WO2000046172A1 - Oxidation of hydrocarbons to acids in the presence of fluoro compounds - Google Patents
Oxidation of hydrocarbons to acids in the presence of fluoro compounds Download PDFInfo
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- WO2000046172A1 WO2000046172A1 PCT/US2000/003109 US0003109W WO0046172A1 WO 2000046172 A1 WO2000046172 A1 WO 2000046172A1 US 0003109 W US0003109 W US 0003109W WO 0046172 A1 WO0046172 A1 WO 0046172A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
Definitions
- TECHNICAL FIELD This invention relates to methods of making intermediate oxidation products, and especially dibasic acids, by oxidizing a compound selected from group consisting of cyclohexane, o-xylene, m-xylene, p-xylene, and a mixture thereof, under controlled conditions in the presence of a small critical amount of a fluorocompound co-solvent.
- Adipic acid is used to produce Nylon 66 fibers and resins, polyesters, polyurethanes, and miscellaneous other compounds.
- Other intermediate oxidation products include, but are not limited to cyclohexanol, cyclohexanone, cyclohexylhydroperoxide, benzoic acid, terephthalic acid, isophthalic acid, phthalic acid, etc.
- the conventional process involves a first step of oxidizing cyclohexane with oxygen to a mixture of cyclohexanone and cyclohexanol (KA mixture), and then oxidation of the KA mixture with nitric acid to adipic acid.
- Other processes include, among others, the "Hydroperoxide Process”, the “Boric Acid Process”, and the “Direct Synthesis Process”, which involves direct oxidation of cyclohexane to adipic acid with oxygen in the presence of solvents, catalysts, and initiators or promoters.
- the Direct Synthesis Process has been given attention for a long time.
- Direct Synthesis a mixture of two liquid phases is present at ambient temperature, along with a solid phase mainly consisting of adipic acid.
- the two liquid phases have been called the "Polar Phase” and the “Non-Polar Phase”.
- no attention has been paid so far to the importance of the two phases, except for separating the adipic acid from the "Polar Phase” and recycling these phases to the reactor partially or totally with or without further treatment. It is also important to note that most studies on the Direct Oxidation have been conducted in a batch mode, literally or for all practical purposes.
- Patent 3,234,271 Barker et al
- U.S. Patent 3,231,608 Kollar
- WO 9631455 discloses the use of strong acids in heterogeneous catalysis of oxidizing hydrocarbons, alcohols, and ketones, leading to acids.
- Costantini et al. mention perfluoroalkylcarboxylic acids, such as trifluoroacetic acid. They also disclose the use of mineral or organic acids, the pKa of which is less than or equal to 3. They further disclose that the addition of a strong acid has the effect of improving kinetics of the reaction and generally its carboxylic acid selectivity.
- the disclosed content of strong acid in the reaction mixture is in the range of 0-20%.
- U.S. Patent 5,585,515 discloses a method and pathway for selectively oxidizing hydrocarbon compounds, especially in the presence of copper compounds.
- Camaioni et al. further disclose fully fluorine substituted carboxylic acids, such as trifluoroacetic acid.
- Other acids may be used such as sulphuric acid, trifluoromethane sulfonic acid, acetic acid, halogenated carboxylic acids, and mixtures thereof.
- French Patent FR 2541993 discloses a method for the preparation of adipic acid from cyclohexanone or a mixture of cyclohexanone and cyclohexanol in the presence of Manganese as catalyst at 65 ° C, and in the presence of strong acids, such as for example hydrochloric, hydrobromic, hydroiodic, orthophosphoric, sulfuric, perchloric, iodic, periodic, phosphorous, dichloroacetic, trichloroacetic, trifluoroacetic, difluoroacetic, methane sulfonic, trifluoromethanesulfonic, methylsulfonylacetic, and paratoluenesulfonic acids.
- strong acids such as for example hydrochloric, hydrobromic, hydroiodic, orthophosphoric, sulfuric, perchloric, iodic, periodic, phosphorous, dichloroacetic, trichloroacetic, trifluoroacetic, diflu
- European Publication EP 341163 Bl (Blanchard et al.) discloses a process for the preparation of cyclohexanol by reaction of cyclohexene with water in the presence of a zeolite and a carboxylic acid.
