WO2004008929A1 - Sheet for cleaning human body by wiping - Google Patents

Sheet for cleaning human body by wiping Download PDF

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Publication number
WO2004008929A1
WO2004008929A1 PCT/JP2003/007424 JP0307424W WO2004008929A1 WO 2004008929 A1 WO2004008929 A1 WO 2004008929A1 JP 0307424 W JP0307424 W JP 0307424W WO 2004008929 A1 WO2004008929 A1 WO 2004008929A1
Authority
WO
WIPO (PCT)
Prior art keywords
sheet
wiping
weight
inner layer
water
Prior art date
Application number
PCT/JP2003/007424
Other languages
French (fr)
Japanese (ja)
Inventor
Hideo Sumitani
Mikio Suzuki
Fumiko Okuda
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2002210102A external-priority patent/JP4282282B2/en
Priority claimed from JP2002238889A external-priority patent/JP2004073529A/en
Priority claimed from JP2003113561A external-priority patent/JP4334263B2/en
Application filed by Kao Corporation filed Critical Kao Corporation
Priority to AU2003244112A priority Critical patent/AU2003244112A1/en
Publication of WO2004008929A1 publication Critical patent/WO2004008929A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K7/00Body washing or cleaning implements
    • A47K7/02Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements
    • A47K7/03Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements containing soap or other cleaning ingredients, e.g. impregnated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2432/00Cleaning articles, e.g. mops, wipes

Definitions

  • the present invention relates to a wet body wiping sheet.
  • the wiping sheet of the present invention is used after being heated to a predetermined temperature.
  • the present invention also relates to a hot wiping tool for wiping a surface to be wiped using the wiping sheet heated to a predetermined temperature. Further, the present invention relates to a thermal wiping method using the thermal wiping tool.
  • a body wiping sheet impregnated with an aqueous liquid is known.
  • the aqueous liquid remains on the body surface and the body temperature is increased by the heat of vaporization generated when the liquid evaporates. Is deprived and becomes a cold stimulus. This cold stimulus can cause the elderly and infants who have wiped their bodies to feel sick, especially in the cold winter months. Therefore, when using the cleaning sheet, the cleaning sheet is heated with a microwave oven or with a special heating device.
  • the present invention provides a body wiping sheet which is prevented from giving a cold stimulus due to vaporization of an impregnated liquid or a decrease in temperature when wiping the body by heating to a predetermined temperature. With the goal.
  • Another object of the present invention is to provide a hot wiping tool and a hot wiping method that can perform a wiping operation while maintaining a high temperature for a long time. Disclosure of the invention
  • the present invention comprises a sheet containing a water-absorbing polymer and impregnated with an aqueous cleaning agent, and the amount of the aqueous cleaning agent released under a load of 200 845 m2 is 0.0. 4 to 0.8 gZ500 cm 2 , which achieves the above object by providing a body wiping sheet to be heated and used.
  • the present invention also provides the wiping sheet, and a heat-resistant storage body in which the wiping sheet is stored in a substantially sealed state, wherein the wiping sheet is substantially sealed in the storage body.
  • An object of the present invention is to provide a thermal wiping tool which is heated to a predetermined temperature in a stored state.
  • the present invention provides the cleaning sheet, wherein the cleaning sheet is substantially tightly packed in a heat-resistant container.
  • the cleaning sheet is stored in a closed state, the cleaning sheet is heated to a predetermined temperature while being stored in the storage body, the heated cleaning sheet is taken out of the storage body, and the body is wiped with heat.
  • the present invention comprises a laminated sheet having at least a three-layer structure comprising an inner layer capable of holding an impregnation of an aqueous detergent and surface layers disposed on both sides of the inner layer, wherein a predetermined amount of the aqueous detergent is impregnated.
  • a body cleaning sheet
  • An object of the present invention is to provide a body wiping sheet to be used after being heated.
  • FIG. 1 is a perspective view showing one embodiment of the wiping sheet of the present invention.
  • FIG. 2 is a sectional view taken along line 11-11 in FIG.
  • FIG. 3 is a perspective view showing another embodiment of the body wiping sheet of the present invention.
  • FIG. 4 is a sectional view taken along line IV-IV in FIG.
  • FIG. 5 is a perspective view showing another embodiment of the wiping sheet shown in FIGS. 1 and 2.
  • FIG. 6 is a perspective view showing an embodiment of the thermal wiping tool of the present invention.
  • FIG. 7 is a schematic diagram showing a wiping sheet in each embodiment.
  • FIG. 1 is a perspective view of an embodiment of a body wiping sheet (hereinafter, also referred to as a wiping sheet) of the present invention
  • FIG. 2 is a sectional view taken along line II-11 in FIG. ing.
  • the wiping sheet 1 of the present embodiment has a rectangular shape, and includes an inner layer 2 and two surface layers 3, 3 disposed on both surfaces of the inner layer 2. It is composed of a laminated sheet having a layer structure.
  • the surface layer 3 has a larger dimension than the inner layer 2 and extends outward from the periphery of the inner layer 2.
  • Both the inner layer 2 and the surface layer 3 are composed of a fiber sheet.
  • the cleaning sheet 1 is a wet sheet impregnated with an aqueous cleaning agent for cleaning the body. Then wipe the sheet 1, in 2 0 0 0 g_ / 4 5 cm 2 of the luggage weight under released amount of the aqueous detergent 0. 0 4 ⁇ 0. 8 gZ 5 0 0 cm 2, preferably 0.1 00.7 g ⁇ 500 cm 2 , more preferably 0.2 00.6 gZ500 cm 2 .
  • the present inventors have conducted various studies on the cold stimulus (so-called cool sensation) when wiping the body using a wet sheet impregnated with an aqueous cleaning agent. if the amount of the agent is 0.
  • the reason why the load at the time of release of the aqueous cleaning agent was set to 2000 g / 45 cm 2 is that the area of the sheet for wiping the body is usually about 45 cm 2 (actual hand force).
  • Force is about 2000 g.
  • the specific method of measuring the release amount of the aqueous cleaning agent is as follows.
  • a high-performance form (1) TT—410 1 manufactured by INOATSU CORPORATION as the surface to be cleaned.
  • the reason why the high-performance foam (1) TT-4101 made by Inoatsu Corporation was adopted as the surface to be cleaned was that this form was used as the surface to be cleaned, This is because there was a correlation between the amount of cleaning agent released and the case where the arm was used as the surface to be cleaned.
  • the sheet constituting the surface layer 3 is controlled by controlling the material of the sheet, for example, by changing the mixing ratio of a hydrophilic fiber and a non-hydrophilic fiber (for example, a core-sheath composite fiber composed of a combination of polyethylene and polypropylene). Can be varied in degree of hydrophilicity. Specifically, hydrophilic When a large amount of conductive fiber is mixed, the surface layer 3 easily holds the aqueous detergent, and the aqueous detergent is easily released by pressure, so that the release amount increases.
  • the sheet constituting the inner layer 2 in the wiping sheet 1 preferably contains a water-absorbing polymer.
  • the inner layer 2 is preferably made of a fiber sheet containing particles of a water-absorbing polymer and a fiber material.
  • the amount of the aqueous detergent impregnated and, consequently, the amount of release can be controlled. Furthermore, since the water-absorbing polymer absorbs the water in the aqueous cleaning agent, the heat capacity of the wiping sheet 1 as a whole increases, and the temperature of the wiping sheet 1 decreases in a short time when heated to a predetermined temperature. Can be prevented. This also prevents a cold stimulus from being applied. As described above, in the present invention, by including the water-absorbing polymer in the wiping sheet, (1) the release amount of the aqueous cleaning agent is controlled and the cold stimulus is suppressed, and (2) the cleaning stimulus is suppressed.
  • the heat retention of the wipe sheet 1 is enhanced and the cold stimulus is suppressed.
  • the amount of the water-absorbing polymer contained in the wiping sheet 1, the amount of the aqueous detergent impregnated therein, and both The weight ratio is important.
  • the reason for setting the storage time to 3 minutes is that the wiping time by one wiping sheet 1 is about 3 minutes in relation to the total release amount of the aqueous cleaning solution.
  • the weight ratio of the water-absorbing polymer to the total weight of the wiping sheet 1 (the weight in the state in which the aqueous cleaning agent is impregnated) varies depending on the type of the water-absorbing polymer, but is from 0.0002 to 0.15. It is particularly preferably 0.04 to 0.11.
  • the ratio of the weight of the aqueous cleaning agent impregnated to the weight of the wiping sheet 1 before the aqueous cleaning agent is impregnated is preferably 2 to 15, particularly preferably 4 to 10.
  • the weight ratio of the water-absorbing polymer to the aqueous detergent (the former or the latter) is preferably from 0.002 to 0.15, particularly preferably from 0.007 to 0.11.
  • Inner layer 2 is in the shape of a strip.
  • the strip-shaped inner layer 2 has a ratio of the length to the width of 1 to 100, particularly about 5 to 40.
  • the width of the inner layer 2 is preferably 2 to 3 Omm, particularly 5 to 3 Omm, particularly preferably 10 to 3 Omm, from the viewpoint of the balance between the retention of the aqueous detergent and the sustained release.
  • the length of the inner layer 2 is shorter than the length of the surface layers 3, and the surface layers 3, 3 extend from the front and rear edges of the inner layer 2.
  • a plurality of inner layers 2 are used, and the inner layers 2 are arranged in one direction at predetermined intervals.
  • the spacing is about 1 to 30 mm, especially about 2 to 20 mm, and especially about 3 to 11 mm, so that the surface layers 3 and 3 can be easily joined together and the area of the inner layer 2 is sufficient. It is preferable from the viewpoint of securing.
  • the peripheral edge of each inner layer 2 is surrounded and continuously sealed by joining the two surface layers 3, 3 together. This prevents the swollen water-absorbing polymer from falling off the wiping sheet 1.
  • the sealing area of the two surface layers 3 is 3 to 95% of the area of the wiping sheet 1, particularly 5 to 80%, particularly 10 to 65%.
  • the surface layers 3 are joined to each other by, for example, heat fusion using heat sealing or adhesion using an adhesive.
  • the inner layer 2 and the surface layer 3 may be partially joined by embossing the sheet.
  • the wiping sheet 1 has on its surface a plurality of linear recesses 4 extending in one direction and reaching the periphery of the wiping sheet.
  • the longitudinal direction of each of the ridges 4 coincides with the longitudinal direction of the wet sheet 1.
  • Each concave ridge 4 extends in the same direction as the longitudinal direction of the inner layer 2.
  • the concave ridge portion 4 is located at the position of a joint portion 5 formed by directly joining the two surface layers 3, 3 except for the inner layer 2 in the laminated sheet, specifically, two surface layers 3, 3.
  • Each inner layer 2 is continuously surrounded by a joint 5 formed by direct joining of the two surface layers 3,3.
  • the concave stripes 4 are formed between the adjacent inner layers 2 and 2 and the concave stripes 4 are also formed on the peripheral edge of the cleaning sheet.
  • the concave ridges 4 formed between the adjacent inner layers 2, 2 have both ends reaching the periphery of the wiping sheet 1.
  • the formation of the concave ridges 4 improves the operability of wiping and the ability to prevent dripping.
  • the concave ridge portion 4 is formed by a step between a three-layer portion composed of the inner layer 2 and the two surface layers 3 in the laminated sheet and a two-layer portion composed of the two surface layers 3. Therefore, the depth of the concave ridge portion 4 can be appropriately increased or decreased by the thickness of the inner layer 2.
  • the thickness of the inner layer 2 can be extremely large due to the water-absorbing polymer swollen by the absorption of the aqueous detergent, and as a result, The depth can easily be increased.
  • the inner layer 2 is continuously surrounded by the joint 5 formed by the direct joining of the two surface layers 3,3. That is, each inner layer 2 is independently and independently held in a sleeve-like space formed by the two surface layers 3, 3. As a result, the cleaning sheet 1 Even if it is used to wipe the body, the inner layer 2 is less likely to break or break.
  • the wiping sheet 1 can be prevented from cooling down quickly, and further, the sustained-release property is improved, and a proper wet feeling is maintained.
  • the inner layer 2 and the surface layer 3 are bonded by heat embossing or the like so that even if a force is applied to the inner layer 2, the inner layer 2 is not broken. It may be possible to do so.
  • the water-absorbing polymer is contained in the inner layer 2, the water-absorbing polymer leaks from the hot embossed portion to the outside, or the water-absorbing polymer is fixed at the hot embossed portion and the absorption is inhibited.
  • the inner layer 2 is not bonded to the surface layer 3 and is kept free in the space formed by the surface layer 3 as in the present embodiment.
  • a laminated sheet before the aqueous detergent is impregnated (a sheet composed of the inner layer 2 and the surface layer 3).
  • the breaking strength of the inner layer 2 in a state where 800% by weight of water is impregnated in the laminated sheet with respect to the dry weight of the laminated sheet is preferably 400 cN / 20 mm or more, more preferably 500 c N / 20 mm or more.
  • the value of the breaking strength measured in the longitudinal direction of the inner layer 2, that is, the same direction as the extending direction of the concave ridge portion 4, is equal to or more than the above value.
  • the breaking strength is measured by the following method. The inner layer 2 is taken out of the impregnated cleaning sheet 1 and a test piece having a width of 2 Omm and a length of 8 Omm is cut out from the inner layer 2. Attach the test piece to the tensile tester with a distance of 50 mm between the chucks. The test piece is pulled at a speed of 300 mm / min, and the maximum load until it breaks is determined. The value is defined as the breaking strength.
  • the inner layer 2 is preferably made of a fiber sheet containing particles of a water-absorbing polymer and a fiber material.
  • Inner layer 2 is typically composed of non-woven fabric or paper. 20 times or more of its own weight as a water-absorbing polymer Those capable of absorbing and retaining the above liquid and gelling are preferred. Any shape, spherical, massive, grape-like, powdery or fibrous
  • polyacrylic acid and its salts include polyacrylic acid and its salts, and polyacrylic acid graft polymers, such as starch-crosslinking lipoxyl methylated cellulose, polymers or copolymers of acrylic acid or alkali metal acrylates, and the like. be able to. It is preferable to use hydrophilic fibers as the fiber material. Specific examples include wood pulp such as softwood kraft pulp and hardwood pulp, natural cellulose fiber such as cotton pulp and straw pulp, regenerated cellulose fiber such as rayon and cuvula, polyvinyl alcohol fiber and polyacrylonitrile fiber.
  • Examples include hydrophilic synthetic fibers, and synthetic fibers such as polyethylene fibers, polypropylene fibers, and polyester fibers that have been subjected to a hydrophilic treatment with a surfactant.
  • One or more fiber materials can be used.
  • the inner layer 2 contains a heat-fusible fiber so that the breaking strength of the inner layer 2 is not less than the above-mentioned value.
  • the blending amount of the heat-fusible fiber in the fiber composition of the inner layer 2 is 20 to 70% by weight, particularly 20 to 50% by weight, particularly 20 to 40% by weight, and the balance is hydrophilic.
  • the heat-fusible fibers include polyolefin resins such as polyethylene and polypropylene, polyester resins such as polyethylene terephthalate, acrylic resins such as polyacrylic acid and polymethacrylic acid, and vinyl resins such as polyvinyl chloride. Fibers made of resin, polyamide resin and the like are used. Further, among the above-mentioned various raw materials, a conjugate fiber (core-sheath type conjugate fiber or a side-by-side type conjugate fiber) composed of a combination of two kinds of resins can be used.
  • a conjugate fiber core-sheath type conjugate fiber or a side-by-side type conjugate fiber
  • the low melting point resin and the high melting point resin It is preferable to use a heat-fusible conjugate fiber in which the point resin forms at least a part of the fiber surface.
  • low-melting resin / high-melting resin combinations include high-density polyethylene polypropylene, low-density polyethylene polypropylene, polypropylene / ethylene / butene-1-1 crystalline copolymer, high-density polyethylene / polyethylene terephthalate, and nylon-6-nonylone. 66, low melting point polyester polyethylene terephthalate, polypropylene polyethylene terephthalate and the like.
  • the form of the heat-fusible conjugate fiber is parallel type, core-sheath type, eccentric sheath-core type, multilayer of three or more layers, hollow parallel type, middle-sheath core type, irregular-shaped sheath-core type, sea-island type, etc. It is sufficient that the resin has a structure in which at least a part of the fiber surface is formed.
  • Preferred among the heat-fusible conjugate fibers are low melting points such as high-density polyethylene, linear low-density polyethylene, ethylene, butene-1 crystalline copolymer, and copolymerized polyester of polyethylene terephthalate and polyethylene isophthalate.
  • thermoplastic resins selected from polyester is used as a low-melting resin
  • polypropylene or polyethylene terephthalate is used as a high-melting resin.
  • the fiber sheet constituting the inner layer 2 can be produced from the above-described materials as a raw material by a wet papermaking method, or various nonwoven fabric production methods such as an airlaid method, an air-through method, and a spunlace method.
  • an absorbent sheet described in Japanese Patent Application Laid-Open No. Hei 8-24639 or International Publication WO09 / 693923 can be used as the fiber sheet.
  • the weight ratio between the particles of the water-absorbing polymer and the fiber material in the fiber sheet constituting the inner layer 2 (the former / the latter) is 0.05 to 1.0, in particular, 0 :!
  • a value of 5 is preferable from the viewpoint of the heat retention performance of the water-absorbing polymer.
  • the basis weight of the water-absorbing polymer itself is preferably from 5 to 100 gm 2 , particularly preferably from 10 to 80 g / m 2 .
  • the basis weight of the fiber sheet constituting the inner layer 2, depending on the basis weight of the whole wiping sheet 1, 3 0 ⁇ 5 0 0 g / m , especially 6 0: is preferably 1 5 0 g Zm 2 .
  • the surface layer 3 is a rectangle whose length is slightly larger than the length of the inner layer 2 and whose width is several times to tens of times the width of the inner layer 2.
  • the surface layer 3 has the outer shape of the wiping sheet 1.
  • the surface layer 3 is preferably made of a fiber sheet containing hydrophilic fibers such as hydrophilic cellulose fibers.
