WO2002006846A1 - Dispositif permettant d'evaluer la densite des protons presents dans un corps donne par rmn - Google Patents
Dispositif permettant d'evaluer la densite des protons presents dans un corps donne par rmn Download PDFInfo
- Publication number
- WO2002006846A1 WO2002006846A1 PCT/FR2001/002211 FR0102211W WO0206846A1 WO 2002006846 A1 WO2002006846 A1 WO 2002006846A1 FR 0102211 W FR0102211 W FR 0102211W WO 0206846 A1 WO0206846 A1 WO 0206846A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coils
- symmetry
- permanent magnet
- plane
- pole pieces
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000012141 concentrate Substances 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 230000004907 flux Effects 0.000 claims description 3
- 239000000696 magnetic material Substances 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 235000013305 food Nutrition 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011435 rock Substances 0.000 abstract description 4
- 238000004458 analytical method Methods 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 description 7
- 230000010287 polarization Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910001035 Soft ferrite Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01V—GEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS
- G01V3/00—Electric or magnetic prospecting or detecting; Measuring magnetic field characteristics of the earth, e.g. declination, deviation
- G01V3/18—Electric or magnetic prospecting or detecting; Measuring magnetic field characteristics of the earth, e.g. declination, deviation specially adapted for well-logging
- G01V3/32—Electric or magnetic prospecting or detecting; Measuring magnetic field characteristics of the earth, e.g. declination, deviation specially adapted for well-logging operating with electron or nuclear magnetic resonance
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R33/00—Arrangements or instruments for measuring magnetic variables
- G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
- G01R33/44—Arrangements or instruments for measuring magnetic variables involving magnetic resonance using nuclear magnetic resonance [NMR]
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N24/00—Investigating or analyzing materials by the use of nuclear magnetic resonance, electron paramagnetic resonance or other spin effects
- G01N24/08—Investigating or analyzing materials by the use of nuclear magnetic resonance, electron paramagnetic resonance or other spin effects by using nuclear magnetic resonance
- G01N24/085—Analysis of materials for the purpose of controlling industrial production systems
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R33/00—Arrangements or instruments for measuring magnetic variables
- G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
- G01R33/28—Details of apparatus provided for in groups G01R33/44 - G01R33/64
- G01R33/38—Systems for generation, homogenisation or stabilisation of the main or gradient magnetic field
- G01R33/383—Systems for generation, homogenisation or stabilisation of the main or gradient magnetic field using permanent magnets
Definitions
- the present invention relates to devices making it possible to evaluate the density of the protons present in a given body with the possibility of identifying the material entering into the constitution of this body, to which the protons belonged, devices which find particularly advantageous applications, in particular, in the food industry to determine the amount of water and / or fat in food, and in the petroleum industry to determine for example the amount of water in the rock surrounding the wall of a well, the distribution of the porosity of this rock and / or its permeability.
- RNM Magnetic Nuclear Resonance
- the device further comprises a transmitting antenna constituted for example by a magnetic coil supplied by a radiofrequency electric current generator, the coil being associated with the permanent magnet so that the lines of force of the radiofrequency magnetic field induced by this coil when it supplied by the radiofrequency electric current makes, in this zone, a non-zero angle with the lines of force of the static field, and advantageously equal to ninety degrees.
- the frequency of the radiofrequency field is such that it corresponds to the precession frequency of the protons in the static field in order to induce a resonant interaction between the protons and the radiofrequency field. This interaction makes it possible to rotate the polarization of the protons from pulses of the radiofrequency field by an angle depending on the amplitude of the radiofrequency field and the duration of the pulses.
- the device further comprises a receiving antenna constituted for example by a magnetic coil which can be constituted by the same coil as the transmitting coil, this receiving antenna picking up the magnetic field produced by the protons when the radiofrequency current is canceled and they return at their initial polarization under the action only of the static field of the permanent magnet.
- a receiving antenna constituted for example by a magnetic coil which can be constituted by the same coil as the transmitting coil, this receiving antenna picking up the magnetic field produced by the protons when the radiofrequency current is canceled and they return at their initial polarization under the action only of the static field of the permanent magnet.
- the amplitude of the magnetic field detected by the receiving antenna is a function of the number of protons which have been excited in the investigation area, and the time it takes for the protons to pass from their second polarization to the first, known by the technicians under the term "relaxation time", is an image of the nature of the products to which these protons belonged.
- the present invention therefore aims to achieve a device for evaluating the density of the protons of a material contained in a given body with the possibility of identifying this material, which largely overcomes the disadvantages of the devices of the art which can be applied to fields as different as the food and petroleum fields.
- the subject of the present invention is a device making it possible to evaluate the density of the protons present in a given body with the possibility of identifying the material entering into the constitution of said body, to which said protons belonged, characterized in that it comprises: a permanent magnet comprising two poles respectively North and South, said permanent magnet having a longitudinal axis of symmetry oriented North-South and a plane of symmetry perpendicular to said longitudinal axis of symmetry, at least two first and second cylindrical coils arranged on one side and on the other side of the permanent magnet, substantially centered on said longitudinal axis of symmetry and substantially symmetrical with respect to said plane of symmetry, a controllable radio-frequency electric current generator whose outputs are respectively connected to the two first and second coils of way that the current electric radio frequency feeds the two coils so that the faces of the two coils respectively opposite the two poles of the permanent magnet are of the same magnetic nature, and a receiver whose inputs are respectively connected to the two coils, said receiver being suitable for analyze the electrical
- FIG. 1 represents, in schematic form, part of a first mode of realization of the device according to the invention making it possible to evaluate the density of the protons present in a given body with the possibility of identifying the material entering into the constitution of this body, to which the protons belonged,
- FIGS. 2, 3 and 4 respectively represent three other embodiments of the device according to the invention, constituting improvements to the embodiment according to FIG. 1, and
- FIG. 5 represents an embodiment of the device according to the invention in a particular application in the food sector.
- the five figures represent different embodiments of the device according to the invention making it possible to evaluate the density of the protons present in a given body with the possibility of identifying the material entering into the constitution of this body, to which the protons.
- the same references designate the same elements there, whatever the figure on which they appear and whatever the form of representation of these elements.
- elements are not specifically referenced in one of the figures, their references can be easily found by referring to another figure.
- FIG. 1 schematically represents a part of the device making it possible to evaluate the density of the protons present in a given body 100 with the possibility of identifying the material entering into the constitution of this body, to which these protons belonged, the other part of the device being illustrated in FIG. 5.
- the device comprises a permanent magnet 1 comprising two poles 6, 7 respectively North and South, the permanent magnet having a longitudinal axis of symmetry 2 oriented North -South and a plane of symmetry 3 perpendicular to this longitudinal axis of symmetry.
- this permanent magnet 1 will advantageously be of cylindrical shape of revolution.
- the device further comprises at least two first 11 and second 12 cylindrical coils arranged on either side of the permanent magnet 1, substantially centered on the longitudinal axis of symmetry 2 and substantially symmetrical with respect to the plane of symmetry 3.
- These coils 11, 12 shown in FIG. 1 are of the “flat coils” type, but they can be of any other type, for example solenoids as shown in FIG. 5. With reference to this FIG.
- the device further comprises a controllable radio-frequency electric current generator 4 whose outputs 5 are respectively connected to the two first and second coils 11, 12 so that the radio-frequency electric current supplies the two coils so that the faces 13, 14 of the two coils respectively opposite the two poles 6, 7 of the permanent magnet 1 are of the same magnetic nature, and a receiver 8 whose inputs 9 are respectively connected to the two coils 11, 12, this receiver being able to analyze the electrical signals delivered to the output 15, 16 of the two coils when the generator is disconnected from these two coils.
- a controllable radio-frequency electric current generator 4 whose outputs 5 are respectively connected to the two first and second coils 11, 12 so that the radio-frequency electric current supplies the two coils so that the faces 13, 14 of the two coils respectively opposite the two poles 6, 7 of the permanent magnet 1 are of the same magnetic nature
- a receiver 8 whose inputs 9 are respectively connected to the two coils 11, 12, this receiver being able to analyze the electrical signals delivered to the output 15, 16 of the two coils when the generator is disconnected from these
- these coils could be supplied in reverse so that it is their South faces (S) which are opposite the North and South poles of the magnet.
- the magnetic force lines 23, 24 would have the same shape as that illustrated in FIG. 1, but would be oriented in the opposite direction to that indicated in this figure.
- Such a device operates on the principle of RNM. This operation is well known, but it is however very briefly recalled below.
- the device When it is desired to measure the density of the protons in the body 100, the device is brought as close as possible to this body, the generator 4 and the receiver 8 being deactivated. Under the effect of the permanent static magnetic field, the protons orient themselves, in the zone 25 which is in the form of an annular toric zone substantially centered on the axis of symmetry 2 and on the plane of symmetry 3 and relatively close to the side wall of the permanent magnet 1, along the lines of force 29 of this permanent field.
