WO2002037143A3 - Liquid curable resin composition with silicone compound - Google Patents

Liquid curable resin composition with silicone compound Download PDF

Info

Publication number
WO2002037143A3
WO2002037143A3 PCT/NL2001/000793 NL0100793W WO0237143A3 WO 2002037143 A3 WO2002037143 A3 WO 2002037143A3 NL 0100793 W NL0100793 W NL 0100793W WO 0237143 A3 WO0237143 A3 WO 0237143A3
Authority
WO
WIPO (PCT)
Prior art keywords
compound
hydroxyl group
silicone
silicone compound
resin composition
Prior art date
Application number
PCT/NL2001/000793
Other languages
French (fr)
Other versions
WO2002037143A2 (en
Inventor
Hiroki Ohara
Hirofumi Uchida
Zen Komiya
Takashi Ukachi
Original Assignee
Dsm Nv
Jsr Corp
Hiroki Ohara
Hirofumi Uchida
Zen Komiya
Takashi Ukachi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Nv, Jsr Corp, Hiroki Ohara, Hirofumi Uchida, Zen Komiya, Takashi Ukachi filed Critical Dsm Nv
Priority to AU2002224200A priority Critical patent/AU2002224200A1/en
Publication of WO2002037143A2 publication Critical patent/WO2002037143A2/en
Publication of WO2002037143A3 publication Critical patent/WO2002037143A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/104—Coating to obtain optical fibres
    • C03C25/106—Single coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C08G18/2835—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds having less than 5 ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24—Coupling light guides
    • G02B6/36—Mechanical coupling means
    • G02B6/38—Mechanical coupling means having fibre to fibre mating means
    • G02B6/3801—Permanent connections, i.e. wherein fibres are kept aligned by mechanical means

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

A structure comprising at least one coated optical fiber, wherein the outermost coating layer is a cured coating having (1) a surface slip of less than 15 N/cm2,(2) an ink adhesion according to JIS K5400 of 90 or more, wherein the coating composition comprises at least one radiation curable oligomer at least one reactive diluent and at least one silicone oligomer. Suitable silicone oligomers are a silicone compound (A1) containing no ehtylenically unsaturated double bond obtained by the reaction of (a) a hydroxyl group-containing polydimethylsiloxane compound, (b) a polyisocyanate compound, and (c) a hydroxyl group-containing compound other than the compound (a) having a molecular weigth of 80-100,000 and a silicone compound (A2) containing an ethylenically unsaturated double bond obtained by the reaction of (a) a hydroxyl group-containing polydimethylsiloxane compound, (b) a polyisocyanate compound, and (d) a hydroxyl group-containing compound other than the compound (a), having a (meth)acroyloyl group and a molecular weight of 500-100,000.
PCT/NL2001/000793 2000-11-02 2001-10-29 Liquid curable resin composition with silicone compound WO2002037143A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002224200A AU2002224200A1 (en) 2000-11-02 2001-10-29 Liquid curable resin composition with silicone compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2000335976A JP4547082B2 (en) 2000-11-02 2000-11-02 Silicone compound, liquid curable resin composition and cured product thereof
JP2000/335976 2000-11-02

Publications (2)

Publication Number Publication Date
WO2002037143A2 WO2002037143A2 (en) 2002-05-10
WO2002037143A3 true WO2002037143A3 (en) 2003-04-24

Family

ID=18811629

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL2001/000793 WO2002037143A2 (en) 2000-11-02 2001-10-29 Liquid curable resin composition with silicone compound

Country Status (3)

