WO2002022262A3 - Rhenium alkylidene catalysts fixed on a carrier and used for the metathesis of olefins - Google Patents
Rhenium alkylidene catalysts fixed on a carrier and used for the metathesis of olefins Download PDFInfo
- Publication number
- WO2002022262A3 WO2002022262A3 PCT/EP2001/010675 EP0110675W WO0222262A3 WO 2002022262 A3 WO2002022262 A3 WO 2002022262A3 EP 0110675 W EP0110675 W EP 0110675W WO 0222262 A3 WO0222262 A3 WO 0222262A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carrier
- metathesis
- olefins
- catalyst
- alkylidene catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000005649 metathesis reaction Methods 0.000 title abstract 2
- 229910052702 rhenium Inorganic materials 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 150000003282 rhenium compounds Chemical class 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical group [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/74—Aziridination
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002526504A JP2004508191A (en) | 2000-09-15 | 2001-09-14 | Catalysts fixed on supports and their use for metathesis of olefins |
EP01976225A EP1322418A2 (en) | 2000-09-15 | 2001-09-14 | Catalysts fixed on a carrier and used for the metathesis of olefins |
CA002422594A CA2422594A1 (en) | 2000-09-15 | 2001-09-14 | Rhenium alkylidene catalysts fixed on a carrier and used for the metathesis of olefins |
AU2001295565A AU2001295565A1 (en) | 2000-09-15 | 2001-09-14 | Rhenium alkylidene catalysts fixed on a carrier and used for the metathesis of olefins |
US10/363,858 US6878660B2 (en) | 2000-09-15 | 2001-09-14 | Catalyst fixed on a carrier and used for the metathesis of olefins |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10046143A DE10046143A1 (en) | 2000-09-15 | 2000-09-15 | Supported catalysts for olefin metathesis |
DE10046143.3 | 2000-09-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2002022262A2 WO2002022262A2 (en) | 2002-03-21 |
WO2002022262A3 true WO2002022262A3 (en) | 2002-10-24 |
Family
ID=7656654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2001/010675 WO2002022262A2 (en) | 2000-09-15 | 2001-09-14 | Rhenium alkylidene catalysts fixed on a carrier and used for the metathesis of olefins |
Country Status (9)
Country | Link |
---|---|
US (1) | US6878660B2 (en) |
EP (1) | EP1322418A2 (en) |
JP (1) | JP2004508191A (en) |
CN (1) | CN1457272A (en) |
AU (1) | AU2001295565A1 (en) |
CA (1) | CA2422594A1 (en) |
DE (1) | DE10046143A1 (en) |
WO (1) | WO2002022262A2 (en) |
ZA (1) | ZA200302067B (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120289617A1 (en) * | 2011-05-10 | 2012-11-15 | Saudi Arabian Oil Company | Hybrid Catalyst for Olefin Metathesis |
DE102014105885A1 (en) * | 2014-04-25 | 2015-10-29 | Universität Stuttgart | N-heterocyclic carbene complexes of metalimidoalkylidenes and metalloxoalkylidenes and their use |
CN104311378B (en) * | 2014-11-11 | 2016-02-24 | 万华化学集团股份有限公司 | A kind of preparation method preparing neohexene and catalyzer thereof |
WO2016207835A1 (en) | 2015-06-25 | 2016-12-29 | King Abdullah University Of Science And Technology | Process for compound transformation |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2525224A1 (en) * | 1982-04-14 | 1983-10-21 | Rhone Poulenc Chim Base | Carbene type transition metal complex coordinated with Lewis acid - used as catalyst for metathesis of simple or functionalised olefin(s) |
US4818442A (en) * | 1984-10-09 | 1989-04-04 | Phillips Petroleum Company | Disproportionation process |
US5087710A (en) * | 1990-01-04 | 1992-02-11 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5146033A (en) * | 1990-01-04 | 1992-09-08 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5342985A (en) * | 1988-12-10 | 1994-08-30 | Hoechst Ag | Organic derivatives of rhenium oxides and their preparation and use for the metathesis of olefins |
WO1998002244A1 (en) * | 1996-07-12 | 1998-01-22 | Centre National De La Recherche Scientifique (Cnrs) | Method of metathesis of alcanes and catalyst |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI84562C (en) * | 1990-01-16 | 1991-12-27 | Neste Oy | FARING EQUIPMENT FOR THE FRAME STATION OF HETEROGENE CATALYSTATORS. |
US5175311A (en) * | 1990-03-29 | 1992-12-29 | Research Corporation Technologies, Inc. | Method of enantioselective cyclopropanation using chiral catalysts |
US5198511A (en) * | 1991-12-20 | 1993-03-30 | Minnesota Mining And Manufacturing Company | Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor |
JP3521912B2 (en) * | 1993-12-30 | 2004-04-26 | エクソンモービル・ケミカル・パテンツ・インク | Method for synthesizing trans non-conjugated diolefin |
BE1008339A3 (en) * | 1994-05-03 | 1996-04-02 | Dsm Nv | Heterogeneous metathesis catalyst. |
DE19932060A1 (en) * | 1999-07-12 | 2001-01-18 | Basf Ag | Process for the production of C¶5¶ / C¶6¶ olefins |