- the generator 4 is then activated to supply the coils 11, 12 with radiofrequency electric current.
- Each coil then creates a radiofrequency induced magnetic field whose lines of force 23, 24 respectively are, in the zone 25 defined above, perpendicular to the lines of force 29.
- the lines of force of the magnetic fields induced by the two coils are, in this zone 25, oriented in the same direction, which has the effect of creating a total radiofrequency magnetic field of relatively high intensity.
- the direction of polarization of the protons is controlled due to the resonant interaction and the angle of rotation is a function of the amplitude of the radiofrequency pulse and its duration, this angle possibly advantageously be ninety degrees.
- the radiofrequency signal emitted by the generator 4 is of the order of 4 megahertz and the coils are designed to create an induced magnetic field of the order of Tesla.
- the generator 4 is deactivated and the receiver 8, activated, picks up the signals delivered at the output of the coils created by the magnetic field produced by the protons returning from their second polarization to the first.
- the analysis of the signal picked up by the receiver 8 makes it possible, as a function of its amplitude, to determine the density of the protons and, as a function of its temporal variation, possibly to identify the nature of the product containing these protons.
- the device advantageously further comprises two first 21 and second 22 magnetic reflectors mounted in cooperation with respectively the first and second coils 11, 12 so that they concentrate the magnetic flux 23, 24 capable of being created by each magnetic coil 11, 12, in the zone 25 defined above.
- the two magnetic reflectors 21, 22 are constituted by two concave surfaces, or of similar shape, 26, 27 of revolution around the axis of symmetry 2 and associated respectively with the two coils 11, 12 so that their centers of curvature are located in the vicinity of the plane of symmetry 3, each concave surface of revolution being constituted by a layer of an electrically conductive material, for example copper, gold, etc.
- the device advantageously further comprises, as illustrated in FIG. 3, two symmetrical pole pieces 31, 32 mounted in cooperation with the two poles 6, 7 of the permanent magnet, these two pole pieces passing respectively through the interior of the two coils 11, 12 and being arranged to concentrate the lines of force of the static magnetic field generated by the permanent magnet 1 , substantially in the zone 25.
- These two pole pieces 31, 32 are made for example of a material such as iron, soft ferrite, etc.
- the device comprises these two pole pieces, it is advantageous, as illustrated in FIG. 3, that the two concave surfaces of revolution 26, 27 are formed on the external lateral surfaces of the two pole pieces, the layer of electrically conductive material defined here before being directly deposited on the external lateral surface of these pole pieces 31, 32.
- the maximum overall dimensions taken in planes parallel to the plane of symmetry 3, respectively of the two coils 11, 12, of the two concave surfaces of revolution 26, 27 and of the two pole pieces 31, 32, are at most equal to the maximum overall dimension of the permanent magnet 1 taken in a plane parallel to the plane of symmetry 3.
- the device further comprises, as illustrated in FIG. 3, a continuous through-hole 40 made along substantially the axis of symmetry 2 in the permanent magnet 1 and the two pole pieces 31, 32.
- This through hole 40 allows the passage of the atmosphere contained in the well on either side of the device when the latter moves in the well. It also allows, advantageously, the passage, for example, of tools of different types, probes, cables, rods, etc. commonly used in the oil sector in particular.
- the permanent magnet 1 and the pole pieces 31, 32 are respectively made up of at least two parts able to be associated along a plane containing the axis of symmetry 2 to form the permanent magnet and the pole pieces, and the device then comprises means 41 for controlling the movement of these two parts in directions perpendicular to the axis of symmetry, for example electric jacks or the like.
- the device then comprises means 41 for controlling the movement of these two parts in directions perpendicular to the axis of symmetry, for example electric jacks or the like.
- the device according to the invention has many applications. It can in particular be used to determine the quantity of water and / or fat contained in food.
- FIG. 5 represents an embodiment more particularly suited to this application.
- the device can advantageously further comprise a needle-shaped sheath 50 capable of penetrating into the body 100 through one 51 of its ends, the assembly comprising the permanent magnet 1, the pole pieces 31, 32 and the concave surfaces of revolution 26, 27 being located in this sheath made for example of a non-magnetic and dielectric material, for example a plastic material, a material known under the trademark "Nylon", etc.
- the device further comprises a handling handle 52 secured to the end 53 of the sheath opposite to that 51 by which the sheath is able to penetrate the body 100.
