WO2003035800A3 - Sulfur removal process - Google Patents

Sulfur removal process Download PDF

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Publication number
WO2003035800A3
WO2003035800A3 PCT/US2002/033888 US0233888W WO03035800A3 WO 2003035800 A3 WO2003035800 A3 WO 2003035800A3 US 0233888 W US0233888 W US 0233888W WO 03035800 A3 WO03035800 A3 WO 03035800A3
Authority
WO
WIPO (PCT)
Prior art keywords
sulfur
contacted
effective
under conditions
feedstock
Prior art date
Application number
PCT/US2002/033888
Other languages
French (fr)
Other versions
WO2003035800A2 (en
Inventor
Stacey Mcdaniel
Ptoshia A Burnett
Original Assignee
Bp Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Corp North America Inc filed Critical Bp Corp North America Inc
Priority to DE60208420T priority Critical patent/DE60208420T2/en
Priority to AT02786478T priority patent/ATE314447T1/en
Priority to UA20040403045A priority patent/UA77013C2/en
Priority to EP02786478A priority patent/EP1438372B1/en
Publication of WO2003035800A2 publication Critical patent/WO2003035800A2/en
Publication of WO2003035800A3 publication Critical patent/WO2003035800A3/en
Priority to ZA2004/02152A priority patent/ZA200402152B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C10G69/126—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step polymerisation, e.g. oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C10G69/123—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step alkylation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intemediate product is then separated into at least three fractions of different volatility, and the highest boiling third fraction is contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide. The intermediate boiling fraction is contacted with a selective hydrotreating catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.
PCT/US2002/033888 2001-10-25 2002-10-23 Sulfur removal process WO2003035800A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE60208420T DE60208420T2 (en) 2001-10-25 2002-10-23 SULFUR REMOVAL PROCESS
AT02786478T ATE314447T1 (en) 2001-10-25 2002-10-23 SULFUR REMOVAL PROCESS
UA20040403045A UA77013C2 (en) 2001-10-25 2002-10-23 Method for producing the product with reduced sulfur content from liquid hydrocarbon feedstock (variants )
EP02786478A EP1438372B1 (en) 2001-10-25 2002-10-23 Sulfur removal process
ZA2004/02152A ZA200402152B (en) 2001-10-25 2004-03-17 Sulfur removal process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33464001P 2001-10-25 2001-10-25
US60/334,640 2001-10-25

Publications (2)

Publication Number Publication Date
WO2003035800A2 WO2003035800A2 (en) 2003-05-01
WO2003035800A3 true WO2003035800A3 (en) 2003-10-23

Family

ID=23308114

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/033888 WO2003035800A2 (en) 2001-10-25 2002-10-23 Sulfur removal process

Country Status (9)

Country Link
US (1) US20030136706A1 (en)
EP (1) EP1438372B1 (en)
AT (1) ATE314447T1 (en)
DE (1) DE60208420T2 (en)
ES (1) ES2254765T3 (en)
RU (1) RU2287554C2 (en)
UA (1) UA77013C2 (en)
WO (1) WO2003035800A2 (en)
ZA (1) ZA200402152B (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6824676B1 (en) * 2002-03-08 2004-11-30 Catalytic Distillation Technologies Process for the selective desulfurization of a mid range gasoline cut
US6881324B2 (en) * 2002-03-16 2005-04-19 Catalytic Distillation Technologies Process for the simultaneous hydrotreating and fractionation of light naphtha hydrocarbon streams
US6855853B2 (en) * 2002-09-18 2005-02-15 Catalytic Distillation Technologies Process for the production of low benzene gasoline
US6984312B2 (en) 2002-11-22 2006-01-10 Catalytic Distillation Technologies Process for the desulfurization of light FCC naphtha
WO2008025002A2 (en) * 2006-08-24 2008-02-28 Intelligent Energy, Inc. Liquid phase desulfurization of fuels at mild operating conditions
FI121308B (en) * 2007-06-11 2010-09-30 Neste Oil Oyj Process for the production of branched hydrocarbons
FI119772B (en) * 2007-06-11 2009-03-13 Neste Oil Oyj Process for the preparation of branched hydrocarbons
ITMI20071610A1 (en) * 2007-08-03 2009-02-04 Eni Spa INTEGRATED PROCESS OF CATALYTIC FLUID CRACKING TO OBTAIN HYDROCARBURIC MIXTURES WITH HIGH QUALITY AS FUEL
EP2250129A2 (en) * 2008-02-21 2010-11-17 Saudi Arabian Oil Company Catalyst to attain low sulfur gasoline
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
FR2975103B1 (en) * 2011-05-12 2014-08-29 IFP Energies Nouvelles PROCESS FOR PRODUCING KEROSENE OR GASOLINE CUT FROM AN OLEFINIC CHARGE HAVING A MAJORITY OF 4 TO 6 CARBON ATOMS
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998014535A1 (en) * 1996-09-30 1998-04-09 Mobil Oil Corporation Alkylation process for desulfurization of gasoline
US6059962A (en) * 1998-09-09 2000-05-09 Bp Amoco Corporation Multiple stage sulfur removal process
WO2001053432A1 (en) * 2000-01-21 2001-07-26 Bp Corporation North America Inc. Sulfur removal process
WO2001053433A1 (en) * 2000-01-21 2001-07-26 Bp Corporation North America Inc. Sulfur removal process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5599441A (en) * 1995-05-31 1997-02-04 Mobil Oil Corporation Alkylation process for desulfurization of gasoline
US20020175108A1 (en) * 2001-03-12 2002-11-28 Institut Francais Du Petrole Process for the production of a desulfurized gasoline from a gasoline fraction that contains conversion gasoline

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998014535A1 (en) * 1996-09-30 1998-04-09 Mobil Oil Corporation Alkylation process for desulfurization of gasoline
US6059962A (en) * 1998-09-09 2000-05-09 Bp Amoco Corporation Multiple stage sulfur removal process
WO2001053432A1 (en) * 2000-01-21 2001-07-26 Bp Corporation North America Inc. Sulfur removal process
WO2001053433A1 (en) * 2000-01-21 2001-07-26 Bp Corporation North America Inc. Sulfur removal process

Also Published As

Publication number Publication date
ZA200402152B (en) 2005-06-29
DE60208420T2 (en) 2006-09-07
EP1438372A2 (en) 2004-07-21
DE60208420D1 (en) 2006-02-02
RU2004113113A (en) 2005-10-27
ES2254765T3 (en) 2006-06-16
US20030136706A1 (en) 2003-07-24
UA77013C2 (en) 2006-10-16
WO2003035800A2 (en) 2003-05-01
EP1438372B1 (en) 2005-12-28
RU2287554C2 (en) 2006-11-20
ATE314447T1 (en) 2006-01-15

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