WO2001002531A1 - Transparent or translucent, liquid or gel type automatic dishwashing detergent product - Google Patents

Transparent or translucent, liquid or gel type automatic dishwashing detergent product Download PDF

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Publication number
WO2001002531A1
WO2001002531A1 PCT/US2000/018070 US0018070W WO0102531A1 WO 2001002531 A1 WO2001002531 A1 WO 2001002531A1 US 0018070 W US0018070 W US 0018070W WO 0102531 A1 WO0102531 A1 WO 0102531A1
Authority
WO
WIPO (PCT)
Prior art keywords
potassium
liquid
automatic dishwashing
type automatic
gel type
Prior art date
Application number
PCT/US2000/018070
Other languages
French (fr)
Inventor
Xiaoqing Song
Peter Robert Foley
Melissa Dee Aquino
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP2001508305A priority Critical patent/JP2003504457A/en
Priority to CA002377728A priority patent/CA2377728C/en
Priority to EP00946933A priority patent/EP1196534A1/en
Priority to AU60617/00A priority patent/AU6061700A/en
Priority to US10/019,175 priority patent/US6911422B1/en
Priority to MXPA02000264A priority patent/MXPA02000264A/en
Publication of WO2001002531A1 publication Critical patent/WO2001002531A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C11D3/048—Nitrates or nitrites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/105—Nitrates; Nitrites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/12—Carbonates bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/16—Phosphates including polyphosphates

Abstract

A process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product is disclosed. The process includes the steps of providing a liquid or gel type automatic dishwashing detergent composition expressly free from (i) potassium tripolyphosphate and (ii) mixture of sodium tripolyphosphate and potassium tripolyphosphate, adding one or more of potassium sources to the liquid or gel type automatic dishwashing detergent composition, the potassium sources being expressly free of potassium tripolyphosphate, and maintaining a K:Na weight ratio greater than at least about 0.5:1.

