WO2002056424A1 - Contact terminal - Google Patents

Contact terminal Download PDF

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Publication number
WO2002056424A1
WO2002056424A1 PCT/JP2001/003319 JP0103319W WO02056424A1 WO 2002056424 A1 WO2002056424 A1 WO 2002056424A1 JP 0103319 W JP0103319 W JP 0103319W WO 02056424 A1 WO02056424 A1 WO 02056424A1
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WO
WIPO (PCT)
Prior art keywords
contact
contact terminal
hard particles
electrode
secondary battery
Prior art date
Application number
PCT/JP2001/003319
Other languages
French (fr)
Japanese (ja)
Inventor
Hiroshi Andou
Original Assignee
Toshiba It & Control Systems Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Toshiba It & Control Systems Corporation filed Critical Toshiba It & Control Systems Corporation
Publication of WO2002056424A1 publication Critical patent/WO2002056424A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R13/00Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
    • H01R13/02Contact members
    • H01R13/03Contact members characterised by the material, e.g. plating, or coating materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R4/00Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
    • H01R4/58Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation characterised by the form or material of the contacting members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/562Terminals characterised by the material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to a contact terminal of a device that comes into contact with a conductor having an electrode, and in particular, can maintain a value of a contact resistance generated between the electrode and the electrode close to an initial value over a long period of time. This is related to the contact terminal.
  • This charging / discharging test apparatus detects the voltage between the electrodes of the secondary battery while charging the secondary battery, and applies a predetermined charge voltage to the secondary battery. Control.
  • the secondary battery is provided with electrodes, and is usually arranged one by one in a plurality of grooves formed on the bottom surface of the tray accommodated in the above-mentioned charge / discharge test device, and the battery electrode portion is located on the lower side. It is arranged as follows.
  • the tray can accommodate a plurality of secondary batteries.
  • FIGS. 1A and 1B are schematic diagrams showing a configuration example of a conventional battery test contact terminal used by being attached to this type of charge / discharge test apparatus.
  • FIGS. 1A and 1B in order to conduct a charge / discharge test of a secondary battery 2 provided with thin plate-shaped positive and negative electrodes 1, a plurality of (three in the figure) secondary batteries 2 were used. A pair of contact terminals 3 and 4 are arranged facing each other so as to be in contact with and sandwich electrode 1 at the center. Is
  • One end (lower end) of the pair of opposed contact terminals 3 and 4 on the opposite side to the electrode 1 is supported by a fixed plate 5, and the fixed plate 5 is operated.
  • the electrode 1 of the secondary battery 2 is pressed (open / closed).
  • a material of the pair of contact terminals 3 and 4 for example, copper or a copper alloy-based material is used as it is, or a surface treatment such as gold plating is used.
  • the contact terminals attached to the conventional charge / discharge test equipment are composed of a high-resistance film adhered to the positive and negative electrodes 1 of the secondary battery 2 when conducting the charge / discharge test of the secondary battery 2.
  • the contact resistance between the pair of contact terminals 34 increases.
  • the stripped piece of the oxide film is moved to the conductive surface side of the contact terminal by repeated operation, and is deposited as if an oxide film is formed on the contact terminal side, thereby further increasing the contact resistance.
  • the contact pressure must be increased to break the high-resistance film.
  • An object of the present invention is to maintain the value of the contact resistance generated between the contact terminal and the electrode at a value close to the initial value for a long period of time without adding a sliding contact force. Prevents overcurrent and overdischarge caused by poor contact between the terminal and the electrode, preventing damage to the secondary battery and causing problems such as heating of the secondary battery.
  • Another object of the present invention is to provide a contact terminal capable of performing a charge / discharge test with high accuracy while preventing the contact terminal.
  • the contact terminals are a pair of contact terminals arranged to face each other so as to be in contact with and sandwich the electrode, and Hard particles are adhered to one contact surface of the contact terminal, and the other contact surface is left as a material without adhering the hard particles.
  • the hard particle attachment surface of the contact terminal and the material surface are slid in contact with each other without sandwiching the electrode, thereby providing a fine polishing action on the contact terminal material surface side.
  • the oxide film which is a high-resistance film deposited in contact with the electrode up to the previous time, is removed to form a rough surface.
  • the secondary battery electrode is arranged between the contact terminals, and the contact terminals are brought into contact with each other, whereby fine irregularities formed on the contact terminal material surface side are reduced.
  • the value of the contact resistance generated between the battery and the electrode of the secondary battery is maintained at a value close to the initial value for a long period of time. Prevents overcurrent and overdischarge of the secondary battery due to poor contact with the battery electrode, causing damage to the secondary battery and causing problems such as heat generation in the secondary battery. In addition, it is possible to perform an accurate charge / discharge test.
  • the contact terminals are a pair of contact terminals arranged so as to be in contact with each other so as to be in contact with and sandwich the electrode at the center.
  • a cut is made in the axial direction from each tip to divide it into a plurality of divided pieces, and hard particles are attached to one of the contact surfaces of the divided contact terminal pieces, and the other contact surface is made of hard particles. The material is left unadhered.
  • fine irregularities are formed on the contact terminal material surface side by the hard particles attached to one contact surface of the plurality of divided contact terminal divided pieces.
  • by making the cuts it is possible to individually absorb the difference in the thickness of the hard particles between the hard particle-attached portion of the same contact terminal and the portion of the raw material as it is.
  • the contact terminal of the present invention when one electrode needs to contact a plurality of contacts with the same space, it is possible to prevent the contact surface from rising due to the attachment of hard particles, Failure of contact resistance can be prevented.
  • FIGS. 1A and 1B are schematic diagrams illustrating a configuration example of a conventional contact terminal for battery test.
  • FIGS. 2A and 2B are schematic views showing a first embodiment of the contact terminal according to the present invention.
  • 3A to 3C are schematic diagrams showing a contact terminal according to a second embodiment of the present invention.
  • FIGS. 1A and 1B are schematic diagrams showing a configuration example of the contact terminal according to the first embodiment.
  • the same parts as those in FIGS. 1A and 1B are denoted by the same reference numerals and the description thereof will be omitted. Omitted, and only the differences are described here.
