WO2003057496A1 - Heat-sensitive recording material - Google Patents

Heat-sensitive recording material Download PDF

Info

Publication number
WO2003057496A1
WO2003057496A1 PCT/JP2002/013394 JP0213394W WO03057496A1 WO 2003057496 A1 WO2003057496 A1 WO 2003057496A1 JP 0213394 W JP0213394 W JP 0213394W WO 03057496 A1 WO03057496 A1 WO 03057496A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat
sensitive recording
electron
recording layer
support
Prior art date
Application number
PCT/JP2002/013394
Other languages
French (fr)
Japanese (ja)
Inventor
Masayuki Iwasaki
Tsutomu Watanabe
Hirofumi Mitsuo
Original Assignee
Fuji Photo Film Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2001388128A external-priority patent/JP3833935B2/en
Priority claimed from JP2001387677A external-priority patent/JP2003182228A/en
Priority claimed from JP2001387597A external-priority patent/JP2003182226A/en
Priority claimed from JP2001387593A external-priority patent/JP3526294B2/en
Application filed by Fuji Photo Film Co., Ltd. filed Critical Fuji Photo Film Co., Ltd.
Priority to EP02786188A priority Critical patent/EP1466750A4/en
Priority to KR10-2004-7009765A priority patent/KR20040065301A/en
Priority to US10/499,514 priority patent/US20060046933A1/en
Publication of WO2003057496A1 publication Critical patent/WO2003057496A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/333—Colour developing components therefor, e.g. acidic compounds
    • B41M5/3333—Non-macromolecular compounds
    • B41M5/3335—Compounds containing phenolic or carboxylic acid groups or metal salts thereof
    • B41M5/3336—Sulfur compounds, e.g. sulfones, sulfides, sulfonamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/333—Colour developing components therefor, e.g. acidic compounds
    • B41M5/3333—Non-macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/337—Additives; Binders
    • B41M5/3377—Inorganic compounds, e.g. metal salts of organic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/04—Direct thermal recording [DTR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/323—Organic colour formers, e.g. leuco dyes
    • B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
    • B41M5/3275—Fluoran compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/337—Additives; Binders
    • B41M5/3372—Macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/337—Additives; Binders
    • B41M5/3375—Non-macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/41—Base layers supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)

Abstract

A heat-sensitive recording material having a support and, formed thereon, a heat-sensitive recording layer containing an electron-donating colorless dye and an electron-accepting compound which reacts with the electron-donating colorless dye to effect coloring. Preferred embodiments include an embodiment wherein the electron-accepting compound is a compound represented by the formula: R1-Ph-SO2R2, an embodiment wherein it exhibits a maximum curl height of 5.0 mm or less, an embodiment wherein an image density is 1.20 or more when the image is heat-printed with an application energy of 15.2 mJ/mm2 from the heat-sensitive recording layer side of the support, an embodiment wherein a static coefficient and a dynamic coefficient between the front surface of the material having at least one above heat-sensitive recording layer and the back surface thereof are in the range of 0.2 to 0.5, and an embodiment wherein the layer contains a pigment exhibiting an oil absorption for a boiled linseed oil of 30 to 200 ml/100 g and having a volume average particle diameter of 0.5 to 3 μm, and the material is used in a recording device capable of heat-printing at a rate of 10 cm/sec or more.
PCT/JP2002/013394 2001-12-20 2002-12-20 Heat-sensitive recording material WO2003057496A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP02786188A EP1466750A4 (en) 2001-12-20 2002-12-20 Heat-sensitive recording material
KR10-2004-7009765A KR20040065301A (en) 2001-12-20 2002-12-20 Heat-sensitive recording material
US10/499,514 US20060046933A1 (en) 2001-12-20 2002-12-20 Heat-sensitive recording material

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2001-388128 2001-12-20
JP2001388128A JP3833935B2 (en) 2001-12-20 2001-12-20 Thermal recording material
JP2001387677A JP2003182228A (en) 2001-12-20 2001-12-20 Thermal recording method
JP2001-387597 2001-12-20
JP2001387597A JP2003182226A (en) 2001-12-20 2001-12-20 Thermal recording material
JP2001-387677 2001-12-20
JP2001387593A JP3526294B2 (en) 2001-12-20 2001-12-20 Thermal recording material
JP2001-387593 2001-12-20

Publications (1)

Publication Number Publication Date
WO2003057496A1 true WO2003057496A1 (en) 2003-07-17

Family

ID=27482742

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/013394 WO2003057496A1 (en) 2001-12-20 2002-12-20 Heat-sensitive recording material

Country Status (4)

Country Link
EP (1) EP1466750A4 (en)
KR (1) KR20040065301A (en)
CN (1) CN1606508A (en)
WO (1) WO2003057496A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114746280A (en) * 2019-12-27 2022-07-12 株式会社理光 Thermal transfer recording medium and transfer product

