WO2002088278A1 - Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant - Google Patents

Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant Download PDF

Info

Publication number
WO2002088278A1
WO2002088278A1 PCT/RU2002/000155 RU0200155W WO02088278A1 WO 2002088278 A1 WO2002088278 A1 WO 2002088278A1 RU 0200155 W RU0200155 W RU 0200155W WO 02088278 A1 WO02088278 A1 WO 02088278A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
base component
titanium
copper
filter
Prior art date
Application number
PCT/RU2002/000155
Other languages
English (en)
Inventor
Nikolai Ivanovich Butenko
Sergei Ivanovich Butenko
Valeriy Ivanovich Nykytenko
Viktor Antonovich Drozdenko
Kirill Viktorovich Kossiakov
Aleksandr Valentinovich Spivak
Original Assignee
Nikolai Ivanovich Butenko
Sergei Ivanovich Butenko
Valeriy Ivanovich Nykytenko
Viktor Antonovich Drozdenko
Kirill Viktorovich Kossiakov
Aleksandr Valentinovich Spivak
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU2001111403/12A external-priority patent/RU2195992C1/ru
Application filed by Nikolai Ivanovich Butenko, Sergei Ivanovich Butenko, Valeriy Ivanovich Nykytenko, Viktor Antonovich Drozdenko, Kirill Viktorovich Kossiakov, Aleksandr Valentinovich Spivak filed Critical Nikolai Ivanovich Butenko
Priority to EP02766699A priority Critical patent/EP1421156A4/fr
Publication of WO2002088278A1 publication Critical patent/WO2002088278A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/09—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2068—Other inorganic materials, e.g. ceramics
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M37/00—Apparatus or systems for feeding liquid fuel from storage containers to carburettors or fuel-injection apparatus; Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines
    • F02M37/22—Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines, e.g. arrangements in the feeding system
    • F02M37/32—Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines, e.g. arrangements in the feeding system characterised by filters or filter arrangements
    • F02M37/34—Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines, e.g. arrangements in the feeding system characterised by filters or filter arrangements by the filter structure, e.g. honeycomb, mesh or fibrous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M37/00—Apparatus or systems for feeding liquid fuel from storage containers to carburettors or fuel-injection apparatus; Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines
    • F02M37/22—Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines, e.g. arrangements in the feeding system
    • F02M37/32—Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines, e.g. arrangements in the feeding system characterised by filters or filter arrangements
    • F02M37/42—Installation or removal of filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/04—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by electric means, ionisation, polarisation or magnetism

Definitions

  • the present invention relates: to the qualitative and quantitative composition and physical characteristics of porous composite filter medium based on titanium and copper (having optional additives, such as zinc, lead, nickel, and some other metals) and/or compounds and alloys thereof that are electron conductors, and to a filter device comprising such filter medium.
  • filter media and filter devices are designed for physical and chemical activation of liquid fuels, preferably hydrocarbon fuels (as for their chemical composition), with simultaneous removal of mechanical impurities directly in the fuel conveying system of gasoline engines, diesels and other internal-combustion engines (ICE hereinafter) or heat power systems, such as steam boilers or hot-water boilers, industrial furnaces and the like.
  • liquid fuels preferably hydrocarbon fuels (as for their chemical composition)
  • ICE internal-combustion engines
  • heat power systems such as steam boilers or hot-water boilers, industrial furnaces and the like.
  • Said heat engines and heat power systems are not sources of energy only but also of toxic effluents, of which CO, CH, NO x , carbon black, and compounds of heavy metals being the most hazardous. For this reason, further requirements are imposed upon filter media and filter devices parallel with the obvious requirement of adequately removing fine particles from liquid fuels, which is easy now to comply with. Among such requirements the most important is that the filter media and filter devices be suitable for physical and chemical activation of fuels with the purpose of: reducing concentration of toxic components in combustion gases discharged to the atmosphere, improving efficiency of ICE and other heat power systems with correspondingly decreasing specific fuel consumption, and decreasing specific consumption of liquid fuel in terms of an arbitrary unit (for example 100 km) of a vehicle run or a unit of heating capacity.
  • a customary approach to this problem consists in introducing, into the fuel-air charge, dispersible additives capable of distributively augmenting combustion to thus even up temperature over all combustion space with an attendant reduction in NO X; CO, CH and carbon black.
  • additives are disclosed to comprise: at least one organic or inorganic compound selected from a vast group or a mixture of compounds having a latent heat of evaporation no less than 21 kJ/mol and speed of laminar Bunsen flame not smaller than 40 cm/s; and non-lead metal or element (including organic or inorganic derivative compounds thereof) selected from the group consisting of alkali and alkaline-earth metals, aluminum, boron, bromine, bismuth, beryllium, chromium, cobalt, copper, gallium, germanium, iodine, iron, indium, molybdenum, nickel, niobium, phosphorus, palladium, tin, zinc, rhenium, silicon, vanadium, scandium, yttrium, elements of the lanthanide and the actinide series, titanium, zirconium, hafnium, tanta
  • filter media and filter devices utilizing such filter media which provide liquid fuel activation without outside power supply and control, and, what is more, allow introduction at will of ions of combustion-control metals into the fuel flow that interacts with extended surfaces of the filter.
  • the prior art filter medium for liquid fuels comprises a porous layer of a titanium-base component with electron conduction, having through pore clear sizes ranging from 100 to 200 ⁇ m, and specifically being disclosed as a sintered plate or cup, and a component having ionic conduction based on a metal with a higher normal electrode potential compared with that of titanium.
  • the basic metal of the latter component is copper in the form of microlayers of a suitable salt thereof made by saturating a sintered titanium bar with a solution of such salt and by drying the saturated bar to a constant weight.
  • the prior art filter device for liquid fuels comprises a case having an inlet and an outlet, and a replaceable active part (insert) made of the disclosed layered filter medium disposed inside said case.
  • the liquid fuel would wash away a copper salt from the pores and into cylinders of ICE or combustion chambers (furnaces) of other heat power systems.
  • the CvX ions, dispersed in the fuel would catalyze combustion and would serve to even up the temperature field over the cylinder space or combustion chambers to result only in a slight decrease in CO and NO x contents of exhaust gases and in formation of minor deposits of copper on the surfaces of the cylinder liners, which deposits were noticeable only when the used filters were replaced by fresh ones prior to the complete washing of the copper salt and when such filters had been used for long time enough (usually longer than 2 to 3 months).
  • the prior art filter medium and the filter device utilizing such filter medium are not able to offset wear on the surfaces of cylinder and piston assemblies of gasoline or diesel ICE in the sense that persistent use of such filter medium and filter device would result in too thin a copper deposit to offset the wear.
  • the problem underlying the invention consists: firstly, in the creation of a filter medium for liquid fuels, specifically automotive fuels, wherein the fuel activation for improving combustion with toxicity-reduced exhaust would be provided by way of refinement upon the filter composition and structure, as well as reduced wear on the surfaces of cylinder and piston assemblies or combustion chambers in ICE would be promoted in a simplest possible way, and secondly, in the creation of a filter device wherein a wide variety of liquid fuels as to chemical composition and viscosity would be activated by way of improved rearrangement of components at least part of which consists of said filter medium.
  • a filter medium for liquid fuels comprising at least one porous layer of a titanium- base component and at least one layer of a copper-base component having a higher normal electrode potential compared with that of titanium, wherein all the components are characterized with electron conduction, and the layers thereof are spaced apart but for a portion of the surface thereof to provide a galvanic coupling, the layer of the copper-base component being likewise porous and having a mean pore size and total porosity in excess of those of the layer of the titanium-base component.
  • the titanium-base component is embodied in a material having pore sizes ranging from 80 to 200 ⁇ m and the total porosity of 35 to 60% and selected from the group consisting of titanium, titanium carbide, titanium nitride, and titanium carbonitride, while the copper-base component is a material having pore sizes ranging from 100 to 300 ⁇ m and the total porosity of 50 to 80% and selected from the group consisting of copper, brass, and bronze.
  • a filter medium of the invention may comprise a third porous layer consisting of zinc and having pore sizes ranging from 100 to 300 ⁇ m and the total porosity of 50 to 80%.
  • said third porous layer is arranged between the layer of the titanium-base component and the layer of the copper-base component, and in contact therewith to provide a galvanic coupling.
  • a filter device for liquid fuels comprising a filter case having an inlet and an outlet for the fuel to be filtered and an active zone in the form of an insert made of layered filter medium including at least one porous layer of a titanium-base component and at least one layer of a copper-base component having a higher normal electrode potential compared with that of titanium, wherein all components of the insert are electronic conductors, the layers thereof are spaced apart but for a portion of the surface to provide a galvanic coupling, the layer of the copper-base component being likewise porous, having a mean pore size and total porosity in excess of those of the layer of the titanium-base component and being arranged upstream from the layer of the titanium-base component.
  • Such filter device is expected to be of reasonable price and is acceptable in terms of quality, since, apart from removing fine particles, it is suitable for physical and chemical activation of liquid fuels to enhance combustion and reduce harmful emissions. It is also suitable for mounting and is easy to maintain (replacement included). Further, the filter device of the invention is capable of providing fuel with components that offset wear on the surfaces of cylinder and piston assemblies to extend service life of ICE and reduce toxicity of the combustion product and specific fuel consumption.
  • the layer of the copper-base component is precisely the layer of the copper-base component, partially consumable (and individually replaceable), being more porous and arranged upstream from the layer of the titanium-base component that accumulates the major portion of mechanical impurities present in liquid fuels to thereby extend the service life of the layer of the titanium-base component.
  • the layer of the titanium-base component is grounded or is in galvanic connection with the frame of a facility equipped with an ICE, and in doing so the potential difference to sustain galvanic corrosion in the layer of the copper-base component is provided continuously. This is a prerequisite for accumulation of ions of copper and associated metals in the fuel that remains in the filter device while the ICE is dead.
  • the layer of the titanium-base component is an axially symmetric cup, while the layer of the copper-base component is a disk (generally flat) fitted in said cup to provide a galvanic coupling therewith along its circumference.
  • This arrangement provides for ease of assembly and replacement of filter parts. It will be appreciated that for ease of production of the cup may be a solid of revolution, cylindrical or conical, a prism or a frustum of a pyramid with equal lateral faces.
  • a primary filter consisting of a porous layer of stainless steel having pore sizes ranging from 100 to 300 ⁇ m and the total porosity of at least 50% may be arranged upstream from the layer of the copper-base component on the side of the inlet. Such part is easily back purged to thus extend the service life of the filter device as a whole.
  • a porous layer consisting of zinc and having pore sizes ranging from 100 to 300 ⁇ m and the total porosity of 50 to 80 % may be arranged between the layer of the titanium-base component and the layer of the copper-base component.