- a housing 54 is produced in this handle, in which the generator 4, the receiver 8, a source of electrical power and all the usual peripherals well known in themselves can be arranged in order to make this autonomous device capable of being used. anywhere and anytime.
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- Physics & Mathematics (AREA)
- High Energy & Nuclear Physics (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Remote Sensing (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geophysics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Geophysics And Detection Of Objects (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01955392A EP1299741A1 (fr) | 2000-07-13 | 2001-07-10 | Dispositif permettant d'evaluer la densite des protons presents dans un corps donne par rmn |
US10/332,137 US6812704B2 (en) | 2000-07-13 | 2001-07-10 | Device for evaluating the density of protons present in a given body using nmr |
AU2001277567A AU2001277567A1 (en) | 2000-07-13 | 2001-07-10 | Device for evaluating the density of protons present in a given body using nmr |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0009155A FR2811767B1 (fr) | 2000-07-13 | 2000-07-13 | Dispositif permettant d'evaluer la densite des protons presents dans un corps donne |
FR00/09155 | 2000-07-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002006846A1 true WO2002006846A1 (fr) | 2002-01-24 |
Family
ID=8852440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2001/002211 WO2002006846A1 (fr) | 2000-07-13 | 2001-07-10 | Dispositif permettant d'evaluer la densite des protons presents dans un corps donne par rmn |
Country Status (5)
Country | Link |
---|---|
US (1) | US6812704B2 (fr) |
EP (1) | EP1299741A1 (fr) |
AU (1) | AU2001277567A1 (fr) |
FR (1) | FR2811767B1 (fr) |
WO (1) | WO2002006846A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2864354B1 (fr) * | 2003-12-17 | 2006-03-24 | Commissariat Energie Atomique | Antenne plane a champ tournant, comportant une boucle centrale et des boucles excentrees, et systeme d'identification par radiofrequence |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5572132A (en) * | 1995-08-15 | 1996-11-05 | Pulyer; Yuly M. | MRI probe for external imaging |
US5610522A (en) * | 1993-09-30 | 1997-03-11 | Commissariat A L'energie Atomique | Open magnetic structure including pole pieces forming a V-shape threbetween for high homogeneity in an NMR device |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3966973A (en) * | 1974-08-26 | 1976-06-29 | The Pillsbury Company | Process for determining and controlling the moisture of food products |
US4717876A (en) * | 1986-08-13 | 1988-01-05 | Numar | NMR magnet system for well logging |
US5831433A (en) * | 1996-12-04 | 1998-11-03 | Sezginer; Abdurrahman | Well logging method and apparatus for NMR and resistivity measurements |
US6133734A (en) * | 1997-12-30 | 2000-10-17 | Schlumberger Technology Corporation | Method and apparatus for evaluating an earth formation using nuclear magnetic resonance techiques |
US6114851A (en) * | 1999-02-12 | 2000-09-05 | Baker Hughes Incorporated | Temperature compensated nuclear magnetic resonance apparatus and method |
US6493572B1 (en) * | 1999-09-30 | 2002-12-10 | Toshiba America Mri, Inc. | Inherently de-coupled sandwiched solenoidal array coil |
US6459262B1 (en) * | 2000-04-25 | 2002-10-01 | Baker Hughes Incorporated | Toroidal receiver for NMR MWD |
-
2000
- 2000-07-13 FR FR0009155A patent/FR2811767B1/fr not_active Expired - Fee Related
-
2001
- 2001-07-10 AU AU2001277567A patent/AU2001277567A1/en not_active Abandoned
- 2001-07-10 WO PCT/FR2001/002211 patent/WO2002006846A1/fr not_active Application Discontinuation
- 2001-07-10 US US10/332,137 patent/US6812704B2/en not_active Expired - Lifetime
- 2001-07-10 EP EP01955392A patent/EP1299741A1/fr not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5610522A (en) * | 1993-09-30 | 1997-03-11 | Commissariat A L'energie Atomique | Open magnetic structure including pole pieces forming a V-shape threbetween for high homogeneity in an NMR device |
US5572132A (en) * | 1995-08-15 | 1996-11-05 | Pulyer; Yuly M. | MRI probe for external imaging |
Also Published As
Publication number | Publication date |
---|---|
EP1299741A1 (fr) | 2003-04-09 |
US20030184295A1 (en) | 2003-10-02 |
FR2811767B1 (fr) | 2002-09-20 |
AU2001277567A1 (en) | 2002-01-30 |
US6812704B2 (en) | 2004-11-02 |
FR2811767A1 (fr) | 2002-01-18 |
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