WO2001051446A3 - Co-production of carboxylic acids and/or their esters - Google Patents

Co-production of carboxylic acids and/or their esters Download PDF

Info

Publication number
WO2001051446A3
WO2001051446A3 PCT/GB2000/004943 GB0004943W WO0151446A3 WO 2001051446 A3 WO2001051446 A3 WO 2001051446A3 GB 0004943 W GB0004943 W GB 0004943W WO 0151446 A3 WO0151446 A3 WO 0151446A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon atoms
carboxylic acids
methanol
water
olefinically unsaturated
Prior art date
Application number
PCT/GB2000/004943
Other languages
French (fr)
Other versions
WO2001051446A2 (en
Inventor
John Glenn Sunley
Original Assignee
Bp Chem Int Ltd
John Glenn Sunley
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0000936A external-priority patent/GB0000936D0/en
Priority claimed from GB0000935A external-priority patent/GB0000935D0/en
Priority claimed from GB0000933A external-priority patent/GB0000933D0/en
Priority claimed from GB0000934A external-priority patent/GB0000934D0/en
Application filed by Bp Chem Int Ltd, John Glenn Sunley filed Critical Bp Chem Int Ltd
Priority to AU2001222071A priority Critical patent/AU2001222071A1/en
Publication of WO2001051446A2 publication Critical patent/WO2001051446A2/en
Publication of WO2001051446A3 publication Critical patent/WO2001051446A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process for the co-carbonylation of methanol and an olefinically unsaturated carbonylatable reactant having at least two carbon atoms, and/or reactive derivatives thereof to produce a mixture of acetic acid and a carboxylic acid having at least three carbon atoms, and/or an ester of either or both carboxylic acids, which process comprises contacting at elevated temperature and pressure (i) carbon monoxide, (ii) methanol and/or a reactive derivative thereof, (iii) an olefinically unsaturated carbonylatable reactant having at least two carbon atoms and/or a reactive derivative thereof and (iv) water in a liquid reaction composition in a carbonylation reactor, the liquid reaction composition comprising (a) a finite concentration of water, (b) a hydrocarbyl halide, (c) a rhodium catalyst and (d) ruthenium and/or osmium as promoter.
PCT/GB2000/004943 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters WO2001051446A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001222071A AU2001222071A1 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
GB0000936A GB0000936D0 (en) 2000-01-14 2000-01-14 Process
GB0000935A GB0000935D0 (en) 2000-01-14 2000-01-14 Process
GB0000933A GB0000933D0 (en) 2000-01-14 2000-01-14 Process
GB0000934A GB0000934D0 (en) 2000-01-14 2000-01-14 Process
GB0000934.0 2000-01-14
GB0000936.5 2000-01-14
GB0000933.2 2000-01-14
GB0000935.7 2000-01-14

Publications (2)

Publication Number Publication Date
WO2001051446A2 WO2001051446A2 (en) 2001-07-19
WO2001051446A3 true WO2001051446A3 (en) 2002-03-14

Family

ID=27447750

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/GB2000/004933 WO2001051445A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004924 WO2001051444A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004943 WO2001051446A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004944 WO2001051447A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Family Applications Before (2)

Application Number Title Priority Date Filing Date
PCT/GB2000/004933 WO2001051445A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004924 WO2001051444A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/GB2000/004944 WO2001051447A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Country Status (2)

Country Link
AU (4) AU2001220161A1 (en)
WO (4) WO2001051445A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7053241B1 (en) * 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
CN108003023B (en) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 A method of preparing methyl propionate
CN108003024B (en) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 A kind of preparation method of methyl propionate
CN108003022B (en) * 2016-11-02 2020-01-07 中国科学院大连化学物理研究所 Method for preparing ester compound
EP4192807A1 (en) * 2020-08-04 2023-06-14 Eastman Chemical Company Propionic acid process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111982A (en) * 1976-07-26 1978-09-05 Monsanto Company Coproduction of acetic and propionic acids
EP0728727A1 (en) * 1995-02-21 1996-08-28 BP Chemicals Limited Process for the carbonylation of an alcohol
US5834622A (en) * 1995-03-08 1998-11-10 Bp Chemicals Limited Process for the carbonylation of a carbonylatable reactant

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132734A (en) * 1976-05-03 1979-01-02 Monsanto Company Synthesis of carboxylic acids
ZA833528B (en) * 1982-05-22 1984-12-24 Bp Chem Int Ltd Process for the production of one or more carboxylic acid anhydrides
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
GB8406126D0 (en) * 1984-03-08 1984-04-11 Bp Chem Int Ltd Esters
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
FR2703351A1 (en) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Process for the preparation of carboxylic acids or the corresponding esters in the presence of a catalyst based on rhodium and iridium.
GB9503383D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
GB9715402D0 (en) * 1997-07-22 1997-09-24 Bp Chem Int Ltd Process
EP1085004A1 (en) * 1999-09-20 2001-03-21 Dsm N.V. Process for the carbonylation of butadiene and/or butadiene derivative

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111982A (en) * 1976-07-26 1978-09-05 Monsanto Company Coproduction of acetic and propionic acids
EP0728727A1 (en) * 1995-02-21 1996-08-28 BP Chemicals Limited Process for the carbonylation of an alcohol
US5834622A (en) * 1995-03-08 1998-11-10 Bp Chemicals Limited Process for the carbonylation of a carbonylatable reactant

Also Published As

Publication number Publication date
AU2001222065A1 (en) 2001-07-24
AU2001223818A1 (en) 2001-07-24
WO2001051444A3 (en) 2002-02-28
AU2001220161A1 (en) 2001-07-24
WO2001051447A2 (en) 2001-07-19
WO2001051445A2 (en) 2001-07-19
AU2001222071A1 (en) 2001-07-24
WO2001051444A2 (en) 2001-07-19
WO2001051446A2 (en) 2001-07-19
WO2001051445A3 (en) 2002-05-10
WO2001051447A3 (en) 2002-03-14

Similar Documents

Publication Publication Date Title
CA2223133A1 (en) Iridium catalysed carbonylation process for the production of a carboxylic acid
MY121194A (en) Process for the production of acetic acid.
DE69906561D1 (en) METHANOL CARBONYLATION IN THE PRESENCE OF A RHODIUM / IRIDIUM / IODIDE ION CATALYTIC SYSTEM
CA2225230A1 (en) Iridium catalysed carbonylation process for the production of acetic acid
MY118787A (en) Iridium- catalysed carbonylation process for the production of acetic acid
KR960031419A (en) Method for producing carboxylic acid
KR970001295A (en) A process for carbonylation of an alkyl alcohol and / or a reactive derivative thereof
MY142257A (en) Process for the production of acetic acid
CA2188217A1 (en) Process for the production of acetic acid by the carbonylation of dimethyl ether
US5250726A (en) Process for the preparation of 3-pentenoic acid from butadiene
JP2761603B2 (en) Method for producing 3-pentenoic acid
US4788334A (en) Acid accelerated hydrocarboxylation
WO2001051446A3 (en) Co-production of carboxylic acids and/or their esters
GB0221800D0 (en) Process
US5198577A (en) Preparation of adipic acid by hydrocarbonylation of pentenic acids
KR960031420A (en) Method for Carbonylation of Butadiene or Butadiene Derivatives
JP2897146B2 (en) Carbonylation of allylic butenols and butenol esters
MY121111A (en) Preparation of acetic acid and/or methyl acetate in the presence of iridium and platinum
GB2298648A (en) Process for the carbonylation of a carbonylatable reactant comprising the use of an iridium catalyst and a ruthenium or osmium promoter
KR20010101278A (en) Process for Carbonylation of an Allylic Butenol or Butenyl Ester of a Carboxylic Acid
TH41645A3 (en) The process for carbonation of allicic, butanol, or butylene ester of carboxylic acid.

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
AK Designated states

Kind code of ref document: A3

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP