Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
  • B01D3/14—Fractional distillation or use of a fractionation or rectification column
  • B01D3/16—Fractionating columns in which vapour bubbles through liquid
  • B01D3/22—Fractionating columns in which vapour bubbles through liquid with horizontal sieve plates or grids; Construction of sieve plates or grids
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
  • B01D3/14—Fractional distillation or use of a fractionation or rectification column
  • B01D3/16—Fractionating columns in which vapour bubbles through liquid
  • B01D3/18—Fractionating columns in which vapour bubbles through liquid with horizontal bubble plates
  • B01D3/20—Bubble caps; Risers for vapour; Discharge pipes for liquid
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
  • B01D3/14—Fractional distillation or use of a fractionation or rectification column
  • B01D3/16—Fractionating columns in which vapour bubbles through liquid
  • B01D3/24—Fractionating columns in which vapour bubbles through liquid with sloping plates or elements mounted stepwise

Definitions

• the invention is directed to an improved gas liquid contacting tray comprising a bubble area and a downcomer opening.
• Such trays are well known as distillation column internals as described in Distillation Design, Henry Z. Kister, McGraw-Hill Inc., 1992, pages 259-267.
• a maximum load will be observed. Higher loads will result in that the column fails to function as a liquid-gas contactor or separator due to a phenomena known as flooding.
• flooding is described as excessive accumulation of liquid inside the column.
• the well known flooding mechanisms are downcomer back-up, jet flooding and downcomer choking. These mechanisms are described in Distillation Design, Henry Z.
• downcomer back-up is due to a build-up of liquid inside the downcomer causing the liquid to back-up on the tray leading to liquid accumulation on that tray.
• the liquid height in the downcomer is determined by the tray pressure drop, liquid height on the tray and frictional losses in the downcomer and downcomer slot area. Jet flooding or entrainment flooding is caused by a too high gas velocity leading to the entrainment of liquid, either by droplets or froth, to the tray above. The liquid will accumulate and leads to flooding.
• Downcomer choking is caused by a too high aerated liquid velocity in the downcomer.
• US-A-3231251 describes a gas-liquid contacting tray provided with a so-called froth disengaging gas permeable element.
• This element is positioned between downcomer opening and the space above the bubble area which is occupied by froth. The element extends vertically from the weir to the next tray above.
• the disclosed element is a woven or knitted crimped wire mesh. According to the specification the liquid handling capacity of a column provided with such trays is improved.
• a disadvantage of the tray according to US-A-3231251 is that the knitted mesh is sensitive for fouling. Another disadvantage is that such a tray is inherently mechanically unstable. It is probably for this reason that the invention as described in this patent publication of 1966 has not been followed up and commercialised up to the present day.
• FR-A-2046521 discloses a process to contact a gas and liquid in a column provided with trays. Between the contact trays free flowing mixing enhancers are present. These enhancers are solid elements which are present in the froth. In order to avoid that these elements flow to a lower tray via the segmental downcomers a shield is present between the space occupied by the froth and the downcomer opening.
• the problem to be solved by the present invention is to provide a practical non-fouling sensitive gas-liquid contacting tray having an increased froth handling capacity of its downcomer and an increased capacity.
• Gas-liquid contact tray comprising a bubble area and a downcomer opening, wherein on the boundary of the bubble area and downcomer opening a shield is positioned, which shield divides the space above the bubble area, which area is, when in use, occupied by froth, from the space above the downcomer opening and which shield is a plate provided with a plurality of openings.
• the tray according to the invention shows a capacity improvement when compared to a tray not having a shield. Furthermore a practical alternative, which is less sensitive to fouling and having a better mechanical strength, has been found for the knitted meshes as described in US-A-3231251.
• the position of the shield should be such that it interacts with the froth moving from a position above the bubble area to the downcomer opening. The froth will, under normal operation, not extend all the way to the next upper tray. Therefore it is not necessary to have a shield that extends all the way to the next tray above.
• a second advantage is that the shield is fixed to one tray only, making installation of said trays into a column more simple.
• the vertical height of the shield is between 15 and 95% of the tray distance and more preferably between 50 and 80% of the tray distance.
• the tray distance is the distance between two consecutive contact trays in a gas-liquid contacting column provided with the trays according the invention. Suitably this distance is between 0.2-1 m.
• the shield is preferably so positioned that gas moving from the froth upwards to the next upper tray will not have to pass the shield.
• the upper end of the shield may extend above the bubble area such that the angle between the vertical and the plane of the shield is less than 30 degrees. More preferably the shield is in a vertical or in a position wherein the shield covers the downcomer opening. With covering the downcomer opening is meant that the shield extends from the boundary of the bubble area and the downcomer opening to a position above the downcomer opening.
• the angle between the vertical and the plane of the shield above the downcomer is preferably between 0 and 60 degrees and more preferably between
• the shield more preferably covers the total downcomer opening when viewed from above.
• the upper end of the shield will preferably terminate at the column wall.
• the downcomer is a segmental downcomer, wherein its curved downcomer wall section runs along the column wall or is the column wall
• the upper end of the shield will preferably terminate at the column wall.
• the downcomer is a rectangular downcomer having bubble area at both elongated sides it is preferred to position two shields.
• the two shields will extend from its respective longitudinal boundary of bubble area and downcomer opening and meet each other above suitably the centre line of the rectangular downcomer opening.
• the form of the surface of the shield facing the froth flowing towards the shield is not critical. This form may be flat, curved or corrugated. Preferably the form is flat because of its mechanical simplicity.
• the openings in the shield may have any form and can optionally be provided with flow direction means. These flow directing means are positioned such that the liquid flow is directed towards the downcomer.
• the openings have suitably a hydraulic diameter which is at least 0.8 times the Sauter mean diameter of the bubble or droplet in the froth. It has been found that the liquid handling capacity improves when even larger openings are used. This has the additional advantage that the shield becomes less sensitive for fouling.
• the openings therefore have a hydraulic diameter which is at least
• the maximum hydraulic diameter is preferably 100 mm and more preferably 50 mm.
• the Sauter mean diameter is the quotient of the volumetric mean diameter with the surface area mean diameter of the bubble or droplet in the froth (see also Hetsroni G, Handbook of Multiphase systems, Hemisphere publishing corporation 1982, pages 10-105). Depending on the regime above the bubble area in the froth either bubbles or droplets are present.
• the shield can be made from any suitable material, for example plastics, like Teflon, metal, or ceramic.
• An example of a suitable metal is stainless steel.
• the shield is made from a metal plate, preferably stainless steel, provided with openings.
• the net free area of such a shield or otherwise said the area of the openings relative to the shield area is preferably between 25 and 80%.
• the open area may vary as a function of the height of the shield, wherein preferably a smaller open area is present at the upper part of the shield.
• the openings are suitably made by punching, drilling or protruding an opening or by mechanical or laser cutting.
• a most preferred shield is made from expanded metal, because of its availability and simplicity of fabrication. Expanded metal typically has openings in the form of a slit having an elongated length and a shorter height. The slits may for example have a trapezoidal, rhombus shaped or hexagonal form.
• the shield may optionally consist of more than one layer of expanded metal .
• a weir is present on the tray.
• a weir is a device positioned on or about on the boundary of the bubble area and the downcomer opening which ensures that a certain pre-selected amount of liquid is present on the upper surface of the bubble area.
• the height of the weir may be selected from conventional values known for well known designs as exemplified below.
• the shield may suitably be positioned on top of the weir or alongside of the weir.
• the shield and weir can optionally be combined in one shield having no openings at its lower end, in order to maintain a certain pre-selected amount of liquid.
• Existing trays provided with a weir are suitably retrofitted by fixing the shield on top of the existing weir.
• the weir may suitably be inclined towards the direction of the liquid flowing towards the downcomer opening.
• the overflow weir is preferably inclined towards the bubble area, such that an imaginary line, drawn from the top of the overflow weir to the base of the overflow weir, forms an angle ⁇ with the horizontal plane of the tray which is smaller than 80° and more preferably larger than 30°.
• the overflow weir height lies preferably in the range from 25 mm to 1/6 of the height of the tray spacing, wherein tray spacing is the distance between two consecutive contacting trays when placed in a column .
• the shape of the downcomer opening is not critical for the present invention. This shape may for example be circular, rectangular, segmental or square.
• the vertical shape of the downcomer is also not critical for the present invention.
• the downcomer wall may optionally be inclined relative to the vertical axis of the column in which the trays are used.
• the invention can be used for cross-over tray layouts with one downcomer per tray or with trays having more than one downcomer. Cross over trays are for example disclosed in US-A-5895608.
• Downcomer openings in such trays are typically circular, square or rectangular formed. Rectangular formed downcomers have a width which is smaller than its length.
• the rectangular downcomer is preferably provided with an anti-jump baffle vertically positioned in the downcomer opening in the longitudinal direction of the downcomer.
• the anti-jump baffle is positioned along the longitudinal centre in the opening of the downcomer.
• This anti-jump baffle plate preferably extends to between 30 and 80% of the tray spacing above the tray level.
• the lower end of this baffle may extend from tray level to the downcomer lower end.
