Classifications

• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
  • G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
  • G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
  • G01R31/3644—Constructional arrangements
  • G01R31/3648—Constructional arrangements comprising digital calculation means, e.g. for performing an algorithm
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
  • G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
  • G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
  • G01R31/374—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC] with means for correcting the measurement for temperature or ageing
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
  • G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
  • G01R31/36—Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
  • G01R31/382—Arrangements for monitoring battery or accumulator variables, e.g. SoC
  • G01R31/3835—Arrangements for monitoring battery or accumulator variables, e.g. SoC involving only voltage measurements

Definitions

• NiCd nickel cadmium
• the battery capacity of NiCd batteries are determined by charging the battery to 100% state of charge and then discharging the battery at a constant current. The time required for the battery to discharge to a specified voltage is measured. The battery capacity in ampere-hour (A- hr.) is then calculated by multiplying the time in hours to discharge the battery by the constant discharge current. This method takes several hours of charging and discharging.
• FIGURE 1 is a schematic of a battery charging and analyzing circuit
• FIGURE 2 is a graphical representation of the voltage and current curves during battery charging at room temperature
• FIGURE 3a is a graphical representation of the voltage and current curves in the evaluation cycle of the invention.
• FIGURE 3b is an alternate current charging curve
• FIGURE 4 is a graphical representation of the capacity-temperature calibration curve at room temperature
• FIGURE 5 is a graphical representation of the capacity-temperature calibration curve at -30°C;
• FIGURE 6 is a graphical representation of the voltage and current curves of a 20 Ah, 24 V NiCd battery under test in accordance with the invention.
• FIGURE 7 is a graphical representation of the voltage and current curves of a A 30 Ah, 24V NiCd battery under test in accordance with the invention.
• This invention provides for a time-saving method for determining the capacity of a nickel cadmium battery, without discharging the battery.
• a NiCd battery charging system 10 comprises a microprocessor 12 in combination with a data acquisition system 14, such as a National Instruments SCXI data acquisition system.
• the components of the data acquisition system 14 are Labview 4.0 software, a signal conditioning unit, such as a National Instruments signal conditioning system with digital to analog converters and analog to digital converters and thermocouple modules.
• System 10 further comprises a programmable power supply 16, a relay 18, a 50A, 50mV shunt 20 to measure current, a thermocouple 21 to measure temperature, a unit under test 22, in this case, a 24V NiCd battery, and a diode 24 to protect the power supply.
• the microprocessor is programmed using Labview 4.0 to control the current output of the power supply 16 and to close/open the relay 18 to electrically connect/disconnect the battery 22.
• the microprocessor 12 stores the voltage, current and temperature data acquired by the data acquisition hardware.
• the battery 22 is charged to full capacity, i.e. 100% state of charge, as graphically shown in Figure 2. This is achieved by applying a constant current 26 to the battery. As the battery is subjected to this constant current charge, the voltage goes through three phases: gradual voltage rise indicating charge reaction, as indicated by time period 28; a sharp voltage rise indicating initiation of gas reaction, as indicated by time period 30; and a plateau region showing simultaneous gas reaction and charge reaction, as indicated by time period 32. During time period 28, the battery voltage gradually rises until the cumulative charge delivered to the battery is about 80 to 90% of the battery's charge capacity. At this point, 75% of the battery's capacity is normally available upon discharge.
• the battery voltage quickly increases as the battery starts evolving gas towards the end of the charge process.
• the battery voltage tends to stabilize until the battery is fully charged at the end of time period 32.
• the battery voltage gradually decreases in the overcharge portion of the charge. After a decrease of 15mV has been detected in the overcharge, the current charge is terminated at point 36 and the battery is left in open circuit, time period 38 and is fully charged.
• the battery 22 After the battery 22 comes to a stabilized status in terms of temperature and open circuit voltage, it is subjected to a test cycle. Before starting the test cycle, safe voltage and current limits are established from the known characteristics of the battery as would be published by the battery manufacturer.
• an increasing charge current 42 is applied to the battery.
• the charge current is started from zero and increases linearly up to the maximum current the charging system can output or to the identified safe battery voltage and current limits, whichever is lower.
• the charge current will be as shown in Fig. 3a due to the output lag time of the power supply compared with the programmed value.
• the increasing current charge does not have to be linear, as long as it increases as a known function of time.
• consecutive pulses with an increasing current amplitude can also be used during the ramp test as shown in Fig. 3b.
• the current charge ramp is then decreased at any negative slope 46 until the current reaches zero.
• the slope of the decreasing current charge is the same slope as the current charge 42.
• the battery terminal voltage 44 is continuously measured and recorded. The slope of the voltage curve is also calculated. When the slope goes through a maximum it indicates the transition from charge reaction to gas reaction. The current at this transition point is referred to as the gas current (l gas ).
• l gas gas correlates with the battery capacity.
• l gas is a function of ambient battery temperature and accordingly, the correlation between l gas and battery capacity must be performed at a given temperature for fully charged nickel-cadmium batteries. Calibrations for nickel cadmium batteries at 21 °C and -30° C are shown in Figures 4 and 5.
• Determination of the slope of the voltage curve is accomplished by calculating the difference in successive voltage values over a small interval. This data is then subjected to a five point moving averaging technique that was found to provide a reliable method to suppress noise caused by the electronics circuitry. As is known to those skilled in the art, any digital filtering technique to suppress noise may be used. Averaging methods using less than 5 data points did not suppress the noise adequately; hence did not provide satisfactory results. Using more than 5 points in the average reduces the peak intensity severely. Peak detection was accomplished by comparing each voltage difference point with an average of two voltage difference points before and after the point. The point should be greater than both the averages by a predetermined margin in order to indicate a maximum in slope. The current at this point is determined to be the l gas for the battery. The battery's capacity is calculated using this l gas and a temperature calibrated curve.
• a temperature-calibrated curve is determined as follows. Nickel cadmium batteries of various capacities were subjected to the charge regime as described above. Once the battery was completely charged, it was left in open circuit until the temperature and voltage stabilized. Once the battery was in an equilibrium state, it was subjected to test cycle outlined above and the l gas value was noted. Next, the battery was completely discharged. This was accomplished by drawing a constant current from the battery. The discharge was terminated when the battery voltage dropped to 0.95 volts per cell. The capacity value was calculated by multiplying the discharge current by the amount of time required to reach 0.95 volts per cell. The calibration curve was generated using the capacity and l gas values from numerous iterations to the above procedure with different nickel cadmium batteries.
• the safe voltage and current limits imposed on the system during the ramp test cycle significantly affect the gas current, l gas . Therefore it is important to remember that one can set these limits at different values within a range for nickel cadmium batteries and generate different calibration curves. As long as the battery whose capacity has to be determined is subjected to the same conditions as the calibration curve batteries, the results should be satisfactory.
• the safe voltage limit for nickel-cadmium batteries can be set at in the range 1.3 to 1.65 volts per cell.
• a 20 Ah, 24 V NiCd battery was completely charged, following the charge regime described above. Once at an equilibrium state, the battery was subjected to a test cycle. Voltage and current data from the test cycle are shown in figure 6. In the figure, the maximum slope and the corresponding current are indicated by the arrows. It was determined, via the methods described above, that the battery had 28.1 Ah available capacity. Upon a complete discharge, the battery was found to provide 27.8 Ah.
• Example 2 With reference to Fig. 7, a 30 Ah, 24V NiCd battery was placed in a temperature-control chamber that was set to -30° Celcius. After the battery temperature reached this ambient temperature, it was completely charged, following the charge regime described above. Once at an equilibrium state, the battery was subjected to a test cycle. Voltage and current data from the test cycle are shown in figure 7. In the figure, the maximum slope and the corresponding current are indicated by the arrows. It was determined, via the methods described above, that the battery had 43.1 Ah available capacity. Upon a complete discharge, the battery was found to provide 44.9 Ah.

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• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Secondary Cells (AREA)
• Charge And Discharge Circuits For Batteries Or The Like (AREA)

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• 1998
  • 1998-09-15 US US09/153,606 patent/US5926008A/en not_active Expired - Fee Related
• 1999
  • 1999-09-15 WO PCT/US1999/020955 patent/WO2000016115A1/en not_active Ceased
  • 1999-09-15 EP EP99949636A patent/EP1114329A1/en not_active Withdrawn
  • 1999-09-15 AU AU62470/99A patent/AU6247099A/en not_active Abandoned
  • 1999-09-15 JP JP2000570597A patent/JP2002525794A/ja active Pending
  • 1999-09-15 CA CA002344386A patent/CA2344386A1/en not_active Abandoned
  • 1999-09-15 KR KR1020017003389A patent/KR20010075142A/ko not_active Ceased

Patent Citations (4)

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