WO2001027444A9 - Bearing housing for a turbomachine - Google Patents

Bearing housing for a turbomachine

Info

Publication number
WO2001027444A9
WO2001027444A9 PCT/US2000/026250 US0026250W WO0127444A9 WO 2001027444 A9 WO2001027444 A9 WO 2001027444A9 US 0026250 W US0026250 W US 0026250W WO 0127444 A9 WO0127444 A9 WO 0127444A9
Authority
WO
WIPO (PCT)
Prior art keywords
space
lubrication
lubricant
buffer
turbomachine
Prior art date
Application number
PCT/US2000/026250
Other languages
French (fr)
Other versions
WO2001027444A1 (en
Inventor
Anatoly Rakhmailov
Original Assignee
Alm Dev Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alm Dev Inc filed Critical Alm Dev Inc
Priority to AU10710/01A priority Critical patent/AU1071001A/en
Priority to JP2001529559A priority patent/JP2003511618A/en
Priority to KR1020027004717A priority patent/KR20020044164A/en
Priority to EP00971984A priority patent/EP1224382A1/en
Publication of WO2001027444A1 publication Critical patent/WO2001027444A1/en
Publication of WO2001027444A9 publication Critical patent/WO2001027444A9/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/66Special parts or details in view of lubrication
    • F16C33/6637Special parts or details in view of lubrication with liquid lubricant
    • F16C33/6685Details of collecting or draining, e.g. returning the liquid to a sump
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/18Lubricating arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D11/00Preventing or minimising internal leakage of working-fluid, e.g. between stages
    • F01D11/02Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type
    • F01D11/04Preventing or minimising internal leakage of working-fluid, e.g. between stages by non-contact sealings, e.g. of labyrinth type using sealing fluid, e.g. steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/18Lubricating arrangements
    • F01D25/183Sealing means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C19/00Bearings with rolling contact, for exclusively rotary movement
    • F16C19/02Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
    • F16C19/14Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load
    • F16C19/18Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls
    • F16C19/181Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact
    • F16C19/183Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact with two rows at opposite angles
    • F16C19/184Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for both radial and axial load with two or more rows of balls with angular contact with two rows at opposite angles in O-arrangement
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2360/00Engines or pumps
    • F16C2360/23Gas turbine engines
    • F16C2360/24Turbochargers

