WO2003076560A1 - Color stable liquid dish cleaning compositions containing a peroxide source - Google Patents
Color stable liquid dish cleaning compositions containing a peroxide source Download PDFInfo
- Publication number
- WO2003076560A1 WO2003076560A1 PCT/US2003/006763 US0306763W WO03076560A1 WO 2003076560 A1 WO2003076560 A1 WO 2003076560A1 US 0306763 W US0306763 W US 0306763W WO 03076560 A1 WO03076560 A1 WO 03076560A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- surfactant
- composition
- dish cleaning
- liquid dish
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Definitions
- This invention relates to a color stable liquid dish cleaning composition which is designed to remove stains from surfaces, disinfect surfaces like dishes, countertops, sponges, while maintaining good foaming grease cutting, rinsing and mildness properties.
- the composition also exhibits excellent stability in terms of color and peroxide level.
- the present invention relates to novel color stable light duty liquid detergent compositions with high foaming and good grease cutting properties as well as disinfecting properties.
- 4,329,335 also discloses a shampoo containing a betaine surfactant as the major ingredient and minor amounts of a nonionic surfactant and of a fatty acid mono- or di- ethanolamide.
- U.S. Patent No. 4,259,204 discloses a shampoo comprising 0.8 to 20% by weight of an anionic phosphoric acid ester and one additional surfactant which may be either anionic, amphoteric, or nonionic.
- U.S. Patent No. 4,329,334 discloses an anionic-amphoteric based shampoo containing a major amount of anionic surfactant and lesser amounts of a betaine and nonionic surfactants.
- U.S. Patent No. 3,935,129 discloses a liquid cleaning composition containing an alkali metal silicate, urea, glycerin, triethanolamine, an anionic detergent and a nonionic detergent.
- the silicate content determines the amount of anionic and/or nonionic detergent in the liquid cleaning composition.
- the foaming properties of these detergent compositions are not discussed therein.
- U.S. Patent No. 4,129,515 discloses a heavy duty liquid detergent for laundering fabrics comprising a mixture of substantially equal amounts of anionic and nonionic surfactants, alkanolamines and magnesium salts, and, optionally, zwitterionic surfactants as suds modifiers.
- U.S. Patent No. 4,224,195 discloses an aqueous detergent composition for laundering socks or stockings comprising a specific group of nonionic detergents, namely, an ethylene oxide of a secondary alcohol, a specific group of anionic detergents, namely, a sulfuric ester salt of an ethylene oxide adduct of a secondary alcohol, and an amphoteric surfactant which may be a betaine, wherein either the anionic or nonionic surfactant may be the major ingredient.
- a specific group of nonionic detergents namely, an ethylene oxide of a secondary alcohol
- anionic detergents namely, a sulfuric ester salt of an ethylene oxide adduct of a secondary alcohol
- amphoteric surfactant which may be a betaine, wherein either the anionic or nonionic surfactant may be the major ingredient.
- the prior art also discloses detergent compositions containing all nonionic surfactants as shown in U.S. Patent Nos. 4,154,706 and 4,329,336 wherein the shampoo compositions contain a plurality of particular nonionic surfactants in order to affect desirable foaming and detersive properties despite the fact that nonionic surfactants are usually deficient in such properties.
- U.S. Patent No. 4,013,787 discloses a piperazine based polymer in conditioning and shampoo compositions which may contain all nonionic surfactant or all anionic surfactant.
- U.S. Patent No. 4,450,091 discloses high viscosity shampoo compositions containing a blend of an amphoteric betaine surfactant, a polyoxybutylenepolyoxyethylene nonionic detergent, an anionic surfactant, a fatty acid alkanolamide and a polyoxyalkylene glycol fatty ester. But, none of the exemplified compositions contain an active ingredient mixture wherein the nonionic detergent is present in major proportion which is probably due to the low foaming properties of the polyoxybutylene polyoxyethylene nonionic detergent.
- U.S. Patent No. 4,595,526 describes a composition comprising a nonionic surfactant, a betaine surfactant, an anionic surfactant and a C12-C14 fatty acid monoethanolamide foam stabilizer.
- an antibacterial liquid dish cleaning composition can be formulated with three different anionic surfactants, a zwitterionic surfactant, polyethylene glycol, a hydroxy aliphatic acid, a peracetic acid and water which has desirable cleaning and foaming properties.
- An object of this invention is to provide a liquid dish cleaning composition that can also be antibacterial, which comprises a sulfate surfactant, two sulfonate anionic surfactants, a zwitterionic surfactant, polyethylene glycol and a hydroxy aliphatic acid, wherein the composition does not contain any silicas, abrasives, acyl isoethionate, 2- hydroxy-4,2',4'-trichloridiphenyl ether, phosphoric acid, phosphonic acid, boric acid, alkali metal carbonates, alkaline earth metal carbonates, alkyl glycine surfactant, cyclic imidinium surfactant, or more than 3 wt. % of a fatty acid or salt thereof.
- Another object of this invention is to provide a liquid dish cleaning composition with desirable stain removal, high foaming and cleaning properties which kills bacteria.
- This invention relates to a color stable liquid dish cleaning composition that can also be antibacterial, which comprises approximately by weight:
- the balance being water, wherein the composition has a pH of 3 to 5 and has a viscosity of 100 to 1 ,000 cps, more preferably 200 to 600 cps at 25°C using a
- any grease release agents such as choline, chloride or buffering system which is a nitrogenous buffer which is ammonium or alkaline earth carbonate, amine oxide surfactants, guanidine derivates, alkoxylalkyl amines and alkyleneamines C3-C7 alkyl and alkenyl monobasic and dibasic acids such as C4-C7 aliphatic carboxylic diacids which do not contain a hydroxy group, boric acid, phosphoric acid, ethoxylated nonionic surfactants, amino aikylene phosphonic acid and alkyl polyglucoside surfactants and the composition is pourable and not a gel has a complex viscosity at 1 rads "1 of less than 0.4 Pascal seconds.
- anionic sulfonate surfactants which may be used in the detergent of this invention are selected from the consisting of water soluble and include the sodium, potassium, ammonium, magnesium and ethanolammonium salts of linear C8-C16 alkyl benzene sulfonates; C10-C20 paraffin sulfonates, alpha olefin sulfonates containing about 10-24 carbon atoms and C8-C18 alkyl sulfates and mixtures thereof.
- the paraffin sulfonates may be monosulfonates or di-sulfonates and usually are mixtures thereof, obtained by sulfonating paraffins of 10 to 20 carbon atoms.
- Preferred paraffin sulfonates are those of C12-I8 carbon atoms chains, and more preferably they are of C14-17 chains.
- Paraffin sulfonates that have the sulfonate group(s) distributed along the paraffin chain are described in U.S. Patents 2,503,280; 2,507,088; 3,260,744; and 3,372,188; and also in German Patent 735,096. Such compounds may be made to specifications and desirably the content of paraffin sulfonates outside the C-14-17 range will be minor and will be minimized, as will be any contents of di- or poly- sulfonates.
- Suitable other sulfonated anionic detergents are the well known higher alkyl mononuclear aromatic sulfonates, such as the higher alkylbenzene sulfonates containing 9 to 18 or preferably 9 to 16 carbon atoms in the higher alkyl group in a straight or branched chain, or C-8-15 alkyl toluene sulfonates.
- a preferred alkylbenzene sulfonate is a linear alkylbenzene sulfonate having a higher content of 3- phenyl (or higher) isomers and a correspondingly lower content (well below 50%) of 2- phenyl (or lower) isomers, such as those sulfonates wherein the benzene ring is attached mostly at the 3 or higher (for example 4, 5, 6 or 7) position of the alkyl group and the content of the isomers in which the benzene ring is attached in the 2 or 1 position is correspondingly low.
- Preferred materials are set forth in U.S. Patent
- the C8-18 ethoxylated alkyl ether sulfate surfactants have the structure
- n is about 1 to about 22 more preferably 1 to 3 and R is an alkyl group having about 8 to about 18 carbon atoms, more preferably 12 to 15 and natural cuts, for example, C-
- the ethoxylated alkyl ether sulfate may be made by sulfating the condensation product of ethylene oxide and Cs-10 alkanol, and neutralizing the resultant product.
- the ethoxylated alkyl ether sulfates differ from one another in the number of carbon atoms in the alcohols and in the number of moles of ethylene oxide reacted with one mole of such alcohol.
- Preferred ethoxylated alkyl ether polyethenoxy sulfates contain 12 to 15 carbon atoms in the alcohols and in the alkyl groups thereof, e.g., sodium myristyl (3 EO) sulfate.
- Ethoxylated C8-18 alkylphenyl ether sulfates containing from 2 to 6 moles of ethylene oxide in the molecule are also suitable for use in the invention compositions.
- These detergents can be prepared by reacting an alkyl phenol with 2 to 6 moles of ethylene oxide and sulfating and neutralizing the resultant ethoxylated alkylphenol.
- concentration of the ethoxylated alkyl ether sulfate surfactant is about 1 to about 8 wt. %.
- the water-soluble zwitterionic surfactant which is an essential ingredient of present liquid detergent composition, provides good foaming properties and mildness to the present nonionic based liquid detergent.
- the zwitterionic surfactant is a water soluble betaine having the general formula:
- is an alkyl group having 10 to 20 carbon atoms, preferably 12 to 16 carbon atoms, or the amido radical:
- R is an alkyl group having 9 to 19 carbon atoms and a is the integer 1 to 4;
- R2 and R3 are each alkyl groups having 1 to 3 carbons and preferably 1 carbon;
- R4 is an aikylene or hydroxyalkylene group having from 1 to 4 carbon atoms and, optionally, one hydroxyl group.
- Typical alkyldimethyl betaines include decyl dimethyl betaine or 2-(N- decyl-N, N-dimethyl-ammonia) acetate, coco dimethyl betaine or 2-(N-coco N, N- dimethylammonio) acetate, myristyl dimethyl betaine, palmityl dimethyl betaine, lauryl diemethyl betaine, cetyl dimethyl betaine, stearyl dimethyl betaine, etc.
- the amidobetaines similarly include cocoamidoethylbetaine, cocoamidopropyl betaine and the like.
- a preferred betaine is coco (Cs-C-is) amidopropyl dimethyl betaine.
- the hydroxy containing organic acid is preferably a hydroxy aliphatic acid selected from the group consisting of salicylic acid and citric acid and mixtures thereof.
- Polyethylene glycol which is used in the instant composition has a molecular weight of 200 to 1 ,000, wherein the polyethylene glycol has the structure HO(CH 2 CH 2 0) n H wherein n is 4 to 52.
- the concentration of the polyethylene glycol in the instant composition is 0.1% to 7 wt. %, more preferably 0.1 wt. % to 5 wt. %.
- the colorant which is a dye and/or pigment is selected from the group consisting of FD&C Yellow (CI15985), FD&C Red (40) (CM 6035), Acid Violet 43 (CI60730), Cl Pigment Blue (15.3) (Colonial Blue B26-130) (CI74160) and Cl Pigment Green 7 (CI74260) and mixtures thereof.
- the instant light duty liquid nonmicroemulsion compositions can contain about 0 wt. % to about 10 wt. %, more preferably about 1 wt. % to about 8 wt. %, of at least one solubilizing agent selected from the group consisting of a C-2-5 mono, dihydroxy or polyhydroxy alkanols such as ethanol, isopropanol, glycerol ethylene glycol, diethylene glycol, propylene glycol, and hexylene glycol and mixtures thereof and alkali metal cumene or xylene sulfonates such as sodium cumene sulfonate and sodium xylene sulfonate.
- the solubilizing agents are included in order to control low temperature cloud clear properties.
- alkali metal silicates and alkali metal builders such as alkali metal polyphosphates, alkali metal carbonates, alkali metal phosphonates and alkali metal citrates because these materials, if used in the instant composition, would cause the composition to have a higher pH.
- the final essential ingredient in the inventive compositions having improved interfacial tension properties is water.
- the proportion of water in the compositions generally is in the range of 10% to 95%.
- the liquid cleaning composition of this invention may, if desired, also contain other components either to provide additional effect or to make the product more attractive to the consumer.
- Colors or dyes in amounts up to 0.5% by weight; bactericides in amounts up to 1% by weight; preservatives, UV absorbers, or antioxidizing agents, such as formalin, 5-bromo-5-nitro- dioxan-1 ,3; 5-chloro-2-methyl-4-isothaliazolin-3-one, 2,6-di-tert.butyl-p-cresol, etc., in amounts up to 2% by weight; pH adjusting agents, such as sulfuric acid or sodium hydroxide, as needed.
- up to 4% by weight of an opacifier may be added.
- the instant compositions exhibit color stability at reduced and increased temperatures. More specifically, such compositions remains stable in the range of 0°C to 50°C, especially 5°C to 43°C. Such compositions exhibit a pH of 3 to 5.
- Example 1 The following compositions in wt. % were prepared by simple mixing procedure:
- Atlas Weather-o-meter a weather-o-meter instrument (supplier Atlas, model Ci35A) providing an irradiance of 0.35 W/m2 at 340 nm was utilized.
- the instrument uses a Xenon arc lamp that produces a stable power distribution which, when unfiltered, closely matches sunlight in outer space. With the proper filters, 1 borosilicate and 1 soda lime, the distribution closely matches sunlight through a window. According to the supplier 6.6 hours exposure from the Xe lamp corresponds to 1 day of sun in Miami, Florida. The products were placed in the Xe chamber a total of 32.8 k ⁇ /m2. (Note, this chamber irradiates 1.24 kJ/m2 of energy every hour.)
- Example 2 The following compositions in wt. % were prepared by simple mixing procedure:
- Example 3 Pigments or combinations of pigments/dyes can also be considered at the following level in the formula.
- compositions in wt. % were prepared by simple mixing procedure:
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003216527A AU2003216527A1 (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing a peroxide source |
IL16385803A IL163858A0 (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing peroxide source |
MXPA04008434A MXPA04008434A (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing a peroxide source. |
DE60301790T DE60301790D1 (en) | 2002-03-05 | 2003-03-05 | COLORABLE LIQUID DISPERSES WITH PEROXIDE SOURCE |
CA002478595A CA2478595A1 (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing a peroxide source |
EP03744192A EP1492862B1 (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing a peroxide source |
AT03744192T ATE305957T1 (en) | 2002-03-05 | 2003-03-05 | COLOR STABLE LIQUID DISHWASHING DETERGENT WITH PEROXIDE SOURCE |
NO20044206A NO20044206L (en) | 2002-03-05 | 2004-10-04 | Color stable liquid detergent containing a peroxide |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/090,702 | 2002-03-05 | ||
US10/090,702 US6475967B1 (en) | 2002-03-05 | 2002-03-05 | Liquid dish cleaning compositions containing a peroxide source |
US10/259,069 | 2002-09-27 | ||
US10/259,069 US6541436B1 (en) | 2002-03-05 | 2002-09-27 | Color stable liquid dish cleaning composition containing a peroxide source |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003076560A1 true WO2003076560A1 (en) | 2003-09-18 |
Family
ID=27807213
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/006763 WO2003076560A1 (en) | 2002-03-05 | 2003-03-05 | Color stable liquid dish cleaning compositions containing a peroxide source |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP1492862B1 (en) |
AT (1) | ATE305957T1 (en) |
AU (1) | AU2003216527A1 (en) |
CA (1) | CA2478595A1 (en) |
DE (1) | DE60301790D1 (en) |
IL (1) | IL163858A0 (en) |
MX (1) | MXPA04008434A (en) |
NO (1) | NO20044206L (en) |
PL (1) | PL372707A1 (en) |
WO (1) | WO2003076560A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004045281A3 (en) * | 2002-11-15 | 2004-09-30 | Virox Technologies Inc | Hydrogen peroxide disinfectant containing an acid and/or an alcohol |
WO2006021285A1 (en) * | 2004-08-25 | 2006-03-02 | Unilever Plc | Shading dyes |
AU2005244462B2 (en) * | 2004-05-14 | 2010-12-16 | Virox Technologies Inc. | Hydrogen peroxide-based skin disinfectant |
JP2012503090A (en) * | 2008-09-30 | 2012-02-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition exhibiting a two-color or multicolor effect |
US8637085B2 (en) | 2002-02-12 | 2014-01-28 | Virox Technologies Inc. | Enhanced activity hydrogen peroxide disinfectant |
US9233180B2 (en) | 2002-11-15 | 2016-01-12 | Virox Technologies Inc. | Hydrogen peroxide disinfectant containing a cyclic carboxylic acid and/or aromatic alcohol |
US9538760B2 (en) | 2011-10-05 | 2017-01-10 | Arkema Inc. | Disinfectant compositions with hydrogen peroxide |
US9737076B2 (en) | 2011-10-05 | 2017-08-22 | Arkema Inc. | Disinfectant compositions with hydrogen peroxide |
US10450535B2 (en) | 2017-10-18 | 2019-10-22 | Virox Technologies Inc. | Shelf-stable hydrogen peroxide antimicrobial compositions |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3469050B1 (en) * | 2016-06-13 | 2019-10-16 | Unilever N.V. | Foamable cleaning composition containing hydrogen peroxide |
WO2023198784A1 (en) * | 2022-04-14 | 2023-10-19 | Glaxosmithkline Consumer Healthcare (Uk) Ip Limited | Cleaning composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4224195A (en) * | 1976-04-28 | 1980-09-23 | Kabushiki Kaisha Tsumura Jutendo | Process for handwashing socks or stockings |
WO2000027990A1 (en) * | 1998-11-10 | 2000-05-18 | The Procter & Gamble Company | Bleaching compositions |
US6147039A (en) * | 1999-04-30 | 2000-11-14 | Colgate-Palmolive Company | Antibacterial liquid hand cleaning compositions containing a hydroxy containing organic acid |
US6306817B1 (en) * | 1997-07-21 | 2001-10-23 | The Procter & Gamble Co. | Alkylbenzenesulfonate surfactants |
US6326347B1 (en) * | 2001-08-06 | 2001-12-04 | Colgate-Palmolive Co. | Reddish peach colored stable liquid cleaning composition comprising red dye and lactic acid |
US6444636B1 (en) * | 2001-12-10 | 2002-09-03 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing hydrogen peroxide |
-
2003
- 2003-03-05 CA CA002478595A patent/CA2478595A1/en not_active Abandoned
- 2003-03-05 PL PL03372707A patent/PL372707A1/en not_active IP Right Cessation
- 2003-03-05 WO PCT/US2003/006763 patent/WO2003076560A1/en not_active Application Discontinuation
- 2003-03-05 EP EP03744192A patent/EP1492862B1/en not_active Expired - Lifetime
- 2003-03-05 IL IL16385803A patent/IL163858A0/en unknown
- 2003-03-05 AT AT03744192T patent/ATE305957T1/en not_active IP Right Cessation
- 2003-03-05 AU AU2003216527A patent/AU2003216527A1/en not_active Abandoned
- 2003-03-05 DE DE60301790T patent/DE60301790D1/en not_active Expired - Lifetime
- 2003-03-05 MX MXPA04008434A patent/MXPA04008434A/en active IP Right Grant
-
2004
- 2004-10-04 NO NO20044206A patent/NO20044206L/en not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4224195A (en) * | 1976-04-28 | 1980-09-23 | Kabushiki Kaisha Tsumura Jutendo | Process for handwashing socks or stockings |
US6306817B1 (en) * | 1997-07-21 | 2001-10-23 | The Procter & Gamble Co. | Alkylbenzenesulfonate surfactants |
WO2000027990A1 (en) * | 1998-11-10 | 2000-05-18 | The Procter & Gamble Company | Bleaching compositions |
US6147039A (en) * | 1999-04-30 | 2000-11-14 | Colgate-Palmolive Company | Antibacterial liquid hand cleaning compositions containing a hydroxy containing organic acid |
US6326347B1 (en) * | 2001-08-06 | 2001-12-04 | Colgate-Palmolive Co. | Reddish peach colored stable liquid cleaning composition comprising red dye and lactic acid |
US6444636B1 (en) * | 2001-12-10 | 2002-09-03 | Colgate-Palmolive Company | Liquid dish cleaning compositions containing hydrogen peroxide |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8637085B2 (en) | 2002-02-12 | 2014-01-28 | Virox Technologies Inc. | Enhanced activity hydrogen peroxide disinfectant |
US8999400B2 (en) | 2002-02-12 | 2015-04-07 | Virox Technologies Inc. | Enhanced activity hydrogen peroxide disinfectant |
US9233180B2 (en) | 2002-11-15 | 2016-01-12 | Virox Technologies Inc. | Hydrogen peroxide disinfectant containing a cyclic carboxylic acid and/or aromatic alcohol |
WO2004045281A3 (en) * | 2002-11-15 | 2004-09-30 | Virox Technologies Inc | Hydrogen peroxide disinfectant containing an acid and/or an alcohol |
AU2005244462B2 (en) * | 2004-05-14 | 2010-12-16 | Virox Technologies Inc. | Hydrogen peroxide-based skin disinfectant |
US8808755B2 (en) | 2004-05-14 | 2014-08-19 | Virox Technologies Inc. | Hydrogen peroxide-based skin disinfectant |
US9198935B2 (en) | 2004-05-14 | 2015-12-01 | Virox Technologies Inc. | Hydrogen peroxide-based skin disinfectant |
WO2006021285A1 (en) * | 2004-08-25 | 2006-03-02 | Unilever Plc | Shading dyes |
JP2012503090A (en) * | 2008-09-30 | 2012-02-02 | ザ プロクター アンド ギャンブル カンパニー | Liquid detergent composition exhibiting a two-color or multicolor effect |
US9538760B2 (en) | 2011-10-05 | 2017-01-10 | Arkema Inc. | Disinfectant compositions with hydrogen peroxide |
US9737076B2 (en) | 2011-10-05 | 2017-08-22 | Arkema Inc. | Disinfectant compositions with hydrogen peroxide |
US10450535B2 (en) | 2017-10-18 | 2019-10-22 | Virox Technologies Inc. | Shelf-stable hydrogen peroxide antimicrobial compositions |
US10968417B2 (en) | 2017-10-18 | 2021-04-06 | Diversey, Inc. | Shelf-stable hydrogen peroxide antimicrobial compositions |
Also Published As
Publication number | Publication date |
---|---|
NO20044206L (en) | 2004-10-04 |
ATE305957T1 (en) | 2005-10-15 |
MXPA04008434A (en) | 2004-11-26 |
EP1492862B1 (en) | 2005-10-05 |
CA2478595A1 (en) | 2003-09-18 |
PL372707A1 (en) | 2005-07-25 |
EP1492862A1 (en) | 2005-01-05 |
IL163858A0 (en) | 2005-12-18 |
AU2003216527A1 (en) | 2003-09-22 |
DE60301790D1 (en) | 2006-02-16 |
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