WO2002079094A2 - Appareil de traitement de l'eau aux ultraviolets equipe d'un generateur vortex mobile - Google Patents

Appareil de traitement de l'eau aux ultraviolets equipe d'un generateur vortex mobile Download PDF

Info

Publication number
WO2002079094A2
WO2002079094A2 PCT/CA2002/000377 CA0200377W WO02079094A2 WO 2002079094 A2 WO2002079094 A2 WO 2002079094A2 CA 0200377 W CA0200377 W CA 0200377W WO 02079094 A2 WO02079094 A2 WO 02079094A2
Authority
WO
WIPO (PCT)
Prior art keywords
water
ultraviolet lamp
moveable
purification apparatus
vortex generator
Prior art date
Application number
PCT/CA2002/000377
Other languages
English (en)
Other versions
WO2002079094A3 (fr
Inventor
Demao Wang
Original Assignee
Photoscience Japan Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Photoscience Japan Corporation filed Critical Photoscience Japan Corporation
Priority to AU2002242537A priority Critical patent/AU2002242537A1/en
Publication of WO2002079094A2 publication Critical patent/WO2002079094A2/fr
Publication of WO2002079094A3 publication Critical patent/WO2002079094A3/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08—Radiation
    • A61L2/10—Ultra-violet radiation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325—Irradiation devices or lamp constructions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/32—Details relating to UV-irradiation devices
    • C02F2201/322—Lamp arrangement
    • C02F2201/3227—Units with two or more lamps
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/32—Details relating to UV-irradiation devices
    • C02F2201/328—Having flow diverters (baffles)
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/02—Fluid flow conditions
    • C02F2301/024—Turbulent

Definitions

  • the present invention relates to water purification apparatus located in an open channel or especially in the form of a tubular or pipe reactor through which water is passed for treatment.
  • the present invention relates to a water purification apparatus with elongated ultraviolet lamp assemblies, in which there is turbulent flow of water that passes through the elongated ultraviolet lamp assembly.
  • the turbulent flow is effected by baffles, flow devices or other moveable vortex generators that in a pipe reactor are located prior to i.e. upstream of, the elongated ultraviolet lamp assemblies.
  • the baffles, flow devices or other moveable vortex generators may be located between elongated ultraviolet lamp assemblies.
  • the moveable vortex generators are free to move in the current of water passing through the apparatus, e.g. by freely swinging on an axis perpendicular to the flow of water, thereby causing turbulence in the water.
  • the expression "moveable vortex generator” is used to include baffles, flow devices and other moveable turbulence generators that are placed in the water to be treated.
  • a variety of apparatus with vertical arrays of elongated ultraviolet lamps are known. Examples include the apparatus disclosed in U.S. Patent 5,019,256. This patent discloses an ultraviolet lamp rack assembly comprising a vertical array of horizontally disposed ultraviolet lamps for the treatment of waste water. Variations of this apparatus are disclosed in U.S. Patents 4,482,809, 4,872,980 and 5,006,244. Such apparatus have the ballast located above the water level. Apparatus with the ballast located under water and adjacent to the lamp is disclosed in U.S. Patent 6,193,939.
  • U.S. Patent 5,660,719 discloses an ultraviolet lamp rack assembly comprising an array of vertically disposed ultraviolet lamps for the treatment of fluids.
  • Tubular reactors also known as pipe reactors, are also used in the ultraviolet treatment of water.
  • a tubular reactor water is passed through a fluid-flow passageway, typically an annular passageway, in which there are elongated ultraviolet lamp assemblies.
  • the lamp assemblies may be aligned with the direction of flow of water i.e. aligned longitudinally, or extend lateral to the direction of flow i.e. extend across a diameter of the annular passageway.
  • the ability of an ultraviolet light treatment system to inactivate (kill) micro-organisms is a function of the UV fluence generated in the treatment system.
  • the UV fluence is the product of the fluence rate and the time of treatment.
  • the ability of ultraviolet light to penetrate wastewater, and hence treat the wastewater, is affected by the transmission of ultraviolet light. As the ultraviolet transmission from the lamp decreases, the fluence rate also decreases.
  • the important factors in the transmission of ultraviolet light include the age of the lamp, the degree of fouling of the lamps i.e. the degree of fouling of the quartz sleeve around the lamp, and the clarity of the wastewater that is being treated.
  • Steps may be taken to clean, the lamps and especially the quartz sleeve around the lamp, but the clarity of the water to be treated may be difficult or impossible to control.
  • the amount of ultraviolet light obtainable from an ultraviolet lamp is limited.
  • the consequence of the need to provide a UV fluence to efficiently and effectively treat the water is that there is a tendency and desire to place the ultraviolet lamps closer and closer together and/or to use more ultraviolet lamps.
  • microorganisms To kill microorganisms in water, it is necessary to subject the microorganisms to a minimum fluence of ultraviolet light.
  • a water purification apparatus As the microorganisms pass through a water purification apparatus, the microorganisms are subjected to a range of UV fluences, depending on the quality of the water and especially on the location of the microorganisms with respect to the array of lamps. Consequently, a water purification apparatus is designed to produce an average fluence that is sufficient to kill the microorganisms. Nonetheless, the UV fluence that a particular microorganism is subjected to may vary over a wide range depending on the particular path that the microorganism takes as it passes through the reactor. In a poorly designed apparatus, microorganisms may be able to pass through the apparatus without being subjected to sufficient UV fluence to kill the microorganism.
  • turbulence within the zone of the apparatus in which treatment occurs is intended to prevent microorganisms from passing through without being subjected to at least the minimum UV fluence to kill the microorganisms.
  • methods to create turbulence include the use of ring-shaped devices e.g. washers, on the exterior surface of the elongated ultraviolet light assemblies as disclosed in WO 98/29345, the use of distributors as disclosed in U.S. 4 952 376, the use of baffles within a tube as disclosed in U.S. 4 304 996, U.S. 5 696 380 and 5 866 910 and the use of serpentine flow as disclosed in U.S. 5 352 359.
  • one aspect of the present invention provides a water purification apparatus comprising at least one elongated ultraviolet light assembly extending into a flow of water to be treated, at least one moveable vortex generator located upstream of said at least one elongated ultraviolet lamp assembly, said moveable vortex generator being adapted to be continuously moveable with respect to the direction of flow of water during said treatment of water.
  • the elongated ultraviolet lamp assemblies are axially located, especially in a fluid-flow passageway that is an annular passage.
  • the elongated ultraviolet lamp assemblies may be staggered.
  • the elongated ultraviolet lamp assemblies extend across a substantial portion of the height of the passageway.
  • the moveable vortex generator causes flow of water in a direction other than the longitudinal direction of flow of water through the channel.
  • the moveable vortex generator is separable from or separate from the elongated ultraviolet lamp assembly for independent removal from the channel.
  • an open channel water purification apparatus comprising at least one elongated ultraviolet light assembly extending into a flow of water to be treated, at least one moveable vortex generator, said moveable vortex generator being adapted to be continuously moveable with respect to the direction of flow of water during said treatment of water.
  • the open channel apparatus of the present invention there are a plurality of elongated ultraviolet lamp assemblies adapted to be immersed in water in an open channel having water flowing longitudinally therethrough, said elongated ultraviolet lamp assemblies being supported by a frame.
  • at least one moveable vortex generator is located upstream of and juxtaposed to said elongated ultraviolet lamp assemblies.
  • at least one moveable vortex generator is located between said elongated ultraviolet lamp assemblies.
  • the moveable vortex generator causes flow of water in a direction other than the longitudinal direction of flow of water through the channel.
  • the moveable vortex generator is separable from the elongated ultraviolet lamp assembly for independent removal from the channel.
  • a method for the photochemical treatment of water in a water purification apparatus comprising at least one ultraviolet lamp assembly extending into a flow of water to be treated, and at least one moveable vortex generator located upstream of said elongated ultraviolet lamp assembly, said method comprising redirecting longitudinally flowing water in a turbulent pattern towards and about said elongated ultraviolet lamp assemblies and throughout said channel, such that any microorganism present in said water is destroyed, wherein said water is redirected by said moveable vortex generator which is continuously moveable with respect to the direction of flow of water during said treatment of water.
  • Figure 1 is a schematic representation of an end view of apparatus of the present invention
  • Figure 2 is a schematic representation of a cross section of the apparatus of Figure 1 , through A-A;
  • Figure 3 is a schematic representation of a cross-section of the apparatus of Figure 1 , through B-B of Fig. 2;
  • Figure 4 is a schematic representation of detail of "C" of the apparatus of Figure 1 ;
  • Figure 5 is a schematic representation of an alternate embodiment of the apparatus of Figure 1 ; and Fig. 6 is a schematic representation of a cross-section of the apparatus of Fig. 5, through D- D.
  • the present invention relates to a water purification apparatus and in preferred embodiments to a water purification apparatus having a housing with a fluid-flow passageway therethrough.
  • the water purification apparatus is of a type that has a pipe reactor with at least one elongated ultraviolet lamp assembly extending into the fluid- flow passageway.
  • elongated ultraviolet lamp assemblies extending into the fluid-flow passageway.
  • the lamp assemblies are for the treatment of water that is passed through the passageway.
  • At least one moveable vortex generator is located in the passageway in the stream of the elongated ultraviolet lamp assemblies, with the vortex generator being adapted to be continuously moveable in position during the treatment of water. This creates turbulence within the fluid-flow passageway.
  • Apparatus 10 has flange 12 with a plurality of bolt holes 14, which are used to attach the flange to a mating flange that forms part of the passageway that brings water into the apparatus for treatment.
  • Apparatus 10 has fluid-flow passageway 16 that passes through flange 12 and through apparatus 10.
  • Fluid-flow passageway 16 has passageway deflector 18 that defines fluid-flow passageway 16.
  • Fluid- flow passageway 16 additionally has first moveable baffle 20 and second moveable baffle 22 that extend downwards through fluid-flow passageway 16, and are located at the entrance to the apparatus 10. Quartz sleeve 24 extends downwards through fluid-flow passageway 16, and encloses ultraviolet lamp 26.
  • ultraviolet lamp 26 In Figure 1 , only one ultraviolet lamp 26 is shown, but in normal use at least two such lamps would be used. The number of lamps will depend on the flow of water to be treated and on the required level of treatment. Thus, more than two lamps may be required, and typically would be used.
  • the quartz sleeves on the elongated ultraviolet lamp assemblies will normally have devices for cleaning of the sleeves during use. Such devices are not shown but examples include scrapers, brushes and chemical cleaning systems.