  • the surface layer 3 is typically composed of a non-woven fabric.
  • hydrophilic cellulose fiber examples include regenerated cellulose fiber such as rayon and cuvula, wood pulp such as softwood kraft pulp and hardwood kraft pulp, and natural cellulose fiber such as cotton pulp and pulp pulp.
  • the fiber sheet constituting the surface layer 3 may be composed only of hydrophilic cellulose fibers, or may contain another fiber material.
  • the other fiber material for example, the same material as the heat-fusible fiber contained in the inner layer 2 can be used.
  • the fiber sheet constituting the surface layer 3 contains fibers other than the hydrophilic cellulose fiber, the other fibers are contained in an amount of 2 to 70% by weight, particularly, based on the weight of the surface layer 3 (dry basis). It is preferably contained in an amount of 30 to 60% by weight.
  • the hydrophilic cellulose fiber is preferably contained in an amount of 30 to 98% by weight, particularly preferably 40 to 70% by weight, based on the weight (dry basis) of the surface layer 3.
  • the fiber sheet constituting the surface layer 3 can be manufactured by various nonwoven fabric manufacturing methods such as a wet papermaking method, a spunless method and an airlaid method.
  • the basis weight of the fiber sheet constituting the surface layer 3 depends on the basis weight of the entire wiping sheet 1, but is 20 to each; L 0 g Zm 2 , particularly 30 to 70 g Zm 2 Is preferred.
  • the two surface layers 3 may be the same or different types.
  • the laminated sheet in which the inner layer 2 and the surface layer 3 are integrally laminated has a basis weight of 40 to 500 gZm 2 , particularly 70 to 400 gZm 2 . g / m 2 , especially 120 to 290 gZm 2 , is preferred from the viewpoint of the feel when holding the sheet in hand and the ease of wiping.
  • the basis weight of the cleaning sheet 1 after the laminated sheet is impregnated with the cleaning agent is 300 to 400 g / m 2 , particularly 500 to 300 g / m 2 , particularly 1 is preferably 0 0 0 ⁇ 1 5 0 0 g Zm 2.
  • the impregnation rate of the aqueous detergent with respect to the weight of the sheet before the impregnation with the aqueous detergent may be 200 to 150% by weight, particularly 400 to 100% by weight. preferable.
  • the aqueous cleaning agent contains water as a medium and contains cleaning components.
  • Various surfactants can be used as the cleaning component.
  • the surfactant any of anionic surfactants, nonionic surfactants, cationic surfactants and amphoteric surfactants can be used.
  • Alkylene oxide addition mole number 1 to 20 Alkyl (C8 to C22 linear or branched chain) Ether, Alkyl (C8 to C22 linear or branched chain) Glycoside (Average saccharide condensation Degree 1-5), sorbitan fatty acid (linear or branched chain having 8 to 22 carbon atoms), ester, and alkyl (linear or branched chain having 6 to 22 carbon atoms) nonionic activator such as glyceryl ether and alkyl Carboxy betaine, alkyl sulfo betaine, alkyl hydroxy sulfo betaine, alkyl amide carboxy betaine, alkyl amide sulfo betaine, alkyl amide An amphoteric surfactant having 8 to 24 alkyl carbon atoms, such as hydroxysulfobetaine, is preferably used.
  • the aqueous cleaning agent may remain inside, thereby indirectly contacting the food with the aqueous cleaning agent. May be From the viewpoint of safety in that case, the surfactant contained in the aqueous detergent is preferably a food additive.
  • the surfactant is preferably contained in the aqueous detergent in an amount of 0.01 to 30% by weight, particularly 0.05 to 2% by weight, from the viewpoint of exhibiting a sufficient cleaning effect. It is preferable that the aqueous detergent contains a water-soluble solvent having a boiling point of 100 ° C. or higher, particularly an alcohol.
  • the water-soluble solvent having a boiling point of 100 ° C. or more alcohols such as propylene glycol, glycerin, polyethylene glycol and dipropylene glycol can be used.
  • the water-soluble solvent is also preferably a food additive-based solvent. The reason for this is the same as the reason why it is preferable to use a food additive-based surfactant.
  • a particularly preferred water-soluble solvent is dipropylene glycol. The use of dipropylene glycol can also prevent stickiness.
  • the water-soluble solvent contains 2 to 70% by weight, particularly 3 to 50% by weight, particularly 5 to 30% by weight in the aqueous detergent, which further suppresses the cold stimulus, and It is preferable from the viewpoint of the heat retaining property of the wipe sheet 1 and the moisture retaining property to the skin.
  • Aqueous detergents include, in addition to the various components described above, viscosity modifiers such as myristic acid, milo II, and montmorinite; fragrance components such as limonene (aromatic substances); antibacterial agents such as methylparaben; A preservative; a natural extract such as petrolatum, pine extract, peach leaf extract, and hamamelis extract; and a humectant can also be contained.
  • silicone oils, silicones such as silicone powder, and other inorganic substances may be contained for giving a moist feeling to the skin.
  • These components can be contained in the aqueous detergent preferably in the range of 0.0001 to 20% by weight.
  • Water as a medium in the aqueous detergent is preferably contained in the aqueous detergent in an amount of 30 to 99.9% by weight, more preferably 50 to 95% by weight, and still more preferably 60 to 95% by weight. .
  • the wiping sheet 1 of the present embodiment is used after being heated to a predetermined temperature by various heating means. It is convenient to use a microwave as a heating means.
  • the heating temperature is from 35 to 85 ⁇ , preferably from 40 to 80, and particularly preferably from 50 to 75 ° C, from the viewpoint of handleability and sufficient suppression of cold stimulation.
  • a second embodiment of the present invention will be described with reference to FIGS. In the second embodiment, only the differences from the first embodiment will be described, and as for the points that are not particularly described, the detailed description of the first embodiment will be applied as appropriate.
  • 3 and 4 the same members as those in FIGS. 1 and 2 are denoted by the same reference numerals.
  • the wiping sheet 1 of the present embodiment has a three-layer structure of an inner layer 2 containing a water-absorbing polymer and surface layers 3 and 3 disposed on both sides of the inner layer 2. Consists of a laminated sheet.
  • the wiping sheet 1 of the present embodiment has a rectangular shape, and includes an inner layer 2 and two surface layers 3, 3 arranged on both surfaces of the inner layer 2. It is composed of a laminated sheet having a layer structure.
  • the surface layer 3 has a larger dimension than the inner layer 2 and extends outward from the periphery of the inner layer 2.
  • Both the inner layer 2 and the surface layer 3 are composed of a fiber sheet.
  • the wiping sheet 1 is embossed in a rhombic lattice pattern, whereby the inner layer 2 and the surface layer 3 are partially integrated. Also, the absorbent polymer contained in the inner layer 2 is prevented from falling off.
  • the swelling of the water-absorbing resin that has absorbed water in the aqueous detergent is not hindered. ing.
  • a large number of irregularities are formed on the surface of the wiping sheet.
  • the unevenness further enhances the wiping effect.
  • the total area of the protrusions is preferably 30 to 97%, particularly 45 to 90%, based on the apparent area of the wiping sheet 1.
  • the convex portions have a rhombic shape.
  • the surface layer 3 extends outward from the periphery of the inner layer 2.
  • the peripheral edge of the inner layer 2 is continuously sealed by being surrounded by the two extended surface layers 3. Thereby, even if the water-absorbing polymer contained in the inner layer 2 swells due to absorption, the water-absorbing polymer is prevented from falling off from the wiping sheet 1.
  • the area sealed by the two surface layers 3, 3 is preferably 2 to 95%, particularly 10 to 70% of the area of the wiping sheet 1.
  • the present invention is not limited to the above embodiment.
  • at a position inside the peripheral edge of the laminated sheet there are a plurality of joints 5 extending in one direction and having both ends reaching the peripheral edge. Instead of this, as shown in FIG.
  • the wiping sheet of the above embodiment has a three-layer structure of the inner layer and the two surface layers, but instead, another layer may be provided between the inner layer and the surface layer or outside the surface layer. They may be arranged to form a multilayer structure of four or more layers. In this case, the bonding portion 5 is formed by bonding the layers except the inner layer.
  • the wiping sheet 1 may have a two-layer structure including the inner layer 2 and one surface layer 3.
  • FIG. 6 shows a perspective view of one embodiment of the thermal wiping tool of the present invention.
  • the thermal wiping tool 10 shown in FIG. 6 includes a wiping sheet 1 and a housing 11.
  • a plurality of cleaning sheets 1 are stored in the storage body 11 in a stacked manner.
  • the storage body 11 has a rectangular parallelepiped storage part 31 having a space in which the wiping sheet 1 can be stored and having an open top.
  • a hinge 32 is provided at the open end of the back surface of the storage section 31.
  • a lid 33 that closes the opening of the storage section 31 is attached to the hinge 32.
  • the lid 33 can be opened and closed by a hinge 32.
  • the lid part 33 closes the opening of the storage part 31, the space in the storage part 31 is substantially closed.
  • a small hole 34 penetrating the lid 33 is provided at a substantially central part of the lid 33.
  • the small holes 34 function as steam exhaust means.
  • One or more sheets of the wiping sheet 1 are stored in the housing 11 in a substantially sealed state, and after being heated to a predetermined temperature by a predetermined heating means in this state. Then, it is taken out of the storage body 11 and used for cleaning the body.
  • a heating means for the wiping sheet 1 an appropriate means is used according to the material of the container. For example, when the storage body 11 is made of a material that transmits electromagnetic waves, for example, various synthetic resins, the cleaning sheet 1 is stored in the storage body 11, and then the storage body 11 is heated in a microwave oven. The wiping sheet 1 can be heated by placing it in the inside and irradiating it with electromagnetic waves.
  • the cleaning sheet 1 is stored in the container 11 and then the container 11 is immersed in hot water to remove the cleaning sheet. 1 can be heated. Regardless of which heating means is used, the housing 11 must be heat-resistant.
  • the heating temperature of the wiping sheet 1 is 35 to 85 ° C, preferably 40 to 80 ° C, and particularly preferably 50 to 75 ° C. Preferred from the point.
  • the housing 11 is provided with steam exhaust means capable of reducing the amount of evaporation of the aqueous cleaning agent to 1 to 20% by weight, particularly 2 to 15% by weight, particularly 3 to 12% by weight.
  • the small hole 34 is provided in the lid 33 of the housing 11, and a part of the steam generated through the small hole 34 is discharged to the outside. It has become so.
  • the diameter of the small holes 34 should be about 0.3 to 5 mm, especially about 0.5 to 4 mm, especially about 0.8 to 2.5 mm. This is preferable because the emission reduction amount can easily be within the above range.
  • the steam exhaust means is not limited to a small hole, and may be, for example, a heat-resistant moisture-permeable film sheet. The wiping sheet 1 thus heated is stored in the storage body 11 until an actual wiping operation is performed, and the high temperature state is maintained for a long time.
  • the storage body 11 has a heat retaining property capable of maintaining the temperature of the wiping sheet 1 at 40 ° C. or more, particularly 50 ° C. or more.
  • the storage body 11 itself may be made of a material having high heat insulation, such as glass fiber, ceramic glass wool, styrene foam, or urethane foam, or the inner surface of the storage body 11.
  • Thermo-Wool wool insulation material
  • Styrofoam Styrofoam
  • Urethane foam Urethane foam
  • a sheet containing a water-absorbing polymer was used as the inner layer.
  • This sheet was manufactured by the airlaid method, and had a basis weight of 120 g Zm 2 .
  • the water-absorbing polymer contained in this sheet was a cross-linked sodium sodium polyarylate, and its basis weight was 30 g Zm 2 .
  • the fiber composition of this sheet was 60% natural cellulose fiber (hydrophilic fiber) made of wood pulp and 40% polyethylene terephthalate / polyethylene core-sheath composite fiber (heat-fusible fiber). .
  • the size of the inner layer was 16 O mm in length and 2 O mm in width, and five of them were used.
  • Inner layers were arranged at equal intervals between the two surface layers, and the surface layers were heat-sealed to form a joint, thereby obtaining a laminated sheet.
  • the specific dimensions are as shown in FIG.
  • the grammage of the obtained laminated sheet was 144 g / m 2 , and the bonding area ratio was 21%.
  • the laminated sheet was impregnated with an aqueous detergent having the composition shown in Table 1 below to obtain a wipe sheet.
  • the impregnation amount is as shown in the table.
  • the wiping sheet was prepared in the same manner as in Example 2 except that the ratio of polyethylene terephthalate / polyethylene core-sheath composite fiber (heat-fusible fiber) was 30%. Got.
  • polyethylene terephthalate instead of polyethylene core-sheath composite fiber (heat-fusible fiber), polypropylene-polyethylene core-sheath composite fiber (heat-fusible fiber) was used, and the ratio of the heat-fusible fiber was 27%.
  • a cleaning sheet was obtained in the same manner as in Example 2 except that (Example 7) and 38% (Example 8) were used.
  • An aqueous detergent having the composition shown in Table 1 was impregnated into a cotton towel having a basis weight of 2300 g Zm 2 so as to have an impregnation amount shown in the table, to obtain a wipe sheet.
  • the release amount of the aqueous detergent and the rupture strength of the inner layer were measured by the above-mentioned methods, and the heat retention of the wiping sheets and the removal of sebum stains were performed by the following methods.
  • the cleaning rate was measured.
  • the sensation of the skin immediately after wiping, the feeling of smoothness of the skin after the aqueous detergent was dried, and the anti-soreness of the inner layer were evaluated. Table 1 shows the results. [Warmness of cleaning sheet]
  • the wiping sheet was heated to 60 ° C using a microwave oven. Then, it was stored for 3 minutes in an environment of 23 V-65% RH. Three minutes later, the temperature of the wiping sheet was measured using a fluorescent optical fiber thermometer [FX9002 manufactured by Anritsu Keiki Co., Ltd.].
  • Mink oil (ARAKAWA SAN GYO CO., LTD.) And oil-soluble blue dye (Orient Chemical Industry Co., Ltd.) Ltd. OILB RA CK 8 6 0) was dissolved in acetone liquid (weight ratio: mink oil 2%, the color-containing 0.2%, 9 7.8% acetone) and a quantity 4 cm 3 daub ( ⁇ acetone Is quickly volatilized, so that mink oil, which is dyed blue, is applied in a film on the entire surface of the mouth, and mink oil is very close to the sebum component of the human body. Was selected).
  • L Measure the L value of the stain with a color difference meter (Minol Yu Camera Co., Ltd .: color difference meter CR—210). Let this value be L. Before applying dirt, measure the L value of the white hollow battery. This value is L. And
  • Sebum dirt cleaning rate (%) (L 2 -L,) / (L 0 -L 1 )
  • the wiping sheet was heated to 60 ° C using a microwave oven.
  • the size of this cleaning sheet was 10 cm x 5 cm, and assuming that there was dirt in the arm of an adult man, he applied force to remove the dirt five times (two and a half reciprocations). ) Wipe.
  • the sheet was quickly released from the arm, and the feeling of the skin on the wiped portion was judged according to the following criteria. After the water-based detergent had dried, the wiped area was touched with a hand to determine whether or not there was a feeling of smoothness.
  • the wiping sheet was heated to 60 ° C using a microwave oven. Assuming that there is dirt on the arm of an adult male, the cleaning sheet was urged to remove the dirt, and was wiped 20 reciprocations over a distance of 20 cm. The direction of wiping was perpendicular to the longitudinal direction of the inner layer. Visually observe the state of the inner layer after wiping, and if the size is small and the shape before wiping is almost maintained, mark it as “ ⁇ ” . If the size is large and clearly different from the shape before wiping. "X" Examples Comparative examples Raw materials
  • Detergent release (g) 0.59 0.59 0.59 0.59 0.59 0.4 0.59 0.59 0.12 0.03 0.90 0.90 0.85 Inner layer breaking strength (cN / 20mm) 580 580 580 580 580 540 1080 1610 580
  • the wiping sheet of the example was one in which an appropriate amount of the aqueous cleaning agent was released and the sheet was also excellent in heat retention, so that the cold stimulus was suppressed. It turns out that it is. Further, it can be seen that in the wiping sheet of the embodiment, even if wiping is performed with a strong force, generation of blemishes in the inner layer is effectively prevented. In addition, it can be seen that it is excellent in sebum dirt cleaning properties and shows a smooth feeling after the detergent is dried. On the other hand, it can be seen that the wiping sheet of Comparative Example 1 releases a small amount of the aqueous cleaning agent, is inferior in the separability of sebum dirt, and has poor moisture retention of the sheet. Further, it can be seen that the wiping sheets of Comparative Examples 2 to 4 release a large amount of the aqueous cleaning agent, do not have good heat retention properties, and give a cold stimulus.
  • Example 1 The same one as used in Example 1 was used.
  • a water-absorbing polymer-containing sheet manufactured by Backay, USA was used as the inner layer.
  • the sheet according to the method described in International Publication WO 9 9/6 3 9 2 3, has been manufactured by E arrays blade method, basis weight 1 0 5 g Z m 2 der ivy.
  • the water-absorbing polymer contained in the sheet is a crosslinked polyacrylic acid sodium salt, a basis weight of 2 6. S g Z m 2 .
  • the surface layer was overlaid on both sides of the inner layer, and the three members were partially integrated by hot embossing to obtain a laminated sheet having a basis weight of 18.5 g Zm 2 in the form shown in FIGS.
  • the emboss pattern was a rhombic lattice pattern shown in FIG.
  • This hot embossing a large number of rhombic projections were formed on the surface of the laminated sheet.
  • the sum of the areas of the protrusions was 45% with respect to the apparent area of the sheet.
  • DK-Ester L-160A (trade name) manufactured by Dai-ichi Kogyo Seiyaku, a surfactant that is a food additive) 0.5%
  • An aqueous detergent consisting of 0.2% of ethyl paraben and the balance of water was impregnated with 800% of the weight of the laminated sheet in a dry state to obtain a wiping sheet.
  • Example 13 is the same as Example 13.
  • Example 2 The same cleaning agent as that used in Example 2 was impregnated with 800% of the weight of the dried laminated sheet to obtain a cleaning sheet.
  • the body wiping sheet of this invention when heating to a predetermined temperature and wiping a body, it is prevented from giving a cold stimulus resulting from vaporization of impregnated liquid or a decrease in temperature. Further, according to the thermal wiping tool and the thermal wiping method of the present invention, a body wiping operation can be performed while maintaining a high temperature for a long time.