Description

TRANSPARENT OR TRANSLUCENT. LIQUID OR GEL TYPE AUTOMATIC DISHWASHING DETERGENT PRODUCT
TECHNICAL FIELD The present invention relates to liquid or gel type automatic dishwashing detergent compositions. More particularly, the invention relates to a process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product and a transparent or translucent a liquid or gel type automatic dishwashing detergent product having one or more potassium sources to maintain pre-selected potassium sodium ratios in order to make the composition transparent or translucent while at the same time not using any (I) potassium tripolyphosphate or (n) mixtures of sodium and potassium tripolyphosphate.
BACKGROUND OF THE INVENTION Improving the aesthetics of a liquid or gel type automatic dishwashing detergent product (liquid/gel ADW or hqui-gel ADW) is believed to be a very important aspect of this product Typically, consumers of liquid ADW products have a preference for liquid ADW products having a certain color or appearance. The addition of a transparent or translucent characteπstics to a liquid ADW composition can improve the desirability of the product because of a transparent or translucent product has a shmy appearance which is liked by consumers. Also, a transparent or translucent product allows for suspension of colored prills into that product, which can further enhance the physical appearance of the product The transparent product may be clear, or dyed, using dyes that do not cause significant staining or dyeing of plastics duπng the wash cycle in automatic dishwashing.
In the low-free water environment of a typical phosphate containing gel type ADW composition, it is a real challenge to obtain clear or translucent characteπstics This is pnmaπly due to the relatively low solubility of commodity phosphate builders, such as sodium tπpolyphosphate (STPP), which has a solubility typically of about 14.5 grams per 100 cc of water at room temperature. Previous formulators wishing to obtain clear or translucent characteristics in a liquid or gel type ADW have been forced to use highly soluble potassium tπpolyphosphate (KTPP), or alternatively, commercially available mixtures of sodium tripolyphosphate and potassium tπpolyphosphates (commonly referred to as SKTPP) which have heretofore served a dual purpose of being a potassium source (for transparency/translucency) and a phosphate source (for cleaning performance) The use of KTPP and SKTPP is generally considered undesirable for vaπous reasons, one of them being the economics of manufacturing Alternatively, the previous formulators have been forced to use very low levels of KTPPs or SKTPs, which detrimentally affects cleaning performance. Thus, a considerable effort has been directed in this field, to develop novel solutions for attaining transparency and/or translucency m hqui-gel ADWs.
It has been desirable to have a hqui-gel ADW product having transparency and/or translucency characteristics, but without using (1) potassium tripolyphosphate (KTPP), and/or (n) commercially available mixtures of sodium tπpolyphosphate and potassium tripolyphosphate
(SKTPP), while at the same time still maintaining high phosphate levels so as to not detrimentally affect cleaning performance.
The inventors of the present invention have discovered that by maintaining a K:Na weight ratio greater than at least about 0.5: 1, K:Na, outstanding translucent characteristics can be imparted without having to use KTPP or SKTPP. Thus, high phosphate levels can be attained by the addition of sodium tπpolyphosphate (STPP) alone, along with the addition of potassium hydroxide (KOH) for obtaining high alkalinity or the addition of other sources of potassium for obtaining moderate alkalinity. The present invention is thus directed to overcome one or more of the problems as set forth before.
SUMMARY OF THE INVENTION
The invention meets the needs above by providing a process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product, and a transparent or translucent a liquid or gel type automatic dishwashing detergent product.
In one aspect of the present invention, the process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product compπses the steps of providing a liquid or gel type automatic dishwashing detergent composition expressly free from (l) potassium tπpolyphosphate and (n) mixture of sodium tripolyphosphate and potassium tripolyphosphate, adding one or more of potassium sources to the liquid or gel type automatic dishwashing detergent composition, the potassium sources being expressly free of potassium tπpolyphosphate, and maintaining a potassium: sodium weight ratio greater than at least about 0.5:1. In another aspect of the present invention, the transparent or translucent a liquid or gel type automatic dishwashing detergent product compπses a liquid or gel type automatic dishwashing detergent composition. The composition is expressly free from (1) potassium tripolyphosphate and (π) mixture of sodium tπpolyphosphate and potassium tπpolyphosphate. The composition includes one or more of potassium sources, the potassium sources being expressly free of potassium tπpolyphosphate. The potassium: sodium weight ratio is greater than at least about 0.5:1
DETAILED DESCRIPTION OF THE INVENTION In the preferred embodiment of the present invention, the process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product compπses the steps of providing a liquid or gel type automatic dishwashing detergent composition expressly free from KTPP and SKTPP. Express exclusion of KTPP and SKTPP In the preferred embodiment, the liquid or gel type automatic dishwashing detergent composition is expressly free of KTPP and SKTPP. The abbreviation KTPP as used herein means potassium tripolyphosphate, as is commercially available, which may contain incidental and/or trace impurities of other tπpolyphosphates, such as STPP. The abbreviation SKTPP, as used herein means commercially available mixtures of STPP and KTPP, wherein the weight ratio of Na;K is more than 95:5. Potassium sources
The process further includes the step of adding one or more of potassium sources to the liquid or gel type automatic dishwashing detergent composition, the potassium sources being expressly free of potassium tripolyphosphate. In the preferred embodiment of the present invention, the potassium source is KOH, added m an amount desirably in a range of from about 4% to about
20% by weight of the detergent composition and preferably in a range of from about 8% to about 15% by weight of the detergent composition. When KOH is the preferred potassium source, the liquid or gel type automatic dishwashing detergent composition has a pH desirably of at least about 9, and preferably, in a range of from about 11 to about 12.5. For purposes of this disclosure, the term pH, as used herein means pH of a 1% solution of liquid ADW composition in water by weight. Alternatively, the potassium source is selected from the group consisting of K2S04, KNO3, K2C03, KC1, KBr, K3PO4, potassium silicate, potassium acetate, or mixtures thereof. When the potassium source is selected from the aforementioned group, it is added in an amount desirably in a range of from about 2% to about 20% by weight of the detergent composition and preferably m a range of from about 5% to about 16% by weight of the detergent composition, depending upon the availability of K in the potassium source on a molar basis. When the potassium source is selected from the aforementioned group, the liquid or gel type automatic dishwashing detergent composition has a pH of at least about 6.5. The lower pH values are preferred when formulating the detergent composition with enzymes, which may be present m the hqui-gel composition m a liquid form or in the form of solid prills that are coated with a permeable or impermeable coating. K'Na weight ratio
The process further includes the step of maintaining a potassium: sodium weight ratio desirably greater than about 0.5 1 , and preferably above 0 65.1. In a more preferred embodiment, the K.Na weight ratio is desirably maintained in a range of from about 0.5: 1 to about 1.25 T , particularly when the detergent composition has a total solids content of less than about 20% by weight. Preferably, the potassium: sodium weight ratio is maintained at least greater than 0.75: 1, and more preferably, in a range of from about 0.75.1 to about 2 1, potassium: sodium, particularly when the liquid or gel type automatic dishwashing detergent composition has a total solids content in a range of from about 20% to about 40% by weight The total solids content compπses solids in the form of STPP, I e , the phosphate builder, which is typically present in an amount in a range of about 10%) to 40%, thickener, such as a polymer, and potassium hydroxide, i.e., one of the potassium sources It should be noted that other optional ingredients may also make up the total solids content in a hqui-gel ADW composition. Phosphate Builder
The liquid or gel type automatic dishwashing detergent composition provided in this process, further includes a phosphate builder an amount desirably m a range of from about 10% to about 40% of said detergent composition, and preferably in a range of from about 12% to about 30% of said detergent composition. The preferred phosphate builder useful m practicing this invention is sodium tπpolyphosphate (STPP) The STPP is essentially free of any KTPP, other than what may be present in trace quantities as naturally occurπng lmpuπty or an impurity duπng the commercial manufacturing of STPP. Other phosphate builders known to those skilled in the art may also be utilized in lieu of or in conjunction with STPP. In another embodiment of the present invention, a transparent or translucent a liquid or gel type automatic dishwashing detergent product includes a liquid or gel type automatic dishwashing detergent composition. The composition is expressly free of KTPP and SKTPP. The composition includes one or more of potassium sources, the potassium sources being expressly free of KTPP. The potassium- sodium weight ratio is desirably greater than about 0.5:1. Other ingredients (a) Thickeners
The physical stability of the liquid product may be improved and the thickness of the liquid product may be altered by the addition of a cross linking polyacrylate thickener to the liquid detergent product as a thixotropic thickener. (b) pH adiustmg components
The above liquid automatic dishwashing detergent product is preferably low foaming, readily soluble in the washing medium and most effective at pH values best conducive to improved cleaning performance, such as in a range of desirably from about pH 6.5 to about pH 12.5, and preferably from about pH 8.0 to about pH 12.0, more preferably from about pH 8.5 to about pH 12.5. The pH adjusting components are desirably selected from sodium or potassium hydroxide, sodium or potassium carbonate or sesquicarbonate, sodium or potassium silicate, bone acid, sodium or potassium bicarbonate, sodium or potassium borate, and mixtures thereof. NaOH or KOH are the preferred ingredients for increasing the pH to within the above ranges. Other preferred pH adjusting ingredients are sodium carbonate, potassium carbonate, and mixtures thereof.
(c) Low Foaming Surfactant
The liquid noniomc surfactant detergents that can be used to practice the present invention are preferably are alkyl ethoxylates m non-chlorine bleach liquid ADW compositions. One example of a non-chloπne bleach stable surfactant is SLF 18® manufactured by BASF
Corporation Alternatively, in chlonne bleach containing liquid ADW compositions, chloπne bleach stable low foaming surfactants are preferred and such surfactants are present in a range of from about 0.1% to about 10% by weight of the liquid composition. Such surfactants are generally known to one skilled m the art and need not be elaborated here, for purposes of brevity. An example of a chlorine bleach stable surfactant is Dowfax® a onic surfactant available from the Dow Chemical Company.
(d) Enzymes
Enzymes may be present in the liqui-gel composition in the form of liquid enzymes when the pH of the liquid ADW is less than about 10.0 At pH's greater than about 10.0, enzymes in the form of solid prills that are coated with impermeable or permeable coating may be used. Various types of enzymes are well known to those skilled in the art, such as proteases and amylases, both of which are useful in carrying out this invention.
(e) Other adjunct ingredients
The liquid automatic dishwashing detergent composition may optionally contain up to about 20% of a dispersant polymer selected from the group consisting of polyacrylates and polyacrylate copolymers.
To exemplify various embodiments of the present invention, Samples A, B and C of the liquid automatic dishwashing detergent product composition are formulated using the below named ingredients, as set forth in Example A.
EXAMPLE A
Ingredient (weight % active) Sample A Sample B Sample C
Sodium Tripolyphosphate 16.0 16.0 16.0
Potassium Tripolyphosphate 0.0 0.0 0.0
Sodium Silicate 0.0 0.0 0.5
Potassium hydroxide 0.0 11.0 11.0
Sodium hydroxide 0.0 0.0 0.0
Polyacrylate polymer 0.0 0.0 1.0
Nitric Acid 0.012 0.0 0.0
Perfume 0.03 0.03 0.03
Nonionic surfactant 0.3 0.5 0.5
Polyacrylate polymer thickener 1.5 1.0 1.0
Protease enzyme 0.5 (liquid) 1.0 (prill) 1.0 (prill)
Amylase enzyme 0.7 (liquid) 1.0 (prill) 1.0 (prill) propylene glycol 4.0 0.0 0.0 sodium borate 4.0 0.0 0.0
Potassium sulfate 16.0 0.0 0.0
Water Bal. Bal. Bal.
TOTAL 100.0 100.0 100.0 pH Sample A Sample B Sample C
8.5 12.1 12.1
Accordingly, having thus descnbed the invention in detail, it will be obvious to those skilled m the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is described m the specification. What is claimed is:

Claims

WHAT IS CLAIMED IS-
1. A process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product, characterized by the steps of: providing a liquid or gel type automatic dishwashing detergent composition expressly free from (I) potassium tπpolyphosphate and (n) mixture of sodium tπpolyphosphate and potassium tπpolyphosphate; adding one or more of potassium sources to said liquid or gel type automatic dishwashing detergent composition, said potassium sources being expressly free of potassium tnpolyphosphate; and maintaining a potassium- sodium weight ratio greater than at least 0.5: 1.
2. A transparent or translucent a liquid or gel type automatic dishwashing detergent product, characterized by: a liquid or gel type automatic dishwashing detergent composition, said composition being expressly free from (I) potassium tripolyphosphate and (n) mixture of sodium tπpolyphosphate and potassium tripolyphosphate; one or more of potassium sources, said potassium sources being expressly free of potassium tπpolyphosphate; and a potassium: sodium weight ratio greater than at least 0.5:1.
3. The process according to any of Claims 1-2, wherein said potassium source is selected from the group consisting of K S04, KN03, K2C03, KC1, KBr, K3P0 , potassium silicate, potassium acetate, or mixtures thereof.
4. The process according to any of Claims 1-3, wherein said potassium source is KOH.
5. The process according to any of Claims 1-4, wherein said potassium source is added m an amount in a range of from 2% to 20% by weight of said detergent composition.
6. The process according to any of Claims 1-5, wherein said liquid or gel type automatic dishwashing detergent composition has a pH of at least 6.5.
7. The process according to any of Claims 1-6, wherein said liquid or gel type automatic dishwashing detergent composition includes a phosphate builder in an amount in a range of from 10% to 40% of said detergent composition.
8. The process according to any of Claims 1-7, wherein said potassium: sodium weight ratio is maintained m an amount greater than 0 65.1.
9. The process according to any of Claims 1-8, wherein said liquid or gel type automatic dishwashing detergent composition has a total solids content of less than 20%) by weight.
10. The process according to any of Claims 1-9, wherein said liquid or gel type automatic dishwashing detergent composition has a total solids content in a range of from 20% to 40% by weight.
H \EPOCLAIMS\7652-EPO LSP
PCT/US2000/018070 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product WO2001002531A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2001508305A JP2003504457A (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent products
CA002377728A CA2377728C (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product
EP00946933A EP1196534A1 (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product
AU60617/00A AU6061700A (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product
US10/019,175 US6911422B1 (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product
MXPA02000264A MXPA02000264A (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14193299P 1999-07-01 1999-07-01
US60/141,932 1999-07-01

Publications (1)

Publication Number Publication Date
WO2001002531A1 true WO2001002531A1 (en) 2001-01-11

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ID=22497864

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PCT/US2000/018070 WO2001002531A1 (en) 1999-07-01 2000-06-30 Transparent or translucent, liquid or gel type automatic dishwashing detergent product

Country Status (6)

Country Link
EP (1) EP1196534A1 (en)
JP (1) JP2003504457A (en)
AU (1) AU6061700A (en)
CA (1) CA2377728C (en)
MX (1) MXPA02000264A (en)
WO (1) WO2001002531A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001029171A1 (en) * 1999-10-15 2001-04-26 The Procter & Gamble Company Liquid or gel detergent with increased specific gravity
US7271141B2 (en) 2000-08-25 2007-09-18 Reckitt Benckiser N.V. & Reckitt Benckiser (Uk) Limited Water soluble packages containing liquid compositions
WO2007110648A1 (en) * 2006-03-29 2007-10-04 King's College London Agonist antibodies against tshr
EP3255132B1 (en) 2009-10-09 2020-03-25 Reckitt Benckiser Finish B.V. Detergent composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201019628D0 (en) * 2010-11-19 2010-12-29 Reckitt Benckiser Nv Dyed coated bleach materials
JP6533030B2 (en) * 2013-12-17 2019-06-19 第一工業製薬株式会社 Cleaning composition for silicon wafer

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Publication number Priority date Publication date Assignee Title
GB1489867A (en) * 1973-10-05 1977-10-26 Albright & Wilson Detergent compositions comprising amine polyphosphates
US4228043A (en) * 1977-08-22 1980-10-14 Lever Brothers Company Liquid detergent composition
GB1577140A (en) * 1976-05-24 1980-10-22 Unilever Ltd Liquid detergent compositions
US4257908A (en) * 1975-08-11 1981-03-24 Colgate Palmolive Company Laundry detergent in gel form
US5213706A (en) * 1991-11-08 1993-05-25 Lever Brothers Company, Division Of Conopco, Inc. Homogeneous detergent gel compositions for use in automatic dishwashers
US5413727A (en) * 1985-06-14 1995-05-09 Colgate Palmolive Co. Thixotropic aqueous compositions containing long chain saturated fatty acid stabilizers
WO1997043392A1 (en) * 1996-05-15 1997-11-20 The Procter & Gamble Company Process for manufacturing bleaching compositions comprising chlorine and bromine sources and product thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1489867A (en) * 1973-10-05 1977-10-26 Albright & Wilson Detergent compositions comprising amine polyphosphates
US4257908A (en) * 1975-08-11 1981-03-24 Colgate Palmolive Company Laundry detergent in gel form
GB1577140A (en) * 1976-05-24 1980-10-22 Unilever Ltd Liquid detergent compositions
US4228043A (en) * 1977-08-22 1980-10-14 Lever Brothers Company Liquid detergent composition
US5413727A (en) * 1985-06-14 1995-05-09 Colgate Palmolive Co. Thixotropic aqueous compositions containing long chain saturated fatty acid stabilizers
US5213706A (en) * 1991-11-08 1993-05-25 Lever Brothers Company, Division Of Conopco, Inc. Homogeneous detergent gel compositions for use in automatic dishwashers
WO1997043392A1 (en) * 1996-05-15 1997-11-20 The Procter & Gamble Company Process for manufacturing bleaching compositions comprising chlorine and bromine sources and product thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001029171A1 (en) * 1999-10-15 2001-04-26 The Procter & Gamble Company Liquid or gel detergent with increased specific gravity
US6583100B2 (en) * 1999-10-15 2003-06-24 The Procter & Gamble Company Method for increasing the specific gravity of low PH transparent or translucent, liquid or gel type detergent product without affecting transluscency
US7271141B2 (en) 2000-08-25 2007-09-18 Reckitt Benckiser N.V. & Reckitt Benckiser (Uk) Limited Water soluble packages containing liquid compositions
WO2007110648A1 (en) * 2006-03-29 2007-10-04 King's College London Agonist antibodies against tshr
US8603466B2 (en) 2006-03-29 2013-12-10 King's College London Agonist antibodies against TSHR
EP3255132B1 (en) 2009-10-09 2020-03-25 Reckitt Benckiser Finish B.V. Detergent composition
EP3255132B2 (en) † 2009-10-09 2023-10-18 Reckitt Benckiser Finish B.V. Detergent composition

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Publication number Publication date
AU6061700A (en) 2001-01-22
MXPA02000264A (en) 2002-06-21
CA2377728A1 (en) 2001-01-11
EP1196534A1 (en) 2002-04-17
CA2377728C (en) 2005-08-16
JP2003504457A (en) 2003-02-04

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