WO2003062515A2 - Dyeing and finishing of modal fabrics - Google Patents
Dyeing and finishing of modal fabrics Download PDFInfo
- Publication number
- WO2003062515A2 WO2003062515A2 PCT/GB2003/000171 GB0300171W WO03062515A2 WO 2003062515 A2 WO2003062515 A2 WO 2003062515A2 GB 0300171 W GB0300171 W GB 0300171W WO 03062515 A2 WO03062515 A2 WO 03062515A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fabric
- acid
- process according
- modal
- dyeing
- Prior art date
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 106
- 238000004043 dyeing Methods 0.000 title claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 51
- 238000000034 method Methods 0.000 claims abstract description 33
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000009981 jet dyeing Methods 0.000 claims abstract description 9
- 229920001407 Modal (textile) Polymers 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 238000011282 treatment Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 238000005470 impregnation Methods 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 238000009988 textile finishing Methods 0.000 claims description 2
- 206010061592 cardiac fibrillation Diseases 0.000 description 13
- 230000002600 fibrillogenic effect Effects 0.000 description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 229920003043 Cellulose fiber Polymers 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000000975 dye Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 239000004627 regenerated cellulose Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000009991 scouring Methods 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 229920000433 Lyocell Polymers 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 229960002337 magnesium chloride Drugs 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 linen Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- RTLULCVBFCRQKI-UHFFFAOYSA-N 1-amino-4-[3-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-sulfoanilino]-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC1=NC(Cl)=NC(Cl)=N1 RTLULCVBFCRQKI-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 229940087810 eco-soft Drugs 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229920004935 Trevira® Polymers 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/02—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fibres, slivers or rovings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/81—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron; with boron halides; with fluoroborates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67358—Halides or oxyhalides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
Definitions
- This invention relates to a process for the dyeing and finishing of certain regenerated cellulose fabrics, specifically modal fabrics.
- modal fabric means a fabric woven or knitted from staple fibre yarns comprising regenerated cellulose fibres of the modal type.
- Modal fibres are defined in International Standard ISO 2076: 1999(E) and are high wet-modulus, high breaking- strength regenerated cellulose fibres produced using particular viscose and regeneration bath compositions which allow greater molecular orientation during stretch coagulation of the fibres .
- Another regenerated cellulose fibre of the modal type again with high wet modulus and high breaking strength, is known as a polynosic fibre and was developed in Japan by the Tachikawa Company. Both modal and polynosic fibres are often referred to as high wet- modulus (HWM) fibres because that is their significant characteristic compared with ordinary viscose fibres.
- HWM high wet- modulus
- the staple fibre yarns used may comprise just modal-type fibres or a blend of modal-type fibres with one or more other fibre types such as cotton, linen, polyester and nylon.
- the fabrics may additionally include yarns which do not incorporate modal-type fibres, for example yarns of the other fibre types referred to and blends thereof.
- Regenerated cellulose fibres are produced by forming cellulose into a soluble chemical derivative and then extruding a solution of this derivative through a spinning jet into a bath which regenerates the extrudate as cellulose fibres. Viscose fibres are produced in this way. Particular spinning conditions and formulations are used to produce the high wet-modulus regenerated cellulose fibres known as modal and polynosic fibres and referred to herein as modal-type fibres .
- Lyocell fibres which are solvent-spun cellulose fibres, not regenerated cellulose fibres (see ISO 2076: 1999 (E) ) , were introduced commercially relatively recently. Lyocell fibres have a tendency to fibrillate during vigorous dyeing and finishing processes, and much effort has been put into controlling this phenomenon. In particular, treatments have been developed to remove the relatively long protruding fibre ends which are formed in the first stage of the fibrillation process (so-called "primary fibrillation") and which otherwise produce a hairy effect, often matted, on the surface of the fabric and thus disfigure its appearance. On the other hand, the development of the shorter fibrils which are formed in the fibrillation process (so-called “secondary fibrillation”) is encouraged.
- These shorter fibrils create a surface finish which is characterised as being “clean”, in the sense of being substantially free from a hairy effect, and as having a soft touch imparted by the shorter fibrils on the fabric surface and which is referred to as a "soft-touch finish”.
