WO2001098562A1 - Method for manufacturing products - Google Patents
Method for manufacturing products Download PDFInfo
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- WO2001098562A1 WO2001098562A1 PCT/AT2001/000015 AT0100015W WO0198562A1 WO 2001098562 A1 WO2001098562 A1 WO 2001098562A1 AT 0100015 W AT0100015 W AT 0100015W WO 0198562 A1 WO0198562 A1 WO 0198562A1
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- WIPO (PCT)
- Prior art keywords
- workpiece
- coating
- nozzle
- workpieces
- nozzle element
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/22—Servicing or operating apparatus or multistep processes
Definitions
- the invention relates to a process for the manufacture of products, in particular decorative and others, with a coating applied to them.
- a method for manufacturing products e.g. Workpieces consisting of valve metals or their alloys and the subsequent application of a coating by means of micro-arc oxidation or electrophoresis in alkaline solution with the addition of additives (SU 9260084, 07.05.82).
- This method has the following disadvantages: 1. When machining the workpieces in the trough, the uneven distribution of the electromagnetic force field on the surface of a workpiece with a complicated shape has a negative effect on the quality of the coating. For this reason, the process of applying the coating to the hidden and shaded, i.e. poorly accessible parts of the workpieces very slowly or not at all. 2.
- the process control in the tub is associated with an unproductively large expenditure of electrical energy, especially in the case of machining local parts of the workpieces.
- the processing of workpieces with complex technology requires protection of the parts that are not subject to processing. It is also necessary to constantly mix the solution, which leads to a disorderly penetration of the particles into the burning zone of the micro arc.
- the invention has for its object to provide a method with which an increase in the quality of the products and an increase in productivity of the work can be achieved.
- This object is achieved by placing a nozzle element at a distance of 5-15 mm from the zone of the surface of the workpiece to be machined before the coating is applied. is brought, the nozzle cross section is selected depending on the nature of the part of the workpiece surface to be machined.
- By feeding the alkaline solution through the nozzle element it is possible to close the cathode-anode electrical circuit by means of the uninterrupted and positively targeted and / or self-draining solution jet to avoid additional cooling of the workpieces and to ensure that the coating melts through all its depth.
- the powdery components and / or the ultra-disperse powders necessary with regard to the chemical composition are used as additives.
- the nozzle element is moved continuously along the entire surface to be machined at a speed of not more than 25 mm / min with a temporary isolation of individual parts of the workpiece.
- Aluminum and titanium or their alloys such as e.g. Duraluminium 1, duraluminium hard, aluminum magnesium, AlMn (aluminum manganese) alloy rods based on titanium, A1V (aluminum vanadium) alloys based on titanium can be used.
- Disperse powder - AI, Ti and Mg can be used.
- a nozzle element When machining surface areas of workpieces with a rectangular shape, a nozzle element is preferably used, the nozzle cross section of which has a rectangular shape.
- the formation process of the coating is not intensified by means of a random (accidental) impact of the powder particles of the powder in the micro-arc. Burning zone, but by means of the targeted electricity.
- Micro-arc discharge causes a large increase in the current, by increasing the electron conductivity.
- Example 1 The workpiece is installed and started on an electromechanical lathe (not shown).
- the alkaline solution is automatically (or inevitably) directed onto the surface of the workpiece to be machined by the nozzle element.
- Voltage is applied between the workpiece and the nozzle.
- the end of the cathode-anode electrical circuit passes through the emerging beam of the solution.
- the solution can be given simultaneously through one or more nozzles, depending on the
- the solution can contain the ultra-disperse powders necessary with regard to the chemical composition.
- the constant concentration of the powder in the solution is maintained in that powder through the Powder dosing device can be added.
- Example 2 It is required to get a wear-resistant decorative coating on the right-angled part on a flat workpiece (plate) made of the alloy AlMg 2 .
- the insulating conductor (conductor) with the opening with respect to the rectangular part was manufactured.
- the nozzle element for the supply of the alkaline solution is placed at a distance of 10 mm from the surface to be machined and firmly anchored on the mechanism for the displacement of the nozzle element.
- the adjustment was made parallel to the processing surface with different speeds, which were given in table 2.
- the diameter of the outlet opening of the nozzle is significantly less than the width of the part to be machined. Therefore, the nozzle is moved in one pass along the length of the part, then across the width at a distance of 0.9 from the diameter of the nozzle, again offset across the length of the part.