  • the contact terminal according to the first embodiment is shown in FIG. 2A.
  • the hard particles 6 are adhered to one contact surface (the contact surface of the contact terminal 3 in this example) of the pair of contact terminals 3 and 4 facing each other in FIG. 1A.
  • the contact surface (the contact surface of the contact terminal 4 in this example) is made of a material (copper or copper alloy material) without the hard particles 6 attached thereto.
  • the hard particles 6 it is preferable to use, for example, any one of diamond, CBN, and the like, but in addition, for example, titanium borohydride, boron carbide Particles of titanium carbide, silicon carbide, silicon nitride, zirconium carbide, titanium nitride, molten aluminum, sintered aluminum, mullite, garnet, and print can also be used. You.
  • a bonding method for attaching the hard particles 6 for example, a method using an electrodeposition bond, a metal bond, a resin bond, or the like can be used.
  • the contact terminal 3 when performing a charge / discharge test of the secondary battery 2, the contact terminal 3 having the hard particles 6 adhered to the contact surface and the contact not having the hard particles 6 adhered to the contact surface
  • the electrode 1 of the secondary battery 2 is brought into sliding contact (opening / closing operation) by operating the fixed plate 5 on which the terminal 4 is supported.
  • the voltage between the electrodes 1 of the secondary battery 2 was detected while charging the secondary battery 2 by means of a charge / discharge test device to which the pair of contact terminals 3 and 4 facing each other was attached.
  • the feedback control is performed so that a predetermined charging voltage is applied to the secondary battery 2 to charge and discharge. Conduct an electrical test.
  • the hard particles 6 were adhered without interposing the electrode 1 of the secondary battery 2 in the gap between the pair of contact terminals 3 and 4 facing each other.
  • This is a high-resistance film adhered by the previous contact with the electrode 1 during the charge / discharge test of the secondary battery 2 on the contact terminal material side by directly sliding the surface and the material surface. By removing the oxide film 7, fine irregularities can be formed on the material surface.
  • the electrode 1 of the secondary battery 2 is arranged between the pair of contact terminals 3 and 4 facing each other, and the contact terminals 3 and 4 supported on one side are brought into contact with each other, so that the contact terminal material surface side is formed.
  • the formed fine irregularities break the oxide film 7, which is a high-resistance film adhered to the surface of the electrode 1, and thus are generated between the contact terminals 3 and 4 and the electrode 1 of the secondary battery 2. Contact resistance can be reduced.
  • the value of the contact resistance generated between the contact terminal and the electrode 1 of the secondary battery 2 is extended over a long period (20,000 or more times of opening and closing). , By maintaining the value close to the initial value (30 m ⁇ or less in this embodiment), thereby preventing overcurrent and overdischarge of the secondary battery 2 due to poor contact with the electrode 1 of the secondary battery 2. To prevent damage to the rechargeable battery 2 or to cause problems such as heat generation in the rechargeable battery 2, and to perform an accurate charge / discharge test. And
  • FIGS. 1A and 1B are schematic diagrams showing a configuration example of a contact terminal according to the second embodiment, and the same parts as those in FIGS. 1A and 1B are the same. The description is omitted by attaching one symbol, and only different portions are described here.
  • the contact terminal according to the second embodiment omits the pair of opposed contact terminals 3 and 4 in FIG. 1A, and replaces this with a notch. It is composed of contact terminals 8.
  • the contact terminals 8 are formed by making one or more (one in this example) axial (in this example) notch in each of a pair of opposing contact terminals from the respective tips. Or it is divided into three or more divided pieces.
  • hard particles 6 are adhered to one of the contact surfaces of the divided contact terminals into eight pieces, and the other contact surface is made of a material (such as copper) without adhering the hard particles 6. Is a copper alloy-based material).
  • the hard particles 6 for example, diamond, CB
  • N particles it is preferable to use any one of N particles, but other than these, for example, titanium boride, boron carbide, titanium carbide, silicon carbide, silicon nitride, zirconium carbide Alternatively, particles such as titanium nitride, molten alumina, sintered alumina, mullite, garnet, and flint can be used.
  • a method for attaching the hard particles 6 for example, a method using an electrodeposition bond, a metal bond, a resin bond, or the like can be used.
  • the rechargeable battery 2 is appropriately charged and discharged by the charge / discharge test device to which the pair of opposing notched contact terminals 8 is attached, and the rechargeable battery 2 is charged. Then, a voltage between the electrodes 1 of the secondary battery 2 is detected, and a charge / discharge test is performed by performing feedback control so that a predetermined charging voltage is applied to the secondary battery 2.
  • the pair of notch contact terminals facing each other are opposed to each other with the electrode 1 of the secondary battery 2 not interposed between the eight divided pieces.
  • the contact terminals to be divided into 8 pieces of the hard particles 6 of the divided piece are directly slid in contact with the material surface, so that fine irregularities can be formed on the contact terminal material surface side.
  • the electrode 1 of the secondary battery 2 is arranged between the pair of opposing contact terminal 8-split pieces, and the contact terminal 8-split pieces supported on one side are brought into contact with each other, so that the contact terminal material surface is reduced.
  • the minute unevenness formed on the side breaks the oxide film 7 which is a high resistance film attached to the surface of the electrode 1, and the contact resistance generated between the contact terminal 8 divided piece and the electrode 1 of the secondary battery 2 Can be reduced.
  • the notched contact terminal 8 having a notch allows individual absorption of the difference in the thickness of the hard particles between the hard particle adhered portion of the same contact terminal and the portion of the raw material as it is. Can be This prevents the contact surface from rising due to the adhesion of the hard particles 6 when one electrode needs to contact multiple contacts in the same space, thereby preventing a problem of contact resistance. can do.
  • the value of the contact resistance generated between the contact terminal and the electrode 1 of the secondary battery 2 is always maintained close to the initial value. This prevents overcurrent and overdischarge of the secondary battery 2 due to poor contact with the electrode 1 of the secondary battery 2 and damages the secondary battery 2 or causes the secondary battery 2 to malfunction due to heat generation or the like. This can prevent the occurrence of such a phenomenon, and also enables a high-precision charge / discharge test to be performed.
  • each embodiment may be implemented in combination as appropriate as possible, and in that case, the combined operation and effect can be obtained.
  • the above embodiments include inventions at various stages, and various inventions can be extracted by appropriately combining a plurality of disclosed constituent elements. .
  • the problems (at least one) described in the section of the problem to be solved by the invention can be solved. If the effect (at least one of the effects) described in the section of the effect of the invention can be obtained, it is possible to extract, as an invention, a configuration from which this constituent requirement has been deleted. You.

Abstract

A pair of contact terminals (3, 4) are opposed to each other with an electrode (1) in contact between them. Hard particles (6) are applied to one contact of the pair of contact terminals (3, 4), with the other contact remaining unprocessed.

Description

明 細 書  Specification
接触端子 Contact terminal
技術分野 Technical field
本発明は、 電極を備えた導電体に接触する装置の接触端 子に係り 、 特に電極との間に発生する接触抵抗の値を、 長期 間にわた り 初期値に近い値に維持でき る よ う に した接触端子 に関する ものである。  The present invention relates to a contact terminal of a device that comes into contact with a conductor having an electrode, and in particular, can maintain a value of a contact resistance generated between the electrode and the electrode close to an initial value over a long period of time. This is related to the contact terminal.
背景技術 Background art
従来から、 例えばリ チウムポ リ マー電池等の二次電池に ついては、 製品の品質を確保するために、 充放電試験装置に よ る充放電試験が行なわれてきている。  Conventionally, for secondary batteries such as lithium polymer batteries, a charge / discharge test has been performed by a charge / discharge test apparatus in order to ensure product quality.
こ の充放電試験装置では、 二次電池を充電しながら二次電 池の電極間電圧を検出 して、 二次電池に対 して所定の充電電 圧を印加する よ う 、 フ ィ一 ドバ ック制御 している。  This charging / discharging test apparatus detects the voltage between the electrodes of the secondary battery while charging the secondary battery, and applies a predetermined charge voltage to the secondary battery. Control.
二次電池は、 電極を備えてお り 、 通常、 上記充放電試験装 置に収納される ト レイ の底面に成形した複数の溝に一つずつ 配置され、 電池電極部が下方側と なる よ う に配置される。 ま た、 ト レィ は、 複数個の二次電池を収納する こ と ができ る。  The secondary battery is provided with electrodes, and is usually arranged one by one in a plurality of grooves formed on the bottom surface of the tray accommodated in the above-mentioned charge / discharge test device, and the battery electrode portion is located on the lower side. It is arranged as follows. In addition, the tray can accommodate a plurality of secondary batteries.
図 1 A及び 1 Bは、 この種の充放電試験装置に取り 付けて 用い られる従来の電池試験用接触端子の構成例を示す概要図 である。  FIGS. 1A and 1B are schematic diagrams showing a configuration example of a conventional battery test contact terminal used by being attached to this type of charge / discharge test apparatus.
図 1 A及び 1 B において、 薄板状の正極および負極の.電極 1 を備えた二次電池 2 の充放電試験を行な う ために、 複数個 (図では 3 個) の二次電池 2 の電極 1 を中心に接触して挟む よ う に、 互いに対向 して一対の接触端子 3 , 4が配置されて いる In FIGS. 1A and 1B, in order to conduct a charge / discharge test of a secondary battery 2 provided with thin plate-shaped positive and negative electrodes 1, a plurality of (three in the figure) secondary batteries 2 were used. A pair of contact terminals 3 and 4 are arranged facing each other so as to be in contact with and sandwich electrode 1 at the center. Is
これらの対向する一対の接触端子 3, 4 の電極 1側と反対 側の一端部 (下端部) は、 それぞれ固定板 5 で支持されてお り 、 当該固定板 5 を動作させる こ と によ り 、 二次電池 2 の電 極 1 を圧接 (開閉動作) する よ う に している。  One end (lower end) of the pair of opposed contact terminals 3 and 4 on the opposite side to the electrode 1 is supported by a fixed plate 5, and the fixed plate 5 is operated. The electrode 1 of the secondary battery 2 is pressed (open / closed).
こ こで、 一対の接触端子 3, 4 の材質と しては、 例えば銅 も し く は銅合金系の素材をそのまま利用するか、 金メ ツキ等 の表面処理を行なって使用 している。  Here, as a material of the pair of contact terminals 3 and 4, for example, copper or a copper alloy-based material is used as it is, or a surface treatment such as gold plating is used.
しかしなが ら、 上述 したよ う な従来の接触端子においては 次のよ う な問題点がある。  However, the conventional contact terminals as described above have the following problems.
すなわち、 従来の充放電試験装置に取り 付けて用い られる 接触端子は、 二次電池 2 の充放電試験を行な う にあたって、 二次電池 2 の正極および負極の電極 1 に付着 した高抵抗被膜 である酸化被膜が挟在する ごとが原因で、 一対の接触端子 3 4 と の間に接触抵抗が増加する。  In other words, the contact terminals attached to the conventional charge / discharge test equipment are composed of a high-resistance film adhered to the positive and negative electrodes 1 of the secondary battery 2 when conducting the charge / discharge test of the secondary battery 2. Each time an oxide film is interposed, the contact resistance between the pair of contact terminals 34 increases.
また、 この酸化被膜の剥離片は繰返し動作によ り接触端子 の導電面側に剥離片が移り 接触端子側に酸化被膜が形成され た様にな り 堆積して更に接触抵抗を高める。  In addition, the stripped piece of the oxide film is moved to the conductive surface side of the contact terminal by repeated operation, and is deposited as if an oxide film is formed on the contact terminal side, thereby further increasing the contact resistance.
また、 前記従来の接触端子では安定した接触抵抗を得るた めには、 前記の高抵抗被膜を破るために接触圧力を増加させ なければな らない。  Further, in order to obtain a stable contact resistance in the conventional contact terminal, the contact pressure must be increased to break the high-resistance film.
そ して、 この接触抵抗が増加する と、 二次電池 2 に対する 過電流や過放電が発生し、 二次電池 2 にダメージを与えた り . 二次電池 2 に発熱等の不具合が発生した り する こ とになる。 発明の開示 本発明の目的は、 接触端子と電極との間に発生する接触 抵抗の値を、 摺接カを增加させる こ と なく 、 長期間にわた り 初期値に近い値に維持 し、 も って接触端子と電極との間の接 触不良によ る過電流や過放電を防止 して二.次電池にダメ ージ を与えた り 、 二次電池の発熱等の不具合が発生した り するの を防止する と共に、 精度のよい充放電試験を行な う こ と が可 能な接触端子を提供する こ と にある。 If the contact resistance increases, overcurrent or overdischarge of the secondary battery 2 occurs, causing damage to the secondary battery 2 or causing a problem such as heat generation in the secondary battery 2. Will be done. Disclosure of the invention An object of the present invention is to maintain the value of the contact resistance generated between the contact terminal and the electrode at a value close to the initial value for a long period of time without adding a sliding contact force. Prevents overcurrent and overdischarge caused by poor contact between the terminal and the electrode, preventing damage to the secondary battery and causing problems such as heating of the secondary battery. Another object of the present invention is to provide a contact terminal capable of performing a charge / discharge test with high accuracy while preventing the contact terminal.
上記の 目 的を達成するために、 この発明によれば、 接触端 子は、 電極を中心に接触して挟むよ う に互いに対向 して配置 される一対の接触端子であって、 対向する一対の接触端子に おける一方の接触面に硬質粒子を付着させ、 も う 一方の接触 面は硬質粒子を付着させずに素材のまま と している。  In order to achieve the above object, according to the present invention, the contact terminals are a pair of contact terminals arranged to face each other so as to be in contact with and sandwich the electrode, and Hard particles are adhered to one contact surface of the contact terminal, and the other contact surface is left as a material without adhering the hard particles.
従って、 この発明の接触端子においては、 上記接触端子の 硬質粒子付着面と素材面と を、 電極を挟まない状態で摺接し 合う こ と によ り 、 接触端子素材面側に微細な研磨作用によ り 前回までの電極との接触で付着 した高抵抗被膜である酸化被 膜を除去 し粗面を形成させておく 。  Therefore, in the contact terminal of the present invention, the hard particle attachment surface of the contact terminal and the material surface are slid in contact with each other without sandwiching the electrode, thereby providing a fine polishing action on the contact terminal material surface side. More specifically, the oxide film, which is a high-resistance film deposited in contact with the electrode up to the previous time, is removed to form a rough surface.
その後、 上記接触端子の間に二次電池の電極を配置 し、 接 触端子を互いに接触させる こ と によ り 、 接触端子素材面側に 形成された微細な凹凸が、 二次電池電極の表面に付着 した高 抵抗被膜である酸化被膜を摺接カを増加させる こ とな く 破つ て、 接触端子と二次電池の電極と の間に生じる接触不良を長 期間にわた り減らすこ とが可能と なる。  Then, the secondary battery electrode is arranged between the contact terminals, and the contact terminals are brought into contact with each other, whereby fine irregularities formed on the contact terminal material surface side are reduced. By breaking the oxide film, which is a high-resistance film adhered to the battery, without increasing the amount of sliding contact, it is possible to reduce the contact failure between the contact terminal and the electrode of the secondary battery over a long period of time. It will be possible.
これによ り 、 二次電池の電極と の間に発生する接触抵抗の 値を、 長期間にわた り 初期値に近い値に維持し、 もって二次 電池の電極との間の接触不良によ る二次電池に対する過電流 や過放電を防止 して二次電池にダメージを与えた り 、 二次電 池に発熱等の不具合が発生した り するのを防止する と共に、 精度のよい充放電試験を行な う こ とができ る。 As a result, the value of the contact resistance generated between the battery and the electrode of the secondary battery is maintained at a value close to the initial value for a long period of time. Prevents overcurrent and overdischarge of the secondary battery due to poor contact with the battery electrode, causing damage to the secondary battery and causing problems such as heat generation in the secondary battery. In addition, it is possible to perform an accurate charge / discharge test.
また、 この発明の第 2 の観点によれば、 接触端子は、 電極 を中心に接触して挟むよ う に互いに対向 して配置される一対 の接触端子であって、 対向する一対の接触端子にそれぞれの 先端部から軸方向の切込みを入れて複数の分割片に分割 し、 複数分割 した接触端子分割片における一方の接触面に硬質粒 子を付着させ、 も う一方の接触面は硬質粒子を付着させずに 素材のまま と している。  Further, according to a second aspect of the present invention, the contact terminals are a pair of contact terminals arranged so as to be in contact with each other so as to be in contact with and sandwich the electrode at the center. A cut is made in the axial direction from each tip to divide it into a plurality of divided pieces, and hard particles are attached to one of the contact surfaces of the divided contact terminal pieces, and the other contact surface is made of hard particles. The material is left unadhered.
従って、 この発明の接触端子においては、 複数分割した接 触端子分割片における一方の接触面に付着させた硬質粒子に よ り 、 前述のよ う に接触端子素材面側に微細な凹凸を形成さ せ、 さ らに切込みを入れたこ と で、 同一接触端子の硬質粒子 付着部分と素材のままの部分と の硬質粒子の厚み差を個々 に 吸収する こ とが可能と なる。  Therefore, in the contact terminal of the present invention, as described above, fine irregularities are formed on the contact terminal material surface side by the hard particles attached to one contact surface of the plurality of divided contact terminal divided pieces. In addition, by making the cuts, it is possible to individually absorb the difference in the thickness of the hard particles between the hard particle-attached portion of the same contact terminal and the portion of the raw material as it is.
これによ り 、 一つの電極に同一スペースで複数接点の接触 を必要とする場合に、 硬質粒子の付着によ る接触面の浮き上 が り を防止する こ とができ、 二次電池の電極との間に発生す る接触抵抗の不具合を防止する こ とができ る。  This makes it possible to prevent the contact surface from rising due to the attachment of hard particles when it is necessary to contact a plurality of contacts in the same space with one electrode. The problem of contact resistance occurring between the contact point and the contact point can be prevented.
なお、 こ こで、 特に上記硬質粒子と しては、 例えば、 ダィ ャモン ド、 C B N等一般工具用砥粒を用いる こ と が好ま しい c 本発明の接触端子によれば、 電極との間に発生する接触抵 杭の値を接触端子の摺接カを増加させる こ となく 、 長期間に わた り 初期値に近い値に維持し、 もって二次電池の電極と の 間の接触不良による二次電池に対する過電流や過放電を防止 して二次電池にダメ ージを与えた り 、 二次電池に発熱等の不 具合が発生した り するのを防止する と共に、 精度のよい充放 電試験を行な う こ とが可能となる。 In here, particularly as the above hard particles, for example, da I Yamon de, according to the contact terminals of the this using abrasive for CBN or the like generally tools preferred correct c present invention, between the electrode The value of the contact post that occurs during a long period of time without increasing the sliding contact force of the contact terminal Maintains a value close to the initial value, thereby preventing overcurrent and overdischarge of the secondary battery due to poor contact with the electrode of the secondary battery, and damaging the secondary battery. In addition to preventing generation of defects such as heat generation in the secondary battery, it also enables accurate charge / discharge tests to be performed.
また、 本発明の接触端子によれば、 一つの電極に同一スぺ ースで複数接点の接触を必要とする場合に、 硬質粒子の付着 によ る接触面の浮き上が り を防止 し、 接触抵抗の不具合を防 止する こ とが可能となる。  Further, according to the contact terminal of the present invention, when one electrode needs to contact a plurality of contacts with the same space, it is possible to prevent the contact surface from rising due to the attachment of hard particles, Failure of contact resistance can be prevented.
図面の簡単な説明 BRIEF DESCRIPTION OF THE FIGURES
図 1 A及び 1 Bは、 従来の電池試験用接触端子の構成例を 示す概要図である。  1A and 1B are schematic diagrams illustrating a configuration example of a conventional contact terminal for battery test.
図 2 A及ぴ 2 Bは本発明によ る接触端子の第 1 の実施の形 態を示す概要図である。  2A and 2B are schematic views showing a first embodiment of the contact terminal according to the present invention.
図 3 A乃至 3 Cは本発明によ る接触端子の第 2 の実施の形 態を示す概要図である。  3A to 3C are schematic diagrams showing a contact terminal according to a second embodiment of the present invention.
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明の実施の形態について図面を参照 して詳細 に説明する。  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
(第 1 の実施の形態)  (First Embodiment)
図 2 A及び 2 Bは、 第 1 の実施の形態による接触端子の構 成例を示す概要図であ り 、 図 1 A及び 1 B と 同一部分には同 一符号を付してその説明を省略し、 こ こでは異なる部分につ いてのみ述べる。  2A and 2B are schematic diagrams showing a configuration example of the contact terminal according to the first embodiment. The same parts as those in FIGS. 1A and 1B are denoted by the same reference numerals and the description thereof will be omitted. Omitted, and only the differences are described here.
すなわち、 第 1 の実施の形態による接触端子は、 図 2 Aに 示すよ う に、 前記図 1 Aの対向する一対の接触端子 3, 4 に おける、 一方の接触面 (本例では、 接触端子 3 の接触面) に . 硬質粒子 6 を付着させ、 またも う 一方の接触面 (本例では、 接触端子 4 の接触面) は、 硬質粒子 6 を付着させずに素材 (銅も し く は銅合金系の素材) のまま と した構成と している , こ こで、 硬質粒子 6 と しては、 例えばダイヤモン ド、 C B N、 の う ちのいずれかの粒子を用いる こ とが好ま しいが、 こ れら以外にも、 例えば、 ほ う化チタ ン、 炭化ホウ素、 炭化チ タ ン、 炭化けい素、 窒化けい素、 炭化ジルコニウム、 窒化チ タ ン、 溶融アルミ ナ、 燒結アルミ ナ、 ムライ ト、 ざく ろ石、 フ リ ン ト等の粒子を用いる こ と もでき る。 That is, the contact terminal according to the first embodiment is shown in FIG. 2A. As shown in FIG. 1A, the hard particles 6 are adhered to one contact surface (the contact surface of the contact terminal 3 in this example) of the pair of contact terminals 3 and 4 facing each other in FIG. 1A. On the other hand, the contact surface (the contact surface of the contact terminal 4 in this example) is made of a material (copper or copper alloy material) without the hard particles 6 attached thereto. Here, as the hard particles 6, it is preferable to use, for example, any one of diamond, CBN, and the like, but in addition, for example, titanium borohydride, boron carbide Particles of titanium carbide, silicon carbide, silicon nitride, zirconium carbide, titanium nitride, molten aluminum, sintered aluminum, mullite, garnet, and print can also be used. You.
また、 硬質粒子 6 を付着させる結合方法と しては、 例えば 電着ポン ド、 メ タルポン ド、 レジノ イ ドボン ド等によ る方法 を利用する こ と ができ る。  Further, as a bonding method for attaching the hard particles 6, for example, a method using an electrodeposition bond, a metal bond, a resin bond, or the like can be used.
次に、 以上のよ う に構成 した第 1 の実施の形態による接触 端子の作用について説明する。  Next, the operation of the contact terminal according to the first embodiment configured as described above will be described.
図 2 A及び 2 Bにおいて、 二次電池 2 の充放電試験を行な う 時には、 接触面に硬質粒子 6 を付着させている接触端子 3 と、 接触面に硬質粒子 6 を付着させていない接触端子 4 とが それぞれ支持されている固定板 5 を動作させる こ と によ り 、 二次電池 2 の電極 1 を摺接 ('開閉動作) する。  2A and 2B, when performing a charge / discharge test of the secondary battery 2, the contact terminal 3 having the hard particles 6 adhered to the contact surface and the contact not having the hard particles 6 adhered to the contact surface The electrode 1 of the secondary battery 2 is brought into sliding contact (opening / closing operation) by operating the fixed plate 5 on which the terminal 4 is supported.
そ して、 これら対向する一対の接触端子 3, 4 を取り 付け た充放電試験装置によ り 、 二次電池 2 を充電しなが ら二次電 池 2 の電極 1 間電圧を検出 して、 二次電池 2 に対して所定の 充電電圧が印加される よ う に、 フ ィ ー ドバック制御して充放 電試験を行な う。 The voltage between the electrodes 1 of the secondary battery 2 was detected while charging the secondary battery 2 by means of a charge / discharge test device to which the pair of contact terminals 3 and 4 facing each other was attached. The feedback control is performed so that a predetermined charging voltage is applied to the secondary battery 2 to charge and discharge. Conduct an electrical test.
一方、 二次電池 2 の充放電試験を行な う 以外の時には、 上 記対向する一対の接触端子 3, 4 の隙問に二次電池 2 の電極 1 を挟まない状態で、 硬質粒子 6 付着面と素材面と を直接摺 接する こ と によ り 、 接触端子素材面側の二次電池 2 の充放電 試験に伴な う前回までの電極 1 と の接触で付着した高抵抗被 膜である酸化被膜 7 を除去 し素材表面に微細な凹凸部分を形 成する こ と ができ る。  On the other hand, when the charge / discharge test of the secondary battery 2 was not performed, the hard particles 6 were adhered without interposing the electrode 1 of the secondary battery 2 in the gap between the pair of contact terminals 3 and 4 facing each other. This is a high-resistance film adhered by the previous contact with the electrode 1 during the charge / discharge test of the secondary battery 2 on the contact terminal material side by directly sliding the surface and the material surface. By removing the oxide film 7, fine irregularities can be formed on the material surface.
その後、 対向する一対の接触端子 3, 4 の間に二次電池 2 の電極 1 を配置 し、 片側支持された接触端子 3, 4 を互いに 接触させる こ と によ り 、 接触端子素材面側に形成された微細 な凹凸が、 電極 1 の表面に付着 した高抵抗被膜である酸化被 膜 7 を破る こ と によ り 、 接触端子 3, 4 と二次電池 2 の電極 1 と の間に生じる接触抵抗を減らすこ とができ る。  After that, the electrode 1 of the secondary battery 2 is arranged between the pair of contact terminals 3 and 4 facing each other, and the contact terminals 3 and 4 supported on one side are brought into contact with each other, so that the contact terminal material surface side is formed. The formed fine irregularities break the oxide film 7, which is a high-resistance film adhered to the surface of the electrode 1, and thus are generated between the contact terminals 3 and 4 and the electrode 1 of the secondary battery 2. Contact resistance can be reduced.
これによ り 、 第 1 の実施の形態によ る接触端子では、 二次 電池 2 の電極 1 との間に発生する接触抵抗の値を長期間 (開 閉回数 2 万回以上) にわた り 、 初期値に近い値 (本実施形態 では 3 0 m Ω以下) に維持し、 も って二次電池 2 の電極 1 と の間の接触不良による二次電池 2 に対する過電流や過放電を 防止 して二次電池 2 にダメ ージを与えた り 、 二次電池 2 に発 熱等の不具合が発生した り するのを防止する と共に、 精度の よい充放電試験を行な う こ とが可能と なる。  As a result, in the contact terminal according to the first embodiment, the value of the contact resistance generated between the contact terminal and the electrode 1 of the secondary battery 2 is extended over a long period (20,000 or more times of opening and closing). , By maintaining the value close to the initial value (30 mΩ or less in this embodiment), thereby preventing overcurrent and overdischarge of the secondary battery 2 due to poor contact with the electrode 1 of the secondary battery 2. To prevent damage to the rechargeable battery 2 or to cause problems such as heat generation in the rechargeable battery 2, and to perform an accurate charge / discharge test. And
(第 2 の実施の形態)  (Second embodiment)
図 3 A乃至 3 Cは、 第 2 の実施の形態による接触端子の構 成例を示す概要図であ り 、 図 1 A及び 1 B と 同一部分には同 一符号を付してその説明を省略し、 こ こでは異なる部分につ いてのみ述べる。 3A to 3C are schematic diagrams showing a configuration example of a contact terminal according to the second embodiment, and the same parts as those in FIGS. 1A and 1B are the same. The description is omitted by attaching one symbol, and only different portions are described here.
すなわち、 第 2実施の形態によ る接触端子は、 図 3 A乃至 3 Cに示すよ う に、 前記図 1 Aの対向する一対の接触端子 3, 4 を省略 し、 これに代えて切込み入り 接触端子 8 によ り 構成 して 、る。  That is, as shown in FIGS. 3A to 3C, the contact terminal according to the second embodiment omits the pair of opposed contact terminals 3 and 4 in FIG. 1A, and replaces this with a notch. It is composed of contact terminals 8.
こ の切込み入 り 接触端子 8 は、 対向する一対の接触端子に それぞれの先端部から、 1 も しく は複数 (本例では 1 ) の軸 方向 (本例では鉛直方向) の切込みを入れて 2 も しく は 3 以 上の複数の分割片に分割したもの と している。  The contact terminals 8 are formed by making one or more (one in this example) axial (in this example) notch in each of a pair of opposing contact terminals from the respective tips. Or it is divided into three or more divided pieces.
さ らに、 この複数分割した接触端子 8分割片における、 一 方の接触面に硬質粒子 6 を付着させ、 も う一方の接触面は、 硬質粒子 6 を付着させずに素材 (銅も し く は銅合金系の素 材) のまま と した構成と している。  Further, hard particles 6 are adhered to one of the contact surfaces of the divided contact terminals into eight pieces, and the other contact surface is made of a material (such as copper) without adhering the hard particles 6. Is a copper alloy-based material).
こ こで、 硬質粒子 6 と しては、 例えばダイヤモン ド、 C B Here, as the hard particles 6, for example, diamond, CB
Nの う ちのいずれかの粒子を用いる こ とが好ま しいが、 これ ら以外に も、 例えば、 ほ う 化チタ ン、 炭化ホウ素、 炭化チタ ン、 炭化けい素、 窒化けい素、 炭化ジルコ ニ ウム、 窒化チタ ン、 溶融アルミ ナ、 燒結アルミ ナ、 ムライ ト、 ざく ろ石、 フ リ ン ト等の粒子を用いる こ と もでき る。 It is preferable to use any one of N particles, but other than these, for example, titanium boride, boron carbide, titanium carbide, silicon carbide, silicon nitride, zirconium carbide Alternatively, particles such as titanium nitride, molten alumina, sintered alumina, mullite, garnet, and flint can be used.
また、 硬質粒子 6 を付着させる方法と しては、 例えば、 電 着ポン ド、 メ タルボン ド、 レジノ ィ ドボン ド等による方法を 利用する こ とができ る。  As a method for attaching the hard particles 6, for example, a method using an electrodeposition bond, a metal bond, a resin bond, or the like can be used.
次に、 以上のよ う に構成 した本実施の形態によ る接触端子 の作用について説明する。 図 2 A及ぴ 2 Bにおいて、 二次電池 2 の充放電試験を行な う時には、 一対の切込み入 り 接触端子 8 がそれぞれ支持され ている固定板 5 を動作させる こ と によ り 、 二次電池 2 の電極 1 を摺接 (開閉動作) する。 Next, the operation of the contact terminal according to the present embodiment configured as described above will be described. 2A and 2B, when a charge / discharge test of the secondary battery 2 is performed, the fixing plate 5 on which the pair of cut-in contact terminals 8 are supported is operated. The electrode 1 of the secondary battery 2 slides (opens and closes).
そ して、 これら対向する一対の切込み入り接触端子 8 を取 り 付けた充放電試験装置によ り 、 二次電池 2 に対して適切な 充放電を行ない、 二次電池 2 を充電しなが ら二次電池 2 の電 極 1 間電圧を検出 して、 二次電池 2 に対して所定の充電電圧 が印加する よ う に、 フィー ドバッ ク制御 して充放電試験を行 な う。  The rechargeable battery 2 is appropriately charged and discharged by the charge / discharge test device to which the pair of opposing notched contact terminals 8 is attached, and the rechargeable battery 2 is charged. Then, a voltage between the electrodes 1 of the secondary battery 2 is detected, and a charge / discharge test is performed by performing feedback control so that a predetermined charging voltage is applied to the secondary battery 2.
一方、 二次電池 2 の充放電試験を行な う 以外の時には、 上 記対向する一対の切込み入 り 接触端子 8分割片の隙問に二次 電池 2 の電極 1 を挟まない状態で、 対向する接触端子 8 分割 片の硬質粒子 6 付着面と素材面と を直接摺接し合う こ と によ り 、 接触端子素材面側に微細な凹凸を形成させる こ と ができ る。  On the other hand, when the charge / discharge test of the secondary battery 2 is not performed, the pair of notch contact terminals facing each other are opposed to each other with the electrode 1 of the secondary battery 2 not interposed between the eight divided pieces. The contact terminals to be divided into 8 pieces of the hard particles 6 of the divided piece are directly slid in contact with the material surface, so that fine irregularities can be formed on the contact terminal material surface side.
その後、 対向する一対の接触端子 8分割片の間に二次電池 2 の電極 1 を配置し、 片側支持された接触端子 8分割片を互 いに接触させる こ と によ り 、 接触端子素材面側に形成された 微細な凹凸が、 電極 1 の表面に付着 した高抵抗被膜である酸 化被膜 7 を破って、 接触端子 8 分割片と二次電池 2 の電極 1 との間に生じる接触抵抗を減らすこ とができる。  Thereafter, the electrode 1 of the secondary battery 2 is arranged between the pair of opposing contact terminal 8-split pieces, and the contact terminal 8-split pieces supported on one side are brought into contact with each other, so that the contact terminal material surface is reduced. The minute unevenness formed on the side breaks the oxide film 7 which is a high resistance film attached to the surface of the electrode 1, and the contact resistance generated between the contact terminal 8 divided piece and the electrode 1 of the secondary battery 2 Can be reduced.
さ らに、 切込みを入れた切込み入り 接触端子 8 と している こ と によ り 、 同一接触端子の硬質粒子付着部分と素材のまま の部分と の硬質粒子の厚み差を個々 に吸収する こ とができ る これによ り 、 一つの電極に同一スペース で複数接点の接触 を必要とする場合に、 硬質粒子 6 の付着による接触面の浮き 上が り を防止する こ とができ、 接触抵抗の不具合を防止する こ とができ る。 In addition, the notched contact terminal 8 having a notch allows individual absorption of the difference in the thickness of the hard particles between the hard particle adhered portion of the same contact terminal and the portion of the raw material as it is. Can be This prevents the contact surface from rising due to the adhesion of the hard particles 6 when one electrode needs to contact multiple contacts in the same space, thereby preventing a problem of contact resistance. can do.
上述 したよ う に、 第 2 の実施の形態によ る接触端子では、 二次電池 2 の電極 1 との間に発生する接触抵抗の値を、 常に 初期値に近い値に維持し、 もって二次電池 2 の電極 1 と の間 の接触不良によ る二次電池 2 に対する過電流や過放電を防止 して二次電池 2 にダメージを与えた り 、 二次電池 2 に発熱等 の不具合が発生した りするのを防止する と共に、 精度のよい 充放電試験を行な う こ とが可能となる。  As described above, in the contact terminal according to the second embodiment, the value of the contact resistance generated between the contact terminal and the electrode 1 of the secondary battery 2 is always maintained close to the initial value. This prevents overcurrent and overdischarge of the secondary battery 2 due to poor contact with the electrode 1 of the secondary battery 2 and damages the secondary battery 2 or causes the secondary battery 2 to malfunction due to heat generation or the like. This can prevent the occurrence of such a phenomenon, and also enables a high-precision charge / discharge test to be performed.
さ らに、 一つの電極に同一スペース で複数接点の接触を必 要とする場合に、 硬質粒子 6 の付着によ る接触面の浮き上が り を防止する こ とができ、 二次電池 2 の電極 1 との間に発生 する接触抵抗の不具合を防止する こ とが可能'となる。  Furthermore, when it is necessary to contact a plurality of contacts with one electrode in the same space, it is possible to prevent the contact surface from floating due to the attachment of the hard particles 6 and to make the secondary battery 2 It is possible to prevent the problem of the contact resistance occurring between the first electrode and the first electrode.
(その他の実施の形態)  (Other embodiments)
尚、 本発明は、 上記各実施の形態に限定される も のではな く 、 実施段階ではその要旨を逸脱 しない範囲で、 種々 に変形 して実施する こ とが可能である。  It should be noted that the present invention is not limited to the above-described embodiments, and can be implemented in various forms without departing from the gist of the invention in the implementation stage.
また、 各実施の形態は可能な限 り 適宜組合わせて実施 して も よ く 、 その場合には組合わせた作用効果を得る こ と ができ る。  In addition, each embodiment may be implemented in combination as appropriate as possible, and in that case, the combined operation and effect can be obtained.
さ らに、 上記各実施の形態には種々 の段階の発明が含まれ てお り 、開示される複数の構成要件における適宜な組合わせ によ り 、種々 の発明を抽出する こ と ができ る。 例えば、 実施の形態に示される全構成要件から幾つかの構 成要件が削除されても、発明が解決 しよ う とする課題の欄で 述べた課題 (の少な く と も一つ) が解決でき、発明の効果の 欄で述べられている効果 (の少な く と も一つ) が得られる場 合には、この構成要件が削除された構成を発明 と して抽出す る こ と ができ る。 Furthermore, the above embodiments include inventions at various stages, and various inventions can be extracted by appropriately combining a plurality of disclosed constituent elements. . For example, even if some constituent elements are deleted from all the constituent elements described in the embodiments, the problems (at least one) described in the section of the problem to be solved by the invention can be solved. If the effect (at least one of the effects) described in the section of the effect of the invention can be obtained, it is possible to extract, as an invention, a configuration from which this constituent requirement has been deleted. You.

Claims

請 求 の 範 囲 The scope of the claims
1 . 電極を中心に接触 して挟むよ う に互いに対向 して配置さ れる一対の接触端子であって、  1. A pair of contact terminals arranged opposite to each other so as to be in contact with and sandwich the electrode,
前記対向する一対の接触端子における一方の接触面に硬質 粒子を付着させ、 も う一方の接触面は前記硬質粒子を付着さ せずに素材のまま と したこ と を特徴とする接触端子。  A contact terminal, wherein hard particles are attached to one contact surface of the pair of opposed contact terminals, and the other contact surface is made of a material without attaching the hard particles.
2 . 電極を中心に接触して挟むよ う に互いに対向 して配置さ れる一対の接触端子であって、  2. A pair of contact terminals arranged opposite to each other so as to contact and sandwich the electrode at the center,
前記対向する一対の接触端子にそれぞれの先端部から軸方 向の切込みを入れて複数の分割片に分割し、 前記複数分割し た接触端子分割片における一方の接触面に硬質粒子を付着さ せ、 も う 一方の接触面は前記硬質粒子を付着させずに素材の まま と したこ と を特徴とする接触端子。  A cut is made in the axial direction from the tip of each of the pair of opposed contact terminals to divide the contact terminals into a plurality of divided pieces, and hard particles are attached to one contact surface of the plurality of divided contact terminal pieces. A contact terminal characterized in that the other contact surface is made of a material without adhering the hard particles.
3 . ク レーム 1 または 2の接触端子において、  3. At the contact terminal of claim 1 or 2,
前記硬質粒子 と しては、 ダイ ヤモ ン ド、 C B N ( Cubi c B oro n Nitride ) 、 ほ うィ匕チタ ン、 炭化ホウ素、 炭化チタ ン、 炭化けい素、 窒化けい素、 炭化ジルコ ニ ウ ム、 窒化チタ ン、 溶融アル ミ ナ、 焼結アルミ ナ、 ム ライ ト、 ざく ろ石、 フ リ ン ト を含む一般工具用砥粒を粒子と して用いたこ と を特徴とす る接触端子。  Examples of the hard particles include diamond, CBN (Cubic Boron Nitride), carbon nitride, boron carbide, titanium carbide, silicon carbide, silicon nitride, and zirconium carbide. A contact terminal characterized by using abrasive grains for general tools, including titanium nitride, molten aluminum, sintered alumina, mullite, garnet, and print, as particles.
4 . ク レー ム 1 または 2 の接触端子において、  4. At the contact terminal of claim 1 or 2,
前記一方の接触面への前記硬質粒子の付着は、 電着ボン ド、 メ タルボン ド、 レジノィ ドポン ドを含む結合方法によ り おこ なわれる こ と を特徴とする接触端子。  The contact terminal, wherein the attachment of the hard particles to the one contact surface is performed by a bonding method including an electrodeposition bond, a metal bond, and a resin bond.
PCT/JP2001/003319 2001-01-04 2001-04-18 Contact terminal WO2002056424A1 (en)

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CN107574333B (en) * 2017-08-10 2019-05-21 浙江大学 A kind of preparation method of Ag-YAG contact material
CN108879228A (en) * 2018-06-28 2018-11-23 杭州登元科技有限公司 The conducting device of adaptive face contact
TWI709459B (en) * 2019-11-06 2020-11-11 大陸商福暘技術開發有限公司 Method for roughening the surface of glass substrate

Citations (5)

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JPS5088582A (en) * 1973-12-10 1975-07-16
JPS58117661A (en) * 1981-12-29 1983-07-13 松下電器産業株式会社 Electrically connecting device
JPH01286276A (en) * 1988-05-11 1989-11-17 Nec Corp Connector contact
JPH0582201A (en) * 1991-06-24 1993-04-02 Mitsubishi Electric Corp Electronic parts
JP2000169997A (en) * 1998-09-28 2000-06-20 Nippon Mining & Metals Co Ltd Metallic material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5088582A (en) * 1973-12-10 1975-07-16
JPS58117661A (en) * 1981-12-29 1983-07-13 松下電器産業株式会社 Electrically connecting device
JPH01286276A (en) * 1988-05-11 1989-11-17 Nec Corp Connector contact
JPH0582201A (en) * 1991-06-24 1993-04-02 Mitsubishi Electric Corp Electronic parts
JP2000169997A (en) * 1998-09-28 2000-06-20 Nippon Mining & Metals Co Ltd Metallic material

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