WO2000050170A3 - A new transition metal complex, its preparation as well as a catalyst system based thereupon and its use for the polymerization of olefins - Google Patents

A new transition metal complex, its preparation as well as a catalyst system based thereupon and its use for the polymerization of olefins Download PDF

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Publication number
WO2000050170A3
WO2000050170A3 PCT/FI2000/000136 FI0000136W WO0050170A3 WO 2000050170 A3 WO2000050170 A3 WO 2000050170A3 FI 0000136 W FI0000136 W FI 0000136W WO 0050170 A3 WO0050170 A3 WO 0050170A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
ligand
polymerization
olefins
preparation
Prior art date
Application number
PCT/FI2000/000136
Other languages
French (fr)
Other versions
WO2000050170A2 (en
Inventor
Ove Andell
Janne Maaranen
Lasse Ketola
Original Assignee
Borealis As
Ove Andell
Janne Maaranen
Lasse Ketola
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As, Ove Andell, Janne Maaranen, Lasse Ketola filed Critical Borealis As
Priority to EP00906395A priority Critical patent/EP1165232A2/en
Priority to AU28081/00A priority patent/AU2808100A/en
Publication of WO2000050170A2 publication Critical patent/WO2000050170A2/en
Publication of WO2000050170A3 publication Critical patent/WO2000050170A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The invention relates to new triaza transition metal complexes and their use as polymerization catalysts. They have the formula (1): LnMXm-n, wherein each L is independently a ligand which is multidentate by adjacent cooordinating atoms, M is the central atom which is a metal selected from Groups 4-8 of the Periodic Table of the Elements (IUPAC 1990), each X is independently a unidentate organic or halogen ligand, m is the coordination number or number of coordination sites on the central atom M, and n is the number of the ligands L which is an integer from 1 to m. At least one of the ligands L has formula (2), wherein each of R1-R6 is independently selected from hydrogen and organic groups having from 1 to 10 carbon atoms and the ligand L is coordinated to the central atom M by one to four of the three nitrogen atoms and/or the carbon atom of the ligand L according to formula (2).
PCT/FI2000/000136 1999-02-22 2000-02-22 A new transition metal complex, its preparation as well as a catalyst system based thereupon and its use for the polymerization of olefins WO2000050170A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP00906395A EP1165232A2 (en) 1999-02-22 2000-02-22 A new transition metal complex, its preparation as well as a catalyst system comprising based thereupon and its use for the polymerization of olefins
AU28081/00A AU2808100A (en) 1999-02-22 2000-02-22 A new transition metal complex, its preparation as well as catalyst system comprising based thereupon and its use for the polymerization of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI990371 1999-02-22
FI990371A FI990371A (en) 1999-02-22 1999-02-22 New transition metal complex, its preparation and its catalyst system and their use for polymerization of olefins

Publications (2)

Publication Number Publication Date
WO2000050170A2 WO2000050170A2 (en) 2000-08-31
WO2000050170A3 true WO2000050170A3 (en) 2000-12-07

Family

ID=8553884

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2000/000136 WO2000050170A2 (en) 1999-02-22 2000-02-22 A new transition metal complex, its preparation as well as a catalyst system based thereupon and its use for the polymerization of olefins

Country Status (4)

Country Link
EP (1) EP1165232A2 (en)
AU (1) AU2808100A (en)
FI (1) FI990371A (en)
WO (1) WO2000050170A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB924364A (en) * 1961-02-21 1963-04-24 Ethylene Plastique Sa Polyaddition polymerisation processes
US3301854A (en) * 1965-04-01 1967-01-31 Norman W Gabel 7-(substituted)-1, 3, 5-triazaadamantanes
US4085106A (en) * 1976-01-07 1978-04-18 E. I. Du Pont De Nemours And Company Bicyclic and tricyclic trisaminomethanes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB924364A (en) * 1961-02-21 1963-04-24 Ethylene Plastique Sa Polyaddition polymerisation processes
US3301854A (en) * 1965-04-01 1967-01-31 Norman W Gabel 7-(substituted)-1, 3, 5-triazaadamantanes
US4085106A (en) * 1976-01-07 1978-04-18 E. I. Du Pont De Nemours And Company Bicyclic and tricyclic trisaminomethanes

Also Published As

Publication number Publication date
FI990371A0 (en) 1999-02-22
AU2808100A (en) 2000-09-14
FI990371A (en) 2000-08-23
EP1165232A2 (en) 2002-01-02
WO2000050170A2 (en) 2000-08-31

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