Abstract

A sheet for cleaning a human body by wiping it which comprises a sheet containing a water-absorbing polymer and being impregnated with an aqueous cleaning agent, wherein it releases the cleaning agent in an amount of 0.04 to 0.8 g/500 cm2 under a load of 2000 g/45 cm2, and is used after warmed; the above sheet which comprises a laminated sheet having at least three layers of an inner layer capable of being impregnated with the aqueous cleaning agent and of holding it and surface layers provided on both the faces of the inner layer; and the above sheet wherein respective layers except the inner layer are jointed with one another in the peripheral portion thereof, and also in positions inside the peripheral portion the respective layers except the inner layer are jointed with one another, to form respective jointed portions.

Description

明 細 書 身体用清拭シート 技術分野  Description Body cleaning sheet Technical field
本発明は、 湿式の身体用清拭シートに関する。 本発明の清拭シートは 所定温度に加温して使用される。 また本発明は、 所定温度に加熱された 前記清拭シ一トを用いて拭き取り対象面の拭き取りを行う温熱拭き取り 用具に関する。 更に本発明は該温熱拭き取り用具を用いた温熱拭き取り 方法に関する。 背景技術  The present invention relates to a wet body wiping sheet. The wiping sheet of the present invention is used after being heated to a predetermined temperature. The present invention also relates to a hot wiping tool for wiping a surface to be wiped using the wiping sheet heated to a predetermined temperature. Further, the present invention relates to a thermal wiping method using the thermal wiping tool. Background art
水性液が含浸された身体用の清拭シートが知られている。 斯かる清拭 シートで身体を清拭する場合、 シ一卜からの水性液の放出量が多いと、 身体表面に水性液が残留し、 その液が気化するときに発生する気化熱に よって体温が奪われてしまい冷刺激となる。 この冷剌激によって、 特に 冬場の寒い時期には、 身体を拭いた高齢者や乳児が体調を崩すおそれが ある。 そこで、 清拭シートの使用に際して、 該清拭シートを電子レンジ で加温したり、 専用の加温器具で加温することが行われている。 しかし、 該清拭シートを温めても、 そこから放出される液量が多く、 結局のとこ ろ、 気化熱により体温が奪われ冷刺激となってしまう。 また、 加温された清拭シートを用いて身体を洗浄すると、 シートを保 温する機能がないことから時間の経過と共にシー卜の温度が低下してい き、 清拭が終わる頃には室温近くまで温度が低下してしまい、 結局冷刺 激を受けてしまう。 特に、 成人の身体全体を清拭する場合など、 清拭面 積が広く清拭に時間がかかる場合には、 清拭終了時でのシートの温度低 下が著しい。 清拭シー卜とは別に、 特開平 9— 2 5 2 9 9 4号公報や実開平 2— 5 2 6 8 9号公報には、 吸水性ポリマ一を含む蒸しタオルが記載されてい る。 斯かる蒸しタオルは、 これを沸騰した湯水に浸したり、 或いは予め 水分を含ませておき、 電子レンジで加熱して用いられる。 しかしこの蒸 しタオルは、 そもそも、 身体の一部分における血管の運動性刺激を活発 化させるために用いられるものであり、 液を放出させて使用することを 目的としていない。 従って本発明は、 所定温度に加熱して、 身体を清拭するときに、 含浸 された液の気化や温度低下に起因する冷刺激を与えることが防止された 身体用清拭シートを提供することを目的とする。 また本発明は、 長時間高温を維持した状態で拭き取り操作を行ない得 る温熱拭き取り用具及び温熱拭き取り方法を提供することを目的とす る。 発明の開示 BACKGROUND ART A body wiping sheet impregnated with an aqueous liquid is known. When wiping the body with such a wiping sheet, if the amount of the aqueous liquid released from the sheet is large, the aqueous liquid remains on the body surface and the body temperature is increased by the heat of vaporization generated when the liquid evaporates. Is deprived and becomes a cold stimulus. This cold stimulus can cause the elderly and infants who have wiped their bodies to feel sick, especially in the cold winter months. Therefore, when using the cleaning sheet, the cleaning sheet is heated with a microwave oven or with a special heating device. However, even when the wiping sheet is warmed, the amount of liquid discharged therefrom is large, and eventually, the body temperature is deprived by the heat of vaporization, resulting in a cold stimulus. In addition, if the body is washed using a heated wiping sheet, the temperature of the sheet will decrease over time due to the lack of a function to keep the sheet warm. The temperature drops until it reaches a cold stimulus. In particular, when the wiping area is wide and it takes a long time to clean the entire body of an adult, the temperature of the sheet at the end of wiping is remarkably lowered. Separately from the wiping sheet, Japanese Patent Application Laid-Open Nos. 9-252924 and 9-252689 describe steamed towels containing a water-absorbing polymer. Such steamed towels are used by immersing them in boiling water or pre-moistened water and heating them in a microwave oven. However, these steamed towels are used to stimulate motility stimulation of blood vessels in a part of the body in the first place, and are not intended to be used by releasing a liquid. Accordingly, the present invention provides a body wiping sheet which is prevented from giving a cold stimulus due to vaporization of an impregnated liquid or a decrease in temperature when wiping the body by heating to a predetermined temperature. With the goal. Another object of the present invention is to provide a hot wiping tool and a hot wiping method that can perform a wiping operation while maintaining a high temperature for a long time. Disclosure of the invention
本発明は、 吸水性ポリマーが含まれ且つ水性洗浄剤が含浸されたシー 卜からなり、 2 0 0 0 8 4 5 じ m2の荷重下での前記水性洗浄剤の放 出量が 0. 0 4〜 0. 8 gZ 5 0 0 c m 2であり、 加温して使用される 身体用清拭シートを提供することにより前記目的を達成したものであ る。 また本発明は、 前記清拭シートと、 該清拭シートがほぼ密閉状態で収 納される耐熱性を有する収納体とを備え、 該清拭シ一卜が該収鈉体内に ほぼ密閉状態で収納された状態で所定温度に加熱される温熱拭き取り用 具を提供するものである。 また本発明は、 前記清拭シートを、 耐熱性を有する収納体内にほぼ密 閉状態で収納し、 該清拭シ一トを該収納体内に収納された状態下に所定 温度に加熱し、 加熱された該清拭シートを該収納体から取り出し、 身体 を拭き取る温熱拭き取り方法を提供するものである。 更に本発明は、 水性洗浄剤の含浸保持が可能な内層と、 該内層の両面 に配された表面層との少なく とも 3層構造の積層シートからなり、 水性 洗浄剤が所定量含浸されている身体用清拭シ一トであって、 The present invention comprises a sheet containing a water-absorbing polymer and impregnated with an aqueous cleaning agent, and the amount of the aqueous cleaning agent released under a load of 200 845 m2 is 0.0. 4 to 0.8 gZ500 cm 2 , which achieves the above object by providing a body wiping sheet to be heated and used. The present invention also provides the wiping sheet, and a heat-resistant storage body in which the wiping sheet is stored in a substantially sealed state, wherein the wiping sheet is substantially sealed in the storage body. An object of the present invention is to provide a thermal wiping tool which is heated to a predetermined temperature in a stored state. Further, the present invention provides the cleaning sheet, wherein the cleaning sheet is substantially tightly packed in a heat-resistant container. The cleaning sheet is stored in a closed state, the cleaning sheet is heated to a predetermined temperature while being stored in the storage body, the heated cleaning sheet is taken out of the storage body, and the body is wiped with heat. To provide. Further, the present invention comprises a laminated sheet having at least a three-layer structure comprising an inner layer capable of holding an impregnation of an aqueous detergent and surface layers disposed on both sides of the inner layer, wherein a predetermined amount of the aqueous detergent is impregnated. A body cleaning sheet,
前記積層シー卜の周縁部において、 前記内層を除く各層どうしが接合 されていると共に、 前記積層シートの周縁部よりも内側の位置において も、 前記内層を除く各層どうしが接合されて、 それぞれ接合部を形成し ており、  At the peripheral edge of the laminated sheet, the respective layers except the inner layer are joined together, and also at a position inside the peripheral edge of the laminated sheet, the respective layers except the inner layer are joined together. And form
2 0 0 0 g /4 5 c m2荷重下での前記清拭シートからの前記水性洗 浄剤の放出量が 0. 0 4〜 0. 8 gZ 5 0 0 c m2であり、 2 is 0 0 0 g / 4 5 cm 2 the from the wiping sheet under load aqueous wash cleaning agent discharge amount is 0. 0 4~ 0. 8 gZ 5 0 0 cm 2 of
加温して使用される身体用清拭シートを提供するものである。 図面の簡単な説明  An object of the present invention is to provide a body wiping sheet to be used after being heated. BRIEF DESCRIPTION OF THE FIGURES
図 1は、 本発明の清拭シートの一実施形態を示す斜視図である。 図 2は、 図 1における 11 _ 11線断面図である。  FIG. 1 is a perspective view showing one embodiment of the wiping sheet of the present invention. FIG. 2 is a sectional view taken along line 11-11 in FIG.
図 3は、 本発明の身体用清拭シ一トの別の実施形態を示す斜視図であ る。  FIG. 3 is a perspective view showing another embodiment of the body wiping sheet of the present invention.
図 4は、 図 3における IV— IV線断面図である。  FIG. 4 is a sectional view taken along line IV-IV in FIG.
図 5は、 図 1及び図 2に示す清拭シートの別の実施形態を示す斜視図 である。  FIG. 5 is a perspective view showing another embodiment of the wiping sheet shown in FIGS. 1 and 2.
図 6は、 本発明の温熱拭き取り用具の一実施形態を示す斜視図であ る。  FIG. 6 is a perspective view showing an embodiment of the thermal wiping tool of the present invention.
図 7は、 各実施例における清拭シ一トを示す模式図である。 発明を実施するための最良の形態  FIG. 7 is a schematic diagram showing a wiping sheet in each embodiment. BEST MODE FOR CARRYING OUT THE INVENTION
以下本発明を、 その好ましい実施形態に基づき図面を参照しながら説 明する。 図 1 には本発明の身体用清拭シート (以下、 清拭シートともい う) の一実施形態の斜視図が示されており、 図 2には図 1における II— 11線断面図が示されている。 図 1及び図 2に示すように、 本実施形態の清拭シート 1は矩形状のも のであり、 内層 2 と、 該内層 2の両面に配された 2枚の表面層 3, 3と の 3層構造の積層シートから構成されている。 表面層 3は内層 2よりも 大きな寸法を有しており、 内層 2の周縁から外方に延出している。 内層 2及び表面層 3の何れも繊維シートから構成されている。 清拭シート 1は、 身体の洗浄のための水性洗浄剤が含浸されている湿 式シートである。 そして清拭シート 1は、 2 0 0 0 g_/ 4 5 c m2の荷 重下において、 水性洗浄剤の放出量が 0. 0 4〜0. 8 gZ 5 0 0 cm 2、 好ましくは 0. 1〜0. 7 gノ 5 0 0 c m2、 更に好ましくは 0. 2 〜0. 6 g Z 5 0 0 c m2となっている。 本発明者らは、 水性洗浄剤が 含浸されている湿式シートを用いて身体を清拭したときの冷刺激 (いわ ゆるひんやり感) について種々の検討を行ったところ、 シートから放出 される水性洗浄剤の量が 0. 8 g Z 5 0 0 c m2以下であれば、 身体表 面に残留する水性洗浄剤の気化に起因する冷刺激を抑制できることを知 見した。 従って、 冬場の寒い時期などに高齢者や乳児の身体を清拭して も、 冷刺激を与えることを防止でき、 体調の崩れなどを防止できる。 一 方、 放出量が 0. 0 4 5 0 0 c m2未満では十分な量の洗浄剤が放 出されず、 所期の洗浄効果が得られない。 洗浄剤の放出量の単位を 5 0 0 c m2に基づき規定する理由は、 この面積が、 成人の腕を 5回清拭し たときの面積にほぼ相当することによるものである ( 1回あたり、 2 0 c mX 5 c m= 1 0 0 c m2) 。 また、 水性洗浄剤の放出時の荷重を 2 0 0 0 g/4 5 c m2とした理由は、 身体を清拭するときのシートの面 積は通常 4 5 c m2程度 (実際に手の力がかかるシートの大きさは、 9 c mX 5 c m= 4 5 c m2程度である) であること、 及びその時に加わ る力が 2 0 0 0 g程度であることによるものである。 水性洗浄剤の放出量の具体的な測定方法は次の通りである。 Hereinafter, the present invention will be described with reference to the drawings based on preferred embodiments. I will tell. FIG. 1 is a perspective view of an embodiment of a body wiping sheet (hereinafter, also referred to as a wiping sheet) of the present invention, and FIG. 2 is a sectional view taken along line II-11 in FIG. ing. As shown in FIGS. 1 and 2, the wiping sheet 1 of the present embodiment has a rectangular shape, and includes an inner layer 2 and two surface layers 3, 3 disposed on both surfaces of the inner layer 2. It is composed of a laminated sheet having a layer structure. The surface layer 3 has a larger dimension than the inner layer 2 and extends outward from the periphery of the inner layer 2. Both the inner layer 2 and the surface layer 3 are composed of a fiber sheet. The cleaning sheet 1 is a wet sheet impregnated with an aqueous cleaning agent for cleaning the body. Then wipe the sheet 1, in 2 0 0 0 g_ / 4 5 cm 2 of the luggage weight under released amount of the aqueous detergent 0. 0 4~0. 8 gZ 5 0 0 cm 2, preferably 0.1 00.7 g ノ 500 cm 2 , more preferably 0.2 00.6 gZ500 cm 2 . The present inventors have conducted various studies on the cold stimulus (so-called cool sensation) when wiping the body using a wet sheet impregnated with an aqueous cleaning agent. if the amount of the agent is 0. 8 g Z 5 0 0 cm 2 or less was observed knowledge to be able to suppress the cold stimulation due to vaporization of the aqueous detergent remaining on the body table surface. Therefore, even when the body of an elderly person or an infant is cleaned in a cold winter season, it is possible to prevent a cold stimulus from being given, and to prevent a physical disorder or the like. On the other hand, if the release amount is less than 0.0450 cm 2 , a sufficient amount of the cleaning agent is not released, and the intended cleaning effect cannot be obtained. The reason for defining the unit of the amount of cleaning agent released based on 500 cm 2 is that this area is almost equivalent to the area obtained by wiping an adult's arm 5 times. , 20 cmX 5 cm = 100 cm 2 ). Also, the reason why the load at the time of release of the aqueous cleaning agent was set to 2000 g / 45 cm 2 is that the area of the sheet for wiping the body is usually about 45 cm 2 (actual hand force). The size of such a sheet is about 9 cm x 5 cm = 45 cm 2 ). Force is about 2000 g. The specific method of measuring the release amount of the aqueous cleaning agent is as follows.
① 2 0 0 0 gの直方体形の重りの下面に、 9 c mX 5 c m (X高さ 2 c m)に切り取ったスポンジ〔株式会社プリジス トン製の P H— 2 0 ( S Fフェルト) 〕 を固定する。 このスポンジの使用目的は、 清拭対象面 (後 述するイノアツク ' コーポレーション社製 「高機能フォーム ( 1 ) TT 一 4 1 0 1」 ) とシートとが常に一定面積で接触するようにするためで ある。  ① Fix a sponge (PH-20 (SF felt, manufactured by Priston Co., Ltd.)) cut to 9 cm x 5 cm (X height: 2 cm) on the lower surface of a 2000 g rectangular parallelepiped weight. . The purpose of using this sponge is to make sure that the surface to be wiped (Ino'ak 'Corporation's “highly functional foam (1) TT1-1401)” described later) and the sheet always contact with a fixed area. is there.
②シー卜を 9 c m X 1 5 c mに切り取り、 洗浄剤を一定量含浸させ る。  ② Cut the sheet to 9 cm x 15 cm and impregnate it with a certain amount of detergent.
③前記スポンジを覆うように、 前記シートを巻き付ける (前記スポン ジと前記シートが接する大きさは、 9 c mX 5 c mである) 。  (3) Wind the sheet so as to cover the sponge (the size of the sponge and the sheet in contact with each other is 9 cm x 5 cm).
④清拭対象面としてイノアツク * コーポレーション社製 「高機能フォ —ム ( 1 ) TT— 4 1 0 1」 を用いる。 この清拭対象面における長さ 2 0 c mの距離を、 重り及びスポンジを巻き付けた状態のシートによって 5回( 2往復半)清拭し (清拭面積は 1 0 0 c m2X 5回 = 5 0 0 c m2) 、 その前後の重量変化から洗浄剤放出量を算出する。 尚、 清拭対象面とし てイノアツク · コーポレ一ション社製 「高機能フォーム ( 1 ) T T - 4 1 0 1」 を採用した理由は、 このフォームを清拭対象面とした場合と、 成人男子の腕を清拭対象面とした場合とで、 洗浄剤の放出量に相関が認 められたことによる。 水性洗浄剤の放出量を前記範囲内にコントロールするためには、 例え ば水性洗浄剤の含浸量ゃシ一トの材質をコントロールすることが効果的 である。 シートの材質をコントロールすること、 例えば親水性繊維と非 親水性繊維 (例えばポリエチレン ポリプロピレンの組み合わせからな る芯鞘型複合繊維等) との混抄率を変化させることで、 表面層 3を構成 するシートの親水性の度合いを変えることができる。 具体的には、 親水 性繊維を多く混抄すると、 表面層 3は水性洗浄剤を保持しやすくなり、 且つ圧力によって水性洗浄剤が容易に放出されることから、 放出量は多 くなる。 逆に、 親水性繊維の混抄率を低下させることで、 表面層 3は、 水性洗浄剤を保持しにく くなり、 内層 2に保持される水性洗浄剤の量が 増えるので、 圧力を加えても水性洗浄剤は放出されにくくなる。 よって 放出量は少なくなる。 一方、 水性洗浄剤の含浸量をコントロールするには、 清拭シート 1の 吸水性をコントロールすればよい。 この目的のために、 清拭シート 1 に おける内層 2を構成するシートには、 吸水性ポリマーが含まれているこ とが好ましい。 詳細には、 内層 2は、 吸水性ポリマーの粒子及び繊維材 料を含む繊維シートから構成されていることが好ましい。 そして、 吸水 性ポリマ一の含有量をコントロールすることで、 水性洗浄剤の含浸量、 ひいてはその放出量をコントロールできる。 更に、 吸水性ポリマーが、 水性洗浄剤中の水を吸収することで、 清拭シート 1全体としての熱容量 が高くなり、 清拭シート 1 を所定温度に加熱したときの短時間での温度 低下を防止できる。 このことによつても、 冷刺激を与えることが防止さ れる。 このように、 本発明においては、 清拭シ一トに吸水性ポリマ一を含有 させることで、 ( 1 ) 水性洗浄剤の放出量がコントロールされて冷刺激 が抑制される、 及び ( 2 ) 清拭シート 1の保温性が高められて冷刺激が 抑制される、 という 2つの面からの効果が奏される。 清拭シ一ト 1の保温性を高めることで冷刺激を効果的に抑制するため には、 清拭シート 1に含まれる吸水性ポリマーの量及び含浸される水性 洗浄剤の量、 並びに両者の重量比が重要となる。 吸水性ポリマー及び水 性洗浄剤は、 清拭シート 1を 6 0 °Cに加熱した後、 2 3で, 6 5 % R H の環境下に 3分間保存した後の温度を 3 0で以上に維持し得る量含まれ ていることが好ましい。 保存時間を 3分間とした理由は、 水性洗浄液の 全放出量との関係で、 1枚の清拭シ一ト 1 による清拭時間は 3分間程度 であることによる。 清拭シート 1全体の重量 (水性洗浄剤が含浸された 状態での重量) に占める吸水性ポリマーの重量比は、 吸水性ポリマーの 種類にもよるが、 0. 0 0 2〜 0. 1 5、 特に 0. 0 0 4〜 0. 1 1で あることが好ましい。 また、 水性洗浄剤が含浸される前の状態における 清拭シート 1の重量に対する水性洗浄剤の含浸重量の比は 2〜 1 5、 特 に 4〜 1 0であることが好ましい。 また、 吸水性ポリマーと水性洗浄剤 との重量比 (前者ノ後者) は 0. 0 0 2〜 0. 1 5、 特に 0. 0 0 7〜 0. 1 1であることが好ましい。 内層 2は細長い短冊形をしている。 短冊形の内層 2は、 その幅に対す る長さの比が 1〜 1 0 0、 特に 5〜 4 0程度のものである。 内層 2の幅 は 2〜 3 O mm、 特に 5〜 3 O mm、 とりわけ 1 0 ~ 3 O mmであるこ とが、 水性洗浄剤の保持性と徐放性とのバランスの点好ましい。 内層 2 の長さは、 表面層 3, 3の長さよりも短くなつており、 内層 2の前後端 縁から表面層 3 , 3が延出している。 内層 2は複数本用いられており、 各内層 2は、 所定間隔を置いて一方向に配列されている。 その間隔は 1 〜 3 0 mm、 特に 2〜 2 0 mm、 とりわけ 3〜 1 1 mm程度であること が、 表面層 3 , 3同士の接合が容易になる点、 及び内層 2の面積を十分 に確保する点から好ましい。 各内層 2の周縁は、 2枚の表面層 3 , 3同士が接合することによって 囲繞されて連続に封止されている。 これによつて、 膨潤した吸水性ポリ マーの清拭シート 1からの脱落が防止される。 この脱落防止の観点か ら、 2枚の表面層 3, 3による封止面積は、 清拭シート 1の面積の 2〜 9 5 %、 特に 5〜 8 0 %、 とりわけ 1 0〜 6 5 %であることが好ましい。 表面層 3, 3同士の接合には、 例えばヒートシールによる熱融着、 接着 剤による接着などが用いられる。 また、 必要に応じ、 本実施形態の清拭 シートにエンボス加工を施して、 内層 2 と表面層 3 とを部分的に接合し てもよい。 清拭シート 1は、 その表面に、 一方向へ延び且つ該清拭用シートの周 縁にまで達する複数本の直線状の凹条部 4 , 4 , · ■ を有している。 各 凹条部 4はその長手方向が、 ウエッ トシート 1 の長手方向と一致してい る。 また各凹条部 4は内層 2の長手方向と同方向に延びている。 凹条部 4は、 積層シートにおける内層 2を除く各層どうし、 具体的には 2枚の 表面層 3 , 3どう しが直接接合して形成された接合部 5の位置に存して いる。 各内層 2は、 2枚の表面層 3, 3 どうしの直接接合で形成された 接合部 5によって連続に囲繞されている。 これによつて、 隣り合う内層 2 , 2間において凹条部 4が形成されていると共に清拭シ一卜の周縁に も凹条部 4が形成されている。 隣り合う内層 2, 2間に形成された凹条 部 4は、 その両端が清拭シート 1における周縁にまで達している。 凹条 部 4が形成されていることによって、 清拭の操作性及びョレ防止性が向 上する。 ' 凹条部 4は、 積層シートにおける内層 2 と 2枚の表面層 3とからなる 3層部分と、 2枚の表面層 3からなる 2層部分との段差で形成されるも のである。 従って、 凹条部 4の深さは、 内層 2の厚さによって適宜増減 できる。 特に、 後述するように、 内層 2が吸水性ポリマーを含む場合に は、 水性洗浄剤の吸収によって膨潤した吸水性ポリマーに起因して内層 2の厚みを極めて大きくでき、 その結果凹条部 4の深さを容易に大きく できる。 先に述べた通り、 内層 2は、 2枚の表面層 3, 3 どうしの直接接合で 形成された接合部 5によって連続に囲繞されている。 つまり、 各内層 2 は、 2枚の表面層 3 , 3によって形成されたスリーブ状の空間内に個々 独立にフリーな状態で保持されている。 これによつて、 清拭シート 1を 用いて身体を強く拭いても、 内層 2がョレたり破れるという不具合が起 こりにく くなる。 また十分な量の水性洗浄剤を含浸保持できることか ら、 清拭シート 1が早く冷えることを防止でき、 更には徐放性が良好に なり適度なゥエツ ト感が持続される。 内層 2を前記空間内に保持するこ とに代えて、 内層 2と表面層 3 とを熱エンボス等で接着することで、 内 層 2に力が加わってもョレゃ破れが生じないようにすることも考えられ る。 しかしながらその場合には、 内層 2に吸水性ポリマーが含有されて いると熱エンボス部位から吸水性ボリマーが外部へ漏れ出てしまった り、 熱エンボス部位において吸水性ポリマーが固定されてしまい吸収阻 害を起こすという不都合がある。 従って、 内層 2は表面層 3と接合さ れておらず、 本実施形態のように表面層 3によって形成された空間内に フリーな状態で保持されていることが好ましい。 内層 2のョレゃ破れを一層効果的に防止して清拭を安定して行う観点 から、 水性洗浄剤が含浸される前の状態における積層シート (内層 2及 び表面層 3からなるシート) の乾燥重量に対して 8 0 0重量%の水を該 積層シートに含浸した状態での内層 2の破断強度を好ましくは 4 0 0 c N / 2 0 m m以上とし、 更に好ましくは 5 0 0 c N / 2 0 m m以上とす る。 この破断強度は、 内層 2の長手方向、 即ち凹条部 4の延びる方向と 同方向において測定された値が前記の値以上であることが特に好まし い。 破断強度は次の方法で測定される。 前記含浸状態の清拭シート 1か ら内層 2を取り出し、 これから幅 2 O m m X長さ 8 O m mの試験片を切 り出す。 試験片を引張試験機のチヤックにチヤック間距離 5 0 m mで取 り付ける。 試験片を 3 0 0 m m / m i nの速度で引っ張り、 これが破断 するまでの最大荷重を求め、 その値を破断強度とする。 先に述べた通り、 内層 2は吸水性ポリマーの粒子及び繊維材料を含む 繊維シー卜から構成されていることが好ましい。 内層 2は典型的には不 織布又は紙から構成される。 吸水性ポリマーとしては、 自重の 2 0倍以 上の液体を吸収 · 保持でき且つゲル化し得るものが好ましい。 形状は特 に問わず、 球状、 塊状、 ブドウ状、 粉末状又は繊維状であり、 大きさがと し て Use a high-performance form (1) TT—410 1 manufactured by INOATSU CORPORATION as the surface to be cleaned. A distance of 20 cm in length on the surface to be wiped is wiped five times (two and a half reciprocations) with a sheet around which a weight and a sponge are wrapped (wiping area is 100 cm 2 X 5 times = 5 times). 0 cm 2 ), and the amount of detergent release is calculated from the weight change before and after that. The reason why the high-performance foam (1) TT-4101 made by Inoatsu Corporation was adopted as the surface to be cleaned was that this form was used as the surface to be cleaned, This is because there was a correlation between the amount of cleaning agent released and the case where the arm was used as the surface to be cleaned. In order to control the release amount of the aqueous detergent within the above range, for example, it is effective to control the material of the sheet impregnated with the aqueous detergent. The sheet constituting the surface layer 3 is controlled by controlling the material of the sheet, for example, by changing the mixing ratio of a hydrophilic fiber and a non-hydrophilic fiber (for example, a core-sheath composite fiber composed of a combination of polyethylene and polypropylene). Can be varied in degree of hydrophilicity. Specifically, hydrophilic When a large amount of conductive fiber is mixed, the surface layer 3 easily holds the aqueous detergent, and the aqueous detergent is easily released by pressure, so that the release amount increases. Conversely, lowering the mixing ratio of the hydrophilic fibers makes it difficult for the surface layer 3 to hold the aqueous detergent, and increases the amount of the aqueous detergent retained in the inner layer 2. Also, the aqueous detergent is less likely to be released. Therefore, the amount released is small. On the other hand, in order to control the impregnation amount of the aqueous cleaning agent, the water absorption of the wiping sheet 1 may be controlled. For this purpose, the sheet constituting the inner layer 2 in the wiping sheet 1 preferably contains a water-absorbing polymer. Specifically, the inner layer 2 is preferably made of a fiber sheet containing particles of a water-absorbing polymer and a fiber material. By controlling the content of the water-absorbing polymer, the amount of the aqueous detergent impregnated and, consequently, the amount of release can be controlled. Furthermore, since the water-absorbing polymer absorbs the water in the aqueous cleaning agent, the heat capacity of the wiping sheet 1 as a whole increases, and the temperature of the wiping sheet 1 decreases in a short time when heated to a predetermined temperature. Can be prevented. This also prevents a cold stimulus from being applied. As described above, in the present invention, by including the water-absorbing polymer in the wiping sheet, (1) the release amount of the aqueous cleaning agent is controlled and the cold stimulus is suppressed, and (2) the cleaning stimulus is suppressed. There are two effects that the heat retention of the wipe sheet 1 is enhanced and the cold stimulus is suppressed. In order to effectively suppress cold stimulation by increasing the heat retention of the wiping sheet 1, the amount of the water-absorbing polymer contained in the wiping sheet 1, the amount of the aqueous detergent impregnated therein, and both The weight ratio is important. For the water-absorbent polymer and water-based cleaning agent, heat the cleaning sheet 1 to 60 ° C, and then maintain the temperature at 30 or higher after storing for 3 minutes in an environment of 23 and 65% RH. Possible amount included Is preferred. The reason for setting the storage time to 3 minutes is that the wiping time by one wiping sheet 1 is about 3 minutes in relation to the total release amount of the aqueous cleaning solution. The weight ratio of the water-absorbing polymer to the total weight of the wiping sheet 1 (the weight in the state in which the aqueous cleaning agent is impregnated) varies depending on the type of the water-absorbing polymer, but is from 0.0002 to 0.15. It is particularly preferably 0.04 to 0.11. The ratio of the weight of the aqueous cleaning agent impregnated to the weight of the wiping sheet 1 before the aqueous cleaning agent is impregnated is preferably 2 to 15, particularly preferably 4 to 10. Further, the weight ratio of the water-absorbing polymer to the aqueous detergent (the former or the latter) is preferably from 0.002 to 0.15, particularly preferably from 0.007 to 0.11. Inner layer 2 is in the shape of a strip. The strip-shaped inner layer 2 has a ratio of the length to the width of 1 to 100, particularly about 5 to 40. The width of the inner layer 2 is preferably 2 to 3 Omm, particularly 5 to 3 Omm, particularly preferably 10 to 3 Omm, from the viewpoint of the balance between the retention of the aqueous detergent and the sustained release. The length of the inner layer 2 is shorter than the length of the surface layers 3, and the surface layers 3, 3 extend from the front and rear edges of the inner layer 2. A plurality of inner layers 2 are used, and the inner layers 2 are arranged in one direction at predetermined intervals. The spacing is about 1 to 30 mm, especially about 2 to 20 mm, and especially about 3 to 11 mm, so that the surface layers 3 and 3 can be easily joined together and the area of the inner layer 2 is sufficient. It is preferable from the viewpoint of securing. The peripheral edge of each inner layer 2 is surrounded and continuously sealed by joining the two surface layers 3, 3 together. This prevents the swollen water-absorbing polymer from falling off the wiping sheet 1. From the viewpoint of preventing the falling-off, the sealing area of the two surface layers 3 is 3 to 95% of the area of the wiping sheet 1, particularly 5 to 80%, particularly 10 to 65%. Preferably, there is. The surface layers 3 are joined to each other by, for example, heat fusion using heat sealing or adhesion using an adhesive. Also, if necessary, The inner layer 2 and the surface layer 3 may be partially joined by embossing the sheet. The wiping sheet 1 has on its surface a plurality of linear recesses 4 extending in one direction and reaching the periphery of the wiping sheet. The longitudinal direction of each of the ridges 4 coincides with the longitudinal direction of the wet sheet 1. Each concave ridge 4 extends in the same direction as the longitudinal direction of the inner layer 2. The concave ridge portion 4 is located at the position of a joint portion 5 formed by directly joining the two surface layers 3, 3 except for the inner layer 2 in the laminated sheet, specifically, two surface layers 3, 3. Each inner layer 2 is continuously surrounded by a joint 5 formed by direct joining of the two surface layers 3,3. As a result, the concave stripes 4 are formed between the adjacent inner layers 2 and 2 and the concave stripes 4 are also formed on the peripheral edge of the cleaning sheet. The concave ridges 4 formed between the adjacent inner layers 2, 2 have both ends reaching the periphery of the wiping sheet 1. The formation of the concave ridges 4 improves the operability of wiping and the ability to prevent dripping. 'The concave ridge portion 4 is formed by a step between a three-layer portion composed of the inner layer 2 and the two surface layers 3 in the laminated sheet and a two-layer portion composed of the two surface layers 3. Therefore, the depth of the concave ridge portion 4 can be appropriately increased or decreased by the thickness of the inner layer 2. In particular, as will be described later, when the inner layer 2 contains a water-absorbing polymer, the thickness of the inner layer 2 can be extremely large due to the water-absorbing polymer swollen by the absorption of the aqueous detergent, and as a result, The depth can easily be increased. As described above, the inner layer 2 is continuously surrounded by the joint 5 formed by the direct joining of the two surface layers 3,3. That is, each inner layer 2 is independently and independently held in a sleeve-like space formed by the two surface layers 3, 3. As a result, the cleaning sheet 1 Even if it is used to wipe the body, the inner layer 2 is less likely to break or break. In addition, since a sufficient amount of the aqueous cleaning agent can be impregnated and held, the wiping sheet 1 can be prevented from cooling down quickly, and further, the sustained-release property is improved, and a proper wet feeling is maintained. Instead of holding the inner layer 2 in the space, the inner layer 2 and the surface layer 3 are bonded by heat embossing or the like so that even if a force is applied to the inner layer 2, the inner layer 2 is not broken. It may be possible to do so. However, in this case, if the water-absorbing polymer is contained in the inner layer 2, the water-absorbing polymer leaks from the hot embossed portion to the outside, or the water-absorbing polymer is fixed at the hot embossed portion and the absorption is inhibited. There is a disadvantage of causing Therefore, it is preferable that the inner layer 2 is not bonded to the surface layer 3 and is kept free in the space formed by the surface layer 3 as in the present embodiment. From the viewpoint of more effectively preventing the inner layer 2 from tearing and stably wiping, a laminated sheet before the aqueous detergent is impregnated (a sheet composed of the inner layer 2 and the surface layer 3). The breaking strength of the inner layer 2 in a state where 800% by weight of water is impregnated in the laminated sheet with respect to the dry weight of the laminated sheet is preferably 400 cN / 20 mm or more, more preferably 500 c N / 20 mm or more. It is particularly preferable that the value of the breaking strength measured in the longitudinal direction of the inner layer 2, that is, the same direction as the extending direction of the concave ridge portion 4, is equal to or more than the above value. The breaking strength is measured by the following method. The inner layer 2 is taken out of the impregnated cleaning sheet 1 and a test piece having a width of 2 Omm and a length of 8 Omm is cut out from the inner layer 2. Attach the test piece to the tensile tester with a distance of 50 mm between the chucks. The test piece is pulled at a speed of 300 mm / min, and the maximum load until it breaks is determined. The value is defined as the breaking strength. As described above, the inner layer 2 is preferably made of a fiber sheet containing particles of a water-absorbing polymer and a fiber material. Inner layer 2 is typically composed of non-woven fabric or paper. 20 times or more of its own weight as a water-absorbing polymer Those capable of absorbing and retaining the above liquid and gelling are preferred. Any shape, spherical, massive, grape-like, powdery or fibrous
:! 〜 1 0 0 0 m、 特に 1 0 ~ 5 0 であることが好ましい。 具体 例としては、 デンプンゃ架橋力ルポキシルメチル化セルロース、 ァクリ ル酸又はアクリル酸アルカリ金属塩の重合体又は共重合体等、 ポリアク リル酸及びその塩並びにポリアクリル酸塩グラフ ト重合体を挙げること ができる。 繊維材料としては親水性繊維を用いることが好ましい。 具体 例としては、 針葉樹クラフ トパルプや広葉樹クラフ トパルプのような木 材パルプ、 木綿パルプ及びワラパルプ等の天然セルロース繊維、 レーョ ン及びキュブラ等の再生セルロース繊維、 ポリ ビニルアルコール繊維及 びポリアクリ ロニトリル繊維等の親水性合成繊維、 並びにポリエチレン 繊維、 ポリプロピレン繊維及びポリエステル繊維等の合成繊維を界面活 性剤により親水化処理したものなどが挙げられる。 繊維材料は 1種又は 2種以上を用いることができる。 特に、 内層 2 の破断強度を前述した値以上とするために、 内層 2に熱 融着性繊維が含まれていることが好ましい。 この場合、 内層 2の繊維組 成における熱融着性繊維の配合量は 2 0〜 7 0重量%、 特に 2 0〜 5 0 重量%、 とりわけ 2 0〜 4 0重量%であり、 残部が親水性繊維からなる ことが、 内層 2の強度向上と水性洗浄剤の含浸性向上とのバランスの点 から好ましい。 熱融着性繊維としては、 例えばポリエチレンゃポリプロピレン等のポ リオレフイン系樹脂、 ポリエチレンテレフタレ一ト等のポリエステル系 樹脂、 ポリアクリル酸ゃポリメタクリル酸等のアクリル系樹脂、 ポリ塩 化ビニル等のビニル系樹脂、 ポリアミ ド系樹脂等からなる繊維が用いら れる。 また、 前記の各種原料のうち、 2種の樹脂の組み合わせからなる 複合繊維 (芯鞘型複合繊維やサイ ド · バイ · サイ ド型複合繊維) を用い ることもできる。 特に、 低融点樹脂と高融点樹脂とからなり且つ該低融 点樹脂が繊維表面の少なく とも一部を形成している熱融着性複合繊維を 用いることが好適である。 低融点樹脂/高融点樹脂の組み合わせとして は、 高密度ポリエチレン ポリプロピレン、 低密度ポリエチレン ポリ プロピレン、 ポリプロピレン/ェチレン · ブテン一 1結晶性共重合体、 高密度ポリエチレン/ポリエチレンテレフタレー卜、 ナイロン一 6ノナ イロンー 6 6、 低融点ポリエステル ポリエチレンテレフタレ一ト、 ポ リプロピレン ポリエチレンテレフ夕レート等が例示できる。 熱融着性複合繊維の形態は、 並列型、 芯鞘型、 偏心鞘芯型、 三層以上 の多層型、 中空並列型、 中鞘芯型、 異形鞘芯型、 海島型等で且つ低融点 樹脂が繊維表面の少なく とも一部を形成した構造であれば良い。 熱融着 性複合繊維のうち好ましいものは、 高密度ポリエチレン、 線状低密度ポ リエチレン、 エチレン , ブテン— 1結晶性共重合体、 ポリエチレンテレ フタレートとポリエチレンイソフタレートとの共重合ポリエステルなど の低融点ポリエステルから選ばれる何れか 1種の熱可塑性樹脂を低融点 樹脂とし、 ポリプロピレン又はポリエチレンテレフタレ一トを高融点樹 脂とする、 並列型、 鞘芯型、 偏心鞘芯型の複合繊維である。 特に熱接着 性の点から、 低密度ポリエチレンとポリエチレンテレフタレートとの複 合繊維や低密度ポリエチレンとポリプロピレンとの複合繊稚を用いるこ とが好ましい。 内層 2を構成する繊維シートは、 前述の材料を原料として湿式抄造法 や、 エアレイ ド法、 エアスルー法及びスパンレース法などの各種不織布 製造法によって製造することができる。 また該繊維シートとして、 特開 平 8— 2 4 6 3 9 5号公報や国際公開 W 0 9 9 / 6 3 9 2 3に記載の吸 収性シートを用いることもできる。 内層 2を構成する繊維シートにおける吸水性ポリマーの粒子と繊維材 料との重量比 (前者/後者) は、 0 . 0 5〜 1 . 0、 特に 0 . :! 〜 0 . 5であることが、 吸水性ポリマ一による温熱保持性能の点から好まし い。 同様の理由により、 吸水性ポリマー自体の坪量は、 5〜 1 0 0 g m2、 特に 1 0 ~ 8 0 g /m2であることが好ましい。 内層 2を構成する 繊維シートの坪量は、 清拭シート 1全体の坪量にもよるが、 3 0〜 5 0 0 g /m 特に 6 0〜: 1 5 0 g Zm2であることが好ましい。 表面層 3はその長さが内層 2の長さより若干大きく、 その幅が内層 2 の幅の数倍〜十数倍である矩形のものである。 表面層 3は清拭シート 1 の外形をなしている。 表面層 3は親水性セルロース繊維等の親水性繊維 を含んでいる繊維シートから構成されていることが好ましい。 表面層 3 は典型的には不織布から構成される。 親水性セルロース繊維としては、 レーョン及びキュブラ等の再生セルロース繊維、 針葉樹クラフ トパルプ や広葉樹クラフ トパルプのような木材パルプ、 木綿パルプ及びヮラパル プ等の天然セルロース繊維などが挙げられる。 表面層 3を構成する繊維 シートは、 親水性セルロース繊維のみから構成されていても良く、 或い は他の繊維材料を含んでいてもよい。 他の繊維材料としては、 例えば内 層 2に含まれる熱融着性繊維と同様のものを用いることができる。 表面層 3 を構成する繊維シ一トが親水性セルロース繊維以外の他の繊 維を含む場合、 該他の繊維は、 表面層 3の重量 (乾燥基準) 当たり、 2 〜 7 0重量%、 特に 3 0〜 6 0重量%含まれることが好ましい。 また親 水性セルロール繊維は表面層 3の重量 (乾燥基準) 当たり、 3 0〜 9 8 重量%、 特に 4 0 〜 7 0重量%含まれることが好ましい。 表面層 3を構 成する繊維シートは、 例えば湿式抄造法や、 スパンレ一ス法及びエアレ ィ ド法などの各種不織布製造法によって製造することができる。 表面層 3を構成する繊維シートの坪量は、 清拭シート 1全体の坪量にもよる が、 それぞれ 2 0〜; L 0 0 g Zm2、 特に 3 0〜 7 0 g Zm2であること が好ましい。 尚、 2枚の表面層 3は、 同一のものでも良く或いは異なる 種類のものでもよい。 内層 2及び表面層 3が積層一体化された積層シート (水性洗浄剤が含 浸される前の積層シート) は、 その坪量が 4 0〜 5 0 0 gZm2、 特に 7 0〜4 0 0 g/m2、 とりわけ 1 2 0〜 2 9 0 gZm2であることが、 シートを手に持った時の感触と、 清拭のし易さの点から好ましい。 また、 積層シー トに洗浄剤が含浸された後の清拭シート 1 の坪量は 3 0 0〜 4 0 0 0 g/m2、 特に 5 0 0〜 3 0 0 0 g/m2、 とりわけ 1 0 0 0 ~ 1 5 0 0 g Zm2であることが好ましい。 更に、 水性洗浄剤が含浸される 前のシー卜の重量に対する水性洗浄剤の含浸率は 2 0 0〜 1 5 0 0重 量%、 特に 4 0 0〜 1 0 0 0重量%であることが好ましい。 次に、 水性洗浄剤について説明する。 水性洗浄剤は水を媒体とし洗浄 成分を含有するものである。 洗浄成分としては各種界面活性剤を用いる ことができる。 界面活性剤としては、 陰イオン界面活性剤、 非イオン界面活性剤、 陽 イオン界面活性剤及び両性界面活性剤の何れもが用いられ、 特に洗浄性 と仕上がり性の両立の面から、 ポリオキシアルキレン (アルキレンォキ サイ ド付加モル数 1 ~ 2 0 ) アルキル (炭素数 8〜 2 2の直鎖又は分岐 鎖) エーテル、 アルキル (炭素数 8〜 2 2の直鎖又は分岐鎖) グリコシ ド (平均糖縮合度 1〜 5 ) 、 ソルビタン脂肪酸 (炭素数 8〜 2 2の直鎖 又は分岐鎖) エステル、 及びアルキル (炭素数 6〜 2 2の直鎖又は分岐 鎖) グリセリルエーテル等の非イオン活性剤並びにアルキルカルポキシ ベタイン、 アルキルスルホベタイン、 アルキルヒ ドロキシスルホべタイ ン、 アルキルアミ ドカルポキシベタイン、 アルキルアミ ドスルホべタイ ン、 アルキルアミ ドヒ ドロキシスルホべタイン等のアルキル炭素数 8〜 2 4の両性界面活性剤が好適に用いられる。 