WO2001045828A1 - Catalytic devices - Google Patents
Catalytic devices Download PDFInfo
- Publication number
- WO2001045828A1 WO2001045828A1 PCT/US2000/035081 US0035081W WO0145828A1 WO 2001045828 A1 WO2001045828 A1 WO 2001045828A1 US 0035081 W US0035081 W US 0035081W WO 0145828 A1 WO0145828 A1 WO 0145828A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- catalytic device
- grains
- catalytic
- metal
- Prior art date
Links
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 97
- 239000003054 catalyst Substances 0.000 claims abstract description 132
- 239000000919 ceramic Substances 0.000 claims abstract description 59
- 239000004071 soot Substances 0.000 claims abstract description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 50
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 229910052697 platinum Inorganic materials 0.000 claims description 25
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 24
- 229910052863 mullite Inorganic materials 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- 230000008033 biological extinction Effects 0.000 claims description 18
- 229910052878 cordierite Inorganic materials 0.000 claims description 17
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 17
- 239000000758 substrate Substances 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 239000010953 base metal Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 239000010970 precious metal Substances 0.000 claims description 3
- 229910052703 rhodium Inorganic materials 0.000 claims description 3
- 239000010948 rhodium Substances 0.000 claims description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 30
- 241000264877 Hippospongia communis Species 0.000 description 25
- 238000000034 method Methods 0.000 description 21
- 239000002245 particle Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 229910000510 noble metal Inorganic materials 0.000 description 7
- 239000012298 atmosphere Substances 0.000 description 6
- 239000004927 clay Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 229910004014 SiF4 Inorganic materials 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 5
- -1 such as an oxide Chemical class 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000004814 ceramic processing Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000001000 micrograph Methods 0.000 description 2
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910003446 platinum oxide Inorganic materials 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910004883 Na2SiF6 Inorganic materials 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical class [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 206010042618 Surgical procedure repeated Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical compound [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000000462 isostatic pressing Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010443 kyanite Substances 0.000 description 1
- 229910052850 kyanite Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000012035 limiting reagent Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000003947 neutron activation analysis Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/06—Ceramic, e.g. monoliths
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the invention relates to catalytic converters for automotive and diesel applications.
- Catalytic converters were first used in the early 1970s to reduce harmful exhaust emissions, such as carbon monoxide, hydrocarbons and nitrous oxides (NO x ) produced by automobiles. These converters are still employed and are typically made by forming a honeycomb support structure comprised of metal or ceramic (for example, cordierite) covered by a coating containing a precious metal catalyst. The catalyst-coated structure is placed in a metal container connected to the exhaust system, such that the exhaust gas flows through the channels of the honeycomb.
- the catalyst coating is typically applied using a wash coat consisting of nanometer size particles of precious metal (for example, platinum, palladium and rhodium) deposited on micrometer size agglomerated particles of alumina.
- the coating thickness is typically 10 to 100 micrometers thick covering the entire surface of the metal or cordierite, including any surface roughness. The catalyst coating is made this thick to provide sufficient catalyst loading within the volumetric limitations of the converter device to ensure adequate initial performance and an adequate performance life of the catalytic converter.
- a first aspect of the invention is a catalytic device comprised of a catalyst support of fused ceramic grains and a catalyst that is surface bound to at least a portion of the ceramic grains, incorporated into at least a portion of the ceramic grains or combinations thereof, wherein the grains and catalyst form a surface structure that has a box counting dimension of greater than 1.00 or the box counting dimension has at least one step change, when measured from a box size "d" of at least 1 micrometer to at most 1 millimeter.
- a second aspect of the invention is a catalytic converter comprised of the catalytic device of the first aspect enclosed within a metal container that has an inlet and outlet for flowing a gas over the catalytic device.
- a third aspect of the invention is a catalytic converter comprised of the catalytic device of the first aspect enclosed within a metal container that has an inlet and outlet for flowing gas through the catalytic device.
- a fourth aspect of the invention is a catalytic converter-soot trap comprised of the catalytic device of the first aspect enclosed within a metal container having an inlet and outlet for flowing a gas through the catalytic device.
- the catalytic device of the first aspect may allow the use of a much thinner catalyst coating and faster lightoff than the typical automobile catalytic converter.
- the catalytic device may be used for any reaction that may be auto-thermal. That is to say, a reaction that has an ignition point and extinction point. Generally, this is when a reaction has a Zeldovich number "B" that has an absolute value of at least 4.
- the Zeldovich number "B” is given by:
- ⁇ H is the heat of reaction
- C 0 is the concentration of limiting reactant
- p is the density of the fluid
- C p is the heat capacity of the fluid
- E is the overall activation energy of the reaction
- T 0 is the reactant temperature
- R is the universal gas constant.
- Figure 1 consists of scanning electron micrographs at 25X and 100X of an example of the present invention's catalytic device, wherein the catalyst is a wash coat of alumina and platinum deposited in the walls and on the needles of an acicular mullite honeycomb substrate.
- Figure 2 consists of scanning electron micrographs at 25X and 100X of a catalytic device, not an embodiment of this invention, wherein the substrate is a commercially available cordierite honeycomb substrate that is covered by the same wash coat as in Figure 1.
- the invention is a catalytic device comprised of a catalyst support of fused ceramic grains and a catalyst that is surface bound to at least a portion of the ceramic grains, incorporated into at least a portion of the ceramic grains or combinations thereof, wherein the grains and catalyst form a surface structure that has a box counting dimension of greater than 1.00 or at least one step change, when measured from a box size "d" of at least 1 micrometer to at most 1 millimeter.
- the ceramic grains and catalyst increase the area on the surface where gases may catalytically react under more favorable diffusion conditions. For example, it is believed the grains and catalyst may lessen the diffusion resistance caused by the small pore channels between wash coat particles.
- these 5 wash coats have pore channel openings on the order of less than 1 micrometer.
- Illustrative of the surface structure of this invention is one in which a flat surface has orthogonal cylindrical protrusions extending outward from the surface, that is, a "bed of nails,” so long as the distance between the protrusions (that is, nails) did not became so small that the channels created between them had an opening so small that diffusion of gases in the 0 channels would be substantially impeded.
- Another example of a surface structure is randomly oriented asymmetric grains that form a porous surface structure.
- the box counting dimension of the surface structure is greater than 1.00 when the structure is a fractal type of structure.
- the box counting dimension has at least a one step 5 change in slope of the line described below.
- the box counting method may be determined by those known in the fractal art, such as those described by Falconer, Fractal Geometry Mathematical Foundations and Applications, John Wiley and Sons, NY, pages 38-47, 1990.
- Figures for example, the micrograph of a "bed of nails” would look like a comb viewed orthogonal to the length of the teeth of the comb).
- the smallest dimension of “d” is the lower limit (1 micrometer) and the largest dimension “d” is the upper limit (1 millimeter), described in the previous paragraph.
- the amount of boxes or circles “M” needed to cover 5 the surface is determined periodically at and between the upper and lower limits.
- the box dimension is given by the logarithmic rate of the log of "M” versus the log of "d” as "d” approaches zero within the confines of the measurement limits.
- the box counting dimension is greater than 1 when the slope of the resulting line has an essentially constant slope (for example, fractal-type surface).
- the box counting dimension has a step change when, within the upper and lower limits, a sudden change in slope of the line occurs and then the slope continues at a similar slope prior to the sudden change in slope.