  • a discrete layer of pellets or tablets as a source of metals known to form brass is further arranged between the titanium-base layer and at least one other layer, the pellets or tablets of said discrete layer being comprised of a mixture of at least one ionic compound of copper and at least one ionic compound of zinc in a ratio of 0.03 to 0.70 mole of zinc per mole of copper, and at least one organic substance that promotes dissolution of salts of said metals in hydrocarbon fuels.
  • Such part of the filter device is able to dissolve in minor amounts of water, which are common in hydrocarbon fuels, let alone the alcohol fuels.
  • This feature allows substantially greater amount of ions of brass-forming chemical elements to be introduced into each fresh fuel charge (typical consumption of salts being 0.5 to 5.0 g per metric ton of fuel) as compared to the galvanic corrosion of the copper-base component.
  • interaction of liquid fuels with copper and zinc within cylinders upon each operating cycle of ICE produces a mixture of neutral atoms of copper and zinc due to reduction of metal ions. This mixture is attracted to cooled cylinder liners and readily forms (and keeps invariable as to thickness) a microfilm of brass over virtually all surface of contact with the pistons to thereby offset wear.
  • molecular weight as applied to metals known to form brass is hereinafter used to mean a corresponding metal in kilograms numerically equal to its atomic weight, but when applied to the ingredients, such as oxyquinoline and the like, it is a corresponding substance in kilograms numerically equal to its molecular weight.
  • molar ratios are pre-assigned to mean pure metals without regard for anions, cations or oxides thereof, present in the filter of the invention, as well as for water of hydration, should it be present in metallic compounds.
  • said organic substance is selected from the group consisting of oxyquinoline, cupferron, neocupferron, and an unspecified chelate compound out of a multitude of aminopolycarboxylic acids attractive due to their efficiency as well as availability.
  • a still further embodiment of the invention consists in that the pellets or tablets of said discrete layer further comprise at least one ionic or covalent compound of tin in an amount of 0.16 to 0.40 mole of tin per mole of copper.
  • Tin salts as well as salts of copper and zinc are soluble in water, while tin oxide easily converts into a soluble form in presence of water and traces of acids in the fuel and further controls composition and properties of brass that is forming deposits on the surfaces of cylinder and piston assemblies in ICE as they wear away.
  • the pellets or tablets of said discrete layer may further comprise at least one ionic compound including a metal selected from the group consisting of lead, molybdenum, tungsten, vanadium, nickel, silver, and zirconium, in an amount of 0.008 to 0.010 mole of lead and/or 0.010 to 0.32 mole of molybdenum, and/or 0.010 to 0.22 mole of tungsten, and/or 0.020 to 0.50 mole of vanadium, and/or 0.004 to 0.40 mole of nickel, and/or 0.004 to 0.115 mole of silver, and/or 0.005 to 0.40 mole of zirconium.
  • Such additives offer more precise selection of brass compositions to be deposited under specific conditions and (what particularly counts) selective catalysis in the process of combustion of various fuels as to composition and purpose.
  • pellets or tablets of said discrete layer further comprise at least one organic substance capable of rendering metal salts (usually by complexing) soluble in hydrocarbon fuels.
  • the invention is illustrated in the drawing which is a schematic representation of the filter medium of the invention shown as a layered structure with an active zone of the filter device for liquid fuels, the case of the filter device being removed.
  • the filter medium of the invention comprises components that are electronic conductors and are suitable for use in filter devices for separation of solids from liquid fuels while activating the latter.
  • the components form the following structural parts: a rigid porous layer 1 of a titanium-base component, a rigid porous layer 2 of a copper-base component, a rigid porous layer 3 of zinc (optional), a rigid porous layer 4 of stainless steel (optional), and a discrete layer 5 of pellets or tablets a composite additive to liquid fuels (optional as well).
  • grounding electrode 6 connected to the layer 1 and forming part of the filter device only.
  • the layers 1 and 2 herewith are essential parts of the structure, while the layer 3 is an optional component of the filter medium of the invention.
  • the layers 1 through 5 can form part of an active zone of the filter device according to the invention.
  • the layer 1 can consist either of pure titanium (e.g. powder of predetermined fineness that was sintered in vacuum or in an inert gas, such as argon, or premolded felt-like structure of a predetermined diameter titanium wire lengths) or of titanium nitride, titanium carbide, or titanium carbonitride that are electron conductors.
  • This layer has pore sizes ranging from 80 to 200 ⁇ m at 35 to 60% total porosity.
  • the layer 2 being a component of the filter medium is typically made of copper or of a suitable kind of brass, specifically leaded brass, or of a suitable kind of bronze, and it is to have pores of 100 to 300 ⁇ m in size at total porosity ranging from 50 to 80%, which is more than in the layer 1.