また食品添加物系界面活性 剤を用いることも好ましい。 この理由は次の通りである。 清拭シート 1 を、 後述するように電子レンジで加熱した場合、 水性洗浄剤がその内部 に残留する可能性があり、 それにより水性洗浄剤が食品と間接的に接す る可能性がある。 その場合の安全性の点から、 水性洗浄剤に含まれる成 分である界面活性剤は食品添加物系のものであることが好ましい。 界面 活性剤は、 水性洗浄剤中に、 0 . 0 1 〜 3 0重量%、 特に 0 . 0 5〜 2 重量%含有されることが、 十分な洗浄効果の発現の点から好ましい。 水性洗浄剤には、 沸点が 1 0 0 °C以上である水溶性溶剤、 特にアルコ —ルが含有されていることが好ましい。 これによつて、 清拭シート 1か ら放出された水性洗浄剤が急速に気化することが抑制されて、 一層冷刺 激が抑制される。 沸点が 1 0 0 °C以上である水溶性溶剤としては、 プロ ピレンダリコール、 グリセリン、 ポリエチレングリコール、 ジプロピレ ングリコールなどのアルコール類を用いることができる。 また水溶性溶 剤は、 食品添加物系のものであることも好ましい。 この理由は、 界面活 性剤として食品添加物系のものを用いることが好ましい理由と同様であ る。 特に好ましい水溶性溶剤はジプロピレングリコールである。 またジ プロピレングリコールを用いると、 ベタつきも防止できる。 水溶性溶剤 は、 水性洗浄剤中に 2〜 7 0重量%、 特に 3〜 5 0重量%、 とりわけ 5 〜 3 0重量%含有されていることが、 より一層の冷刺激抑制の点、 及び 清拭シ一ト 1の保温性、 更には肌への保湿性の観点から好ましい。 水性洗浄剤には、 前述した各種成分に加えて、 ミ リスチン酸、 ミッロ ゥ、 モンモリナイ ト等の粘度調整剤 ; リモネン等の香料成分 (芳香性物 質) ; メチルパラベンなどの抗菌剤 ; 除菌剤 ; 防腐剤 ; ワセリ ン、 マツ エキス、 モモ葉エキス、 ハマメリスエキス等の天然エキスや保湿剤など を含有させることもできる。 またサラつと感ゃしっとり感の付与のため に、 シリ コーンオイルゃシリコーンパウダー等のシリコーン類 ; 及びそ の他の無機物質などを含有させることもできる。 これらの成分は、 水性 洗浄剤中に好ましくはそれぞれ 0 . 0 0 0 1 〜 2 0重量%含有させるこ とができる。 水性洗浄剤における媒体としての水は、 水性洗浄剤中に好ましくは 3 0〜 9 9 . 9重量%、 更に好ましくは 5 0〜 9 5重量%、 一層好ましく は 6 0〜 9 5重量%含まれる。 本実施形態の清拭シート 1は各種加熱手段によって所定温度に加熱さ れた後に使用される。 加熱手段としては電子レンジを用いることが簡便 である。 加熱温度は 3 5〜 8 5 ^、 好ましくは 4 0〜 8 0で、 特に 5 0 - 7 5 °Cであることが、 取り扱い性及び冷刺激の十分な抑制の点から好 ましい。 次に、 本発明の第 2の実施形態を図 3及び図 4を参照しながら説明す る。 第 2の実施形態については、 第 1の実施形態と異なる点についての み説明し、 特に説明しない点については、 第 1の実施形態に関して詳述 した説明が適宜適用される。 また、 図 3及び図 4において、 図 1及び図 2 と同じ部材に同じ符号を付してある。 本実施形態の清拭シ一ト 1は、 第 1の実施形態と同様に、 吸水性ポリマーを含む内層 2 と、 内層 2の両 面に配された表面層 3 , 3 との 3層構造の積層シートからなる。 図 3及び図 4に示すように、 本実施形態の清拭シート 1は矩形状のも のであり、 内層 2と、 該内層 2の両面に配された 2枚の表面層 3 , 3 と の 3層構造の積層シートから構成されている。 表面層 3は内層 2よりも 大きな寸法を有しており、 内層 2の周縁から外方に延出している。 内層 2及び表面層 3の何れも繊維シートから構成されている。 図 3に示すように、 清拭シート 1 には、 菱形格子状のパターンのェン ボス加工が施されており、 これによつて内層 2及び表面層 3が部分的に 一体化されている。 また、 内層 2に含まれている吸収性ポリマーの脱落 が防止されている。 内層 2 と表面層 3 とを部分的に一体化することで、 水性洗浄剤中の水を吸収した吸水性樹脂の膨潤が阻害されないようにし ている。 また、 部分的に一体化することで、 清拭シートの表面に多数の 凹凸が形成される。 この凹凸によって清拭効果が一層高まる。 清拭効果 を更に一層高める観点から、 凸部の面積の総和は、 清拭シート 1の見か けの面積に対して 3 0〜9 7 %、 特に 4 5〜9 0 %であることが好まし い。 本実施形態においては菱形格子状のパターンのエンボス加工が施さ れているので、 凸部は菱形形状となる。 図 4に示すように、 表面層 3は内層 2の周縁から外方に延出してい る。 内層 2の周縁は、 延出した 2枚の該表面層 3 , 3によって囲繞され て連続に封止されている。 これによつて、 内層 2に含まれる吸水性ポリ マーが吸収によって膨潤しても、 清拭シート 1からの脱落が防止され る。 この脱落防止の観点から、 2枚の表面層 3, 3 による封止面積は、 清拭シート 1の面積の 2 ~ 9 5 %、 特に 1 0〜7 0 %であることが好ま しい。 本発明は前記実施形態に制限されない。 例えば図 1及び図 2に示す実 施形態においては、 積層シートの周縁部よりも内側の位置において、 一 方向に延び且つその両端が該周縁部にまで達している接合部 5が複数箇 所に形成されていたが、 これに代えて図 5に示すように、 一枚のシート からなる内層 2に複数の開孔 6を形成し、 該開孔 6の位置において内層 2を除く各層どうしを接合して複数の接合部 5を形成してもよい。 また前記実施形態の清拭シートは、 内層と 2枚の表面層の 3層構造で あつたが、 これに代えて、 内層と表面層との間や、 表面層の外側に更に 別の層を配して 4層以上の多層構造となしてもよい。 この場合、 接合部 5は、 内層を除く各層どう しが接合されて形成される。 また図 3及び図 4に示す実施形態の変形例として、 清拭シート 1 を内 層 2と 1枚の表面層 3 とからなる 2層構造としてもよい。 また、 吸水性 ポリマーを保持でき且つその脱落のおそれがない限り、 単層構造として もよい。 また前記実施形態においては、 内層 2及び表面層 3 として繊維シート を用いたがこれに代えてスポンジなどの発泡シートを用いることもでき る。 また、 前記実施形態においては、 2枚の表面層が接合して形成された 接合部によって内層が連続的に囲繞されていたが、 吸水性ポリマーの脱 落を防止できる範囲において、 内層は該接合部によって不連続に囲繞さ れていてもよい。 次に本発明の温熱拭き取り用具及び温熱拭き取り方法を、 その好まし い実施形態に基づき図面を参照しながら説明する。 図 6 には、 本発明の 温熱拭き取り用具の一実施形態の斜視図が示されている。 図 6に示す温熱拭き取り用具 1 0は、 清拭シ一ト 1 と収納体 1 1 とを 備えている。 清拭シート 1 は、 複数枚が重ねられて収納体 1 1内に収納 されている。 収納体 1 1は、 清拭シート 1の収容が可能な空間を有し且 つ上部が開口した直方体状の収納部 3 1 を備えている。 収納部 3 1の背 面部の開口端にはヒンジ 3 2が設けられている。 ヒンジ 3 2には、 収納 部 3 1の開口部を塞ぐ蓋部 3 3が取り付けられている。 蓋部 3 3はヒン ジ 3 2によって開閉可能になっている。 蓋部 3 3が収納部 3 1の開口部 を閉塞した場合には、 該収納部 3 1内の空間はほぼ密閉状態となる。 蓋 部 3 3のほぼ中央部には、 該蓋部 3 3を貫通する小孔 3 4が設けられて いる。 後述するように小孔 3 4は蒸気排気手段として機能する。 清拭シート 1 は、 一枚又は複数枚が収納体 1 1内にほぼ密封状態で収 納され、 この状態下に所定の加熱手段によって所定温度に加熱された後 に、 収納体 1 1から取り出されて身体の清拭に使用される。 清拭シート 1 の加熱手段としては、 収納体の材質に応じて適切な手段が用いられ る。 例えば収納体 1 1が電磁波透過性の材料、 例えば各種合成樹脂から 構成されている場合には、 清拭シート 1を収納体 1 1内に収納した後、 収納体 1 1 を電子レンジの加熱庫内に入れ電磁波を照射することで清拭 シート 1 を加熱することができる。 収納体が電磁波透過性でない材料、 例えば金属から構成されている場合には、 清拭シート 1 を収納体 1 1内 に収納した後、 収納体 1 1 を熱水に浸漬することで清拭シ一卜 1を加熱 することができる。 何れの加熱手段を用いる場合にも、 収納体 1 1は耐 熱性である必要がある。 清拭シート 1 の加熱温度は 3 5〜 8 5 °C、 好ま しくは 4 0〜 8 0 °C、 特に 5 0〜 7 5 °Cであることが、 取り扱い性及び 冷刺激の十分な抑制の点から好ましい。 収納体 1 1 内にほぼ密封した状態下に清拭シ一ト 1 を加熱すると、 そ れに含浸されている水性洗浄剤から蒸気が発生し、 収納体 1 1内が加圧 状態となる。 収納体 1 1の内圧が高まると、 収納体 1 1 の破裂のおそれ がある。 また破裂がなくても、 収納体 1 1の温度が室温近くまで下がつ てくると内部が減圧され、 収納体 1 1が変形してしまう。 そこで、 発生 する蒸気の一部を放出して収納体 1 1 の内圧を大気圧と同一にすること が好ましい。 この観点から、 清拭シート 1が 7 5 °Cになるまで加熱した 後、 収納体 1 1を 2 3 °C · 6 5 %RHの環境下に 4分間保存した後の、 収納体 1 1内における水性洗浄剤の蒸発減少量を 1〜 2 0重量%、 特に 2〜 1 5重量%、 とりわけ 3〜 1 2重量%にし得る蒸気排気手段が収納 体 1 1に備えられていることが好ましい。 本実施形態においては、 先に 述べた通り、 収納体 1 1 における蓋部 3 3に小孔 3 4が設けられてお り、 該小孔 3 4を通じて発生した蒸気の一部が外部へ放出されるように なっている。 小孔 3 4の径は 0. 3〜 5 mm程度、 特に 0. 5〜4mm 程度、 とりわけ 0. 8〜 2. 5 mm程度であることが、 水性洗浄剤の蒸 発減少量を容易に前記範囲内とし得る点から好ましい。 なお蒸気排気手 段は小孔に限られず、 例えば耐熱性の透湿フィルムシ一トでも良い。 このようにして加熱された清拭シート 1は、 実際の清拭操作が行われ るまで収納体 1 1内に収納され、 その高温状態が長時間維持される。 そ して、 清拭操作を行うときに初めて収納体 1 1から取り出され、 拭き取 り対象である身体の拭き取りが行われる。 この観点から、 清拭シート 1 が 7 5 °Cになるまで加熱した後、 収納体 1 1 を 2 3で · 6 5 % R Hの環 境下に 4分間保存した後の、 収納体 1 1内における清拭シート 1の温度 を 4 0 °C以上、 特に 5 0 °C以上に維持し得る保温性を収納体 1 1が有し ていることが好ましい。 収納体 1 1の保温性を高めるためには、 例えば 収納体 1 1 自体を断熱性の高い材料、 例えばグラスファイバ一、 セラミ ックグラスウール、 発泡スチロール、 発泡ウレタンから構成したり、 収 納体 1 1 の内面に断熱材、 例えばサーモウ一ル (羊毛断熱材) 、 発泡ス チロール、 発泡ウレタンを貼り付ければよい。 なお、 清拭シート 1 を収 納体 1 1 内に収納せず直接加熱した場合には、 収納体 1 1内に収納して 加熱した場合に比べて高温状態の維持時間が相対的に短くなる。 収納体 1 1の形状は図 6に示す形状に限られず、 清拭シ一ト 1 をほぼ 密封状態に収容し得る形状であれば、 いかなる形状でも良い。 以下の例中、 特に断らない限り、 「%」 は 「重量%」 を意味する。 : 100 to 100 m, particularly preferably 10 to 50 m. Specific examples include polyacrylic acid and its salts, and polyacrylic acid graft polymers, such as starch-crosslinking lipoxyl methylated cellulose, polymers or copolymers of acrylic acid or alkali metal acrylates, and the like. be able to. It is preferable to use hydrophilic fibers as the fiber material. Specific examples include wood pulp such as softwood kraft pulp and hardwood pulp, natural cellulose fiber such as cotton pulp and straw pulp, regenerated cellulose fiber such as rayon and cuvula, polyvinyl alcohol fiber and polyacrylonitrile fiber. Examples include hydrophilic synthetic fibers, and synthetic fibers such as polyethylene fibers, polypropylene fibers, and polyester fibers that have been subjected to a hydrophilic treatment with a surfactant. One or more fiber materials can be used. In particular, it is preferable that the inner layer 2 contains a heat-fusible fiber so that the breaking strength of the inner layer 2 is not less than the above-mentioned value. In this case, the blending amount of the heat-fusible fiber in the fiber composition of the inner layer 2 is 20 to 70% by weight, particularly 20 to 50% by weight, particularly 20 to 40% by weight, and the balance is hydrophilic. It is preferable to be made of conductive fibers from the viewpoint of the balance between the improvement in the strength of the inner layer 2 and the improvement in the impregnation property of the aqueous detergent. Examples of the heat-fusible fibers include polyolefin resins such as polyethylene and polypropylene, polyester resins such as polyethylene terephthalate, acrylic resins such as polyacrylic acid and polymethacrylic acid, and vinyl resins such as polyvinyl chloride. Fibers made of resin, polyamide resin and the like are used. Further, among the above-mentioned various raw materials, a conjugate fiber (core-sheath type conjugate fiber or a side-by-side type conjugate fiber) composed of a combination of two kinds of resins can be used. In particular, the low melting point resin and the high melting point resin It is preferable to use a heat-fusible conjugate fiber in which the point resin forms at least a part of the fiber surface. Examples of low-melting resin / high-melting resin combinations include high-density polyethylene polypropylene, low-density polyethylene polypropylene, polypropylene / ethylene / butene-1-1 crystalline copolymer, high-density polyethylene / polyethylene terephthalate, and nylon-6-nonylone. 66, low melting point polyester polyethylene terephthalate, polypropylene polyethylene terephthalate and the like. The form of the heat-fusible conjugate fiber is parallel type, core-sheath type, eccentric sheath-core type, multilayer of three or more layers, hollow parallel type, middle-sheath core type, irregular-shaped sheath-core type, sea-island type, etc. It is sufficient that the resin has a structure in which at least a part of the fiber surface is formed. Preferred among the heat-fusible conjugate fibers are low melting points such as high-density polyethylene, linear low-density polyethylene, ethylene, butene-1 crystalline copolymer, and copolymerized polyester of polyethylene terephthalate and polyethylene isophthalate. A parallel, sheath-core, or eccentric sheath-core composite fiber in which any one of thermoplastic resins selected from polyester is used as a low-melting resin, and polypropylene or polyethylene terephthalate is used as a high-melting resin. In particular, from the viewpoint of thermal adhesion, it is preferable to use a composite fiber of low-density polyethylene and polyethylene terephthalate or a composite fiber of low-density polyethylene and polypropylene. The fiber sheet constituting the inner layer 2 can be produced from the above-described materials as a raw material by a wet papermaking method, or various nonwoven fabric production methods such as an airlaid method, an air-through method, and a spunlace method. Further, as the fiber sheet, an absorbent sheet described in Japanese Patent Application Laid-Open No. Hei 8-24639 or International Publication WO09 / 693923 can be used. The weight ratio between the particles of the water-absorbing polymer and the fiber material in the fiber sheet constituting the inner layer 2 (the former / the latter) is 0.05 to 1.0, in particular, 0 :! A value of 5 is preferable from the viewpoint of the heat retention performance of the water-absorbing polymer. For the same reason, the basis weight of the water-absorbing polymer itself is preferably from 5 to 100 gm 2 , particularly preferably from 10 to 80 g / m 2 . The basis weight of the fiber sheet constituting the inner layer 2, depending on the basis weight of the whole wiping sheet 1, 3 0~ 5 0 0 g / m , especially 6 0: is preferably 1 5 0 g Zm 2 . The surface layer 3 is a rectangle whose length is slightly larger than the length of the inner layer 2 and whose width is several times to tens of times the width of the inner layer 2. The surface layer 3 has the outer shape of the wiping sheet 1. The surface layer 3 is preferably made of a fiber sheet containing hydrophilic fibers such as hydrophilic cellulose fibers. The surface layer 3 is typically composed of a non-woven fabric. Examples of the hydrophilic cellulose fiber include regenerated cellulose fiber such as rayon and cuvula, wood pulp such as softwood kraft pulp and hardwood kraft pulp, and natural cellulose fiber such as cotton pulp and pulp pulp. The fiber sheet constituting the surface layer 3 may be composed only of hydrophilic cellulose fibers, or may contain another fiber material. As the other fiber material, for example, the same material as the heat-fusible fiber contained in the inner layer 2 can be used. When the fiber sheet constituting the surface layer 3 contains fibers other than the hydrophilic cellulose fiber, the other fibers are contained in an amount of 2 to 70% by weight, particularly, based on the weight of the surface layer 3 (dry basis). It is preferably contained in an amount of 30 to 60% by weight. The hydrophilic cellulose fiber is preferably contained in an amount of 30 to 98% by weight, particularly preferably 40 to 70% by weight, based on the weight (dry basis) of the surface layer 3. The fiber sheet constituting the surface layer 3 can be manufactured by various nonwoven fabric manufacturing methods such as a wet papermaking method, a spunless method and an airlaid method. The basis weight of the fiber sheet constituting the surface layer 3 depends on the basis weight of the entire wiping sheet 1, but is 20 to each; L 0 g Zm 2 , particularly 30 to 70 g Zm 2 Is preferred. Incidentally, the two surface layers 3 may be the same or different types. The laminated sheet in which the inner layer 2 and the surface layer 3 are integrally laminated (the laminated sheet before being impregnated with the aqueous detergent) has a basis weight of 40 to 500 gZm 2 , particularly 70 to 400 gZm 2 . g / m 2 , especially 120 to 290 gZm 2 , is preferred from the viewpoint of the feel when holding the sheet in hand and the ease of wiping. The basis weight of the cleaning sheet 1 after the laminated sheet is impregnated with the cleaning agent is 300 to 400 g / m 2 , particularly 500 to 300 g / m 2 , particularly 1 is preferably 0 0 0 ~ 1 5 0 0 g Zm 2. Further, the impregnation rate of the aqueous detergent with respect to the weight of the sheet before the impregnation with the aqueous detergent may be 200 to 150% by weight, particularly 400 to 100% by weight. preferable. Next, the aqueous cleaning agent will be described. The aqueous cleaning agent contains water as a medium and contains cleaning components. Various surfactants can be used as the cleaning component. As the surfactant, any of anionic surfactants, nonionic surfactants, cationic surfactants and amphoteric surfactants can be used. (Alkylene oxide addition mole number 1 to 20) Alkyl (C8 to C22 linear or branched chain) Ether, Alkyl (C8 to C22 linear or branched chain) Glycoside (Average saccharide condensation Degree 1-5), sorbitan fatty acid (linear or branched chain having 8 to 22 carbon atoms), ester, and alkyl (linear or branched chain having 6 to 22 carbon atoms) nonionic activator such as glyceryl ether and alkyl Carboxy betaine, alkyl sulfo betaine, alkyl hydroxy sulfo betaine, alkyl amide carboxy betaine, alkyl amide sulfo betaine, alkyl amide An amphoteric surfactant having 8 to 24 alkyl carbon atoms, such as hydroxysulfobetaine, is preferably used. It is also preferable to use a food additive-based surfactant. The reason is as follows. If the cleaning sheet 1 is heated in a microwave oven as described below, the aqueous cleaning agent may remain inside, thereby indirectly contacting the food with the aqueous cleaning agent. May be From the viewpoint of safety in that case, the surfactant contained in the aqueous detergent is preferably a food additive. The surfactant is preferably contained in the aqueous detergent in an amount of 0.01 to 30% by weight, particularly 0.05 to 2% by weight, from the viewpoint of exhibiting a sufficient cleaning effect. It is preferable that the aqueous detergent contains a water-soluble solvent having a boiling point of 100 ° C. or higher, particularly an alcohol. As a result, rapid evaporation of the aqueous cleaning agent released from the wiping sheet 1 is suppressed, and cold irritating is further suppressed. As the water-soluble solvent having a boiling point of 100 ° C. or more, alcohols such as propylene glycol, glycerin, polyethylene glycol and dipropylene glycol can be used. The water-soluble solvent is also preferably a food additive-based solvent. The reason for this is the same as the reason why it is preferable to use a food additive-based surfactant. A particularly preferred water-soluble solvent is dipropylene glycol. The use of dipropylene glycol can also prevent stickiness. The water-soluble solvent contains 2 to 70% by weight, particularly 3 to 50% by weight, particularly 5 to 30% by weight in the aqueous detergent, which further suppresses the cold stimulus, and It is preferable from the viewpoint of the heat retaining property of the wipe sheet 1 and the moisture retaining property to the skin. Aqueous detergents include, in addition to the various components described above, viscosity modifiers such as myristic acid, milo II, and montmorinite; fragrance components such as limonene (aromatic substances); antibacterial agents such as methylparaben; A preservative; a natural extract such as petrolatum, pine extract, peach leaf extract, and hamamelis extract; and a humectant can also be contained. In addition, silicone oils, silicones such as silicone powder, and other inorganic substances may be contained for giving a moist feeling to the skin. These components can be contained in the aqueous detergent preferably in the range of 0.0001 to 20% by weight. Water as a medium in the aqueous detergent is preferably contained in the aqueous detergent in an amount of 30 to 99.9% by weight, more preferably 50 to 95% by weight, and still more preferably 60 to 95% by weight. . The wiping sheet 1 of the present embodiment is used after being heated to a predetermined temperature by various heating means. It is convenient to use a microwave as a heating means. The heating temperature is from 35 to 85 ^, preferably from 40 to 80, and particularly preferably from 50 to 75 ° C, from the viewpoint of handleability and sufficient suppression of cold stimulation. Next, a second embodiment of the present invention will be described with reference to FIGS. In the second embodiment, only the differences from the first embodiment will be described, and as for the points that are not particularly described, the detailed description of the first embodiment will be applied as appropriate. 3 and 4, the same members as those in FIGS. 1 and 2 are denoted by the same reference numerals. Similar to the first embodiment, the wiping sheet 1 of the present embodiment has a three-layer structure of an inner layer 2 containing a water-absorbing polymer and surface layers 3 and 3 disposed on both sides of the inner layer 2. Consists of a laminated sheet. As shown in FIGS. 3 and 4, the wiping sheet 1 of the present embodiment has a rectangular shape, and includes an inner layer 2 and two surface layers 3, 3 arranged on both surfaces of the inner layer 2. It is composed of a laminated sheet having a layer structure. The surface layer 3 has a larger dimension than the inner layer 2 and extends outward from the periphery of the inner layer 2. Both the inner layer 2 and the surface layer 3 are composed of a fiber sheet. As shown in FIG. 3, the wiping sheet 1 is embossed in a rhombic lattice pattern, whereby the inner layer 2 and the surface layer 3 are partially integrated. Also, the absorbent polymer contained in the inner layer 2 is prevented from falling off. By partially integrating the inner layer 2 and the surface layer 3, the swelling of the water-absorbing resin that has absorbed water in the aqueous detergent is not hindered. ing. Also, by partially integrating, a large number of irregularities are formed on the surface of the wiping sheet. The unevenness further enhances the wiping effect. From the viewpoint of further improving the wiping effect, the total area of the protrusions is preferably 30 to 97%, particularly 45 to 90%, based on the apparent area of the wiping sheet 1. Better. In the present embodiment, since the rhombic lattice pattern is embossed, the convex portions have a rhombic shape. As shown in FIG. 4, the surface layer 3 extends outward from the periphery of the inner layer 2. The peripheral edge of the inner layer 2 is continuously sealed by being surrounded by the two extended surface layers 3. Thereby, even if the water-absorbing polymer contained in the inner layer 2 swells due to absorption, the water-absorbing polymer is prevented from falling off from the wiping sheet 1. From the viewpoint of preventing the falling-off, the area sealed by the two surface layers 3, 3 is preferably 2 to 95%, particularly 10 to 70% of the area of the wiping sheet 1. The present invention is not limited to the above embodiment. For example, in the embodiment shown in FIG. 1 and FIG. 2, at a position inside the peripheral edge of the laminated sheet, there are a plurality of joints 5 extending in one direction and having both ends reaching the peripheral edge. Instead of this, as shown in FIG. 5, a plurality of openings 6 are formed in the inner layer 2 made of one sheet, and each layer except the inner layer 2 is joined at the position of the opening 6. Thus, a plurality of joints 5 may be formed. Further, the wiping sheet of the above embodiment has a three-layer structure of the inner layer and the two surface layers, but instead, another layer may be provided between the inner layer and the surface layer or outside the surface layer. They may be arranged to form a multilayer structure of four or more layers. In this case, the bonding portion 5 is formed by bonding the layers except the inner layer. As a modification of the embodiment shown in FIGS. 3 and 4, the wiping sheet 1 may have a two-layer structure including the inner layer 2 and one surface layer 3. Also, water absorption A single-layer structure may be used as long as the polymer can be retained and there is no risk of falling off. Further, in the above-described embodiment, a fiber sheet is used as the inner layer 2 and the surface layer 3, but a foam sheet such as a sponge may be used instead. Further, in the above embodiment, the inner layer is continuously surrounded by the joint formed by joining the two surface layers. However, the inner layer is connected to the inner layer as long as the water-absorbing polymer can be prevented from falling off. It may be discontinuously surrounded by parts. Next, a thermal wiping tool and a thermal wiping method of the present invention will be described based on preferred embodiments with reference to the drawings. FIG. 6 shows a perspective view of one embodiment of the thermal wiping tool of the present invention. The thermal wiping tool 10 shown in FIG. 6 includes a wiping sheet 1 and a housing 11. A plurality of cleaning sheets 1 are stored in the storage body 11 in a stacked manner. The storage body 11 has a rectangular parallelepiped storage part 31 having a space in which the wiping sheet 1 can be stored and having an open top. A hinge 32 is provided at the open end of the back surface of the storage section 31. A lid 33 that closes the opening of the storage section 31 is attached to the hinge 32. The lid 33 can be opened and closed by a hinge 32. When the lid part 33 closes the opening of the storage part 31, the space in the storage part 31 is substantially closed. At a substantially central part of the lid 33, a small hole 34 penetrating the lid 33 is provided. As described later, the small holes 34 function as steam exhaust means. One or more sheets of the wiping sheet 1 are stored in the housing 11 in a substantially sealed state, and after being heated to a predetermined temperature by a predetermined heating means in this state. Then, it is taken out of the storage body 11 and used for cleaning the body. As a heating means for the wiping sheet 1, an appropriate means is used according to the material of the container. For example, when the storage body 11 is made of a material that transmits electromagnetic waves, for example, various synthetic resins, the cleaning sheet 1 is stored in the storage body 11, and then the storage body 11 is heated in a microwave oven. The wiping sheet 1 can be heated by placing it in the inside and irradiating it with electromagnetic waves. If the container is made of a material that is not permeable to electromagnetic waves, for example, metal, the cleaning sheet 1 is stored in the container 11 and then the container 11 is immersed in hot water to remove the cleaning sheet. 1 can be heated. Regardless of which heating means is used, the housing 11 must be heat-resistant. The heating temperature of the wiping sheet 1 is 35 to 85 ° C, preferably 40 to 80 ° C, and particularly preferably 50 to 75 ° C. Preferred from the point. When the wiping sheet 1 is heated while being substantially sealed in the housing 11, steam is generated from the aqueous cleaning agent impregnated therein, and the inside of the housing 11 is pressurized. When the internal pressure of the storage body 11 increases, the storage body 11 may be ruptured. Even if there is no rupture, when the temperature of the container 11 decreases to near room temperature, the pressure inside is reduced, and the container 11 is deformed. Therefore, it is preferable to release a part of the generated steam to make the internal pressure of the housing 11 equal to the atmospheric pressure. From this point of view, after the wiping sheet 1 is heated to 75 ° C, the container 11 is stored for 4 minutes in an environment of 23 ° C and 65% RH, and then the container 11 is It is preferable that the housing 11 is provided with steam exhaust means capable of reducing the amount of evaporation of the aqueous cleaning agent to 1 to 20% by weight, particularly 2 to 15% by weight, particularly 3 to 12% by weight. In the present embodiment, as described above, the small hole 34 is provided in the lid 33 of the housing 11, and a part of the steam generated through the small hole 34 is discharged to the outside. It has become so. The diameter of the small holes 34 should be about 0.3 to 5 mm, especially about 0.5 to 4 mm, especially about 0.8 to 2.5 mm. This is preferable because the emission reduction amount can easily be within the above range. The steam exhaust means is not limited to a small hole, and may be, for example, a heat-resistant moisture-permeable film sheet. The wiping sheet 1 thus heated is stored in the storage body 11 until an actual wiping operation is performed, and the high temperature state is maintained for a long time. Then, when the wiping operation is performed, it is first taken out of the housing 11 and the body to be wiped is wiped. From this point of view, after the wiping sheet 1 is heated to 75 ° C, the container 11 is stored in the container 11 at 23 for 4 minutes in an environment of 65% RH. It is preferable that the storage body 11 has a heat retaining property capable of maintaining the temperature of the wiping sheet 1 at 40 ° C. or more, particularly 50 ° C. or more. In order to enhance the heat retaining property of the storage body 11, for example, the storage body 11 itself may be made of a material having high heat insulation, such as glass fiber, ceramic glass wool, styrene foam, or urethane foam, or the inner surface of the storage body 11. Insulation material, for example, Thermo-Wool (wool insulation material), Styrofoam, or Urethane foam may be attached. In addition, when the cleaning sheet 1 is directly heated without being stored in the storage body 11, the maintenance time of the high temperature state is relatively shorter than when the cleaning sheet 1 is stored in the storage body 11 and heated. . The shape of the storage body 11 is not limited to the shape shown in FIG. 6, and may be any shape as long as the cleaning sheet 1 can be housed in a substantially sealed state. In the following examples, "%" means "% by weight" unless otherwise specified.
〔実施例 1〜 5及び比較例 1〕 (Examples 1 to 5 and Comparative Example 1)
( 1 ) 表面層の製造  (1) Production of surface layer
レーヨン繊維 ( 1. 7 d t e x X 4 0 mm) 6 0 %、 及びポリェチレ ンテレフ夕レー 卜/ポリエチレンの芯鞘型複合繊維 ( 2. 2 d t e X 5 1 mm) 4 0 %からなる坪量 4 0 gZm2のスパンレース不織布を製 造し、 これを表面層として用いた。 表面層の大きさは、 長さ 2 0 0 mm X幅 1 5 0 mmとした。 ( 2) 内層の製造 60 g of rayon fiber (1.7 dtex X 40 mm) and 40% of polyethylene-core composite fiber / polyethylene core-sheath composite fiber (2.2 dte X 51 mm) 40 g The spunlace nonwoven fabric of No. 2 was manufactured and used as a surface layer. The size of the surface layer is 200 mm in length The X width was set to 150 mm. (2) Manufacturing of inner layer
吸水性ポリマー含有シートを内層として用いた。 このシートはエアレ ィ ド法によって製造されたものであり、 坪量は 1 2 0 g Zm2であった。 このシートに含まれる吸水性ポリマーは架橋されたポリアタリル酸ナト リ ウム塩であり、 その坪量は 3 0 g Zm2であった。 このシートの繊維 組成は、 木材パルプからなる天然セルロース繊維 (親水性繊維) が 6 0 %、ポリエチレンテレフ夕レート/ポリエチレンの芯鞘型複合繊維(熱 融着性繊維) が 4 0 %であった。 内層の大きさは、 長さ 1 6 O mm X幅 2 Ommとし、 5本用いた。 A sheet containing a water-absorbing polymer was used as the inner layer. This sheet was manufactured by the airlaid method, and had a basis weight of 120 g Zm 2 . The water-absorbing polymer contained in this sheet was a cross-linked sodium sodium polyarylate, and its basis weight was 30 g Zm 2 . The fiber composition of this sheet was 60% natural cellulose fiber (hydrophilic fiber) made of wood pulp and 40% polyethylene terephthalate / polyethylene core-sheath composite fiber (heat-fusible fiber). . The size of the inner layer was 16 O mm in length and 2 O mm in width, and five of them were used.
( 3 ) 積層シー卜の製造 (3) Production of laminated sheet
2枚の表面層間に内層を等間隔で配し、 表面層どうしをヒートシール して接合部を形成し積層シートを得た。 具体的な寸法は図 7に示す通り である。 得られた積層シートの坪量は、 1 44 g/m2であり、 接合面 積率は 2 1 %であった。 Inner layers were arranged at equal intervals between the two surface layers, and the surface layers were heat-sealed to form a joint, thereby obtaining a laminated sheet. The specific dimensions are as shown in FIG. The grammage of the obtained laminated sheet was 144 g / m 2 , and the bonding area ratio was 21%.
( 4) 清拭シ一卜の製造 (4) Manufacture of cleaning sheets
以下の表 1に示す組成からなる水性洗浄剤を積層シ一トに含浸させて 清拭シートを得た。 含浸量は同表に示す通りである。  The laminated sheet was impregnated with an aqueous detergent having the composition shown in Table 1 below to obtain a wipe sheet. The impregnation amount is as shown in the table.
〔実施例 6〕 (Example 6)
内層を構成する繊維の組成において、 ポリエチレンテレフタレー卜/ ポリエチレンの芯鞘型複合繊維 (熱融着性繊維) の割合を 3 0 %とする 以外は実施例 2 と同様にして清拭シ一トを得た。  In the composition of the fiber constituting the inner layer, the wiping sheet was prepared in the same manner as in Example 2 except that the ratio of polyethylene terephthalate / polyethylene core-sheath composite fiber (heat-fusible fiber) was 30%. Got.
〔実施例 7及び 8〕 (Examples 7 and 8)
内層を構成する繊維の組成において、 ポリエチレンテレフタレ一トノ ポリエチレンの芯鞘型複合繊維 (熱融着性繊維) に代えて、 ポリプロピ レンノポリエチレンの芯鞘型複合繊維 (熱融着性繊維) を用い、 該熱融 着性繊維の割合を 2 7 % (実施例 7〉 及び 3 8 % (実施例 8 ) とする以 外は実施例 2と同様にして清拭シートを得た。 In the composition of the fiber constituting the inner layer, polyethylene terephthalate Instead of polyethylene core-sheath composite fiber (heat-fusible fiber), polypropylene-polyethylene core-sheath composite fiber (heat-fusible fiber) was used, and the ratio of the heat-fusible fiber was 27%. A cleaning sheet was obtained in the same manner as in Example 2 except that (Example 7) and 38% (Example 8) were used.
〔比較例 2及び 3〕 (Comparative Examples 2 and 3)
坪量 2 3 0 g Zm 2の綿製のタオルに、 表 1 に示す組成からなる水性 洗浄剤を、 同表に示す含浸量となるように含浸させて清拭シートを得 た。 An aqueous detergent having the composition shown in Table 1 was impregnated into a cotton towel having a basis weight of 2300 g Zm 2 so as to have an impregnation amount shown in the table, to obtain a wipe sheet.
〔比較例 4〕 (Comparative Example 4)
レーヨンを 8 0 %、 芯鞘型複合繊維 (芯がポリエチレンテレフタレー トで、 鞘がポリエチレン) を 2 0 %含み、 坪量が 6 0 g Zm2の不織布 に、 以下の組成からなる水性洗浄剤 Aを表 1 に示す含浸量となるように 含浸させて清拭シ一トを得た。 水性洗浄剤 Aの組成 Rayon 80%, (in the core is polyethylene terephthalate, sheath polyethylene) sheath-core composite fiber comprising 2 0%, the basis weight of 6 0 g Zm 2 nonwoven, the following composition aqueous detergent A was impregnated so as to have the impregnation amount shown in Table 1 to obtain a wiped sheet. Composition of aqueous detergent A
• プロピレングリコール 3 %  • 3% propylene glycol
• パラベン 0 . 1 %  • Paraben 0.1%
• 塩化セチルピリジニゥム (除菌剤) 0 . 1 %  • Cetylpyridinium chloride (germicide) 0.1%
• 香料 0 . 0 1 %  • Fragrance 0.0 1%
. 水 9 6 . 7 9 % 〔性能評価〕  Water 96.7 9% [Performance evaluation]
実施例及ぴ比較例で得られた清拭シートについて、 前述の方法で水性 洗浄剤の放出量及び内層の破断強度を測定し、 また次の方法で清拭シー 卜の保温性及び皮脂汚れの洗浄率を測定した。 更に、 清拭直後の皮膚の 感覚、 水性洗浄剤が乾燥した後の皮膚のサラサラ感、 及び内層のョレ防 止性を評価した。 結果を表 1 に示す。 〔清拭シー卜の保温性〕 With respect to the wiping sheets obtained in Examples and Comparative Examples, the release amount of the aqueous detergent and the rupture strength of the inner layer were measured by the above-mentioned methods, and the heat retention of the wiping sheets and the removal of sebum stains were performed by the following methods. The cleaning rate was measured. Furthermore, the sensation of the skin immediately after wiping, the feeling of smoothness of the skin after the aqueous detergent was dried, and the anti-soreness of the inner layer were evaluated. Table 1 shows the results. [Warmness of cleaning sheet]
電子レンジを用いて清拭シートを 6 0 °Cに加熱した。 次いで 2 3 V - 6 5 % RHの環境下に 3分間保存した。 3分後、 清拭シートの温度を蛍 光式光ファイバ一温度計 〔安立計器 (株) 製の F X 9 0 2 0〕 を用いて 測定した。  The wiping sheet was heated to 60 ° C using a microwave oven. Then, it was stored for 3 minutes in an environment of 23 V-65% RH. Three minutes later, the temperature of the wiping sheet was measured using a fluorescent optical fiber thermometer [FX9002 manufactured by Anritsu Keiki Co., Ltd.].
〔皮脂汚れ洗浄率〕 [Sebum dirt cleaning rate]
① 2 0 0 0 gの直方体形の重りの下面に、 9 c m X 5 c m ( X高さ 2 c m) に切り取つたスポンジ〔株式会社ブリジストン製の P H - 2 0 ( S Fフェルト) 〕 を固定する。  (1) Fix a sponge (PH-20 (SF felt, manufactured by Bridgestone Corporation)) cut to 9 cm x 5 cm (X height 2 cm) on the lower surface of a 2000 g rectangular parallelepiped weight.
②清拭シートを 9 c m X 1 5 c mに切り取る。  ② Cut the cleaning sheet to 9 cm x 15 cm.
③スポンジを覆うように、 清拭シートを巻き付ける (スポンジと清拭 シートとが接する大きさは、 9 c mX 5 c mである) 。  (3) Wrap a cleaning sheet so as to cover the sponge (the size of the sponge and the cleaning sheet in contact is 9 cm x 5 cm).
④白色ホ一口一バッ ト (T o p製硬質ホー口一バッ ト) の上に、 ミン クオイル (ARAKAWA S AN GYO C O. , L TD製) と、 油 溶性青色系色素 (オリエント化学工業株式会社製 O I L B RA C K 8 6 0 ) をアセ トンで溶解させた液体 (重量比 : ミンクオイル 2 %、 色 素 0. 2 %、 アセトン 9 7. 8 %) とを一定量 4 c m 3塗り付ける (ァ セトンは直ぐに揮発するので、 ホ一口一面上には、 青く染まったミンク オイルが膜状に塗布された状態になる。 またミンクオイルは、 人体の皮 脂成分に極めて近いことから、 人体皮脂モデル汚れとして選定したもの である) 。 に Mink oil (ARAKAWA SAN GYO CO., LTD.) And oil-soluble blue dye (Orient Chemical Industry Co., Ltd.) Ltd. OILB RA CK 8 6 0) was dissolved in acetone liquid (weight ratio: mink oil 2%, the color-containing 0.2%, 9 7.8% acetone) and a quantity 4 cm 3 daub (§ acetone Is quickly volatilized, so that mink oil, which is dyed blue, is applied in a film on the entire surface of the mouth, and mink oil is very close to the sebum component of the human body. Was selected).
⑤当該汚れの L値を、 色差計 (ミノル夕カメラ株式会社製 : 色彩色差 計 C R— 2 1 0 ) にて測定をする。 この値を L,とする。 また、 汚れを 塗りつける前に、 白色ホ一ローバッ トの L値を測定しておく。 この値を L。とする。  L Measure the L value of the stain with a color difference meter (Minol Yu Camera Co., Ltd .: color difference meter CR—210). Let this value be L. Before applying dirt, measure the L value of the white hollow battery. This value is L. And
⑥重り及びスポンジに巻き付けた状態の清拭シ一トを、 当該汚れの上 で滑らせる。 ⑦先に L ,値を測定した部分について L値を再度測定する。 この値を L2とする。 ら せ る Slide the cleaning sheet wrapped around the weight and sponge on the dirt. (4) Measure the L value again for the part where the L and value were measured first. This value and L 2.
⑧皮脂汚れ洗浄率 (%) は、 得られた L„、 L ,及び L 2の値を用い次式 で定義される。 ⑧ sebum detergency ratio (%) is obtained L ", L, and is defined by the following equation using the values of L 2.
皮脂汚れ洗浄率 (%) = (L2-L,)/(L0-L1) Sebum dirt cleaning rate (%) = (L 2 -L,) / (L 0 -L 1 )
〔清拭直後の皮膚の感覚及び水性洗浄剤が乾燥した後の皮膚のサラ サラ感〕 [Skin sensation immediately after wiping and smoothness of the skin after the aqueous detergent has dried]
電子レンジを用いて清拭シートを 6 0 °Cに加熱した。 この清拭シート を 1 0 c mX l 5 c mの大きさにして、 成人男性の腕を、 そこに汚れが あると想定して、 その汚れを落とすように力を入れて 5回 ( 2往復半) 拭く。 その直後に、 シートを腕から素早く離し、 拭いた部分の肌の感じ 方を以下の基準で判断させた。 また、 水性洗浄剤が乾燥した後に、 拭い た部分を手で触らせてサラサラ感の有無を判断させた。  The wiping sheet was heated to 60 ° C using a microwave oven. The size of this cleaning sheet was 10 cm x 5 cm, and assuming that there was dirt in the arm of an adult man, he applied force to remove the dirt five times (two and a half reciprocations). ) Wipe. Immediately after that, the sheet was quickly released from the arm, and the feeling of the skin on the wiped portion was judged according to the following criteria. After the water-based detergent had dried, the wiped area was touched with a hand to determine whether or not there was a feeling of smoothness.
〇: 冷たく感じなかった (腕がヒャッとしなかった) 。  〇: I didn't feel cold (the arms didn't snap).
X : 冷たく感じた (腕がヒャッとした) 。  X: I felt cold (the arms were nervous).
〔内層のョレ防止性〕 [Prevention of swelling of inner layer]
電子レンジを用いて清拭シートを 6 0 °Cに加熱した。 成人男性の腕 を、 そこに汚れがあると想定して、 その汚れを落とすように清拭シート に力を入れ 2 O c mの距離を 2 0往復清拭した。 清拭の方向は、 内層の 長手方向と直交する方向とした。 清拭後の内層の状態を目視観察し、 ョ レが小さく、 清拭前の形状をほぼ保っていれば 「〇」 とし、 ョレが大き く、 清拭前の形状と明らかに異なる場合は 「X」 とした。 実施例 比較例 原料 The wiping sheet was heated to 60 ° C using a microwave oven. Assuming that there is dirt on the arm of an adult male, the cleaning sheet was urged to remove the dirt, and was wiped 20 reciprocations over a distance of 20 cm. The direction of wiping was perpendicular to the longitudinal direction of the inner layer. Visually observe the state of the inner layer after wiping, and if the size is small and the shape before wiping is almost maintained, mark it as “〇” .If the size is large and clearly different from the shape before wiping. "X" Examples Comparative examples Raw materials
1 2 3 4 5 6 7 8 1 2 3 4 シリコ-ンオイル " 1 3 5 一 ― 3 3 3 ― ― ― シ'フ'ロピレンク'リコ-ル 5 5 5 5 5 5 5 ― ― ― フ'ロビレンク'リコ-ル 20 5  1 2 3 4 5 6 7 8 1 2 3 4 Silicone oil 1 3 5 1 ― 3 3 3 ― ― ― シ 'ロ ピ ピ ピ ピ ロ 5 5 5 ― 5 5 5 5 ―' 'ロ ロRecall 20 5
洗 水性洗浄剤 界面活性剤 * 2 0.5 0.5 0.5 诤 (重量%) Wash Aqueous detergent Surfactant * 2 0.5 0.5 0.5 诤 (% by weight)
フエノキシエタノ-ル 0.3 0.3 0.3 0.3 0-3 0.3 0.3 0.3 一 一 ― 剤  Phenoxyethanol 0.3 0.3 0.3 0.3 0-3 0.3 0.3 0.3
A  A
メチルパラベン 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 ― 0.2 天然植物エキス * 3 0.05 0.05 0.05 0.05 ― 0.05 0.05 0.05 ― 一 ― 水 93.45 91.45 89.45 94.45 94.0 91.45 91.45 91.45 79.3 100 94.3 洗浄剤含浸重量 Methylparaben 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2-0.2 Natural plant extract * 3 0.05 0.05 0.05 0.05-0.05 0.05 0.05-I-Water 93.45 91.45 89.45 94.45 94.0 91.45 91.45 91.45 79.3 100 94.3 Weight of detergent impregnated
8俟 8倍 8倍 5Ϊ倍 6 8倍 8倍 R倍 2倍 2倍  8 times 8 times 8 times 5 times 6 6 times 8 times R times 2 times 2 times
(対乾燥シ一ト重量) (Dry sheet weight)
洗浄剤の放出量 (g ) 0.59 0.59 0.59 0.59 0.4 0.59 0.59 0.12 0.03 0.90 0.90 0.85 内層の破断強度 (cN/20mm) 580 580 580 580 580 540 1080 1610 580 Detergent release (g) 0.59 0.59 0.59 0.59 0.4 0.59 0.59 0.12 0.03 0.90 0.90 0.85 Inner layer breaking strength (cN / 20mm) 580 580 580 580 580 540 1080 1610 580
清拭シートの保温性 C) 34 34 34 34 30 34 34 34 28 25 25 25 清拭直後の皮膚の感覚 〇 〇 〇 〇 〇 〇 〇 〇 〇 X X X 皮膚のサラサラ感 有り 有り 有り なし なし 有り 有り 有り なし 'なし なし なし ョレ防止性 〇 〇 〇 〇 〇 〇 〇 〇 〇 C) 34 34 34 34 30 34 34 34 28 25 25 25 Skin sensation immediately after wiping 〇 〇 〇 〇 〇 〇 〇 〇 〇 XXX Skin smoothness Yes Yes Yes No No Yes Yes No No 'None N / A N / A レ 〇 〇 〇 〇 〇 〇 〇
皮脂汚れ洗浄率 (%) 91 92 92 98 99 99 99 99 88 86 99 90Sebum dirt cleaning rate (%) 91 92 92 98 99 99 99 99 88 86 99 90
* 1 :シリコーン SH- 245 (東レ ·ダウコ一ニング社製) * 1: Silicone SH-245 (manufactured by Toray Dow Corning)
* 2 :ショ糖ラウリン酸エステル (第一工業製薬製の 「D Kエステル L一 1 6 0 AJ )  * 2: Sucrose laurate (“DK ester L-160 AJ” manufactured by Daiichi Kogyo Seiyaku)
* 3 :ハマメリスリキッド (一丸フアルコス社製 Type B) * 3: Hamamelis liquid (Type B, manufactured by Ichimaru Fuarcos)
表 1 に示す結果から明らかなように、 実施例の清拭シートは適正な量 の水性洗浄剤が放出され、 またシ一卜の保温性も良好であることから、 冷刺激が抑制されたものであることが判る。 更に実施例の清拭シ一ト は、 強い力で清拭を行っても内層にョレが発生することが効果的に防止 されることが判る。 その上、 皮脂汚れの洗浄性に優れ、 洗浄剤の乾燥後 にはサラサラ感を呈するることが判る。 これに対して比較例 1 の清拭シ ー トは水性洗浄剤の放出量が少なく、 皮脂汚れの洗浄性に劣り、 かつシ 一トの保湿性も良くないことが判る。 また、 比較例 2〜4の清拭シート は、 水性洗浄剤の放出量が多く、 しかもシートの保温性も良好でなく、 冷刺激を与えるものであることが判る。 As is clear from the results shown in Table 1, the wiping sheet of the example was one in which an appropriate amount of the aqueous cleaning agent was released and the sheet was also excellent in heat retention, so that the cold stimulus was suppressed. It turns out that it is. Further, it can be seen that in the wiping sheet of the embodiment, even if wiping is performed with a strong force, generation of blemishes in the inner layer is effectively prevented. In addition, it can be seen that it is excellent in sebum dirt cleaning properties and shows a smooth feeling after the detergent is dried. On the other hand, it can be seen that the wiping sheet of Comparative Example 1 releases a small amount of the aqueous cleaning agent, is inferior in the separability of sebum dirt, and has poor moisture retention of the sheet. Further, it can be seen that the wiping sheets of Comparative Examples 2 to 4 release a large amount of the aqueous cleaning agent, do not have good heat retention properties, and give a cold stimulus.
〔実施例 9〜 1 2並びに比較例 5及び 6〕 (Examples 9 to 12 and Comparative Examples 5 and 6)
( 1 ) 表面層の製造  (1) Production of surface layer
実施例 1で用いたものと同様のものを用いた。  The same one as used in Example 1 was used.
( 2 ) 内層の製造  (2) Manufacture of inner layer
米国バッカイ社製の吸水性ポリマ一含有シートを内層として用いた。 このシートは、 国際公開 W O 9 9 / 6 3 9 2 3 に記載の方法に準じ、 ェ アレイ ド法によって製造されたものであり、 坪量は 1 0 5 g Z m 2であ つた。 このシートに含まれる吸水性ポリマーは架橋されたポリアクリル 酸ナトリウム塩であり、 その坪量は 2 6 . S g Z m 2であった。 A water-absorbing polymer-containing sheet manufactured by Backay, USA was used as the inner layer. The sheet according to the method described in International Publication WO 9 9/6 3 9 2 3, has been manufactured by E arrays blade method, basis weight 1 0 5 g Z m 2 der ivy. The water-absorbing polymer contained in the sheet is a crosslinked polyacrylic acid sodium salt, a basis weight of 2 6. S g Z m 2 .
( 3 ) 積層シ一卜の製造  (3) Production of laminated sheets
内層の両面に表面層を重ね合わせ、 熱エンボス加工によって三者を部 分的に一体化し、 図 3及び 4に示す形態の坪量 1 8 5 g Z m 2の積層シ — トを得た。 エンボスパターンは図 3に示す菱形格子模様であった。 こ の熱エンボス加工によって、 積層シ一卜の表面には菱形の凸部が多数形 成された。 凸部の面積の総和は、 シートの見かけの面積に対して 4 5 % であった。 The surface layer was overlaid on both sides of the inner layer, and the three members were partially integrated by hot embossing to obtain a laminated sheet having a basis weight of 18.5 g Zm 2 in the form shown in FIGS. The emboss pattern was a rhombic lattice pattern shown in FIG. By this hot embossing, a large number of rhombic projections were formed on the surface of the laminated sheet. The sum of the areas of the protrusions was 45% with respect to the apparent area of the sheet.
( 4 ) 清拭シ一トの製造 表 2に示す組成からなる水性洗浄剤を、 同表に示す含浸量となるよう に積層シートに含浸させて清拭シートを得た。 (4) Manufacture of cleaning sheets An aqueous detergent having the composition shown in Table 2 was impregnated into the laminated sheet so as to have the impregnation amount shown in the table, to obtain a wipe sheet.
〔性能評価〕 (Performance evaluation)
実施例及び比較例で得られた清拭シートについて、 前述の方法によつ て水性洗浄剤の放出量及び皮脂汚れ洗浄率を測定し、 また清拭シートの 保温性及び清拭直後の皮膚の感覚を評価した。 これらの結果を表 2に示 す。 表 2  With respect to the wiping sheets obtained in Examples and Comparative Examples, the release amount of the aqueous cleaning agent and the sebum dirt cleaning rate were measured by the above-described methods, and the heat retaining property of the wiping sheets and the skin immediately after wiping were measured. The feeling was evaluated. Table 2 shows the results. Table 2
Figure imgf000028_0001
Figure imgf000028_0001
ショ糖ラウリン酸エステル (第一工業 の 「D Kェ  Sucrose laurate (DDK
ステル L— 1 6 0 A」 ) 表 2に示す結果から明らかなように、 実施例の清拭シ一トは適正な量 の水性洗浄剤が放出され、 またシ一トの保温性も良好であることから、 冷刺激が抑制されたものであることが判る。 これに対して比較例 5の清 拭シ一トはシ一トの保温性に劣り、 比較例 6の清拭シ一トは冷刺激を与 えるものであることが判る。 〔実施例 1 3 ) Steril L-160 A ”) As is evident from the results shown in Table 2, the cleaning sheet of the example releases an appropriate amount of the aqueous cleaning agent and also has a good heat retaining property of the sheet. This indicates that the cold stimulus was suppressed. In contrast, the wiping sheet of Comparative Example 5 is inferior in heat retention of the sheet, and the wiping sheet of Comparative Example 6 gives a cold stimulus. (Example 13)
( 1 ) 表面層、 内層及び積層シー トの製造  (1) Manufacture of surface layer, inner layer and laminated sheet
実施例 1 と同様とした。  Same as Example 1.
( 2 ) 清拭シートの製造  (2) Manufacture of cleaning sheets
プロピレンダリコール 2 0 %、 ショ糖ラウリ ン酸エステル (第一工業 製薬製の 「DK—エステル L一 1 6 0 A」 (商品名) 、 食品添加物で ある界面活性剤) 0. 5 %、 ェチルパラベン 0. 2 %、 残部水からなる 水性洗浄剤を、 乾燥状態にある積層シ一卜の重量に対して 8 0 0 %含浸 させて清拭シ一 トを得た。  Propylene dalicol 20%, sucrose laurate (“DK-Ester L-160A” (trade name) manufactured by Dai-ichi Kogyo Seiyaku, a surfactant that is a food additive) 0.5%, An aqueous detergent consisting of 0.2% of ethyl paraben and the balance of water was impregnated with 800% of the weight of the laminated sheet in a dry state to obtain a wiping sheet.
( 3 ) 清拭シートの加熱  (3) Heating the cleaning sheet
清拭シートを図 6に示すポリエチレン製の収納体内に 2枚重ねて収納 し、 収納体ごと電子レンジの加熱庫内に入れて加熱した。 収納体の外部 には直径 1. 5 mmの小孔が設けられていた。 加熱は清拭シートの温度 が 7 5でとなるようにした。 清拭シートを 7 5 °Cになるまで加熱した 後、 収納体から取り出して 2 3 °C - 6 5 % R Hの環境下に 4分間保存し た。 保存後の水性洗浄剤の蒸発減少量を測定したところ 1 0. 0 %であ つた。 また、 清拭シートを 7 5 °Cになるまで加熱した後、 収納体を 2 3 V · 6 5 % R Hの環境下に 4分間保存した。 保存後の収納体内におけ る清拭シートの温度を測定したところ 6 2 °Cであった。 〔実施例 1 4〕  Two wiping sheets were stored in a polyethylene housing as shown in Fig. 6, and the entire housing was heated in a microwave oven. A small hole with a diameter of 1.5 mm was provided outside the container. The heating was performed so that the temperature of the wiping sheet was 75. After the wiping sheet was heated to 75 ° C, it was taken out of the container and stored in an environment of 23 ° C-65% RH for 4 minutes. The amount of evaporation loss of the aqueous detergent after storage was measured and was found to be 10.0%. After the wiping sheet was heated to 75 ° C., the container was stored for 4 minutes in an environment of 23 V · 65% RH. The temperature of the wiping sheet in the container after storage was 62 ° C. (Example 14)
( 1 ) 表面層、 内層及び積層シー トの製造  (1) Manufacture of surface layer, inner layer and laminated sheet
実施例 1 3と同様とした。  Example 13 is the same as Example 13.
( 2 ) 清拭シー卜の製造  (2) Manufacture of cleaning sheets
実施例 2で用いた洗浄剤と同様の洗浄剤を、 乾燥状態にある積層シ一 卜の重量に対して 8 0 0 %含浸させて清拭シートを得た。  The same cleaning agent as that used in Example 2 was impregnated with 800% of the weight of the dried laminated sheet to obtain a cleaning sheet.
( 3 ) 清拭シ一卜の加熱  (3) Heating the cleaning sheet
清拭シ一トを図 6に示すポリエチレン製の収納体内に 2枚重ねて収納 し、 収納体ごと電子レンジの加熱庫内に入れて加熱した。 収納体の外部 には、 直径 1 m mの小孔が設けられていた。 加熱は、 清拭シートの温度 が 7 5でとなるようにした。 清拭シートを 7 5 °Cになるまで加熱した 後、 収納体から取り出して、 2 3 °C、 6 5 % R Hの環境下に 4分間保存 した。 保存後の洗诤剤の蒸発量を測定したところ 1 1 . 2 %であった。 また、 清拭シートを 7 5 °Cになるまで加熱した後、 収納体を 2 3 °C, 6 5 % R Hの環境下に 4分間保存した。 保存後の収納体内における清拭シ 一卜の温度を測定したところ 6 8 °Cであった。 産業上の利用可能性 Two sheets of cleaning sheets are stored in a polyethylene housing as shown in Fig. 6. Then, the container was put into a microwave oven and heated. A small hole with a diameter of 1 mm was provided outside the container. The heating was performed so that the temperature of the wiping sheet was 75. After the wiping sheet was heated to 75 ° C, it was taken out of the container and stored at 23 ° C and 65% RH for 4 minutes. The measured amount of evaporation of the detergent after storage was 11.2%. After heating the wiping sheet to 75 ° C, the container was stored at 23 ° C and 65% RH for 4 minutes. The temperature of the wiping sheet in the container after storage was 68 ° C. Industrial applicability
本発明の身体用清拭シートによれば、 所定温度に加熱して、 身体を清 拭するときに、 含浸された液の気化や温度低下に起因する冷刺激を与え ることが防止される。 また本発明の温熱拭き取り用具及び温熱拭き取り 方法によれば、 長時間高温を維持した状態で、 身体の清拭操作を行ない 得る。  ADVANTAGE OF THE INVENTION According to the body wiping sheet of this invention, when heating to a predetermined temperature and wiping a body, it is prevented from giving a cold stimulus resulting from vaporization of impregnated liquid or a decrease in temperature. Further, according to the thermal wiping tool and the thermal wiping method of the present invention, a body wiping operation can be performed while maintaining a high temperature for a long time.

Claims

請 求 の 範 囲 The scope of the claims
1. 吸水性ポリマーが含まれ且つ水性洗诤剤が含浸されたシートからな り、 2 0 0 0 gZ4 5 c m2の荷重下での前記水性洗浄剤の放出量が 0. 0 4〜 0. 8 gZ 5 0 0 c m 2であり、 加温して使用される身体用清拭 シー卜。 1. A sheet containing a water-absorbing polymer and impregnated with an aqueous detergent, wherein the release amount of the aqueous detergent under a load of 2000 gZ4 5 cm 2 is from 0.04 to 0. 8 gZ a 5 0 0 cm 2, warmed body for wiping Sea Bok used.
2. 6 0 °Cに加熱した後、 2 3 °C · 6 5 % R Hの環境下に 3分間保存し た後の温度を 3 0 °C以上に維持し得る量の前記吸水性ポリマー及び前記 水性洗浄剤が含まれている請求の範囲第 1項記載の身体用清拭シート。 2.After heating to 60 ° C, the water-absorbing polymer and the amount of the above-mentioned water-absorbing polymer that can be maintained at 30 ° C or more after storage for 3 minutes in an environment of 23 ° C and 65% RH. 2. The body cleaning sheet according to claim 1, which contains an aqueous cleaning agent.
3. 前記吸水性ポリマーと前記水性洗浄剤との重量比 (前者 Z後者) が 0. 0 0 2〜 0. 1 5である請求の範囲第 1項記載の身体用清拭シート。 3. The body wiping sheet according to claim 1, wherein a weight ratio of the water-absorbing polymer to the aqueous cleaning agent (the former Z the latter) is from 0.002 to 0.15.
4. 2層以上の積層シートからなり、 その 1層が吸水性ポリマーを含み、 その層中における吸水性ポリマーの坪量が 5〜 1 0 0 gZm2である請 求の範囲第 1項記載の身体用清拭シート。 4. consists of a laminate of two or more sheets, including the one layer of the water-absorbing polymer, the billed basis weight of the water-absorbing polymer is 5~ 1 0 0 gZm 2 in that a layer in the range of claim 1 wherein Body cleaning sheet.
5. 吸水性ポリマーを含む内層と、 該内層の両面に配された表面層との 3層構造の積層シートからなり、 該内層の周縁が 2枚の該表面層によつ て囲繞されて連続に又は不連続に封止されており、 2枚の該表面層によ る封止面積が前記身体用清拭シートの面積の 2〜 9 5 %である請求の範 囲第 4項記載の身体用清拭シート。 5. Consists of a three-layer laminated sheet consisting of an inner layer containing a water-absorbing polymer and surface layers disposed on both sides of the inner layer. The periphery of the inner layer is continuously surrounded by two surface layers. 5. The body according to claim 4, wherein the surface area of the body cleaning sheet is 2 to 95% of the area of the body cleaning sheet. Cleaning sheet.
6. 前記内層が短冊形をしており、 該短冊形の複数の該内層が、 一方向 に配列されて 2枚の前記表面層間に介在配置されている請求の範囲第 5 項記載の身体用清拭シート。 6. The body according to claim 5, wherein the inner layer has a strip shape, and the plurality of strip-shaped inner layers are arranged in one direction and interposed between the two surface layers. Cleaning sheet.
7. 前記水性洗浄剤中に、 沸点が 1 0 0で以上である水溶性溶剤が 2〜 7 0重量%含有されている請求の範囲第 1項記載の身体用清拭シート。 7. In the aqueous cleaning agent, a water-soluble solvent having a boiling point of 100 or more 2. The body cleaning sheet according to claim 1, which is contained at 70% by weight.
8. 前記水性洗浄剤中に、 界面活性剤が 0. 0 1〜 3 0重量%含有され ている請求の範囲第 1項記載の身体用清拭シート。 8. The body cleaning sheet according to claim 1, wherein the aqueous cleaning agent contains 0.01 to 30% by weight of a surfactant.
9. 前記水性洗浄剤が含浸される前の状態におけるシ一ト重量に対する 該水性洗浄剤の含浸重量の比が、 2〜 1 5である請求の範囲第 1項記載 の身体用清拭シ一ト。 9. The body cleaning sheet according to claim 1, wherein the ratio of the weight of the aqueous cleaning agent impregnated to the weight of the sheet before the aqueous cleaning agent is impregnated is 2 to 15. G.
1 0. シート表面に多数の凹凸があり、 凸部の面積の総和がシートの見 かけの面積に対して 3 0〜 9 7 %である請求の範囲第 1項記載の身体用 清拭シ一ト。 10. The body cleaning sheet according to claim 1, wherein the sheet surface has a large number of irregularities, and the total area of the convex portions is 30 to 97% based on an apparent area of the sheet. G.
1 1. 前記表面層が、 該表面層の重量 (乾燥基準) 当たり、 親水性セル ロース繊維 3 0〜 9 8重量%及び低融点の熱可塑性繊維 2〜 7 0重量% を含んでいる請求の範囲第 5項記載の身体用清拭シート。 1 1. The surface layer contains 30 to 98% by weight of hydrophilic cellulose fibers and 2 to 70% by weight of low-melting thermoplastic fibers per weight (dry basis) of the surface layer. 6. The body wiping sheet according to item 5 above.
1 2. 前記水溶性溶剤が食品添加物系水溶性溶剤からなる請求の範囲第 7項記載の身体用清拭シート。 12. The body wiping sheet according to claim 7, wherein the water-soluble solvent comprises a food additive-based water-soluble solvent.
1 3. 前記界面活性剤が食品添加物系界面活性剤からなる請求の範囲第 8項記載の身体用清拭シート。 1 3. The body cleaning sheet according to claim 8, wherein the surfactant comprises a food additive-based surfactant.
1 4. 請求の範囲第 1項記載の身体用清拭シートと、 該清拭シートがほ ぼ密閉状態で収納される耐熱性を有する収納体とを備え、 該清拭シート が該収納体内にほぼ密閉状態で収納された状態で所定温度に加熱される 温熱拭き取り用具。 1 4. A body wiping sheet according to claim 1, and a heat-resistant storage body in which the wiping sheet is stored in a substantially sealed state, wherein the wiping sheet is provided in the storage body. A heat wiping tool that is heated to a specified temperature while being stored in a substantially sealed state.
1 5. 前記清拭シートが 7 5でになるまで加熱した後、 前記収納体を 2 3 °C - 6 5 % RHの環境下に 4分間保存した後の、 該収納体内における 前記水性洗浄剤の蒸発減少量を 1〜 2 0重量%にし得る蒸気排気手段が 前記収納体に備えられている請求の範囲第 1 4項記載の温熱拭き取り用 具。 1 5. After the wiping sheet is heated to 75, the container is stored in an environment of 23 ° C-65% RH for 4 minutes, and then stored in the container. 15. The thermal wiping tool according to claim 14, wherein a vapor exhaust unit capable of reducing the amount of evaporation of the aqueous cleaning agent to 1 to 20% by weight is provided in the housing.
1 6. 前記清拭シートが 7 5 になるまで加熱した後、 前記収納体を 2 3°C · 6 5 % RHの環境下に 4分間保存した後の、 該収納体内における 該清拭シー卜の温度を 40 °C以上に維持し得る保温性を該収納体が有し ている請求の範囲第 1 4項記載の温熱拭き取り用具。 1 6. After heating the wiping sheet to 75, store the container in an environment of 23 ° C and 65% RH for 4 minutes. 15. The thermal wiping tool according to claim 14, wherein the housing has a heat retaining property capable of maintaining a temperature of 40 ° C. or more.
1 7. 請求の範囲第 1項記載の身体用清拭シートを、 耐熱性を有する収 納体内にほぼ密閉状態で収納し、 該清拭シートを該収納体内に収納され た状態下に所定温度に加熱し、 加熱された該清拭シ一トを該収納体から 取り出し、 身体を拭き取る温熱拭き取り方法。 1 7. The body wiping sheet according to claim 1 is stored in a heat-resistant container in a substantially sealed state, and the wiping sheet is stored in the container at a predetermined temperature. And heating the wiping sheet out of the housing and wiping the body.
1 8. 水性洗浄剤の含浸保持が可能な内層と、 該内層の両面に配された 表面層との少なく とも 3層構造の積層シー卜からなり、 水性洗浄剤が所 定量含浸されている身体用清拭シートであって、 1 8. A body that has at least a three-layer laminated sheet with an inner layer capable of holding and retaining an aqueous detergent and surface layers disposed on both sides of the inner layer, and a body to which a predetermined amount of the aqueous detergent is impregnated. Cleaning sheet,
前記積層シートの周縁部において、 前記内層を除く各層どうしが接合 されていると共に、 前記積層シ一トの周縁部よりも内側の位置において も、 前記内層を除く各層どうしが接合されて、 それぞれ接合部を形成し ており、  At the peripheral portion of the laminated sheet, the layers except the inner layer are joined together, and at a position inside the peripheral portion of the laminated sheet, the layers except the inner layer are joined and joined. Part,
2 0 0 0 g/4 5 c m2荷重下での前記清拭シ一卜からの前記水性洗 浄剤の放出量が 0. 0 4〜 0. S gZ S O O c m2であり、 The release amount of the aqueous detergent from the wiping sheet under a load of 200 g / 45 cm 2 is 0.04 to 0.S gZ SOO cm 2 ,
加温して使用される身体用清拭シート。  A body wiping sheet that is heated and used.
1 9. 前記清拭シートはその表面に、 一方向へ延び且つ該清拭シートの 周縁にまで達する一本又は複数本の凹状部を有し、 1 9. The wiping sheet has on its surface one or more concave portions extending in one direction and reaching the periphery of the wiping sheet,
前記凹状部は前記接合部の位置に存している請求の範囲第 1 8項記載 の身体用清拭シー ト。 The body cleaning sheet according to claim 18, wherein the concave portion is located at the position of the joint.
2 0. 前記水性洗浄剤が含浸される前の状態における前記積層シートの 乾燥重量に対して 8 0 0重量%の水を該積層シ一卜に含浸した状態での 前記内層の破断強度が 4 0 0 c N/ 2 0 mm以上である請求の範囲第 1 8項記載の身体用清拭シ一ト。 20. The breaking strength of the inner layer when the laminated sheet is impregnated with 800% by weight of water with respect to the dry weight of the laminated sheet before impregnation with the aqueous cleaning agent is 4%. 19. The body wiping sheet according to claim 18, which has a diameter of not less than 0 cN / 20 mm.
2 1. 前記内層が吸水性ポリマーを含み、 前記水性洗浄剤が含浸される 前の状態における前記積層シ一トの乾燥重量に対する該水性洗浄剤の含 浸重量の比 (後者 Z前者) が 2〜 1 5である請求の範囲第 1 8項記載の 身体用清拭シ一ト。 2 1. The ratio of the impregnated weight of the aqueous cleaning agent to the dry weight of the laminated sheet before impregnation of the aqueous cleaning agent is 2 (the latter Z). 19. The body cleaning sheet according to claim 18, wherein
2 2. 6 0 °Cに加熱した後、 2 3で · 6 5 % RHの環境下に 3分間保存 した後の温度を 3 0 °C以上に維持し得る量の前記吸水性ポリマ一及び前 記水性洗浄剤が含まれている請求の範囲第 2 1項記載の身体用清拭シ一 2 After heating to 260 ° C, store in an environment of 65% RH for 3 minutes at 23 ° C, and keep the temperature of the water-absorbing polymer in an amount that can maintain the temperature at 30 ° C or higher. 21. The body cleaning system according to claim 21, which contains an aqueous cleaning agent.
2 3. 前記接合部の面積が前記清拭シ一卜の面積の 2〜 9 5 %である請 求の範囲第 1 8項記載の身体用清拭シート。 23. The body cleaning sheet according to claim 18, wherein the area of the joint is 2 to 95% of the area of the cleaning sheet.
2 4. 前記吸水性ポリマーと前記水性洗浄剤との重量比 (前者/後者) が 0. 0 0 2〜 0. 1 5である請求の範囲第 2 1項記載の身体用清拭シ22. The body wipe according to claim 21, wherein a weight ratio (former / latter) between the water-absorbing polymer and the aqueous cleaning agent is 0.002 to 0.15.
-— . -—.
2 5. 前記内層における前記吸水性ポリマ一の坪量が 5〜 1 0 0 g / 2である請求の範囲第 2 1項記載の身体用清拭シート。 25. The body cleaning sheet according to claim 21, wherein a basis weight of the water-absorbing polymer in the inner layer is 5 to 100 g / 2 .
2 6. 前記水性洗浄剤中に界面活性剤が 0. 0 1 ~ 3 0重量%含有され ている請求の範囲第 1 8項記載の身体用清拭シート。 26. The body cleaning sheet according to claim 18, wherein the aqueous cleaning agent contains 0.01 to 30% by weight of a surfactant.
2 7. 前記内層は、 前記凹部の延びる方向と同方向へ延びる細長形状を しており且つ複数本が所定間隔をおいて前記不織布層間に配されてお り、 2 7. The inner layer has an elongated shape extending in the same direction as the extending direction of the recess. And a plurality of fibers are arranged between the nonwoven fabric layers at a predetermined interval,
隣り合う前記内層間において、 前記表面層どうしが直接接合されて前 記接合部が形成されている請求の範囲第 1 8項記載の身体用清拭シー  19. The body cleaning sheet according to claim 18, wherein the surface layer is directly joined between the adjacent inner layers to form the joint.
2 8 . 前記表面層がその乾燥重量当り親水性セルロース繊維 3 0〜 9 8 重量%及び熱融着性繊維 2〜 7 0重量%を含んでいる請求の範囲第 1 8 項記載の身体用清拭シート。 28. The body cleansing composition according to claim 18, wherein said surface layer contains 30 to 98% by weight of hydrophilic cellulose fibers and 2 to 70% by weight of heat-fusible fibers based on its dry weight. Wipe sheet.
2 9 . 前記水性洗浄剤中にシリコーンオイル及び Z又はシリコーンパゥ ダ一が 0 . 0 0 0 1 〜 2 0重量%含有されている請求の範囲第 1 8項記 載の身体用清拭シート。 29. The body cleaning sheet according to claim 18, wherein the aqueous cleaning agent contains 0.0001 to 20% by weight of silicone oil and Z or silicone padder.
PCT/JP2003/007424 2002-07-18 2003-06-11 Sheet for cleaning human body by wiping WO2004008929A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003244112A AU2003244112A1 (en) 2002-07-18 2003-06-11 Sheet for cleaning human body by wiping

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2002210102A JP4282282B2 (en) 2001-12-27 2002-07-18 Body cleaning sheet
JP2002-210102 2002-07-18
JP2002238889A JP2004073529A (en) 2002-08-20 2002-08-20 Heating wiping tool
JP2002-238889 2002-08-20
JP2003-113561 2003-04-18
JP2003113561A JP4334263B2 (en) 2003-04-18 2003-04-18 Body cleaning sheet

Publications (1)

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WO (1) WO2004008929A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190200815A1 (en) * 2016-06-29 2019-07-04 Oji Holdings Corporation Body wiping sheet

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001031135A (en) * 1999-07-16 2001-02-06 Nissei Kogyo Kk Clean towel packaged body
JP2002325698A (en) * 2001-05-02 2002-11-12 Kao Corp Base material for sheet for dry bath

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001031135A (en) * 1999-07-16 2001-02-06 Nissei Kogyo Kk Clean towel packaged body
JP2002325698A (en) * 2001-05-02 2002-11-12 Kao Corp Base material for sheet for dry bath

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190200815A1 (en) * 2016-06-29 2019-07-04 Oji Holdings Corporation Body wiping sheet
US11027516B2 (en) * 2016-06-29 2021-06-08 Oji Holdings Corporation Body wiping sheet

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