WO2002034821A1 - Compositions pour la production de mousses de poly(meth)acrylimide contenant du graphite expanse - Google Patents
Compositions pour la production de mousses de poly(meth)acrylimide contenant du graphite expanse Download PDFInfo
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- WO2002034821A1 WO2002034821A1 PCT/EP2001/011377 EP0111377W WO0234821A1 WO 2002034821 A1 WO2002034821 A1 WO 2002034821A1 EP 0111377 W EP0111377 W EP 0111377W WO 0234821 A1 WO0234821 A1 WO 0234821A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/24—Homopolymers or copolymers of amides or imides
Definitions
- the present invention relates to compositions for the production of poly (eth) acrylimide show materials • with reduced flammability, poly (meth) acrylimide molding compositions, poly (meth) acrylimide foams and processes for their production.
- Poly (meth) acrylimide foams have been known for a long time and are widely used because of their excellent mechanical properties and their low weight, in particular in the production of layered materials, laminates, composites or foam composites.
- ⁇ prepregs with core materials made of poly (meth) acryli id are often linked.
- Phosphorus compounds are another class of flame retardants with which poly (meth) acrylimide foams are finished.
- the disadvantage here is in particular that a very high fire
- known flame-retardant poly (meth) acrylimide foams do not all exist for certain applications Fire safety standards.
- known foams which are obtained according to DE-OS 33 46 060, EP-A-0 146 892 or US 4 576 971, are self-extinguishing, but do not or only insufficiently meet the vertical flame test according to 60s
- FAR 25.853 (1) (i) or the flue gas density test according to FAR 25.853 (c), AITM 2.0007 and show high heat development according to FAR 25.853 (c).
- a strong dependency on the density of the test specimen is particularly noteworthy. Foams with a high density may pass the vertical flame test 60s, but show very high heat development. The materials mentioned above do not pass the fire test for rail vehicles in accordance with DIN 54837.
- Another problem was to create poly (meth) acrylimide foams that meet the standards of the fire test for rail vehicles according to DIN 54837.
- Another object of the invention was to provide poly (meth) acrylimide foams with low flammability, the reduced amounts of Have phosphorus compounds or halogenated hydrocarbons.
- the invention was also based on the object of specifying the most cost-effective flame retardant for poly (meth) acrylimides and / or poly (meth) acrylimide foams.
- the flame retardant used to finish the poly (meth) acrylimides or the poly (meth) acrylimide foams should be as safe as possible from a health point of view.
- a particularly advantageous embodiment of a method for producing a poly (meth) acrylimide foam according to the invention is described in Process claim 10 provided.
- a layer material is described in claim 14.
- compositions for the production of poly (meth) acrylimide foams or poly (meth) acrylimide molding compositions have expandable graphite, it is possible to provide poly (meth) acrylimide foams and poly (meth) acrylimide molding compositions with reduced flammability, which show a low smoke development and a low heat development.
- compositions according to the invention can be produced inexpensively, since relatively expensive flame retardants are replaced by inexpensive expanded graphite.
- Poly (meth) acrylimide foams do not produce any or only very small amounts of toxic halogenated hydrocarbons when burned.
- Poly (meth) acrylimide foams pass the fire test for rail vehicles according to DIN 54837.
- Expandable graphite used according to the invention to reduce the flammability of poly (meth) acrylimides and / or poly (meth) acrylimide foams is known per se. Expandable graphite expands when heated. " It is believed that this
- Expandable graphite can be obtained, for example, by reacting graphite with sulfuric acid.
- expandable graphite Manufacture of expandable graphite is described, inter alia, in US-A-3,574,644.
- density of expandable graphite is in the range from 1.5 to 2.1 g / cm 3
- average particle size is from 70 to 2000 ⁇ m, in particular from 100 to 100 ⁇ m, without any intention that this should impose a restriction.
- Expandable graphite in the composition according to the invention is preferably in the range from 1 to 50% by weight. -%, particularly preferably 5 to 30 wt. -%, based on the total weight of the monomers, used, without this being intended to be a limitation.
- the upper limit results on the one hand from economic Considerations, on the other hand, the mechanical properties can be adversely affected. Amounts less than 1 wt. -% in many cases only lead to a slight reduction in flammability if no further flame retardants are added.
- the composition according to the invention can contain further flame retardants in order to additionally reduce the flammability.
- flame retardants are widely known in the art.
- phosphorus-containing compounds can also be used. Compounds containing phosphorus are preferred due to the better recyclability of the plastics.
- the phosphorus compounds include, among others, phosphines, phosphine oxides, phosphonium compounds, phosphonates, phosphites and / or phosphates. These compounds can be organic and / or inorganic in nature, derivatives of these compounds, such as phosphoric acid monoesters,
- Phosphonic acid monoesters phosphoric acid diesters, phosphonic acid diesters and phosphoric acid triesters as well as polyphosphates are included.
- Phosphorus compounds of the formula (I) are preferred.
- R are identical or different radicals from the group methyl, ethyl and chloromethyl and X is a hydrogen or halogen atom, a hydroxyl group or a group R ⁇ -CO-, wherein R 1 is methyl, ethyl or chloromethyl.
- phosphorus compounds according to formula (I) include dimethyl methane phosphonate (DMMP), diethyl ethane phosphonate, dimethyl chloro ethane phosphonate, diethyl chloromethane phosphonate, dimethyl hydroxymethane phosphonate, diethyl hydroxymethane phosphonate,
- the phosphorus compounds can be used individually or as a mixture. Mixtures which contain phosphorus compounds of the formula (I) are particularly preferred.
- These compounds can be used in a proportion of up to 25% by weight, based on the weight of the monomers, in order to meet the fire protection standards.
- the proportion of phosphorus compounds is in the range from 1 to 15% by weight, without any intention that this should impose a restriction. If increasing amounts of these compounds are used, the other thermal and mechanical properties of the plastics, such as, for example, the compressive strength, the bending strength and the heat resistance, may deteriorate.
- the amounts of phosphorus or halogen-containing flameproofing additives can be significantly minimized with a constant LOI value, so that the plastic has particularly good mechanical and has thermal properties.
- Mixtures of at least one phosphorus compound and expandable graphite are of particular interest exhibit. It has surprisingly been found that such mixtures have a synergistic effect.
- Phosphorus-containing flame retardants and expandable graphite are preferably used in a mass ratio in the range from 1:20 to 20: 1, preferably 1: 5 to 5: 1, based on the weight of the compounds, without any intention that this should impose a restriction.
- the reduced flammability can be determined, for example, by the so-called LOI values (Low Oxygen Index).
- LOI values Low Oxygen Index
- the LOI values can be determined, for example, in accordance with ASTM Standard D 2863: Standard Method of Test for Flammability of Plastics Using the Oxygen Index Method.
- the LOI value corresponds to an oxygen-nitrogen gas mixture in which a plastic sample ignited at the upper end, which is in the form of a molded body, just burns completely.
- Reduction here means an increase in the LOI value by adding expandable graphite, based on the molded article produced from the poly (meth) acrylimide molding composition or the poly (meth) acrylimide foam without this additive.
- the LOI value of untreated poly (meth) acrylimide foams is approximately 20. In general, therefore, one can speak of a reduced flammability with LOI values greater than 22, preferably greater than 24 and very particularly preferably greater than 27, without this is to be a limitation.
- the foams show a low smoke development according to FAR 25.853 (c), AITM 2.0007 and a low heat development according to FAR 25.853 (c).
- the heat development is ⁇ 160 kW / m 2 , preferably ⁇ 140 kW / m 2 and particularly preferably ⁇ 120 kW / m 2 .
- the foams pass the vertical flame test 60s according to FAR 25.853 (a) (1) (i).
- the poly (meth) acrylimide foams meet the standards of the fire test for rail vehicles according to DIN 54837.
- Special embodiments of foams according to the invention achieve an S4 flammability classification according to DIN 54837.
- the destroyed length is accordingly ⁇ 20 cm and the afterburning time ⁇ 10s.
- the smoke development class SR-2 is achieved in the test according to DIN 54837 with special designs. This means that the integral smoke density is ⁇ 50% * min.
- Particularly preferred foams achieve values below 25% * min.
- particularly preferred foams are characterized by a low drop formation during firing. In this way, particularly preferred configurations are classified into the class ST2 according to the test according to DIN 54837.
- compositions according to the invention for the production of poly (meth) acrylimide foams are polymerizable mixtures which contain at least one, usually usually two or more monomers, such as (meth) acrylic acid and (meth) acrylonitrile, blowing agents, at least one polymerization initiator and expandable graphite. These compositions are polymerized into precursors from which poly (meth) acrylimide foams are formed by heating.