  • Baffle 20 is held in position by baffle mountings 28 and 30 that are located in wall 32 of apparatus 10. Further details of mountings 28 and 30 are shown as detail C in Fig. 4. As discussed herein, baffles 20 and 22 are freely moveable in the respective mountings, so that the baffles will move in the current of water passing through passageway 16. It is the flow of water that causes movement of the baffles in the pivot holes.
  • Fig. 2 shows a cross section of apparatus 10, along A-A of Fig. 1.
  • Apparatus 10 has two ultraviolet lamps 26 and 26A, with their respective quartz sleeves 24 and 24A. Quartz sleeve 24, which encompasses lamp 26, extends from lower lamp support 46 to upper lamp_support 48. Similarly, quartz sleeve 24A extends from lower lamp support 46A to upper lamp support 48A. It is understood that each of ultraviolet lamps 26 and 26A would have a ballast and electrical connections thereto for operation of the lamp, which are not shown in Fig. 2.
  • Second baffle 22 is shown in fluid-flow passageway 16, approximately at the location of flange 12. Thus, second baffle 22 is located upstream from ultraviolet lamp 26. Arrow 50 shows the direction of flow of water through fluid-flow passageway 16 of apparatus 10.
  • Fig. 3 shows a section of apparatus 10, through B-B of Fig. 2.
  • the direction of flow of water is indicated by arrow 50.
  • first baffle 20 and second baffle 22 are shown as being near, but separate from, passageway deflectors 18, which also cause turbulence in the water flowing into fluid-flow passageway 16.
  • apparatus 10 is shown with two ultraviolet lamps, but is understood that the apparatus could have more than two lamps. It would not normally have only one lamp, although one lamp could be used:
  • Apparatus 10 is also shown with two baffles, but could have one or more than two baffles. The locations of the baffles can be varied, but will be in advance of ultraviolet lamps in the fluid-flow passageway.
  • FIG. 4 shows detail of a mounting, indicated by "C” shown in Fig. 1.
  • Baffle vane 40 of a baffle e.g. 20 or 22, is attached to wall 42 of apparatus 10.
  • the mounting, generally indicated by 30 has bushing 44 in wall 42.
  • Bushing 44 has a female thread and spindle 52 connects to bushing 44 by a corresponding male thread.
  • Seal 46 is located between bushing 44 and spindle head 48.
  • Baffle vane 40 has housing 53.
  • Spindle 52 is inserted in housing 53 in baffle vane 40 to hold the baffle vane in place, permitting baffle vane 40 to freely rotate or swing around spindle 52. It is understood that other means may be used to mount baffle vane 40 into pipe wall 42 so that baffle vane 40 is free to swing or rotate.
  • Fig. 5 shows an end view of an alternate attachment of baffles into apparatus 10.
  • Baffle vane 60 is attached at opposed ends to spindles 62, which in turn are connected to threaded shaft 64 that extends through ring plate 66, and is held in place by end 68 of threaded shaft 64.
  • Seal 70 is located between end 68 and ring plate 66.
  • Fig. 6 shows a cross-section of Fig. 5 through D-D. Apparatus
  • Apparatus 10 has wall 42, which forms fluid-flow passageway 16. Ultraviolet lamps 26 and 26A extend across fluid-flow passageway 16, as described previously.
  • Apparatus 10 has end flanges 12 and bolt holes 14. Attached to the forward flange 12 is ring plate 66 with baffle vane 60. Ring plate 66 is between flange 12 and flange 72 of pipe 74. Pipe 74 forms the inlet for water entering apparatus 10 for treatment, the direction of flow being indicated by arrow 50.
  • the moveable vortex generator of the present invention creates turbulence, especially in a pipe reactor, using vortex generators that are capable of being moved by the flow of water through the apparatus.
  • the moveable vortex generators are placed upstream of the first of the ultraviolet lamp assemblies, and thus, do not shade water that is being treated in the apparatus.
  • the moveable vortex generators are simple to manufacture and to install, and can be used to retrofit pre-existing ultraviolet water treatment systems.
  • the vortex generators may be fitted into the apparatus in a manner that permits removal for cleaning.
  • the flow of water will result in changes of water pressure on opposed sides of the baffle vane, which will cause the vane to move.
  • the side of the vane with the higher pressure will alternate, causing the vane to move from side to side in the flow of water, and consequently causing interruptions in the flow and turbulence in the water.
  • the vortex generators may also be located between elongated ultraviolet light assemblies.
  • the vortex generators are preferably located upstream or adjacent to the ballasts but may also be located between the ultraviolet lamps.
  • the movement of the vortex generators creates additional turbulence i.e. additional turbulence to that created in the absence of movement of the same vortex generators.
  • additional turbulence i.e. additional turbulence to that created in the absence of movement of the same vortex generators.
  • the flow of water will be disturbed by the change of flow direction resulting from the use of the moveable vortex generators, thereby creating more turbulence.