- An example of a step change is when the box size just becomes equal to the space between the nails in the "bed of nails.”
- the box counting dimension is preferably at least 1.01, more preferably at least 1.05, even more preferably at least 1.2 and most preferably at least 1.5.
- the desired structure is periodic, it is preferred to have at least 2 step changes, more preferably at least 3 step changes and most preferably at least 4 step changes.
- the box counting dimension is determined at a lower limit of 1 micrometer and an upper limit of 1 millimeter. It is understood that the lower limit corresponds to the pore channel size between wash coat particles. Wash coat particles generally are comprised of agglomerated particles, which define smaller pore channels than those between the wash coat particles. It is also understood that cracks in a wash coat, for example, due to microscopy sample preparation are not applicable to the measurement.
- the lower limit is 2 micrometers, more preferably 5 micrometers, and most preferably 10 micrometers.
- the ceramic grains may be any suitable ceramic grains, such as those known in the art. Generally, the ceramic grains are oxides. Preferably, the ceramic is an alumina, silica or an aluminosilicate. More preferably, the ceramic is the aluminosilicate. Most preferably, the ceramic grains are mullite grains.
- the type of grains may be determined by any suitable technique or techniques, such as electron diffraction, X-ray diffraction and energy dispersive spectroscopy.
- substantially all of the ceramic grains are acicular ceramic grains.
- Substantially all of the ceramic grains are acicular means that at least 90 percent of the grains of the support are acicular grains. More preferably, all of the grains are acicular grains.
- Acicular ceramic grains are ceramic grains that, generally, have an aspect ratio of at least 2.
- the acicular grains have an aspect ratio of at least 10.
- the cross-sectional dimension (that is, width and depth) are at least 0.1 micrometer to 250 micrometers.
- the cross-sectional dimension is at least 1 micrometer, more preferably at least 2 micrometers and most preferably at least 10 micrometers to preferably at most 150 micrometers, more preferably at most 100 micrometers and most preferably at most 50 micrometers.
- the length of acicular grains (that is, the longest dimension) is, generally, at least 1 micrometer to at most 2 millimeters.
- the length is at least 10 micrometers, more preferably at least 20 micrometers and most preferably at least 100 micrometers, to preferably at most 1.5 millimeters, more preferably at most 1 mm, and most preferably at most 500 micrometers.
- the ceramic grains are also fused with each other to form the catalyst support. "Fused” means that the grains have been sintered together (that is, the grain boundary between grains is comprised of a ceramic including, for example, a glass).
- the catalyst support is preferably porous (that is, a porous catalyst support). It is also preferred that substantially all of the porosity is open porosity. Open porosity is porosity that is accessible to a liquid or gas (that is, can be penetrated by a liquid or gas). In other words, the open porosity is not closed or entrapped. Preferably, this open porosity is continually interconnected throughout the support, which generally occurs when the acicular grains are randomly oriented. "Substantially all,” in this context, means that the catalyst support contains at most 5 percent closed porosity out of the total amount of porosity of the catalyst support. Preferably, the amount of closed porosity is at most about a trace amount. Preferably, most of the closed porosity is comprised of pores within individual grains (that is, not pores defined by the surfaces of more than one grain). The open and closed porosity may be measured by a suitable technique, such as those known in the art.
- the porous catalyst support may have a strength suitable for catalytic converter applications, while having a porosity of at least 40 percent by volume.
- the porosity is at least 50 percent, more preferably at least 60 percent and most preferably at least 65 percent, to, generally, at most 85 percent by volume of the catalyst support.
- the catalytic device in addition to the catalyst support, is comprised of a catalyst that is surface-bound to at least a portion of the ceramic grains, incorporated into at 5 least a portion of the ceramic grains or combinations thereof.
- the catalyst may be any suitable catalyst, such as those known in the art.
- the catalyst may be any one of the following preferred embodiments or combinations of them.
- a first preferred catalyst is directly bound-metal catalysts, such as noble metals, base metals and combinations thereof.
- noble metal catalysts include 0 platinum, rhodium, palladium, ruthenium, rhenium, silver and alloys thereof.
- base metal catalysts include copper, chromium, iron, cobalt, nickel, zinc, manganese, vanadium, titanium, scandium and combinations thereof.
- the metal catalyst preferably, is in the form of a metal, but may be present as an inorganic compound, such as an oxide, nitride and carbide, or as a defect structure within the ceramic grains of the porous catalyst 5 support.
- the metal may be applied by any suitable technique, such as those known in the art.
- the metal catalyst may be applied by chemical vapor deposition.
- a second preferred catalyst coating is one that is incorporated into the lattice structure of the ceramic grains of the porous catalyst support.
- an element may be Ce, Zr, La, Mg, Ca, a metal element described in the previous paragraph or combinations o thereof. These elements may be incorporated in any suitable manner, such as those known in the art and by methods described later.
- a third preferred catalyst is a combination of ceramic particles having metal deposited thereon. These are typically referred to as wash coats. Generally, wash coats consist of micrometer sized ceramic particles, such as zeolite, aluminosilicate, silica, ceria, 5 zirconia, barium oxide, barium carbonate and alumina particles that have metal deposited thereon. The metal may be any previously described for directly deposited metal.
- a particularly preferred wash coat catalyst coating is one comprised of alumina particles having a noble metal thereon. It is understood that the wash coat may be comprised of more than one metal oxide, such as alumina having oxides of at least one of zirconium, barium, o lanthanum, magnesium and cerium.
- a fourth preferred catalyst is a perovskite-type catalyst comprising a metal oxide composition, such as those described by Golden in U.S. Patent No. 5,939,354.
- a fifth preferred catalyst is one that is formed by and deposited on the catalyst support by calcining at a temperature of from 300°C to 3000°C, a composition that comprises (a) an aqueous salt solution containing at least one metal salt and (b) an amphiphilic ethylene oxide containing copolymer, wherein the copolymer has an average molecular weight of greater than 400, an ethylene oxide content of 5 to 90 percent and an HLB of between -15 and 15, as described by Gruenbauer, et al., PCT Patent Application No. 99/18809.
- the catalyst may also be one such as described by U.S. Patent No. 5,698,483 and PCT Patent Application No. 99/03627.
- the catalyst is bound or incorporated into at least a portion of the ceramic grains when there is enough catalyst for the particular application. Generally, at least 10 percent to essentially all of the ceramic grains are coated or contain a catalyst.
- the catalyst is bound when it is chemically bonded to at least one element of the ceramic grains of the porous catalyst support.
- the catalyst that is bound to the surface of the grains forms a layer, such that at least 10 percent of the grains bound by the catalyst has a thickness of at most 1/2 the thickness of the smallest dimension of each grain coated.
- the thickness is at most 1/3, more preferably at most 1/4 and most preferably at most 1/5, as described in the previous sentence.
- the catalyst coating may also be desirable for the catalyst coating to be at most a monolayer (that is, one atom or one molecule thick).
- Ceramic grains that form a porous catalyst support may also be attached to a structural support that is comprised of a material having a porosity less than the porosity of the porous catalyst support.
- the structural support has a porosity that is at least 20 percent less porous than the porous catalyst support.
- the structural support would generally have a porosity of at most 50 percent by volume.
- the structural support has a porosity of at most 50 percent, more preferably at most 30 percent and most preferably at most 10 percent by volume.
- the structural support may be attached by any suitable method.
- the structural support is attached sufficiently to withstand the rigors of the catalytic converter operation.
- the structural support is fused to the porous catalyst support; fused being used in the same way as previously described.
- the structural support may be any suitable material.
- the material may be the same chemistry as the porous catalyst support or different chemistry, so long as the porosity is different as described previously.
- the structural support may be a metal, ceramic or combination thereof.
- the structural support is a ceramic, it is preferred that the grains are substantially symmetrical as opposed to acicular. Substantially symmetrical is when the grains have an average aspect ratio of at most 2. Cordierite is a preferred structural support.
- the ceramic grains that form the catalyst support may be made by any suitable method. Suitable methods include, for example, methods for making acicular mullite, such as those described by U.S. Patent Nos. 5,194,154; 5,198,007; 5,173,349; 4,911,902; 5,252,272; 4,948,766 and 4,910,172.
- precursor compounds are generally mixed and then heated sufficiently to form the acicular ceramic grains of the support.
- precursor compounds containing Al, Si and oxygen are generally mixed to form a mixture capable of forming fluorotopaz and, subsequently, mullite.
- precursor compounds that may be used to form a mullite porous catalyst support are described in the aforementioned U.S. patents.
- the mixture of precursor compounds may also contain precursor catalyst compounds that have elements that may be incorporated in the grain structure of the porous catalyst's acicular ceramic grains.
- precursor catalyst compounds that have elements that may be incorporated in the grain structure of the porous catalyst's acicular ceramic grains.
- Examples of compounds useful for forming these incorporated catalysts include inorganic and organic compounds that have elements described previously for catalysts that may be incorporated in the ceramic grains of the porous catalyst.
- the mixture when forming a mullite porous catalyst support, is comprised of compounds, such as clay (that is, hydrated aluminum silicate), other aluminosilicates, such as kyanite or zeolites, alumina, silica, aluminum trifluoride and fluorotopaz.
- the precursor compounds are selected from the group consisting of clay, silica, alumina and mixtures thereof.
- the mixture is comprised of clay and alumina when forming a mullite porous catalyst support.
- the mixture may be made by any suitable method, such as those known in the art. Examples include ball milling ribbon blending, vertical screw mixing, V-blending and attrition milling.
- the mixture may be prepared dry (that is, in the absence of a liquid medium) or wet.
- the mixture is then shaped into a porous shape by any suitable method, such as those known in the art.
- suitable method such as those known in the art. Examples include injection molding, extrusion, isostatic pressing, slip casting, roll compaction and tape casting. Each of these is described in more detail in Introduction to the Principles of Ceramic Processing, J. Reed, Chapters 20 and 21, Wiley Interscience, 1988.
- the mixture of precursor compounds is heated under an atmosphere sufficient to form the porous catalyst support.
- Any suitable temperature and atmosphere may be used depending on the chemistry of the ceramic grains of the porous catalyst desired.
- fluorine is present in the atmosphere from sources, such as SiF 4 ,
- the source of fluorine in the atmosphere is from SiF 4 .
- the porous body when making mullite, is generally heated to a first temperature for a time sufficient to convert the precursor compounds in the porous body to fluorotopaz and then raised to a second temperature sufficient to form the mullite composition.
- the temperature may also be cycled between the first and second temperature to ensure complete mullite formation.
- the porous body may be treated to reduce the amount of fluoride ions in the article. Methods for reducing the fluoride ions include those described by U.S. Patent No. 5,173,349.
- the first temperature may be from 500°C to 950°C.
- the first temperature is at least 550°C, more preferably at least 650°C and most preferably at least 725°C to preferably at most 850°C, more preferably at most 800°C and most preferably at most 775°C.
- the second temperature generally is at least 1000°C to at most 1700°C.
- the second temperature is at least 1050°C, more preferably at least 1075°C and most preferably at least 1100°C to preferably at most 1600°C, more preferably at most OODC and most preferably at most 1200°C.
- the atmosphere is inert (for example, nitrogen) or a vacuum until 500°C, which is when the fluorine-containing gas is typically introduced.
- organic compounds and water may be removed. These may also be removed in a separate heating step common in the art, such as described in Introduction to the Principles of Ceramic Processing, J. Reed, Wiley Interscience, 1988.
- the catalyst may be applied after the support has been made by a suitable method, such as those known in the art.
- the catalyst may be applied by a vapor deposition method and solution methods.
- a metal catalyst may be applied to the catalyst support from solution via a soluble salt (for example, platinum salts) in a suitable solvent (for example, water) followed by heating to decompose the salt.
- the catalyst may also be applied to the porous catalyst support by using known wash coats and methods of applying them. Of course, any one or combination of methods of forming the catalyst coatings may be used.
- the catalytic device is also particularly useful when used in a catalytic converter.
- the catalytic device is enclosed within a metal container that has an inlet and outlet for flowing a gas (for example, exhaust gas) over the catalytic device, such as typically done in automobile exhaust systems.
- the catalytic device is enclosed within a metal container that has an inlet and outlet for flowing gas through the catalytic device.
- the metal container may be any suitable container, such as those known in the art for making catalytic converters.
- the shape of the catalytic device may be any suitable shape, such as pellets, flat disks and honeycombs.
- the catalytic converter comprised of the catalytic device generally has a shorter light-off time than known catalytic converters.
- Light-off time is the time required for the catalyst to reach the ignition temperature of the reaction.
- the amount of noble metal catalyst, if used may be less because the particles or clusters of metal catalyst atoms may be more uniformly spread apart, avoiding the most problematic poisoning of catalytic converters, "sintering of the metal catalysts together.”
- the catalytic converter or device has a substantially shorter light-off time.
- substantially, shorter light-off time generally means that the time is at least 5 percent shorter.
- the catalytic converter or device may have a lower light-off temperature than known catalytic converters made of metal or cordierite substrates prepared with substantially the same catalyst and tested under substantially the same conditions.
- substantially the same catalyst and conditions include, for example, the same platinum loading and wash coat and gas flow rate and gas composition.
- the light-off temperature is substantially lower.
- the light-off temperature is generally substantially lower when the temperature is at least 10°C lower.
- the light-off temperature is at least 15°C and more preferably at least 20°C lower.
- the catalytic device is also particularly useful as a particulate (soot) trap and exhaust catalyst for diesel engines.
- the catalytic device is contained within a metal can having an inlet and outlet for passing the exhaust gas through the catalytic device.
- the soot particles generally would be trapped on a region having a porosity of smaller size and the exhaust gas would typically be catalyzed in a region having a porosity of larger size. Since the soot particles are retained at the catalyst, surprisingly, the soot particles may be combusted as the catalyst heats up to operating temperature and the resultant combustion gases catalyzed just as the exhaust gases are.
- Square channel honeycombs having a cell density of 240 cells per square inch and a wall thickness of 0.013 to 0.014 inch were formed by extruding a mixture of natural ball clay (Todd Dark grade, Kentucky-Tennessee Clay Company), K-alumina (ALCOA gibbsite calcined at 1100°C) and polymer binders. The clay and alumina were mixed in proportions to give an Al:Si atom ratio of 3.15.
- a honeycomb was extruded.
- the extruded honeycomb was then slowly heated in air up to 1000°C for one hour in order to burn off the polymeric binder and drive off the clay's structural water.
- the resulting calcined honeycomb was cut to the size required for testing and then converted to acicular mullite in a vacuum furnace attached to a SiF 4 source and equipped to allow control of the gas atmosphere.
- the calcined honeycomb was heated under vacuum to 735°C and held at that temperature for at least one hour, then cooled under vacuum to 720°C. At this point, SiF gas was added to maintain a pressure of 600 torr. The furnace was then heated at 1.5°C per minute, adding SiF 4 as necessary, to maintain a pressure of 600 torr, until the absorption of SiF was essentially complete (820°C). At this point, the reactor pressure was reduced to 200 torr and the reactor set to remove SiF 4 , as necessary, to maintain that pressure. The furnace was heated at 3°C per minute to 1000°C, then 1°C per minute until evolution of
- SiF substantially ceased (1100°C).
- the reactor was evacuated and cooled to ambient temperature and the resultant mullite honeycomb having a cell density of 238 cells per square inch was removed.
- the mullite honeycomb was completely immersed into an aqueous alumina slurry (20 percent by weight), having a particle size of 120 nm and a surface area, after firing of 155 m 2 per gram available under the tradename DISPAL (Condea Chemie GMBH, Lake Charles, LA).
- the mullite honeycomb was pulled from the slurry and the excess slurry removed by blowing compressed air through the channels of the honeycomb.
- the sample was dried and immersed again in the slurry until enough alumina was added to give 30,000 ⁇ T of surface area per liter of honeycomb volume after firing.
- the mullite honeycomb was heated in an oven to a temperature of 600°C for two hours.
- the end of the honeycomb was dipped into a dilute ammonia solution of diaminedinitritoplatinum (0.425 percent by weight of diaminedinitritoplatinum), until the solution wicked halfway up the honeycomb, the honeycomb was then inverted and the procedure repeated.
- the sample was heated in an air oven to 200°C for two hours to decompose the diaminedinitritoplatinum to platinum oxide.
- the sample was then heated for six hours at 225°C in a 5 percent hydrogen nitrogen atmosphere to reduce the platinum oxide to platinum metal.
- the resultant catalytic device had a platinum concentration of 0.84 gram per liter, as calculated from the mass of platinum determined by neutron activation analysis and the outer dimensions of the catalytic device or monolith.
- the light of temperature of the monolith was determined as follows.
- the monolith was fastened into a stainless steel sample holder by using INTERAM Mount Mat (3M Corporation).
- Calibrated mass- flow-controllers (Brooks) and an air/N 2 /CO gas manifold were used to generate an O 2 /N 2 /CO gas mixture having a flow rate of 40 standard liters per minute (slpm).
- the gas mixture was heated by a packed bed heat exchanger (stainless steel pipe filled with quartz chips and situated in a tube furnace) and then passed through the test monolith.
- the temperature of the gas entering the monolith was measured by a type K thermocouple located in the sample holder approximately 1 % inches upstream from the front face of the monolith.
- the set point temperature of the tube furnace was adjusted to limit dT 3 /dt to less then 5°C per minute in the vicinity of the sample ignition.
- Composition of the gas mixture exiting the monolith and the sample holder was continuously monitored by CO/O 2 /CO 2 analyzers (Servomex 1440 series) having the response time of less than 10 seconds.
- the light-off temperature was defined as the temperature (T 3 ) at which the CO concentration in the gas exiting the monolith dropped to 50 percent of its value in the inlet gas.
- the extinction temperature was defined as the inlet gas temperature at which exit CO concentration reaches 50 percent of the inlet value.
- This example had a light-off temperature of 246°C and extinction temperature of 212°C, which is also shown in Table 1.
- this example is shown in Figure 1 , wherein the catalyst wash coat is deposited in the walls and on the needles of an acicular mullite honeycomb substrate.
- Example 2 was prepared and tested in the same way as Example 1 , except that the platinum concentration was 1.56 grams per liter and the light-off temperature was 233°C and extinction temperature of 200°C (also shown in Table 1).
- Example 3 was prepared and tested in the same way as Example 1, except that the aqueous solution of diaminedinitritoplatinum concentration was 0.85 percent by weight thereof, the concentration of platinum was 2.03 grams per liter and the light-off temperature was 224°C and extinction temperature of 185°C (also shown in Table 1).
- Example 4 was prepared and tested in the same way as Example 3, except that the concentration of platinum was 2.73 grams per liter and the light-off temperature was 232°C and extinction temperature of 192° C (also shown in Table 1).
- the platinum concentration was 1.5 grams per liter and the monolith had a light-off temperature of 271°C and extinction temperature of 229°C (see Table 1).
- a commercial cordierite (Grade EX-80) honeycomb, available from Corning Inc., Corning NY, having a cell density of 300 cells per square inch was made and tested in the same way as Comparative Example 1, except that the concentration of the aqueous solution of diaminedinitritoplatinum was 1.7 percent by weight thereof.
- the platinum l o concentration was 3.0 grams per liter and the monolith had a light-off temperature of 240°C and extinction temperature of 201°C (see Table 1).
- a commercial cordierite (Grade EX-80) honeycomb, available from Corning Inc., Corning NY, having a cell density of 400 cells per square inch was made and tested in 15 the same way as Comparative Example 1 , except that the concentration of the aqueous solution of diaminedinitritoplatinum was 1.7 percent by weight thereof.
- the platinum concentration was 2.2 grams per liter and the monolith had a light-off temperature of 265°C and extinction temperature of 223 °C (see Table 1).
- Examples 1 through 4 show the general trend that the light-off temperature decreases with increasing platinum concentration, as do Comparative Examples 1 and 3. It appears that a lower limit is reached with increasing platinum, which may be due, for example, to the platinum sintering together, effectively reducing the amount of platinum 5 available for the reaction. In addition, the cells per square inch of the honeycomb appears to have little or no affect on the light-off temperature (see Comparative Examples 1, 2 and 4).
- the invention's catalytic device has a light- off temperature almost 40°C less than a commercial cordierite substrate (see Example 1 0 versus Comparative Examples 1 and 2). Even more surprising, the invention's catalytic devices, even at platinum concentrations half or less of that present on the cordierite-based catalytic devices, have a light-off temperature that is lower by 30°C (see Example 1 versus Comparative Examples 1, 2 and 4). It is only when the cordierite-based devices have 4 times the concentration of platinum that the light-off temperature becomes comparable to 5 the invention's catalytic devices.
- the extinction temperature is surprisingly lower in the same fashion as the light-off temperature.
- a lower extinction temperature is highly desirable 5 because, once the catalyst is ignited, variation in engine speed and exhaust composition and temperature can cause extinction of the reaction. Consequently, a catalyst with lower extinction temperature is less susceptible to this problem. Thus, a catalyst with lower extinction temperature will produce higher conversion (efficiency), all other things being equal. It is also believed the lower extinction temperature should improve the life of the o catalyst because the reaction will generally be closer to the inlet of the catalyst.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU22899/01A AU2289901A (en) | 1999-12-23 | 2000-12-21 | Catalytic devices |
DE60037205T DE60037205T2 (en) | 1999-12-23 | 2000-12-21 | CATALYTIC DEVICES |
JP2001546764A JP4917230B2 (en) | 1999-12-23 | 2000-12-21 | Catalytic device |
BRPI0016908-0A BR0016908B1 (en) | 1999-12-23 | 2000-12-21 | catalytic device and catalytic converter. |
EP00986708A EP1251942B1 (en) | 1999-12-23 | 2000-12-21 | Catalytic devices |
MXPA02006264A MXPA02006264A (en) | 1999-12-23 | 2000-12-21 | Catalytic devices. |
CA002396471A CA2396471C (en) | 1999-12-23 | 2000-12-21 | Catalytic devices |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17301799P | 1999-12-23 | 1999-12-23 | |
US60/173,017 | 1999-12-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001045828A1 true WO2001045828A1 (en) | 2001-06-28 |
Family
ID=22630169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/035081 WO2001045828A1 (en) | 1999-12-23 | 2000-12-21 | Catalytic devices |
Country Status (13)
Country | Link |
---|---|
US (1) | US6953554B2 (en) |
EP (1) | EP1251942B1 (en) |
JP (1) | JP4917230B2 (en) |
KR (1) | KR100843992B1 (en) |
CN (1) | CN1223398C (en) |
AU (1) | AU2289901A (en) |
BR (1) | BR0016908B1 (en) |
CA (1) | CA2396471C (en) |
DE (1) | DE60037205T2 (en) |
ES (1) | ES2292494T3 (en) |
MX (1) | MXPA02006264A (en) |
WO (1) | WO2001045828A1 (en) |
ZA (1) | ZA200204252B (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006044822A1 (en) * | 2004-10-13 | 2006-04-27 | Dow Global Technologies Inc. | Catalyzed diesel soot filter and process for its use |
JP2006524630A (en) * | 2003-04-24 | 2006-11-02 | ダウ グローバル テクノロジーズ インコーポレイティド | Improved porous mullite bodies and methods for their formation |
EP1941940A1 (en) * | 2007-01-03 | 2008-07-09 | Ford Global Technologies, LLC | Porous substrate for use as a particulate filter for catalytic or non-catalytic soot regeneration methods |
US7603852B2 (en) | 2004-06-30 | 2009-10-20 | Ibiden Co., Ltd. | Exhaust gas purification apparatus |
WO2010080412A1 (en) | 2008-12-18 | 2010-07-15 | Dow Global Technologies Inc. | Ceramic honeycomb filter with enhanced thermal shock resistance |
WO2011008461A2 (en) | 2009-06-29 | 2011-01-20 | Dow Global Technologies Inc. | Ceramic honeycomb structure with applied inorganic skin |
WO2011008463A1 (en) | 2009-06-29 | 2011-01-20 | Dow Global Technologies Inc. | Process for producing cemented and skinned acicular mullite honeycomb structures |
WO2011082399A1 (en) | 2009-12-31 | 2011-07-07 | The Dow Global Technologies Llc. | Method of making polymeric barrier coating to mitigate binder migration in a diesel particulate filter to reduce filter pressure drop and temperature gradients |
WO2013015932A1 (en) | 2011-07-22 | 2013-01-31 | Dow Global Technologies Llc | Process for producing cemented and skinned ceramic honeycomb structures |
WO2013078005A1 (en) | 2011-11-21 | 2013-05-30 | Dow Global Technologies Llc | Method for making porous mullite-containing composites |
WO2013162814A1 (en) | 2012-04-23 | 2013-10-31 | Dow Global Technologies Llc | Axially sectioned ceramic honeycomb assemblies |
US20140295132A1 (en) * | 2011-10-11 | 2014-10-02 | Hitachi Metals, Ltd. | Production method of ceramic honeycomb structure, and ceramic honeycomb structure |
US8999872B2 (en) | 2011-03-29 | 2015-04-07 | Dow Global Technologies Llc | Method for making porous mullite-tialite composites |
US9079798B2 (en) | 2008-09-18 | 2015-07-14 | Dow Global Technologies Llc | Method for making porous mullite-containing composites |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050124745A1 (en) * | 2002-04-19 | 2005-06-09 | Saint-Gobain Ceramics & Plastics, Inc. | Flame retardant composites |
KR20060100447A (en) * | 2003-11-24 | 2006-09-20 | 다우 글로벌 테크놀로지스 인크. | Catalyst for a diesel particulate filter |
CN1925912A (en) * | 2004-02-27 | 2007-03-07 | 陶氏环球技术公司 | Improved catalyzed method for forming products froma liquid reactant |
BRPI0510875A (en) | 2004-04-21 | 2007-12-26 | Dow Global Technologies Inc | method for increasing the strength of a porous ceramic body, porous ceramic body and filter |
DE102004028276B4 (en) * | 2004-06-11 | 2008-08-21 | Universität Karlsruhe | Device for cleaning exhaust gases of an internal combustion engine |
DE602005009961D1 (en) * | 2004-07-26 | 2008-11-06 | Dow Global Technologies Inc | IMPROVED CATALYZED SOIL FILTER |
CA2619598C (en) | 2005-08-23 | 2013-05-14 | Dow Global Technologies Inc. | Improved method for debindering ceramic honeycombs |
US7485594B2 (en) * | 2005-10-03 | 2009-02-03 | Dow Global Technologies, Inc. | Porous mullite bodies and methods of forming them |
CN101489950B (en) | 2006-07-21 | 2013-05-08 | 陶氏环球技术有限责任公司 | Imroved diesel particulate filter |
WO2008011146A1 (en) * | 2006-07-21 | 2008-01-24 | Dow Global Technologies Inc. | Improved zone catalyzed soot filter |
FR2907471B1 (en) * | 2006-10-24 | 2009-01-23 | Saint Gobain Ct Recherches | PROCESS FOR THE PRODUCTION OF LANSHANE - STRONTIUM - MANGANESE PEROVSKITE FUSION MELTS |
TWI454427B (en) | 2006-11-01 | 2014-10-01 | Dow Global Technologies Llc | Shaped porous bodies of alpha-alumina and methods for the preparation thereof |
US8800268B2 (en) * | 2006-12-01 | 2014-08-12 | Basf Corporation | Zone coated filter, emission treatment systems and methods |
JP2008168278A (en) * | 2006-12-15 | 2008-07-24 | Nissan Motor Co Ltd | Catalyst for cleaning exhaust gas and its manufacturing method |
US7947102B2 (en) * | 2006-12-21 | 2011-05-24 | Dow Global Technologies Llc | Soot filter |
KR20100017601A (en) * | 2007-05-04 | 2010-02-16 | 다우 글로벌 테크놀로지스 인크. | Improved honeycomb filters |
DE112008001372T5 (en) * | 2007-05-22 | 2010-04-15 | National University Corporation Nagaoka University of Technology, Nagaoka-shi | Method and apparatus for forming a metal oxide thin film |
WO2009014099A1 (en) * | 2007-07-20 | 2009-01-29 | National University Corporation Nagaoka University Of Technology | Method and apparatus for depositing nitride film |
JP5736173B2 (en) * | 2007-10-12 | 2015-06-17 | ダウ グローバル テクノロジーズ エルエルシー | Improved thermal shock resistant soot filter |