- the example in question shows the possibility of obtaining the coating on a single one
- the method of manufacturing the products in this way increases the quality of the products and the labor productivity.
- the method according to the invention can of course also be applied to other materials, e.g. Metals or alloys in general, provided that a circuit can be closed between them and the nozzle. If necessary, this can be done by an electrically conductive coating of the workpiece.
- the invention can be used, for example, in the manufacture of products made from valve metals and their alloys. Table 1:
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Formation And Processing Of Food Products (AREA)
- Powder Metallurgy (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Perforating, Stamping-Out Or Severing By Means Other Than Cutting (AREA)
Abstract
The invention relates to a method for coating products e.g. workpieces (in particular consisting of valve metals or their alloys) by micro arc oxidation or electrophoresis in the presence of at least one additive that is incorporated into an alkaline solution. Said method is characterised in that a nozzle element is placed at a distance of 5-15 mm from the region of the surface of the workpiece to be treated, prior to the application of the coating. The cross-section of the nozzle is selected depending on the geometry of the workpiece to be treated. In addition, by supplying the alkaline solution through the nozzle element, an electric cathode-anode circuit is closed by the uninterrupted stream of solution that is guided in a specifically targeted manner and/or flows freely, to prevent a further cooling of the workpiece and to ensure the fusion of the coating over its entire depth. The additives used consist of powdered components or ultra-disperse powder that is necessary for the chemical composition.
Description
Verfahren zur Herstellung von ErzeugnissenProcess for the production of articles
Die Erfindung betrifft ein Verfahren zur Herstellung von Erzeugnissen, insbesondere von dekorativen und anderen, mit einem auf sie aufgetragenem Überzug.The invention relates to a process for the manufacture of products, in particular decorative and others, with a coating applied to them.
Bekannt ist ein Verfahren zur Fertigung von Erzeugnissen, wie z.B. Werkstücken, bestehend aus Ventilmetallen bzw. ihren Legierungen und das darauffolgende Auftragen eines Überzugs mittels Mikro-Bogen-Oxidation oder Elektrophorese in alkalischer Lösung mit der Eintragung von Zusätzen (SU 9260084, 07.05.82). Dieses Verfahren hat folgende Nachteile: 1. Bei der Bearbeitung der Werkstücke in der Wanne beeinflußt die Ungleichmäßigkeit der Verteilung des elektromagnetischen Kraftfeldes auf der Oberfläche eines Werkstücks mit komplizierter Form die Qualität des Überzugs negativ. Aus diesem Grund verläuft der Prozeß des Auftragens des Überzugs auf den verborgenen und beschatteten, d.h. schlecht zugänglichen Stellen der Werkstücke sehr langsam oder findet überhaupt nicht statt. 2. Die Prozeßführung in der Wanne ist mit unproduktiv großem Aufwand an Elektroenergie verbunden, besonders im Falle der Bearbeitung von lokalen Stellen der Werkstücke. Dabei erfordert die Bearbeitung von Werkstücken mit komplizierter Technologie einen Schutz der Teile, die der Bearbeitung nicht unterliegen. Ebenso ist es notwendig, ständig die Lösung zu vermischen, was zu einem ungeordneten Eindringen der Teilchen in die Brennzone des Miko-Bogens führt.A method for manufacturing products, e.g. Workpieces consisting of valve metals or their alloys and the subsequent application of a coating by means of micro-arc oxidation or electrophoresis in alkaline solution with the addition of additives (SU 9260084, 07.05.82). This method has the following disadvantages: 1. When machining the workpieces in the trough, the uneven distribution of the electromagnetic force field on the surface of a workpiece with a complicated shape has a negative effect on the quality of the coating. For this reason, the process of applying the coating to the hidden and shaded, i.e. poorly accessible parts of the workpieces very slowly or not at all. 2. The process control in the tub is associated with an unproductively large expenditure of electrical energy, especially in the case of machining local parts of the workpieces. The processing of workpieces with complex technology requires protection of the parts that are not subject to processing. It is also necessary to constantly mix the solution, which leads to a disorderly penetration of the particles into the burning zone of the micro arc.
3. Der Prozeß ist kompliziert gesteuert, mit einem niedrigen Ausnutzungsgrad des Pulvers. Dabei braucht man Pulver mit einer sehr kleinen Dispersion, für die Aufrechterhaltung der Lösung im Suspensions- (Schwebe- ) Zustand und auch zum Ausschluß seines Absinkens auf dem Wannenboden. 4. Eine Realisierung des lokalen Auftragens von Überzügen auf große Werkstücke ist praktisch kompliziert und in einzelnen Fällen unmöglich. Deshalb ist der Prozeß des Anwachsens der Überzüge unproduktiv; gleichzeitig senkt das die Qualität der erhaltenen Überzüge und erhöht die Instabilität ihrer Eigenschaften.3. The process is complicatedly controlled, with a low utilization rate of the powder. Powder with a very small dispersion is required to maintain the solution in the suspension (suspended) state and also to prevent it from sinking onto the tub floor. 4. Realizing the local application of coatings on large workpieces is practically complicated and impossible in individual cases. Therefore, the process of coating growth is unproductive; at the same time, this lowers the quality of the coatings obtained and increases the instability of their properties.
Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zu schaffen, mit dem eine Steigerung der Qualität der Erzeugnisse und eine Produktivitätssteigerung der Arbeit erreicht werden kann.The invention has for its object to provide a method with which an increase in the quality of the products and an increase in productivity of the work can be achieved.
Diese Aufgabe wird gelöst, indem ein Düsenelement vor dem Auftragen des Überzugs in der Entfernung von 5-15 mm von der Zone der zu bearbeitenden Oberfläche des Werkstücks an-
gebracht wird, dessen Düsenquerschnitt in Abhängigkeit von der Beschaffenheit des zu bearbeitenden Teils der Werkstückoberfläche ausgewählt wird. Durch Zuführen der alkalischen Lösung durch das Düsenelement gewährt man die Möglichkeit eines Schlusses des elektrischen Stromkreises Kathode - Anode durch den ununterbrochenen und zwangs-zielgerichteten und/oder von selbst auslaufenden Lösungsstrahl zur Vermeidung einer zusätzlichen Kühlung der Werkstücke und für die Gewährleistung des Durchschmelzens des Überzuges in seiner ganzen Tiefe. Dabei werden als Zusätze die pulverförmigen Komponenten und/oder die hinsichtlich der chemischen Zusammensetzung notwendigen Ultra-Dispers-Pulver verwendet.This object is achieved by placing a nozzle element at a distance of 5-15 mm from the zone of the surface of the workpiece to be machined before the coating is applied. is brought, the nozzle cross section is selected depending on the nature of the part of the workpiece surface to be machined. By feeding the alkaline solution through the nozzle element, it is possible to close the cathode-anode electrical circuit by means of the uninterrupted and positively targeted and / or self-draining solution jet to avoid additional cooling of the workpieces and to ensure that the coating melts through all its depth. The powdery components and / or the ultra-disperse powders necessary with regard to the chemical composition are used as additives.
Es ist notwendig, daß bei Werkstücken mit komplizierter Geometrie das Düsenelement kontinuierlich entlang der ganzen zu bearbeitenden Oberfläche mit einer Geschwindigkeit von nicht mehr als 25 mm/min bei einer vorübergehenden Isolation von einzelnen Stellen des Werkstückes bewegt wird.It is necessary that, in the case of workpieces with a complicated geometry, the nozzle element is moved continuously along the entire surface to be machined at a speed of not more than 25 mm / min with a temporary isolation of individual parts of the workpiece.
Vorzugsweise werden als Ventilmetalle Aluminium und Titan bzw. deren Legierungen, wie z.B. Duraluminium 1, DuraluminiumlόHart, Aluminium Magnesium, AlMn (Aluminium Mangan)-Legierangen auf Titanbasis, A1V (Aluminium Vanadium)-Legierungen auf Titanbasis, verwendet werden.Aluminum and titanium or their alloys, such as e.g. Duraluminium 1, duraluminium hard, aluminum magnesium, AlMn (aluminum manganese) alloy rods based on titanium, A1V (aluminum vanadium) alloys based on titanium can be used.
Als pulverförmige Komponenten können AI, Ti; Al2O3, TiO2, Aluminiumalaun und als Ultra-Al, Ti; Al 2 O 3 , TiO 2 , aluminum alum and as ultra
Dispers-Pulver - AI, Ti und Mg verwendet werden.Disperse powder - AI, Ti and Mg can be used.