  • the layer 2 is not only a means for the removal of particles from fuels, but an ion contributor as well, since it has a higher normal electrode potential than the titanium-base layer 1. Therefore, water and traces of acids, common in liquid fuels, induce partial galvanic corrosion in the layer 2.
  • Pure copper as the layer 2 is preferably useful in filtering leaded gasoline because combustion of leaded gasoline in ICE results in leaded brass-like material which produces deposits on the walls of cylinder and piston assemblies. Brass and bronze are preferred in the layer 2 in case of clear gasoline or fuels for jet and diesel systems.
  • the layer 3 being a component of the filter medium, consists of porous zinc of 100 to 300 ⁇ m pore sizes at total porosity ranging from 50 to 80%.
  • Zinc readily corrodes against a titanium background and in the presence of copper to thereby enhance deposition of brass micro-layers on the parts of cylinder and piston assemblies upon combustion of unspecified fuel mixtures in ICE.
  • any combination of the layers does contribute to a noticeable reduction in harmful exhaust, while wear on the parts of cylinder and piston assemblies or combustion chambers of unspecified ICE is offset to some extent, when filtered fuels are burnt.
  • the layer 1 as a cylindrical cup is preferred, though other preferably axially symmetric shapes are contemplated, such as a cone, pyramid, prism and so on.
  • the layer 1 may be shaped as a disk fitted in a filter case (not shown) so as to provide a galvanic coupling with at least the layer 2 or the layers 2, 3.
  • the layers 2, 3, and 4 are specifically disks of constant thickness, each being in contact along its circumference with the side wall of the cylindrical cup, or the layer 1, to thereby provide a galvanic coupling therewith. It is to be understood that the layers 2, 3, and 4 are useful in other shapes as well, such as disks of variable thickness like biconvex, biconcave, planoconvex or planoconcave lenses; convex or concave disks of constant thickness; stepped preferably axially symmetric insert pieces and so on. The choice of shape will only be guided by mounting and replacement considerations. Also, all or some of the axially aligned layers 2, 3, and 4 can be axially spaced apart to accumulate filtered off particles in the thus provided spaces.
  • the layer 4 being a relatively self-contained part - primary filter, and having pore sizes ranging from 150 to 300 ⁇ m at total porosity of at least 50%, is preferred as a pre-molded feltlike structure of a predetermined diameter wire lengths and arranged so in the case of the filter device as to be the first in the stream of the fuel being filtered.
  • the discrete layer 5 is preferably arranged either between the portion adjoining the bottom of the porous cup, being a shape of the titanium-base layer 1 of the filter device, and the copper-base porous layer 2 or between the layers 1 and 3, provided zinc is present in the filter.
  • the layer 5 can be arranged between the layers 4 and 2.
  • inactive parts e.g. inserts consisting of one or several layers of polyamide or basalt web to retain pellets as the layer 5.
  • the filter devices further designated FI, F2, and F3 were constructed from materials having a composition (pore sizes and porosity included) and disposed in the layers arranged in a downstream order as shown in Table 1.
  • Salt pellets for the layer 5 were prepared from active ingredients and in proportions that correspond to some volumes borrowed from Table 2 and in specific molar amounts presented by specific examples that follow.
  • composition of active parts mean pore sizes ( ⁇ m) and porosity (%) in the layers of filter devices tested
  • column 7 shows preferred mean amounts of ingredients in moles per mole of copper
  • salt additives may comprise the above-exemplified ingredients in any combination and may be used in whatever amounts desired.
  • the titanium layer was shaped as a cup of 70 mm in diameter and 60 mm in height with the wall thickness of 6.0 mm, while the layers of brass, copper, and zinc were shaped as flat disks of 58 mm in diameter and 10 mm thick and were fitted in the porous titanium cup so that spaces of 5 to 6 mm between the layers and 20 mm between the last layer and the bottom of the cup were allowed.
  • the latter spacing was filled with salt pellets of about 10 mm in diameter and about 5mm thick fixed with the help of inert substance in the form of polyamide fibers.
  • the pellets as consumable material of the layer 5 were prepared from formates, acetates, oxalates, and tartrates of copper, zinc, tin, and lead.
  • Other salts of these metals with inorganic anions, such as nitrates or chlorides, and organic anions, such as propionates, butyrates, etc., can also be utilized.
  • Molybdenum, tungsten, and vanadium are preferred as the MoO " , WO " , and VO " anions existing in commonly known salts of sodium, potassium or ammonium, which are to be understood as nonlimiting examples.
  • Nickel and silver are preferably useful as nitrates, while nickel alone is acceptable as sulfates or water-soluble salts of lower monocarboxylic acid or lower bicarboxylic acid.
  • Zirconium is preferred in additives as zirconium oxychloride hydrate.
