WO2001051444A3 - Co-production of carboxylic acids and/or their esters - Google Patents

Co-production of carboxylic acids and/or their esters Download PDF

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Publication number
WO2001051444A3
WO2001051444A3 PCT/GB2000/004924 GB0004924W WO0151444A3 WO 2001051444 A3 WO2001051444 A3 WO 2001051444A3 GB 0004924 W GB0004924 W GB 0004924W WO 0151444 A3 WO0151444 A3 WO 0151444A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon atoms
carboxylic acids
promoter
methanol
water
Prior art date
Application number
PCT/GB2000/004924
Other languages
French (fr)
Other versions
WO2001051444A2 (en
Inventor
Stephen David Cook
John Glenn Sunley
Original Assignee
Bp Chem Int Ltd
Stephen David Cook
John Glenn Sunley
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0000933A external-priority patent/GB0000933D0/en
Priority claimed from GB0000934A external-priority patent/GB0000934D0/en
Priority claimed from GB0000936A external-priority patent/GB0000936D0/en
Priority claimed from GB0000935A external-priority patent/GB0000935D0/en
Application filed by Bp Chem Int Ltd, Stephen David Cook, John Glenn Sunley filed Critical Bp Chem Int Ltd
Priority to AU2001223818A priority Critical patent/AU2001223818A1/en
Publication of WO2001051444A2 publication Critical patent/WO2001051444A2/en
Publication of WO2001051444A3 publication Critical patent/WO2001051444A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

A process for the co-carbonylation of methanol and an olefinically unsaturated carbonylatable reactant having at least two carbon atoms, and/or reactive derivatives thereof to produce a mixture of acetic acid and a carboxylic acid having at least three carbon atoms, and/or an ester of either or both carboxylic acids, which process comprises contacting at elevated temperature and pressure (i) carbon monoxide, (ii) methanol and/or a reactive derivative thereof, (iii) an olefinically unsaturated carbonylatable reactant having at least two carbon atoms and/or a reactive derivative thereof and (iv) water in a liquid reaction composition in a carbonylation reactor, the liquid reaction composition comprising (a) a finite concentration of water, (b) a hydrocarbyl halide, (c) a rhodium and/or iridium catalyst, (d) ruthenium and/or osmium as promoter and (e) cobalt as co-promoter.
PCT/GB2000/004924 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters WO2001051444A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001223818A AU2001223818A1 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
GB0000933A GB0000933D0 (en) 2000-01-14 2000-01-14 Process
GB0000934A GB0000934D0 (en) 2000-01-14 2000-01-14 Process
GB0000934.0 2000-01-14
GB0000935.7 2000-01-14
GB0000936A GB0000936D0 (en) 2000-01-14 2000-01-14 Process
GB0000933.2 2000-01-14
GB0000936.5 2000-01-14
GB0000935A GB0000935D0 (en) 2000-01-14 2000-01-14 Process

Publications (2)

Publication Number Publication Date
WO2001051444A2 WO2001051444A2 (en) 2001-07-19
WO2001051444A3 true WO2001051444A3 (en) 2002-02-28

Family

ID=27447750

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/GB2000/004924 WO2001051444A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004944 WO2001051447A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004933 WO2001051445A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004943 WO2001051446A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Family Applications After (3)

Application Number Title Priority Date Filing Date
PCT/GB2000/004944 WO2001051447A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004933 WO2001051445A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters
PCT/GB2000/004943 WO2001051446A2 (en) 2000-01-14 2000-12-21 Co-production of carboxylic acids and/or their esters

Country Status (2)

Country Link
AU (4) AU2001222071A1 (en)
WO (4) WO2001051444A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7053241B1 (en) * 2005-02-24 2006-05-30 Celanese International Corporation Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer
CN108003022B (en) * 2016-11-02 2020-01-07 中国科学院大连化学物理研究所 Method for preparing ester compound
CN108003024B (en) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 A kind of preparation method of methyl propionate
CN108003023B (en) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 A method of preparing methyl propionate
CN116157380A (en) * 2020-08-04 2023-05-23 伊士曼化工公司 Propionic acid process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132734A (en) * 1976-05-03 1979-01-02 Monsanto Company Synthesis of carboxylic acids
US4658053A (en) * 1984-03-08 1987-04-14 Bp Chemicals Limited Production of esters
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
GB2327420A (en) * 1997-07-22 1999-01-27 Bp Chem Int Ltd Production of oxygenated compounds

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111982A (en) * 1976-07-26 1978-09-05 Monsanto Company Coproduction of acetic and propionic acids
ZA833528B (en) * 1982-05-22 1984-12-24 Bp Chem Int Ltd Process for the production of one or more carboxylic acid anhydrides
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
FR2703351A1 (en) * 1993-03-31 1994-10-07 Rhone Poulenc Chimie Process for the preparation of carboxylic acids or the corresponding esters in the presence of a catalyst based on rhodium and iridium.
GB9503382D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
GB9503383D0 (en) * 1995-02-21 1995-04-12 Bp Chem Int Ltd Process
GB9504708D0 (en) * 1995-03-08 1995-04-26 Bp Chem Int Ltd Process
US5817869A (en) * 1995-10-03 1998-10-06 Quantum Chemical Corporation Use of pentavalent Group VA oxides in acetic acid processing
EP1085004A1 (en) * 1999-09-20 2001-03-21 Dsm N.V. Process for the carbonylation of butadiene and/or butadiene derivative

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4132734A (en) * 1976-05-03 1979-01-02 Monsanto Company Synthesis of carboxylic acids
US4681707A (en) * 1982-09-30 1987-07-21 The British Petroleum Company P.L.C. Process for the production of carboxylic acid esters and/or carboxylic acids
US4658053A (en) * 1984-03-08 1987-04-14 Bp Chemicals Limited Production of esters
GB2327420A (en) * 1997-07-22 1999-01-27 Bp Chem Int Ltd Production of oxygenated compounds

Also Published As

Publication number Publication date
AU2001223818A1 (en) 2001-07-24
WO2001051446A2 (en) 2001-07-19
WO2001051444A2 (en) 2001-07-19
AU2001220161A1 (en) 2001-07-24
WO2001051447A3 (en) 2002-03-14
WO2001051445A2 (en) 2001-07-19
WO2001051445A3 (en) 2002-05-10
WO2001051446A3 (en) 2002-03-14
WO2001051447A2 (en) 2001-07-19
AU2001222065A1 (en) 2001-07-24
AU2001222071A1 (en) 2001-07-24

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