WO2003030839A1 - Cosmetic containing electrolyzed ocean deep water - Google Patents

Abstract

A cosmetic which comprises an electrolyzed ocean deep water prepared by subjecting an ocean deep water being taken out from a deep portion of the ocean having a depth from the surface of 200 m or more to electrolysis and, added thereto, desired cosmetic components. The cosmetic imparts improved moisture retention properties to a skin and a hair, and thus improves their dampish and soft feeling, glossiness, smoothness and the like.

Description

 Specification

 Electrolyte deep sea water containing cosmetics

 Technical field

 The present invention relates to a cosmetic containing electrolytic deep sea water. More specifically, the present invention relates to an electrolytic deep sea water-containing cosmetic containing electrolyzed water obtained by electrolyzing deep sea water and having excellent moisturizing properties.

 Background art

 Normally, cosmetics use water obtained by subjecting groundwater or the like to physical filtration and treatment or sterilization, so-called ordinary water, or purified water obtained by distilling and purifying ordinary water. In general, water is used for the purpose of diluting cosmetic preparations. Recently, however, there has been a technology to use deep ocean water collected from the deep ocean below 200 meters for cosmetics. It has been published.

 Japanese Patent Application Laid-Open No. 11-12154 discloses that deep sea water enhances the moisturizing ability of cosmetics and prevents bulkiness and rough skin. However, the effect is not fully satisfactory, and the emergence of new water that can enhance the ability to moisturize the skin and hair has been anticipated.

 Disclosure of the invention

 An object of the present invention is to provide a cosmetic having excellent moisturizing properties that prevents the skin and hair from becoming bulky and rough, and gives the skin and hair firmness and moisture. The present inventors include, in cosmetics, electrolytic deep sea water obtained by electrolyzing deep sea water or a mixture of deep sea water and working water selected from groundwater, purified water, and tap water. And improved the moisture retention, and completed the present invention.

 Cosmetics containing electrolytic deep water obtained by electrolyzing deep sea water or a mixed water containing deep sea water have not yet been known at all.

 BEST MODE FOR CARRYING OUT THE INVENTION

The electrolytic deep sea water-containing cosmetic composition of the present invention comprises a cosmetic component and water, wherein the water contains 0.0] to 100% by weight of deep sea water collected from a deep sea part at a depth of 200 m or less. The electrolyzed raw water contained in a given amount is provided with electrolytic water generated on one of the cathode side and the cathode side. In the cosmetics containing electrolytic deep sea water of the present invention, it is preferable that the electrolytic water is weakly basic mineral water generated on the negative electrode side.

 In the present invention, deep sea water means water collected from the deep sea below 200 m deep, and also includes physical filtration, reverse osmosis filtration, electrodialysis or ion exchange. At least one type of treatment selected and concentrated to 1/10 to 1/100, and the precipitates (such as sodium chloride crystals) are removed by filtration. Includes those obtained by diluting the filtrate obtained to the original volume with purified water, groundwater, spring water, tap water, or other common water. In the present invention, the raw water supplied to the electrolyzer contains the deep sea water in a content of 0.01 to 100% by weight, preferably 1.0 to 100% by weight, and is mixed with the deep sea water. The other water used is generally used for cosmetics production, and can be selected from, for example, purified water, groundwater, spring water, tap water, and other common waters, but may be distilled water and / or ion exchange resin. It is preferable to use treated purified water. The deep sea water used in the present invention is not limited to an intake site as long as it is seawater collected from a place 200 meters below the sea level or deeper in the ocean. This includes offshore Muroto-misaki in Kochi Prefecture, Suruga Bay in Shizuoka Prefecture, and Kumejima in Okibashi Prefecture, etc., and globally, those collected from offshore of Nonolle-ichi and offshore of Hawaii. When the content of the deep sea water in the raw water is less than 0.01% by weight, the effect of increasing the moisturizing power of the present invention becomes insufficient. Also, deep sea water 100 weight ° /. This means that deep ocean water itself is used as raw water and is supplied to the electrolyzer. As described above, deep seawater is concentrated to 1/10 to 1/100, and precipitates such as sodium chloride are removed by filtration. Diluted water and further diluted water can be used as raw water.

Deep sea water and deep sea water dilution water are electrolyzed as raw water in an electrolyzer by a known method. By this electrolysis, so-called weakly acidic water is generated on the anode side, and so-called weakly basic mineral water is generated on the cathode side. The cosmetic of the present invention prepared by blending a water component containing each of the two with a cosmetic component exhibits the moisturizing effect. However, depending on the desired liquidity of the cosmetic, acidic water and weakly basic Any of mineral water can be selected and used. The weakly basic mineral water and the weakly acidic water are each diluted with a common water to a desired fold, preferably 100 fold or less, to form a cosmetic. Can be used as a water component.

 The electrolyzer used in the present invention is not particularly limited as long as it is used for electrolyzing water.For example, a two-chamber type separated by a diaphragm, a DC voltage is used. A three-pole type that switches between lip-flop circuits to perform alternating current charging (Japanese Patent Laid-Open No. 6-254567), a type in which water is supplied to a water storage tank and electrolysis is performed for a certain time in a two-tank type electrolyzer, and Examples include a type for continuously supplying water from tap water and the like. The present invention is a preferred electrolyzer, for example, a ferrite electrode, a platinum metal titanium electrode, a titanium platinum fired electrode, or the like as an anode, and a stainless steel electrode as a cathode. In addition, a two-tank water-storage type electrolysis apparatus configured by using a platinum-medium titanium electrode, a titanium platinum fired electrode, or the like, and using an ion exchange membrane or the like as a diaphragm is used.

 There are no particular restrictions on the cosmetic ingredients in the present invention. Examples thereof include hair growth agents, bath agents, and medicated cosmetics specified in the Pharmaceutical Affairs Law, that is, medicated stones, medicated shampoos, medicated rinses, medicated lotions, and medicated cosmetics. Reams ・ Emulsions in medicated emulsions, medicated packs, and other cosmetics specified in the Pharmaceutical Affairs Law, including cleansing cosmetics, hair cosmetics, basic cosmetics, foundations, bath cosmetics, etc. Can be used. The effect of the present invention is exhibited by replacing water used in various preparations with electrolytic deep water according to the present invention. In addition, cosmetics can be prepared by using a combination of ordinary water used for general cosmetics and electrolytic deep water. It is also possible to subject the electrolytic deep water to a desalination treatment using a reverse osmosis membrane to control the salt concentration to a desired value, and mix it with a cosmetic ingredient.

The cosmetics of the present invention include components usually used in cosmetics, such as animals, plants, fish and shellfish, extracts derived from microorganisms, powder components, liquid fats and oils, solid fats and oils, roux, hydrocarbons, higher fatty acids, and higher alcohols. , Esters, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, humectants, water-soluble polymers, thickeners, coating agents, ultraviolet absorbers, anti-inflammatory agents , Sequestering agents, lower alcohols, sugars, amino acids, organic amines, synthetic resin emulsions, pH adjusters, skin nourishes, vitamins, antioxidants, antioxidants, fragrances , And / or two or more kinds of ordinary water may be used as necessary. The cosmetic of the present invention includes, as a part of the cosmetic ingredient, extracts derived from animals, plants, fish and shellfish, and microorganisms, for example, tea extract, aloe extract, ginkgo extract, assembly kiss, mugwort extract, and garlic extract. Extracts such as corn extract, rosemary extract, luffa extract, placenta extract, lactic acid bacteria culture extract and seaweed extract can be used in combination.

 The powder component that can be used as a cosmetic component in the cosmetic of the present invention includes inorganic powders such as talc, kaolin, mica, sericite (cellite), muscovite, phlogopite, Synthetic mica, biotite, biotite, lithium mica, vercumite, magnesium carbonate, zirconium silicate, aluminum silicate, barium silicate, calcium silicate, zinc silicate, magnesium silicate, strontium silicate, tungsten Acid metal salts, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined ゥ), phosphoric acid phosphate, fluorine apatite, hydroxyapatite, ceramic knock. Activated charcoal, activated charcoal, medicinal charcoal, metal stones (zinc myristate, calcium palmitate, aluminum stearate, etc.), boron nitride, etc. are examples of organic powders. Polyamide resin powder (Nylon powder), Polyethylene powder, Polymethyl methacrylate powder, Polystyrene powder, Copolymer resin powder of styrene and acrylic acid, Benzoguanamine Resin powder, polytetrafluoroethylene powder, and cellulose powder.

 Examples of the liquid fats and oils used in the cosmetic of the present invention include apogado oil, camellia oil, grape seed oil, turtle oil, madi diana nats oil, corn oil, mink oil, Olive oil, sunflower oil, rapeseed oil, egg yolk oil, sesame oil, parsley oil, wheat germ oil, southern power oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil , Teaseed oil, cocoa oil, Komenu oil, Shinagiri oil, Japanese krill oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, triisopalmitic acid glycerin No.

The solid fat used in the cosmetic of the present invention includes cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow, sheep fat, hardened tallow, palm kernel oil, lard, beef bone fat , Butterflies, hardened oil, beef tallow, mokurou, hardened castor oil, and the like. Kanole Naunokuro, Babyry ゥ, Ibotaro, Whale Lo, Montan Lo, Nucalou, Lanolin, Kapok Lo, Lanolin acetate, liquid lanolin, sugar cane roux, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, holonolol, rigid lanolin , Celac Row, POE lanolin alcohol alcohol, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol Ether and the like.

 Examples of the hydrocarbon oil used in the cosmetic of the present invention include liquid paraffin, ozokerite, squalene, pristane, and the like. Examples include Raffin, Seresin, Screenan, Vaseline, and Micro-Crystallin Wax. The higher fatty acids include rauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxyxesteric acid, pendecylenic acid, Tall oil fatty acids, coconut oil fatty acids, palm fatty acids, palm kernel fatty acids, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid, docosahexaenoic acid and the like.

Examples of the synthetic ester oil used in the cosmetic of the present invention include isopropyl isopropyl myristate, cetyl octanoate, octyl dodecyl myristate, isopyl palmitate, and stearin. Butyl phosphate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyl octanoate, cetyl lactate, myristyl lactate, lanolin acetate, stearic acid Socetyl, disocetyl disostearate, 12-hydroxycholesteryl cholesterol phosphate, di-2-ethylinohexyl hexenolate ethyl glycol, dipentaerythritol fatty acid ester, capric acid Neopentyl glycol, diisostearyl linoleate, di-2-heptylglycerin didecanoate, tri-2-ethyl Sill acid door Li main Chirorupu down, door Li Yi Sosutea-phosphate door Li main Chirorupurono ヽ. Pentaerythritol 2-ethyl hexynoleate, glycerin tri-2-ethyl hexylate, trimethylethyl oleate triisostearate 2-ethylaminohexanoate, 2-ethylaminohexyl remitate, glycerin trimyristate, glyceride tri2-heptyl pentadecanoate, Castor oil fatty acid methyl ester, oleic acid oil, setostearinoleanololechol, acetate glycerite, 2-heptyl decyl palmitate, disobutyl adipate, N-radioyl L- Glutamic acid 1-2-octyl dodecyl ester, adipic acid 12-heptyl pentadecinole, ethyl laurate, cenoxine Acid di-2-ethynolehexyl, myristic acid 1-2-hexyldecinole, panolemitic acid 1-2-hexyldecinole, adipic acid-2-hexyldecyl, cenosinic acid diisopropynole, cocholic acid-2- Examples include ethylhexyl, ethyl acetate, butyl acetate, amino acetate, and triethyl citrate.

 Examples of the silicones used in the cosmetic of the present invention include dimethylsilicone oil, methylpolysiloxane, octamethyltrisiloxane, high-polymerization degree methylsiloxane, decamethylpolysiloxane, dodecamecene. Chilpolysiloxane xantante tramethyltilde hydrazidepolysiloxane, dimethylsiloxane.Methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane, Examples thereof include a methyl (polyoxypropylene) siloxane copolymer and an amino-modified silicone.