  • zirconium oxychloride hydrate may be replaced by or used together with Seignette's salt (potassium sodium tartrate) or with alums, e.g. potash alum, ammonium vanadic alum, and so on, having 12 to 24 molecules of water of hydration, as inherent sources of moisture which, by interacting with the salts of brass-forming metals, assist in dispersing the latter throughout the dehydrated fuels.
  • Seignette's salt potassium sodium tartrate
  • alums e.g. potash alum, ammonium vanadic alum, and so on, having 12 to 24 molecules of water of hydration, as inherent sources of moisture which, by interacting with the salts of brass-forming metals, assist in dispersing the latter throughout the dehydrated fuels.
  • combustible binders that are soluble in water and/or liquid hydrocarbons, such as methyl- or carboxymethyl cellulose, polyvinyl alcohol, etc., may be used along with the specified active substances that are contributors of brass metals and optionally with auxiliary substances that assist in dispersing the active substances throughout the liquid fuels.
  • the above mentioned substances are useful in preparing durable tablets or pellets from the active and auxiliary substances.
  • the material for the layer 5 was prepared as follows:
  • the mixture produced was shaped (with binders if required) as tablets or pellets.
  • the active zone of the filter device defined by an assortment of the above-described filter medium layers, was assembled in the porous cup (the layer 1) of the titanium-base component.
  • Such cups were fitted into filter cases provided with means for connecting the same into the fuel conveying system of ICE. Then, assembled filter devices were connected into the fuel conveying systems and tested.
  • the active zone of the filter devices tested was of the composition of FI as in Table 1.
  • the brass in the layer 2 contained copper and zinc in the molar ratio of 1 Cu to 0.4 Zn.
  • the filter devices were used for removing particles and activating leaded fuels inherently containing water, with an octane number of 76, in the fuel conveying systems of 4-cylinder gasoline engines of 6 economy cars that had already run 5,000 to 6,000 km each.
  • a 600 km run in the test showed compression in the ICE cylinders of all the cars level off and increase by an average of 3.0% compared with that at the beginning of the test, while fuel consumption per 100 km run under urban conditions was decreased by 3%, and CO, CH, and NO x were decreased by 20, 45, and 16% respectively with lead in exhaust gases practically nonexistent.
  • the cars as in Example la were used in further tests but the active zone of the filter device FI also contained tablets prepared from a mixture of copper acetate, tin dioxide, ammonium molybdate, ammonium tungstate and ammonium vanadate, nickel nitrate, hydrated zirconium oxychloride, and Trilon B, all present in the molar ratio of
  • the active zone of the filter devices tested was of the composition of F2 as in Table 1.
  • the filter devices were used for removing particles and activating clear gasoline inherently containing water, with an octane number of 95, in the fuel conveying systems of gasoline engines of 4 VOLGA taxicabs that had already run about 25,000 km each.
  • a 400 km run in the test showed compression in the ICE cylinders of all the cars level off and increase by an average of 3.5% compared with that at the beginning of the test, while fuel consumption per 100 km run under urban conditions was decreased by 4% and CO, CH, and NO x were decreased by 26, 48, and 17% respectively.
  • the active zone of the filter device F2 also contained tablets prepared from a mixture of copper sulfate pentahydrate (CuSO 4 • 5H 2 O), zinc acetate, lead acetate, ammonium molybdate, ammonium tungstate, ammonium vanadate, nickel nitrate, silver nitrate, and hydrated zirconium oxychloride with additioin of cupferron, all present in the molar ratio of
  • the active zone of the filter devices tested was of the composition of F3 as in Table 1.
  • the filter devices were used for removing particles and activating commercial grade winter diesel fuels inherently containing water, in the fuel conveying systems of 8-cylinder diesel engines of 2 trucks of load carrying capacity up to 8 metric tons, which had already run about 35,000 km each.
  • the trucks of Example 3a were used in further tests but running on dehydrated winter diesel fuel, and the active zone of the filter device F3 contained tablets prepared from a mixture of copper sulfate pentahydrate, lead formate, ammonium molybdate, ammonium tungstate, ammonium vanadic alum, nickel nitrate, oxyquinoline, all present in the molar ratio
  • the filtering medium and the filter device for liquid fuels as hereinbefore described can be used as alternative means for reducing toxicity in exhaust gases of a major pollutant of the environment, such as automobiles. Also, the filtering medium and the filter device of the invention will produce the same effect if used in other heat power systems that burn liquid fuels and where such reactors are not utilized.
  • the present invention When used with piston engines, the present invention provides for a means of fundamental importance for offsetting wear on the surfaces of cylinder and piston assemblies while engines are running to thereby decrease specific fuel consumption and increase specific power of internal combustion engines.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
  • Filtering Materials (AREA)

Abstract

Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant, ledit milieu filtrant comprenant au moins une couche poreuse d'un composé à base de titane et au moins une couche d'un composant à base de cuivre présentant un potentiel d'électrode plus élevé par rapport à celui du titane. Afin de créer un dispositif de filtrage capable d'activer le combustible alimenté, on a conféré une conductivité d'électrons à tous les composants du milieu filtrant et, partant, aux parties de la zone active du dispositif filtrant, les couches étant espacées entre elles à l'exception d'une partie de la surface, et ce pour assurer le couplage galvanique. De façon similaire, la couche du composant à base de cuivre est poreuse et présente une taille de pores moins importante, la porosité globale dépassant celle de la couche du composé à base de titane. Montée dans le boîtier du filtre, la couche du composant à base de cuivre se trouve en aval des autres couches.
PCT/RU2002/000155 2001-04-27 2002-04-08 Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant WO2002088278A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP02766699A EP1421156A4 (fr) 2001-04-27 2002-04-08 Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2001111403/12A RU2195992C1 (ru) 2000-12-28 2001-04-27 Фильтрующий материал для жидких топлив и фильтр на его основе
RU2001111403 2001-04-27

Publications (1)

Publication Number Publication Date
WO2002088278A1 true WO2002088278A1 (fr) 2002-11-07

Family

ID=20248983

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2002/000155 WO2002088278A1 (fr) 2001-04-27 2002-04-08 Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant

Country Status (2)

Country Link
EP (1) EP1421156A4 (fr)
WO (1) WO2002088278A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014110339A1 (de) * 2014-07-22 2016-01-28 Haver & Boecker Ohg Lagenverbund von flächigen porösen Lagen

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111036256B (zh) * 2019-12-19 2021-05-25 昆明理工大学 一种钒酸盐复合Mxene气凝胶光催化剂的制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6447450A (en) * 1987-05-16 1989-02-21 Dornier System Gmbh Catalytically active coating for diesel soot filter
SU1586747A1 (ru) * 1988-08-23 1990-08-23 Институт проблем материаловедения АН УССР Способ изготовлени фильтрующего элемента дл очистки топлива
RU2038217C1 (ru) * 1992-12-07 1995-06-27 Лев Хатевич Певзнер Слоистый пористый материал
RU2134238C1 (ru) * 1997-12-29 1999-08-10 Геологический факультет МГУ им.М.В.Ломоносова Способ очистки воды
RU2177073C2 (ru) * 1996-01-22 2001-12-20 Клинэр Энвайроментал Текнолоджиз (Айрлэнд) Лимитед Топливный фильтр и способ его получения

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6447450A (en) * 1987-05-16 1989-02-21 Dornier System Gmbh Catalytically active coating for diesel soot filter
SU1586747A1 (ru) * 1988-08-23 1990-08-23 Институт проблем материаловедения АН УССР Способ изготовлени фильтрующего элемента дл очистки топлива
RU2038217C1 (ru) * 1992-12-07 1995-06-27 Лев Хатевич Певзнер Слоистый пористый материал
RU2177073C2 (ru) * 1996-01-22 2001-12-20 Клинэр Энвайроментал Текнолоджиз (Айрлэнд) Лимитед Топливный фильтр и способ его получения
RU2134238C1 (ru) * 1997-12-29 1999-08-10 Геологический факультет МГУ им.М.В.Ломоносова Способ очистки воды

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1421156A4 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014110339A1 (de) * 2014-07-22 2016-01-28 Haver & Boecker Ohg Lagenverbund von flächigen porösen Lagen

Also Published As

Publication number Publication date
EP1421156A4 (fr) 2005-02-09
EP1421156A1 (fr) 2004-05-26

Similar Documents

Publication Publication Date Title
US5501714A (en) Operation of diesel engines with reduced particulate emission by utilization of platinum group metal fuel additive and pass-through catalytic oxidizer
US5816225A (en) Device for the treatment of engine and heating fuels obtained from mineral oil or from plants
KR100636699B1 (ko) 연료 첨가제
EP0603392B1 (fr) Piege a particules destine a epurer les gaz d'echappement des moteurs diesel
RU2361903C2 (ru) Присадки из наносплава к топливу
CN1317372C (zh) 纳米燃油添加剂
WO1997004045A1 (fr) Procedes permettant de diminuer les emissions toxiques d'un moteur diesel
US6152972A (en) Gasoline additives for catalytic control of emissions from combustion engines
EP0714692B1 (fr) Catalyseur pour la purification de gaz d'échappement d'un moteur diesel
DE69908557T2 (de) Katalysator zur abgasbehandlung bei zweitaktmotoren
CN101039736A (zh) 带催化剂的柴油机炭烟过滤器及其使用方法
JP3370707B2 (ja) 燃料に添加剤としてフェロセンを添加する方法
WO2010109734A1 (fr) Catalyseur de purification de gaz d'échappement pour véhicule à selle
EP1421156A1 (fr) Milieu filtrant pour carburants liquides et dispositif de filtrage l'utilisant
RU2195992C1 (ru) Фильтрующий материал для жидких топлив и фильтр на его основе
EP0925823B1 (fr) Dispositif de réglage des émissions d' échappement et procédé pour sa fabrication
US3455843A (en) Hydrocarbon oxidation catalyst
JP2009072764A (ja) 排気ガス粒子用フィルター、および排気ガス粒子用フィルターの製造方法
Krutzsch et al. Effect of sodium-and lithium-based fuel additives on the regeneration efficiency of diesel particulate filters
CN108753383A (zh) 一种燃油助剂及其制备方法以及该燃油助剂的应用
RU2187541C1 (ru) Композиционная присадка к жидким топливам
EP1528097B1 (fr) Procédé pour diminuer l'écaillage des dépôts de la chambre de combustion.
CN101307706A (zh) 提供钨到含铁的燃烧系统或燃烧系统废气流
CN101191086A (zh) 石油燃烧促进添加剂及其制备方法
KR19990029096A (ko) 디젤엔진으로부터의 유해 배출물을 감소시키는 방법

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2002766699

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 2002766699

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2002766699

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP