WO2002005952A3 - Attrition resistant catalyst for light olefin production - Google Patents

Attrition resistant catalyst for light olefin production Download PDF

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Publication number
WO2002005952A3
WO2002005952A3 PCT/US2001/021958 US0121958W WO0205952A3 WO 2002005952 A3 WO2002005952 A3 WO 2002005952A3 US 0121958 W US0121958 W US 0121958W WO 0205952 A3 WO0205952 A3 WO 0205952A3
Authority
WO
WIPO (PCT)
Prior art keywords
light olefin
olefin production
attrition resistant
resistant catalyst
molecular sieve
Prior art date
Application number
PCT/US2001/021958
Other languages
French (fr)
Other versions
WO2002005952A2 (en
Inventor
Paul T Barger
Terry L Marker
John A Karch
Original Assignee
Uop Llc
Paul T Barger
Terry L Marker
John A Karch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc, Paul T Barger, Terry L Marker, John A Karch filed Critical Uop Llc
Priority to AU2001275901A priority Critical patent/AU2001275901A1/en
Publication of WO2002005952A2 publication Critical patent/WO2002005952A2/en
Publication of WO2002005952A3 publication Critical patent/WO2002005952A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catalyst compositions that are effective for the conversion of methanol to light olefins (e.g. ethylene) are disclosed. The catalysts comprise a crystalline metalloaluminophosphate molecular sieve (e.g. SAPO-34) and a matrix material comprising an inorganic oxide binder and a filler, preferably a clay (e.g. kaolin). It has been discovered that by maintaining the content of the molecular sieve at 40 % or less by weight, the overall catalyst attrition resistance is markedly improved.
PCT/US2001/021958 2000-07-13 2001-07-12 Attrition resistant catalyst for light olefin production WO2002005952A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001275901A AU2001275901A1 (en) 2000-07-13 2001-07-12 Attrition resistant catalyst for light olefin production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61581600A 2000-07-13 2000-07-13
US09/615,816 2000-07-13

Publications (2)

Publication Number Publication Date
WO2002005952A2 WO2002005952A2 (en) 2002-01-24
WO2002005952A3 true WO2002005952A3 (en) 2002-06-06

Family

ID=24466924

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/021958 WO2002005952A2 (en) 2000-07-13 2001-07-12 Attrition resistant catalyst for light olefin production

Country Status (4)