- a soft-touch finish When the shorter fibrils are sufficiently developed, the soft touch of the fabric surface is more pronounced and the soft-touch finish is referred to as a "peach-touch finish”. Examples of such treatments for lyocell fabrics are described in WO 95/30043, WO 97/30204, and GB 2314568.
- modal fibres themselves are less susceptible to fibrillation than lyocell fibres .
- fibrillation can be induced in such modal fibres by vigorous processing, controlling the fibrillation to produce the desired clean, soft-touch finish to a commercially acceptable standard has proved difficult.
- Polynosic fibres fibrillate more easily than modal fibres but, again, controlling the fibrillation to produce the desired surface finish is difficult.
- the present invention aims to provide modal fabrics as defined with a clean, soft-touch finish which is consistently reproducible to a commercial standard.
- the present invention provides a process for producing a dyed and finished modal fabric having a clean, soft-touch surface finish by carrying out the steps of dyeing, washing and drying the fabric using vigorous action on the fabric in at least one of the steps, characterised in that, before the dyeing step is carried out, the fabric is evenly impregnated with an aqueous solution of an acid or acid donor and is then heat treated in a gaseous atmosphere to activate the action of the acid or acid donor, whereby the dyed and finished fabric has a clean, soft-touch surface finish.
- the soft-touch finish achieved may be a peach-touch finish.
- the ability of the process of the invention to deliver dyed modal fabrics having a clean, soft-touch finish after a vigorous processing step such as jet dyeing or rotary tumbling is of commercial importance. It means that the fabric can be processed on existing equipment using normal process routines without the need for extended processing times. For example, a dyeing cycle of six hours or less may be used in a jet dyeing machine. Suitable jet dyeing machines include machines known as Thies Ecosoft, Thies Soft TRD, Gaston County Futura, and Hisaka Circular CUT-SL.
- Conventional dyes and dye recipes for modal fabrics may be used in the process of the invention, including those based on direct dyes, vat dyes, sulphur dyes and reactive dyes.
- the process of the invention can also be used in respect of the dyeing and finishing of piece goods or garments made from modal fabrics .
- Garments made from modal fabrics can benefit by acquiring a desirable clean, soft-touch finish on the surface of the garment .
- the application of the solution of the acid or acid donor and the subsequent heat treatment step may be applied to the modal fabric prior to its being converted into piece goods or garments. However, it may also be applied to the piece goods or garments after conversion.
- the solution of the acid or acid donor is preferably an aqueous solution.
- the fabric may be evenly impregnated with this solution using any of the conventional techniques for applying liquids to fabric.
- Fabric in the length may be passed in open width through a pad bath of the aqueous solution, usually with a wet pick-up of the solution in the range 65 to ' 80 per cent by weight on weight of fabric.
- Piece goods such as garments may be immersed in the solution in a vessel such as a drum washing machine.
- the acid or acid donor is preferably a weak acid of the type used as a catalyst for resins used in textile finishing processes. Usually, these have a pH of greater than about 3. Suitable acids or acid donors include organic acids such as citric acid and tartaric acid, and Lewis acids.
- Magnesium chloride, ammonium chloride, zinc chloride, zinc fluoroborate and zinc nitrate are suitable weak acids or acid donors . Mixtures of two or more of these compounds may also be used and, indeed, manufacturers of acid catalysts for resin finishing sometimes use mixtures in their catalyst formulations.
- An example of a commercial product which can be used in the process of the invention is Condensol FB (trade mark of BASF AG) , an acid catalyst comprising a mixture of magnesium chloride and zinc fluoroborate.
- Preferred solution concentrations of the acid or acid donor depend upon the particular acid or acid donor used, lower concentrations with highly active materials to avoid unwanted acid damage to the fabric and higher concentrations with less active materials.
- Organic acids can be used in the concentration range of about 2 to 20 g/1, for example about 4 to 6 g/1 in the case of citric acid.
- Citric acid applied at a concentration of 4 g/1 has a pH of 3.2.
- Less active acids or acid donors may use greater concentrations, for example up to about 40 g/1.
- Magnesium chloride applied at a concentration of 20 g/1 has a pH of 7.5. Unnecessarily large concentrations are preferably to be avoided in all cases to prevent unwanted acid damage to the fabric and to minimise chemical usage.
- the impregnated fabric is then heat-treated in a gaseous atmosphere, for example in a hot air oven. It may previously be dried in a separate step but preferably the drying is just the initial stage of the heating step.
- the modal fabric preferably is treated in open width, for example on a stenter passing through a heating oven or chamber.
- the temperature of the gaseous atmosphere used in the heat treatment is chosen to be effective in initiating the action of the particular acid or acid donor used. In general, a range of 120°C to 220°C is suitable, more preferably a range of 140 °C to 200 °C. Again, preferred processing times depend upon the particular acid or acid donor used but are usually in the range 30 seconds to 5 minutes. Any residual acid may be removed by washing or scouring the heat-treated fabric and then re-drying it.
- the fabric preferably is subjected to a desizing or scouring operation, usually carried out prior to the impregnation with the acid or acid donor. This may be a conventional operation in which the fabric is passed through a scouring bath to remove the size or lubricant. If pre-bleaching of the fabric is required, then it is preferred that this is carried out prior to the impregnation with the acid or acid donor .
- Another possible treatment of the fabric is a so-called causticising treatment with an aqueous sodium hydroxide solution.
- This should be carried out after the impregnation with the acid or acid donor and the subsequent heat treatment but before the dyeing step.
- Causticising is carried out to improve the flexibility of the fabric in the wet state.
- Causticising also enhances dyeability of the fabric, which may be depressed by the acid treatment, and has the further effect that the fabric is tightened in structure, which helps to reduce any propensity for shrinkage in later wet processing.
- the fabric should be thoroughly rinsed with hot and then cold water to remove residual caustic soda.
- the dyed fabric may be given one or more conventional finishing treatments, including application of a soft-finish by a conventional padding operation. This may be carried out after the dyeing and washing processes without the need for any intermediate drying of the fabric. If a wet tumbling treatment is required to develop a soft-touch finish, this may be carried out in a rotary tumbling machine after dyeing, either together with or after any soft finish treatment. The finished fabric may then be given a final drying, for example in a tumble-drying machine.
- a modal fabric comprised a woven fabric of basis weight 180 gsm (grams per square metre) constructed in a 2 by 1 twill weave from yarns of count l/20s Ne comprising 100 per cent high wet-modulus modal fibres of 1.3 dtex (HWM Modal fibres ex Lenzing AG) .
- the fabric was scoured in open width using an aqueous scour bath containing a non-ionic detergent and sodium carbonate and at a temperature of 90° C, and it was then dried on a stenter at a temperature of 100°C.
- Half of the scoured fabric was reserved as a control and the other half was impregnated by padding with an aqueous solution of 14 g/1 of magnesium chloride hexahydrate and 1.0 g/1 of a wetting agent, Kieralon JET (Kieralon is a trademark of BASF AG) , at 80 per cent wet pick-up.
- the impregnated fabric was stentered and dried at a temperature of 110° C and then heat treated in air at a temperature of 190° C for 50 seconds.
- the treated fabric and the control fabric were then each dyed and finished using the same regime. Dyeing was carried out on a Gaston County Futura jet dyeing machine over a period of 6 hours using an aqueous dyebath containing :-
- Procion H-EXL dye at 4.0 per cent owf (on weight of fabric) (Procion is a trademark of Dystar AG) , Sodium sulphate at 60g/l, Soda ash at 20 g/1.
- the dyed fabrics were rinsed with water to remove unfixed dye, softened using Edunine CSA (Edunine is a trademark of Uniqema) at 2.0 per cent owf applied from an aqueous bath at a temperature of 40° C, and then tumble-dried in a Thies Rototu bler fabric tumbling machine.
- Edunine CSA is a trademark of Uniqema
- control fabric was unfibrillated and had a normal smooth surface.
- the treated fabric had developed a clean, soft-touch finish.
- a modal fabric comprised a woven fabric of basis weight 180 gsm constructed in a 2 by 1 twill weave from yarns of count l/20s Ne comprising 100 per cent high wet-modulus fibres of the modal type of 1.3 dtex (HWM Modal fibres ex Lenzing AG)
- the fabric was scoured in open width using an aqueous scour bath containing a non-ionic detergent and sodium carbonate and at a temperature of 90°C, and then it was dried on a stenter at a temperature of 100°C.
- the desized fabric was then evenly impregnated with an aqueous solution of citric acid at a concentration of 4.0 g/1 by uniformly squeezing the solution into the fabric using a pad mangle at an expression of 75 per cent wet pick-up.
- the impregnated fabric was dried and heat- treated on a stenter frame in air at a temperature of 160°C for 5.0 minutes. After thorough rinsing with water and drying, the treated fabric was ready for dyeing. Dyeing was carried out in a Thies Ecosoft Plus jet dyeing machine. In addition to the treated fabric, an untreated but desized control fabric of the same specification was also dyed and finished as hereinafter set out.
- the dyeing method used was a hot-exhaust migration dyeing method carried out over a period of 6 hours using an aqueous dyebath containing :- Procion Navy H-EXL dye at 4.0 per cent owf, Sodium sulphate at 60g/l, Soda ash at 20g/l.
- the dyed fabrics were treated with a soft finish, Edunine CSA, at 20 per cent owf applied from an aqueous bath at a temperature of 40°C, before being tumble-dried in a fabric rope tumbler (Biancalani Aero 1000) .
- the dyed control fabric was unfibrillated and had a normal smooth surface.
- the treated fabric had developed a degree of fibrillation of the short, secondary fibrillation type, which gave it a clean, soft-touch surface having the characteristic of a peach-touch finish.
- a modal fabric comprised a double jersey interlock fabric knitted from yarn of count 1/20s Ne.
- the yarn comprised a 70:30 blend by weight of polynosic fibres and polyester fibres of which the polynosic fibres were of 1.7 dtex and 38mm staple length (Junalon fibres ex Fujibo) and the polyester fibres were of 1.5 dtex and 38mm staple length (Trevira type 140 fibres ex Hoechst AG) .
- the fabric was slit to open width and divided, with part being kept as an untreated control and part being impregnated in a pad bath at 80 per cent wet pick-up with an aqueous solution containing 14 g/1 magnesium chloride and 1.0 per cent Kieralon JET.
- the impregnated fabric was then placed on a stenter and dried in air at a temperature of 110°C before being heat treated in air at a temperature of 190°C for 45 seconds.
- the treated fabric and the control fabric were then individually subjected to the following scouring, dyeing, softening and drying regime. Scouring was carried out using an aqueous solution of a nonionic detergent and sodium carbonate at a temperature of 90°C for 30 minutes. The fabrics were then rinsed in water before being dyed over a period of 6 hours in a jet dyeing machine as described in Example 1 using the same dyebath recipe but with the dye at 3.0 per cent owf.
- the dyed fabrics were treated with a soft finish, Sandoperm MEJ (Sandoperm is a trademark of Clariant AG) , at 2.0 per cent owf from an aqueous bath at a temperature of 40°C and were then tumble- dried in a Biancalani Aero 1000 fabric rope tumbler.
- Sandoperm MEJ Sandoperm is a trademark of Clariant AG
- the dyed control fabric had a somewhat matted surface appearance created by uncontrolled fibrillation.