Abstract

L'invention concerne un appareil d'épuration de l'eau comprenant au moins un ensemble allongé à lumière ultraviolette, s'étendant dans un courant d'eau à traiter. Au moins un générateur vortex mobile est disposé en amont dudit ensemble allongé à lampe ultraviolette. Le générateur mobile est adapté de manière à pouvoir se déplacer en continu par rapport au sens d'écoulement de l'eau au cours dudit traitement. De préférence, il est prévu une enveloppe comportant un passage d'écoulement de fluide, ledit ensemble allongé à lampe ultraviolette s'étendant dans ce passage en vue du traitement de l'eau circulant à travers celui-ci. Le générateur vortex comprend de préférence au moins une chicane disposée dans ledit passage, en amont de l'ensemble à lampe ultraviolette.
PCT/CA2002/000377 2001-03-28 2002-03-20 Appareil de traitement de l'eau aux ultraviolets equipe d'un generateur vortex mobile WO2002079094A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002242537A AU2002242537A1 (en) 2001-03-28 2002-03-20 Ultraviolet water treatment apparatus with moveable vortex generator

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US27924801P 2001-03-28 2001-03-28
US60/279,248 2001-03-28

Publications (2)

Publication Number Publication Date
WO2002079094A2 true WO2002079094A2 (fr) 2002-10-10
WO2002079094A3 WO2002079094A3 (fr) 2003-04-03

Family

ID=23068217

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2002/000377 WO2002079094A2 (fr) 2001-03-28 2002-03-20 Appareil de traitement de l'eau aux ultraviolets equipe d'un generateur vortex mobile

Country Status (2)

Country Link
AU (1) AU2002242537A1 (fr)
WO (1) WO2002079094A2 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1212633A (en) * 1968-04-03 1970-11-18 Erex Hydro Engineering Pty Ltd Improvements relating to the irradiation of fluids
US5545335A (en) * 1994-09-26 1996-08-13 Adrian P. Sween Water purifier
US5997812A (en) * 1996-06-20 1999-12-07 Coolant Treatment Systems, L.L.C. Methods and apparatus for the application of combined fields to disinfect fluids
US6083387A (en) * 1996-06-20 2000-07-04 Burnham Technologies Ltd. Apparatus for the disinfection of fluids
US20020030011A1 (en) * 2000-07-31 2002-03-14 Maritime Solutions, Inc. Apparatus and method for treating water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1212633A (en) * 1968-04-03 1970-11-18 Erex Hydro Engineering Pty Ltd Improvements relating to the irradiation of fluids
US5545335A (en) * 1994-09-26 1996-08-13 Adrian P. Sween Water purifier
US5997812A (en) * 1996-06-20 1999-12-07 Coolant Treatment Systems, L.L.C. Methods and apparatus for the application of combined fields to disinfect fluids
US6083387A (en) * 1996-06-20 2000-07-04 Burnham Technologies Ltd. Apparatus for the disinfection of fluids
US20020030011A1 (en) * 2000-07-31 2002-03-14 Maritime Solutions, Inc. Apparatus and method for treating water

Also Published As

Publication number Publication date
WO2002079094A3 (fr) 2003-04-03
AU2002242537A1 (en) 2002-10-15

Similar Documents

Publication Publication Date Title
CA1293847C (fr) Systeme epurateur de fluide
EP0080780B1 (fr) Appareil purificateur de fluides par rayonnement U.V.
US5843309A (en) Water purification system
AU782998B2 (en) Fluid treatment device and method for treatment of fluid
US20100224562A1 (en) Ultraviolet Disinfection System and Method
US6570167B1 (en) Apparatus for treating a liquid
JP4690872B2 (ja) 紫外線照射水処理装置
US7507973B2 (en) UV treatment reactor
JP2007144386A (ja) 紫外線照射水処理装置
CA2149266C (fr) Appareil servant a la desinfection d'un liquide en ecoulement, et materiel servant au traitement des eaux usees decantees
CA2513878C (fr) Dispositif modulaire pour desinfecter un grand volume de liquide sous haute pression a l'aide d'un rayonnement uv
US20040118786A1 (en) Fluid treatment system
EP2805064B1 (fr) Modificateur de flux de fluide et système de traitement de fluide comprenant ce modificateur
US20030129105A1 (en) Ultraviolet water disinfection reactor for installing in an existing water pipeline
WO1999052566A1 (fr) Systeme de desinfection de l'eau par les ultraviolets
WO2016110829A1 (fr) Système et méthode de traitement par rayonnement
WO2002079095A1 (fr) Nettoyage de lampes decalees dans un systeme de traitement d'eau legere par ultraviolet
US6781137B2 (en) Fluid treatment apparatus
WO2002079094A2 (fr) Appareil de traitement de l'eau aux ultraviolets equipe d'un generateur vortex mobile
WO2003024874A2 (fr) Systeme de traitement de fluide
WO2002072480A1 (fr) Dispositif de purification d'eau par rayonnement u.v. a courant tourbillonnaire
WO2009076765A1 (fr) Ensemble de source de rayonnements et système de traitement de fluide
CN212425512U (zh) 一种改变紫外线消毒器中水流分布的装置
JP2004050169A (ja) 渦流加速紫外線殺菌滅藻液体処理器
WO2003024873A1 (fr) Appareil de traitement de l'eau par ultraviolets comprenant une chicane en forme de dome

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase in:

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP