WO2001076734A1 - Procede de preparation d'un catalyseur fischer-tropsch - Google Patents

Procede de preparation d'un catalyseur fischer-tropsch Download PDF

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Publication number
WO2001076734A1
WO2001076734A1 PCT/US2000/010457 US0010457W WO0176734A1 WO 2001076734 A1 WO2001076734 A1 WO 2001076734A1 US 0010457 W US0010457 W US 0010457W WO 0176734 A1 WO0176734 A1 WO 0176734A1
Authority
WO
WIPO (PCT)
Prior art keywords
impregnated
catalyst
cobalt
acid
process according
Prior art date
Application number
PCT/US2000/010457
Other languages
English (en)
Inventor
Gyanesh P. Khare
Original Assignee
Phillips Petroleum Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Company filed Critical Phillips Petroleum Company
Priority to PCT/US2000/010457 priority Critical patent/WO2001076734A1/fr
Priority to AU2000244691A priority patent/AU2000244691A1/en
Publication of WO2001076734A1 publication Critical patent/WO2001076734A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Definitions

  • This invention relates to Fischer- Tropsch catalysts, and more
  • Synthesis gas (typically a mixture of carbon monoxide and
  • a particulate carrier is typically
  • an active metal particularly cobalt, iron, manganese, or
  • the invention provides a novel process for preparing a Fischer-ray
  • Tropsch catalyst comprising the steps of: impregnating a particulate carrier with
  • an active metal preferably selected from cobalt, iron, manganese, nickel
  • particulate carrier can be an oxide of silicon, aluminum, titanium, zinc, zirconium, or magnesium; zeolites; or a mixture thereof.
  • Alumina is most
  • Suitable alpha-hydroxy carboxylic acids include citric, glycolic,
  • the particulate carrier can be sprayed with the solution while
  • the acid impregnated ca ⁇ ier is then dried, preferably in air, at a
  • the drying temperature is preferably about 100-275°C.
  • present in the acid impregnated carrier is preferably in the range of about 2-20
  • the acid impregnated and dried carrier can be impregnated with
  • the most prefened active metal is cobalt, and cobalt(II) nitrate hexahydrate is a preferred cobalt compound.
  • the particulate carrier is cobalt, and cobalt(II) nitrate hexahydrate is a preferred cobalt compound.
  • the particulate carrier is cobalt, and cobalt(II) nitrate hexahydrate is a preferred cobalt compound.
  • the particulate carrier is cobalt, and cobalt(II) nitrate hexahydrate.
  • promoter metals are examples of promoter metals.
  • molybdenum molybdenum, wolfram, lanthanum, palladium, praseodymium, neodymium or
  • Preferred promoters are selected from platinum, rhodium, ruthenium, and
  • Impregnation of the particulate carrier with the promoter metals is
  • the promoter metal compound is soluble in the above mentioned
  • Suitable compounds include
  • impregnated carrier is preferably dried in flowing air at a temperature of
  • a suitable temperature typically in the range of about 200-
  • Calcination is preferably carried out in a flowing air environment for a
  • the active metal in the finished catalyst can be, by way of
  • the particulate carrier could also be
  • a citric acid solution was prepared by dissolving 5.0 g citric acid in
  • impregnated alumina was then removed from the oven and allowed to cool.
  • alumina was further impregnated with cobalt and platinum and then heated a
  • a particulate alumina carrier obtained from Condea Chemie,
  • citric acid solution was prepared by dissolving 5.0 g citric acid in 25 ml of
  • the citric acid solution was sprayed on the alumina while the
  • impregnated alumina was then removed from the oven and allowed to cool.
  • alumina was further impregnated with cobalt and platinum and then heated a
  • a Catalyst was prepared in accordance with the process described
  • impregnated carrier was calcined at 230°C for 2 hours in an air flow of 1.5 1, min.
  • the resultant calcined sample was re-slurried in a solution that was
  • impregnated carrier was calcined at 230°C for 2 hours in an air flow of 1.5
  • a particulate alumina earner obtained from Condea Chemie,
  • the reactor used in this catalyst test was a 300 cc stirred tank
  • the stining speed was maintained at 1200 rpm during all tests,
  • the catalyst was
  • Catalyst Catalyst A Catalyst B 1 Catalyst C Catalyst D
  • the data for Catalyst B is an average of two runs except for the Co content where only one of the two runs was analyzed for Co content.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un procédé de préparation d'un catalyseur Fischer-Tropsch, consistant a) à imprégner un support particulier avec un acide carboxylique alpha-hydroxylé ; b) à imprégner le support enduit d'acide avec un métal actif sélectionné parmi cobalt, fer, manganèse et nickel ; c) et à calciner le support ainsi imprégné pour produire le catalyseur.
PCT/US2000/010457 2000-04-07 2000-04-18 Procede de preparation d'un catalyseur fischer-tropsch WO2001076734A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/US2000/010457 WO2001076734A1 (fr) 2000-04-07 2000-04-18 Procede de preparation d'un catalyseur fischer-tropsch
AU2000244691A AU2000244691A1 (en) 2000-04-07 2000-04-18 Process for preparing fischer-tropsch catalyst

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US54468500A 2000-04-07 2000-04-07
US09/544,685 2000-04-07
PCT/US2000/010457 WO2001076734A1 (fr) 2000-04-07 2000-04-18 Procede de preparation d'un catalyseur fischer-tropsch

Publications (1)

Publication Number Publication Date
WO2001076734A1 true WO2001076734A1 (fr) 2001-10-18

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ID=26680202

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PCT/US2000/010457 WO2001076734A1 (fr) 2000-04-07 2000-04-18 Procede de preparation d'un catalyseur fischer-tropsch

Country Status (1)

Country Link
WO (1) WO2001076734A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7147769B2 (en) 2003-08-25 2006-12-12 Conocophillips Company Desulfurization and novel methods for same
US7807602B2 (en) 2006-11-22 2010-10-05 Shell Oil Company Process for hydrocarbon synthesis
WO2010097754A3 (fr) * 2009-02-26 2011-05-26 Sasol Technology (Proprietary) Limited Catalyseurs
EP2341120A1 (fr) 2009-12-29 2011-07-06 Shell Internationale Research Maatschappij B.V. Procédé de revêtement pour catalyseurs structurés
WO2011080198A2 (fr) 2009-12-29 2011-07-07 Shell Internationale Research Maatschappij B.V. Procédé de couchage pour catalyseurs structurés
WO2011080196A1 (fr) 2009-12-28 2011-07-07 Shell Internationale Research Maatschappij B.V. Réacteur à système de distribution de gaz au fond
US8003564B2 (en) 2005-12-16 2011-08-23 Shell Oil Company Process for preparing a hydrocarbon synthesis catalyst
EP2407237A1 (fr) * 2010-07-16 2012-01-18 IFP Energies nouvelles Catalyseur à base de cobalt sur support silice-alumine pour la synthèse fischer-tropsch
US8394864B2 (en) 2008-04-15 2013-03-12 Sasol Technology (Proprietary) Limited Catalysts
MD4294C1 (ro) * 2013-02-06 2015-02-28 Государственный Университет Молд0 Procedeu de obţinere a nanocompozitelor pe bază de nanotuburi din dioxid de titan şi instalaţie pentru realizarea acestuia
US9192921B1 (en) 2014-09-10 2015-11-24 Chevron U.S.A. Inc. Support for Fischer-Tropsch catalyst having improved activity
US9687826B2 (en) 2014-09-10 2017-06-27 Chevron U.S.A. Inc. Support for fischer-tropsch catalyst having improved activity
WO2018078069A1 (fr) 2016-10-27 2018-05-03 Shell Internationale Research Maatschappij B.V. Corps de catalyseur fischer-tropsch
WO2018083172A1 (fr) 2016-11-07 2018-05-11 Shell Internationale Research Maatschappij B.V. Procédé de production d'hydrocarbures
US10399061B2 (en) 2014-03-21 2019-09-03 Shell Oil Company Catalyst

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4409131A (en) * 1982-02-22 1983-10-11 Maine Preparation of CoMo and NiMo catalyst using cobalt or nickel complexes that are stable in basic solution
US4568450A (en) * 1982-08-19 1986-02-04 Union Oil Company Of California Hydrocarbon conversion process
US4568449A (en) * 1982-08-16 1986-02-04 Union Oil Company Of California Hydrotreating catalyst and process
US5783607A (en) * 1996-04-09 1998-07-21 Institut Francais Du Petrole Process for converting synthesis gas in the presence of a catalyst based on cobalt and titanium
US5856365A (en) * 1995-08-04 1999-01-05 Agip Petroli S.P.A. Process for the preparation of a catalyst useful for the conversion of synthesis gas
US5863856A (en) * 1997-04-22 1999-01-26 Exxon Research And Engineering Company Preparation of high activity catalysts the catalysts and their use

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4409131A (en) * 1982-02-22 1983-10-11 Maine Preparation of CoMo and NiMo catalyst using cobalt or nickel complexes that are stable in basic solution
US4568449A (en) * 1982-08-16 1986-02-04 Union Oil Company Of California Hydrotreating catalyst and process
US4568450A (en) * 1982-08-19 1986-02-04 Union Oil Company Of California Hydrocarbon conversion process
US5856365A (en) * 1995-08-04 1999-01-05 Agip Petroli S.P.A. Process for the preparation of a catalyst useful for the conversion of synthesis gas
US5783607A (en) * 1996-04-09 1998-07-21 Institut Francais Du Petrole Process for converting synthesis gas in the presence of a catalyst based on cobalt and titanium
US5863856A (en) * 1997-04-22 1999-01-26 Exxon Research And Engineering Company Preparation of high activity catalysts the catalysts and their use

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7147769B2 (en) 2003-08-25 2006-12-12 Conocophillips Company Desulfurization and novel methods for same
US8003564B2 (en) 2005-12-16 2011-08-23 Shell Oil Company Process for preparing a hydrocarbon synthesis catalyst
US7807602B2 (en) 2006-11-22 2010-10-05 Shell Oil Company Process for hydrocarbon synthesis
US8394864B2 (en) 2008-04-15 2013-03-12 Sasol Technology (Proprietary) Limited Catalysts
WO2010097754A3 (fr) * 2009-02-26 2011-05-26 Sasol Technology (Proprietary) Limited Catalyseurs
TWI486210B (zh) * 2009-02-26 2015-06-01 Sasol Tech Pty Ltd 催化劑
US8841229B2 (en) 2009-02-26 2014-09-23 Sasol Technology (Proprietary) Limited Process for the preparation of fischer-tropsche catalysts and their use
RU2517700C2 (ru) * 2009-02-26 2014-05-27 Сэсол Текнолоджи (Проприетери) Лимитед Катализаторы
WO2011080196A1 (fr) 2009-12-28 2011-07-07 Shell Internationale Research Maatschappij B.V. Réacteur à système de distribution de gaz au fond
US9738835B2 (en) 2009-12-28 2017-08-22 Shell Oil Company Process for performing a fischer tropsch reaction
WO2011080198A2 (fr) 2009-12-29 2011-07-07 Shell Internationale Research Maatschappij B.V. Procédé de couchage pour catalyseurs structurés
EP2341120A1 (fr) 2009-12-29 2011-07-06 Shell Internationale Research Maatschappij B.V. Procédé de revêtement pour catalyseurs structurés
FR2962664A1 (fr) * 2010-07-16 2012-01-20 IFP Energies Nouvelles Catalyseur a base de cobalt sur support silice-alumine pour la synthese fischer-tropsch
EP2407237A1 (fr) * 2010-07-16 2012-01-18 IFP Energies nouvelles Catalyseur à base de cobalt sur support silice-alumine pour la synthèse fischer-tropsch
CN102380386A (zh) * 2010-07-16 2012-03-21 恩尼有限公司 用于费托合成的在二氧化硅-氧化铝载体上的钴基催化剂
MD4294C1 (ro) * 2013-02-06 2015-02-28 Государственный Университет Молд0 Procedeu de obţinere a nanocompozitelor pe bază de nanotuburi din dioxid de titan şi instalaţie pentru realizarea acestuia
US10399061B2 (en) 2014-03-21 2019-09-03 Shell Oil Company Catalyst
US9192921B1 (en) 2014-09-10 2015-11-24 Chevron U.S.A. Inc. Support for Fischer-Tropsch catalyst having improved activity
US9687826B2 (en) 2014-09-10 2017-06-27 Chevron U.S.A. Inc. Support for fischer-tropsch catalyst having improved activity
WO2018078069A1 (fr) 2016-10-27 2018-05-03 Shell Internationale Research Maatschappij B.V. Corps de catalyseur fischer-tropsch
US11273429B2 (en) 2016-10-27 2022-03-15 Shell Oil Company Fischer-Tropsch catalyst body
WO2018083172A1 (fr) 2016-11-07 2018-05-11 Shell Internationale Research Maatschappij B.V. Procédé de production d'hydrocarbures
US10597585B2 (en) 2016-11-07 2020-03-24 Shell Oil Company Method of producing hydrocarbons

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