• the shield preferably extends from the boundary of the bubble area and downcomer opening to the upper part of the anti-jump baffle.
• a shield in combination with a gas-liquid contacting tray having a tray layout as described as follows.
• the layout is such that the tray is divided in two tray sections by a diametrical line, each tray section provided with a row of rectangular downcomers, the downcomers arranged perpendicular to the diametrical line such that the ends of the downcomers of each tray section meet this line in an alternating fashion.
• a segmental downcomer is present in each tray section at the intersection of the diametrical line and the column wall.
• Figure 1 is a cross-sectional view along the longitudinal axis of a distillation column showing the gas-liquid tray according to the invention.
• Figure 2 is a cross-sectional view AA' of the distillation column of Figure 1 showing the gas-liquid tray from above .
• FIG 3 is as Figure 1 except that the shield covers the downcomer opening.
• Figure 4 is a cross-sectional view CC of the distillation column of Figure 3 showing the gas-liquid tray from above .
• Figure 1 shows a single pass gas-liquid contact tray (1) comprising a bubble area (2), a weir (3), a downcomer opening (4) and a liquid receiving area (5) .
• a shield (6) is positioned, which shield, at least partly, divides a space above the bubble area (2) from the space above the downcomer opening (4) and which shield (6) is provided with a plurality of openings.
• Figure 1 also shows a downcomer wall (7) and part of a column (8) .
• the trays (1) in column (8) are axially spaced apart in the column (8). The distance between two trays will be referred to as tray distance.
• the vertical distance between the highest point of shield (6) and the tray (1) is shown as distance (a).
• Figure 2 illustrates the cross-sectional view AA' of the distillation column (8) of Figure 1 showing the gas-liquid tray from above. As shown a plurality of openings (9) is present in the bubble area (2).
• Figure 3 illustrates another preferred embodiment of the invention for a single pass gas-liquid contacting tray (1) wherein the shield (6) is positioned in an inclined plane relative to the vertical. The inclined shield (6) is positioned above the downcomer opening (4) and the upper periphery (10) of the shield runs along the wall of the distillation column (8) thereby effectively dividing the space above the bubble area (2) from the space above the downcomer opening (4) .
• the horizontal base (11) of the shield (6) is positioned on the top of the weir (3) .
• the angle (b) is the angle formed by the shield (5) and the vertical.
• FIG 4 is a cross-sectional view CC of the distillation column (8) of Figure 3 showing the gas-liquid tray from above. Clearly illustrated in this
• Figure is that the upper periphery (10) of the shield (6) runs along the wall of the distillation column (8) .
• the tray according to the invention is preferably used in a gas-liquid contacting column, which column is provided with these trays, axially spaced away from each other.
• Preferred gas-liquid contacting columns are distillation and absorption columns. In absorption processes a downwardly moving liquid is contacted with a upwardly moving gas and one or more components is transferred from the gas to the liquid or vice versa. In a distillation process one or more components are separated from a feed due to differences in their boiling points. In a distillation process the feed is typically supplied to an intermediate position in the column, wherein trays are present above and below said inlet position. Such a column is further provided with reboiler, condensation and reflux means. No free flowing solid mixing enhancing elements are present in the froth. Because of the simplicity of the shield it is very easy to install such a shield in an existing distillation column and arrive at a tray according to the invention. In this manner a simple method of increasing the capacity of an existing distillation column is provided for.
• Example 1 The invention shall be illustrated by the following non-limiting examples .
• Example 1 The invention shall be illustrated by the following non-limiting examples .
• Example 1 The invention shall be illustrated by the following non-limiting examples .
• a gas-liquid contacting column provided with normal sieve trays, a downcomer opening and a weir was provided with a vertical shield made of expanded metal wherein the hydraulic diameter of the openings was 0.0026 m.
• the Sauter mean diameter of the droplets in the froth was about 6 mm.
• the height of the shield was 80% of the tray distance. Water and air were contacted. At an air load of
• Example 1 was repeated except that no shield was present. At an air load of 245 mVh it was observed that the maximum attainable water load due to choking was 8.3 m 3 /h.
• Example 2
• Example 1 was repeated except that the shield was now positioned in an inclined plane relative to the tray as shown in Figure 3 and the downcomer opening area was three times as high.
• the upper periphery of the shield followed the wall of the column.
• the angle of the shield with the vertical was 10 degrees.
• Example 2 was repeated except that no shield was present. At an air load of 245 mVh it was observed that the maximum attainable water load due to choking was 18.8 m 3 /hour.
• Example 3
• Example 2 was repeated except that the hydraulic diameter of the openings in the shield was 0.0057 m. At an air load of 245 m 3 /h it was observed that the maximum attainable water load was greater than 28 m-Vh.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
• Physical Or Chemical Processes And Apparatus (AREA)
• Gas Separation By Absorption (AREA)

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Applications Claiming Priority (2)

Publications (1)

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Citations (2)

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• 2001
  • 2001-02-14 AU AU2001231751A patent/AU2001231751A1/en not_active Abandoned
  • 2001-02-14 WO PCT/EP2001/001658 patent/WO2001060484A1/en active Application Filing
  • 2001-02-16 AU AU44148/01A patent/AU770266B2/en not_active Ceased
  • 2001-02-16 JP JP2001559578A patent/JP2003522630A/ja not_active Withdrawn
  • 2001-02-16 CA CA002399687A patent/CA2399687A1/en not_active Abandoned
  • 2001-02-16 WO PCT/EP2001/001809 patent/WO2001060487A1/en not_active Application Discontinuation
  • 2001-02-16 EP EP01917004A patent/EP1257336A1/en not_active Withdrawn
  • 2001-02-16 US US10/204,080 patent/US20030011084A1/en not_active Abandoned
  • 2001-02-16 BR BR0108420-8A patent/BR0108420A/pt not_active IP Right Cessation
  • 2001-02-16 MX MXPA02007936A patent/MXPA02007936A/es not_active Application Discontinuation
  • 2001-02-16 CN CN01805108A patent/CN1400917A/zh active Pending
  • 2001-02-16 KR KR1020027010485A patent/KR20020077442A/ko not_active Application Discontinuation
  • 2001-02-16 RU RU2002124585/15A patent/RU2002124585A/ru not_active Application Discontinuation
• 2002
  • 2002-08-16 ZA ZA200206583A patent/ZA200206583B/en unknown

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