- (meth) acrylic means acrylic, methacrylic and mixtures of the two.
- the poly (meth) acrylimide foams obtainable from the compositions according to the invention have recurring units which can be represented by formula (II),
- R 1 and R 2 are the same or different hydrogen or a methyl group and R 3 is hydrogen or an alkyl or aryl radical having up to 20 carbon atoms.
- Units of structure (II) preferably form more than 30% by weight, particularly preferably more than 50% by weight and very particularly preferably more than 80% by weight of the poly (meth) acrylimide foam.
- the units of structural formula (II) can be formed from neighboring units of (meth) acrylic acid and (meth) acrylonitrile by a cyclizing isomerization reaction when heated to 150 to 250 ° C (cf. DE-C 18 17 156, DE -C 27 26 259, EP-B 146 892).
- a precursor is first by polymerizing the monomers in the presence of a radical initiator at low temperatures, e.g. B. 30 to 60 ° C with Post-heating to 60 to 120 ° C generated, which is then foamed by heating to about 180 to 250 ° C by a blowing agent contained (see EP-B 356 714).
- a copolymer can first be formed which contains (meth) acrylic acid and
- these copolymers can contain further monomer units which result, for example, from esters of acrylic or methacrylic acid, in particular with lower alcohols having 1-4 carbon atoms, styrene, maleic acid or their anhydride, itaconic acid or their anhydride, vinylpyrrolidone, vinyl chloride or vinylidene chloride ,
- the proportion of the comonomers which are difficult or difficult to cyclize should not exceed 30% by weight, preferably 20% by weight and particularly preferably 10% by weight, based on the weight of the monomers.
- Allyl acrylate, allyl methacrylate, ethylene glycol diacrylate or dimethacrylate or polyvalent metal salts of acrylic or methacrylic acid, such as magnesium methacrylate, can advantageously be used.
- the proportions of these crosslinkers are frequently in the range from 0.005 to 5% by weight, based on the total amount of polymerizable monomers.
- metal salt additives can be used, which often reduce smoke gas.
- metal salt additives include the acrylates or methacrylates of
- the polymerization initiators used are those which are customary per se for the polymerization of (meth) acrylates, for example azo compounds, such as azodiisobutyronitrile, and peroxides, such as dibenzoyl peroxide or dilauroyl peroxide, or else other peroxide compounds, such as, for example, t-butyl peroctanoate or perketals, as well as optionally redox initiators (see also redox initiators) see, for example, H. Rauch-Puntigam, Th. Völker, Acryl- und MethacrylVerbindenn Institute, Springer, Heidelberg, 1967 or Kirk-Othmer, Encyclopedia of Chemical Technology, Vol. 1, pages 286 ff, John Wiley & Sons, New York, 1978 ).
- the polymerization initiators are preferably used in amounts of 0.01 to 0.3% by weight, based on the total weight of the monomers used.
- polymerization initiators can also be advantageous to combine polymerization initiators with different disintegration properties with regard to time and temperature.
- it is well suited the simultaneous use of tert-butyl perpivalate, tert-butyl perbenzoate and tert-butyl per-2-ethylhexanoate or of tert-butyl perbenzoate, 2, 2-azobisiso-2, 4-dimethylvaleronitrile, 2, 2-azobisisobutyronitrile and di -tert. -butyl peroxide.
- the polymerization is preferably carried out via variants of bulk polymerization, such as the so-called chamber method, without being limited to this.
- the weight average molecular weight M w of the polymers is preferably greater than 10 6 g / mol, in particular greater than 3 ⁇ 10 6 g / mol, without this being intended to impose a restriction.
- blowing agents are used to foam the copolymer during the conversion into an imide group-containing polymer, which form a gas phase at 150 to 250 ° C. by decomposition or evaporation.
- Blowing agents with an amide structure such as urea, monomethyl or N, N '-dimethylurea, formamide or monomethylformamide, release ammonia or - A ine upon decomposition, which leads to the additional formation of
- Imid groups can contribute.
- nitrogen-free blowing agents such as formic acid, water or monohydric aliphatic alcohols having 3 to 8 carbon atoms, such as 1-propanol, 2-propanol, n-butan-1-ol, n-butan-2-ol, isobutan-1, can also be used -ol, isobutan-2-ol, pentanols and / or hexanols can be used.
- the amount of blowing agent used depends on the desired foam density, the blowing agents being used in the reaction mixture usually in amounts of about 0.5 to 15% by weight, based on the total weight of the monomers used.
