WO2000013522A1 - Confiserie a base de nougat a macher contenant de la cafeine - Google Patents

Confiserie a base de nougat a macher contenant de la cafeine Download PDF

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Publication number
WO2000013522A1
WO2000013522A1 PCT/US1999/017838 US9917838W WO0013522A1 WO 2000013522 A1 WO2000013522 A1 WO 2000013522A1 US 9917838 W US9917838 W US 9917838W WO 0013522 A1 WO0013522 A1 WO 0013522A1
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WO
WIPO (PCT)
Prior art keywords
saccharide
group
confectionery
ingredients
hydrobinding
Prior art date
Application number
PCT/US1999/017838
Other languages
English (en)
Inventor
Subraman R. Cherukuri
Martin K. Schaller
Robert K. Yang
Supapong Siris
David M. Teale
Original Assignee
Fuisz Technologies Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuisz Technologies Ltd. filed Critical Fuisz Technologies Ltd.
Priority to AU53937/99A priority Critical patent/AU5393799A/en
Publication of WO2000013522A1 publication Critical patent/WO2000013522A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02—Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/0205—Manufacture or treatment of liquids, pastes, creams, granules, shred or powder
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02—Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/10—Candy-pulling machines ; Processes or apparatus for making cotton candy or candy floss
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/364—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
    • A23G3/368—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/52—Aerated, foamed, cellular or porous products
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/50—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by shape, structure or physical form, e.g. products with supported structure
    • A23G3/54—Composite products, e.g. layered, coated, filled

