WO2001058998A1 - Agent de demoulage a base d'acide gras et de cire polyolefinique - Google Patents

Agent de demoulage a base d'acide gras et de cire polyolefinique Download PDF

Info

Publication number
WO2001058998A1
WO2001058998A1 PCT/US2000/003496 US0003496W WO0158998A1 WO 2001058998 A1 WO2001058998 A1 WO 2001058998A1 US 0003496 W US0003496 W US 0003496W WO 0158998 A1 WO0158998 A1 WO 0158998A1
Authority
WO
WIPO (PCT)
Prior art keywords
release agent
fatty acid
wax
polyolefin wax
weight
Prior art date
Application number
PCT/US2000/003496
Other languages
English (en)
Inventor
Christopher J. Moriarty
James A. Yavorsky
Original Assignee
Huntsman International Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman International Llc filed Critical Huntsman International Llc
Priority to MXPA02007710A priority Critical patent/MXPA02007710A/es
Priority to PL00356539A priority patent/PL356539A1/xx
Priority to AU33609/00A priority patent/AU3360900A/en
Priority to CA002397210A priority patent/CA2397210A1/fr
Priority to PCT/US2000/003496 priority patent/WO2001058998A1/fr
Priority to EP00911768A priority patent/EP1268639A1/fr
Priority to BR0017102-6A priority patent/BR0017102A/pt
Priority to ARP010100411A priority patent/AR027326A1/es
Publication of WO2001058998A1 publication Critical patent/WO2001058998A1/fr
Priority to US10/215,427 priority patent/US20030015122A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08—Moulding or pressing
    • B27N3/083—Agents for facilitating separation of moulds from articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60—Releasing, lubricating or separating agents
    • B29C33/62—Releasing, lubricating or separating agents based on polymers or oligomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse

Definitions

  • This invention relates to release agents comprising a blend of fatty acid and polyolefm wax which release agents are useful in processes for binding lignocellulosic material and in particular to such processes utilizing polyisocyanate binders.
  • Organic polyisocyanates are known to be superior binders for use with lignocellulosic material, particularly in the manufacture of sheets or molded bodies such as waferboard, chipboard, fiberboard, plywood, etc.
  • the organic polyisocyanate optionally in the form of a solution, dispersion or aqueous emulsion, is applied to the lignocellulosic material which is then subjected to heat and pressure.
  • Organic polyisocyanates offer many benefits to conventional binder materials in addition to their superior binding qualities. For example, the use of organic polyisocyanates reduces manufacturing downtime by allowing blenders to be cleaned with greater ease. Also the organic polyisocyanates improve process efficiency by allowing pressing to take place at higher moisture levels, thereby increasing throughput without increasing emissions.
  • the organic polyisocyanates provide excellent adhesive properties, they have demonstrated an inherent disadvantage in that they can cause severe sticking of the lignocellulosic material to the metal surfaces of the press plates with which it comes into contact during the pressing operations. Often the final product is damaged during removal from the press and significant time is required to remove the lignocellulosic material from the surfaces of the press plates.
  • binding agents such as phenol formaldehyde
  • phenol formaldehyde are often used in the faces of the boards to be produced, since such binding agents generally cause less sticking of the lignocellulosic material to the surfaces of the press plates.
  • barriers such as phenolic impregnated paper, have been used to make products commercially.
  • the phenolic paper is used to cover the strands of lignocellulosic material so that no polyisocyanate coated strands come into contact with the hot press platens. After pressing, the paper is adhered to the panel and becomes part of the final product.
  • such solutions are viable only for very high grade products, such as siding and concrete forms.
  • the dominant, commercially used external release agent is based upon fatty acid salts (e.g., potassium oleate, sodium oleate, etc.).
  • fatty acid salts e.g., potassium oleate, sodium oleate, etc.
  • the press temperatures can be lowered in order to significantly eliminate the color problem; however, the resultant decrease in efficiency of the pressing operations is commercially unacceptable.
  • wax release agents in the binding of lignocellulosic material with polyisocyanates is described in, for example, EP 46014 and EP 57502.
  • the wax is preferably applied in the form of an aqueous dispersion, preferably a dispersion in an aqueous emulsion of the polyisocyanate. Montan wax is preferably used.
  • the present invention is related to a release agent useful for producing lignocellulosic bodies which release agent comprises a blend of fatty acid and polyolefm wax.
  • the invention is also related to a process for the production of sheets or molded bodies from lignocellulosic materials utilizing an organic polyisocyanate binder material and a release agent which comprises a blend of fatty acid and polyolefm wax.
  • the process includes the steps of treating the lignocellulosic material with the fatty acid and polyolefm wax release agent and the organic polyisocyanate binder material, and pressing the treated lignocellulosic material to form the sheets or molded bodies.
  • Figure 1 is a graph which demonstrates the release agent build up of various release agents according to Example 5.
  • Figure 2 is a graph demonstrating the effectiveness of the release agents according to Example 6 at various pressing temperatures.
  • the release agent of the invention comprises a blend of fatty acid and polyolefm wax.
  • the blend can be in neat form, emulsifiable form, or in emulsified form.
  • polyolefin wax is used in neat form.
  • the polyolefm wax can be dispersible in an aqueous medium to form an aqueous emulsion.
  • the polyolefms can be functionalized in order to improve the dispersability in aqueous medium.
  • the polyolefms can be functionalized by means of oxidation which has the added benefit of improving the release properties of the polyolefin.
  • the polyolefin wax is selected from oxidized polyethylene waxes and oxidized polypropylene waxes.
  • the oxidized polyethylene waxes can be, for example, oxidized homopolymers of polyethylene or copolymers of polyethylene and ⁇ , ⁇ -unsaturated carboxylic acids, such as acrylic acid.
  • the oxidized polyethylene wax may have a melting temperature in the range of about 80 to 120°C, a viscosity in the range of about 25 to 200 cPs at 140°C and a hardness in the range of about 0.5 to 98 dmm.
  • the number average molecular weight of the oxidized polyethylene wax is preferably in the range of about 500 to 5000, most preferably about 500 to 1500.
  • Suitable oxidized polyethylene wax which can be used in the present invention include, for example, AC 629, 655, 656, 680, and 6702, all available from Allied Signal.
  • oxidized polypropylene waxes useful in the present invention include, for example, oxidized homopolymers of polypropylene which may have a softening point of about 100 to 170°C, a penetration hardness of about 0.1 to 5 dmm and a number average molecular weight of about 3000 to 30,000 and preferably about 4000 to about 12,000.
  • Suitable oxidized polypropylene wax which can be used in the present invention include, for example, Epolenel4, 15, 20, and 43, all available from Eastman Chemicals.
  • the oxidized polyolefin wax is an emulsifiable, non-aqueous blend.
  • the emulsifiable, non-aqueous blend of polyolefin wax can be made by any suitable method, including those well known to the skilled artisan, for example, by simply stirring the polyolefm wax in a vessel heated to a temperature above the melting point of the wax.
  • the aqueous emulsion of the polyolefin wax can be made by any suitable method, such as by high shear mixing.
  • the emulsion will preferably further comprise an emulsifier to improve the capability of the polyolefin with the aqueous medium.
  • Suitable emulsifiers used can either be anionic, non- ionic, or cationic emulsifiers, with anionic emulsifiers being preferred when the wax emulsion is used as an external release agent and non-ionic emulsifiers being preferred when the wax emulsion is used as an internal release agent.
  • the emulsifiers can be used in an amount of about 1 to about 10 and preferably about 4 to about 7% by weight of the total emulsion.
  • anionic emulsifiers include the carboxylates, sulphates, sulphonates and phosphates, such as alkylbenzene derivatives; alkyl ether carboxylic acids and salts, e.g., sodium alkyl ether carboxylates; alkyl sulphosuccinates, e.g., di-sodium monoalkylsulphosuccinate, sodium di-alkyl sulphosuccinates and disodium monoalkyl ethoxy sulphosuccinates; alpha olefin sulphonates; aromatic hydrocarbon suphohic acids, e.g., benzene sulphonic acid blends, cumene sulphonic acid, phenol sulphonic acid, toluene sulphonic acid and xylene sulphonic acid; aromatic hydrocarbon sulphonate salts, e.g., ammonium xylene sulphonate, dihydroxyl
  • non-ionic emulsifiers include fatty acid esters of alcohols, ethylene glycol, polyethylene glycol, propylene glycol, glycerine, polyglycerine, sorbitol, pentaerythritol, polyamines, polyglycol ethers of alcohols, thioalcohols, fatty acid esters, fatty acid amines, fatty acid alkanolamides, alkyl phenols, polysiloxanes, polypropylene glycol, ethers of alcohols, fatty acids, fatty amines, and oxo-alcohols such as isooctyl-alcohol.
  • non-ionic emulsifiers can be made anionic through their combination with suitable base materials, such as potassium hydroxide.
  • suitable base materials such as potassium hydroxide.
  • Non-ionic emulsifiers are preferably used in case the polyolefin wax emulsion is used as internal release agent; the potlife of the emulsion used in combination with the polyisocyanate is improved, ensuring enough processing window m wood mills
  • Suitable cationic emulsifiers include alkyl dimethylammes and quaternary ammonium compounds
  • polyethylene wax emulsions which can be used in the present invention are ADD 9887, and ADD 9898, which aie 30% non-iomc polyethylene wax emulsions available from Huntsman Polyurethanes, West Deptford, NJ and BSP-32W (30% solids anionic polyethylene wax emulsion) available from Blackhawk Specialties, Inc of Rock Island, Illinois
  • One preferred polypropylene wax emulsion which can be used m the present invention is ME 42040 (an 40% anionic emulsion of Epolene E 43) available from Michelman, Inc of Cincinnati, Ohio
  • the aqueous emulsion preferably has a non- aqueous components content of from about 1 to 40% by weight, more preferably from about 2 to 20%, more preferably from about 5 to 15%o and even more preferably from about 5 to 10%) by weight non-aqueous components
  • Useful fatty acids include, for example, any naturally occurring or synthetically manufactured saturated or unsaturated monobasic, di-basic or polybasic fatty acid
  • the fatty acids are composed of a chain of alkyl groups containing from 4 to 22 carbon atoms and having a terminal carboxyl group -COOH
  • the fatty acids utilized in the present invention are those which compnse an acid having an aliphatic chain of about 8 to about 24 carbon atoms
  • the fatty acid is one having an aliphatic chain of about 8 to about 20 and most preferably about 16 to about 18 carbon atoms
  • Examples of preferred fatty acids useful in the present invention are stea ⁇ c acid, oleic acid, lau ⁇ c acid, my ⁇ stic acid, palmitic acid, Imoleic acid, Imolenic acid and mixtures thereof
  • the fatty acid used in the present invention is oleic acid Metallic fatty acids may also be useful in the invention.
  • Preferred metallic fatty acids are those which comprise an acid having an aliphatic chain of about 4 to about 24 carbon atoms and preferably about 12 to about 20, such as oleic acid, stearic acid, lauric acid, myristic acid, plamitic acid, linoleic acid and linolenic acid.
  • Any metallic compound may be used to form the acid salt.
  • suitable metallic compounds include aluminum, barium, calcium, lithium, magnesium, potassium, sodium and zinc. The most preferred metallic compound is zinc.
  • the fatty acid may be used in any suitable form, including neat, emulsifiable and emulsified.
  • the fatty acid is provided as an aqueous emulsion. Any suitable method may be used to form such aqueous emulsions.
  • the fatty acid may be mixed by hand mixing with a surfactant and then high sheer-mixed with de-ionized water to form an emulsion. Methods for forming aqueous emulsions of the fatty acid are well known to an artisan of ordinary skill.
  • the aqueous emulsion preferably has a non- aqueous components content of from about 1 to 40% by weight, more preferably from about 2 to 20%), and even more preferably from about 5 to 10% by weight non-aqueous components content.
  • the fatty acid and polyolefin wax release agents of the invention can be used as either a neat blend, a non-aqueous, emulsifiable blend, or an aqueous, emulsified blend.
  • the neat blend or non-aqueous, emulsifiable blend may be preferred when it is desirable to reduce shipping costs of the release agent blend. Since the blend is non-aqueous, a significant portion of shipping weight and space (i.e., water) is eliminated.
  • the non-aqueous, emulsifiable blend can be emulsified simply be adding water and mixing, without the requirement of added heat or pressure.
  • the non-aqueous, emulsifiable polyolefin wax and the non- aqueous, emulsifiable fatty acid can be separately prepared and then mixed together to form the non-aqueous blend at the point of use.
  • these emulsions can be either mixed together prior to shipping, or shipped in separate containers for blending at the point of use.
  • the aqueous emulsion of the fatty acid/polyolefin wax blend useful in the present invention should contain a sufficient amount of fatty acid/polyolefin wax to provide a coverage of about 0.1 to about 1.6 and preferably about 0.2 to about 0.9 milligrams of the fatty acid/polyolefin wax per square cm of lignocellulosic material. Generally, the lower levels of fatty acid/polyolefin wax are preferred as they are more cost effective.
  • any ratio of fatty acid to polyolefin wax may be useful; however, the emulsion blend preferably is from about 20 to 90%) fatty acid by weight, more preferably from about 40 to 80% o fatty acid, and even more preferably from about 60 to 80% fatty acid by weight, based on the total weight of the fatty acid and polyolefin wax only.
  • the present fatty acid/polyolefin wax blend when used as external release agent may be applied to the lignocellulosic material in an amount of about 2 to about 35 and preferably about 8 to about 16 and most preferably about 10 milligram/square cm.
  • the amount of application can be varied as needed for a particular purpose.
  • the blend of the present invention may also contain other additives, such as flame retardants, lignocellulosic preserving agents, fungicides, waxes, sizing agents, biocides, fillers, other binders (such as formaldehyde condensate adhesives) and catalysts.
  • additives such as flame retardants, lignocellulosic preserving agents, fungicides, waxes, sizing agents, biocides, fillers, other binders (such as formaldehyde condensate adhesives) and catalysts.
  • fatty acid/polyolefin wax blends of the invention in a process for binding lignocellulosic material with polyisocyanates leads to improved release compared to many conventional processes. Board properties are not detrimentally influenced. Moreover, the fatty acid/polyolefin wax blends of the invention result in good release memory and little or no build-up on the press surfaces. Further these fatty acid/polyolefin wax blends are effective in a wider temperature range than conventional wax release agents, for example montan wax (max 185°C) and thus higher press temperatures can be used which speeds up the cure process.
  • conventional wax release agents for example montan wax (max 185°C) and thus higher press temperatures can be used which speeds up the cure process.
  • surfactants to disperse the fatty acid and polyolefin waxes in water.
  • Such surfactants can be ionic, anionic, cationic, non-ionic, or amphoteric in nature.
  • a preferred surfactant for the fatty acid is a non-ionic octophenol ethoxylate.
  • the fatty acid/polyolefin wax blend release systems of the present invention are intended to be used with a wide range of polyisocyanate based binders, which are discussed, generally, below.
  • Suitable organic polyisocyanates include dusocyanates, particularly aromatic dusocyanates, and isocyanates of higher functionality.
  • organic polyisocyanates which may be used in the process of the present invention include aliphatic isocyanates such as hexamethylene diisocyanate; aromatic isocyanates, such as m-and p-phenylene diisocyanate, tolylene-2,4- and -2,6-diisocyanate, diphenylmethane-4,4' -diisocyanate, chlorophenylene-2,4-diisocyanate, naphthylene-1 ,5- diisocyanate, diphenyl ene-4,4' diisocyanate, 4,4'-diisocyanate-3,3'-dimethyldiphenyl, 3- methyldiphenylmethane-4,4'-diisocyanate and diphenyl ether diisocyanate; and cycloaliphatic dusocyanates such as cyclohexane-2,4- and -2,3-diisocyanate, 1- methylcyclohe
  • Modified polyisocyanates containing isocyanurate, carbodiimide or uretonimine groups may also be used according to the present invention.
  • blocked polyisocyanates such as the reaction product of a phenol or an oxide and a polyisocyanate, having a deblocking temperature below the temperature applied when using the polyisocyanate composition may be utilized as the organic polyisocyanate binder in the present process.
  • the organic polyisocyanate may also be an isocyanate-ended prepolymer prepared by reacting an excess of a diisocyanate or a higher functionality polyisocyanate with a polyol.
  • Water-emulsifiable organic polyisocyanates like those described in UK Patent No. 1 ,444,933; in European Patent Publication No. 516361 ; and in PCT Patent Publication No. 91/03082 can also be used.
  • isocyanates may also be used in the present process.
  • a mixture of tolylene diisocyanate isomers such as the commercially available mixtures of 2,4- and 2.6- isomers and also the mixture of di- and higher polyisocyanates produced by phosgenation of aniline/formaldehyde condensates may be utilized as the organic polyisocyanate binder according to the present invention.
  • Such mixtures are well-known in the art and further include the crude phosgenation products containing methylene bridged polyphenylpolyisocyanates, including diisocyanate, triisocyanate and higher polyisocyanates together with any phosgenation by-products.
  • Useful isocyanates include those wherein the isocyanate is an aromatic diisocyanate or polyisocyanate of higher functionality, such as pure diphenylm ethane diisocyanate or mixture of methylene bridged polyphenyl polyisocyanates containing dusocyanates, triisocyanates and higher functionality polyisocyanates. Such materials are prepared by the phosgenation of corresponding mixtures of polyamines obtained by condensation of aniline and formaldehyde. For convenience, polymeric mixtures of methylene bridged polyphenyl polyisocyanates containing diisocyanate, triisocyanate and higher functionality polyisocyanates are referred to hereinafter as "polymeric MDI". Both polymeric MDI and emulsifiable MDI or aqueous emulsions thereof can be used. Preferably the polyisocyanate is liquid at room temperature.
  • the organic polyisocyanate binder composition may further comprise additives conventionally used in the art such as flame retardants, lignocellulosic preserving agents, fungicides, waxes, sizing agents, fillers, catalysts, surfactants and other binders such as formaldehyde condensate adhesives.
  • additives conventionally used in the art such as flame retardants, lignocellulosic preserving agents, fungicides, waxes, sizing agents, fillers, catalysts, surfactants and other binders such as formaldehyde condensate adhesives.
  • the organic polyisocyanate binder is generally applied to the lignocellulosic material in an amount of about 0.1 to about 25, preferably about 1 to about 10 and most preferably about 2 to about 6%o by weight based upon the dry weight of the lignocellulosic material.
  • the lignocellulosic material is treated with the organic polyisocyanate binder material by means of, for example, mixing, blending, spraying and/or spreading the polyisocyanate composition with or onto the lignocellulosic material.
  • Such application may generally take place in a conventional blender.
  • the treated lignocellulosic material is formed into a mat, preferably upon a screen.
  • at least a portion of the mat surface can be treated (e.g., by spraying, spreading, etc.) with the fatty acid/polyolefin wax blend release agent.
  • the press platens Preferably all surfaces of the mat which will contact the press platens are treated.
  • the treated lignocellulosic material is then conveyed to a press where pressure is applied thereto at elevated temperatures.
  • the pressing operation generally consists of pressing at 120°C to 260°C at pressures of about 2 to 6 MPa.
  • Such binding processes are commonly known in the art. However, it will be recognized by those in the art that the pressing operation may be modified as needed for a particular operation.
  • the fatty acid/polyolefin wax blend release agent is used as an internal release agent.
  • the fatty acid polyolefin wax release agent blend is either pre-mixed with the polyisocyanate binder and applied to the lignocellulosic material as one stream; this route is advisable when the polyisocyanate is used as an aqueous emulsion or suspension. Otherwise the fatty acid/polyolefin wax blend release agent and the polyisocyanate binder are applied, preferably simultaneously, to the lignocellulosic material as two separate streams.
  • the fatty acid/polyolefin wax blend release agent can be applied to the lignocellulosic material with a slack wax or emulsified slack wax.
  • the present process can also be used in the manufacture of various types of composite structures, such as, for example, medium density fiberboard, hardboard, particle board (also known as chipboard) and plywood.
  • the lignocellulosic materials suitable for use in the present process includes all types known in the industry, such as wood strands, wood chips, wood fibers, shavings, veneers, wood wool, cork, bark, sawdust and similar waste products of the woodworking industry as well as other materials having a lignocellulosic basis such as paper, bagasse, straw, flax, sisal, hemp, rushes, reeds, rice hulls, husks, grass, nutshells and the like.
  • the lignocellulosic material may be mixed with other particulate or fibrous materials such as mineral fillers, glass fiber, mica, rubber, textile waste such as plastic fibers and fabrics.
  • the sheets and molded bodies produced according to the present invention have excellent mechanical properties and they may be used in any of the situations where such articles are customarily used.
  • An emulsion of a fatty acid was prepared at room temperature using a high sheer-mixing cup attached to a laboratory Waring blender base. Specifically, about 5 grams of Triton-X 100 (Union Carbide Corporation) surfactant was added to about 30 grams of Priolene 6906 oleic acid (Uniqema International Corporation) and hand mixed for about one minute. This mixture was then transferred to a Eberbach high sheer-mixing cup and mixing was started at about 7000 rpm and about 65 grams of de-ionized water was quickly added to the mixture and the mix speed was increased slightly. The emulsion was immediately formed and mixing continued for a total of about 5 minutes. The emulsion had the physical characteristics at 25°C listed in Table 1 : TABLE 1
  • emulsified polyethylene wax emulsion BSP EX 72, oxidized polyethelyne wax emulsion, 35% non-aqueous components, from Blackhawk Specialties, Inc., Rock Island, IL
  • BSP EX 72 oxidized polyethelyne wax emulsion, 35% non-aqueous components, from Blackhawk Specialties, Inc., Rock Island, IL
  • the emulsified release agent blend had the following formulation:
  • BSP EX 72 oxidized polyethylene wax emulsion, 35%o non-aqueous components
  • the emulsified release agent blend had the formula and characteristics listed in Table 2:
  • a second fatty acid/polyolefin emulsion release agent blend was prepared by the following method.
  • an emulsion of a fatty acid was prepared at room temperature by adding about 4 parts by weight of Triton-X 100 surfactant (Union Carbide Corporation) to about 21 parts by weight Priolene 6906 oleic acid (Uniqema International Corporation) and hand mixed for about 1 minute. To this mixture was added about 75 parts by weight de-ionized water, by stirring in an Eberbach high sheer-mixing cup at about 7000 rpm for about 5 minutes to form the fatty acid emulsion.
  • Triton-X 100 surfactant Union Carbide Corporation
  • Priolene 6906 oleic acid Uniqema International Corporation
  • a polyethylene wax emulsion was prepared by adding to a Parr pressurized reactor the following: about 40 parts by weight AC 629; about 7 parts by weight of ACINTOL FA2 tall oil fatty acid available from Arizona Chemical; about 7 parts by weight of diethyl amino ethanol; trace amount of KOH; trace amount of Na2S2O5; and about 13.7 parts by weight de- ionized water.
  • the vessel was then heated and pressurized to a temperature of about 125°C and a pressure of about 2 to 3 bar. The contents of the vessel was stirred for about 30 minutes, while temperature and pressure were maintained.
  • the fatty acid emulsion was then blended with the polyethylene wax emulsion in a fatty acid emulsion to polyethylene wax emulsion weight ratio of about 75:25 by hand mixing.
  • the emulsion had the characteristics at 25°C listed in Table 3:
  • Wood composite panels bonded with polymeric MDI-based binders were pressed to test the release characteristics of the above test release agent.
  • Aspen OSB flakes (having various lengths and widths and about 1 mm thick, with a moisture content -6%, Weyerhaeuser Company, Drayton Valley, Canada) were blended with about 4%o by weight Rubinate ® M isocyanate (a polymeric MDI available from Huntsman Polyurethanes, West Deptford, NJ) in a rotary laboratory blender at a rate of about 100 grams of isocyanate per minute.
  • Slack Wax 600 (petroleum slack wax, Exxon Corp., Houston, TX) was then spray atomized on the flakes to form a mix.
  • the mix consisted of about 5.5 kg wood flakes, about 209 grams Rubinate ® M isocyanate, and about 55 grams slack wax. Separate mats of the mix were then hand formed on a screen, and the top surface of each mat was sprayed with about 10 grams of the release agents listed in Table 5. Prior to pressing, the metal surface of the press platens was polished to expose new metal and then solvent cleaned. The mats were then pressed in a programmable logic controller controlled hot press at a temperature of about 205°C using a pressing cycle of 60 second close, 180 second hold, and 30 second decompression time. The mats were about 30 x 30 cm and were pressed to a thickness of about 6.4 mm directly to the steel platen surface. Following pressing, the panels were removed from the press and evaluated qualitatively for release performance. Table 4 describes the release rating system:
  • Table 5 demonstrates the release characteristics of 4 tested release agent systems.
  • a test method was developed to quantify the release buildup that deposits on the platen of the press over many pressing operations.
  • the method uses a series of panels described in Example 4 with the addition of 4 thin metal shim stock pieces strategically placed over the surface of the panel prior to pressing. After each pressing the shims were weighed with an analytical balance and the weight gain recorded and then placed onto the next panel prior to pressing.
  • This example reflects the problems that are experienced regarding release buildup on the platen and screen surfaces when only a polyethylene wax emulsion is used as a release agent.
  • the oxidized polyethylene wax based release agent experienced a steady weight buildup over time.
  • the fatty acid/polyethylene wax blends of the present invention by contrast experience much lower buildup.
  • Example 6 This example demonstrates that the release agents of the present invention can be used at various pressing temperatures and result in little or no build-up. Release testing was conducted using the method explained in Example 5. A release agent was prepared substantially as described in Example 3. Three pressing temperatures were selected and 15 pressing operations were conducted at each temperature, using the release agent described above, which had been diluted to about 10 % by weight non-aqueous components content and applied to the top surface of the mats at an application rate of about 10 grams of release agent per square foot of mat surface. The graph depicted in Figure 2 displays the buildup results at the three pressing temperatures, namely, 177, 205, and 232°C.
  • This example demonstrates the formation of a non-aqueous, emulsifiable fatty acid/polyolefin wax release agent blend which is subsequently emulsified by mixing with water at room temperature.
  • Three emulsifiable release agent blends were then formed from the liquid blend formed above. Specifically, three samples, weighing about 60 grams each, of the above liquid blend were measured-out.
  • a first release agent blend was formed by adding about 40 grams of Surfonyl L24-9 ethoxylated alcohol, available from Huntsman Surfactants, to the first of the three samples by stirring at room temperature.
  • a second release agent blend was formed by adding about 30 grams of Surfonyl L24-9 ethoxylated alcohol and about 10 grams of Surfonyl L24-5 ethoxylated alcohol, available from Huntsman Surfactants, to the second of the three samples by stirring at room temperature.
  • a third release agent blend was formed by adding about 20 grams of Surfonyl L24-9 ethoxylated alcohol and about 20 grams of Surfonyl L24-5 ethoxylated alcohol to the third of the three samples by stirring at room temperature.
  • release agent blends were then emulsified by stirring together at room temperature about 10 parts by weight release agent and about 90 parts by weight water. It was noted that the third release agent was the most stable of the three release agents.
  • a test emulsified release agent was then formed substantially the same as the third release agent formed above, except that the emulsion was formed by stirring together at room temperature about 15 parts by weight of the third release agent and about 85 parts by weight water, thus forming an emulsion having about 15% non-aqueous components content.
  • the fatty acid/polyolefin release agents of the present invention provide for good release rating, good "release memory", and little or no build-up as measured at various press temperatures.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Forests & Forestry (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Developing Agents For Electrophotography (AREA)

Abstract

L'invention concerne des systèmes d'agents de démoulage acide gras/cire polyoléfinique utiles pour la fabrication de matériaux lignocellulosiques. Ces systèmes acide gras/cire polyoléfinique conviennent particulièrement bien pour la production de matériaux lignocellulosiques fabriqués avec des liants polyisocyanate.
PCT/US2000/003496 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique WO2001058998A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
MXPA02007710A MXPA02007710A (es) 2000-02-11 2000-02-11 Agente desmoldante basado en acidos grasos y cera de poliolefina.
PL00356539A PL356539A1 (en) 2000-02-11 2000-02-11 Fatty acid and polyolefin wax release agent
AU33609/00A AU3360900A (en) 2000-02-11 2000-02-11 Fatty acid and polyolefin wax release agent
CA002397210A CA2397210A1 (fr) 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique
PCT/US2000/003496 WO2001058998A1 (fr) 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique
EP00911768A EP1268639A1 (fr) 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique
BR0017102-6A BR0017102A (pt) 2000-02-11 2000-02-11 Agente de liberação, e, método para formar materiais lignocelulósicos ligados com aglutinante de poliisocianato orgânico
ARP010100411A AR027326A1 (es) 2000-02-11 2001-01-30 Agente desmoldante basado en acidos grasos y cera de poliolefina y metodo de obtencion
US10/215,427 US20030015122A1 (en) 2000-02-11 2002-08-09 Fatty acid and polyolefin wax release agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2000/003496 WO2001058998A1 (fr) 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/215,427 Continuation US20030015122A1 (en) 2000-02-11 2002-08-09 Fatty acid and polyolefin wax release agent

Publications (1)

Publication Number Publication Date
WO2001058998A1 true WO2001058998A1 (fr) 2001-08-16

Family

ID=21741054

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/003496 WO2001058998A1 (fr) 2000-02-11 2000-02-11 Agent de demoulage a base d'acide gras et de cire polyolefinique

Country Status (7)

Country Link
EP (1) EP1268639A1 (fr)
AR (1) AR027326A1 (fr)
AU (1) AU3360900A (fr)
BR (1) BR0017102A (fr)
CA (1) CA2397210A1 (fr)
MX (1) MXPA02007710A (fr)
WO (1) WO2001058998A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011058086A1 (fr) * 2009-11-12 2011-05-19 Akzo Nobel N.V. Procédé pour la production de papier
EP2332946A1 (fr) 2009-12-10 2011-06-15 Evonik Goldschmidt GmbH Agent de séparation et utilisation pour la fabrication de corps moulés composites
WO2012007242A1 (fr) 2010-07-15 2012-01-19 Evonik Goldschmidt Gmbh Procédé de fabrication de corps moulés à partir de matériaux contenant de la cellulose
EP2443164A1 (fr) * 2009-06-16 2012-04-25 Huntsman International LLC Compositions de libération pour des composites lignocellulosiques
US8377359B2 (en) 2005-05-06 2013-02-19 Evonik Goldschmidt Gmbh Process for the production of moldings from cellulose-containing materials
CN108789762A (zh) * 2018-04-08 2018-11-13 南通慧源塑胶有限公司 一种抗菌环保木塑复材料的制作工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD102039A3 (fr) * 1972-05-17 1973-12-12
JPS60192748A (ja) * 1984-03-15 1985-10-01 Sekisui Chem Co Ltd 塩化ビニル系樹脂組成物
US4717727A (en) * 1984-08-31 1988-01-05 Hoechst Aktiengesellschaft Esters of pyridine-2,4- and 2,5-dicarboxylic acid as medicaments for the inhibition of proline hydroxylase and lysine hydroxylase
US5554438A (en) * 1994-07-22 1996-09-10 Imperial Chemical Industries, Plc Self-release binder system
US5908496A (en) * 1996-07-01 1999-06-01 Imperial Chemical Industries Plc Process for binding lignocellulosic material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD102039A3 (fr) * 1972-05-17 1973-12-12
JPS60192748A (ja) * 1984-03-15 1985-10-01 Sekisui Chem Co Ltd 塩化ビニル系樹脂組成物
US4717727A (en) * 1984-08-31 1988-01-05 Hoechst Aktiengesellschaft Esters of pyridine-2,4- and 2,5-dicarboxylic acid as medicaments for the inhibition of proline hydroxylase and lysine hydroxylase
US5554438A (en) * 1994-07-22 1996-09-10 Imperial Chemical Industries, Plc Self-release binder system
US5908496A (en) * 1996-07-01 1999-06-01 Imperial Chemical Industries Plc Process for binding lignocellulosic material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Derwent World Patents Index; AN 1985-281034, XP002150292 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8377359B2 (en) 2005-05-06 2013-02-19 Evonik Goldschmidt Gmbh Process for the production of moldings from cellulose-containing materials
EP2443164A1 (fr) * 2009-06-16 2012-04-25 Huntsman International LLC Compositions de libération pour des composites lignocellulosiques
EP2443164A4 (fr) * 2009-06-16 2013-12-11 Huntsman Int Llc Compositions de libération pour des composites lignocellulosiques
WO2011058086A1 (fr) * 2009-11-12 2011-05-19 Akzo Nobel N.V. Procédé pour la production de papier
EP2332946A1 (fr) 2009-12-10 2011-06-15 Evonik Goldschmidt GmbH Agent de séparation et utilisation pour la fabrication de corps moulés composites
DE102009047764A1 (de) 2009-12-10 2011-06-16 Evonik Goldschmidt Gmbh Trennmittel und Verwendung zur Herstellung von Kompositformkörpern
US9120827B2 (en) 2009-12-10 2015-09-01 Evonik Degussa Gmbh Release agent and use for the production of composite mouldings
WO2012007242A1 (fr) 2010-07-15 2012-01-19 Evonik Goldschmidt Gmbh Procédé de fabrication de corps moulés à partir de matériaux contenant de la cellulose
DE102010031376A1 (de) 2010-07-15 2012-01-19 Evonik Goldschmidt Gmbh Verfahren zur Herstellung von Formkörpern aus Cellulose enthaltenden Materialien
CN108789762A (zh) * 2018-04-08 2018-11-13 南通慧源塑胶有限公司 一种抗菌环保木塑复材料的制作工艺

Also Published As

Publication number Publication date
EP1268639A1 (fr) 2003-01-02
CA2397210A1 (fr) 2001-08-16
AU3360900A (en) 2001-08-20
MXPA02007710A (es) 2002-10-11
AR027326A1 (es) 2003-03-26
BR0017102A (pt) 2003-01-14

Similar Documents

Publication Publication Date Title
US6132503A (en) Process for binding lignocellulosic material
EP0909295B1 (fr) Procede pour lier une matiere lignocellulosique
US6231656B1 (en) Release agents for use in lignocellulosic processes and process for preparing molded lignocellulosic composites
US7029612B2 (en) Release agent for lignocellulosic composites
CA2193618C (fr) Systeme de liant a auto-liberation
US20030015122A1 (en) Fatty acid and polyolefin wax release agent
CA2476899A1 (fr) Agents anti-adherents
CA2740674A1 (fr) Composition de polyisocyanate utilisee pour lier des materiaux ligno-cellulosiques
EP1268639A1 (fr) Agent de demoulage a base d'acide gras et de cire polyolefinique
US5587414A (en) Compatibilising agents
EP2344308A1 (fr) Composition de polyisocyanate utilisée pour lier des matériaux ligno-cellulosiques
CA2362750A1 (fr) Procedes pour la preparation d'un materiau composite moule, et agents de decollement a base de cire
EP0708789B1 (fr) Composition de polyisocyanate
US5130419A (en) Process for preparing lignocellulosic bodies
AU681914B2 (en) Compatibilising agents
KR20000011065A (ko) 리그노셀룰로오스 물질의 결합 방법
KR100255788B1 (ko) 접착제, 리그노셀룰로스성형판용 접착제, 리그노셀룰로스성형판 및 그들의 제조방법
MXPA98009824A (en) Process for aggluting lignocellules material
WO2003026878A1 (fr) Systeme de moulage equipe d'un element mobile a liberation automatique

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2000911768

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 33609/00

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2397210

Country of ref document: CA

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWE Wipo information: entry into national phase

Ref document number: 520620

Country of ref document: NZ

WWE Wipo information: entry into national phase

Ref document number: PA/a/2002/007710

Country of ref document: MX

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWP Wipo information: published in national office

Ref document number: 2000911768

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2000911768

Country of ref document: EP