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE602005017664D1 (en) † 2004-12-27 2009-12-24 Oji Paper Co HEAT-SENSITIVE RECORDING MATERIAL
BRPI0615443B1 (en) * 2005-08-25 2017-12-26 Oji Holdings Corporation Process for the production of a heat-sensitive recording material
CN102180050B (en) * 2011-03-19 2013-11-20 金华盛纸业（苏州工业园区）有限公司 Bisphenol-A-free heat-sensitive paper
CN102616046A (en) * 2012-04-16 2012-08-01 金华盛纸业（苏州工业园区）有限公司 Thermo-sensitive paper and preparing method thereof
KR101253591B1 (en) * 2012-11-05 2013-04-12 임성식 Special thermal paper, special thermal paper label for medical use and the manufacturing methods thereof
CN105082815A (en) * 2015-09-07 2015-11-25 广东冠豪高新技术股份有限公司 Thermosensitive recording material and preparation method thereof
CN107128095B (en) * 2017-04-26 2019-08-09 顾涛 Temperature-sensitive draws pyrography material
CN112726274A (en) * 2020-12-28 2021-04-30 江苏金大包装材料科技有限公司 Preparation method of thermosensitive film adhesive sticker composite material
CN114960275A (en) * 2022-05-23 2022-08-30 杭州东仪纸业有限公司 High-grade hot-melt blueprint paper and production method thereof

Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585483A (en) * 1983-05-20 1986-04-29 Fuji Photo Film Co., Ltd. Recording materials
JPH02169291A (en) * 1988-12-23 1990-06-29 Ricoh Co Ltd Thermal recording material
JPH04105987A (en) * 1990-08-24 1992-04-07 Ricoh Co Ltd Support for thermal recording paper
JPH04221681A (en) * 1990-12-21 1992-08-12 Ricoh Co Ltd Heat sensitive recording material
JPH04332682A (en) * 1991-05-09 1992-11-19 Honshu Paper Co Ltd Thermal recording material
JPH0524343A (en) * 1991-07-25 1993-02-02 Fuji Photo Film Co Ltd Multi-color heat-sensitive recording material printing device
JPH07314914A (en) * 1994-05-30 1995-12-05 Fuji Photo Film Co Ltd Heat-sensitive recording material
JPH08118808A (en) * 1994-10-21 1996-05-14 Ricoh Co Ltd Thermal recording material
JPH08197848A (en) * 1995-01-30 1996-08-06 New Oji Paper Co Ltd Pressure sensitive adhesive label for thermal recording
JPH08253264A (en) * 1995-03-20 1996-10-01 Fuji Photo Film Co Ltd Packing of multicolor thermal recording material
JPH08310131A (en) * 1995-03-10 1996-11-26 Ricoh Co Ltd Thermal recording material
JPH08324123A (en) * 1995-03-30 1996-12-10 New Oji Paper Co Ltd Thermal recording material
JPH09142018A (en) * 1995-11-17 1997-06-03 Mitsubishi Paper Mills Ltd Thermosensitive recording material
JPH09193550A (en) * 1996-01-17 1997-07-29 Ricoh Co Ltd Thermal recording material
EP0791578A2 (en) * 1996-02-21 1997-08-27 Sanko Kaihatsu Kagaku Kenkyusho Sulfonyl compound and thermalsensitive recording medium using the same
JPH09314999A (en) * 1996-05-31 1997-12-09 Nippon Paper Ind Co Ltd Thermal recording paper
JPH10181205A (en) * 1996-12-25 1998-07-07 Hokuetsu Paper Mills Ltd Heat sensitive recording material
US5847744A (en) * 1995-02-07 1998-12-08 Rohm Co., Ltd. Thin-film thermal print head and method of producing same
EP0992363A1 (en) * 1998-10-09 2000-04-12 Fuji Photo Film Co., Ltd. Heat-sensitive recording material
JP2000247038A (en) * 1999-03-03 2000-09-12 Fuji Photo Film Co Ltd Thermal recording material
JP2000272245A (en) * 1999-03-25 2000-10-03 Fuji Photo Film Co Ltd Polymer supporting body for heat-sensitive or heat developing recording material, its manufacture and heat-sensitive or heat developing recording material using the same
JP2000345067A (en) * 1999-06-03 2000-12-12 Mitsui Chemicals Inc Developer composition and thermal recording material
JP2001018526A (en) * 1999-07-07 2001-01-23 Mitsubishi Paper Mills Ltd Thermosensitive recording material and manufacture thereof
JP2001063210A (en) * 1999-08-25 2001-03-13 Ricoh Co Ltd Thermal recording method and thermal recording material
JP2001219651A (en) * 2000-02-10 2001-08-14 General Kk Heat-sensitive recording body
JP2001293956A (en) * 2000-04-11 2001-10-23 Mitsubishi Paper Mills Ltd Manufacturing method for information recording material
JP2002127604A (en) * 2000-10-24 2002-05-08 Fuji Photo Film Co Ltd Heat-sensitive recording material
WO2002098673A1 (en) * 2001-06-01 2002-12-12 Fuji Photo Film Co., Ltd. Thermosensitive recording material
WO2003002354A1 (en) * 2001-06-28 2003-01-09 Fuji Photo Film Co., Ltd. Thermal recording material