-
2000
- 2000-09-15 DE DE10046143A patent/DE10046143A1/en not_active Withdrawn
-
2001
- 2001-09-14 AU AU2001295565A patent/AU2001295565A1/en not_active Abandoned
- 2001-09-14 CA CA002422594A patent/CA2422594A1/en not_active Abandoned
- 2001-09-14 US US10/363,858 patent/US6878660B2/en not_active Expired - Fee Related
- 2001-09-14 EP EP01976225A patent/EP1322418A2/en not_active Ceased
- 2001-09-14 CN CN01815641A patent/CN1457272A/en active Pending
- 2001-09-14 WO PCT/EP2001/010675 patent/WO2002022262A2/en active Application Filing
- 2001-09-14 JP JP2002526504A patent/JP2004508191A/en not_active Withdrawn
-
2003
- 2003-03-14 ZA ZA200302067A patent/ZA200302067B/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2525224A1 (en) * | 1982-04-14 | 1983-10-21 | Rhone Poulenc Chim Base | Carbene type transition metal complex coordinated with Lewis acid - used as catalyst for metathesis of simple or functionalised olefin(s) |
US4818442A (en) * | 1984-10-09 | 1989-04-04 | Phillips Petroleum Company | Disproportionation process |
US5342985A (en) * | 1988-12-10 | 1994-08-30 | Hoechst Ag | Organic derivatives of rhenium oxides and their preparation and use for the metathesis of olefins |
US5087710A (en) * | 1990-01-04 | 1992-02-11 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
US5146033A (en) * | 1990-01-04 | 1992-09-08 | Massachusetts Institute Of Technology | Homogeneous rhenium catalysts for metathesis of olefins |
WO1998002244A1 (en) * | 1996-07-12 | 1998-01-22 | Centre National De La Recherche Scientifique (Cnrs) | Method of metathesis of alcanes and catalyst |
Non-Patent Citations (12)
Title |
---|
BUFFON, R.; LECONTE, M.; CHOPLIN, A.; BASSET, J.M.: "Molecular Heterogenous Metathesis Catalysts: an Attempted Synthesis of Surface-anchored Alkylidenetungsten Complexes", JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS, 1994, pages 1723 - 1729, XP001057094 * |
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; TOREKI, ROBERT ET AL: "A well-defined rhenium(VII) olefin metathesis catalyst", XP002191429, retrieved from STN Database accession no. 112:158626 CA * |
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; TOREKI, ROBERT ET AL: "Metathetical reactions of rhenium(VII) alkylidene-alkylidyne complexes of the type Re(CR')(CHR')[OCMe(CF3)2]2 (R' = CMe3 or CMe2Ph) with terminal and internal olefins", XP002191428, retrieved from STN Database accession no. 118:124718 CA * |
HERRMANN W A: "Essays on organometallic chemistry, VII. Laboratory curiosities of yesterday, catalysts of tomorrow: organometallic oxides", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 500, no. 1, 1 September 1995 (1995-09-01), pages 149 - 173, XP004023682, ISSN: 0022-328X * |
HERRMANN, W.A.; WAGNER, W.; FLESSNER, U.N.; VOLKHARDT, U.; KOMBER, H.: "Methyltrioxorhenium as Catalyst for Olefin Metathesis", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION ENGLISH, vol. 30, no. 12, 1991, pages 1636 - 1638, XP002191427 * |
HORTON, A.D.; SCHROCK, R.R.: "Preparation of Bis and Tris(arylimido) Complexes of Rhenium(VII), including Bis(arylimido) Neopentylidene Complexes, Candidates as Olefin Metathesis Catalysts", POLYHEDRON, vol. 7, no. 19/20, 1988, pages 1841 - 1853, XP002203232 * |
J. AM. CHEM. SOC. (1990), 112(6), 2448-9, 1990 * |
J. AM. CHEM. SOC. (1993), 115(1), 127-37, 1993 * |
LAPOINTE, ANNE M. ET AL: "Alkyl, Alkylidene, and Alkylidyne Complexes of Rhenium", ORGANOMETALLICS (1995), 14(4), 1875-84, XP002203230 * |
SCHEKLER-NAHAMA F ET AL: "Influence of Lewis acidity of rhenium heptoxide supported on alumina catalyst on the catalytic performances in olefin metathesis", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 167, no. 2, 27 February 1998 (1998-02-27), pages 237 - 245, XP004271398, ISSN: 0926-860X * |
TOREKI, ROBERT ET AL: "Synthesis and characterization of rhenium(VII) alkylidene alkylidyne complexes of the type Re(CR')(CHR')(OR)2 and related species", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 114, no. 9, 1992, pages 3367 - 3380, XP002203231 * |
WEISS, K.; LÖSSEL, G.: "Heterogenous, Metathesis-active Schrock-type Carbene Complexes by Reaction of Carbyne Tungsten(VI) Complexes with Silica Gel", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION ENGLISH, vol. 28, no. 1, 1989, pages 62 - 64, XP001061665 * |
Also Published As
Publication number | Publication date |
---|---|
CN1457272A (en) | 2003-11-19 |
US20030181776A1 (en) | 2003-09-25 |
DE10046143A1 (en) | 2002-05-29 |
US6878660B2 (en) | 2005-04-12 |
WO2002022262A2 (en) | 2002-03-21 |
ZA200302067B (en) | 2004-04-01 |
CA2422594A1 (en) | 2003-03-14 |
AU2001295565A1 (en) | 2002-03-26 |
EP1322418A2 (en) | 2003-07-02 |
JP2004508191A (en) | 2004-03-18 |
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