Examples of the anion activator used in the cosmetic of the present invention include a fatty acid soap, for example, a base material for a soap, sodium laurate, sodium palmitate, and coconut soap , Higher alkyl sulfates, such as sodium lauryl sulfate, potassium laurino sulfate, triethanolamine lauryl sulfate; alkyl ether sulfates, such as POE Triarylethanol laurate sulfate, POE Sodium laurate sulfate; N-acylaminate, such as lauroylsarco cinnatrium, lauroyl jS—araninna Triuium, Lauroyno N-methyl-1-alanine sodium, sodium rauroylglutamate Monosodium, sodium stearoinoleglutamate Ginatridium, Ν-Myristolyl L-Monosodium glutamate, Ν-Palmitoinolespartate diethanolamine, Palm fatty acid silk peptide; Higher fatty acid amido sulfo Phosphates, for example, Ν-myristyl Ν-methyl-taurinate, coconut fatty acid methyltaurinate-natrium, lauroyl-methyltiltaulinatodium; phosphate esters Salts, for example, sodium polyoleate norrenate, sodium stearate ether, sodium peroleate, sodium midoleate; sulfoconoate, for example, di- 2-Ethylhexyl sodium sulfoconodate, monolauroinolenoethanol amide polypolyoxysulfensulfonic acid Application Benefits © beam, La U Li Norepo Li Pro Pirengu recall sulfo co Haq Sanna Application Benefits © beam; alkylbenzene sulfonic acid salts, for example, Li Nia dodecyl Sodium benzene sulfonate, linear dodecylbenzene sulfonic acid triethanolamine, urea dodecyl benzene sulfonate; higher fatty acid ester sulfate ester salt, for example, hydrogenated coconut oil fatty acid grease Sodium sulfate; sulfated oils such as roto oil; α-refined sulfonate, higher fatty acid ester sulfonate, secondary alcohol sulfate, higher fatty acid alkyl amide Sulfate, sodium lauroyl monoethanolamide conodate, sodium caseinate and the like.

 Examples of the cationic surfactant used in the cosmetic of the present invention include alkyltrimethylammonium salts, for example, stearyl trimethylammonium chloride, laminole trimethylammonium chloride. Auryl bromide triammonium bromide; dialkildimethylammonium salt, for example, distearyldimethylammonium chloride; anoalkylpyrimidine, for example, cetylpyridium chloride; alkyl dimethylammonium Benzene chloride, benzalkonium chloride, and the like.

 Examples of the amphoteric surfactant used in the cosmetic of the present invention include amide amide amphoteric surfactants, for example, 2-indesyl-Ν-carboxymethyl-Ν-hydroxishetinoreimidazolium. Betaine, Ν— Lauroyl Ν Ν ”— Carboxymethyl Ν Ν” — Hydroxicetil Ethylene Diamine Minorium, Ν— Coconut Fatty Acid シ ル ー N '— Power Norrevoxetil Ν' — Hydroxicetil Ethylene diamine; amido acetic acid betaine-type amphoteric surfactants, such as amide fatty acid amidopropyl betaine, amidopropyrbetaine myristate; Amidosulfobetain-type amphoteric surfactants, such as amidopropyl hydroxysulfobetaine laurate; Aminoxide-type amphoteric surfactants, such as C Lil Application Benefits main Chirua Mi Nokishi de, la c Li Nsana Mi Dopuro Pirua Mi Nokishi de; alkyl acetate base tie down type amphoteric surfactants and Al Kirusuruhobetai emission type amphoteric surfactants, and the like.

Examples of the nonionic surfactant used in the cosmetic of the present invention include glycerin fatty acid esters such as glyceryl monostearate and self-emulsifying glyceryl monostearate. Glyceryl monoisostearate; polyoxyethylene glyceryl fatty acid esters, such as monostearic acid and glycerol monooleate POE glyceryl acid; polyglycerin fatty acid esters, for example, diglyceryl monostearate, tetraglyceryl tristearate, decaglyceryl pentastearate; Sorbitan fatty acid esters, for example, sorbitan monolaurate, sonorebitan sesquistearate, sorbitan monooleate; fatty acid esters of polyoxyethylene sorbitan, for example, POE sorbitan monococonut fatty acid POE sonorebitan stearate, POE sonorebitan trioleate; polyoxyethylene sorbite fatty acid esters, for example, POE sorbitol monolaurate, POE sorbate tetratetraoleate; Polyethylene glycol fatty acid esters, such as monolauric Acid polyethylene glycol, Monosutea Li Nsanpo Li Echirengu recall, mono- Orei phosphate poly Echirengu recall, Jisutea Li down walk triethylene glycol; poly oxyethylene alkyl ethers, for example,

POE laurylene ether, POE cetyl ether, POE stearyl ether; polyoxyethylene polyoxypropylene alkyl ethers, for example, POE. POP cetyl ether, POE. POP decyl tetradecyl ether; polyoxyethylene alkyl Phenyl ethers, for example, P0E phenyl ether, P0 octyl phenyl ether, POE branched octyl phenyl ether; polyoxyethylene alkylamines, for example, POE stearinoleamine, POE oleinoreamin; Fatty acid alcohol amides, for example, coconut fatty acid diethanolamide, coconut fatty acid monoethanolamide, lauric acid ethanol amide, palm kernel oil fatty acid ethanol amide; PO Reoxyethylene alcohol Mides, for example, POE monoethanolamine amide, POE coconut fatty acid monoethanolamide, POE tallow fatty acid monoethanolamine amide; acetylene glycol, POE acetylenic alcohol, P0E Norin, POE lanolin alcohol, P0E castor oil, P0E hard castor oil, P0E phytosterol, P0E cholestanol, and P0E nonylphenylformaldehyde condensate .

Examples of the humectant used in the cosmetic of the present invention include glycerin, propylene glycol, 1,3-butylene glycol, sonorebitol, sodium lactate, pyrrolidone rubonic acid and salts thereof. Examples of the water-soluble polymer include guar gum, queen seed, pectin, gelatin, xanthan gum, methylcellulose, and cellulose. Tinoresenorelose, hydroxyxetinoresenorelose, hydroxypropinoresenorelose, carboxymethylcellulose and salts, algin salts, polybutyl alcohol, carboxyvinyl polymer, sodium polyacrylate, bentonite And chitin / chitosan derivatives, hyaluronic acid and salts, collagen and derivatives thereof, and the like. Examples of the thickening agent used in the cosmetic of the present invention include coconut oil fatty acid monoethanolamide, diethanolamide laurate, isopropanol amide laurate, and polyoxyethylene. Examples include coconut oil monoethanolamide, polyoxypropylene oil fatty acid monoethanolamide, and the like.

 Examples of the coating agent used in the cosmetic of the present invention include polyvinyl alcohol, polyvinylpyrrolidone, cationi-deno-senorerose, anioni-dani senorerose, and silicone.

 Examples of the ultraviolet absorber used in the cosmetic of the present invention include 2-hydroxy-14-methoxybenzophenone, 2-hydroxy-14-methoxybenzophenone-15-snorrefonic acid and Salts, benzophenone derivatives such as dihydroxydimethoxybenzophenone, paraaminobenzoic acid derivatives, paraaminobenzoic acid derivatives such as paraaminobenzoic acid and ethyl ethyl paraaminobenzoate. Ethyl lamethoxycinnamate, isopropyl paramethoxycinnamate, octyl lamethoxycinnamate, methoxycinnamic acid derivatives, salicylic acid derivatives such as octyl salicylate, phenyl salicylate, perocanic acid and derivatives, 4-tert —Butyl-4′-methoxydibenzoinolemethane, 2- (hydroxy-5′-methinolephenyl) benzotriazole, methyl anthranilate, and the like.

 Examples of the anti-inflammatory agent used in the cosmetic of the present invention include glycyrrhizic acid and derivatives thereof, glycyrrhetinic acid and its derivatives, alantoin, hydrocortisone acetate, and azulene.

 Examples of the metal sequestering agent used in the cosmetic of the present invention include ethylenediaminetetraacetic acid and sodium salt, phosphoric acid, cunic acid, ascorbic acid, diconic acid, dalconic acid, and polylactic acid. Examples include sodium phosphate and sodium metaphosphate.

Examples of the lower alcohol used in the cosmetic of the present invention include ethanol, propyl alcohol, ethylene glycol, and diethyl glycol. Sugars include glucose, lactose, sucrose, starch, carboxymethyl starch, Cyclodextrin and the like.

 Examples of the amino acids used in the cosmetic of the present invention include aspartic acid and salts, alanine, arginine, lysine and salts, glycine, cystine, threonine, serine, methionine, and the like. .

 Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine, and triethylamine.

 Examples of the synthetic resin emulsion used in the cosmetic of the present invention include polyacrylic acid ester copolymer and polybutyl acetate. Examples of the pH adjuster include citric acid, hydrochloric acid, sulfuric acid, and sulfuric acid. Phosphoric acid, sodium hydroxide, ammonia and the like. As skin nutritional agents, vitamins A, B1, B2, B6, E and derivatives thereof, pantothenic acid and derivatives thereof And piotin.

 Examples of the antioxidant used in the cosmetic of the present invention include vitamin E, dibutylhydroxytoluene, butylhydroxyanisole, and gallic esters.

 Examples of the antioxidant aid include ascorbic acid, phytic acid, cephalic acid, maleic acid and the like, but the ingredients are not limited to these.

 Furthermore, when comparing the characteristics of both electrolyzed waters used in the present invention, the electrolyzed deep ocean water, which is a weakly basic mineral water generated on the negative electrode side, is weakly acidic marine electrolyzed water generated on the deep ocean water and the positive electrode side. It has an excellent moisturizing effect as compared to. The pH of the weakly basic water fraction is greater than 7 and less than or equal to 10 and the oxidation-reduction potential during production is +300 mV to 1500 mV, and this basic mineral water is used as the water component of the cosmetic of the present invention. When used, the pH value is preferably in the range of 8 to 10.

 The moisturizing effect of the weakly acidic marine electrolyzed water generated on the positive electrode side is superior to that of ordinary water, and has a more moisturizing effect than deep sea water. Further, the pH of the weakly acidic marine electrolyzed water fraction is less than 7 and is 4 or more, and the oxidation-reduction potential at the time of production shows +500 mV to +100 mV. When this weakly acidic water is used as the water component of the cosmetic of the present invention, the pH value is preferably in the range of 4 to 6.

Since the pH of the weakly acidic water shows a weak acidity of 4 to 7, hair conditioner and shampoo 1. Suitable for use in cosmetic creams.

 In order to produce the cosmetic of the present invention, a conventionally used compounding operation may be used.

 Example

 The present invention is further described by the following examples.

Production Example 1

 A deep ocean sampled at a depth of 200m or less in Toyama Bay on each of the anode and cathode sides of a two-tank activated calcium ion water generator (Trim Ion TI-200; S-Trim Co., Ltd.) Two liters of water were added, and electrolysis was performed at 0.2 A for 60 minutes at room temperature. As a result, it was possible to obtain weakly basic mineral water on the cathode electrode side and weakly acidic water on the anode side.

<Table 1>

Production Example 2

 On the anode and cathode sides of the same device as in Production Example 1, deep sea water collected at a depth of 200m or less in Toyama Bay was placed in purified water and the volume ratio was reduced to 1: 1. A electrolyzed at room temperature for 35 minutes. As a result, it was possible to obtain weakly basic mineral water on the cathode electrode side and weakly acidic water on the anode side.

Table 2>

Production Example 3

On the anode and cathode sides of the same device as in Production Example 1, dilute deep sea water from Toyama Bay at a depth of 200 m or less with working water to a volume ratio of 1: 100. Two liters of the raw water was added and electrolyzed at 0.61 A for 15 minutes at room temperature. As a result, weakly basic mineral water can be obtained on the cathode electrode side, and weakly acidic water can be obtained on the anode side. Was.

 <Table 3>

 Production Example 4

 Deep seawater collected from a depth of 200m or less in Toyama Bay at a depth of 200m or less in a continuous two-layer electrolyzer. Raw water prepared by diluting it 80 times with groundwater is supplied at about 7.2 to 8.5 liter / min. , And water was passed to the anode side and the cathode side. Electrolysis was performed by passing a current of 1.7 to 2.OA at the constant current setting using a stabilized DC power source to the cathode and anode. The pH of the weakly basic mineral water obtained from the cathode side was 8.85, and the oxidation-reduction potential was 133 mV. The pH of the mineral water obtained by heat-sterilizing the mineral water at 85 ° C or higher for 30 minutes or more was 8.90.

 [0041]

 Moisturizing effect test of electrolyzed water

 Test method: Wash the forearms of 10 panelists with tap water, wipe off moisture with a towel, drop a few drops on each forearm, apply with palms, and evaluate the moisture retention according to the following rating did. The evaluation was the sum of the scores of each panelist.

 Rating Contents

 3 Moisture retention is observed.

 2 Moisture retention is slightly recognized.

 1 No moisture retention is observed.

 Table 4 shows the test results.

<Table 4>

 From the above evaluation, it was confirmed that deep electrolyzed water has the best moisturizing effect compared to deep sea water and purified water (distilled water). ·

Examples 1-3, Comparative Examples 1-3 Emulsion composition

 An emulsion composition having the composition shown in Table 5 below was prepared by the following method, and the feeling of use was evaluated as panelists for 10 women aged 20 to 55 years.

How to adjust the emulsion

 Heat and dissolve components 1 to 9 shown in Table 5 to 80 ° C and keep the temperature at 80 ° C (oil phase). In a separate container, components 10 to 12 and one selected from components 13 to 18 were mixed and heated to 80 ° C to dissolve (aqueous phase). The solution of the above components 1 to 9 was added to the solution, and the solution was stirred. This emulsion was aged for 30 minutes, cooled to room temperature, defoamed, and used as a sample for evaluation.

Evaluation criteria

 As a panel, 10 females aged 20 to 55 years old were applied to the test sample per day, and an appropriate amount of the test emulsion was applied to the face every morning and before going to bed. One week later, evaluation was performed according to the following evaluation criteria.

 Evaluation Contents

 3 The firmness and firmness of the skin have been improved.

 2 The firmness and firmness of the skin were slightly improved.

 1 No change from before use

 Therefore, the highest point of the evaluation is 30 points and the lowest point is 10 points. The results are shown in Table 5.

<Table 5>

As is clear from Table ^5, it was confirmed that the cosmetic emulsion containing the electrolytic deep sea water of the present invention imparts firmness and a firm skin.

Examples 4 to 6, Comparative Examples 4 to 6

Lotion A lotion composition having the composition shown in Table 6 below was prepared as described below, and the feeling of use was evaluated as follows, using 10 women aged 20 to 55 as panelists.

How to adjust lotion

 One of the components 101 to 105 and 106 to 110 shown in Table 6 was placed in a container, heated to 80 ° C and dissolved, and cooled to room temperature to obtain a sample for evaluation. Evaluation criteria

 For each test sample, apply an appropriate amount of the test milk to the face daily in the morning and before going to bed as a panel of 10 women from the age of 20 to 55 years. evaluated.

 Evaluation Contents

 3 Improves firmness and firmness of skin.

 2 The firmness and firmness of the skin were slightly improved.

 1 No change from before use

 Therefore, the highest point of the evaluation is 30 points, and the lowest point is] .0 point. Table 6 shows the results.

<Table 6>

As is evident from Table 6, it was confirmed that the cosmetic containing the electrolytic deep sea water of the present invention imparts skin firmness and astringency.

Examples 7 to 9, Comparative Examples 7 to 9

Cream A cream composition having the composition shown in Table 7 below was prepared by the following method, and the feeling of use was evaluated as follows, using 10 women aged 20 to 55 as panelists.

How to adjust the cream

 The components 201 to 206 shown in Table 7 were dissolved by heating to 80 ° C and kept at a temperature of 80 ° C (oil phase). The seeds were mixed in a separate container and selected from among components 207-208 and 209-213] and heated to 80 ° C to dissolve (aqueous phase). The solution of the above-mentioned components 201 to 206 was added to this solution and emulsified. This emulsion was aged for 30 minutes, cooled to room temperature, defoamed, and used as a sample for evaluation.

Evaluation criteria

 Test sample]. For each product, apply an appropriate amount of the test milk to the face daily in the morning and before going to bed as a panel of 10 women aged 20 to 55 years, and evaluate it according to the following evaluation criteria one week later. did.

 Evaluation Contents

 3 Improves firmness and firmness of skin.

 2 The firmness and firmness of the skin were slightly improved.

 1 No change from before use

 Therefore, the highest score of the evaluation is 30 points and the lowest score is 10 points. The results are shown in Table 7.

Kupa 7>

As is clear from Table ^7, it was confirmed that the cosmetic cream containing the electrolytic deep sea water of the present invention imparts firmness and firmness to the skin.

Examples 10 to 12, Comparative Examples 10 to: L2

shampoo A shampoo composition having the composition shown in Table 8 below was prepared by the following method, and the feeling of use was evaluated by the following method using 10 women aged 20 to 55 as panelists. How to adjust shampoo

 One selected from components 301 to 305 and components 306 to 311 shown in Table 8 was placed in a container, dissolved by heating to 80 ° C, cooled to room temperature, and used as a sample for evaluation. Evaluation criteria

 For each test sample, 10 women between the ages of 20 and 55 served as panelists, and the hair was shampooed with an appropriate amount of the sample, dried, and evaluated according to the following evaluation criteria.

 Evaluation Contents

 3 The firmness of the hair has been improved.

 2 The firmness of the hair was slightly improved.

 1 No change from before use

 Therefore, the highest point of the evaluation is 30 points, and the lowest point is 1 () point. Table 8 shows the results.

Table 8>

As is clear from Table 8, it was confirmed that the shampoo containing the electrolytic deep sea water of the present invention was effective in increasing the firmness of hair.

Example 13-: 1.5, Comparative Example 13-: 15 Rinse

 A rinse composition having the composition shown in Table 9 below was prepared by the following method, and the feeling of use was evaluated by the following method using 10 women from 20 to 55 years as panelists.

How to adjust the rinse

 Heat and dissolve components 401 to 406 listed in Table 9 to 80 ° C and keep the temperature at 80 ° C (oil phase). In a separate container, components 407 to 408 and one selected from 409 to 413 were mixed and dissolved by heating to 80 ° C (aqueous phase). The solution of the above components 401 to 406 was added to this solution and emulsified. This emulsion was aged for 30 minutes, cooled to room temperature, defoamed, and used as an evaluation sample.

Evaluation criteria

 For each test sample, 10 women aged 20 to 55 as panelists, wash the hair with shampoo, take an appropriate amount of sample, rinse the hair, and evaluate according to the following evaluation criteria did.

 Evaluation Contents

 3 Improved hair smoothness and gloss.

 2 Smoothness and luster of hair were slightly improved.

 1 No change from before use

 Therefore, the highest point of the evaluation is 30 points, and the lowest point is 10 points. Table 9 shows the results.

<Table 9>

 As is evident from Table 9, it was confirmed that the rinse containing the electrolytic deep sea water of the present invention improved the smoothness and gloss of hair.

Example 16 C-Heating)

A hair lotion having the following composition was prepared. 501 Succinylated carboxymethyl chitosan solution 2.0% by weight 2% aqueous solution (Note 13)

502 ethanol 20.0

503 Fragrance 0.1

504 Deionized water 30.0

 505 Deep water electrolysis production example 1, 1A

 (Note 13) Trademarks: Kit Aqua, manufactured by Kawaken Fine Chemicals Co., Ltd.

The above components 501 to 505 were heated and mixed up to 80 ° C, uniformly dissolved, cooled and filled in a container. It was found that the use of this product increased hair gloss and increased moisture. Example 17 (Essence)

 A serum having the following composition was prepared.

601 glass 0.1% by weight

 602 Succinylated Carboxymethyl Tosan Solution 2.0

 2% aqueous solution (Note 13)

603 Polyoxyethylene hydrogenated castor oil (60E O) 0.1

604 Kisang Langham 0.2

605 Sorbit solution (Note 14) 3.0

606 methyl paraben 0.1

607 Fragrance 0.1

608 Deep water electrolysis production example 3, 3B

 (Note 14) Trademark: Sorbit D-70, manufactured by Towa Kasei Co., Ltd.

 The above components 601 to 608 were heated and mixed to 80 ° C, uniformly dissolved, cooled, and filled in a container. It was recognized that the use of this product increased skin firmness and improved skin roughness.

 Industrial applicability

 ADVANTAGE OF THE INVENTION The cosmetics containing the electrolytic deep sea water of the present invention can improve the moisturizing property of the skin or hair, improve firmness, hydration, luster, smoothness, etc., and are practically excellent. It is.

Claims

The scope of the claims

 1. Electrolysis of raw water containing a cosmetic ingredient and a water ingredient, wherein the water ingredient contains 0.01-100% by weight of deep ocean water collected from the deep ocean below 200m. And an electrolytic deep sea water-containing cosmetic comprising electrolytic water produced on one of the cathode side and the cathode side.

 2. The electrolytic deep seawater-containing cosmetic according to claim 1, wherein the electrolyzed water is weakly basic mineral water generated on the negative electrode side.