WO2003080225A1 - Traitement et systeme pour eau de grande purete, par elimination d'azote organique - Google Patents

Traitement et systeme pour eau de grande purete, par elimination d'azote organique Download PDF

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Publication number
WO2003080225A1
WO2003080225A1 PCT/US2003/008373 US0308373W WO03080225A1 WO 2003080225 A1 WO2003080225 A1 WO 2003080225A1 US 0308373 W US0308373 W US 0308373W WO 03080225 A1 WO03080225 A1 WO 03080225A1
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WO
WIPO (PCT)
Prior art keywords
treatment
water
enzyme
contaminant
stream
Prior art date
Application number
PCT/US2003/008373
Other languages
English (en)
Inventor
Juchui R. Lin
Russell J. Macdonald
Richard D. Godec
Paul Melanson
William W. Carson
Lawrence C. Costa
Thomas J. Susa
Original Assignee
Ionics, Incorporated
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ionics, Incorporated filed Critical Ionics, Incorporated
Priority to AU2003256147A priority Critical patent/AU2003256147A1/en
Publication of WO2003080225A1 publication Critical patent/WO2003080225A1/fr

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • B01D61/026Reverse osmosis; Hyperfiltration comprising multiple reverse osmosis steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027Nanofiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/147Microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/16Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14Dynamic membranes
    • B01D69/141Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/04Specific process operations in the feed stream; Feed pretreatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2317/00Membrane module arrangements within a plant or an apparatus
    • B01D2317/02Elements in series
    • B01D2317/025Permeate series
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/38Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/04Non-contaminated water, e.g. for industrial water supply for obtaining ultra-pure water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage

Abstract

L'invention concerne une installation de traitement pour eau de grande pureté (100), traitant une charge de fluide à contaminant d'azote organique, par contact avec une unité d'élimination ciblée (30), dans le but de faire tomber en-dessous d'un seuil une concentration à l'état de traces. L'unité d'élimination peut comprendre une enzyme ou un autre agent, libre ou en liaison, qui a une efficacité spécifique pour rompre le contaminant. Il s'agit de préférence d'une enzyme stabilisée, immobilisée ou protégée, de sorte que son intégrité, ou au moins son activité, soit maintenue pendant plusieurs heures, plusieurs jours, ou plus longtemps, sans cofacteur, et avec une grande efficacité. Ce système est utile pour l'élimination de l'urée, dans le cadre d'un processus de lithographie à autocatalyse ou de préparation pharmaceutique. Par exemple, l'enzyme est une uréase lyophilisée/cristallisée, que l'on peut mettre en contact avec le flux par injection directe, ou bien l'enzyme peut transiter via une cuve de réaction ou une conduite de mélange à retard, afin que le temps de contact soit approprié, pour la rupture ou la capture du contaminant. On peut immobiliser l'enzyme sur un support, par exemple une membrane ou des billes, ce qui permet de faire passer le flux sur des billes, dans une colonne ou sur une surface, de manière à réaliser le clivage de l'urée dans la charge de fluide. On peut également utiliser des microparticules résidant dans le fluide, elles-mêmes séparées et réutilisées. Lorsqu'on utilise une enzyme libre ou liée à des microparticules, il est possible de récupérer le substrat de microparticules comme rétentat depuis une unité d'hyperfiltration (215) ou autre unité de filtration en aval ou en boucle latérale. On peut aussi récupérer le rétentat dans une cuve de dépôt et réutiliser le produit pour la réaction afin de maintenir une forte concentration d'enzyme ou d'agent, en fonctionnement.
PCT/US2003/008373 2002-03-18 2003-03-18 Traitement et systeme pour eau de grande purete, par elimination d'azote organique WO2003080225A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003256147A AU2003256147A1 (en) 2002-03-18 2003-03-18 Upw treatment and system with organic nitrogen removal

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US36536602P 2002-03-18 2002-03-18
US60/365,366 2002-03-18
US38697202P 2002-06-06 2002-06-06
US60/386,972 2002-06-06
US41404902P 2002-09-27 2002-09-27
US60/414,049 2002-09-27

Publications (1)

Publication Number Publication Date
WO2003080225A1 true WO2003080225A1 (fr) 2003-10-02

Family

ID=28457767

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/008373 WO2003080225A1 (fr) 2002-03-18 2003-03-18 Traitement et systeme pour eau de grande purete, par elimination d'azote organique

Country Status (2)

Country Link
AU (1) AU2003256147A1 (fr)
WO (1) WO2003080225A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008096108A2 (fr) 2007-02-06 2008-08-14 H2Oil & Gas Ltd Système de filtration
CN102583880A (zh) * 2012-02-08 2012-07-18 广州市环境保护工程设计院有限公司 一种抗生素制药废水的处理工艺
JP2013034962A (ja) * 2011-08-09 2013-02-21 Nippon Rensui Co Ltd 超純水の製造方法
US20140148625A1 (en) * 2010-12-07 2014-05-29 Exxonmobil Chemical Patents Inc. Processes Utilizing Solvent Extraction
EP2835355A4 (fr) * 2012-03-29 2015-12-16 Kubota Kk Système et procédé de traitement d'une solution de traitement anaérobie
CN107555683A (zh) * 2017-10-20 2018-01-09 苏州淡林环境科技有限公司 一种含dmac的高浓度有机废水预处理装置
CN108751534A (zh) * 2018-06-05 2018-11-06 上海问鼎环保科技有限公司 一种纳米硅溶胶生产废水资源化处理方法
CN111252932A (zh) * 2018-11-30 2020-06-09 广州中国科学院先进技术研究所 基于直接接触式微孔曝气强化的膜吸收脱氨方法及系统
US20200355586A1 (en) * 2017-11-28 2020-11-12 Organo Corporation Analyzing method and analyzing apparatus for urea

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3617545A (en) * 1969-03-13 1971-11-02 Thomson Csf Removing urea from saline water solutions particularly in an artificial kidney
US4307195A (en) * 1978-09-29 1981-12-22 Hitachi, Ltd. Immobilized enzyme membrane
US5156739A (en) * 1991-09-30 1992-10-20 Millipore Corporation System for purifying and degasifying water by reverse osmosis
US6022478A (en) * 1996-02-01 2000-02-08 Akzo Nobel N.V. Device and process for the substance-specific treatment of fluids
US6110375A (en) * 1994-01-11 2000-08-29 Millipore Corporation Process for purifying water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3617545A (en) * 1969-03-13 1971-11-02 Thomson Csf Removing urea from saline water solutions particularly in an artificial kidney
US4307195A (en) * 1978-09-29 1981-12-22 Hitachi, Ltd. Immobilized enzyme membrane
US5156739A (en) * 1991-09-30 1992-10-20 Millipore Corporation System for purifying and degasifying water by reverse osmosis
US6110375A (en) * 1994-01-11 2000-08-29 Millipore Corporation Process for purifying water
US6022478A (en) * 1996-02-01 2000-02-08 Akzo Nobel N.V. Device and process for the substance-specific treatment of fluids

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008096108A3 (fr) * 2007-02-06 2009-05-22 H2Oil & Gas Ltd Système de filtration
US8795527B2 (en) 2007-02-06 2014-08-05 H2Oil & Gas Ltd Filtration system
WO2008096108A2 (fr) 2007-02-06 2008-08-14 H2Oil & Gas Ltd Système de filtration
US9643902B2 (en) * 2010-12-07 2017-05-09 Exxonmobil Chemical Patents Inc. Processes utilizing solvent extraction
US20140148625A1 (en) * 2010-12-07 2014-05-29 Exxonmobil Chemical Patents Inc. Processes Utilizing Solvent Extraction
JP2013034962A (ja) * 2011-08-09 2013-02-21 Nippon Rensui Co Ltd 超純水の製造方法
CN102583880A (zh) * 2012-02-08 2012-07-18 广州市环境保护工程设计院有限公司 一种抗生素制药废水的处理工艺
EP2835355A4 (fr) * 2012-03-29 2015-12-16 Kubota Kk Système et procédé de traitement d'une solution de traitement anaérobie
CN107555683A (zh) * 2017-10-20 2018-01-09 苏州淡林环境科技有限公司 一种含dmac的高浓度有机废水预处理装置
US20200355586A1 (en) * 2017-11-28 2020-11-12 Organo Corporation Analyzing method and analyzing apparatus for urea
US11860075B2 (en) * 2017-11-28 2024-01-02 Organo Corporation Analyzing method and analyzing apparatus for urea
CN108751534A (zh) * 2018-06-05 2018-11-06 上海问鼎环保科技有限公司 一种纳米硅溶胶生产废水资源化处理方法
CN108751534B (zh) * 2018-06-05 2021-02-19 上海问鼎环保科技有限公司 一种纳米硅溶胶生产废水资源化处理方法
CN111252932A (zh) * 2018-11-30 2020-06-09 广州中国科学院先进技术研究所 基于直接接触式微孔曝气强化的膜吸收脱氨方法及系统
CN111252932B (zh) * 2018-11-30 2022-07-05 广州中国科学院先进技术研究所 基于直接接触式微孔曝气强化的膜吸收脱氨方法及系统

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