- the preliminary products can also contain customary additives. These include, among others, antistatic agents, antioxidants, mold release agents, lubricants, dyes, flame retardants,
- Conductive particles that prevent the foams from becoming electrostatically charged are another class of preferred additives. These include metal and soot particles, too can be present as fibers, with a size in the range of 10 nm and 10 mm, as described in EP 0 356 714 AI.
- anti-settling agents are preferred additives because these substances effectively stabilize the compositions for the production of polyacrylimide foams.
- These include carbon blacks, for example KB EC-600 JD from Akzo Nobel, and Aerosile, for example Aerosil 200 from Degussa-Hüls AG.
- a poly (meth) acrylimide foam according to the invention can be produced, for example, by mixing a mixture of
- component (A) 0-20% by weight of further vinylically unsaturated monomers, the constituents of component (A) giving 100% by weight;
- thermoplastically processable molding compositions have
- Poly (meth) acrylimides with high heat resistance which can be obtained, for example, by reacting polymethyl methacrylate or its copolymers with primary amines. Representative of the large number of examples of this polymer-analogous imidation are: US 4,246,374, EP 216 505 A2, EP 860 821. High heat resistance can be achieved either by using arylamines (JP 05222119 A2) or by using special co-monomers reach (EP 561 230 A2, EP 577 002 AI). All of these reactions result in solid polymers which can be foamed to obtain a foam in a separate second step, with suitable techniques known to those skilled in the art for this purpose.
- Poly (meth) acrylimide molding compositions according to the invention contain expandable graphite as an essential constituent. This component is preferably used in the amounts set out above.
- these molding compositions can have the optional additives mentioned above. They can be expanded with expandable graphite before, during or after the polymerization or imidation using known methods.
- these molding compositions can be foamed using known techniques. This can include the blowing agents mentioned above are used, which can be added to the molding compounds by compounding, for example.
- Poly (meth) acrylimide foams according to the invention can be provided with cover layers, for example to increase the strength.
- layer materials are known which offer a certain level of flame protection simply by choosing the covering material.
- the fire protection achieved by using these composite materials can be significantly improved.
- any known flat structure can be used as the cover layer, which is stable in the processing parameters required for producing the composite structure, such as pressure and temperature.
- These include, for example, films and / or sheets made of polypropylene, polyester, polyether, polyamide, polyurethane, polyvinyl chloride, polymethyl (meth) acrylate, by curing reactive resins, such as, for example, • epoxy resins (EP resins), methacrylate resins (MA resins), unsaturated polyester resins (UP resins), isocyanate resins and phenacrylate resins (PHA resins), bismaleimide resins and phenolic resins, plastics and / or metals obtained, such as aluminum, for example.
- mats or webs can preferably be used as the top layer, which comprise glass fibers, carbon fibers and / or aramid fibers, wherein webs which have a multilayer structure can also be used as the top layer.
- fibrous webs can be applied to the foams, among other things, as prepregs.
- fiber mats pre-impregnated with curable plastics mostly glass fiber mats or Glass filament fabric that can be processed into molded parts or semi-finished products by hot pressing.
- curable plastics mostly glass fiber mats or Glass filament fabric that can be processed into molded parts or semi-finished products by hot pressing.
- carbon fiber reinforced plastics are also known which are particularly suitable as cover layers.
- the thickness of the cover layer is preferably in the range from 0.1 to 100 mm, preferably in the range from 0.5 to 10 mm.
- An adhesive can also be used to improve adhesion. Depending on the material of the cover layer, this is not necessary.
- the poly (meth) acrylimide foams according to the invention and in particular the layer materials containing these foams can be used, for example, in aircraft construction and for the construction of ships or rail vehicles.
- 1000g (10.0 wt. Parts) of dimethyl methane phosphonate (DMMP) and 1500 g (15.0 parts by weight) of expanded graphite (Nord Min 250 from Nordmann, Rassman GmbH & Co.) Were added as flame retardants.
- the mixture contained 40 g (0.40 part by weight) of release agent (PAT 1037), 70 g (0.70 part by weight) of ZnO and 140 g (1.4 part by weight) of carbon black (KB 600 EC from Akzo Nobel ).
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then
- Final polymerization is subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming took place for 3 hours at 193 ° C.
- the foam thus obtained had a density of 48 kg / m 3 .
- DMMP dimethyl methanephosphonate
- expanded graphite Ned Min 250 from Nordmann, Rassman GmbH & Co.
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming was carried out for 2 hours at 195 ° C.
- the foam thus obtained had a density of 55 kg / m 3 .
- DMMP dimethyl methanephosphonate
- expanded graphite Ned Min 250 from Nordmann, Rassman GmbH & Co.
- This mixture was polymerized only 21 hours at 38 ° C. and then for another 48 hours at 39 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal.
- the polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours.
- the subsequent foaming was carried out for 2 hours at 195 ° C.
- the foam thus obtained had a density of 50 kg / m 3 .
- Blowing agent 400g (4 parts by weight) of isopropanol and 200g (2 parts by weight) of water are added.
- 5 g (0.05 part by weight) of tert-butyl perbenzoate, 8 g (0.08 part by weight) of 2,2-azobisiso-2, 4-dimethylvaleronitrile, 5 g (0.05 part by weight) were added to the mixture. parts
- This mixture was polymerized for 71 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming was carried out for 2 hours at 190 ° C.
- the foam thus obtained had a density of 52 kg / m 3 .
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming took place for 3 hours at 193 ° C.
- the foam thus obtained had a density of 58 kg / m 3 .
- DMMP dimethyl methane phosphonate
- expanded graphite Ned Min 250 from Nordmann, Rassman GmbH & Co.
- PAT 1037 release agent
- ZnO ZnO
- 120 g 120 g (1.2 part by weight) of carbon black
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming was carried out for 2 hours at 195 ° C.
- the foam thus obtained had a density of 95 kg / m 3 .
- This foam was subjected to the tests set out in Table 1. This table also contains the data obtained.
- DMMP dimethyl methane phosphonate
- expanded graphite expanded graphite
- the mixture contained 40g (0.40 part by weight) of release agent (PAT 1037), 70g (0.70 part by weight) ZnO and 150g (1.5 part by weight) carbon black (KB 600 EC from Akzo Nobel ).
- This mixture was polymerized for 68 hours at 39.5 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming was carried out for 2 hours at 195 ° C.
- the foam thus obtained had a density of 97 kg / m 3 .
- DMMP dimethyl methane phosphonate
- expanded graphite Ned Min 250 from Nordmann, Rassman GmbH & Co.
- PAT 1037 release agent
- ZnO ZnO
- 120 g 120 g (1.2 part by weight) of carbon black
- This mixture was 92h at 39.5 ° C in one of two glass plates size 50 * 50cm and a 2.2cm thick Edge seal formed chamber poly erized.
- the polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming took place at 185 ° C. for 2 hours.
- the foam thus obtained had a density of 146 kg / m 3 .
- This foam was subjected to the tests set out in Table 1. This table also contains the data obtained.
- DMMP dimethyl methanephosphonate
- expanded graphite Ned Min 250 from Nordmann, Rassman GmbH & Co.
- Aerosil (Aerosil 200 from Degussa-Huls AG).
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a final polymerization of 17.25 h from 40 ° C. to 115 ° C. sufficient tempering program. The subsequent foaming took place for 3 hours at 200 ° C.
- the foam thus obtained had a density of 40 kg / m 3 .
- This foam was subjected to the tests set out in Table 1. This table also contains the data obtained.
- a foam with a density of 71 kg / m 3 was produced in accordance with DE 33 46 060, 10 parts by weight of DMMP being used as the flame retardant.
- tert-butyl perbenzoate 10.0 g (0.100 part by weight) of tert-butyl perbenzoate, 4.0 g (0.0400 part by weight) of tert-butyl perpivalate, 3.0 g (0.0300 part by weight) were tert of the mixture .
- Butyl per-2-ethylhexanoate 10.0 g (0.1000 parts by weight) of cumyl perneodecanoate added as initiators.
- 1000 g (10.00 parts by weight) of dimethyl methane phosphonate (DMMP) were added to the mixture as a flame retardant.
- DMMP dimethyl methane phosphonate
- the mixture contained 20 g (0.20 part by weight) of release agent (MoldWiz) and 70 g (0.70 part by weight) of ZnO.
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then
- the foam thus obtained had a density of 71 kg / m 3 .
- methacrylonitrile 140 g 1.4 parts by weight
- formamide 135 g (1.35 parts by weight) water as a blowing agent.
- 10.0 g (0.100 part by weight) of tert-butyl perbenzoate, 4.0 g (0.040 part by weight) of tert-butyl perpivalate, 3.0 g (0.030 part by weight) were tert.
- -Butylper-2-ethylhexanoate and 10g (0.100 parts by weight) cumyl perneodecanoate added as initiators.
- 1000 g (10.00 parts by weight) of dimethyl methane phosphonate (DMMP) were added to the mixture as a flame retardant.
- the mixture contained 15 g (0.15 part by weight) of release agent (PAT) and 70 g (0.70 part by weight) of ZnO.
- PAT release agent
- ZnO ZnO
- This mixture was polymerized for 92 hours at 40 ° C. in a chamber formed from two glass plates of size 50 * 50 cm and a 2.2 cm thick edge seal. The polymer was then subjected to a tempering program ranging from 40 ° C. to 115 ° C. for 17.25 hours. The subsequent foaming took place at 220 ° C. for 2 hours.
- the foam thus obtained had a density of 51 kg / m 3 .
- This foam was subjected to the tests set out in Table 1. This table also contains the data obtained.
- Comparative Example 1 except that the foaming took place at 210 ° C. and the density of the foam obtained was then 110 kg / m 3 .
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Abstract
La présente invention concerne des compositions pour produire des mousses de poly(méth)acrylimide présentant une inflammabilité réduite, contenant du graphite expansé. L'invention concerne également des matières moulables de poly(méth)acrylimide, ainsi que des mousses de poly(méth)acrylimide obtenues à partir de ces matières moulables et des compositions mentionnées ci-dessus. L'invention concerne en outre des procédés pour produire des mousses de poly(méth)acrylimide présentant une inflammabilité réduite.
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AU2002213988A AU2002213988A1 (en) | 2000-10-21 | 2001-10-02 | Compositions for the production of poly(meth)acrylimide foams containing expanded graphite |
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DE2000152239 DE10052239A1 (de) | 2000-10-21 | 2000-10-21 | Zusammensetzungen zur Herstellung von Poly(meth)arylimid-Schaumstoffen mit verminderter Entflammbarkeit, Poly(meth)acrylimid-Formmassen, Poly(meth)acrylimid-Schaumstoffe sowie Verfahren zur Herstellung |
DE10052239.4 | 2000-10-21 |
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WO2011138060A1 (fr) * | 2010-05-06 | 2011-11-10 | Evonik Röhm Gmbh | Mousses polyméthacrylimide présentant une inflammabilité réduite ainsi que procédé pour la fabrication desdites mousses polyméthacrylimide |
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DE10259674A1 (de) * | 2002-12-18 | 2004-07-15 | Röhm GmbH & Co. KG | Derivatisierung hochmolekularer Polymethacrylimide |
DE102008001695A1 (de) * | 2008-05-09 | 2009-11-12 | Evonik Röhm Gmbh | Poly(meth)acrylimide mit verbesserten optischen und Farbeigenschaften, insbesondere bei thermischer Belastung |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE29605891U1 (de) * | 1996-03-29 | 1996-06-20 | Heuser Holger | Führungsschlauch |
JPH09208731A (ja) * | 1996-02-06 | 1997-08-12 | Sekisui Chem Co Ltd | 難燃性ポリオレフィン系樹脂発泡体 |
-
2000
- 2000-10-21 DE DE2000152239 patent/DE10052239A1/de not_active Ceased
-
2001
- 2001-10-02 AU AU2002213988A patent/AU2002213988A1/en not_active Abandoned
- 2001-10-02 WO PCT/EP2001/011377 patent/WO2002034821A1/fr not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09208731A (ja) * | 1996-02-06 | 1997-08-12 | Sekisui Chem Co Ltd | 難燃性ポリオレフィン系樹脂発泡体 |
DE29605891U1 (de) * | 1996-03-29 | 1996-06-20 | Heuser Holger | Führungsschlauch |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 12 25 December 1997 (1997-12-25) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011138060A1 (fr) * | 2010-05-06 | 2011-11-10 | Evonik Röhm Gmbh | Mousses polyméthacrylimide présentant une inflammabilité réduite ainsi que procédé pour la fabrication desdites mousses polyméthacrylimide |
US20130041056A1 (en) * | 2010-05-06 | 2013-02-14 | Evonik Roehm Gmbh | Polymethacrylimide foam materials having reduced flammability and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
DE10052239A1 (de) | 2002-05-02 |
AU2002213988A1 (en) | 2002-05-06 |
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