- Acids suitable for the process are formic, acetic, trifluoroacetic, monochloroacetic, butyric, isobutyric, succinic, glutaric, dodecanedioic, and benzoic.
- acetic, and trifluoroacetic are particularly suitable.
- French Publication 2744719 discloses decomposition of organic hydroperoxides, such as cyclohexylhydroperoxide, in the presence of heterogeneous catalysts consisting of molecular sieves. Cyclohexylhydroperoxide in decomposition leads to formation of cyclohexanone and cyclohexanol, which in turn may be oxidized to adipic acid.
- a mobilizing agent such as hydroxide, fluoride, or amine is especially suitable.
- PCT/US97/ 10830 filed on June 23, 1997 (WO 97/49485); PCT/US97/12944 filed on July 23, 1997 (WO 98/07677); PCT/US96/07056 filed May 17, 1996 (WO 96/40610); PCT/US97/17684 filed September 30, 1997 (WO 98/19789); PCT/US97/17812 filed October 2, 1997 (WO 98/27029); PCT/US97/17883 filed October 3, 1997 (WO 98/20966); PCT/US98/25105 filed December 1, 1998; PCT/US98/19111 filed September 14, 1998; PCT/US98/14506 filed July 13, 1998; PCT/US98/19099 filed September 16, 1998; and PCT/US98/19057 filed September 14, 1998.
- the present invention relates to methods and devices of oxidizing a hydrocarbon, such as cyclohexane for example, to an acid, such as adipic acid for example. More particularly this invention pertains a method of oxidizing a hydrocarbon selected from a group consisting of cyclohexane, o-xylene, m-xylene, p- xylene, and a mixture of two or more of o-xylene, m-xylene, and p-xylene, to a respective acid, in a mixture comprising a solvent and a cobalt catalyst, the method comprising a step of adding to the mixture an effective amount of a fluorocompound resulting in a rate of increase of reaction rate, preferably at least 5%, as compared to a rate of increase of reaction rate in the absence of the fluorocompound, without changing relative oxygen consumption to become lower than 75% of a relative oxygen consumption observed in the absence of the fluorocompound.
- the fluorocompound is a perfluorinated compound. More preferably, the fluorocompound is selected from a group consisting essentially of fluoroacid, fluoroketone, fluoroalcohol, fluorinated hydrocarbon, and a mixture thereof. Still more preferably, the fluorocompound is a fluoroacid comprising 2 to 22 carbon atoms. Even more preferably, the fluorocompound is a perfluoroacid comprising 2 to 22 carbon atoms.
- perfluoroacids examples include perfluoroacetic acid, perfluoropropionic acid, perfluorobutyric acid, perfluoropentanoic acid, perfluorohexanoic acid, perfluoroheptanoic acid, etc. It is preferable that the perfluoroacid is perfluoroacetic acid, and it is added to the single-phase liquid mixture in an in a level within the range of 0.1 to 4% by weight.
- the perfluoroacid may also be selected from a group consisting essentially of perfluorobutyric acid, perfluoroctanoic acid, and a mixture thereof.
- Perfluorobutyric acid may be preferable from a downstream processing point of view.
- perfluoroacids having more than two carbon atoms are introduced at a level of 1 to 5% by weight.
- This invention is particularly applicable in the case that the hydrocarbon comprises cyclohexane, the solvent comprises acetic acid or a mixture of acetic acid and propionic acid, and the respective acid comprises adipic acid.
- the reaction mixture may also contain an initiator, which preferably is cyclohexanone or acetaldehyde. Other initiators may also be used, including ketones, such as methylethylketone for example, peroxides, etc.
- the respective acid in other examples of the present invention, may comprise a compound selected from a group consisting of adipic acid, phthalic acid, isophthalic acid, and terephthalic acid, and the method may further comprise a step of reacting said respective acid with a third reactant selected from a group consisting of a polyol, a polyamine, and a polyamide in a manner to form a polymer of a polyester, or a polyamide, or a (polyimide and/or poyamideimide), respectively.
- the method may further comprise a step of spinning the polymer into fibers or making composites.
- steady state it is meant that the reaction has reached an equilibrium, which equilibrium, however, may be adjusted periodically or continuously in order to achieve a desired result. If, for example, more water is needed in the reaction zone to avoid catalyst precipitation, the water feed rate to the reaction zone may be increased appropriately, and still the reaction may be considered to be at a "steady state”. Similarly, if less water is needed to avoid formation of two phases, the water feed rate to the reaction zone may be decreased appropriately, and still the reaction may be considered to be at a "steady state”.
- the terms “substantially single-phase liquid”, “substantially single liquid phase” “single liquid phase”, and “single phase” are for all practical purposes synonymous for the purposes of this invention.
- second phase formation or “formation of a second phase” refer to a second liquid phase, and not to a solid phase or gaseous phase, unless otherwise specified.
- level of an ingredient (reactant, reaction product, inert matter, solvent, or any other type of matter present) is given as a percentage by weight .
- Selectivity to an acid is the mole percent of the acid in a mixture of other major acids.
- the selectivity to adipic acid in the direct oxidation of cyclohexane is the mole percent level of adipic acid in the total moles of adipic acid, plus moles of glutaric acid, plus moles of succinic acid.
- Reaction rate of hydrocarbon is defined as the rate of moles of hydrocarbon oxidized per unit of time.
- reaction rate of oxidant is defined as the rate of moles of oxidant reacted per unit of time.
- the two reaction rates may be assumed to be proportional to each other, and also proportional to the pressure drop in a closed reactor in which no matter is entering or exiting.
- Reactivity is defined as the reaction rate divided by the volume of the reaction mixture. Rate of increase of the reaction rate is measured by the tangent at the ascending portion of a curve having dP/dt as the Y-axis and time as the X-axis. Therefore it is dP/(dt) 2 , and can be expressed as psig/min 2 .
- An example of such a tangent is tangent 53.1 in Figure 1.
- a controller may handle with ease and accuracy the operation of this invention. Programming a computerized controller to perform such functions is a routine process, well known to the art. According to this invention, a controller, based on information received, from a reaction zone for example, controls feed rates, temperatures, pressures, and other parameters in order to achieve the desired results. The controller may also be pre-programmed, by well known to the art techniques, to include flow sheet simulation, which may account for vapor/liquid equilibrium and energy balance effects.
- a preferable type of controller is a computerized controller, and more preferably a "learning computer” or a “neuro- computer”, the functionality of which is known to the art, and which collects information from different places of the device (for example pressure, temperature, chemical or other analysis, etc.), stores this information along with the result (reaction rate, for example), and is programmed to use this information in the future, along with other data if applicable, to make decisions regarding the action to be taken at each instance.
- a “learning computer” or a “neuro- computer” the functionality of which is known to the art, and which collects information from different places of the device (for example pressure, temperature, chemical or other analysis, etc.), stores this information along with the result (reaction rate, for example), and is programmed to use this information in the future, along with other data if applicable, to make decisions regarding the action to be taken at each instance.
- FIGURE 1 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, wherein the curve is characterized by an ascending portion, a tangent to the ascending portion, the inclination (psig/min 2 ) of which represents the rate of increase of the reaction rate, and a maximum followed by a descending portion.
- FIGURE 2 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, with and without adding different amounts of perfluoroacetic acid into the reaction mixture.
- FIGURE 3 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, with and without adding different smaller amounts of perfluoroacetic acid than in the case of Figure 2.
- FIGURE 4 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, with and without adding perfluorooctanoic acid into the reaction mixture.
- FIGURE 5 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, with and without adding different amounts of perfluorobutyric acid into the reaction mixture.
- FIGURE 6 illustrates a curve of pressure change vs. time in a batch reactor during oxidation of cyclohexane to adipic acid, with and without adding perfluorononane or perfluoroacetophenone in the reaction mixture.
- this invention relates to methods of making dibasic acids, by oxidizing a hydrocarbon with a gas containing an oxidant, preferably oxygen.
- the first parameter is the rate at which the initial reaction rate increases after initiation of the reaction and before it reaches a maximum value.
- the second parameter is the consumption of oxidant; oxygen in this case.
- a tubular rocking mini-reactor containing steel balls is used for the determinations.
- the steel balls are added to provide highly enhanced surface factor by means of distributing a thin film on the surface of the steel balls.
- Surface factor is defined in this case as the ratio of the surface of the liquid/gas interface per unit volume of the liquid.
- the mini-reactor comprises a tubular stainless steel body having an inside diameter of 23/32", an outside diameter of 2 ", an outside length of about 11 Y 2 ", and an inside length of about 9 V 2 ".
- the total capacity of the mini-reactor is 75 cc. 890 stainless steel balls having a diameter of 1/8" are used in the mini-reactor as agitation and mixing means, along with a rocking action of + 33 degrees from horizontal at a frequency of 10 cycles per minute.
- the mini -reactor has a screw cap top, a number of thermocouples inside and outside for measuring and controlling the temperature. It is surrounded by heating tape, and insulated by glass fiber. It has ports for feeding gases and liquids. It is also provided with a pressure transducer. Both temperature and pressure are recorded and controlled through a computer using supervisory control software.
- the system is initially purged with nitrogen, and the feed (6-6.5 grams) is added through a port in the top of the mini-reactor which is in an upright position.
- the mini-reactor is then capped and purged again with nitrogen to a pressure of about 50 psig, the temperature is raised to 100° C, the pressure is brought to 100 psig with nitrogen, and the oxygen is introduced to a pressure of an additional 100 psig, thus bringing the total pressure to substantially 200 psig.
- the pressure (P) and the rate of pressure drop (dP/dt), among other variables are then recorded.
- dP/dt follows a parallel path to the path of the reaction rate
- dP/dt represents the reaction rate for all practical purposes. Unless no substantial reaction takes place, the dP/dt follows a curve from substantially zero rate to a maximum through an ascending portion of the curve, and then it drops off again to substantially zero rate on a descending portion of the curve. Oxygen is incrementally added during the period of the ascending portion of the curve, and oxygen feeding is stopped soon after the maximum on the curve has been passed. The increments of oxygen are then added. An initial sharp peak preceding the ascending portion of the curve is disregarded, as it is believed to correspond to a fast oxidation of the initiator, such as acetaldehyde for example.
- promoter and “initiator” are many times used in the literature and in this work interchangeably to mean “initiator”, the more strict meaning of the term “initiator” should be used for a substance which decreases the reaction initiation period, such as acetaldehyde or cyclohexanone, or methylethylketone, for example, and the term “promoter” should be used for a substance that promotes the reaction, such as bromide ions in the case of producing terephthalic acid from p-xylene, for example.
- the mini-reactor was used to run a series of experiments for determining the two important parameters mentioned above, and for demonstrating the instant invention. The procedures presented above were followed.
- the feed solutions for the mini -reactor in the miscellaneous cases are shown in Tables 1 to 13.
- the increments of oxygen additions and oxygen consumption are shown in Tables 1A to 13 A.
- Curve 10 is a plot of oxidation rate in terms of dP/dt (psig/min) versus time that the reaction takes place.
- the initial sharp peak 52.1 is due to an abrupt oxidation of the initiator, acetaldehyde.
- the Curve 10 has an ascending portion 54.1, a maximum 55.1, and a descending portion 56.1.
- the tangent 53.1 to the ascending portion 54.1 given in this case in psig/min 2 , is a measure of the rate of increase of the reaction rate observed within the ascending portion 54.1, in a batch reactor. In other words it is the tangent of the angle formed by the line 53.1 and the Time axis.
- the value of the tangent 53.1 as measured in the batch system, provides the potential for an increased or decreased steady state reaction rate in the case of a respective continuous reactor.
- the rate of increase of the reaction rate by the addition of the fluorocompound, and preferably perfluoroacid is preferably at least 5% higher than the one observed in the absence of the fluorocompound. At increases less than 5%. any benefits received are small.
- the curve of Figure 1 was used as a control to be compared to respective curves obtained with addition of additives, and in order to evaluate different compositions containing fluorocompounds, and especially perfluoroacids.