Definitions

  • the present invention relates to the art of unique delivery systems for comestibles, especially to novel methods of making a functionalized confectionery mass which do not require cooking to dehydrate, as well as products therefrom. More particularly, the invention relates to comestible delivery systems, uncooked confectioneries and nougats, and methods for making same.
  • the invention also provides a soft, chewy confectionery nougat-type composition in the form of a bite-size serving containing an active ingredient, advantageously caffeine. Further provided is a novel encapsulation containing an active ingredient such as caffeine, which may be utilized as part of a comestible delivery system.
  • nougats It is generally considered a necessity in the art of preparing food or drug delivery systems like confectionery masses such as chewy nougats to use water as a mixing medium and source of hydration for ingredients.
  • a typical recipe calls for soaking egg albumen in water over a period of time, such as overnight, in order to fully hydrate the proteinaceous material contained therein. Following hydration the egg albumen is stirred and strained before being beaten into a stiff foam.
  • Other ingredients such as sugar, honey, and corn syrup are separately cooked with water to a relatively high cooking temperature of from about 135°C to about 138°C to achieve the necessary interaction among the ingredients. The cooked mixture is then poured into the egg and beaten with a nougat mixer.
  • This conventional nougat preparation method requires cooking the ingredients and using a significant amount of water to serve as a mixing medium and source of hydration.
  • the amount of water used is much larger than that which would permit the formation of the solid nougat.
  • the water is supplied in more than sufficient quantity to ensure that specific ingredients are wetted and functionalized. Consequently, the excessive moisture must be driven off as much as possible to achieve the structural integrity and consistency necessary for the end product. Unless the water is forcibly removed, the process will result in an incoherent product having no significant structural integrity.
  • Removal of excess water is generally undertaken by a combination of mixing and boiling to drive off the moisture and bring the mass to proper viscosity and consistency.
  • This process can be highly energy-inefficient and very costly as it requires heat, excessive handling of nougat masses, flashing off of some critical fluids, and an inability to incorporate heat sensitive materials, as well as a less desirable overall stability of the product.
  • it is not effective in completely eliminating a substantial amount of the moisture contained in the confectionery mass.
  • the present invention overcomes the difficulties set forth above as well as other difficulties generally associated with the prior art.
  • both the necessity of cooking the confection and using excessive water to mix and hydrate one or more ingredients is eliminated, and the method and product of the invention are obtained without any need for dehydration. Consequently, the detrimental heat history generally associated with energy-intensive procedures is also eliminated. Separation of the water from the resulting product is avoided and the lowered water activity results in a product having superior physical, storage, and organoleptic properties with reduced microbial growth problems.
  • the present invention addresses the issue of producing a chewy nougat confectionery formulation containing caffeine which is highly palatable and is storage stable.
  • the composition of the invention also effectively solves the problem of taste- masking the foul, bitter characteristics of caffeine without diluting its potency or efficacy.
  • the present invention is a method of making a unique food and drug delivery system, and especially a novel confectionery delivery system, especially a nougat, via hydration, without the need for cooking or subsequent dehydrating in order to produce the confectionery mass.
  • the present invention also includes the product resulting from the new method of preparation.
  • a saccharide-based component is combined with a hydrated hydrobinding component to form the confectionery of the system.
  • one or more active ingredients can be included in the confectionery mass which is formed as a result of the present invention.
  • the active ingredients are typically ones which are intended to produce a biological and/or chemical response in the body.
  • One or more of these active ingredients may be encapsulated using a novel combination of materials, hereinafter described. The active ingredient encapsulation may then be included as part of the confectionery mass.
  • Especially preferred actives as part of the composition of the invention include bioassimilable sources of minerals such as calcium, or calcium with magnesium.
  • Other preferred actives include one or more vitamins.
  • substances such as botanical substance extracts like herbs and derivatives of plant material such as bark, seeds, stem, flowers, leaves, roots and the like.
  • Other preferred actives include many types of chemical substances which cannot be delivered in a chewable delivery system because of the attendant organoleptic problems associated with these substances. Such actives can include the bitter drug caffeine, for example.
  • the product resulting from the present invention is unique because it requires no cooking and no dehydration by traditional heating at high temperatures to produce, and has substantially no phase separation of moisture.
  • the only moisture present is bound therein in an amount sufficient to functionalize the mass.
  • the product can be prepared without cooking.
  • the product may also be prepared using flash-flow processing, low or high shear mixing, or any combination thereof.
  • flash-flow processing low or high shear mixing, or any combination thereof.
  • the final product furthermore exhibits improved content uniformity and improved organoleptic qualities.
  • the formulated confectionery delivery system herein described is more tasty (no grit or chalkiness) and is highly storage stable as compared to many of the current formulations available in the art.
  • the confectionery-mass delivery systems in accordance with the present invention includes a saccharide-based component and a hydrobinding component, the latter component being hydrated sufficiently to provide controlled water delivery to the saccharide-based component and/or other ingredients.
  • Controlled water delivery means delivery of water in an amount and at a rate which is sufficient to provide internal viscosity and cohesivity to the saccharide-based component.
  • the word hydrated as used in the term hydrated hydrobound component herein means containing sufficient water to provide the requisite controlled water delivery.
  • the system created by the combination of the present invention is a water-starved system, which means that the system has only enough moisture to bind the ingredients together and provide internal lubricity. Since the ingredients are competing for moisture due to enhanced wettability, there is virtually no free moisture available to separate from the mass, and thus no attendant problems associated therewith.
  • the hydrobinding component is used to provide a functionalized hydrobound confectionery mass.
  • the hydrobinding component is thus an ingredient which imbibes, delivers and maintains water in an amount sufficient to functionalize the resulting mass.
  • the water which is hydrobound does not separate and become a separate phase.
  • a hydrobinding component cooperates with other ingredients to deliver and maintain water sufficient to functionalize the mass of ingredients (including those ingredients which may have been subjected to flash-flow processing - e.g. the saccharide-based component, hereinafter described).
  • ingredients useful in the present invention which make up the hydrobinding component include, for example, proteinaceous materials known to those skilled in the art, and preferably gelatins of various grades and types. Also preferred are food grade gums such as gum arabic, carrageenan, guar gum, and locust bean gum, and mixtures thereof. Hydrobinding components constituting a mixture of ingredients are desirable in some situations. Highly preferred hydrobinding ingredients include, for example, a mixture of gelatin and gum arabic, or a mixture of carrageenan and locust bean gum with a crosslinking agent, such as potassium citrate or potassium chloride, which induces crosslinking between these materials.
  • a crosslinking agent such as potassium citrate or potassium chloride
  • hydrobinding materials are advantageous not only for their hydrobinding capacities, but also because they impart viscoelasticity to the resulting confectionery. It is possible that crosslinking in these materials contributes to their desirable physical properties.
  • the hydrobinding material can also benefit from inclusion of a wetting agent or humectant such as a polyol known in the art, desirably glycerin, or other functionally similar materials which are commercially available.
  • the hydrobinding component will comprise about 0.5-20% of the confectionery system of the invention. Preferably, the hydrobinding component will be within the range of about 5-15%, and even more desirably within the range of about 5-12% of the final confectionery composition.
  • water will comprise about 10 - 80% thereof, and preferably about 10 - 60% of the hydrobinding component.
  • the proteinaceous material or the gum, or combination thereof will make up about 0.5 to 60% of the hydrobinding component, and more preferably be within the range of about 3 to 50%, more desirably about 3 to 20% (unless otherwise set forth, all %s herein are percentages by weight, or weight percent).
  • a wetting or softening agent such as a polyol, preferably glycerin, which may be included in amounts equal to about 0 - 75%, preferably about 0.1 - 70% of the composition of the invention, even more desirably about 10-70%.
  • the glycerin (or other selected material) can also function as a humectant, and thereby keep moisture in the system.
  • the hydrobinding component may also be aerated, preferably in the presence of an aerating agent, before or after being combined with the other components making up the confectionery composition of the invention.
  • aerating agents include egg whites and soy protein.
  • Aerating agents are desirably added in amounts within the range of about 0 - 5%, more desirably 0.1 - 3% of the confectionery mass of the invention.
  • ingredients which are used in the hydrobinding component may also be added as part of the saccharide-based component, hereinbelow described.
  • gelatins and food grade gums such as gum arabic, carrageenan, guar gum, locust bean gum, etc., can be used to prepare the saccharide-based component, e.g., by being included in the feedstock used to prepare that component.
  • the invention also employs a saccharide-based material as another major component (the hydrobinding material being the heretofore set forth first major component).
  • the saccharide-based material can include any of a large variety of saccharide materials, such as small sugars, e.g., dextrose, sucrose, fructose, etc., and larger saccharides such as corn syrup solids and polydextrose, as well as mixtures of two or more of these materials.
  • Corn syrup solids are highly preferred for use as the saccharide-based material in the composition of the invention.
  • Corn syrup solids are commonly known as maltodextrins.
  • Maltodextrins are composed of water soluble glucose polymers obtained from the reaction of the starch with acid or enzymes in the presence of water.
  • Polydextrose is a non-sucrose, essentially non-nutritive, carbohydrate substitute. It can be prepared from polymerization of glucose in the presence of polycarboxylic acid catalysts and polyols. Generally, polydextrose is known to be commercially available in three forms: Polydextrose A and Polydextrose K, which are powdered solids, and Polydextrose N supplied as a 70% solution. Each of these products can also contain some low molecular weight components, such as glucose, sorbitol, and oligomers.
  • Sugars can also be used as saccharide-based materials according to the invention.
  • Sugars are those substances which are based on simple crystalline mono- and di-saccharide structures, i.e., based on C 5 (pentose) and C 6 (hexose) sugar structures.
  • Sugars include dextrose, sucrose, fructose, lactose, maltose, etc., and sugar alcohols such as sorbitol, mannitol, maltitol, etc. Of these, fructose and/or maltose may often be especially desirable.
  • the foregoing saccharide-based component can comprise about 30 - 99.5% of the confectionery delivery system according to the embodiments herein set forth.
  • saccharide-based component there will be about 40 - 75% of this component present, and even more desirably about 50-70% present.
  • those skilled in the art may discover a higher or lower percentage of the saccharide-based component, or other ingredients herein set forth, will produce a suitable final product, depending upon the final characteristics, e.g. texture, mouth feel, juiciness, product consistency, etc., which are desired.
  • a highly preferred saccharide-based material will comprise a mixture of corn syrup solids and fructose in a ratio range of approximately 50/50 or 30/70.
  • enhancing materials can include, for example, flavors, sweeteners, colorants, surfactants or emulsifiers, and fats or oils. Any one or a combination of more than one of the foregoing may comprise from about 0 - 20% of the confectionery mass, and more desirably be within the range of about 5 - 10% or even up to 15% of the comestible mass.
  • Flavors may be chosen from natural and synthetic flavoring liquids.
  • An illustrative list of such agents includes volatile oils, synthetic flavor oils, flavoring aromatics, oils, liquids, oleoresins or extracts derived from plants, leaves, flowers, fruits, stems and combination thereof available to the skilled artisan.
  • flavorings may include whole and partial fruits and nuts, peanut butter, candy bits, chocolate chips, bran flakes, etc.
  • Sweeteners may be added to the confectionery system of the invention. These may be chosen from the following non-limiting list: glucose (corn syrup), dextrose, invert sugar, fructose, and mixtures thereof (in addition to those which may be utilized as part of the saccharide-based component), saccharin and its various salts such as the sodium salt; dipeptide sweeteners such as aspartame; dihydrochalcone compounds, glycyrrhizin; Stevia Rebaudiana (Stevioside); chloro derivatives of sucrose such as sucralose; sugar alcohols such as sorbitol, mannitol, xylitol, and the like.
  • sweeteners 3,6-dihydro- 6-methyl-l-l-l,2,3-oxathiazin- 4-one-2,2-dioxide, particularly the potassium salt (acesulfame-K), and sodium and calcium salts thereof.
  • Other sweeteners may also be used.
  • the sweeteners are added in amounts equal to about 0 - 10% of the composition, and preferably about 0.1 - 5%.
  • Surfactants or emulsifiers may also be included in the composition of the invention. These may be any food grade emulsifying material, for example, lecithin or other phospholipid material, monoglycerides and/or diglycerides, and mixtures thereof in amounts of from about 0 - 3%, more desirably about 0.1 - 1%.
  • Fats may also be included in the composition, and these can include partially or entirely unsaturated fats such as palm oil and cocoa butter. Hard fats having melting points above body temperature (37 degrees C), and soft fats having a melting point of about or below body temperature, can be used alone or in combination. The texture and mouth feel of the resulting confection can be influenced by selecting the types and amounts of fats included in the saccharide-based component. Fats marketed under such trade names as Durem and Paramount have been found to be useful. Those skilled in the art will find that fats are optional as part of the composition of the invention, and may be eliminated altogether if so desired. Thus, fats will comprise about 0 - 10% of the product herein set forth, preferably less than about 7%, and even more preferably less than about 5%.
  • Additional materials which can be incorporated into the confectionery composition include, for example, biologically and chemically active ingredients such as medicinal substances, e.g. drugs, pharmaceuticals and antacids. These are referred to herein as active ingredients. Active ingredients may make up from about 0 - 50% of the product of the invention, and even more depending upon the needs and abilities of those skilled in the art. It is preferred, however, to include up to about 40% of active substance in the compositions set forth herein.
  • actives would include many OTC preparations suitable for oral consumption, as for example, analgesics such as acetominophen, ibuoprofen, antihistamines and cough and cold relief actives.
  • analgesics such as acetominophen, ibuoprofen, antihistamines and cough and cold relief actives.
  • Other examples of such actives would include vitamins and minerals (e.g. calcium, magnesium, etc.), as well as protein from animal and/or vegetable sources (to be distinguished from the proteinaceous material utilized in the hydrobinding component), and soluble and/or insoluble dietary fiber.
  • Also to be included as actives include such naturally-derived products as botanical substance extracts such as derivatives of plants and herbs, as for example, bark, stem, leaves, roots, berries and flowers.
  • the botanical extracts would much desirably be those which are recognized for their nutraceutical properties.
  • Non-limiting examples of these botanical extracts could include ginseng, ginkoba, gingko biloba, St. John's wort, and the like.
  • One source for these materials may be found under the brand name STAND-EXTM from Bio- Botanica, Inc., including Lipo Chemicals.
  • Other nutraceutical ingredients are also contemplated by the invention.
  • actives i.e. active ingredients
  • these can include such food material as fiber and other vegetable and fruit materials.
  • useful comestible delivery systems can also be produced wherein as little as only a trace amount of the total weight of the product is a deliverable active ingredient.
  • the chewy confectionery composition herein set forth contains one or more active substances which until now could not be easily administered via a chewable delivery system because of their relatively poor organoleptic properties. These biological and chemical substances are fairly unpleasant looking, tasting or smelling, have a disagreeable mouthfeel, or are otherwise difficult to swallow. Chewing would normally only exacerbate the unpleasantness.
  • the unique confectionery system herein provided effectively taste masks many or all of these substances, and thereby functions as a unique delivery system for these actives.
  • the heretofore described components constituting these formulations effectively taste-mask the bitterness and bad taste associated with these myriad drugs, food substances and nutraceuticals.
  • caffeine is an extremely bitter tasting white drug, and therefore is not a likely candidate for inclusion in a chewy confectionery formulation.
  • the chewy confectionery herein described thus functions as a delivery system for the caffeine, as well as for other active substances.
  • a dosage of caffeine within the range of about 0.1 to 500 mg is recommended.
  • a single serving should contain about 10 to 150 mg of caffeine. It is especially desirable to include about 25 to 100 mg. in a single dose.
  • any caffeine will typically make up about 0.1 to 5% of the final composition of the invention, and more desirably be within the range of about 0.5 to 2%. These amounts can vary, depending upon the desires of the particular skilled artisan.
  • one or more active ingredients herein described as part of the confectionery composition of the invention may be included as part of an encapsulated matrix using methods known in the art, or hereinafter available.
  • the flash-flow processing techniques as set forth in U.S. Patent No. 5,380,473 are utilized.
  • the techniques of the '473 patent may be further utilized in conjunction with a unique tower device in which material to be encapsulated is provided in free fall by a sprayer at the top of the tower, and an encapsulant material such as oleaginous substances is extruded in the form of droplets to coat and encapsulate the dry, particulate material exiting the tower.
  • Other methods available in the art such as, e.g.
  • Simple mixing methods with industrial scale mixing equipment may also be utilized.
  • Caffeine for example, may be encapsulated using one or more food agents such as emulsifiers, as well as oleaginous material such as fats or oils, and food-grade waxes. Flavoring agents and sweeteners (which may be selected from the listing heretofore provided, and further providing one or more coffees or coffee flavors) may also be utilized.
  • the caffeine is enrobed and encased by the oleaginous material and other ingredients, thereby masking its bitter taste, but at the same time providing a mechanism for absorption in the dietary tract.
  • the active ingredient will comprise about 0.01 to 99.99% of the encapsulation, and preferably be within the range of about 5 to 50% thereof.
  • the oleaginous material will make up from about 0.01 to 99.99% of the encapsulation, and more desirably will comprise about 10 to 80% thereof.
  • the chewy confectionery products according to the various embodiments of the invention are tasty and sweet, with a smooth nougat-like texture and consistency, with no grit or chalkiness. These products are well hydrated, and yet evidence no phase separation of moisture upon extended periods of storage. They require no dehydration to produce, i.e., the product can be prepared without cooking. The only moisture present is supplied by the hydrated hydrobinding component in an amount sufficient to functionalize the mass. No excess water is thus present, and thus the final product of the invention is stabilized with regard to nutritional content, microbial growth, organoleptic characteristics and other factors.
  • water activity is significantly lower than water activity of similar products found in the candy bar industry.
  • candy bars usually have a water activity of 62% - 68% equilibrium relative humidity (ERH).
  • ERH equilibrium relative humidity
  • the confectionery product of the invention has at most only about a 60% ERH, and is preferably not greater than about 55% ERH.
  • Another measure of free water in foodstuffs can be provided by the amount of biological growth within the composition.
  • the biological activity is less than about 100 ppm, preferably less than about 25 ppm, and most preferably less than 10 ppm.
  • Shearform matrix refers to the product prepared by the method of flash-flow processing, a method which mixes and conditions ingredients for intimate contacting and enhanced hydration described, for example, in U.S. Patent No. 5,587,198 and its progeny.
  • flash-flow has become recognized in the art as referring to a process which uses conditions of temperature and force to transform a solid feedstock having a certain morphological and/or chemical structure into a different morphological and/or chemical form without subjecting the solids to excessive heat or other requirements inherent in extrusion processing.
  • the resultant structure has now been referred to as a "shearform matrix.”
  • the terms flash-flow and shearform matrix are further described and set forth in commonly-owned U.S. Patent Nos. 5,236,734, 5,238,696, 5,518,730, 5,387,431, 5,429,836, 5,582,855 and recently allowed U.S. S.N. 08/854,344.
  • Flash-flow processing can be advantageous in the present invention since it is useful for preparing ingredients to be easily and quickly mixed and hydrated.
  • Another very important result of flash-flow processing is intimate mixing of the ingredients. Intimate mixing has traditionally been achieved by the use of water as a mixing medium. Flash-flow processing, however, intimately contacts ingredients and randomizes ingredient location and structure of the resulting shearform matrix. Randomizing the structure can be thought of as opening the physical and/or chemical structure for hydration.
  • flash-flow processing not only ensures intimate mixing of ingredients without the use of water as a medium, but also conditions the ingredients for subsequent wetting with a minimum of water.
  • Flash-flow processing can be accomplished either by a flash-heat method or via the somewhat less preferred flash-shear method, as described further herein.
  • the feedstock is heated sufficiently to create an internal flow condition, which permits internal movement of the feedstock at a subparticle level, and to exit openings provided in the perimeter of a spinning head.
  • the centrifugal force created in the spinning head flings the flowing feedstock material outwardly from the head so that it reforms with a changed structure, i.e. a shearform matrix.
  • the force necessary to separate and discharge flowable feedstock is provided by centrifugal force and the force of the ambient atmosphere impinging on feedstock exiting the spinning head.
  • One apparatus for implementing a flash-heat process is a cotton candy fabricating type machine.
  • Other apparatus which provides similar forces and temperature gradient conditions substantially equivalent to flash-heat can also be used.
  • a spinning machine developed by Fuisz Technologies Ltd. of Chantilly, VA and patented under U.S. Patent No. 5,458,823 may be especially preferred for the flash-heat process.
  • This patent describes a spinning machine which has a series of elongated heating elements arranged in between a base and a cover. The heating elements, base and cover together define a chamber into which a non-solubilized feedstock material is inserted which is capable of intraparticle flow upon application of heat and force.
  • Means are provided for individually heating each of the elongated heating elements, and restriction means in the form of a cylindrical shell or annular plate which circumscribes the heating elements permits restrictive flow of the processed feedstock which is expelled from the chamber.
  • a shearform matrix is produced by raising the temperature of the feedstock, which includes a non-solubilized carrier such as a saccharide material, until the carrier undergoes internal flow upon application of a fluid shear force.
  • the feedstock is advanced and ejected while in internal flow condition, and subjected to disruptive fluid shear force to form multiple parts or masses which have a morphology different from that of the original feedstock.
  • the flash-shear process can be carried out in an apparatus which has means for increasing the temperature of a non-solubilized feedstock and means for simultaneously advancing it for ejection.
  • a multiple heating zone twin screw extruder can be used for increasing the temperature of the non-solubilized feedstock.
  • a second element of the apparatus is an ejector which reduces the feedstock to a condition for shearing.
  • the ejector is in fluid communication with the means for increasing the temperature and is arranged at a point to receive the feedstock while it is in internal flow condition.
  • one or more components of the composition of the invention may be advantageously processed using flash-flow procedures, e.g. flash-heat or flash shear.
  • flash-flow procedures e.g. flash-heat or flash shear.
  • the saccharide-based component of the invention Maltodextrin, for example, may be utilized as the feedstock to process through the flash-flow apparatus.
  • the saccharide-based component can also serve as a "carrier" material for piggybacking some of the other constituents which may also be flash-flow processed with the saccharide-based component, e.g. one or more of the emulsifiers, oils, fats, flavorings, and sweeteners etc., as well as one or more of the active materials.
  • the saccharide-based component and any optional ingredients are provided in the form of a shearform matrix, as set forth above.
  • One embodiment of the present invention may also include pre-flash-flow processing of certain ingredients.
  • Pre-flash-flow processing is simply flash-flow processing of one or more ingredients before combining these with either the saccharide- based component or the hydrobinding component for additional flash-flow processing or additional admixing. Flash-flow processing results in increased surface area and increased solubility of the ingredients subjected thereto, and contributes to actual binding of the ingredients to each other, and therefore, preliminary or pre-flash-flow processing may be particularly advantageous to the skilled artisan.
  • Another means for processing the components making up the compositions of the invention is via low and high shear mixing processes. In some instances, the added time and expense associated with flash-flow processing (or pre-flash-flow processing) may be significantly reduced or avoided.
  • the same qualities associated with the final product e.g. shear-form matrix attributes, intimate mixing, no cooking
  • high shear mixing refers to relatively intensive mixing action concentrated in a localized area.
  • the high speed impact of mixing mechanisms such as blades or choppers results in shearing action.
  • This in turn creates localized high shear force and a fluidizing effect at the point of contact, which causes particular scale diffusion and disagglomeration and faster mixing in a relatively small area of the entire mixing volume, i.e. the formation of a localized shearform matrix.
  • High shear mixing may also result in increased temperature at the point of impact of the shearing apparatus with the mix, thereby further contributing to the effective mixing action.
  • High shear mixing should be contrasted with "low shear mixing" in which the main action of mixing is due to the relative motion of a much larger volume of mix being circulated by the spinning or churning action of a lower impact type mechanism, such as a paddle-blade typically found in a Sigma or Hobart mixer.
  • a lower impact type mechanism such as a paddle-blade typically found in a Sigma or Hobart mixer.
  • the resultant product can be referred to as both uncooked (in the sense that excessive heat is not utilized) and unspun (in the sense that a flash-flow apparatus is not utilized).
  • the product is also in the form of shearform matrix.
  • any number of the components comprising the composition of the invention may be mixed together through the use of high or low shear mixing, as well as flash-flow processing, as well as any combination thereof.
  • the materials making up the hydrobinding component such as the cited gums, gelatin and glycerine can then be combined and hydrated, for example, using high or low shear mixing.
  • the final composition can then be formed by combining all the aforementioned components, again by utilizing either high or low shear mixing, preferably high shear mixing.
  • moisture is readily imbibed and disseminated throughout the non-hydrated components and/or ingredients.
  • additional moisture is not required to form a hydrated mixture.
  • excess water is not present in the resulting mass, and no cooking or heating is then required to drive off this excess moisture.
  • the saccharide-based component, optional ingredients, and any actives may be admixed using high shear.
  • the ingredients constituting the hydrobinding component may also be processed using high shear.
  • the final formulation can be achieved by then submitting all components to high shear mixing.
  • An especially preferred high-shear mixer for use with the invention is known as a Littleford FKM 1200.
  • This device provides high shear mixing by proximal shearing blades which are at right angles to one another.
  • the shearing blades consist of "plowers” and choppers, both of which are utilized for high shear mixing action. While not wishing to be bound by any particular theory, it is believed that high shear action provides both mixing and heating at the localized points of blade contact with the mix ingredients, thereby resulting in excellent dispersibility without the undesired effects of lumping etc.
  • Other high shear mixers (with one or more mixing blades), currently available or yet to be developed, are also contemplated by the method of the invention.
  • the high shear mixer can be further equipped with a jacket heater to provide the benefits of additional warming.
  • a preferred temperature range is from about 30 degrees C to about 60 degrees C, more desirably within the range of about 30 degrees to about 45 degrees C.
  • a preferred procedure for high shear mixing is as follows: The jacket heater on the high shear mixer is first activated and allowed to warm to a temperature of about 40 degrees C. Next, the saccharide-based component and other dry ingredients may be fed through the open hopper and allowed to mix using the plowers provided on the apparatus. For an 18 pound mixture, for example, the device is first run for about 2 minutes. Any added fat, along with emulsifiers, and the liquid-based hydrobinding component (which has been previously prepared using low shear mixing), together with any flavorings, sweeteners and coloring, are then fed into the mixer, and the choppers or high shear blades are activated to further complete the mixing.
  • the jacket temperature may be increased to within the range of about 50-60 degrees C, preferably about 58-60 degrees to assist in the mixing, especially if fat is present in the mixture.
  • the mixer is then run for about 5-10 minutes more, perhaps longer, to complete the mixing of the saccharide-based component and the hydrobinding component. Once mixing is complete, the entire matrix is then emptied into an appropriate container for slicing, sorting, packaging and shipping etc., e.g. is extruded and cut into dosage size pieces.
  • the use of low shear mixing apparatus can also provide the product of the invention.
  • a Sigma mixer and/or Hobart industrial paddle mixer may be suitable.
  • the dry ingredients saccharide-based component and any additional materials, including active ingredients
  • the liquid ingredients hydrobinding components along with any liquid-based active ingredients
  • the whole mixture is then run in the Sigma mixer for about 3 minutes. Variations of the foregoing process are certainly within the scope of the invention, depending upon the characteristics of the individual ingredients, and the attributes desired within the final product.
  • another method of formulating the product of the invention may comprise the utilization of both high- and low-shear mixing apparatus set forth above, depending upon the needs of the skilled artisan.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Inorganic Chemistry (AREA)
  • Microbiology (AREA)
  • Confectionery (AREA)

Abstract

La présente invention concerne une formulation de confiserie à mâcher contenant des nutriments, dont la préparation consiste à hydrater un mélange de composants comprenant un agent de rétention d'eau, un matériau à base de saccharide et une substance à action biologique possédant de faibles caractéristiques organoleptiques. La présente invention concerne aussi un procédé de fabrication d'une masse de confiserie, telle qu'un supplément à mâcher à base de caféine, au moyen d'une hydratation suffisante afin de former la masse sans être obligé de déshumidifier par cuisson.
PCT/US1999/017838 1998-09-08 1999-08-06 Confiserie a base de nougat a macher contenant de la cafeine WO2000013522A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU53937/99A AU5393799A (en) 1998-09-08 1999-08-06 Chewy nougat confectionery formulation with caffeine

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14959798A 1998-09-08 1998-09-08
US09/149,597 1998-09-08

Publications (1)

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WO2000013522A1 true WO2000013522A1 (fr) 2000-03-16

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Cited By (6)

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WO2002001962A2 (fr) * 2000-06-30 2002-01-10 Biovail Technologies Ltd. Perfectionnement apporte a un procede d'hydratation positive pour l'elaboration de confiserie, et produit ainsi obtenu
US6673380B2 (en) 1998-11-17 2004-01-06 Mcneil-Ppc, Inc. Fortified confectionery delivery systems and methods of preparation thereof
WO2004040992A1 (fr) * 2002-11-06 2004-05-21 Ssl International Plc Comestibles medicinaux
WO2007116429A1 (fr) * 2006-04-10 2007-10-18 Daniele Giovannone Compositions alimentaires, diététiques ou nutraceutiques à base de pâte ou de farine de noix et utilisation de celles-ci dans la production de dragées et similaires
US20170135368A1 (en) * 2014-06-30 2017-05-18 Roquette Freres Novel fat-free confectionery item
US10201498B2 (en) 2016-03-12 2019-02-12 Mybite Vitamins, Llc Shelf-stable foam-like confectionaries comprising erythritol and active ingredients

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EP0601965A2 (fr) * 1992-10-23 1994-06-15 Fuisz Technologies Ltd. Procédé de fabrication d'une "shearform" matrice
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EP0656426A2 (fr) * 1993-10-07 1995-06-07 Fuisz Technologies Ltd. Procédé de fabrication de sucre cristallisé et produits obtenues
US5429836A (en) * 1991-10-25 1995-07-04 Fuisz Technologies Ltd. Saccharide-based matrix
WO1996038049A1 (fr) * 1995-05-31 1996-12-05 Fuisz Technologies, Ltd. Procede de preparation de confiserie par hydratation positive et produit obtenu
US5633027A (en) * 1994-08-05 1997-05-27 Fuisz Technologies Ltd. Confectioneries containing stabilized highly odorous flavor component delivery systems

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Publication number Priority date Publication date Assignee Title
US4526525A (en) * 1983-04-08 1985-07-02 Meiji Seika Kaisha, Ltd. Fleecy confectionery producing machine
US5370881A (en) * 1987-04-20 1994-12-06 Fuisz Technologies Ltd. Water-soluble delivery systems for hydrophobic liquids
US5429836A (en) * 1991-10-25 1995-07-04 Fuisz Technologies Ltd. Saccharide-based matrix
WO1993008699A1 (fr) * 1991-11-04 1993-05-13 Fuisz Technologies Ltd. Systemes d'apport solubles dans l'eau pour liquides hydrophobes
EP0601965A2 (fr) * 1992-10-23 1994-06-15 Fuisz Technologies Ltd. Procédé de fabrication d'une "shearform" matrice
EP0656426A2 (fr) * 1993-10-07 1995-06-07 Fuisz Technologies Ltd. Procédé de fabrication de sucre cristallisé et produits obtenues
US5633027A (en) * 1994-08-05 1997-05-27 Fuisz Technologies Ltd. Confectioneries containing stabilized highly odorous flavor component delivery systems
US5744180A (en) * 1994-08-05 1998-04-28 Fuisz Technologies Ltd. Comestibles containing stabilized highly odorous flavor component delivery systems
WO1996038049A1 (fr) * 1995-05-31 1996-12-05 Fuisz Technologies, Ltd. Procede de preparation de confiserie par hydratation positive et produit obtenu

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6517886B1 (en) 1997-06-24 2003-02-11 Biovail Corporation International Positive hydration method of preparing confectionery and the resulting product
US7655264B2 (en) 1997-08-29 2010-02-02 Mcneil-Ppc, Inc. Process for promoting calcium absorption
US6673380B2 (en) 1998-11-17 2004-01-06 Mcneil-Ppc, Inc. Fortified confectionery delivery systems and methods of preparation thereof
WO2002001962A2 (fr) * 2000-06-30 2002-01-10 Biovail Technologies Ltd. Perfectionnement apporte a un procede d'hydratation positive pour l'elaboration de confiserie, et produit ainsi obtenu
WO2002001962A3 (fr) * 2000-06-30 2002-07-18 Biovail Tech Ltd Perfectionnement apporte a un procede d'hydratation positive pour l'elaboration de confiserie, et produit ainsi obtenu
WO2004040992A1 (fr) * 2002-11-06 2004-05-21 Ssl International Plc Comestibles medicinaux
WO2007116429A1 (fr) * 2006-04-10 2007-10-18 Daniele Giovannone Compositions alimentaires, diététiques ou nutraceutiques à base de pâte ou de farine de noix et utilisation de celles-ci dans la production de dragées et similaires
US20170135368A1 (en) * 2014-06-30 2017-05-18 Roquette Freres Novel fat-free confectionery item
US10201498B2 (en) 2016-03-12 2019-02-12 Mybite Vitamins, Llc Shelf-stable foam-like confectionaries comprising erythritol and active ingredients

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