Patent Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585483A (en) * 1983-05-20 1986-04-29 Fuji Photo Film Co., Ltd. Recording materials
JPH02169291A (en) * 1988-12-23 1990-06-29 Ricoh Co Ltd Thermal recording material
JPH04105987A (en) * 1990-08-24 1992-04-07 Ricoh Co Ltd Support for thermal recording paper
JPH04221681A (en) * 1990-12-21 1992-08-12 Ricoh Co Ltd Heat sensitive recording material
JPH04332682A (en) * 1991-05-09 1992-11-19 Honshu Paper Co Ltd Thermal recording material
JPH0524343A (en) * 1991-07-25 1993-02-02 Fuji Photo Film Co Ltd Multi-color heat-sensitive recording material printing device
JPH07314914A (en) * 1994-05-30 1995-12-05 Fuji Photo Film Co Ltd Heat-sensitive recording material
JPH08118808A (en) * 1994-10-21 1996-05-14 Ricoh Co Ltd Thermal recording material
JPH08197848A (en) * 1995-01-30 1996-08-06 New Oji Paper Co Ltd Pressure sensitive adhesive label for thermal recording
US5847744A (en) * 1995-02-07 1998-12-08 Rohm Co., Ltd. Thin-film thermal print head and method of producing same
JPH08310131A (en) * 1995-03-10 1996-11-26 Ricoh Co Ltd Thermal recording material
JPH08253264A (en) * 1995-03-20 1996-10-01 Fuji Photo Film Co Ltd Packing of multicolor thermal recording material
JPH08324123A (en) * 1995-03-30 1996-12-10 New Oji Paper Co Ltd Thermal recording material
JPH09142018A (en) * 1995-11-17 1997-06-03 Mitsubishi Paper Mills Ltd Thermosensitive recording material
JPH09193550A (en) * 1996-01-17 1997-07-29 Ricoh Co Ltd Thermal recording material
EP0791578A2 (en) * 1996-02-21 1997-08-27 Sanko Kaihatsu Kagaku Kenkyusho Sulfonyl compound and thermalsensitive recording medium using the same
JPH09314999A (en) * 1996-05-31 1997-12-09 Nippon Paper Ind Co Ltd Thermal recording paper
JPH10181205A (en) * 1996-12-25 1998-07-07 Hokuetsu Paper Mills Ltd Heat sensitive recording material
EP0992363A1 (en) * 1998-10-09 2000-04-12 Fuji Photo Film Co., Ltd. Heat-sensitive recording material
JP2000247038A (en) * 1999-03-03 2000-09-12 Fuji Photo Film Co Ltd Thermal recording material
JP2000272245A (en) * 1999-03-25 2000-10-03 Fuji Photo Film Co Ltd Polymer supporting body for heat-sensitive or heat developing recording material, its manufacture and heat-sensitive or heat developing recording material using the same
JP2000345067A (en) * 1999-06-03 2000-12-12 Mitsui Chemicals Inc Developer composition and thermal recording material
JP2001018526A (en) * 1999-07-07 2001-01-23 Mitsubishi Paper Mills Ltd Thermosensitive recording material and manufacture thereof
JP2001063210A (en) * 1999-08-25 2001-03-13 Ricoh Co Ltd Thermal recording method and thermal recording material
JP2001219651A (en) * 2000-02-10 2001-08-14 General Kk Heat-sensitive recording body
JP2001293956A (en) * 2000-04-11 2001-10-23 Mitsubishi Paper Mills Ltd Manufacturing method for information recording material
JP2002127604A (en) * 2000-10-24 2002-05-08 Fuji Photo Film Co Ltd Heat-sensitive recording material
WO2002098673A1 (en) * 2001-06-01 2002-12-12 Fuji Photo Film Co., Ltd. Thermosensitive recording material
WO2003002354A1 (en) * 2001-06-28 2003-01-09 Fuji Photo Film Co., Ltd. Thermal recording material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114746280A (en) * 2019-12-27 2022-07-12 株式会社理光 Thermal transfer recording medium and transfer product
CN114746280B (en) * 2019-12-27 2024-03-08 株式会社理光 Thermal transfer recording medium and transfer product

Also Published As

Publication number Publication date
KR20040065301A (en) 2004-07-21
CN1606508A (en) 2005-04-13
EP1466750A1 (en) 2004-10-13
EP1466750A4 (en) 2005-03-30

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