- the relative oxygen consumption (measured as total psig drop) during the reaction was 267 psig (see Table 1A). Further, the curve 10 has a gradual and smooth transition from the ascending portion 54.1 to the maximum 55.1, to the descending portion 56.1, and then to its substantially zero value 58.1. The maximum was 4 psig/min. The selectivity to adipic acid was 84%.
- Curve 12 in Figure 2 represents a composition containing 7% perfluoroacetic acid.
- This curve is characterized by a high initiator peak 52.2 and an excessively fast rate increase of the reaction rate at the ascending portion 54.2 of curve 12.
- This condition fulfills the requirement of the present invention regarding the rate increase of the reaction rate.
- the relative oxygen consumption in this case was 140 psig, which is considerably lower than 200 psig (75% of 267 psig of curve 10, which represents the same composition of the reaction mixture in the absence of the fluorocompound). This shows that the level of perfluoroacetic acid of at least 7% does not fall within the beneficial range of the present invention, despite the fact that the selectivity to adipic acid was 82%.
- Control of the reaction would suffer substantially in a continuous system under steady state conditions. Suffering of control of the reaction is also indicated by the excessively fast rate increase of the reaction rate at the ascending portion 54.2 of curve 12. It should be noted that the perfluoroacetic acid was injected into the reactor after the initiation had started. In all other cases, discussed hereinbelow, the fluorocompound was in the feed itself.
- Curve 14 in Figure 2 represents a composition containing 3.2% perfluoroacetic acid. This curve is also characterized by a high initiator peak 52.3 and a very fast reaction rate at the ascending portion 54.3 of curve 14. It has a very long initiation (about 1.5 hours). It should be noted that there was no incremental addition of oxygen during the reaction, so that oxygen depletion took over and minimized the conversion to 92 psig. One can also see that if oxygen had been added as in the other cases, the curve would have a higher maximum 55.3, and certainly considerably higher relative oxygen consumption. The selectivity to adipic acid was 76%. This low value is probably due to the long initiation period (about 1.5 hours).
- Curve 16 in Figure 3 represents a composition containing 1.3% perfluoroacetic acid. This curve is also characterized by a very fast reaction rate 53.4 (as compared to 53.1) at the ascending portion 54.4 of curve 16. It had a very short initiation period. It has a considerably higher maximum 55.4 (6 vs. 4 psig/min of the control). The relative oxygen consumption was 262.8 psig, well within the limits of the instant invention. The selectivity to adipic acid was 84%.
- Curve 18 in Figure 3 represents a composition containing 0.3% perfluoroacetic acid. This curve is also characterized by a fast reaction rate 53.5 (as compared to 53.1) at the ascending portion 54.5 of curve 18. It had a very short initiation period. It has a higher reaction rate maximum 55.5 (4.7 vs. 4 psig/min of the control). The relative oxygen consumption was 275.2 psig, well within the limits of the instant invention.. The selectivity to adipic acid was 84%.
- Curve 20' in Figure 4 represents a composition containing 6.4% perfluorooctanoic acid, run at 90° C.
- the inclination of the curve 20' has started deteriorating, mainly because of the lower temperature at which the reaction was conducted. This indicates that the temperature should be certainly higher than 80° C, and preferably higher than 90° C.
- temperatures between 95° C and 105° C are most preferable in the oxidation of cyclohexane to adipic acid, although temperatures as high as 120-150° C may also be used in certain occasions.
- the total oxygen consumed was 268 psig, as compared to 266 psig in the case of the control.
- the selectivity to adipic acid was 84%.
- Curves 22, 24, and 26 in Figure 5 correspond to compositions containing 4.05%, 3.13%), and 2.35% perfluorobutyric acid, respectively.
- Curve 24 has the highest maximum.
- the level (3-13%) of perfluorobutyric acid in the composition corresponding to curve 34 is between the levels (4.05% and 2.35%) of the compositions corresponding to the other two curves 22 and 26.
- the selectivity to adipic acid was 82%, 84%, and 84% for the compositions corresponding to curves 22, 24, and 26, respectively.
- the oxygen consumption was 218, 215 and 243, respectively.
- the above data place these levels of perfluorobutyric acid well within the requirements of the present invention. It is believed by the inventors that a level in the range of 1.2% to 1.7% perfluorobutyric acid in the composition would bring the maximum closer to that of the control, with a lower rate of increase of the reaction rate, and an increase of the amount of relative oxygen consumption.
- Curves 28 and 30 in Figure 6 correspond to compositions containing 4.94% perfluorononane and 6.03%> perfluoroacetophenone, respectively. Both have maxima and rate of increase of the reaction rate moderately higher than that of the control. However, the relative oxygen consumption was considerably higher than that of the control (347 psig and 359 psig, respectively, as compared with 267 psig in the case of the control). The selectivity to adipic acid was in both cases 82%. The above data place these levels of perfluorononane and perfluoroacetophenone well within the requirements of the present invention. The addition of the fluorocompound at the desired levels may be done by direct feeding to the reactor, or through recycled streams, or a combination thereof.
- miscellaneous functions are preferably controlled by a computerized controller, it is possible, according to this invention, to utilize any other type of controller or even manual controls for controlling one or more functions.
- Oxidations according to this invention are non-destructive oxidations, wherein the oxidation product is different than carbon monoxide, carbon dioxide, and a mixture thereof.
- the oxidation product is different than carbon monoxide, carbon dioxide, and a mixture thereof.
- small amounts of these compounds may be formed along with the oxidation product, which may be one product or a mixture of products.
- Examples include, but of course, are not limited to preparation of C 5 - C 8 aliphatic dibasic acids from the corresponding saturated cycloaliphatic hydrocarbons, such as for example preparation of adipic acid from cyclohexane.
- Other examples include, but are not limited to formation of benzoic acid, phthalic acid, isophthalic acid, and terephthalic acid from toluene, ortho-xylene, meta-xylene, and para-xylene, respectively.
- Diacids for example adipic acid, phthalic acid, isophthalic acid, terephthalic acid, and the like
- a third reactant selected from a group consisting of a polyol, a polyamine, and a polyamide in a manner to form a polymer of a polyester, or a polyamide, or a (polyimide and/or poyamideimide), respectively.
- the polyol, the polyamine, and the polyamide are mainly a diol, a diamine, and a diamide, respectively, in order to avoid excessive cross-linking.
- the polymer resulting from this reaction may be spun by well known to the art techniques to form fibers.
- the polymer may be combined with other polymers, fillers, extenders, etc., well known to the art for making miscellaneous composites.
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Abstract
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Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR0008034-9A BR0008034A (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acid in the presence of fluorocomposite |
KR1020017009904A KR20010101783A (en) | 1999-02-04 | 2000-02-04 | Oxidanon of hydrocarbons to acids in the presence of fluoro compounds |
EP00915753A EP1150938A1 (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acids in the presence of fluoro compounds |
AU36974/00A AU3697400A (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acids in the presence of fluoro compounds |
MXPA01007874A MXPA01007874A (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acids in the presence of fluoro compounds. |
JP2000597245A JP2002536350A (en) | 1999-02-04 | 2000-02-04 | Method for oxidizing hydrocarbons to acids in the presence of fluoro compounds |
CA002361709A CA2361709A1 (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acids in the presence of fluoro compounds |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11865299P | 1999-02-04 | 1999-02-04 | |
US60/118,652 | 1999-02-04 |
Publications (1)
Publication Number | Publication Date |
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WO2000046172A1 true WO2000046172A1 (en) | 2000-08-10 |
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ID=22379918
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US2000/003109 WO2000046172A1 (en) | 1999-02-04 | 2000-02-04 | Oxidation of hydrocarbons to acids in the presence of fluoro compounds |
Country Status (9)
Country | Link |
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EP (1) | EP1150938A1 (en) |
JP (1) | JP2002536350A (en) |
KR (1) | KR20010101783A (en) |
CN (1) | CN1339021A (en) |
AU (1) | AU3697400A (en) |
BR (1) | BR0008034A (en) |
CA (1) | CA2361709A1 (en) |
MX (1) | MXPA01007874A (en) |
WO (1) | WO2000046172A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001066502A1 (en) * | 2000-03-08 | 2001-09-13 | Rhodia Polyamide Intermediates | Method for oxidising hydrocarbons into acids |
WO2001066506A1 (en) * | 2000-03-08 | 2001-09-13 | Rhodia Polyamide Intermediates | Method for oxidising hydrocarbons into acids |
US7507856B2 (en) * | 2001-08-03 | 2009-03-24 | Rhodia Polyamide Intermediates | Method of oxidising hydrocarbons to acids |
JP2011520442A (en) * | 2008-05-14 | 2011-07-21 | ジャワハーラル ネール センター フォー アドヴァンスド サイエンティフィック リサーチ | DNA sequence of TAT, gene construct, vaccine and methods thereof |
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CN108341939A (en) * | 2018-01-23 | 2018-07-31 | 浙江省现代纺织工业研究院 | A kind of preparation method of hydridization paraxylene |
CN112521266B (en) * | 2019-09-18 | 2023-04-07 | 中国石油化工股份有限公司 | Process for producing adipic acid |
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US3947494A (en) * | 1972-12-20 | 1976-03-30 | Standard Oil Company | Quality of phthalic acids improved by haloacetic acid |
JPH05286891A (en) * | 1992-04-10 | 1993-11-02 | Nkk Corp | Production of naphthalenedicarboxylic acid |
WO1996031455A1 (en) * | 1995-04-07 | 1996-10-10 | Rhone-Poulenc Fiber And Resin Intermediates | Method for oxidising hydrocarbons, alcohols or ketones using heterogeneous catalysis |
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2000
- 2000-02-04 KR KR1020017009904A patent/KR20010101783A/en not_active Application Discontinuation
- 2000-02-04 EP EP00915753A patent/EP1150938A1/en not_active Withdrawn
- 2000-02-04 AU AU36974/00A patent/AU3697400A/en not_active Abandoned
- 2000-02-04 CA CA002361709A patent/CA2361709A1/en not_active Abandoned
- 2000-02-04 JP JP2000597245A patent/JP2002536350A/en not_active Withdrawn
- 2000-02-04 BR BR0008034-9A patent/BR0008034A/en not_active Application Discontinuation
- 2000-02-04 WO PCT/US2000/003109 patent/WO2000046172A1/en not_active Application Discontinuation
- 2000-02-04 MX MXPA01007874A patent/MXPA01007874A/en unknown
- 2000-02-04 CN CN00803252A patent/CN1339021A/en active Pending
Patent Citations (3)
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Cited By (6)
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WO2001066502A1 (en) * | 2000-03-08 | 2001-09-13 | Rhodia Polyamide Intermediates | Method for oxidising hydrocarbons into acids |
WO2001066506A1 (en) * | 2000-03-08 | 2001-09-13 | Rhodia Polyamide Intermediates | Method for oxidising hydrocarbons into acids |
FR2806078A1 (en) * | 2000-03-08 | 2001-09-14 | Rhodia Polyamide Intermediates | Oxidizing aliphatic, cycloaliphatic or alkyl aromatic hydrocarbons to acids or polyacids, especially for use in production of adipic acid, using molecular oxygen containing oxidizing agent and auxiliary fluorinated compound |
US7041848B2 (en) | 2000-03-08 | 2006-05-09 | Rhodia Polymide Intermediates | Method for oxidizing hydrocarbons into acids |
US7507856B2 (en) * | 2001-08-03 | 2009-03-24 | Rhodia Polyamide Intermediates | Method of oxidising hydrocarbons to acids |
JP2011520442A (en) * | 2008-05-14 | 2011-07-21 | ジャワハーラル ネール センター フォー アドヴァンスド サイエンティフィック リサーチ | DNA sequence of TAT, gene construct, vaccine and methods thereof |
Also Published As
Publication number | Publication date |
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CN1339021A (en) | 2002-03-06 |
CA2361709A1 (en) | 2000-08-10 |
AU3697400A (en) | 2000-08-25 |
BR0008034A (en) | 2001-11-06 |
EP1150938A1 (en) | 2001-11-07 |
JP2002536350A (en) | 2002-10-29 |
MXPA01007874A (en) | 2002-04-24 |
KR20010101783A (en) | 2001-11-14 |
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