WO2001038455A1 - Cornue - Google Patents

Cornue Download PDF

Info

Publication number
WO2001038455A1
WO2001038455A1 PCT/AU2000/001427 AU0001427W WO0138455A1 WO 2001038455 A1 WO2001038455 A1 WO 2001038455A1 AU 0001427 W AU0001427 W AU 0001427W WO 0138455 A1 WO0138455 A1 WO 0138455A1
Authority
WO
WIPO (PCT)
Prior art keywords
retort
combustion
metal
chamber
charge
Prior art date
Application number
PCT/AU2000/001427
Other languages
English (en)
Inventor
David Wilson
Original Assignee
Maddingley Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AUPQ4227A external-priority patent/AUPQ422799A0/en
Priority claimed from AUPR0384A external-priority patent/AUPR038400A0/en
Application filed by Maddingley Technology Pty Ltd filed Critical Maddingley Technology Pty Ltd
Priority to AU15051/01A priority Critical patent/AU767268B2/en
Publication of WO2001038455A1 publication Critical patent/WO2001038455A1/fr

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/004—Systems for reclaiming waste heat
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B1/00—Retorts
    • C10B1/02—Stationary retorts
    • C10B1/04—Vertical retorts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B27/00—Arrangements for withdrawal of the distillation gases
    • C10B27/02—Arrangements for withdrawal of the distillation gases with outlets arranged at different levels in the chamber
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/18—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
    • C10B47/20—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge according to the moving bed type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/08—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/04—Making spongy iron or liquid steel, by direct processes in retorts

Definitions

  • the invention relates to a retort or furnace for use at high temperatures.
  • the invention particularly relates to a retort for use in the pyrolysis of carbonaceous materials, especially low rank carbonaceous materials such as for instance, brown coal, peat, certain soft lignites, anaerobically decomposed plant matter or any combination thereof.
  • the invention may be used to produce char or to produce metals or metal alloys from carbonaceous material-metal composites.
  • Retorts currently used for coal pyrolysis are predominantly horizontal refractory lined vessels operated in a batchwise manner.
  • the vessels are externally heated in various ways until all the volatiles are removed from the brown coal or other carbon containing materials intended for conversion to char.
  • the volatiles produced are often directly discharged to the atmosphere to the obvious detriment of the environment.
  • the volatiles may be processed in chemical recovery plants which pose health risks due to the production of carcinogenic compounds, such as for instance phenols, benzpyrenes, etc.
  • carcinogenic compounds such as for instance phenols, benzpyrenes, etc.
  • a retort including a thermally insulated casing defining a furnace chamber therein; one or more columns provided within said chamber, each column comprising a plurality of vertically orientated, vertically spaced, heat resistant tubes, wherein the cross-sectional area of each tube is smaller than that of an adjacent, lower tube, and wherein the ends of adjacent tubes are arranged so as to provide an annular space therebetween, an inlet through which a combustible charge is fed into the uppermost tube, an outlet from which reacted charge is removed from the lowermost tube; and a fluid conduit for conveying combustible volatiles evolved by heating said charge to a gas burning means for combustion, to thereby provide heat to said retort.
  • the present invention also provides a process for producing char by pyrolysis of low rank carbonaceous material, said process including the steps: (i) forming pellets containing said carbonaceous material, (ii) feeding said pellets to the inlet of a retort according to the invention, (iii) operating said retort in order to heat the pellets to a combustion temperature and effect pyrolysis of said pellets to char; and
  • the present invention further provides a process for producing metal from carbonaceous material-metal containing composites, said process including the steps: (i) forming composite bodies containing a mixture of carbonaceous material and metal containing material, (ii) feeding said composites to the inlet of a retort according to the invention, (iii) operating said retort in order to heat said composites to a combustion temperature and effect pyrolysis of said carbonaceous material and reduction of the metal containing material.
  • the retort includes one or more heating means for initiating combustion of said combustible charge.
  • the retort of the present invention is especially suitable for use in the production of char by the pyrolysis of carbonaceous material, particularly low rank carbonaceous material, such as brown coal.
  • the retort can be used in the production of metal and/or metal alloys from composites of carbonaceous material and metal containing material.
  • the metal containing material typically comprises one or more metal compounds, such as oxides, sulphides, hydroxides, etc.
  • the metal compound is a metal oxide.
  • the carbonaceous material is preferably brown coal.
  • the composite is preferably a brown coal-iron oxide composite in a pellet form, in which the carbonaceous material produces reductants upon heating which react with the iron oxide to produce iron and/or steel.
  • the retort of the invention will be described largely with reference to its use in the production of char or metal as set out above. However, it is to be understood that the retort is not restricted to such use.
  • a key feature of the retort of the invention is the provision of one or more columns, each comprising a succession of vertically spaced heat resistant tubes located inside an internally insulated surrounding shell or casing.
  • the casing is preferably made of steel, more preferably mild steel.
  • the tubes themselves are typically made from a suitable heat and chemical resistant material, such as an alloy, which may contain steel. The distance between the columns of tubes and the shell will vary but should be such as to provide adequate volume for efficient combustion of the heating medium used.
  • the retort may contain two or more laterally spaced columns, each comprising a succession of vertically spaced tubes, in order to increase the throughput of material treated in the retort.
  • the or each column includes three or more vertically orientated, substantially coaxial tubes. These are advantageously vertically spaced from each other such that there is partial overlap between adjacent ends, thereby defining an annular space therebetween.
  • the annular space enables volatiles evolved during heating and/or reaction of the charge to escape therefrom. After the initial start up, combustible volatiles combust at the annuli, thereby providing heat for subsequent reaction of the charge, meaning that the external heating means can be turned down or off.
  • each vertical tube is suspended at an end thereof within the retort, allowing free discharge of the charge into the adjacent, lower vertical tube. Moreover free suspension of each tube and the absence of joins between tubes facilitates thermal expansion and contraction of the tubes and reduces failure due to thermal cycling.
  • the retort preferably comprises two or more combustion zones.
  • a first combustion zone is typically located in an upper region of the retort and a second combustion zone is typically located in a lower region of the retort.
  • the first and second combustion zones are separated by a wall, and together form a unitary body. More preferably, the wall supports one of the vertically orientated tubes which is suspended therefrom.
  • the first and second combustion zone each accommodate one or more vertical tubes, such that each combustion zone has an annulus between tubes opening therein. The provision of more than one combustion zone is advantageous in that it enables greater control over the heating process, as will be subsequently discussed in further detail.
  • the temperature of the charge is raised causing chemically fixed water to be evolved from the charge. With increasing temperature, low temperature coal volatiles are released, then carbon dioxide is released from any carbonate breakdown. Finally high temperature coal volatiles are released.
  • the temperature of the charge is raised to a value and for a time sufficient to effect the desired reaction, such as the formation of char or the reduction to metal, as the case may be.
  • Each combustion zone preferably includes a heating means, more preferably a gas burner.
  • each gas burner is located proximate to an annular space between adjacent tubes.
  • the rate of heating in the first combustion zone is preferably controlled to be relatively low.
  • the high temperature coal volatiles and reducing gases evolved from the charge in the second combustion zone are released via an open annulus into the first combustion zone where they are mixed with air and burnt to provide heat.
  • An external heating means such as an LPG burner is preferably provided in each combustion zone to provide ignition and to assist with start up of the combustion. Once the combustion reaction has commenced, the burners can be run as pilot burners on minimum gas flow to prevent flame failure.
  • the calcination reactions in the first combustion zone typically evolve water, low temperature coal volatiles and carbon dioxide. These gases mix with partially combusted gases from the charge and then pass to the second combustion zone, where they are mixed with air and completely combusted to produce heat.
  • the initial start up energy in the second combustion zone may be provided by an LPG burner, whose supply of gas is turned down or off once combustion gases are generated in the primary combustion zone.
  • the greatest proportion of volatiles released from the dry carbonaceous material is released in the temperature range 300 to 400°C, which typically occurs in the first combustion zone. These volatiles mostly travel downwards to an annular space, which means that they pass through material of increasing temperature, thereby preventing the prior art problem of recondensation of the volatiles.
  • high temperature tar vapours tend to be released in the temperature range of 650 to 750°C, typically in the second combustion zone. These vapours also mostly travel downwards to an annular space through material of increasing temperature which prevents their recondensation.
  • the retort preferably further includes a heat exchanger or recuperator.
  • Hot waste gases from the second combustion zone are passed into the heat exchanger where heat is transferred to incoming combustion air before being passed into the first and/or second combustion zones.
  • a discharging means for removing the reacted charge from the lowermost tube.
  • a discharging means comprises a rotary discharge valve which may feed into a chute.
  • the retort may additionally include a third combustion zone into which pass residual combustible gases exhausted from the second and possibly first, combustion zones.
  • the third combustion zone also preferably includes a heating means, more preferably a gas burner. These residual combustible gases are burnt in the third combustion zone before they pass into the heat exchanger and vented to atmosphere. The gases thereby exhausted are low in greenhouse gases.
  • the need for a third combustion zone may arise, for instance, where the second combustion zone is operated under fuel rich conditions and accordingly gases exhausted therefrom still contain significant quantities of combustibles.
  • the column/s of tubes need not be actually housed in the third combustion zone. While the first and second combustion zones preferably together form a unitary body, the third combustion zone may be a separate unit to the first and second combustion zones, which is linked thereto via a fluid conduit.
  • the retort may advantageously also include an integral metal melting unit.
  • the melting unit typically communicates with the outlet of the furnace chamber, such that the composite pellets are fed thereto after being reduced.
  • the melting unit is located vertically below the outlet of the furnace chamber such that the reduced pellets are automatically and continuously fed into the melting unit under gravity.
  • the melting unit preferably includes an insulated melting chamber for receiving the reduced pellets. Once in the melting unit, the temperature of the reduced pellets is raised sufficiently to effect melting of the metal. This may be achieved by simple combustion of the carbonaceous material remaining in the reduced pellets, possibly aided by injection of an oxidising gas through pipes or tuyeres. If necessary, additional fuel may also be added at this time, for example combustible gases and/or solid materials.
  • the oxidising gas is preheated, such as by heat exchange with waste gases from the retort, and typically comprises air or some other oxygen containing gas.
  • the temperature increase in the melting unit is augmented by employing an external heating means.
  • the external heating means is an electrical heating means, such as an induction heater, resistance heater or a submerged arc.
  • An induction heater is particularly preferred.
  • the wall of the insulated melting chamber typically accommodates a conductor coil, with the metal to be melted forming the secondary of a transformer.
  • An induction heater can be used alone or in conjunction with the oxidising gas assisted combustion.
  • the melting unit preferably further includes two outlets : one for slag discharge and one for molten metal discharge.
  • the slag outlet is typically located higher than the molten metal outlet.
  • the particular arrangement of slag and molten metal outlets can determine whether the metal melting unit is used in a continuous or batch mode.
  • the location of the metal outlet towards the bottom of the melting chamber, below the conductor coil, typically requires the melting unit to be operated in batch mode. This is because the reservoir of molten metal within the melting chamber can be completely emptied.
  • the metal reservoir forms the secondary of a transformer, its intermittent discharge means that the induction heater cannot be continuously operated.
  • the location of the metal outlet towards the top of the melting chamber, and above the conductor coil ensures that the chamber will always contain a reservoir of molten metal and enable uninterrupted, continuous operation of the induction heater.
  • An advantage of the present invention is a retort of light weight and simple design, enabling relatively inexpensive construction and maintenance which particularly facilitates its use in remote or inaccessible locations. Another advantage is that the retort enables high efficiency continuous operation with minimal recondensation of off-gases. Moreover, internal combustion of off-gases provides a source of heat and external heating by any desired means selected, is largely only needed in the start-up operation. Further, the controlled two to three stage combustion of particular embodiments ensures high thermal efficiency and low levels of greenhouse emissions, such as CO and NO x .
  • Advantages of the embodiment of the invention including a metal melting unit are: (i) Simple gravity flow feed of material from the furnace chamber to the melting chamber, requiring no control system between the two chambers. The feed rate of material through the retort can be simply controlled by the output from the melting chamber, (ii) Maximised thermal efficiency - the heat and chemical composition of the waste gases evolved from the melting chamber can be used in the reduction of pellets before they enter the melting chamber. The gases can be then fully combusted and oxidised to carbon dioxide in the third combustion chamber before passing to the heat exchanger where heat is recovered. Accordingly, the final gas discharge has a relatively low temperature of around 350°C and virtually no carbon monoxide.
  • FIG. 1 is a vertical cross-section through a first embodiment of a retort according to the invention.
  • Figure 2 is a vertical cross-section through a second embodiment of a retort according to the invention.
  • Figure 3 is a cut-away vertical cross-section through the basal portion of a third embodiment of a retort, showing the details of a batch metal melting unit.
  • Figure 4 is a cut-away vertical cross-section through the basal portion of a fourth embodiment of a retort, showing the details of a continuous metal melting unit.
  • a retort 10 includes a thermally insulated metal shell or casing 12 defining therein an annular furnace chamber 14.
  • the furnace chamber 14 houses a column 15 of heat resistant tubes 16, 18, 20 and 22 which are vertically orientated and vertically spaced from each other.
  • the cross-sectional area of the tubes 16, 18, 20 and 22 increases in going from the top of the retort 10 to its bottom. Accordingly, the relative cross-sectional area of the tubes is as follows tube 16 ⁇ tube 18 ⁇ tube 20 ⁇ tube 22.
  • the uppermost tube 16 includes an inlet 17 and accordingly acts as a feeder tube through which the charge material 29 is fed into the retort 10.
  • the charge moves through the tubes 16, 18, 20 and 22 in succession under the force of gravity.
  • An outlet 30 is provided at the bottom of the lowermost tube 22 through which the reacted charge 29 is removed from the retort 10.
  • the furnace chamber 14 is divided into first and second combustion zones comprising first and second chambers 14a and 14b, respectively, by a transverse wall 34.
  • the combustion chambers 14a and 14b each include a heating means comprising a gas burner 31 , 32 respectively which provide an initial heat source for raising the temperature of the charge 29.
  • the gas burner 32 in the combustion zone 14b is larger than burner 31 in order to provide sufficient heat for commencement of combustion.
  • a fluid conduit 36 extends from the top of chamber 14a to the base of chamber 14b. Gases evolved from heating the charge 29 are evolved from open annuli 26 and 24 and travel through the conduit 36 to the chamber 14b, where they are combusted.
  • the retort 10 further includes a third combustion chamber 38 communicating with the second combustion chamber 14b via a conduit 40.
  • the third combustion chamber 38 in turn communicates with a recuperator 42 through which exhaust gases pass to exhaust outlet 44 under operation of an exhaust fan (not shown).
  • a gas burner 43 is provided inside the third combustion chamber 38.
  • a damper 56 regulates the amount of combustion air fed to the gas burner 43.
  • the recuperator 42 includes an inlet 46 through which is admitted atmospheric air under action of a fan (not shown), and an outlet 47 through which preheated air exits.
  • the heat from the exhaust gases is transferred to the incoming air to thereby preheat it and the preheated air enters the first and second chambers 14a and 14b via fluid conduits 48 and 50, respectively.
  • the amount of air flowing into the chambers 14a and 14b can be regulated by dampers 52, 54 respectively.
  • a cold charge 29 of composite pellets comprising a homogeneous mixture of brown coal and iron oxide fines is fed into the top of retort 10 via inlet 17 of feeder tube 16.
  • Combustion air is introduced to chambers 14a, 14b and 38 by adjusting the dampers 52, 54 and 56, respectively.
  • burners 31 , 32 and 43 are then lit using an external source of LPG gas as fuel. The largest burner 32 is adjusted to its maximum firing rate.
  • Hot reduced pellets can be removed from the lowermost tube 22 via outlet 30.
  • the charge 29 is replenished by addition of further pellets to inlet 17.
  • the burner 32 may be turned off, or preferably down, to a pilot setting.
  • the other two burners 31 and 43 may also be adjusted to pilot settings at this stage.
  • the exhaust and combustion air fans (not shown) are adjusted to give a slight negative pressure in the chambers 14a and 14b to prevent leakage of waste gas therefrom.
  • Temperature regulation in chambers 14a, 14b and 38 is achieved by adjusting the dampers 52, 54, 56, respectively, to control the amount of combustion air entering those chambers (e.g., reducing the flow of combustion air reduces temperature).
  • the retort 10 is in a continuous operating mode.
  • the charge 29 can be continuously replenished by feeding further pellets into the inlet 17.
  • the charge 29 descends under gravity through the column 15, it increases in temperature.
  • the charge is preheated and calcined. There, water is first evolved via annular space 24. With further increase in temperature, low, then medium temperature coal volatiles are driven off and escape via annular spaces 24 and 26.
  • the pellets After entering the second chamber 14b, the pellets are maintained at a sufficiently high temperature and for a sufficient length of time to effect the desired level of reduction. High temperature volatiles and gaseous products from the reduction, and other, reactions are released which escape from annular space 28 and to a lesser extent, annular space 26. Those gases leaving annular space 26 are mixed with controlled amounts of combustion air entering via damper 52 and partially burnt to provide heat for chamber 14a. Waste gases from this combustion combine with gases leaving annular space 24 and are ducted down conduit 36 to the bottom of chamber 14b. These gases are mixed with gases leaving annular space 28 and combusted with sufficient combustion air to achieve the required temperature in the combustion chamber 14b.
  • waste gases from the combustion travel via conduit 40 to the third combustion chamber 38, where they are combusted with an excess of combustion air thereby ensuring complete reaction of the waste gases to provide a substantially clean effluent.
  • the effluent is discharged from gas outlet 44 via a recuperator 42, where heat from the effluent gas is transferred to incoming atmospheric air entering via inlet conduit 46.
  • tar vapours are present in the charge 29, they tend to be released in the temperature range 650 to 750°C, which is typically in the second combustion zone.
  • the tar vapours also tend to travel downwards, to the annular space 28, through material of increasing temperature, thereby substantially preventing recondensation of those vapours.
  • FIG. 2 A second embodiment of the retort of the invention is illustrated in Figure 2.
  • the second embodiment 110 is essentially similar to the first embodiment and like reference numerals accordingly refer to like parts.
  • the second embodiment includes an integral metal melting unit 158 which communicates with the outlet 130 of the furnace chamber 114 via a conduit 162.
  • the outlet 130 is provided at the lowermost part of an integral funnel shaped section 160 at the base of the chamber 114.
  • the funnel shaped section 160 performs essentially the same function as the lowermost tube 22 of the first embodiment in that the gap 128 between the bottom of tube 120 and the funnel shaped section 160 allows evolved gases to escape from the charge for combustion, similarly to the open annulus 28 of the first embodiment 10.
  • the integral metal melting unit 158 includes an insulated melting chamber 164 with pipes or tuyeres 166,168 extending into the melting chamber 158.
  • a hot, oxidising gas such as air or oxygen, is injected into the melting chamber 158 through the tuyeres in order to combust carbonaceous material in the pellets and raise the temperature sufficiently to effect melting of the metal therein.
  • the hot oxidising gas is heated by means of heat exchange with waste gases expelled from furnace chamber 114. This is effected in an additional heat exchanger 167 placed in between the third combustion chamber 138 and the recouperator 142.
  • the melting chamber 158 is provided with two outlets : a first, slag outlet
  • the hot reduced pellets are fed into the top of the melting chamber 158 whereupon hot air, or hot oxidising gas, is injected into the melting chamber to combust carbonaceous material in the pellets and raise the temperature of the pellets to the melting temperature of the metal.
  • a slag phase may form on top of the molten metal phase.
  • Any slag phase which forms is removed via outlet 170, which can be closeable by any suitable means, (in this case by moist fireclay plugs).
  • the molten metal is removed via lower outlet 172, which again may be closeable by any suitable means, such as moist fireclay plugs.
  • Hot gases produced in the melting chamber 158 include a high proportion of carbon monoxide. These gases travel upwardly through the hot pellets in the conduit 162 and the funnel shaped section 160, thereby enhancing the reduction of the pellets before they enter the melting chamber 158, and supplying further heat to the furnace chamber 114. The gases then join the other waste gases from the first and second combustion chambers 114a and 1 14b.
  • a third embodiment of the retort 210 is illustrated in Figure 3 which, for simplicity, illustrates the basal area of the retort 210 only. Again the third embodiment 210 is essentially similar to the second embodiment 110 and accordingly, like reference numerals refer to like parts.
  • the retort 210 includes two columns 215a and 215b of heat resistant tubes, of which only the respective lowermost tubes 220a and 220b are visible.
  • Each of the columns 215a and 215b are arranged in the same manner as column 115 in the second embodiment (refer to Figure 2).
  • the third embodiment is similar to the second embodiment in that the third embodiment also includes an integral metal melting unit 258.
  • the integral metal melting unit 258 differs from unit 158 in that it comprises an induction heater 276 housed in an insulated melting chamber 264. Induction heaters are commonly used in the foundry industry and it will therefore not be necessary to further explain their operation.
  • the integral metal melting unit 258 is located at the outlet 230 of the furnace chamber 214.
  • the outlet 230 is provided at the lowermost point of an integral funnel shaped section 260 of the furnace chamber 214.
  • the funnel shaped section 260 directs the reduced charge from the furnace chamber 214 into the melting unit 258 via the outlet 230.
  • the gap 228 between the bottom of tube 220 and the funnel shaped section 260 allows evolved gases to escape from the charge as it enters the melting unit 258, which gases are combusted in the chamber 214.
  • an integral metal melting unit 258 at the base of the retort 210 is advantageous for a number of reasons.
  • One reason is that the feed of reduced charge into the metal melting unit 258 is automatically and continuously achieved under gravity by virtue of the melting unit 258 being located vertically underneath the outlet 230 of furnace chamber 214.
  • an induction heater 276 in the metal melting unit 258 is also advantageous.
  • An induction heater 276 provides better control of temperature in the melting unit 258 as compared with a melting unit relying solely on combustion, such as melting unit 158 of the second embodiment herein.
  • the use of the induction heater 276 also facilitates start up of the retort of 210.
  • an induction heater 276 enables higher levels of metal refining, by virtue of being able to maintain high temperatures in the metal melting unit 258 for extended periods of time.
  • impurity removal from molten iron is optimised, especially removal of sulphur, typically by reaction with calcium oxide to produce calcium sulphate.
  • carbon solubility in the iron melt is favoured, thereby enhancing reducing conditions in the melt and permitting retention of desirable species having a strong affinity for oxygen.
  • One such species is magnesium, which is typically easily oxidised.
  • the integral metal melting unit 258 also includes an upper, slag outlet 270 and a lower, molten metal outlet 272.
  • the slag outlet 270 is located above the induction heater 276 and the metal outlet 272 is located below it.
  • any slag phase which forms on top of the molten metal phase is tapped off via the slag outlet 270.
  • the molten metal phase is tapped off via molten metal outlet 272.
  • Both the slag and metal outlets 270, 272 can be closed by removable, moist fireclay plugs.
  • the arrangement of slag and metal outlets 270, 272 requires that metal melting unit 258 be operated in a batch mode.
  • the induction heater 276 requires the chamber 274 of the metal melting unit 258 to contain metal which forms the secondary of a transformer, thereby allowing the induction heater 276 to operate.
  • the chamber 274 is empty, after the molten metal is tapped off, the induction heater 276 cannot operate.
  • FIG. 4 A fourth embodiment of a retort 310 having an integral metal melting unit which operates in a continuous mode is illustrated in Figure 4. Only the basal area of the retort 310 is shown in Figure 4 for simplicity.
  • the fourth embodiment is essentially similar to the third embodiment in Figure 3 and, again, like reference numerals will refer to like parts. For brevity, only those features which differ from the third embodiment will be discussed herein.
  • the retort 310 includes pipes or tuyeres 366, 368 extending into the chamber 374 of the metal melting unit 358.
  • the tuyeres 366, 368 operate similarly to the tuyeres 166, 168 of the second embodiment, with a hot, oxidising gas being injectable therethrough in order to combust carbonaceous material in the charge.
  • the hot oxidising gas may be heated by means of heat exchange with waste gases from furnace chamber 314 using a similar set up as that described in relation to the second embodiment.
  • the metal melting unit 358 is operable in a continuous manner. This is achieved by the location of both the slag and metal outlets 370, 372 above the induction heater 376.
  • This arrangement ensures that the chamber 374 will always contain a metal phase, and typically a slag phase also, at least up to the level of the inlet 378 of the conduit 380 linking the chamber 374 with slag and metal outlets 370, 372.
  • the continual presence of a metal phase in chamber 374 provides the secondary of a transformer, thereby allowing continuous operation of the induction heater 376 and, consequently, continuous operation of the retort 310 (subject to continued throughput of feed).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

L'invention concerne une cornue (10) comprenant un blindage (12) à isolation thermique définissant un laboratoire de four (14); une ou plusieurs colonnes (15) ménagées à l'intérieur dudit laboratoire (14), comprenant chacune une pluralité de tubes (16, 18, 20, 22) résistants à la chaleur, espacés et orientés verticalement. La superficie de la section transversale de chaque tube est plus petite que celle d'un tube inférieur adjacent; les extrémités des tubes adjacents sont conçues de manière à fournir un espace annulaire (24, 26, 28) entre eux. La cornue (10) comprend également un orifice d'entrée (17) à travers lequel passe une charge combustible pour alimenter le tube le plus haut (16); un orifice de sortie (30) à partir duquel la charge qui a réagit est évacuée du tube le plus bas (22); et une canalisation (36) pour fluides permettant d'acheminer des volatiles combustibles émis par chauffage de ladite charge vers des moyens de combustion (32, 31) de gaz, afin d'y être brûlés, de manière à pouvoir fournir de la chaleur à la cornue (10).
PCT/AU2000/001427 1999-11-24 2000-11-23 Cornue WO2001038455A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU15051/01A AU767268B2 (en) 1999-11-24 2000-11-23 Retort

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
AUPQ4227A AUPQ422799A0 (en) 1999-11-24 1999-11-24 Retort
AUPQ4227 1999-11-24
AUPR0384A AUPR038400A0 (en) 2000-09-26 2000-09-26 Retort
AUPR0384 2000-09-26

Publications (1)

Publication Number Publication Date
WO2001038455A1 true WO2001038455A1 (fr) 2001-05-31

Family

ID=25646209

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU2000/001427 WO2001038455A1 (fr) 1999-11-24 2000-11-23 Cornue

Country Status (1)

Country Link
WO (1) WO2001038455A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1565585A1 (fr) * 2002-10-15 2005-08-24 The Australian Steel Company (operations) PTY LTD Procede et appareil d'extraction de zinc
AU2003269603B2 (en) * 2002-10-15 2008-10-30 D. Wilson Investments Pty Ltd Process and apparatus for extracting zinc
CN103087729A (zh) * 2012-08-06 2013-05-08 山西鑫立能源科技有限公司 一种燃烧废气干熄产生可燃高温废气装置
CN103712464A (zh) * 2012-10-09 2014-04-09 丹阳市江南工业炉有限公司 排烟口余热再利用装置
US20190300982A1 (en) * 2016-11-23 2019-10-03 Environmental Clean Technologies Limited Low temperature direct reduction of metal oxides via the in situ production of reducing gas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3963415A (en) * 1975-01-10 1976-06-15 Union Carbide Corporation Method and apparatus for conveying and/or heating coal particles in a dense phase flow
US4399846A (en) * 1980-04-18 1983-08-23 Petroleo Brasileiro S.A. - Petrobras Mechanism for granulometric distribution of solid particles
US4619738A (en) * 1983-09-21 1986-10-28 The United States Of America As Represented By The United States Department Of Energy Apparatus for oil shale retorting
US4732368A (en) * 1985-11-19 1988-03-22 St. Joe Minerals Corporation Apparatus for the pyrometallurgical treatment of finely divided materials

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3963415A (en) * 1975-01-10 1976-06-15 Union Carbide Corporation Method and apparatus for conveying and/or heating coal particles in a dense phase flow
US4399846A (en) * 1980-04-18 1983-08-23 Petroleo Brasileiro S.A. - Petrobras Mechanism for granulometric distribution of solid particles
US4619738A (en) * 1983-09-21 1986-10-28 The United States Of America As Represented By The United States Department Of Energy Apparatus for oil shale retorting
US4732368A (en) * 1985-11-19 1988-03-22 St. Joe Minerals Corporation Apparatus for the pyrometallurgical treatment of finely divided materials
US4732368B1 (fr) * 1985-11-19 1993-04-20 Horsehead Resource Dev Co Inc

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1565585A1 (fr) * 2002-10-15 2005-08-24 The Australian Steel Company (operations) PTY LTD Procede et appareil d'extraction de zinc
EP1565585A4 (fr) * 2002-10-15 2007-01-24 D Wilson Investments Pty Ltd Procede et appareil d'extraction de zinc
AU2003269603B2 (en) * 2002-10-15 2008-10-30 D. Wilson Investments Pty Ltd Process and apparatus for extracting zinc
US7790099B2 (en) 2002-10-15 2010-09-07 David Wilson Investments Pty. Ltd. Process and apparatus for extracting zinc
CN103087729A (zh) * 2012-08-06 2013-05-08 山西鑫立能源科技有限公司 一种燃烧废气干熄产生可燃高温废气装置
CN103087729B (zh) * 2012-08-06 2014-04-30 山西鑫立能源科技有限公司 一种燃烧废气干熄产生可燃高温废气装置
CN103712464A (zh) * 2012-10-09 2014-04-09 丹阳市江南工业炉有限公司 排烟口余热再利用装置
US20190300982A1 (en) * 2016-11-23 2019-10-03 Environmental Clean Technologies Limited Low temperature direct reduction of metal oxides via the in situ production of reducing gas

Similar Documents

Publication Publication Date Title
CN204648253U (zh) 一种危险废物焚烧装置
RU2086869C1 (ru) Способ непрерывного предварительного нагрева шихтовых материалов для сталеплавильной печи и установка для его осуществления
US5042964A (en) Flash smelting furnace
CN201964423U (zh) 一种热解与热解气体二次燃烧一体化焚烧设备
PL193225B1 (pl) Reaktor i sposób zgazowania i/lub stopienia materiałów
KR930009968B1 (ko) 용해로에 의한 제철법
US9574770B2 (en) Start-up torch
US8114185B2 (en) Method of melting a mixture of scrap metal using scrap rubber
US5605104A (en) Method and device for melting down solid combustion residues
JP2002521561A (ja) 幅の狭い頂部を有する溶鉱炉および使用法
UA119892C2 (uk) Металургійна піч для виробництва металевих сплавів
WO2001038455A1 (fr) Cornue
JPH08504937A (ja) コークス燃焼キュポラで鉄系金属材料を溶解する方法及び装置
CN111250510B (zh) 一种分段运行的飞灰熔融处理装置及飞灰熔融处理方法
AU767268B2 (en) Retort
CN110805911A (zh) 一种自排式焚烧垃圾灰渣熔融处理装置
US5518524A (en) Method of reducing emissions from a metal melting furnace
RU2678557C2 (ru) Металлургическая печь
US7909909B2 (en) Method of production of secondary steel based on scrap
RU2323260C2 (ru) Способ получения металлов, имеющих низкую температуру испарения
KR20010075318A (ko) 다중 상로에서의 직접 환원금속 제조방법
US3303257A (en) Apparatus for utilizing waste heat of gas generated from an electric smelting furnace
WO2001020046A1 (fr) Appareil de prefusion a haute temperature
CN101520176B (zh) 热解气化亚熔融炉纯氧条件下放热式催化燃烧方法
RU2044756C1 (ru) Установка для пиролиза твердых бытовых и промышленных отходов

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 15051/01

Country of ref document: AU

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
WWG Wipo information: grant in national office

Ref document number: 15051/01

Country of ref document: AU