WO2001005246A2 - A process for the preparation of a composition comprising at least one emulsifier and at least one edible fibre - Google Patents

A process for the preparation of a composition comprising at least one emulsifier and at least one edible fibre Download PDF

Info

Publication number
WO2001005246A2
WO2001005246A2 PCT/IB2000/001132 IB0001132W WO0105246A2 WO 2001005246 A2 WO2001005246 A2 WO 2001005246A2 IB 0001132 W IB0001132 W IB 0001132W WO 0105246 A2 WO0105246 A2 WO 0105246A2
Authority
WO
WIPO (PCT)
Prior art keywords
fibre
composition
emulsifier
edible
integrated
Prior art date
Application number
PCT/IB2000/001132
Other languages
French (fr)
Other versions
WO2001005246A3 (en
Inventor
Bent Jensen
Original Assignee
Danisco A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9916905.4A external-priority patent/GB9916905D0/en
Application filed by Danisco A/S filed Critical Danisco A/S
Priority to AU63106/00A priority Critical patent/AU6310600A/en
Priority to GB0130962A priority patent/GB2366984B/en
Priority to MXPA02000758A priority patent/MXPA02000758A/en
Publication of WO2001005246A2 publication Critical patent/WO2001005246A2/en
Publication of WO2001005246A3 publication Critical patent/WO2001005246A3/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A21—BAKING; EDIBLE DOUGHS
    • A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14—Organic oxygen compounds
    • A21D2/16—Fatty acid esters
    • A—HUMAN NECESSITIES
    • A21—BAKING; EDIBLE DOUGHS
    • A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14—Organic oxygen compounds
    • A21D2/18—Carbohydrates
    • A21D2/188—Cellulose; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A21—BAKING; EDIBLE DOUGHS
    • A21D—TREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/36—Vegetable material
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
    • A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
    • A23L33/22—Comminuted fibrous parts of plants, e.g. bagasse or pulp
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10—Cereal-derived products
    • A23L7/115—Cereal fibre products, e.g. bran, husk
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00—Shaping or working of foodstuffs characterised by the products
    • A23P10/30—Encapsulation of particles, e.g. foodstuff additives
    • A23P10/35—Encapsulation of particles, e.g. foodstuff additives with oils, lipids, monoglycerides or diglycerides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00—Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/40—Foaming or whipping
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Mycology (AREA)
  • Molecular Biology (AREA)
  • Botany (AREA)
  • Biophysics (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Medicinal Preparation (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Seasonings (AREA)

Abstract

There is provided a process for the preparation of composition comprising at least one emulsifier and at least one edible fibre, the process comprising i) providing an initial composition comprising the emulsifier in a melted form and the edible fibre, ii) spray crystallising the initial composition such that the emulsifier crystallises and the emulsifier and the edible fibre are integrated.

Description

COMPOSITION
The present invention relates to an integrated composition comprising an emulsifier and an edible fibre.
Integrated blends of emulsifiers and additional components such as stabilisers are known in the art. For example GB-A- 1082283 (to a predecessor of the present applicant) relates to a particulate combined emulsifier and stabiliser composition. The composition is used in the preparation of edible and drinkable products.
GB-A- 1082283 addresses the problems of providing mixtures of emulsifier and stabiliser. GB-A- 1082283 discusses that emulsifier and stabilisers are commonly used in the production of foodstuffs, either alone or in combination. It is described that emulsifiers alone may give an unsatisfactory effect and therefore fail to form a satisfactory dispersion, emulsion or suspension. It is described that stabilisers are generally hydrophilic. On hydration prior to dispersion/dissolution in aqueous media, it is often found that stabilisers have a tendency to form lumps. This tendency to form lumps has been addressed by the use of wetting agents or suspension of the stabilisers in anhydrous organic liquids such as ethyl alcohol. Both of these proposed solutions are discussed as being disadvantageous.
GB-A- 1082283 also describes how combinations of stabiliser and emulsifier have previously been provided in the form of a simple mixture of the two components. However, separation may occur in transit resulting in the problems of the individual components previously discussed and, in addition, incorrect dosing on use because of variation in the amounts of the components within a given batch.
GB-A- 1082283 addresses the problems discussed by providing a particulate combined emulsifier and stabiliser composition. The composition is provided in an integrated (encapsulated) form to make the powder composition more convenient for use. GB-A- 1082283 teaches that the combined system may be obtained by spray-drying, although drying on belts or drums is also envisaged. The products of GB-A-1082283 have been used in the industry for the preparation of highfat cakes. In highfat cakes the whipability of the cake batter is not critical.
Whilst the teachings of GB-A-1082283 have been useful in the provision of stabiliser and emulsifier to foodstuffs, there is a desire to provide a stabiliser and emulsifier combination which provides further improved properties of foodstuffs or which may be readily used in low fat products, such as low fat bakery products.
The supply of stabiliser/emulsifier combinations has also been achieved by the provision of cake gels and cake hydrates. These systems have a number of well recognised disadvantages. They are inconvenient to use and may require preparation by the end user (this involves hydration and subsequent handling of a greasy gels). Moreover, the shelf life of bakery products prepared with such systems, such as cakes, is rather short. Yet further disadvantages include the limited possibilities of modifying cake texture and surface, no possibility of adding extra water to the cake recipe and it is not possible to use them in a full cake mix.
Powdered sponge improvers have also been provided. However, like cake gels and cake hydrates, the shelf life of bakery products, such as cakes, prepared with such systems is rather short. Moreover, there are limited possibilities of modifying cake surface and texture and there a limited possibility of adding extra water to the cake recipe.
Systems comprising emulsifiers integrated with additional components are know in the art. For example, GB-A- 1062423 discloses the integration of cellulose, a non-dietary fibre, and an emulsifier. The components are integrated by methods such as spray drying.
EP-A-0153870 relates to a powder product comprising one or more surface-active substances applied on a carrier. The carrier may be selected from bran products such as beanbran. The surface active material may be an emulsifier. A product is obtained by extrusion of the surface-active substance and carrier. ~, WO-A-95/20328 teaches a composite of a particulate cellulose and one or more surfactants such as an emulsifier absorbed onto the surface of this cellulose.
US-A-5658609 relates to a fat replacer system using an emulsifier and in one alternative a vegetable fibre. The system is prepared by spray drying the components together.
The present invention alleviates the problems of the prior art.
In one aspect the present invention provides a process for the preparation of composition comprising at least one emulsifier and at least one edible fibre, the process comprising i) providing an initial composition comprising the emulsifier in a melted form and the edible fibre, ii) spray crystallising the initial composition such that the emulsifier crystallises and the emulsifier and the edible fibre are integrated.
By the term "integrated" it is meant that at least some particles of the composition of the present invention comprise both the emulsifier and the edible fibre. Preferably by the term it is meant that the edible fibre is encapsulated by the emulsifier.
The term "edible fibre" is commonly used in the art and is analogous to the term "dietary fibre". By the term "edible fibre" it is meant the edible parts of plants, or analogous carbohydrates, that are resistant to digestion and absorption in the human small intestine with complete or partial fermentation in the large intestine. This is the consensus definition of the American Association of Cereal Chemists (AACC) Dietary Fibre Definition Committee.
Emulsifiers used in the preparation of products such as whipped products are generally in the α-crystal form, which facilitates the uptake of water in to the composition. When the composition is contacted with water the emulsifier quickly brings the water into the composition. It is generally understood that spray dried emulsifier products are able to provide emulsifier in the α-crystal form. This is because spray-drying retains emulsifier provided in the α-crystal form predominantly in that form. In view of this understanding in the art prior art systems have typically used spray drying to produce an integrated system. A significant disadvantage of using spray drying however is that large amounts of water or other solvents are removed from the composition during the drying process. The removal of water/solvent is at a substantial energy cost. A further significant disadvantage is that spray crystallisation requires the addition to the composition to be sprayed of a carrier material. This material, which does not add to the functionality to the final product, adds to production and transport costs. Moreover, the carrier material, if incorporated in a final food product may have to be declared as an additive in an ingredients list.
We have surprisingly found that by spray crystallising the initial composition an integrated composition is obtained in which channels are formed in the emulsifier. When contacted with water, the water will access this channel system. These channels allow for improved ingress of the water into the integrated composition. The improved ingress provides more rapid disintegration of the product and improved functional properties. This result is surprising and allows for the provision of an integrated product which has acceptable disintegration properties yet does not require production by energy consuming techniques such as spray drying.
The spray crystallised products of the present invention provide further advantages. Spray crystallisation provides particles which are more uniform and generally more spherical in shape than particles produced by alternative methods. These more regular and more spherical particles have improved flow properties compared to the alternatively produced products. In particular extruded products provide irregular or jagged particles. Such particles have poor flow properties. Moreover, spray crystallisation allows for the production of particles larger than those which may be provided by spray drying. For example, spray crystallisation may provide particles with an average diameter of 500 to 800 μm. Larger particles generally speaking have improved flow properties and produce less dust on handling.
The present invention provides an integrated composition comprising an emulsifier and an edible fibre. For example, the edible fibre is encapsulated by the emulsifier. The blend may be used in the production of cakes, in particular for whipped sponge low-fat sponge cake. By integrating the edible fibre and the emulsifier using spray crystallisation, we may improve the whipability of products prepared with the emulsifier by approximately up to 40%.
Preferably the initial composition of the process of the present invention is substantially free of free water.
By the term "free water" it is meant water which is not incorporated within one of the constituents of the initial composition. For example, water may be present in the edible fibre of the present invention. This is not free water.
By the term "substantially free of free water" it is meant having a free water content of preferably less than 20 wt%, preferably less than 15 wt%, preferably less than 10 wt%, preferably less than 5 wt%, preferably less than 2 wt %, more preferably less than 1 wt%, more preferably less than 0.5 wt%, yet more preferably less than 0.1 wt%.
In contrast to the present invention spray drying of compositions is always performed in the presence of free water, for example a free water content of 40-98 wt%.
In a further aspect of the present invention, the initial composition consists essentially of the emulsifier and the edible fibre.
The composition of the present invention may be used in the preparation of a variety of foodstuffs. Foodstuffs include bakery products prepared from bakery batters such as cake batters and whipping systems such as toppings, whipping agents for creams.
The composition of the present invention may be in the form of a free-flowing non-dusty powder which consists of small uniform beads. The flowability of the composition may be improved by the addition of anti-caking agent. The emulsifier part imparts a good whipability to the batter. Water loss during baking of a product of the present invention is reduced, resulting in a higher water content of the finished cake. It has been identified that this provides a prolonged shelf life. It has been found that when compared to prior art systems, the emulsifier and fibre composition of the present invention, the shelf life of Swiss rolls may be prolonged from 12 days to at least 21 days, and may be up to 1 month.
It is also found that the composition of the present invention gives resilience to a cake. This is particularly advantageous in cakes which are manipulated after baking. For example the present composition may improve the reliability of a Swiss roll without breaking.
As discussed above the present invention relates to a process for the preparation of composition comprising at least one emulsifier and at least one edible fibre, the process comprising i) providing an initial composition comprising the emulsifier in a melted form and the edible fibre, ii) spray crystallising the initial composition such that the emulsifier crystallises and the emulsifier and the edible fibre are integrated.
FIBRE
The term edible fibre includes polysaccharides, oligosaccharides, lignin and associated plant substances.
Preferably the edible fibre is selected from sugar beet fibre, apple fibre, pea fibre, wheat fibre, oat fibre, barley fibre, rye fibre, rice fibre, potato fibre, tomato fibre, other plant non-starch polysaccharide fibres, and combinations thereof.
More preferably the edible fibre comprises at least sugar beet fibre.
EMULSIFIER
Preferably the emulsifier of the composition of the present invention is selected from propylene glycol monostearate (PGMS), sodium stearoyl lactylate (SSL), calcium stearoyl lactylate (CSL), monoglycerides, diglycerides, monodiglycerides, polyglycerol esters, lactic acid esters, polysorbate, sucrose esters, diacetyl tartaric acid esters of monodiglycerides (DATEM), citric acid esters of monoglycerides (CITREM) and combinations thereof.
The emulsifier of the composition of the present invention may also be selected from DIMODAN including DIMODAN® B 727 and DIMODAN® PV, GRINDSTED™ CITREM, GRINDSTED™ GA, GRINDSTED™ PS such as GRINDSTED™ PS 100, GRINDSTED™ PS 200, GRINDSTED™ PS 300, GRINDSTED™ PS 400; RYLO™ (manufactured and distributed by DANISCO CULTOR), including RYLO™ AC, RYLO™ CI, RYLO™ LA, RYLO™ MD, RYLO™ MG, RYLO™ PG, RYLO™ PR, RYLO™ SL, RYLO™ SO, RYLO™ TG; and combinations thereof.
In aspects the emulsifier may be in alpha crystal form or in beta crystal form. When the composition of the present invention is used in a whippable product such as a cake batter, the emulsifier is preferably in alpha crystal form. In this aspect the composition preferably contains propylene glycol monostearate (PGMS), and/or sodium calcium stearoyl lactylate (C/SSL). When the composition of the present invention is used in a product in which whipability is not required, such as in bread dough, the emulsifier may be in beta crystal form.
The composition may comprise at least two emulsifiers. The composition may comprise three emulsifiers
EMULSIFER IMPROVER
In addition to the emulsifier and the edible fibre, the composition of the present invention may further comprise an emulsifier improver. The emulsifier improver may be incorporated in the initial composition and spray crystallised with the composition or may be added after spray crystallisation of the edible fibre and emulsifier. By the term "emulsifier improver" it is meant a material which enhances the distribution and/or emulsifying action of an emulsifier when compared to the distribution and/or emulsifying action of the emulsifier in absence of the material.
The emulsifier improver of the present composition may be a swelling improver or a non- swelling improver. By the terms "swelling" and "non-swelling" it is meant the properties of the emulsifier improver on contact of the present composition with water.
The emulsifier improver may be selected from hydrocolloids, fibres, salts, proteins, sugars and combinations thereof.
In one aspect the emulsifier improver is other than a salt alone. In other words, if the emulsifier improver comprises a salt, the improver comprises at least one further improver other than a salt.
In one further aspect when the emulsifier is a distilled monoglyceride, the emulsifier improver is other than calcium propionate alone. In other words, when the emulsifier is a distilled monoglyceride, if the emulsifier improver comprises calcium propionate, the improver comprises at least one further improver other than calcium propionate.
The hydrocolloids may be selected from alginate, carrageenan, carboxymethyl cellulose (CMC), guar gum, locust bean gum (LBG), xanthan gum, microcrystalline cellulose (MCC), methyl cellulose (MC), cellulose ethers including hydroxy propyl methyl cellulose (HPMC), pectin, starch including native and modified starch, pregelatinated starch and non-pregelatinated starch, including starch from corn, potato, tapioca, wheat, and rice, gelatin, agar, and combinations thereof.
The fibres may be selected from the fibres described above.
The salts may be selected from baking powder systems, ammonium carbonate, salts in general including sodium chloride, and combinations thereof. The proteins may be selected from milk proteins, wheat proteins, pea proteins, soy proteins, buckwheat proteins, carob proteins, barley proteins, oat proteins, rice proteins, rye proteins, gelatin, whey proteins, and combinations thereof.
The sugars may be selected from sucrose, lactose, glucose, maltose and combinations thereof.
The composition may comprise from 1 to 3 emulsifier improvers.
It has been identified that specific emulsifier improvers in compositions of the present invention provide particularly advantageous properties. These combinations include, but are not limited to, the emulsifier improver comprising
• at least pectin and carrageenan, (preferably in a ratio of 20:80 to 40:60, with respect to each other, preferably approximately 30:70) • at least pectin and guar gum (preferably present in a ratio of 30:70 to 70:30 with respect to each other, preferably 40:60 to 60:40, more preferably 45:55 to 55:45)
• at least sugar beet fibre
• at least a baking powder, preferably wherein the baking powder consists of 40-60 wt% di-Na-pyrophosphate, and 40-60 wt% Na-bicarbonate
COMPOSITIONS
It is to be appreciated that the product obtainable and/or obtained by the process of the present invention is encompassed by the present invention. Accordingly in further aspects the present invention provides
• a composition obtainable by the process of the present invention
• a composition obtained by the process of the present invention
The composition of the present invention may be used in the preparation of any number of products, in particular food products such as bakery foodstuffs and whipped foodstuffs. Thus in further aspects, the present invention provides
• a bakery product comprising or prepared from a composition of the present invention. • a whipped foodstuff comprising or prepared from a composition of the present invention.
Further aspects of the invention include
• use of a composition for improving the crumb structure of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated.
• use of a composition for increasing the storage life of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated. • use of a composition for increasing the flexibility of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated.
It has been found that compositions of the present invention may exhibit one or more of the following advantages • is produced by a low energy method
• has excellent flow properties
• may improve the whipping effect and thereby the volume of a bakery product such as a baked cake.
• is convenient in use since it is a powder product and can be applied in all-in-bakery procedures.
• has excellent water binding properties.
• provides improved tolerance towards mixer type and mixing time.
• can be applied in full foodstuff mixes such as cake mixes.
• gives excellent moisture retention during baking. • produce excellent product surface and texture and give many more possibilities of modifying these two parameters than in the prior art systems.
• showed excellent stability in full cake mixes, up to at least approximately 1 year.
• provides the possibility of adding up to 5% extra water to foodstuff (e.g., cake) recipes.
• dramatic prolongation of the shelf life of the baked products, such as cake. Cakes with a shelf life of 2-3 days will easily, by using a composition of the present invention, end with a shelf life of 1-2 weeks. Cakes with a shelf life of 1 week will have an extra 2-3 weeks and cakes with a shelf life of 1 month will have an extra 1-2 months, etc. • excellent resilience in the cakes
Further broad aspects of the present invention include
• a process for the preparation of composition comprising at least one emulsifier and at least one emulsifier improver, the process comprising i) providing an initial composition comprising the emulsifier in a melted form and the emulsifier improver, ii) cooling the initial composition such that the emulsifier crystallises and the emulsifier and the emulsifier improver are integrated • the emulsifier improver is as defined above • a composition comprising an emulsifier, pectin and guar gum, wherein the emulsifier, pectin and guar gum are integrated.
• a composition comprising an emulsifier, and edible fibre, wherein the emulsifier, and edible fibre are integrated.
• a composition comprising an emulsifier, and baking powder, wherein the emulsifier, and baking powder are integrated.
The invention will now be described, by way of example only, with reference to the following Examples.
EXAMPLES
Example 1: Monoglycerides + SSL + PGMS + Sugar Beet Fibre
A mixture of 70% GRINDSTED™ GA 1350 (monodiglycerides + SSL + PGMS) from Danisco Cultor and 30% Fibrex 595 (sugar beet fibre) from Danisco Sugar AB was prepared. The sugar beet fibres were mixed into the melted emulsifiers and the mix was turned into a fine free-flowing powder by spray crystallisation.
The product was used as whipping agent in a sponge cake recipe with the following composition:
Figure imgf000013_0001
30 g of the integrated product of the present invention was added to this recipe. The procedure was an all-in procedure i.e. single stage. The batter was whipped for 6 minutes on a Hobart mixer and the batter density was measured.
Figure imgf000013_0002
This Example may be compared with Comparative Example 3.
From the batter a sponge cake was prepared and given the following evaluation: Surface: nice and smooth, middle brown colour Crumb: yellowish, homogeneous, coarse structured Specific volume: 5.95 ml/g.
Furthermore, it was possible to add 1-3% extra water still maintaining the same benefits compared to Comparative Example 3.
Example 2: DATEM + Sugar Beet Fibre
A mixture of 70% PANODAN™(DATEM) supplied by Danisco Cultor and 30% Fibrex 595 from Danisco Sugar AB, was prepared. The sugar beet fibre was mixed into the melted DATEM and the mixture was then spray crystallised into a fine free-flowing powder.
The product was tested in a Danish roll procedure and compared with a similar dosage (0.45%) of DATEM without sugar beet fibre.
Figure imgf000014_0001
The integration of DATEM and sugar beet fibre resulted in a beneficial volume effect. In addition, the integration of DATEM and sugar beet fibre provides the possibility of adding 2% extra water.
Example 3: Monoglycerides + SSL + PGMS (Comparative)
This example serves as comparison to the previous integrated products. In this example only an emulsifier blend is provided and no emulsifier improver is incorporated in the composition. The example demonstrates, by comparison, the positive effect of the various emulsifier improvers used in the previous examples.
GRINDSTED™ GA 1350 (monodiglycerides + SSL + PGMS) supplied by Danisco Cultor is used in the test. 30 g of the product was applied to the same sponge cake recipe as in Example 1.
Figure imgf000014_0002
Characteristics of sponge cake made from the batter: Surface: slightly uneven with some bubbles. Crumb: some tunnels and somewhat non-homogeneous, dries out rather fast Not possible to add extra water
This test demonstrates that in Examples 1 and 2 we are able to achieve the same whipping effect with 13-31% less emulsifier i.e. there is a very significant positive effect from the integrated emulsifier improver(s) on the effect of the emulsifiers. Furthermore, Example 1 demonstrate the possibility of adding 1-5%) extra water still maintaining the same benefits which was not the case for this comparative Example. Also surface and crumb structure in this example is inferior compared to Example 1.
Example 4: Monoglycerides + SSL + PGMS (Comparative)
The product was prepared according to Example 3. However, in this Example the composition was stored together with the other dry ingredients from the cake recipe thereby simulating the conditions for premix products to which only water and egg are added.
Figure imgf000015_0001
The characteristics of sponge cake made from batter were similar to those of Example 3. The conclusion from this comparison example are in line with those from Example 3.
Example 5: Integrated Monoglyceride Emulsifier & Functional Ingredient
The following baking experiments were conducted to evaluate the performance of two products. One product was an integrated product in accordance with the present invention. The second product was a comparison comprising a distilled monoglyceride emulsifier, DIMODAN® B 727. The primary goal was to test the product of the present invention versus the product containing DIMODAN® B 727 which is usually used as a bread softener.
To investigate the improvement in softness of crumb structure when an emulsifier such as a distilled monoglyceride is integrated with at least one emulsifier improver by spray crystallisation, the following combinations were prepared by spray crystallisation. The samples were then tested in the preparation of bread.
The product in accordance with the present invention consisted of 35%> Fibrex 595 (a sugar beet fibre available from Danisco Sugar AB) and 65%> DIMODAN® PV (a distilled monoglyceride emulsifier available from Danisco Cultor, Denmark)
The samples are tested against a control, DIMODAN® B 727 (a distilled monoglyceride emulsifier available from Danisco Cultor, Denmark), in a toast bread recipe below in dosages resulting in the same distilled monoglyceride content in each trial.
Figure imgf000016_0001
Recipe:
Figure imgf000016_0002
Both of the products were applied to dough. The dough was split into 4 parts. The dough samples were then treated and baked as follows.
Three of the four samples were baked in forms with lid and one was baked in a form without lid. Three loaves of bread were used for softness measurements and one bread for volume measurements.
Procedure:
Kneading: Hobart, 2 + 10 min. (depending on flour) Dough temperature: 24-25°C
Resting: 10 min. at 30°C
Scaling: 750 g
Resting: 5 min. at room temperature
Moulding: Glimek 1 :4; 2:3,5; 3:14; 4:12 (10 at each side)
Proofing: 50-60 min. at 33°C, 85% RH.
Baking : Bago 1 : 30 min. at 220°C, 12 sec. Steam
Bago 2 : 30 min. at 220°C, 10 sec. Steam
The softness of the crumb structure was measured on a Instron UTM (universal testing machine), available from Instron International Limited, High Wycombe, England, at the following settings:
Full scale load 100 N Crosshead speed 100 mm/min
Anvil height 14 mm
Stress and load are reported at 25%
Test is ended with compression exceeds 26%
Sample dimensions 1962.5 square mm Statistics printed mean values, and standard deviations
Volume is measured on Volumeter, type LB size Volumeter 1675-3000cc.
Figure imgf000017_0001
The data are given in the Table below.
Figure imgf000018_0001
The following notation have been used:
'DAY' denotes the baking-day;
'TIME' denotes time within the baking-day;
'MIX' denotes the mixer;
'TRT' denotes the treatments (the control is denoted as 0 and the treatments in accordance with the present invention is denoted 1).
DISCUSSION
Based on the results it can be concluded that there is not a significant difference in volume between the different samples.
As regards softness some of the samples of compositions in accordance with the present invention result in significantly lower values (improved softness) compared to the control. On day 7 after baking sample the sample of the present invention resulted in significantly softer bread compared to control. An integrated composition in accordance with the present invention comprising Fibrex 595 in combination with a distilled monoglyceride emulsifier (DIMODAN® PV) results in an improved effect of the distilled monoglyceride emulsifier.
The differences in the softness measurements on the Instron are in the ratio 8-10 hPa; the lowest values are approx. 75 hPa and the highest values are approx. 85 hPa.
One may conclude that an integrated composition comprising an emulsifier and an edible fibre in accordance with the present invention such as Fibrex 595 (35% Fibrex 595) provides an improved effect of DIMODAN® PV when compared to application of the other ingredients used as carrier.
All publications mentioned in the above specification are herein incorporated by reference. Various modifications and variations of the described methods and system of the invention will be apparent to those skilled in the art without departing from the scope and spirit of the invention. Although the invention has been described in connection with specific preferred embodiments, it should be understood that the invention as claimed should not be unduly limited to such specific embodiments. Indeed, various modifications of the described modes for carrying out the invention which are obvious to those skilled in chemistry or related fields are intended to be within the scope of the following claims.

Claims

1. A process for the preparation of composition comprising at least one emulsifier and at least one edible fibre, the process comprising i) providing an initial composition comprising the emulsifier in a melted form and the edible fibre, ii) spray crystallising the initial composition such that the emulsifier crystallises and the emulsifier and the edible fibre are integrated.
2. A process according to claim 1 wherein the emulsifier is selected from propylene glycol monostearate (PGMS), sodium stearoyl lactylate (SSL), calcium stearoyl lactylate (CSL), monoglycerides, diglycerides, monodiglycerides, polyglycerol esters, lactic acid esters, polysorbate, sucrose esters, diacetyl tartaric acid esters of mono-diglycerides (DATEM), citric acid esters of monoglycerides (CITREM) and combinations thereof.
3. A process according to claim 1 or 2 wherein the edible fibre is selected from sugar beet fibre, apple fibre, pea fibre, wheat fibre, oat fibre, barley fibre, rye fibre, rice fibre, potato fibre, tomato fibre, other plant non-starch polysaccharide fibres, and combinations thereof.
4. A process according to any one of the preceding claims wherein the edible fibre comprises at least sugar beet fibre
5. A process according to any one of the preceding claims wherein the initial composition is substantially free of free water.
6. A composition obtainable by the process of any one of claims 1 to 5.
7. A composition obtained by the process of any one of claims 1 to 5.
8. A bakery product comprising or prepared from a composition as defined in claim 6 or 7.
9. A whipped foodstuff comprising or prepared from a composition as defined in claim 6 or 7.
10. Use of a composition for improving the crumb structure of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated.
11. Use of a composition for increasing the storage life of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated.
12. Use of a composition for increasing the flexibility of a bakery foodstuff, wherein the composition comprises an emulsifier and an edible fibre which are integrated.
13. A process according to claim 1 as substantially hereinbefore described with reference to any one of Examples 1, 2 or 5.
14. A composition according to claim 6 or 7 as substantially hereinbefore described with reference to any one of Examples 1 , 2 or 5.
15. A use according to claim 10, 11 or 12 as substantially hereinbefore described with reference to any one of Examples 1, 2 or 5.
PCT/IB2000/001132 1999-07-19 2000-07-17 A process for the preparation of a composition comprising at least one emulsifier and at least one edible fibre WO2001005246A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU63106/00A AU6310600A (en) 1999-07-19 2000-07-17 Composition
GB0130962A GB2366984B (en) 1999-07-19 2000-07-17 Composition
MXPA02000758A MXPA02000758A (en) 1999-07-19 2000-07-17 Composition.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9916905.4 1999-07-19
GBGB9916905.4A GB9916905D0 (en) 1999-07-19 1999-07-19 Composition
US15904799P 1999-10-12 1999-10-12
US60/159,047 1999-10-12

Publications (2)

Publication Number Publication Date
WO2001005246A2 true WO2001005246A2 (en) 2001-01-25
WO2001005246A3 WO2001005246A3 (en) 2001-08-23

Family

ID=26315778

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2000/001132 WO2001005246A2 (en) 1999-07-19 2000-07-17 A process for the preparation of a composition comprising at least one emulsifier and at least one edible fibre

Country Status (4)

Country Link
AU (1) AU6310600A (en)
GB (1) GB2366984B (en)
MX (1) MXPA02000758A (en)
WO (1) WO2001005246A2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101095473B (en) * 2007-07-04 2010-06-23 美晨集团股份有限公司 Powder type composite cake emulsifying agent
EP2204095A1 (en) * 2008-12-23 2010-07-07 Basf Se Mix crystal, method for their manufacture and application thereof in the production of baking goods
WO2012066961A1 (en) * 2010-11-15 2012-05-24 株式会社武蔵野化学研究所 Composition containing sodium stearoyl lactylate
WO2013182518A2 (en) 2012-06-07 2013-12-12 Dupont Nutrition Biosciences Aps Composition
US8747935B2 (en) 2005-12-27 2014-06-10 Kraft Foods Group Brands Llc Nutritionally enhanced pasta
JP2015039341A (en) * 2013-08-22 2015-03-02 理研ビタミン株式会社 Quality improver for steamed product

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1062423A (en) * 1963-06-15 1967-03-22 Nippon Yushi Kabushiki Kaisha Process for manufacture of dry shortening
GB1082283A (en) * 1964-01-13 1967-09-06 Grindstedvaerket As Improvements in or relating to emulsifier and stabilizer compositions
EP0153870A1 (en) * 1984-02-29 1985-09-04 Nexus Aps Method for the production of a powder product
US4933192A (en) * 1986-03-27 1990-06-12 Unilever Patent Holdings B.V. Hydratable powders which form WOW emulsions
WO1995020328A1 (en) * 1994-01-28 1995-08-03 Fmc Corporation Coprocessed particulate bulking and formulating aids
US5658609A (en) * 1994-06-29 1997-08-19 Kraft Foods, Inc. Fat replacement system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1062423A (en) * 1963-06-15 1967-03-22 Nippon Yushi Kabushiki Kaisha Process for manufacture of dry shortening
GB1082283A (en) * 1964-01-13 1967-09-06 Grindstedvaerket As Improvements in or relating to emulsifier and stabilizer compositions
EP0153870A1 (en) * 1984-02-29 1985-09-04 Nexus Aps Method for the production of a powder product
US4933192A (en) * 1986-03-27 1990-06-12 Unilever Patent Holdings B.V. Hydratable powders which form WOW emulsions
WO1995020328A1 (en) * 1994-01-28 1995-08-03 Fmc Corporation Coprocessed particulate bulking and formulating aids
US5658609A (en) * 1994-06-29 1997-08-19 Kraft Foods, Inc. Fat replacement system

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BUICK, K. ET AL.: "Konfektionierung von Fettstoffen" FETTE, SEIFEN, ANSTREICHMITTEL, vol. 84, no. 1, 1982, pages 516-523, XP002160958 HAMBURG.; DE *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8747935B2 (en) 2005-12-27 2014-06-10 Kraft Foods Group Brands Llc Nutritionally enhanced pasta
CN101095473B (en) * 2007-07-04 2010-06-23 美晨集团股份有限公司 Powder type composite cake emulsifying agent
EP2204095A1 (en) * 2008-12-23 2010-07-07 Basf Se Mix crystal, method for their manufacture and application thereof in the production of baking goods
US9894905B2 (en) 2008-12-23 2018-02-20 Basf Se Mixed crystals, method for the production thereof and use thereof in the production of baked goods
US10609931B2 (en) 2008-12-23 2020-04-07 Basf Se Mixed crystals, method for the production thereof and use thereof in the production of baked goods
WO2012066961A1 (en) * 2010-11-15 2012-05-24 株式会社武蔵野化学研究所 Composition containing sodium stearoyl lactylate
WO2013182518A2 (en) 2012-06-07 2013-12-12 Dupont Nutrition Biosciences Aps Composition
WO2013182518A3 (en) * 2012-06-07 2014-01-30 Dupont Nutrition Biosciences Aps Particulate composition for food products comprising an emulsifier
CN104427877A (en) * 2012-06-07 2015-03-18 杜邦营养生物科学有限公司 Particulate composition for food products comprising emulsifier
JP2015519904A (en) * 2012-06-07 2015-07-16 デュポン ニュートリション バイオサイエンシーズ エーピーエス Composition
AU2013270719B2 (en) * 2012-06-07 2016-08-04 Dupont Nutrition Biosciences Aps Particulate composition for food products comprising an emulsifier
JP2015039341A (en) * 2013-08-22 2015-03-02 理研ビタミン株式会社 Quality improver for steamed product

Also Published As

Publication number Publication date
WO2001005246A3 (en) 2001-08-23
MXPA02000758A (en) 2002-07-22
GB2366984A (en) 2002-03-27
GB2366984B (en) 2003-08-06
AU6310600A (en) 2001-02-05
GB0130962D0 (en) 2002-02-13

Similar Documents

Publication Publication Date Title
US4668519A (en) Reduced calorie baked goods and methods for producing same
US4481222A (en) Dry mix for bread
US4826699A (en) Method for the production of a powdered additive for use in preparing food products having a foamed structure
US4395426A (en) Dry mix for bread
CA2617504C (en) Batter-like compositions containing setting agent and methods of preparing and using same
CA2704665C (en) Low-fat batter-like compositions and methods of preparing and using same
AU2013270719B2 (en) Particulate composition for food products comprising an emulsifier
US4275088A (en) Dry mix for layer cake containing citrus juice vesicle solids
EP2088872B1 (en) Coated carriers
EP1928252A2 (en) Batter-like compositions and methods of preparing and using same
US6306447B1 (en) Integrated emulsifier and edible fiber
WO2001005246A2 (en) A process for the preparation of a composition comprising at least one emulsifier and at least one edible fibre
CN103108550A (en) Method for manufacturing bread containing dried fruit
US20020119232A1 (en) Co-processed emulsifier /carrier systems for full-fat farinaceous baked goods
CA1191379A (en) Dry mix for bread
JP2021097663A (en) Water retention additive for food, freezing resistant additive using the same, water separation inhibitor, dough composition, and production method of bakery food
DE102005059406A1 (en) Production of extruded surface-active substances involves hydrophilization of carrier by addition of hydrophilic emulsifying agents and surface-active substances which can be extruded

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: GB0130962.4

Country of ref document: GB

WWE Wipo information: entry into national phase

Ref document number: PA/a/2002/000758

Country of ref document: MX

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase in:

Ref country code: JP