- the fabric treated according to the invention had a soft peach-touch finish and a uniform, clean appearance free from long fibrils and visible crease marks.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003202038A AU2003202038A1 (en) | 2002-01-17 | 2003-01-16 | Dyeing and finishing of modal fabrics |
KR1020047010439A KR100963697B1 (en) | 2002-01-17 | 2003-01-16 | Dyeing and finishing of modal fabrics |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0201066A GB2384249A (en) | 2002-01-17 | 2002-01-17 | Dyeing & finishing of regenerated cellulose fabric with controlled fibrillation involving treatment with acid or acid donor then heat in gaseous atmosphere |
GB0201066.8 | 2002-01-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2003062515A2 true WO2003062515A2 (en) | 2003-07-31 |
WO2003062515A3 WO2003062515A3 (en) | 2004-10-07 |
Family
ID=9929267
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2003/000171 WO2003062515A2 (en) | 2002-01-17 | 2003-01-16 | Dyeing and finishing of modal fabrics |
Country Status (5)
Country | Link |
---|---|
KR (1) | KR100963697B1 (en) |
CN (1) | CN1301356C (en) |
AU (1) | AU2003202038A1 (en) |
GB (1) | GB2384249A (en) |
WO (1) | WO2003062515A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130267140A1 (en) * | 2010-11-24 | 2013-10-10 | Lenzing Ag | Flame resistant fabric for protective clothing |
CN103767200A (en) * | 2014-01-06 | 2014-05-07 | 浙江金三发粘合衬有限公司 | Preparation process of modal double-point liner |
WO2021180817A1 (en) | 2020-03-12 | 2021-09-16 | Lenzing Aktiengesellschaft | Method for reducing the pilling behaviour of a fabric containing or consisting of man-made cellulosic fibers |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT512460B1 (en) * | 2011-11-09 | 2013-11-15 | Chemiefaser Lenzing Ag | Dispersible non-woven textiles |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994020656A1 (en) * | 1993-03-10 | 1994-09-15 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
WO1995030043A1 (en) * | 1994-05-03 | 1995-11-09 | Courtaulds Fibres (Holdings) Limited | Lyocell fabric treatment to reduce fibrillation tendency |
GB2314568A (en) * | 1996-06-28 | 1998-01-07 | Courtaulds Fibres | Fibre finishing treatment |
WO1999040251A1 (en) * | 1998-02-03 | 1999-08-12 | Acordis Fibres (Holdings) Limited | Improvements in dyeing and finishing of cellulosic fabric |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB833284A (en) * | 1956-05-31 | 1960-04-21 | American Viscose Corp | Improving the resistance to soiling of regenerated cellulose |
GB930133A (en) * | 1959-02-12 | 1963-07-03 | Courtaulds Ltd | Improvements in the treatment of cellulose materials |
NL261875A (en) * | 1960-03-02 | |||
GB1050794A (en) * | 1963-03-25 |
-
2002
- 2002-01-17 GB GB0201066A patent/GB2384249A/en not_active Withdrawn
-
2003
- 2003-01-16 KR KR1020047010439A patent/KR100963697B1/en active IP Right Grant
- 2003-01-16 CN CNB038023539A patent/CN1301356C/en not_active Expired - Fee Related
- 2003-01-16 WO PCT/GB2003/000171 patent/WO2003062515A2/en not_active Application Discontinuation
- 2003-01-16 AU AU2003202038A patent/AU2003202038A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994020656A1 (en) * | 1993-03-10 | 1994-09-15 | Courtaulds Fibres (Holdings) Limited | Fibre treatment |
WO1995030043A1 (en) * | 1994-05-03 | 1995-11-09 | Courtaulds Fibres (Holdings) Limited | Lyocell fabric treatment to reduce fibrillation tendency |
GB2314568A (en) * | 1996-06-28 | 1998-01-07 | Courtaulds Fibres | Fibre finishing treatment |
WO1999040251A1 (en) * | 1998-02-03 | 1999-08-12 | Acordis Fibres (Holdings) Limited | Improvements in dyeing and finishing of cellulosic fabric |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130267140A1 (en) * | 2010-11-24 | 2013-10-10 | Lenzing Ag | Flame resistant fabric for protective clothing |
CN103767200A (en) * | 2014-01-06 | 2014-05-07 | 浙江金三发粘合衬有限公司 | Preparation process of modal double-point liner |
CN103767200B (en) * | 2014-01-06 | 2015-11-18 | 浙江金三发粘合衬有限公司 | A kind of preparation technology of Modal two point lining |
WO2021180817A1 (en) | 2020-03-12 | 2021-09-16 | Lenzing Aktiengesellschaft | Method for reducing the pilling behaviour of a fabric containing or consisting of man-made cellulosic fibers |
Also Published As
Publication number | Publication date |
---|---|
GB0201066D0 (en) | 2002-03-06 |
CN1617963A (en) | 2005-05-18 |
KR20040076879A (en) | 2004-09-03 |
AU2003202038A1 (en) | 2003-09-02 |
KR100963697B1 (en) | 2010-06-14 |
GB2384249A (en) | 2003-07-23 |
WO2003062515A3 (en) | 2004-10-07 |
CN1301356C (en) | 2007-02-21 |
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