Es ist weiters möglich, die Erzeugnisse vorab mit einer leitfähigen Schicht zu versehen, wodurch auch nicht leitende Werkstoffe nach der Erfindung beschichtet werden können.It is also possible to provide the products with a conductive layer beforehand, as a result of which non-conductive materials according to the invention can also be coated.
Bei der Bearbeitung von Oberflächenstellen von Werkstücken mit rechtwinkliger Form wird vorzugsweise ein Düsenelement verwendet, dessen Düsenquerschnitt eine rechtwinklige Form hat.When machining surface areas of workpieces with a rectangular shape, a nozzle element is preferably used, the nozzle cross section of which has a rectangular shape.
Die Eigenart der Fertigungsmethode der Werkstücke wird im Folgenden erklärt.The peculiarity of the manufacturing method of the workpieces is explained below.
Dank einer Zwangszuführung der alkalischen Lösung durch die Düse in die Bearbeitungszone im Abstand von 5-15 mm von der Oberfläche des Werkstücks entsteht eine Intensivierung des Bildungsprozesses des Überzugs nicht mittels ungeordnetem (zufälligen) Auftreffen der Pul- verteilchen des Pulvers in die Mikro- Bogen- Brennzone, sondern mittels des zwangs-zielge-
zielgerichteten Stroms.Thanks to the forced feeding of the alkaline solution through the nozzle into the processing zone at a distance of 5-15 mm from the surface of the workpiece, the formation process of the coating is not intensified by means of a random (accidental) impact of the powder particles of the powder in the micro-arc. Burning zone, but by means of the targeted electricity.
Dabei wird die Notwendigkeit einer zusätzlichen Kühlung der Werkstücke dank dem ununterbrochenen Abspülen der Werkstücke durch die Strömung der Lösung mit den Pulverteil- chen ausgeschlossen. Infolge eines intensiveren Eindringens der Pulverteilchen ins Gebiet derThe need for additional cooling of the workpieces is eliminated thanks to the continuous rinsing of the workpieces by the flow of the solution with the powder particles. As a result of a more intensive penetration of the powder particles into the area of
Mikro-Bogen-Entladung erfolgt eine starke Erhöhung des Stroms, mittels der Vergrößerung der Elektronen- Leitfähigkeit.Micro-arc discharge causes a large increase in the current, by increasing the electron conductivity.
Das gewährleistet das Durchschmelzen des Überzugs in der ganzen Tiefe und seine hohe Ad- häsion. Aus diesem Grund wird sparsamerer Verbrauch an Elektroenergie ermöglicht.This ensures that the coating melts through the entire depth and its high adhesion. For this reason, more economical consumption of electrical energy is made possible.
Bei der Prozeßführung entfällt auf den lokalen Stellen der Werkstücke die Notwendigkeit zur Isolation aller Teile, die der Bearbeitung nicht unterliegen.When carrying out the process, the local places on the workpieces eliminate the need to isolate all parts that are not subject to processing.
Auf diese Art und Weise wird die Technologie der Prozeßführung deutlich vereinfacht. Folglich ist die erklärte Methode rentabler, einfacher, und die zu fertigenden Erzeugnisse haben erhöhte Qualitäten.In this way, the technology of process control is significantly simplified. As a result, the method explained is more profitable, simpler and the products to be manufactured are of higher quality.
Die Ergebnisse der durchgeführten Versuche sind in den Tabellen 1 und 2 geführt.The results of the tests carried out are shown in Tables 1 and 2.
Aus den Tabellen ist ersichtlich, daß die zweckmäßigste Entfernung vom Düsenelement bis zu den bearbeiteten Oberflächen der Werkstücke 5-15 mm beträgt.From the tables it can be seen that the most appropriate distance from the nozzle element to the machined surfaces of the workpieces is 5-15 mm.
Beispiel 1 : Das Werkstück wird auf einem elektromechanischen Dreher (ist nicht gezeigt) installiert und in Gang gebracht. Die alkalische Lösung wird von selbst (oder zwangsläufig) auf die zu bearbeitende Oberfläche des Werkstücks durch das Düsenelement gerichtet.Example 1: The workpiece is installed and started on an electromechanical lathe (not shown). The alkaline solution is automatically (or inevitably) directed onto the surface of the workpiece to be machined by the nozzle element.
Zwischen dem Werkstück und der Düse wird Spannung angelegt. Der Schluß des elektrischen Stromkreises Kathode- Anode geht durch den auslaufenden Strahl der Lösung. Die Lösung kann gleichzeitig durch eine oder mehrere Düsen gegeben werden, in Abhängigkeit von derVoltage is applied between the workpiece and the nozzle. The end of the cathode-anode electrical circuit passes through the emerging beam of the solution. The solution can be given simultaneously through one or more nozzles, depending on the
Anzahl von gleichzeitig zu bearbeitenden Stellen der Werkstücke.Number of workpieces to be machined simultaneously.
Für die Realisierung des Elektrophoreseprozesses kann die Lösung die hinsichtlich der chemischen Zusammensetzung notwendigen Ultra-Dispers-Pulver enthalten. Die konstante Kon- zentration des Pulvers in der Lösung wird dadurch aufrechterhalten, daß Pulver durch die
Pulver- Dosiereinrichtung zugegeben werden kann.For the implementation of the electrophoresis process, the solution can contain the ultra-disperse powders necessary with regard to the chemical composition. The constant concentration of the powder in the solution is maintained in that powder through the Powder dosing device can be added.
Beispiel 2: Es wird gefordert, auf einem flachen Werkstück (Platte) aus der Legierung AlMg2 einen verschleißfesten dekorativen Überzug auf dem rechtwinkeligen Teil zu bekom- men. Für die Lösung dieser Aufgabe wurde der isolierende Konduktor (Leiter) mit der Öffnung hinsichtlich des rechtwinkeligen Teils gefertigt. Das Düsenelement für die Zuführung der alkalischen Lösung wird in 10 mm Abstand von der zu bearbeitenden Oberfläche plaziert, und auf dem Mechanismus für die Verschiebung des Düsenelements fest verankert. Die Verstellung wurde parallel zu den bearbeitenden Oberfläche mit unterschiedlichen Geschwindig- keiten, die in der Tabelle 2 angegeben wurden, realisiert. Der Durchmesser der Austrittsöffnung der Düse ist deutlich weniger als die Breite des zu bearbeitenden Teils. Deshalb wird die Düse auf einem Durchgang über die Länge des Teils bewegt, dann über die Breite in der Entfernung von 0,9 des Durchmessers der Düse, versetzt wieder über die Länge des Teils.Example 2: It is required to get a wear-resistant decorative coating on the right-angled part on a flat workpiece (plate) made of the alloy AlMg 2 . To solve this task, the insulating conductor (conductor) with the opening with respect to the rectangular part was manufactured. The nozzle element for the supply of the alkaline solution is placed at a distance of 10 mm from the surface to be machined and firmly anchored on the mechanism for the displacement of the nozzle element. The adjustment was made parallel to the processing surface with different speeds, which were given in table 2. The diameter of the outlet opening of the nozzle is significantly less than the width of the part to be machined. Therefore, the nozzle is moved in one pass along the length of the part, then across the width at a distance of 0.9 from the diameter of the nozzle, again offset across the length of the part.
Das betreffende Beispiel zeigt die Möglichkeit zum Erhalt des Überzugs auf einer einzelnenThe example in question shows the possibility of obtaining the coating on a single one
Stelle des Erzeugnisses bei der aufeinander folgenden Verschiebung des Düsenelements mit einer Geschwindigkeit von bis zu 25 mm/min innerhalb des isolierenden Konduktors (Leiters).Place the product during the successive displacement of the nozzle element at a speed of up to 25 mm / min within the insulating conductor (conductor).
Die analogen optimalen Bereiche bekam man bei der Mikro-Bogen-Oxidation von Titanlegierung.The analog optimal ranges were obtained in the micro-arc oxidation of titanium alloy.
Die auf diese Art und Weise vorliegende Methode der Fertigung der Erzeugnisse erhöht die Qualität der Erzeugnisse und die Arbeitsproduktivität.The method of manufacturing the products in this way increases the quality of the products and the labor productivity.
Das erfindungsgemäße Verfahren kann selbstverständlich auch auf andere Werkstoffe, z.B. Metalle bzw. Legierungen allgemein, angewandt werden, sofern zwischen diesen und der Düse ein Stromkreis geschlossen werden kann. Erforderlichenfalls kann dies durch eine elektrisch leitfähige Beschichtung des Werkstückes erfolgen.The method according to the invention can of course also be applied to other materials, e.g. Metals or alloys in general, provided that a circuit can be closed between them and the nozzle. If necessary, this can be done by an electrically conductive coating of the workpiece.
Industrielle Anwendbarkeit: Die Erfindung kann z.B. bei der Fertigung der Erzeugnisse verwendet werden, die aus Ventilmetallen und ihren Legierungen hergestellt wurden.
Tabelle 1:Industrial Applicability: The invention can be used, for example, in the manufacture of products made from valve metals and their alloys. Table 1:
Tabelle 2:Table 2:
Claims
1. Verfahren zur Beschichtung von Erzeugnissen, wie z.B. Werkstücken, insbesondere aus Ventilmetallen bzw. deren Legierungen, durch Mikro-Bogen-Oxidation oder Elek- trophorese in Anwesenheit von zumindest einem in eine alkalische Lösung eingetragenen1. Process for coating products such as Workpieces, in particular made of valve metals or their alloys, by micro-arc oxidation or electrophoresis in the presence of at least one which has been introduced into an alkaline solution
Zusatz, dadurch gekennzeichnet, daß ein Düsenelement vor dem Auftragen der Beschichtung in der Entfernung von 5-15 mm von der Zone der zu bearbeitenden Oberfläche des Werkstücks angebracht wird, wobei der Düsenquerschnitt wird Abhängigkeit von der Geometrie des zu bearbeitenden Teils der Werkstückoberfläche ausgewählt wird, und durch Zuführen der alkalischen Lösung durch das Düsenelement ein elektrischer Stromkreis Kathode - Anode geschlossen wird durch den ununterbrochenen und zwangs-zielgerichteten und/oder von selbst auslaufenden Lösungsstrahl zur Vermeidung einer zusätzlichen Kühlung der Werkstük- ke und für die Gewährleistung des Durchschmelzens des Überzugs in seiner ganzen Tiefe und wobei als Zusätze die pulverförmige Komponenten oder die hinsichtlich der chemischen Zu- sammensetzung notwendigen Ultra-Dispers-Pulver verwendet werden.Additive, characterized in that a nozzle element is applied before the application of the coating at a distance of 5-15 mm from the zone of the surface of the workpiece to be machined, the nozzle cross-section being selected depending on the geometry of the part of the workpiece surface to be machined, and by supplying the alkaline solution through the nozzle element, an electrical circuit cathode - anode is closed by the continuous and positively targeted and / or self-draining solution jet to avoid additional cooling of the workpieces and to ensure the melting of the coating in it whole depth and the additives used are the powdery components or the ultra-disperse powders necessary with regard to the chemical composition.
2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Düsenelement bei einer vorübergehenden Isolation von einzelnen Stellen der Werkstücke mit einer Geschwindigkeit von nicht mehr als 25 mm/min konsequent entlang der ganzen zu bearbeitenden Ober- fläche des Werkstücks der komplizierten Konfiguration bewegt wird.2. The method according to claim 1, characterized in that the nozzle element is moved with a temporary isolation of individual parts of the workpieces at a speed of not more than 25 mm / min consistently along the entire surface to be machined of the workpiece of the complicated configuration.
3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß als Ventilmetalle AI, Ti, und als ihre Legierungen Duraluminium 1, Duraluminium 16Hart, Aluminium Magnesium, AlMn (Aluminium Mangan)-Legierungen auf Titanbasis, A1V (Aluminium Va- nadium)-Legierangen auf Titanbasis, verwendet werden.3. The method according to claim 1 or 2, characterized in that as valve metals AI, Ti, and as their alloys duralumin 1, duralumin 16 hard, aluminum magnesium, AlMn (aluminum manganese) alloys based on titanium, A1V (aluminum vanadium) - Titanium-based alloy oranges can be used.
4. Verfahren nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß als pulverförmige Komponenten AI, Ti, Al2O3, TiO2, Aluminiumalaun und als Ultra-Dispersions-Pulver - AI, Ti, und Mg verwendet werden.4. The method according to one or more of the preceding claims, characterized in that Al, Ti, Al 2 O 3 , TiO 2 , aluminum alum and as ultra-dispersion powder - Al, Ti, and Mg are used as powdery components.