BRPI0817413A2 (en) * | 2007-12-21 | 2015-06-16 | Dow Global Technologies Inc | Soot catalyst, soot catalyst filter and method for forming a soot catalyst filter |
US8334043B2 (en) | 2008-03-20 | 2012-12-18 | Dow Global Technologies Llc | Cement to make thermal shock resistant ceramic honeycomb structures and method to make them |
US8460768B2 (en) | 2008-12-17 | 2013-06-11 | Saint-Gobain Ceramics & Plastics, Inc. | Applications of shaped nano alumina hydrate in inkjet paper |
JP2012532082A (en) | 2009-06-29 | 2012-12-13 | ダウ グローバル テクノロジーズ エルエルシー | Adhesives containing multimodal fibers for making heat shock resistant ceramic honeycomb structures |
JP5251776B2 (en) | 2009-07-27 | 2013-07-31 | ソニー株式会社 | Base station, communication system, mobile terminal and relay device |
US9174158B2 (en) | 2009-11-11 | 2015-11-03 | Dow Global Technologies Llc | Cement to make thermal shock resistant ceramic honeycomb structures and method to make them |
CN102917790A (en) * | 2010-03-16 | 2013-02-06 | 陶氏环球技术有限责任公司 | Catalytic composition for production of olefins with decreased oxygenate byproducts |
CN102792114A (en) | 2010-06-25 | 2012-11-21 | 陶氏环球技术有限责任公司 | Drying method for ceramic green ware |
MX2013002501A (en) | 2010-09-01 | 2013-04-29 | Dow Global Technologies Llc | Method for applying discriminating layer onto porous ceramic filters via gas-borne prefabricated porous assemblies. |
US9745227B2 (en) | 2010-09-01 | 2017-08-29 | Dow Global Technologies Llc | Method for applying discriminating layer onto porous ceramic filters |
CN103764357B (en) | 2011-08-26 | 2016-11-09 | 陶氏环球技术有限责任公司 | Prepare the improved method of ceramic body |
CN103827055B (en) | 2011-09-27 | 2016-04-27 | 陶氏环球技术有限责任公司 | For joint cement and the skin material of ceramic honeycomb structural body |
DE112012005235T5 (en) | 2011-12-15 | 2014-10-09 | Dow Global Technologies Llc | Cement and skin materials based on a water-swellable clay and method for producing segmented or skinned ceramic honeycomb structures |
KR20140104035A (en) | 2011-12-19 | 2014-08-27 | 다우 글로벌 테크놀로지스 엘엘씨 | Improved method and apparatus for preparing ceramic body segments |
WO2013172916A1 (en) | 2012-05-18 | 2013-11-21 | Coopersurgical, Inc. | Suture passer guides and related kits and methods |
KR20150032256A (en) | 2012-06-28 | 2015-03-25 | 다우 글로벌 테크놀로지스 엘엘씨 | Process for bonding arrays of ceramic filters |
US9908718B2 (en) | 2012-10-19 | 2018-03-06 | Dow Global Technologies Llc | Device, system, and method for lifting and moving formable and/or collapsible parts |
CN107816378B (en) * | 2017-12-07 | 2023-06-30 | 中国地质大学(武汉) | Graphene type engine tail gas purification and dual power generation integrated device |
CN108854589B (en) * | 2018-07-10 | 2020-06-26 | 天津工业大学 | Mullite whisker hollow fiber membrane for oil-water separation and preparation method thereof |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4910172A (en) | 1989-02-08 | 1990-03-20 | The United States Of America As Represented By The Secretary Of The Navy | Preparation of mullite whiskers from AlF3, SiO2, and Al2 O3 powders |
US4911902A (en) | 1987-07-06 | 1990-03-27 | The United States Of America As Represented By The Secretary Of The Navy | Mullite whisker preparation |
US4948766A (en) | 1988-08-05 | 1990-08-14 | The United States Of America As Represented By The Secretary Of The Navy | Rigid mullite=whisker felt and method of preparation |
US5173349A (en) | 1989-07-28 | 1992-12-22 | Engelhard Corporation | Thermal shock and creep resistant mullite articles prepared from topaz and process of manufacture |
US5194154A (en) | 1991-12-05 | 1993-03-16 | The Dow Chemical Company | Structure for filter or heat exchanger, composed of a fused single crystal acicular ceramic |
US5198007A (en) | 1991-12-05 | 1993-03-30 | The Dow Chemical Company | Filter including a porous discriminating layer on a fused single crystal acicular ceramic support, and method for making the same |
US5252272A (en) | 1989-07-28 | 1993-10-12 | Engelhard Corporation | Thermal shock and creep resistant porous mullite articles prepared from topaz and process for manufacture |
US5340516A (en) * | 1989-07-28 | 1994-08-23 | Engelhard Corporation | Thermal shock and creep resistant porous mullite articles prepared from topaz and process for manufacture |
US5698483A (en) | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
US5783515A (en) * | 1993-09-24 | 1998-07-21 | N.E. Chemcat Corporation | Catalyst for treating exhaust gases containing dioxines, production process for the catalyst and method of treating the exhaust gases |
US5939354A (en) | 1996-04-10 | 1999-08-17 | Catalytic Solutions, Inc. | Perovskite-type metal oxide compounds and method for preparing the compounds |
WO1999042360A1 (en) | 1998-02-20 | 1999-08-26 | Karem Abraham E | Optimum speed rotor |
WO2000010913A1 (en) | 1998-08-19 | 2000-03-02 | The Dow Chemical Company | Process for preparing nanosize metal oxide powders |
Family Cites Families (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3097115A (en) * | 1960-08-01 | 1963-07-09 | Leesona Corp | Catalysts and electrodes for fuel cells |
NL270252A (en) * | 1960-10-15 | |||
US3565830A (en) * | 1963-02-07 | 1971-02-23 | Engelhard Min & Chem | Coated film of catalytically active oxide on a refractory support |
US3397154A (en) * | 1963-07-09 | 1968-08-13 | Du Pont | Preparation of alumina-supported catalyst compositions and the products thereof |
US3407604A (en) * | 1965-06-10 | 1968-10-29 | Engelhard Ind Inc | Catalytic rocket propulsion method of chemically combining hydrogen and oxygen at low subzero ignition temperatures |
US3441381A (en) * | 1965-06-22 | 1969-04-29 | Engelhard Ind Inc | Apparatus for purifying exhaust gases of an internal combustion engine |
US3856706A (en) * | 1972-06-08 | 1974-12-24 | Minnesota Mining & Mfg | High surface area siliceous support |
JPS5546338A (en) | 1978-09-28 | 1980-04-01 | Ngk Insulators Ltd | Heat and shock resistant, revolving and heat-regenerating type ceramic heat exchanger body and its manufacturing |
JPS577215A (en) | 1980-06-16 | 1982-01-14 | Ngk Insulators Ltd | Preparation of ceramic honeycomb filter |
JPS5939782A (en) | 1982-08-30 | 1984-03-05 | 株式会社デンソー | Manufacture of porous ceramic carrier |
DE3232729A1 (en) | 1982-09-03 | 1984-03-08 | Degussa Ag, 6000 Frankfurt | METHOD FOR REDUCING THE IGNITION TEMPERATURE OF DIESEL CARBON FILTERED OUT OF THE EXHAUST GAS FROM DIESEL ENGINES |
JPS5954683A (en) | 1982-09-20 | 1984-03-29 | 日本碍子株式会社 | Open end sealing method for ceramic honeycomb structure |
US4483944A (en) * | 1983-07-27 | 1984-11-20 | Corning Glass Works | Aluminum titanate-mullite ceramic articles |
DE3437641C2 (en) | 1984-10-13 | 1988-07-07 | Kanthal GmbH, 6082 Mörfelden-Walldorf | Catalytic converter |
US4727052A (en) * | 1986-06-27 | 1988-02-23 | Engelhard Corporation | Catalyst compositions and methods of making the same |
US4810463A (en) * | 1986-09-12 | 1989-03-07 | Syracuse University | Process for forming sintered ceramic articles |
US4902664A (en) * | 1987-08-13 | 1990-02-20 | Engelhard Corporation | Thermally stabilized catalysts containing alumina and methods of making the same |
JP2748961B2 (en) | 1989-10-24 | 1998-05-13 | 佐賀県 | Method for producing surface-modified alumina ceramics |
JPH0465372A (en) | 1990-07-02 | 1992-03-02 | Saga Pref Gov | Production of high strength porous ceramics |
JPH0478447A (en) | 1990-07-20 | 1992-03-12 | Matsumoto Kokan Kk | Catalytic metal carrier and production thereof |
JP2593740B2 (en) | 1990-11-27 | 1997-03-26 | 東芝モノフラックス株式会社 | Method for producing mullite porous body |
US5427601A (en) * | 1990-11-29 | 1995-06-27 | Ngk Insulators, Ltd. | Sintered metal bodies and manufacturing method therefor |
US5098455A (en) | 1990-12-21 | 1992-03-24 | The Dow Chemical Company | Regenerable exhaust gas filter element for diesel engines |
JP3118035B2 (en) | 1991-09-05 | 2000-12-18 | 東芝モノフラックス株式会社 | Mullite needle crystals and mullite porous bodies |
JP3269533B2 (en) | 1992-05-26 | 2002-03-25 | トヨタ自動車株式会社 | Manufacturing method of catalytic converter for purifying exhaust gas |
US5569455A (en) * | 1992-06-10 | 1996-10-29 | Shimadzu Corporation | Exhaust gas catalytic purifier construction |
US5307292A (en) * | 1992-06-24 | 1994-04-26 | Christopher A. Brown | Method of quantifying the topographic structure of a surface |
GB9216392D0 (en) * | 1992-07-31 | 1992-09-16 | Univ Waterloo | Surface roughness characterization of extruded plastic products |
DE69418671T2 (en) * | 1993-10-15 | 1999-12-16 | Corning Inc., Corning | Process for the production of bodies with impregnated pores |
JPH0877002A (en) * | 1994-08-31 | 1996-03-22 | Sony Corp | Parallel processor device |
US5848177A (en) * | 1994-12-29 | 1998-12-08 | Board Of Trustees Operating Michigan State University | Method and system for detection of biological materials using fractal dimensions |
US5982386A (en) * | 1996-04-02 | 1999-11-09 | Dainippon Screen Mfg. Co., Ltd. | Image boundary correction by fractal processing |
CN1211312C (en) * | 1996-07-01 | 2005-07-20 | 宇部兴产株式会社 | Ceramic composite material and porous ceramic material |
JP3042601B2 (en) * | 1996-10-31 | 2000-05-15 | ファイラックインターナショナル株式会社 | Internal combustion engine using ceramic catalyst for reforming fluid fuel and means for transportation or power generation using the same |
US6143158A (en) * | 1997-04-25 | 2000-11-07 | Fuji Photo Film Co., Ltd. | Method for producing an aluminum support for a lithographic printing plate |
US20010048971A1 (en) * | 1997-09-17 | 2001-12-06 | Sridhar Komarneni | Method of producing a porous ceramic with a zeolite coating |
JP4191276B2 (en) * | 1998-01-09 | 2008-12-03 | 富士通株式会社 | Display device |
US20020128151A1 (en) * | 1998-05-01 | 2002-09-12 | Michael P. Galligan | Catalyst members having electric arc sprayed substrates and methods of making the same |
-
2000
- 2000-12-21 EP EP00986708A patent/EP1251942B1/en not_active Expired - Lifetime
- 2000-12-21 BR BRPI0016908-0A patent/BR0016908B1/en not_active IP Right Cessation
- 2000-12-21 DE DE60037205T patent/DE60037205T2/en not_active Expired - Lifetime
- 2000-12-21 WO PCT/US2000/035081 patent/WO2001045828A1/en active IP Right Grant
- 2000-12-21 US US09/745,590 patent/US6953554B2/en not_active Expired - Lifetime
- 2000-12-21 JP JP2001546764A patent/JP4917230B2/en not_active Expired - Fee Related
- 2000-12-21 MX MXPA02006264A patent/MXPA02006264A/en unknown
- 2000-12-21 CN CNB008173850A patent/CN1223398C/en not_active Expired - Fee Related
- 2000-12-21 KR KR1020027008123A patent/KR100843992B1/en active IP Right Grant
- 2000-12-21 ES ES00986708T patent/ES2292494T3/en not_active Expired - Lifetime
- 2000-12-21 CA CA002396471A patent/CA2396471C/en not_active Expired - Fee Related
- 2000-12-21 AU AU22899/01A patent/AU2289901A/en not_active Abandoned
-
2002
- 2002-05-28 ZA ZA200204252A patent/ZA200204252B/en unknown
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4911902A (en) | 1987-07-06 | 1990-03-27 | The United States Of America As Represented By The Secretary Of The Navy | Mullite whisker preparation |
US4948766A (en) | 1988-08-05 | 1990-08-14 | The United States Of America As Represented By The Secretary Of The Navy | Rigid mullite=whisker felt and method of preparation |
US4910172A (en) | 1989-02-08 | 1990-03-20 | The United States Of America As Represented By The Secretary Of The Navy | Preparation of mullite whiskers from AlF3, SiO2, and Al2 O3 powders |
US5252272A (en) | 1989-07-28 | 1993-10-12 | Engelhard Corporation | Thermal shock and creep resistant porous mullite articles prepared from topaz and process for manufacture |
US5173349A (en) | 1989-07-28 | 1992-12-22 | Engelhard Corporation | Thermal shock and creep resistant mullite articles prepared from topaz and process of manufacture |
US5340516A (en) * | 1989-07-28 | 1994-08-23 | Engelhard Corporation | Thermal shock and creep resistant porous mullite articles prepared from topaz and process for manufacture |
US5194154A (en) | 1991-12-05 | 1993-03-16 | The Dow Chemical Company | Structure for filter or heat exchanger, composed of a fused single crystal acicular ceramic |
US5198007A (en) | 1991-12-05 | 1993-03-30 | The Dow Chemical Company | Filter including a porous discriminating layer on a fused single crystal acicular ceramic support, and method for making the same |
US5783515A (en) * | 1993-09-24 | 1998-07-21 | N.E. Chemcat Corporation | Catalyst for treating exhaust gases containing dioxines, production process for the catalyst and method of treating the exhaust gases |
US5698483A (en) | 1995-03-17 | 1997-12-16 | Institute Of Gas Technology | Process for preparing nanosized powder |
US5939354A (en) | 1996-04-10 | 1999-08-17 | Catalytic Solutions, Inc. | Perovskite-type metal oxide compounds and method for preparing the compounds |
WO1999042360A1 (en) | 1998-02-20 | 1999-08-26 | Karem Abraham E | Optimum speed rotor |
WO2000010913A1 (en) | 1998-08-19 | 2000-03-02 | The Dow Chemical Company | Process for preparing nanosize metal oxide powders |
Non-Patent Citations (2)
Title |
---|
FALCONER.: ""Fractal Geometry Mathematical Foundations and Applications", 1990, JOHN WILEY AND SONS, N.Y., pages: 38-47 |
J.REED: "Introduction to the Principles of Ceramic Processing, certain details of page 10 in description(SA-file 317680) are to be found in Chapter 20 & 21", 1988, WILEY INTERSCIENCE |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006524630A (en) * | 2003-04-24 | 2006-11-02 | ダウ グローバル テクノロジーズ インコーポレイティド | Improved porous mullite bodies and methods for their formation |
US7603852B2 (en) | 2004-06-30 | 2009-10-20 | Ibiden Co., Ltd. | Exhaust gas purification apparatus |
WO2006044822A1 (en) * | 2004-10-13 | 2006-04-27 | Dow Global Technologies Inc. | Catalyzed diesel soot filter and process for its use |
WO2006044268A1 (en) * | 2004-10-13 | 2006-04-27 | Dow Global Technologies Inc. | Catalysed diesel soot filter and process for its use |
US7713909B2 (en) | 2004-10-13 | 2010-05-11 | Dow Global Technologies Inc. | Catalyzed diesel soot filter and process |
EP1941940A1 (en) * | 2007-01-03 | 2008-07-09 | Ford Global Technologies, LLC | Porous substrate for use as a particulate filter for catalytic or non-catalytic soot regeneration methods |
US9079798B2 (en) | 2008-09-18 | 2015-07-14 | Dow Global Technologies Llc | Method for making porous mullite-containing composites |
WO2010080412A1 (en) | 2008-12-18 | 2010-07-15 | Dow Global Technologies Inc. | Ceramic honeycomb filter with enhanced thermal shock resistance |
WO2011008461A2 (en) | 2009-06-29 | 2011-01-20 | Dow Global Technologies Inc. | Ceramic honeycomb structure with applied inorganic skin |
WO2011008463A1 (en) | 2009-06-29 | 2011-01-20 | Dow Global Technologies Inc. | Process for producing cemented and skinned acicular mullite honeycomb structures |
WO2011082399A1 (en) | 2009-12-31 | 2011-07-07 | The Dow Global Technologies Llc. | Method of making polymeric barrier coating to mitigate binder migration in a diesel particulate filter to reduce filter pressure drop and temperature gradients |
US9593608B2 (en) | 2009-12-31 | 2017-03-14 | Dow Global Technologies Llc | Method of making polymeric barrier coating to mitigate binder migration in a diesel particulate filter to reduce filter pressure drop and temperature gradients |
US8999872B2 (en) | 2011-03-29 | 2015-04-07 | Dow Global Technologies Llc | Method for making porous mullite-tialite composites |
US8999448B2 (en) | 2011-07-22 | 2015-04-07 | Dow Global Technologies Llc | Process for producing cemented and skinned ceramic honeycomb structures |
WO2013015932A1 (en) | 2011-07-22 | 2013-01-31 | Dow Global Technologies Llc | Process for producing cemented and skinned ceramic honeycomb structures |
US20140295132A1 (en) * | 2011-10-11 | 2014-10-02 | Hitachi Metals, Ltd. | Production method of ceramic honeycomb structure, and ceramic honeycomb structure |
US9840444B2 (en) * | 2011-10-11 | 2017-12-12 | Hitachi Metals, Ltd. | Production method of ceramic honeycomb structure, and ceramic honeycomb structure |
US10377673B2 (en) | 2011-10-11 | 2019-08-13 | Hitachi Metals, Ltd. | Production method of ceramic honeycomb structure, and ceramic honeycomb structure |
WO2013078005A1 (en) | 2011-11-21 | 2013-05-30 | Dow Global Technologies Llc | Method for making porous mullite-containing composites |
US9764991B2 (en) | 2011-11-21 | 2017-09-19 | Dow Global Technologies Llc | Method for making porous mullite-containing composites |
WO2013162814A1 (en) | 2012-04-23 | 2013-10-31 | Dow Global Technologies Llc | Axially sectioned ceramic honeycomb assemblies |
Also Published As
Publication number | Publication date |
---|---|
CA2396471C (en) | 2009-06-16 |
JP2003517921A (en) | 2003-06-03 |
DE60037205D1 (en) | 2008-01-03 |
CA2396471A1 (en) | 2001-06-28 |
KR100843992B1 (en) | 2008-07-07 |
ZA200204252B (en) | 2003-05-28 |
KR20020070363A (en) | 2002-09-06 |
BR0016908A (en) | 2002-10-22 |
JP4917230B2 (en) | 2012-04-18 |
DE60037205T2 (en) | 2008-10-02 |
MXPA02006264A (en) | 2003-01-28 |
ES2292494T3 (en) | 2008-03-16 |
AU2289901A (en) | 2001-07-03 |
BR0016908B1 (en) | 2009-08-11 |
CN1411391A (en) | 2003-04-16 |
US6953554B2 (en) | 2005-10-11 |
EP1251942B1 (en) | 2007-11-21 |
US20010038810A1 (en) | 2001-11-08 |
CN1223398C (en) | 2005-10-19 |
EP1251942A1 (en) | 2002-10-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2396471C (en) | Catalytic devices | |
JP4275406B2 (en) | Catalyst support filter | |
AU653095B2 (en) | A coating dispersion for exhaust gas catalysts | |
EP1398069B1 (en) | Exhaust treatment device | |
JP5767770B2 (en) | Diesel dust filter with ultra-thin catalytic oxidation coating | |
JP5447757B2 (en) | Catalyst coated particle filter, process for its production and use thereof | |
US8241579B2 (en) | Diesel exhaust gas treatment system | |
RU2481883C2 (en) | Ageing-resistant to of oxidising no to no2 in exhaust gas flows | |
US5958829A (en) | Coating dispersion for exhaust gas catalysts | |
EP1967263B1 (en) | Catalytic Material And Catalyst For Purifying Exhaust Gas Component | |
RU2516465C2 (en) | Diesel oxidative catalyst with high low-temperature activity | |
KR20020048433A (en) | Catalyst and method for preparation thereof | |
JP2003154223A (en) | Filter with catalyst, method for manufacturing the same and exhaust gas control system | |
US7399728B2 (en) | Catalyst formulation, exhaust system, and gas treatment device | |
JP2010504205A (en) | Catalyst for reducing NOx in exhaust gas flow and method for producing the same | |
US20050159292A1 (en) | Catalytic filter based on silicon carbide (beta-SiC) for combustion of soot derived from exhaust gases from an internal combustion engine | |
JP6875615B1 (en) | Exhaust gas purification catalyst, exhaust gas purification method, and exhaust gas purification catalyst manufacturing method | |
JPH08229404A (en) | Exhaust gas purifying catalyst and apparatus | |
US20220023847A1 (en) | Catalyst for exhaust gas oxidation, method for producing same, and exhaust gas oxidation method using same | |
CN117858759A (en) | Catalytic coating | |
KR20240064639A (en) | Particulate filter with partially coated catalyst layer | |
JP2001046875A (en) | Exhaust gas cleaning catalyst and exhaust gas cleaning filter | |
JPH0780306A (en) | Waste gas purifying material and waste gas purifying method | |
JPS6256783B2 (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG UZ YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2002/04252 Country of ref document: ZA Ref document number: 200204252 Country of ref document: ZA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2396471 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 2001 546764 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 008173850 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: IN/PCT/2002/939/CHE Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2002/006264 Country of ref document: MX Ref document number: 1020027008123 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2000986708 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020027008123 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2000986708 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 2000986708 Country of ref document: EP |