Country Link
CN (1) CN1341584A (en)
AU (1) AU2001275901A1 (en)
WO (1) WO2002005952A2 (en)
ZA (1) ZA200105793B (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2282488T3 (en) 2001-07-02 2007-10-16 Exxonmobil Chemical Patents Inc. INHIBITION OF THE COKE FORMATION IN A CATALYST IN THE MANUFACTURE OF AN OLEFINA.
US6844291B2 (en) 2002-02-28 2005-01-18 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
US6995111B2 (en) 2002-02-28 2006-02-07 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6906232B2 (en) 2002-08-09 2005-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US7208442B2 (en) 2002-02-28 2007-04-24 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalyst thereof, their making and use in conversion processes
KR20040089680A (en) * 2002-02-28 2004-10-21 엑손모빌 케미칼 패턴츠 인코포레이티드 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes
US7319178B2 (en) 2002-02-28 2008-01-15 Exxonmobil Chemical Patents Inc. Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US6872680B2 (en) 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7271123B2 (en) 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
US6759360B2 (en) 2002-03-29 2004-07-06 Exxonmobil Chemical Patent Inc. Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins
US6951830B2 (en) * 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US7125821B2 (en) 2003-09-05 2006-10-24 Exxonmobil Chemical Patents Inc. Low metal content catalyst compositions and processes for making and using same
US7241713B2 (en) * 2003-10-02 2007-07-10 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7312369B2 (en) * 2004-04-28 2007-12-25 Exxonmobil Chemical Patents Inc. Attrition resistant molecular sieve catalyst, method of making and process for using
US7309383B2 (en) 2004-09-23 2007-12-18 Exxonmobil Chemical Patents Inc. Process for removing solid particles from a gas-solids flow
CN100569370C (en) * 2005-01-31 2009-12-16 埃克森美孚化学专利公司 Molecular sieve catalyst composition, its preparation and the application in method for transformation
CN1332761C (en) * 2005-07-13 2007-08-22 清华大学 Process for preparing load type silicon phoshporus aluminium molecular sieve
US7309679B2 (en) 2005-08-08 2007-12-18 Uop Llc Attrition resistant MTO catalyst
CN101121148B (en) * 2006-08-08 2010-05-12 中国科学院大连化学物理研究所 Direct forming method of fluidized reaction catalyst containing molecular sieve
CN101284244B (en) * 2007-04-13 2010-10-13 中国中化股份有限公司 Catalyst for synthesizing the aziridine type compound
EP2082803A1 (en) * 2008-01-25 2009-07-29 Total Petrochemicals Research Feluy Process for obtaining catalyst composites comprising MeAPO and their use in conversion of organics to olefins
SG11201505810VA (en) * 2013-02-08 2015-08-28 Chevron Usa Inc Molecular sieve ssz-85 composition of matter and synthesis thereof
CN103706393B (en) * 2013-12-24 2016-02-10 太原大成环能化工技术有限公司 A kind of wear-resistant catalyst method for preparing microsphere for the production of low-carbon alkene
CN105233864A (en) * 2015-07-01 2016-01-13 北京中鼎亚科技有限公司 Microsphere catalyst for fluidized bed and preparation method and application thereof
CN105396615B (en) * 2015-10-18 2017-02-15 任丘市华北石油科林环保有限公司 Catalyst for preparing low carbon olefins from methanol
CN107971024B (en) * 2016-10-21 2021-02-09 中国石油化工股份有限公司 Preparation method of fluidized bed catalyst
CN107971025B (en) * 2016-10-21 2020-12-29 中国石油化工股份有限公司 Catalyst for preparing olefin from methanol and preparation method thereof
CN108067300B (en) * 2017-12-20 2021-01-26 卓悦环保新材料（上海）有限公司 Method for forming SAPO-34 molecular sieve catalyst
CN112604644A (en) * 2020-12-14 2021-04-06 江苏磊金环境工程有限公司 Thermal desorption regeneration tower equipment for saturated active alumina pellets
CN115924933A (en) * 2022-12-19 2023-04-07 太原理工大学 Forming method of phosphorus-aluminum molecular sieve

Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0209793A1 (en) * 1985-07-15 1987-01-28 W.R. Grace & Co.-Conn. Cracking catalyst
EP0496226A1 (en) * 1991-01-22 1992-07-29 W.R. Grace & Co.-Conn. Catalytic compositions
WO1999021651A1 (en) * 1997-10-29 1999-05-06 Exxon Chemical Patents Inc. Method for making catalysts containing silicoaluminophosphate molecular sieve and catalyst thus prepared
US5914433A (en) * 1997-07-22 1999-06-22 Uop Lll Process for producing polymer grade olefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0209793A1 (en) * 1985-07-15 1987-01-28 W.R. Grace & Co.-Conn. Cracking catalyst
EP0496226A1 (en) * 1991-01-22 1992-07-29 W.R. Grace & Co.-Conn. Catalytic compositions
US5914433A (en) * 1997-07-22 1999-06-22 Uop Lll Process for producing polymer grade olefins
WO1999021651A1 (en) * 1997-10-29 1999-05-06 Exxon Chemical Patents Inc. Method for making catalysts containing silicoaluminophosphate molecular sieve and catalyst thus prepared

Also Published As

Publication number Publication date
ZA200105793B (en) 2002-02-08
AU2001275901A1 (en) 2002-01-30
WO2002005952A2 (en) 2002-01-24
CN1341584A (en) 2002-03-27

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