5. Verfahren nach einem oder mehreren der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das Erzeugnis mit einer leitfähigen Schicht versehen wird, insbesondere in jenen Oberflächenbereichen, die von der Düse überstrichen werden. 5. The method according to one or more of the preceding claims, characterized in that the product is provided with a conductive layer, in particular in those surface areas which are swept by the nozzle.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SK1820-2002A SK18202002A3 (en) | 2000-06-21 | 2001-01-22 | Method for coating products |
| CA002411825A CA2411825A1 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
| US10/311,809 US20040026247A1 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
| AU2001228172A AU2001228172A1 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
| DE50112162T DE50112162D1 (en) | 2000-06-21 | 2001-01-22 | METHOD FOR PRODUCING PRODUCTS |
| EP01984036A EP1292725B1 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
| HU0301662A HUP0301662A2 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
| BR0111884-6A BR0111884A (en) | 2000-06-21 | 2001-01-22 | Product Manufacturing Procedure |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2000115910/12A RU2166434C1 (en) | 2000-06-21 | 2000-06-21 | Article manufacture method |
| RU2000115910 | 2000-06-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2001098562A1 true WO2001098562A1 (en) | 2001-12-27 |
Family
ID=20236443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/AT2001/000015 WO2001098562A1 (en) | 2000-06-21 | 2001-01-22 | Method for manufacturing products |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20040026247A1 (en) |
| EP (1) | EP1292725B1 (en) |
| AT (1) | ATE356232T1 (en) |
| AU (1) | AU2001228172A1 (en) |
| CA (1) | CA2411825A1 (en) |
| DE (1) | DE50112162D1 (en) |
| HU (1) | HUP0301662A2 (en) |
| RU (1) | RU2166434C1 (en) |
| SK (1) | SK18202002A3 (en) |
| WO (1) | WO2001098562A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8277626B2 (en) * | 2010-06-11 | 2012-10-02 | Ppg Industries Ohio, Inc. | Method for depositing an electrodepositable coating composition onto a substrate using a plurality of liquid streams |
| CN103233219B (en) * | 2013-03-22 | 2015-06-03 | 常州大学 | Metal TiN ceramic coating preparation process method |
| CN110904488B (en) * | 2019-12-09 | 2021-08-10 | 湖南湘投金天科技集团有限责任公司 | Micro-arc oxidation method and titanium alloy structural part obtained by adopting same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7001486A (en) * | 1970-02-03 | 1971-08-05 | ||
| US4107016A (en) * | 1976-06-07 | 1978-08-15 | Standard T. Chemical Company, Inc. | Method and apparatus for electro-phorectic coating |
| US5720866A (en) * | 1996-06-14 | 1998-02-24 | Ara Coating, Inc. | Method for forming coatings by electrolyte discharge and coatings formed thereby |
-
2000
- 2000-06-21 RU RU2000115910/12A patent/RU2166434C1/en not_active IP Right Cessation
-
2001
- 2001-01-22 AT AT01984036T patent/ATE356232T1/en not_active IP Right Cessation
- 2001-01-22 CA CA002411825A patent/CA2411825A1/en not_active Abandoned
- 2001-01-22 AU AU2001228172A patent/AU2001228172A1/en not_active Abandoned
- 2001-01-22 HU HU0301662A patent/HUP0301662A2/en unknown
- 2001-01-22 DE DE50112162T patent/DE50112162D1/en not_active Expired - Fee Related
- 2001-01-22 SK SK1820-2002A patent/SK18202002A3/en unknown
- 2001-01-22 WO PCT/AT2001/000015 patent/WO2001098562A1/en active IP Right Grant
- 2001-01-22 US US10/311,809 patent/US20040026247A1/en not_active Abandoned
- 2001-01-22 EP EP01984036A patent/EP1292725B1/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7001486A (en) * | 1970-02-03 | 1971-08-05 | ||
| US4107016A (en) * | 1976-06-07 | 1978-08-15 | Standard T. Chemical Company, Inc. | Method and apparatus for electro-phorectic coating |
| US5720866A (en) * | 1996-06-14 | 1998-02-24 | Ara Coating, Inc. | Method for forming coatings by electrolyte discharge and coatings formed thereby |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1292725A1 (en) | 2003-03-19 |
| RU2166434C1 (en) | 2001-05-10 |
| ATE356232T1 (en) | 2007-03-15 |
| EP1292725B1 (en) | 2007-03-07 |
| US20040026247A1 (en) | 2004-02-12 |
| CA2411825A1 (en) | 2001-12-27 |
| DE50112162D1 (en) | 2007-04-19 |
| SK18202002A3 (en) | 2003-09-11 |
| AU2001228172A1 (en) | 2002-01-02 |
| HUP0301662A2 (en) | 2003-08-28 |
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