Definitions

  • the invention relates to the lubrication of turbomachines, and more specifically to a bearing lubrication system for a gas turbine engine.
  • Lubricant is supplied to the lubrication space through, e.g., a mist forming nozzle, and the lubricant is removed from the lubrication space through a drain by gravity or by means of a scavenging pumps.
  • the lubrication system of this type usually requires a separator to separate oil from the air, because the lubricant contains air and gas owing to the pressure fluctuations in the fluid space. The lubricant is recovered from the bottom of the separator, and the air escapes through an exhaust duct.
  • the gage pressure which normally prevails outside the lubrication chamber suddenly drops for a certain time period below the pressure in the lubrication chamber. This will cause lubricant to escape from the lubrication space, resulting in the lubricant entering the fluid space of the gas turbine engine.
  • the negative impact of such lubricant leak into the fluid space of a gas turbine engine is well known to those skilled in the art.
  • the lubricant tank level will drop substantially, and the system may lack lubricant.
  • a prior art depressurization device disclosed in US Patent No. 5,429,208 to Christian Largiller et al. was aimed at eliminating this disadvantage.
  • the depressurization device is made in the form of a jet nozzle which communicates with the lubrication space.
  • the jet nozzle ejects air (with lubricant) from the lubrication space using air from the engine compressor as a carrier fluid.
  • a sensor in a control circuit sends a signal to a valve to open the jet nozzle to the compressor.
  • the excessive air (with lubricant) is removed from the lubrication space to establish a reduced pressure in the lubrication space.
  • Prior art bearing lubrication systems such as that described above require lubricant/air separators because the lubrication chamber is pressurized.
  • the lubricant/oil separators are devices that have to be manufactured and installed on the gas turbine engine.
  • the lubricant/air separators consume a certain amount of the engine output power, thus lowering engine efficiency.
  • the depressurization of the lubrication space during engine deceleration requires the provision of a jet nozzle or an evacuation pump and a control system with a sensor and controls to activate the depressurization system.
  • Apart from the added cost of these devices their use in gas turbine engine impairs its reliability. These devices require periodic checks and maintenance. A malfunction of one of these devices may result in lubricant entering the fluid space of the gas turbine engine.
  • Another object of the invention is to provide a bearing lubrication system for a turbomachine which would be reliable in operation. Further object of the invention is to provide a bearing lubrication system for a turbomachine which requires minimum maintenance. Still another object of the invention to provide ' a bearing lubrication system for a turbomachine which would be simple in design and easy to manufacture.
  • a bearing lubrication system for a turbomachine having a lubrication chamber that defines a lubrication space surrounding the bearings, lubricant feeding devices for supplying lubricant to the lubrication space, a lubricant removing device for removing lubricant from the lubrication space, and a buffer case surrounding the lubrication chamber, located in the fluid space of the turbomachine, and defining a buffer space communicating with the atmosphere.
  • Shaft contact seals are provided between the buffer case and the fluid space and shaft seals are provided between the buffer space and the lubrication space.
  • Fig. 1 is a schematic sectional view that shows a bearing lubrication system for a turbomachine according to the invention
  • Fig. 2 is another embodiment of a bearing lubrication system for a turbomachine according to the invention, which shows details of sealing.
  • a turbomachine 10 which can be, among other machines, a gas turbine engine, has a fluid space 14 communicating with the gas turbine engine flow duct in which a gas turbine 12 and a compressor 15 are installed. Turbine 14 and compressor 15 are installed on a shaft 16. Shaft 16 is supported by bearings 18 and 20 which are installed in a lubrication chamber 22. Lubrication chamber 22 is made as a closed chamber in a turbomachine casing 23. The lubrication chamber 22 has a lubrication space shown at LS which is used to lubricate bearings 18 and 22. Devices 24 feed lubricant into the lubrication space LS.
  • Lubrication chamber 22 has a drain 26 to remove from lubrication space LS lubricant splashing from bearings 18 and 20. Drain 26 may be connected to a lubricant tank (not shown) to remove lubricant by gravity, or it may be connected to a scavenging pump (not shown) which removes lubricant and pumps it back to the lubricant tank.
  • a lubricant tank not shown
  • a scavenging pump not shown
  • a buffer case 28 is provided in fluid space 12, and this buffer case is surrounded by fluid space 12.
  • Buffer case 28 surrounds the lubrication chamber 22 and communicates with the atmosphere through an opening 30 as shown by arrow A. It will be understood that lubrication chamber 22 will be under the pressure that establishes in the interior or buffer space BF of buffer case 28 (which is about equal to the atmospheric pressure). The pressure in lubrication chamber 22 will never be higher than atmospheric pressure.
  • Buffer case 28 is separated from fluid space 12 of gas turbine engine 10 by contact seals 32 and 34.
  • Contact seals 32 and 34 allow only a minimal leak from fluid space 12 into buffer space BS if the fluid pressure in the fluid space is greater than atmospheric pressure, or they allow only a minimal leak of air or gas from buffer space BS into fluid space 12. In any case, the pressure in buffer space BS will always be about equal to atmospheric pressure.
  • the lubrication space LS of lubrication chamber 22 is separated from buffer space BS of buffer case 28 by seals 36 and 38. Seals 36 and 38 are provided to prevent oil from escaping from lubrication space LS 22 into buffer space BS 22 from which oil might escape into the atmosphere. As shown in Fig. 1, all contact seals 32 and 36 are made as brush seals.
  • Brush seals are known in the art. As an example, the construction of a brush seal is disclosed in U.S. Patent 5,201,530. Brush seals 32 and 34 ensure a minor gas leakage from fluid space 12 into buffer space BS of buffer case 22. Any leakage will escape to the atmosphere, so with any leakage flow through brush seals 32 and 34, the pressure in buffer space BS will be about atmospheric pressure.
  • Fig. 2 which illustrates another embodiment of the invention in which the same parts are shown at the same reference numerals as in Fig. 1 with the addition of 100
  • the shaft contact seals 132 and 134 are made as brush seals as shown in the left-hand part and in the right hand part of the drawing.
  • Shaft seals 136 separating the lubrication space LS of lubrication chamber 122 from buffer space BS of buffer case 128 may be made as the contact seals (as shown in left hand part of the drawing in Fig. 2).
  • shaft seals 138 separating the lubrication space LS of the lubrication chamber 122 from the buffer space BS of the buffer case 128 may be made as labyrinth seals (as shown in the right hand part of the drawing in Fig. 2) or any other type of seal. Their main function is to minimize lubricant flow from lubrication space LS into buffer space BS.
  • the invention prevents lubricant from escaping into the fluid space of a turbomachine or into the atmosphere without using complicated mechanical devices and control systems.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

A bearing lubrication system for a turbomachine having a lubrication chamber which defines a lubrication space (LS) surrounding the bearings (18, 20) has lubricant feeding devices (24) for supplying lubricant to the lubrication space (LS), a lubricant removing device (26) for removing lubricant from the lubrication space (LS), and a buffer case (BS) surrounding the lubrication chamber (22), that is located in the fluid space (BS) of the turbomachine, and defines a buffer space communicating with the atmosphere. Shaft contact seals (32, 34) are provided between the buffer case (BS) and the fluid space, and shaft seals (36, 38) are provided between the buffer space (BS) and the lubrication space (LS).

Description

BEARING HOUSING FOR A TURBOMACHINE
This application cross-references nine co-pending U.S. patent applications, Serial Nos. 09/161,104, 09/161,114, 09/161,115 and 09/161,170, all of which were filed on September 25, 1998, and Serial Nos. 09/267,893, 09/267,894, 09/267,895, 09/267,896 and 09/267,897 all of which were filed on March 11, 1999, and also four co-pending U.S. provisional patent applications, Serial Nos. 60/159,066, 60/159,065, 60/158,934 and 60/158/935, all of which were filed on October 12, 1999. Each of the above is incorporated by reference herein.
The invention relates to the lubrication of turbomachines, and more specifically to a bearing lubrication system for a gas turbine engine.
Background of the Invention
It is a common practice in gas turbine engines to provide a lubrication chamber surrounding the shaft bearings using seals that separate the interior space, or lubrication space, of the lubrication chamber from the fluid space of the gas turbine engine. Lubricant is supplied to the lubrication space through, e.g., a mist forming nozzle, and the lubricant is removed from the lubrication space through a drain by gravity or by means of a scavenging pumps. The lubrication system of this type usually requires a separator to separate oil from the air, because the lubricant contains air and gas owing to the pressure fluctuations in the fluid space. The lubricant is recovered from the bottom of the separator, and the air escapes through an exhaust duct. If the speed of the gas turbine engine falls below a certain level, the gage pressure which normally prevails outside the lubrication chamber suddenly drops for a certain time period below the pressure in the lubrication chamber. This will cause lubricant to escape from the lubrication space, resulting in the lubricant entering the fluid space of the gas turbine engine. The negative impact of such lubricant leak into the fluid space of a gas turbine engine is well known to those skilled in the art. In addition, if a large quantity of lubricant escapes from the lubrication system, the lubricant tank level will drop substantially, and the system may lack lubricant.
A prior art depressurization device disclosed in US Patent No. 5,429,208 to Christian Largiller et al. was aimed at eliminating this disadvantage. The depressurization device is made in the form of a jet nozzle which communicates with the lubrication space. The jet nozzle ejects air (with lubricant) from the lubrication space using air from the engine compressor as a carrier fluid. When the speed of the gas turbine engine drops below a certain level, and there is a danger of the pressure in the fluid space of the engine falling below the pressure in the lubrication space, a sensor in a control circuit sends a signal to a valve to open the jet nozzle to the compressor. As a result, the excessive air (with lubricant) is removed from the lubrication space to establish a reduced pressure in the lubrication space.
Prior art bearing lubrication systems such as that described above require lubricant/air separators because the lubrication chamber is pressurized. The lubricant/oil separators are devices that have to be manufactured and installed on the gas turbine engine. In addition, the lubricant/air separators consume a certain amount of the engine output power, thus lowering engine efficiency. The depressurization of the lubrication space during engine deceleration requires the provision of a jet nozzle or an evacuation pump and a control system with a sensor and controls to activate the depressurization system. Apart from the added cost of these devices, their use in gas turbine engine impairs its reliability. These devices require periodic checks and maintenance. A malfunction of one of these devices may result in lubricant entering the fluid space of the gas turbine engine.
It should be added that even a small quantity of lubricant which inevitably escapes from the lubrication system with air leaving the lubricant/air separator (because even the best separators cannot ensure the 100% separation), as well as the lubricant that escapes from the jet nozzle is irrecoverably lost. Moreover, the discharge of the lubricant into the open air has an adverse effect on the environment. It is thus an object of the invention to provide a bearing lubrication system for a turbomachine which would prevent pressure from increasing in the lubrication space.
Another object of the invention is to provide a bearing lubrication system for a turbomachine which would be reliable in operation. Further object of the invention is to provide a bearing lubrication system for a turbomachine which requires minimum maintenance. Still another object of the invention to provide' a bearing lubrication system for a turbomachine which would be simple in design and easy to manufacture.
One more, it is an object of the invention to prevent lubricant from being irrecoverably lost. Finally, it is an object of the invention to prevent the adverse environmental effect of lubricant.
Summary of the Invention
The above and other objects of the invention are accomplished by providing a bearing lubrication system for a turbomachine having a lubrication chamber that defines a lubrication space surrounding the bearings, lubricant feeding devices for supplying lubricant to the lubrication space, a lubricant removing device for removing lubricant from the lubrication space, and a buffer case surrounding the lubrication chamber, located in the fluid space of the turbomachine, and defining a buffer space communicating with the atmosphere. Shaft contact seals are provided between the buffer case and the fluid space and shaft seals are provided between the buffer space and the lubrication space.
These and other objects and advantages of the invention will become apparent from the following detailed description of preferred embodiments of a bearing lubrication system for a turbomachine, in which:
Brief Description of the Drawings
Fig. 1 is a schematic sectional view that shows a bearing lubrication system for a turbomachine according to the invention;
Fig. 2 is another embodiment of a bearing lubrication system for a turbomachine according to the invention, which shows details of sealing.
Detailed Description of the Drawings
In Fig. 1, a turbomachine 10, which can be, among other machines, a gas turbine engine, has a fluid space 14 communicating with the gas turbine engine flow duct in which a gas turbine 12 and a compressor 15 are installed. Turbine 14 and compressor 15 are installed on a shaft 16. Shaft 16 is supported by bearings 18 and 20 which are installed in a lubrication chamber 22. Lubrication chamber 22 is made as a closed chamber in a turbomachine casing 23. The lubrication chamber 22 has a lubrication space shown at LS which is used to lubricate bearings 18 and 22. Devices 24 feed lubricant into the lubrication space LS. These devices may be spray nozzles for generating a lubricant mist in the lubrication space LS in proximity to bearings 18 and 20. Lubrication chamber 22 has a drain 26 to remove from lubrication space LS lubricant splashing from bearings 18 and 20. Drain 26 may be connected to a lubricant tank (not shown) to remove lubricant by gravity, or it may be connected to a scavenging pump (not shown) which removes lubricant and pumps it back to the lubricant tank. The systems for lubricant supply and removal are well known to those skilled in the art are not discussed in detail here. These systems would normally use lubricant/air separators to separate lubricant from the air and gas that would be present in the lubricant leaving the lubrication chamber in the conventional lubrication systems. Such lubricant/air separators are not used in the bearing lubrication system of a turbomachine according to the invention.
A buffer case 28 is provided in fluid space 12, and this buffer case is surrounded by fluid space 12. Buffer case 28 surrounds the lubrication chamber 22 and communicates with the atmosphere through an opening 30 as shown by arrow A. It will be understood that lubrication chamber 22 will be under the pressure that establishes in the interior or buffer space BF of buffer case 28 (which is about equal to the atmospheric pressure). The pressure in lubrication chamber 22 will never be higher than atmospheric pressure.
Buffer case 28 is separated from fluid space 12 of gas turbine engine 10 by contact seals 32 and 34. Contact seals 32 and 34 allow only a minimal leak from fluid space 12 into buffer space BS if the fluid pressure in the fluid space is greater than atmospheric pressure, or they allow only a minimal leak of air or gas from buffer space BS into fluid space 12. In any case, the pressure in buffer space BS will always be about equal to atmospheric pressure. The lubrication space LS of lubrication chamber 22 is separated from buffer space BS of buffer case 28 by seals 36 and 38. Seals 36 and 38 are provided to prevent oil from escaping from lubrication space LS 22 into buffer space BS 22 from which oil might escape into the atmosphere. As shown in Fig. 1, all contact seals 32 and 36 are made as brush seals. Brush seals are known in the art. As an example, the construction of a brush seal is disclosed in U.S. Patent 5,201,530. Brush seals 32 and 34 ensure a minor gas leakage from fluid space 12 into buffer space BS of buffer case 22. Any leakage will escape to the atmosphere, so with any leakage flow through brush seals 32 and 34, the pressure in buffer space BS will be about atmospheric pressure.
In Fig. 2, which illustrates another embodiment of the invention in which the same parts are shown at the same reference numerals as in Fig. 1 with the addition of 100, the construction of the lubrication system is the same as that shown in Fig. 1. The shaft contact seals 132 and 134 are made as brush seals as shown in the left-hand part and in the right hand part of the drawing. Shaft seals 136 separating the lubrication space LS of lubrication chamber 122 from buffer space BS of buffer case 128 may be made as the contact seals (as shown in left hand part of the drawing in Fig. 2). On the other hand, shaft seals 138 separating the lubrication space LS of the lubrication chamber 122 from the buffer space BS of the buffer case 128 may be made as labyrinth seals (as shown in the right hand part of the drawing in Fig. 2) or any other type of seal. Their main function is to minimize lubricant flow from lubrication space LS into buffer space BS.
It will be apparent from the above description that the invention prevents lubricant from escaping into the fluid space of a turbomachine or into the atmosphere without using complicated mechanical devices and control systems.

Claims

I claim:
1. In a bearing lubrication system for a turbomachine having a fluid space and a shaft installed in bearings:
- a lubrication chamber, said lubrication chamber having a lubrication space surrounding said bearings;
- a lubricant feeding means for supplying lubricant to said lubrication space;
- a lubricant removing means for removing lubricant from said lubrication space; - a buffer case located in said fluid space having a buffer space communicating with the atmosphere, said buffer case surrounding said lubrication chamber;
- shaft contact sealing means provided between said buffer case and said fluid space; and - shaft sealing means provided between said buffer space and said lubrication space.
2. The bearing lubrication system of claim 1, wherein said shaft contact sealing means comprises brush seals.
3. The bearing lubrication system of claim 1, wherein said shaft sealing means comprises contact seals.
4. The bearing lubrication system of claim 2, wherein said shaft sealing means comprises contact seals.
PCT/US2000/026250 1999-10-12 2000-10-11 Bearing housing for a turbomachine WO2001027444A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU10710/01A AU1071001A (en) 1999-10-12 2000-10-11 Bearing housing for a turbomachine
JP2001529559A JP2003511618A (en) 1999-10-12 2000-10-11 Bearing lubrication system for turbomachinery
KR1020027004717A KR20020044164A (en) 1999-10-12 2000-10-11 Bearing housing for a turbomachine
EP00971984A EP1224382A1 (en) 1999-10-12 2000-10-11 Bearing housing for a turbomachine

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US15892999P 1999-10-12 1999-10-12
US60/158,929 1999-10-12
US63256500A 2000-08-04 2000-08-04
US09/632,565 2000-08-04

Publications (2)

Publication Number Publication Date
WO2001027444A1 WO2001027444A1 (en) 2001-04-19
WO2001027444A9 true WO2001027444A9 (en) 2002-10-03

Family

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PCT/US2000/026250 WO2001027444A1 (en) 1999-10-12 2000-10-11 Bearing housing for a turbomachine

Country Status (7)

Country Link
US (1) US20040003968A1 (en)
EP (1) EP1224382A1 (en)
JP (1) JP2003511618A (en)
KR (1) KR20020044164A (en)
CN (1) CN1399706A (en)
AU (1) AU1071001A (en)
WO (1) WO2001027444A1 (en)

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JP2003511618A (en) 2003-03-25
CN1399706A (en) 2003-02-26
KR20020044164A (en) 2002-06-14
US20040003968A1 (en) 2004-01-08
WO2001027444A1 (en) 2001-04-19
AU1071001A (en) 2001-04-23
EP1224382A1 (en) 2002-07-24

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