Country Link
JP (1) JP4547082B2 (en)
AU (1) AU2002224200A1 (en)
WO (1) WO2002037143A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004210850A (en) * 2002-12-27 2004-07-29 Kyoeisha Chem Co Ltd Curable resin composition for coating and its curing method
KR100691858B1 (en) 2005-10-07 2007-03-12 주식회사 디에프씨 Resin composition for cellular phone
ATE485326T1 (en) * 2006-03-23 2010-11-15 Dow Corning NON-LINEAR POLYSILOXANE WITH COATINGS WITH IMPROVED ADHESION PROPERTIES
DE602007013605D1 (en) * 2006-12-14 2011-05-12 Dsm Ip Assets Bv RADIATION-HARDENABLE D 1368 CR BASE COATING FOR OPTICAL FIBERS
JP5980626B2 (en) * 2011-08-31 2016-08-31 三洋化成工業株式会社 Active energy ray-curable resin composition
KR101995725B1 (en) * 2016-03-11 2019-07-03 주식회사 엘지화학 Curable Composition
KR102118395B1 (en) * 2016-11-11 2020-06-03 주식회사 엘지화학 Curable composition
WO2023099995A1 (en) * 2021-12-03 2023-06-08 3M Innovative Properties Company Free-radically polymerizable compounds, compositions including the same, polymerized compounds, methods of making and articles including the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4647643A (en) * 1985-11-08 1987-03-03 Becton, Dickinson And Company Soft non-blocking polyurethanes
EP0860485A1 (en) * 1997-02-20 1998-08-26 Dsm N.V. Liquid curable resin composition
WO1998046693A1 (en) * 1997-04-14 1998-10-22 Dsm N.V. Liquid curable resin composition
WO1999018043A1 (en) * 1997-10-07 1999-04-15 Dsm N.V. Optical fiber coatings

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63107846A (en) * 1986-10-24 1988-05-12 Nitto Electric Ind Co Ltd Coating material for optical glass fiber
JP2934782B2 (en) * 1990-06-28 1999-08-16 ジェイエスアール株式会社 UV curable colorant composition for optical fiber
JPH04209679A (en) * 1990-11-30 1992-07-31 Nippon Polyurethane Ind Co Ltd Coating resin curable by electron beam
JP3607748B2 (en) * 1995-01-24 2005-01-05 Ｊｓｒ株式会社 Multilayer coating
US5646227A (en) * 1996-02-01 1997-07-08 Bayer Corporation Low surface energy polyisocyanates and their use in one- or two-component coating compositions
JP3715021B2 (en) * 1996-04-09 2005-11-09 Ｊｓｒ株式会社 Liquid curable resin composition
AR012538A1 (en) * 1996-11-01 2000-11-08 Dow Global Technologies Inc A COMPOSITION OF POLYFUNCTIONAL LIQUID URETHANE, PROCESS TO PREPARE IT, METHOD TO COAT SURFACES WITH SUCH COMPOSITION, A METHOD TO PREPARE A LATEX STABILIZER, CURED RESINS IN THE PRESENCE OF SUCH COMPOSITION
JP2000086302A (en) * 1998-09-09 2000-03-28 Takeda Chem Ind Ltd Resin composition for coating optical fiber
JP2000273127A (en) * 1999-03-23 2000-10-03 Jsr Corp Curable liquid resin composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4647643A (en) * 1985-11-08 1987-03-03 Becton, Dickinson And Company Soft non-blocking polyurethanes
EP0860485A1 (en) * 1997-02-20 1998-08-26 Dsm N.V. Liquid curable resin composition
WO1998046693A1 (en) * 1997-04-14 1998-10-22 Dsm N.V. Liquid curable resin composition
WO1999018043A1 (en) * 1997-10-07 1999-04-15 Dsm N.V. Optical fiber coatings

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BENRASHID R ET AL: "SYNTHESIS OF NEW SILOXANE URETHANE BLOCK COPOLYMERS AND THEIR PROPERTIES", JOURNAL OF POLYMER SCIENCE, POLYMER CHEMISTRY EDITION, JOHN WILEY AND SONS. NEW YORK, US, vol. 32, no. 10, 30 July 1994 (1994-07-30), pages 1847 - 1865, XP000452317, ISSN: 0887-624X *
KOZAKIEWICZ J ET AL: "INVESTIGATIONS OF MORPHOPOGY OF MOISTURE-CURED SILICONE-URETHANES", POLYMERS FOR ADVANCED TECHNOLOGIES, JOHN WILEY AND SONS, CHICHESTER, GB, vol. 11, no. 2, February 2000 (2000-02-01), pages 82 - 91, XP000898487, ISSN: 1042-7147 *

Also Published As

Publication number Publication date
AU2002224200A1 (en) 2002-05-15
WO2002037143A2 (en) 2002-05-10
JP4547082B2 (en) 2010-09-22
JP2002138127A (en) 2002-05-14

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