WO2003074743A3 - Process for bismuth recovery from lead-bismuth dross - Google Patents

Process for bismuth recovery from lead-bismuth dross Download PDF

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Publication number
WO2003074743A3
WO2003074743A3 PCT/CA2003/000287 CA0300287W WO03074743A3 WO 2003074743 A3 WO2003074743 A3 WO 2003074743A3 CA 0300287 W CA0300287 W CA 0300287W WO 03074743 A3 WO03074743 A3 WO 03074743A3
Authority
WO
WIPO (PCT)
Prior art keywords
bismuth
lead
enriched
dross
containing material
Prior art date
Application number
PCT/CA2003/000287
Other languages
French (fr)
Other versions
WO2003074743A2 (en
Inventor
Rui-Qing Li
Ralph Harris
Original Assignee
Univ Mcgill
Rui-Qing Li
Ralph Harris
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Mcgill, Rui-Qing Li, Ralph Harris filed Critical Univ Mcgill
Priority to AU2003208205A priority Critical patent/AU2003208205A1/en
Publication of WO2003074743A2 publication Critical patent/WO2003074743A2/en
Publication of WO2003074743A3 publication Critical patent/WO2003074743A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B30/00Obtaining antimony, arsenic or bismuth
    • C22B30/06Obtaining bismuth
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B13/00Obtaining lead
    • C22B13/02Obtaining lead by dry processes
    • C22B13/025Recovery from waste materials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/04Working-up slag
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

A process for recovering bismuth, from lead-bismuth containing material, which is characterized by a series of steps of selective oxidation of lead from said material with the addition of at least one slag forming agent which produces a lead-enriched bismuth-poor slag and an enriched-bismuth product. The slag forming agents are chosen from a group which selectively stabilize Pb while rejecting Bi at the oxygen activity levels required to stabilize the Pb. Typically the process includes a pretreatment process where calcium and magnesium content of the lead-bismuth containing material is reduced and an post-treatment where chlorine is added to remove the residual lead, and obtain a high purity bismuth metal.
PCT/CA2003/000287 2002-03-01 2003-02-28 Process for bismuth recovery from lead-bismuth dross WO2003074743A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003208205A AU2003208205A1 (en) 2002-03-01 2003-02-28 Process for bismuth recovery from lead-bismuth dross

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36081602P 2002-03-01 2002-03-01
US60/360,816 2002-03-01

Publications (2)

Publication Number Publication Date
WO2003074743A2 WO2003074743A2 (en) 2003-09-12
WO2003074743A3 true WO2003074743A3 (en) 2007-10-18

Family

ID=27789030

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2003/000287 WO2003074743A2 (en) 2002-03-01 2003-02-28 Process for bismuth recovery from lead-bismuth dross

Country Status (2)

Country Link
AU (1) AU2003208205A1 (en)
WO (1) WO2003074743A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2738036C2 (en) * 2020-04-13 2020-12-07 Виталий Евгеньевич Дьяков Method for purification of bismuth by zone melting, covering flux and apparatus for implementation of zone melting method

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100413984C (en) * 2006-09-26 2008-08-27 郴州市三和有色金属有限公司 Impurity removing refining process of high pure bismuth
CN101570825B (en) * 2009-06-03 2010-07-28 郴州雄风稀贵金属材料股份有限公司 Process for selectively preparing bismuth-based nanometer materials from crude bismuth by reduced-pressure evaporation method
RU2514766C2 (en) * 2012-06-05 2014-05-10 Федеральное государственное бюджетное учреждение науки Институт неорганической химии Сибирского отделения Российской академии наук (ИНХ СО РАН) Method of bismuth treatment
RU2660444C1 (en) * 2017-05-30 2018-07-06 Федеральное государственное бюджетное учреждение науки Институт металлургии Уральского отделения Российской академии наук (ИМЕТ УрО РАН) Method of processing germanium containing materials
CN108796241A (en) * 2018-07-13 2018-11-13 中南大学 A method of the starch reduction-oxidation lead in low-temperature molten salt
CN108823432A (en) * 2018-07-13 2018-11-16 中南大学 A method of the starch reduction-oxidation antimony in low-temperature molten salt
CN115961152A (en) * 2022-12-02 2023-04-14 中南大学 Preparation method of high-purity metal bismuth

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955931A (en) * 1957-11-12 1960-10-11 American Metal Climax Inc Refining of bismuth alloys by halogenation
WO1981001297A1 (en) * 1979-11-06 1981-05-14 Boliden Ab A method of purifying non-ferrous metal melts from foreign elements
JPS61174341A (en) * 1985-01-29 1986-08-06 Mitsubishi Metal Corp Method for refining slime produced by electrolysis of copper
US4734129A (en) * 1985-06-10 1988-03-29 Britannia Refined Metals Limited Recovery of metals from their alloys with lead using consummable lance and apparatus
US5234492A (en) * 1992-04-14 1993-08-10 Asarco Incorporated Refining of bismuth

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955931A (en) * 1957-11-12 1960-10-11 American Metal Climax Inc Refining of bismuth alloys by halogenation
WO1981001297A1 (en) * 1979-11-06 1981-05-14 Boliden Ab A method of purifying non-ferrous metal melts from foreign elements
JPS61174341A (en) * 1985-01-29 1986-08-06 Mitsubishi Metal Corp Method for refining slime produced by electrolysis of copper
US4734129A (en) * 1985-06-10 1988-03-29 Britannia Refined Metals Limited Recovery of metals from their alloys with lead using consummable lance and apparatus
US5234492A (en) * 1992-04-14 1993-08-10 Asarco Incorporated Refining of bismuth

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 010, no. 383 (C - 393) 23 December 1986 (1986-12-23) *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2738036C2 (en) * 2020-04-13 2020-12-07 Виталий Евгеньевич Дьяков Method for purification of bismuth by zone melting, covering flux and apparatus for implementation of zone melting method

Also Published As

Publication number Publication date
AU2003208205A8 (en) 2003-09-16
AU2003208205A1 (en) 2003-09-16
WO2003074743A2 (en) 2003-09-12

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