WO2002012154A3 - Katalysatorsystem zur polymerisation von olefinen - Google Patents

Katalysatorsystem zur polymerisation von olefinen Download PDF

Info

Publication number
WO2002012154A3
WO2002012154A3 PCT/EP2001/008691 EP0108691W WO0212154A3 WO 2002012154 A3 WO2002012154 A3 WO 2002012154A3 EP 0108691 W EP0108691 W EP 0108691W WO 0212154 A3 WO0212154 A3 WO 0212154A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
polymerisation
olefins
metal
relates
Prior art date
Application number
PCT/EP2001/008691
Other languages
English (en)
French (fr)
Other versions
WO2002012154A2 (de
Inventor
Sigurd Becke
Uwe Denninger
Steffen Kahlert
Werner Obrecht
Claudia Schmid
Heike Windisch
Original Assignee
Bayer Ag
Sigurd Becke
Uwe Denninger
Steffen Kahlert
Werner Obrecht
Claudia Schmid
Heike Windisch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10040860A external-priority patent/DE10040860A1/de
Application filed by Bayer Ag, Sigurd Becke, Uwe Denninger, Steffen Kahlert, Werner Obrecht, Claudia Schmid, Heike Windisch filed Critical Bayer Ag
Priority to AU2001277556A priority Critical patent/AU2001277556A1/en
Publication of WO2002012154A2 publication Critical patent/WO2002012154A2/de
Publication of WO2002012154A3 publication Critical patent/WO2002012154A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2637—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions between a compound containing only oxygen and possibly halogen as hetero-atoms and a halogenated hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2632—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving an organo-magnesium compound, e.g. Grignard synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C07C25/22—Polycyclic aromatic halogenated hydrocarbons with condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Die vorliegende Erfindung betrifft eine metallfreie Cyclopentadienid-Verbindung, die in Verbindung mit einem Metallocen ein Katalysatorsystem bilden kann, welches zur Polymerisation von Olefinen eingesetzt werden kann. Hierbei kann auf den Einsatz von Methylaluminoxan (MAO) oder borhaltigen Verbindungen als Cokatalysator verzichtet werden und dennoch eine hohe Katalysatoraktivität erreicht werden. Weiterhin betrifft die Erfindung ein Verfahren zur Herstellung der metallfreien Cyclopentadienid-Verbindung sowie deren Verwendung als Katalysatorkomponente bei der Herstellung von Polyolefinen.
PCT/EP2001/008691 2000-08-09 2001-07-27 Katalysatorsystem zur polymerisation von olefinen WO2002012154A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001277556A AU2001277556A1 (en) 2000-08-09 2001-07-27 Catalyst system for the polymerisation of olefins

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10039626.7 2000-08-09
DE10039626 2000-08-09
DE10040860.5 2000-08-21
DE10040860A DE10040860A1 (de) 2000-08-09 2000-08-21 Katalysatorsystem zur Polymerisation von Olefinen

Publications (2)

Publication Number Publication Date
WO2002012154A2 WO2002012154A2 (de) 2002-02-14
WO2002012154A3 true WO2002012154A3 (de) 2002-06-27

Family

ID=26006694

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/008691 WO2002012154A2 (de) 2000-08-09 2001-07-27 Katalysatorsystem zur polymerisation von olefinen

Country Status (3)

Country Link
US (1) US20020058765A1 (de)
AU (1) AU2001277556A1 (de)
WO (1) WO2002012154A2 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
ATE529431T1 (de) 2005-12-14 2011-11-15 Exxonmobil Chem Patents Inc Halogensubstituierte metallocenverbindungen für die olefinpolymerisation
EP2112173A1 (de) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Katalysatorverbindungen und ihre Verwendung
EP2103634A1 (de) 2008-03-20 2009-09-23 ExxonMobil Chemical Patents Inc. Herstellung propylen-basierter polymere
US8530712B2 (en) 2009-12-24 2013-09-10 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
WO2012112259A2 (en) 2011-02-15 2012-08-23 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
CN118202023A (zh) 2021-11-05 2024-06-14 埃克森美孚化学专利公司 聚丙烯粘度改性剂及其润滑油
CA3237354A1 (en) 2021-11-05 2023-05-11 Exxonmobil Chemical Patents Inc. Syndiotactic propylene-based ethylene-propylene copolymers
US11926802B2 (en) 2021-11-05 2024-03-12 Exxonmobil Chemical Patents Inc. Lubricating oil composition with viscosity modifier based on syndiotactic propylene-based ethylene- propylene copolymers with improved properties

