WO2003099735A3 - Substrate comprising a titanium oxide/cerium oxide protective layer - Google Patents

Substrate comprising a titanium oxide/cerium oxide protective layer Download PDF

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Publication number
WO2003099735A3
WO2003099735A3 PCT/EP2003/005502 EP0305502W WO03099735A3 WO 2003099735 A3 WO2003099735 A3 WO 2003099735A3 EP 0305502 W EP0305502 W EP 0305502W WO 03099735 A3 WO03099735 A3 WO 03099735A3
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
protective layer
titanium oxide
cerium oxide
oxide
Prior art date
Application number
PCT/EP2003/005502
Other languages
German (de)
French (fr)
Other versions
WO2003099735A2 (en
Inventor
Martin Amlung
Klaus Endres
Martin Mennig
Helmut Schmidt
Original Assignee
Inst Neue Mat Gemein Gmbh
Martin Amlung
Klaus Endres
Martin Mennig
Helmut Schmidt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Neue Mat Gemein Gmbh, Martin Amlung, Klaus Endres, Martin Mennig, Helmut Schmidt filed Critical Inst Neue Mat Gemein Gmbh
Priority to EP03755136A priority Critical patent/EP1507746A2/en
Publication of WO2003099735A2 publication Critical patent/WO2003099735A2/en
Publication of WO2003099735A3 publication Critical patent/WO2003099735A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208—Oxides, e.g. ceramics
    • C23C18/1216—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C03C17/256—Coating containing TiO2
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5045—Rare-earth oxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/87—Ceramics
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1229—Composition of the substrate
    • C23C18/1245—Inorganic substrates other than metallic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1254—Sol or sol-gel processing
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/212—TiO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/23—Mixtures
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/113—Deposition methods from solutions or suspensions by sol-gel processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

A substrate having a surface consisting of an inorganic non-metallic matrix material comprises a protective layer based on titanium oxide/cerium oxide. This protective layer can be obtained by applying a coating composition, which comprises precursors of both titanium oxide and cerium oxide, onto the surface of the substrate and by compacting the coating composition at a temperature of at least 500 °C. The coating is suited for use as a heat-resistant, UV stable, and transparent protection for inorganic non-metallic materials, particularly glass, glass ceramics and ceramics, against corrosion caused by alkaline media.
PCT/EP2003/005502 2002-05-27 2003-05-26 Substrate comprising a titanium oxide/cerium oxide protective layer WO2003099735A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP03755136A EP1507746A2 (en) 2002-05-27 2003-05-26 Substrate comprising a titanium oxide/cerium oxide protective layer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2002123531 DE10223531A1 (en) 2002-05-27 2002-05-27 Substrate with a titanium oxide / cerium oxide protective layer
DE10223531.7 2002-05-27

Publications (2)

Publication Number Publication Date
WO2003099735A2 WO2003099735A2 (en) 2003-12-04
WO2003099735A3 true WO2003099735A3 (en) 2004-12-09

Family

ID=29432345

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/005502 WO2003099735A2 (en) 2002-05-27 2003-05-26 Substrate comprising a titanium oxide/cerium oxide protective layer

Country Status (3)

Country Link
EP (1) EP1507746A2 (en)
DE (1) DE10223531A1 (en)
WO (1) WO2003099735A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10324583B4 (en) * 2003-05-30 2005-08-11 Schott Ag Sol-gel coating solution for later production of Li-ion transparent storage layers for lithium ions, process for the preparation of the sol-gel coating solution and method for producing a transparent Li-ion storage layer
DE102005018246A1 (en) 2005-04-19 2006-10-26 Schott Ag Glass or glass ceramic articles with decorative coating
US7744951B2 (en) 2006-04-13 2010-06-29 Guardian Industries Corp. Coated glass substrate with infrared and ultraviolet blocking characteristics
US8322754B2 (en) 2006-12-01 2012-12-04 Tenaris Connections Limited Nanocomposite coatings for threaded connections
DE102008062881B4 (en) 2008-12-16 2021-04-08 Schott Ag Process for the production of a hollow molded glass body
AR100953A1 (en) 2014-02-19 2016-11-16 Tenaris Connections Bv THREADED PIPE FOR AN OIL WELL PIPING
GB2614722A (en) * 2022-01-13 2023-07-19 Pilkington Group Ltd Corrosion-resistant and/or cleanable coated glass substrate

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0890556A1 (en) * 1996-12-25 1999-01-13 Nippon Sheet Glass Co., Ltd. Thin film for optics, composition for the formation thereof, and ultraviolet-absorbing and heat-reflecting glass made by using the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR0168710B1 (en) 1994-08-11 1999-01-15 후지이 히로시 Anticorrosive cathodic electrodeposition paint
DE19714949A1 (en) 1997-04-10 1998-10-15 Inst Neue Mat Gemein Gmbh Process for providing a metallic surface with a glass-like layer
WO2000028109A1 (en) 1998-11-08 2000-05-18 Nkk Corporation Surface treated steel sheet having excellent corrosion resistance and method for producing the same
JP4532690B2 (en) 2000-07-24 2010-08-25 新日本製鐵株式会社 Metal material with resin-based corrosion-resistant layer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0890556A1 (en) * 1996-12-25 1999-01-13 Nippon Sheet Glass Co., Ltd. Thin film for optics, composition for the formation thereof, and ultraviolet-absorbing and heat-reflecting glass made by using the same

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
A. MAKISHIMA ET AL: "Preparation of CeO2-TiO2 coatings by the sol-gel process", JOURNAL OF NON-CRYSTALLINE SOLIDS., vol. 100, 1988, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM., NL, pages 321 - 324, XP002256434, ISSN: 0022-3093 *
AKIO MAKISHIMA ET AL: "PREPARATION AND PROPERTIES OF TIO2-CEO2 COATINGS BY THE SOL-GEL PROCESS", JOURNAL OF NON-CRYSTALLINE SOLIDS, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM, NL, vol. 121, no. 1 / 3, 1 May 1990 (1990-05-01), pages 310 - 314, XP000161073, ISSN: 0022-3093 *
KEOMANY D ET AL: "SOL GEL PREPARATION OF MIXED CERIUM-TITANIUM OXIDE THIN FILMS", SOLAR ENERGY MATERIALS AND SOLAR CELLS, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 33, no. 4, 1 August 1994 (1994-08-01), pages 429 - 441, XP000461958, ISSN: 0927-0248 *
MORIMOTO T ET AL: "Ultraviolet ray absorbing coatings on glass for automobiles", THIN SOLID FILMS, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 351, no. 1-2, 30 August 1999 (1999-08-30), pages 61 - 65, XP004183067, ISSN: 0040-6090 *
NAZERI A ET AL: "SYNTHESIS AND PROPERTIES OF CERIUM AND TITANIUM OXIDE THIN COATINGSFOR CORROSION PROTECTION OF 304 STAINLESS STEEL", JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, KLUWER ACADEMIC PUBLISHERS, DORDRECHT, NL, vol. 10, no. 3, 1 November 1997 (1997-11-01), pages 317 - 331, XP000721256, ISSN: 0928-0707 *

Also Published As

Publication number Publication date
EP1507746A2 (en) 2005-02-23
WO2003099735A2 (en) 2003-12-04
DE10223531A1 (en) 2003-12-11

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