the bands Cc and C is inverted so that the first band to touch the web material is again the band Cc.
- Less time is available to perform severing of the web material than in the previous case, as the second band of glue C T touches the web material after a relatively small angle of rotation of the tubular core.
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- Replacement Of Web Rolls (AREA)
- Making Paper Articles (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/531,455 US7350739B2 (en) | 2002-10-16 | 2003-10-14 | Method for producing logs of web material and rewinding machine implementing said method |
AU2003279549A AU2003279549A1 (en) | 2002-10-16 | 2003-10-14 | Method for producing logs of web material and rewinding machine implementing said method |
JP2004544689A JP4452623B2 (en) | 2002-10-16 | 2003-10-14 | Web material log manufacturing method and unwinder performing said method |
DE60317813T DE60317813T2 (en) | 2002-10-16 | 2003-10-14 | METHOD OF MANUFACTURING RAIL MATERIAL ROLLERS AND A WRAPPING MACHINE CONNECTING THE METHOD |
EP03772657A EP1551740B1 (en) | 2002-10-16 | 2003-10-14 | Method for producing logs of web material and rewinding machine implementing said method |
BRPI0315331-2A BR0315331B1 (en) | 2002-10-16 | 2003-10-14 | Method for producing coils of continuous sheet material and rewinding machine by implementing said method. |
CA2501185A CA2501185C (en) | 2002-10-16 | 2003-10-14 | Method for producing logs of web material and rewinding machine implementing said method |
KR1020057006397A KR101116077B1 (en) | 2002-10-16 | 2003-10-14 | Method for producting logs of web material and rewinding machine implementing said mehtod |
ZA2005/02540A ZA200502540B (en) | 2002-10-16 | 2005-03-30 | Method for producing logs of web material and rewinding machine implementing said method |
IL168014A IL168014A (en) | 2002-10-16 | 2005-04-13 | Method for producing logs of web material and rewinding machine implementing said method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITFI2002A000194 | 2002-10-16 | ||
IT000194A ITFI20020194A1 (en) | 2002-10-16 | 2002-10-16 | METHOD FOR THE PRODUCTION OF ROLLS OF TAPE MATERIAL AND REWINDER MACHINE THAT IMPLEMENTS THAT METHOD |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004035441A1 true WO2004035441A1 (en) | 2004-04-29 |
Family
ID=32104758
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IT2003/000624 WO2004035441A1 (en) | 2002-10-16 | 2003-10-14 | Method for producing logs of web material and rewinding machine implementing said method |
Country Status (15)
Country | Link |
---|---|
US (1) | US7350739B2 (en) |
EP (1) | EP1551740B1 (en) |
JP (1) | JP4452623B2 (en) |
KR (1) | KR101116077B1 (en) |
CN (1) | CN100500534C (en) |
AU (1) | AU2003279549A1 (en) |
BR (1) | BR0315331B1 (en) |
CA (1) | CA2501185C (en) |
DE (1) | DE60317813T2 (en) |
ES (1) | ES2295659T3 (en) |
IL (1) | IL168014A (en) |
IT (1) | ITFI20020194A1 (en) |
RU (1) | RU2326044C2 (en) |
WO (1) | WO2004035441A1 (en) |
ZA (1) | ZA200502540B (en) |
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EP1557386A1 (en) * | 2004-01-13 | 2005-07-27 | Andritz AG | Method and device for winding a paper web into a roll |
GR1004958B (en) * | 2002-12-03 | 2005-08-03 | Fabio Perini S.P.A. | An impppoved rewinder machine for the prodduction of rolls of web materail |
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EP1982939A1 (en) * | 2007-04-17 | 2008-10-22 | Chan Li Machinery Co., Ltd. | Web material winding machine |
US7494086B2 (en) | 2006-04-21 | 2009-02-24 | Chan Li Machinery Co., Ltd. | Web material winding machine |
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IT1393041B1 (en) * | 2009-03-04 | 2012-04-11 | Perini Fabio Spa | GLUE FOR ROLLS OF WRAPPED RIBBONS |
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Also Published As
Publication number | Publication date |
---|---|
KR101116077B1 (en) | 2012-02-13 |
DE60317813D1 (en) | 2008-01-10 |
BR0315331B1 (en) | 2013-02-05 |
KR20050074483A (en) | 2005-07-18 |
ZA200502540B (en) | 2005-11-30 |
DE60317813T2 (en) | 2008-03-13 |
IL168014A (en) | 2009-12-24 |
US7350739B2 (en) | 2008-04-01 |
CA2501185A1 (en) | 2004-04-29 |
BR0315331A (en) | 2005-08-16 |
EP1551740A1 (en) | 2005-07-13 |
CA2501185C (en) | 2012-06-26 |
JP4452623B2 (en) | 2010-04-21 |
RU2005114616A (en) | 2006-01-10 |
CN100500534C (en) | 2009-06-17 |
CN1705604A (en) | 2005-12-07 |
JP2006502931A (en) | 2006-01-26 |
RU2326044C2 (en) | 2008-06-10 |
EP1551740B1 (en) | 2007-11-28 |
ES2295659T3 (en) | 2008-04-16 |
AU2003279549A1 (en) | 2004-05-04 |
US20050258298A1 (en) | 2005-11-24 |
ITFI20020194A1 (en) | 2004-04-17 |
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