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029845A1 (en) * 1996-02-20 1997-08-21 Northwestern University An organo-lewis acid as cocatalyst for cationic homogeneous metallocene ziegler-natta olefin polymerizations
WO1997035893A1 (en) * 1996-03-27 1997-10-02 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
JPH1060034A (ja) * 1996-06-14 1998-03-03 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
WO1999045042A1 (en) * 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Noncoordinating anions for olefin polymerization
WO2000011006A1 (en) * 1998-08-18 2000-03-02 The Dow Chemical Company Metalloid salt catalyst/activators
EP1013675A2 (de) * 1998-12-17 2000-06-28 Enichem S.p.A. Aktivatorzusammensetzung für metallocenkomplexe in der katalyse von olefin(co)polymerisationsverfahren

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997029845A1 (en) * 1996-02-20 1997-08-21 Northwestern University An organo-lewis acid as cocatalyst for cationic homogeneous metallocene ziegler-natta olefin polymerizations
WO1997035893A1 (en) * 1996-03-27 1997-10-02 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
JPH1060034A (ja) * 1996-06-14 1998-03-03 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
WO1999045042A1 (en) * 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Noncoordinating anions for olefin polymerization
WO2000011006A1 (en) * 1998-08-18 2000-03-02 The Dow Chemical Company Metalloid salt catalyst/activators
EP1013675A2 (de) * 1998-12-17 2000-06-28 Enichem S.p.A. Aktivatorzusammensetzung für metallocenkomplexe in der katalyse von olefin(co)polymerisationsverfahren

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 128, no. 19, 11 May 1998, Columbus, Ohio, US; abstract no. 230831, DOI, YASUSHI ET AL: "Olefin polymerization catalysts and olefin polymerization" XP002195942 *

Also Published As

Publication number Publication date
WO2002012154A2 (de) 2002-02-14
AU2001277556A1 (en) 2002-02-18
US20020058765A1 (en) 2002-05-16

Similar Documents

Publication Publication Date Title
WO2001047635A3 (de) Geträgertes katalysatorsystem enthaltend ein metallocen, eine lewis-base und eine elementorganische verbindung der iii. hauptgruppe, sowie dessen verwendung
WO2002088201A8 (en) Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
ZA200108415B (en) Organometallic compound useful as cocatalyst for polymerizing olefins.
ATE391735T1 (de) Mehrkerniger metallocenkatalysator
AU4547800A (en) Catalyst system
WO2000001738A3 (en) Process for the preparation of substantially amorphous alpha-olefin polymers, compositions containing them and process for the preparation of bridged ligand
EP1548022A3 (de) Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen
WO2003000755A3 (en) Olefin polymerisation catalyst and methods for preparing the same
HUT74773A (en) Components and catalysts for the polymerization of olefins, process for polymerizing olefins by using said catalysts, polymers obtained using said catalysts and articles obtained from said polymers
WO2002012154A3 (de) Katalysatorsystem zur polymerisation von olefinen
WO2005058916A3 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins
NO971843L (no) Katalysatorblanding, samt fremgangsmåte ved polymerisering av et olefin
WO2003016321A3 (de) Neue phosphitverbindungen und neue phosphitmetallkomplexe
AU2003294764A1 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
AU2003233648A1 (en) Group 4 metal complexes containing 4-aryl-substituted, tricyclic indenyl derivatives
EP0970974A4 (de) Verfahren zur herstellung von olefinpolymeren
EP1054022A4 (de) Katalysator zur olefinpolymerisation und verfahren zur herstellung von olefinpolymeren damit
WO2001092346A3 (en) Catalyst for the production of olefin polymers
AU2728999A (en) Novel dendrimer compounds, method for the production thereof, use thereof as catalysts
TW200615288A (en) ANSA-metallocene compound, process of preparing the same, and process of preparing polyolefin using the same
WO2002040549A3 (en) A method for preparing a catalyst composition and its use in a polymerization process
CA2429936A1 (en) Polymerization process
CA2425588A1 (en) A method for preparing a catalyst system and its use in a polymerization process
ATE260945T1 (de) Zwitterionische, neutrale übergansmetallverbindung
WO2006018264A3 (en) Cyclopentadienyl complexes of group 6 substituted by silyl halides

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP