WO2000000133A1 - Faecal collector with flexible skin attachment means - Google Patents
Faecal collector with flexible skin attachment means Download PDFInfo
- Publication number
- WO2000000133A1 WO2000000133A1 PCT/US1999/013001 US9913001W WO0000133A1 WO 2000000133 A1 WO2000000133 A1 WO 2000000133A1 US 9913001 W US9913001 W US 9913001W WO 0000133 A1 WO0000133 A1 WO 0000133A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wearer
- adhesive
- skin
- management device
- bag
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
- A61F13/49—Absorbent articles specially adapted to be worn around the waist, e.g. diapers
- A61F13/495—Absorbent articles specially adapted to be worn around the waist, e.g. diapers with faecal cavity
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/56—Supporting or fastening means
- A61F13/66—Garments, holders or supports not integral with absorbent pads
- A61F13/82—Garments, holders or supports not integral with absorbent pads with means for attaching to the body
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F5/00—Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
- A61F5/44—Devices worn by the patient for reception of urine, faeces, catamenial or other discharge; Portable urination aids; Colostomy devices
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F5/00—Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
- A61F5/44—Devices worn by the patient for reception of urine, faeces, catamenial or other discharge; Portable urination aids; Colostomy devices
- A61F5/451—Genital or anal receptacles
Definitions
- the present invention relates to human waste management devices such as urine management devices and faecal management devices for babies, children or adults to be attached directly to the skin between the buttocks of the wearer.
- the device utilises an optimised skin attachment means in order to securely attach the device to the skin of the wearer such that the device is maintained in position for the entire period of wear, including circumstances or periods of wear during which the wearer is active, i.e. not bedridden.
- the skin attachment device of the present invention has a specific flexibility such that it can readily adapt to changes in the contour of the skin due to bodily movements, by stretching and contracting with the skin to which it is attached, as required.
- Urine and faecal management devices are known articles of manufacture that are designed to be worn principally by incontinence sufferers and in particular by bedridden patients. Such human waste management devices are attached to the natural anal region or artificial anus and or uro genital area of the wearer and are intended to entrap and immediately contain faecal material and other bodily discharges. Such devices as they are mostly known today are designed to be worn by bedridden patients. As such the devices are constituted of a relatively long and narrow tube, at one extremity of which there is an aperture surrounded by a flange upon which an adhesive can be applied in order to attach the device to the wearer. The flanges are typically comprised of flexible material which-can stretch and contract so that the aperture size can be increased for example upon defecation. The materials typically utilised are closed cell foams.
- Such flanges are disclosed for example in US 3,577,989, which details a disposable elimination-trapping bag for incontinence sufferers including a container member having an open-top portion, and an expandable flange secured to the container member around the open-top portion.
- the flange may include a layer of adhesive on its surface as a means of attachment of the bag to the wearer or alternatively discloses the use of elastic straps to attach the bag to the wearer.
- US 4,784,656 also describes a receptacle for collecting faecal matter from incontinence sufferers.
- the faecal collector comprises a gasket, a conduit means or a cylinder and a receptacle; the gasket is made of soft pliable stretchable material such as a closed cell foam and the side surface of the gasket is coated with a layer of adhesive;
- GB 2 152 387 teaches a faecal collector for incontinence sufferers comprising a collection bag and a ring, which is provided with an adhesive.
- the ring can extend and contract and is a closed cell thermoplastic foam.
- the likelihood that the faecal material once excreted and contained within the bag will be caused to exert pressure upon the attachment means of the device will increase and as a result not only will the storage capacity of the device be detrimentally affected, but also more importantly, it may result in unintentional detachment of the device from the wearer during use. Such an occurrence is unacceptable causing distressing consequences for both the wearer and the carer.
- the urine and/or faecai management devices are designed such that they are securely attached to the skin of the wearer and do not become unintentionally unattached during all circumstances of use.
- the prior art typically discloses the utilisation of certain adhesives having very high cohesive strengths such as rubber based adhesives, acrylics and hydrocolloid adhesives as for example described in EP 245 064. These adhesives are then applied as thick layers over the entire surface of the flange of the device to maximise the adhesive force by which the device is secured to the skin of the wearer.
- adhesives having very high cohesive strengths such as rubber based adhesives, acrylics and hydrocolloid adhesives as for example described in EP 245 064.
- These adhesives are then applied as thick layers over the entire surface of the flange of the device to maximise the adhesive force by which the device is secured to the skin of the wearer.
- it is also important to achieve a gasket between the adhesive and the skin, such that none of the excreted matter whether during the defaecation process or once stored in the bag, can escape from the confines of the bag in-between sections of the adhesive and skin which have not formed a gasket.
- these skin attachment devices in particular raise a number of problems related to the comfort of the wearer of such faecal management devices.
- the skin attachment means are satisfactory in terms of adhesion to the skin of the wearer, on the other hand they do not allow for easy removal of the device from the wearer, without the wearer experiencing unacceptable pain levels.
- providing a painless adhesive is essential in order to allow for the application of such devices on sensitive skin and wearer groups such as infants.
- the current skin attachment means utilise adhesives that cause the wearer of such devices discomfort, especially for active wearers.
- the wearer of the device disregards the pain associated with a particular movement, due to the presence of the adhesive or cannot prevent a particular movement such the defaecation process itself, and continues a movement whereby for example the skin is stretched, the device may eventually, if the force of this movement is sufficient, become detached from the wearer.
- the skin attached to such an adhesive is not able to naturally contract but will buckle on the adhesive, thereby destroying the gasket. Consequently the adhesion of the device to the skin is reduced and the device may again ultimately become detached.
- the flange material itself may be provided from a compliant and flexible material, which may be able to some extent adapt to the contours of the skin, the wearer of such a device will not recognise this benefit, as it is entirely lost on application of the above mentioned adhesives onto the surface of the flange. Consequently, the combination of the flange and the adhesive results in stiff, non flexible devices.
- the adhesives are formed from cross linked organic polymers of polyvinyipyrolidine with plasticizers and find application in a number of articles such as bandages and wound dressing as well as ostomy devices.
- the adhesive can be provided with a number of properties so that it can be utilised as a self supporting layer without the need of additional layers or in combination with non supporting web like substrates such as gauze or non wovens.
- the adhesives as described therein exhibit minimal resilience and are malleable such that they will not resist any pressure applied to them but yield to it. In applications such as faecal management devices however the amount of pressure exerted on the device during use and particularly during the defaecation process itself is very high and hence such self supporting layers would not be suitable.
- a skin attachment device for use in human waste management devices comprising a flange and a surface coating of a suitable adhesive wherein the attachment device meets a certain parameters as defined herein after.
- a skin attachment means selected so as to provide a specified degree of flexibility, stretchability and contractability will ensure that the means provides sufficient flexibility so it is able to adapt to the contours of the body during all bodily movements and hence be comfortable for the wearer of the device, whilst still having sufficient adhesive capacity to ensure secure attachment during use.
- the human waste management devices in particular the faecal management device with its specific skin attachment device can be advantageously used in combination with a reusable underwear garment or preferably with a disposable diaper.
- Figure 1 is a perspective view of a faecal management device according to the present invention.
- Figure 2 shows a perspective view of the faecai management device of the present invention in conjunction with a disposable diaper
- Figure 3 is a partially cut-away perspective view of a disposable diaper embodying the present invention.
- Figure 4 is a plan view of a disposable human waste management device of the present invention.
- the present invention hence relates to human waste management devices such as a urine management device and a faecai management device (10) comprising a bag (11), said bag (11) having an aperture and a skin attachment means surrounding said aperture (21) said skin attachment means comprising a flange (12) having a wearer facing surface (23) and a garment facing surface (22), and wherein said wearer facing surface (23) of said flange (12) comprises an adhesive (20) characterised in that said skin attachment means has a flexibility as defined herein of less than 0.055N, preferably less than 0.03N, most preferably less than 0.004N.
- said skin attachment device also has a tensile strength at 50% elongation as defined herein of less than 25N, preferably less than 10N.
- the human waste management device is used in combination with a disposable diaper.
- the present invention hence relates to a human waste management device such as a urine management or a faecal management device (10) comprising a bag (11), said bag (11) having an aperture and a skin attachment means surrounding said aperture (21).
- the skin attachment means comprises a flange (12) having a wearer facing surface (23) and a garment facing surface (22), and wherein said wearer facing surface of said flange comprises an adhesive (20).
- the bag (11) is provided with an aperture (21) whereby excreted matter is received from the body pnor to storage within the bag cavity.
- the aperture (21) is surrounded a skin attachment means.
- the skin attachment means comprises a flange (12) which has a garment facing portion (22) and a wearer facing portion (23). In an preferred embodiment these are two large, substantially flat surfaces, however, the flange may also comprise projections (28, 29) designed to fit the perineal or coccygeal area of the wearer.
- the skin attachment means which are compliant with the skin and ensure secure attachment and painless removal of the device to the skin can be provided by selecting the skin attachment means materials such that the means meet a key identified criteria defined by the flexibility parameter as defined hereinafter.
- the skin attachment means not only provide secure attachment, a gasket between the adhesive and the skin and painless application and removal from the skin, but also that the means allow the skin bound to the adhesive to move unhindered. It is believed that in this manner the wearer of the device can undertake normal activities without experiencing any pain and without the risk that the device will become detached.
- the skin attachment means comprising the flange (12) and adhesive (20) exhibit sufficient flexibility to enable the means to be applied to the skin at the peria ⁇ ai area and adapt to the contours of the body, particularly at the coccyx, and form a gasket.
- the sin attachment means having a flexibility as defined by the test method hereinafter of less than 0.055N, preferably less than 0.03N, most preferably less than 0.004N provide such a benefit.
- the skin .attachment means is selected such that it allows the skin to stretch as required by certain bodily movements or functions such as defaecation without the wearer experiencing any pain but again still ensuring secure attachment and the retention of a gasket.
- the ability of the means to stretch with the skin can be quantified by the tensile strength of the sin attachment means as detailed in the test method hereinafter.
- said skin attachment means also has a tensile strength at 50% elongation as defined herein of less than 25N, preferably less than 10N.
- the ability of the skin attachment means to flex and stretch is dependent upon the combination of the properties of the flange material and in particular the viscous modulus (G ) of the adhesive.
- the skin attachment means should also exhibit compressibility.
- the skin bonded to the adhesive should be able to contract once the wearer resumes a relaxed position without the wearer experiencing any pain and whilst preventing the skin from buckiing and forming channels through the gasket.
- the flange (12) should be made of soft, flexible and malleable material to allow easy placement of the flange to the perianal area. Any materials which meet the flexibility requirements may be usefully employed herein Typical materials include nonwoven materials, wovens, open celled thermoplastic foams, composites of open celled foams and stretch nonwoven, and films and any combination thereof. Preferably, such foams have a thickness within the general range of 0.1 to 5 millimetres and a basis weight of 5 to 250 g/m 2 , more preferably 50 g/m 2 .
- thermoplastic foam materials or other suitable plastics sheet materials having the described properties of such foams (i.e., softness, pliability, stretchability, and contractability) might also be used.
- the flange comprises an open celled foam, a nonwoven or a combination thereof.
- the material of garment facing surface (23) of the flange (12) may extend into the defined aperture area so as to form a skirt or flap of material which prevents unintentional adhesion of the surface edges of the flange defining the aperture to oneanother during use.
- the flange (12) is attached to the bag (11) according to any means known to the man skilled in the art which may provide permanent or releasable attachment.
- the flange is attached to the bag by adhesive.
- the bag will be attached to the flange, towards the outer periphery of flange so as not to cause any obstruction for the ente ⁇ ng faecal matter.
- the flange may be provided in any size depending on the wearer group for which the device is intended. Similarly the flange may be provided in any shape and preferably has a symmetrical shape preferably comprising a plurality of lobes (13). Similarly, the aperture provided by the flange may be provided in any shape or size, such as circular, oblong, heart shaped and may be symmetrical or asymmetrical, preferably the aperture has an oblong configuration either in the longitudinal or in the transversal direction, most preferably the contours of the aperture are in the shape of two ellipses with the respective main axes being substantially perpendicular.
- the skin attachment means further comprises an adhesive applied to the wearer facing surface (23) of the flange (12) to secure the device to the wearer.
- the adhesive (20) is preferably covered with a release means (not shown) in order to protect the adhesive layer, such as siliconized paper.
- the adhesive (20) can cover the entire wearer facing surface of the flange or more preferably have at least one, preferably two to six non- adhesive portions. These portions may be adhesive free or may contain inactivated or covered adhesives.
- the adhesive is in one preferred embodiment not applied to the entire wearer facing surface area of the flange (12), so as to provide lobes (13) on either side of the flange (12) which are non-adhesive and can thereby serve to facilitate placement and removal of the device whilst avoiding contact with the adhesive.
- These lobes are however preferably also covered by the release paper.
- any suitable medically approved adhesive which meet the flexibility criteria can be usefully employed herein.
- an adhesive which is a medically approved water resistant pressure sensitive adhesive comprising a polymer which forms a 3-dimensional matrix, and comprising less than 10%, preferably less than 5% by weight of said adhesive of hydrocolloids may be used to attach the device to the perianal area of the wearer.
- hydrocolloid refers to colloidal absorbent materials and mixtures of colloidal absorbent materials selected from starch, modified starches such as dextrin, cellulose ester such as carboxymethycellulose, natural gums such as pectin karaya, gelatin, guar gum, gum arabic, locust bean gum, and carboxypolymethylene.
- the 3-dimensional matrix also referred to herein as a gel, comprises as an essential component a polymer which can be physically or chemically cross linked.
- the polymer may be naturally or synthetically derived.
- the uncrosslinked polymer includes repeating units derived from vinyl alcohols, vinyl ethers and their copolymers, carboxy vinyl monomer, vinyl ester monomers, esters of carboxy vinyl monomers, vinyl amide monomers, hydroxy vinyl monomers, cationic vinyl monomers containing amines or quaternary groups, N-vinyl lactam monomer, polyethylene oxides, polyvinylpyrrolidon (PVP), acrylics such as hydroxyethylmethacrylate, methoxydiethoxyethyl methacrylate and hydroxydiethoxyethyl methacrylate and sulphonated polymers such as acrylamide sulphonated polymers and mixtures thereof.
- PVP polyvinylpyrrolidon
- the uncrosslinked polymer may be a homopolymer or copolymer of a polyvinyl ether, or a copolymer derived from half ester of maleic ester.
- any other compatible polymer monomer units may be used as copolymers such as for example polyvinyl alcohol and polyacrylic acid or ethylene and vinyl acetate.
- the polymers may be block copolymer thermoplastic elastomers such as ABA block copolymers such as styrene-olefin-styrene block copolymers or ethylene-propylene block copolymers. More preferably such polymers include hydrogenated grade Styrol/Ethylene-Butylene/Styrol (SEBS), Styrene/isoprene/Styrene (SIS), and Styrol/Ethylene-Propylene/Styrol (SEPS).
- SEBS Styrol/Ethylene-Butylene/Styrol
- SIS Styrene/isoprene/Styrene
- SEPS Styrol/Ethylene-Propylene/Styrol
- Particularly preferred polymers are acrylics, sulphonated polymers such as acrylamide sulphonated polymers, vinyl alcohols, vinyl pyrrolidine, polyethylene oxide and mixtures thereof.
- the 3 dimensional adhesive matrix also essentially comprises a plasticiser, which is preferably a liquid at room temperature.
- a plasticiser which is preferably a liquid at room temperature.
- This material is selected such that the polymer may be solubilized or dispersed within the plasticiser.
- the plasticiser must also be irradiation cross linking compatible such that it does not inhibit the irradiation cross linking process of the polymer.
- the plasticiser may be hydrophilic or hydrophobic.
- Suitable plasticisers include water, alcohols, polyhydric alcohols such as glycerol and sorbitol, and glycols and ether glycols such as mono- or diethers of polyalkylene glycol, mono- or diester polyalkylene glycols, polyethylene glycols (typically up to a molecular weight of about 600), glycolates, glyceril, sorbitan esters, esters of citric and tartaric acid, imidazoiine derived amphoteric surfactants, lactams, amides, polyamides, quaternary ammonium compounds, condensation products of polyethylene imine and epichlorohydrin, liquid polybutenes, esters such phthalates, adipates, stearates, palmitates, sebacates, or myristates, natural or synthetic oils such as vegetable oils, mineral oils, and combinations thereof. Particularly preferred are polyhydric alcohols, polyethylene glycol (with a molecular weight up to about 600), gly
- the adhesive comprises a ratio of polymer to plasticiser by weight of from 1 :100 to 100:1, more preferably from 50:1 to 1:50.
- the exact amounts and ratios of the polymer and plasticiser will depend to a large extent on the exact nature of polymer and plasticisers utilised and can be readily selected by the skilled person in the art. For example a high molecular weight polymer material will require a greater amount of plasticiser than a low molecular weight polymer.
- the adhesive may comprise a number of optional additional components for example the composition may comprise from 0% to 50% by weight of the composition, of a tackifying resin.
- tackifying resins are particularly useful in combination with ABA block copolymer adhesive compositions.
- Suitable tackifying resins include for example rosin derivatives, terpene, and terpene-phenolic resins, hydrocarbon resins such as C 5 and C 5 /C 9 resins, aromatic resins and hydrogenated resins.
- suitable optional ingredients include from 0% to 10% and more preferably form 0% to 5% by weight of substances for further facilitating and stabilising the 3-dimensional matrix and the matrix forming process.
- these may be fatty acids of Cs to C22. their metallic salts and their polyoxo-derivatives; lanolin derivatives; silica; bentonite, montmorillonite and their derivatives; waxes or mixtures thereof.
- additives known in the art such as preservatives, antioxidants, anti UV agents, pigments, mineral fillers and mixtures thereof may also be comprised within the adhesive composition in quantities up to 10% each respectively.
- the polymer component of the adhesive can be physically or chemically cross linked in order to form the 3-dimensional matrix.
- Physical cross linking refers to polymers having cross links which are not chemical covalent bonds but are of a physical nature such that there are areas in the 3 dimensional matrix having high crystallinity or areas having a high glass transition temperature.
- Chemical cross linking refers to polymers which are linked by chemical bonds.
- the polymer is chemically cross linked by radiation techniques such as thermal-, E beam- , UV-, gamma or micro-wave radiation.
- a free radical initiator may be present in the premix to initiate the irradiation.
- Such an initiator can be present preferably in quantities up to 5% by weight.
- the resulting adhesive compositions may be divided into three family types; hydrophilic, hydrophobic and mixed phase compositions dependant upon the nature of the components of the adhesive.
- Hydrophilic adhesives are compositions in which typically the plasticiser is water or glycerol or glycol and/or mixtures thereof and the polymeric phase is of synthetic (e.g. polyacrylics).
- such compositions may comprise up to 10% by weight of colloid natural gums.
- Hydrophobic adhesives are compositions in which the plasticiser is typically an oil or blend of oils of vegetable or mineral origin and the polymer is usually a synthetic polymer, preferably an elastomer, which is soluble or dispersible in such oils.
- Mixed phase adhesives are compositions in which both hydrophobic and hydrophilic components, possibly in both plasticisers and polymers, form two or more separate phases.
- an emulsifier/surfactant is preferably present at a suitable level to form stable emulsions between the incompatible phases.
- the preferred adhesive compositions for use in the present invention are hydrophilic.
- Suitable adhesives for use herein include Promeon, available from Promeon Division of Medtronic Inc., Minneapolis Minnesota, USA and hydrogel adhesive available from 3M.
- the adhesive (20) can be applied to the wearer facing surface of the flange (12) by any means known in the art such as slot coating, spiral, or bead application or printing.
- the adhesive is applied at a basis weight of from 20g/m 2 to 2500g/m 2 , more preferably from 500g/m 2 to 2000g/m 2 most preferably from 700g/m 2 to 1500g/m 2 depending on the end use envisioned.
- the bag (11) as used herein is a flexible receptacle for the containment of excreted faecal matter.
- the bag (11) can be provided in any shape or size depending on the intended use thereof, i.e. whether the device is intended for bedridden patients or active patients suffering from incontinence or requiring an artificial bowel or for infants.
- elongated bags which are principally tubular or rectangular are typically utilised by bedridden patients and elderly incontinence sufferers.
- the faecal management device should preferably be anatomically shaped such that the device follows the contours of the body and can be worn inconspicuously by the wearer under normal garments.
- the bag (11) has a substantially truncated cone shape.
- a preferred shape for urine management devices is shown in figure 4.
- the bags will have a wearer facing portion (16) and a garment facing portion (17).
- the wearer facing portion (16) of the human waste management device (10) is disposed adjacent the buttocks of the wearer. As such, the wearer facing portion (16) amply covers the buttocks of the wearer and does not hang between the thighs of the wearer.
- the bag (11) is preferably shaped to allow at least partial insertion and retention of the bag in-between the buttocks of the wearer and thereby ensure good contact between the flange and the skin of the wearer.
- the human waste management bag may be provided with a neck portion or conduit.
- the bag (11) is preferably designed to provide sufficient volume for excreted material under a variety of wearing conditions, also when worn by a freely moving, i.e. not bedridden wearer. Sitting on the bag, for example, will result in a largely reduced volume in some areas of the bag.
- the bag is preferably shaped to provide sufficient volume in areas which are not subjected to much pressure in wearing conditions such as sitting.
- the bag (11) is designed to safely contain any entrapped material, typically it will be liquid impermeable, yet it may be breathable.
- the bag is designed of sufficient strength to withstand rupture in use, also when pressure on the bag is exerted in typical wearing conditions, such as sitting.
- the bag (11) may be provided from a unitary piece of material or from a number of separate pieces of material, which may be identical or different and which are sealed at their respective peripheries.
- the bags herein have a wearer facing portion (16) and a garment facing portion (17) which comprise separate pieces of material.
- the wearer facing portion (16) and the garment facing portion (17) are sealed at the periphery of the bag (11), thus creating a bag peripheral rim (18).
- the wearer facing portion (16) of the bag (11) may comprise two further sections (19), which are secured to each other by means known to the man skilled in the art, such as adhesive, thermobonding or pressure bonding in order to provide the desired bag configuration.
- the bag (11) can comprise one or multiple layers, preferably two or three layers.
- the layer on the inside of the bag, which will typically at least partially come in contact with excreted material is called the inner layer.
- the layers of the bag material may be provided from any material, preferably so that the bag is liquid impervious.
- the layers may in particular comprise any material such as non-wovens or films.
- a laminate may be formed from a non-woven layer and a film. The laminate can be formed by means known to the man skilled in the art.
- Any non-woven layer can comprise felt fabrics, spunlaced fabrics, fluid jet entangled fabrics, air-laid fabrics, wet-laid fabrics, dry-laid fabrics, melt-blown fabrics, staple fibre carding fabrics, spunbonded fabrics, stitch-bonded fabrics, apertured fabrics, combinations of the above or the like.
- Suitable film materials for any of said layers preferably comprise a thermoplastic material.
- the thermoplastic material can be selected from among all types of hot-melt adhesives, polyolefins especially polyethylene, polypropylene, amorphous polyolefins, and the like; material containing meltable components comprising fibres or polymeric binders including natural fibres such as cellulose - wood pulp, cotton, jute, hemp; synthetic fibres such as fibreglass, rayon, polyester, polyolefin, acrylic, polyamid, aramid, polytetrafluroethylene metal, polyimide: binders such as bicomponent high melt/low melt polymer, copolymer polyester, polyvinyl chloride, polyvinyl acetate/chloride copolymer, copolymer poiyamide, materials comprising blends wherein some of the constituent materials are not meltable; air and vapour permeable materials including microporous films such as those supplied by EXXON Chemical Co., Ill, US under the designation EXXAIRE or those supplied by Mitsui Toatsu Co., Japan under the
- a film which is comprised in any layer, is preferably permeable to gases such as air and to vapour such as water vapour in order to avoid the problem of entrapment and condensation of moisture vapour given off by the body of the wearer and thus, the hot, clammy and uncomfortable conditions after a short period of use.
- the outer layer of the bag is preferably provided with a non-woven layer.
- Such material layers present an uneven surface to the skin of the wearer and thus reduce significantly the problem of occlusion and greatly improve skin healthiness.
- the bag comprises two layers.
- the outer layer comprises a non-woven layer and the inner layer comprises a film.
- the bag (11) comprises three layers, preferably one film and two non-woven layers.
- the film is interposed between the two non-woven layers. This sequence of layers results in a closed fibrous structure, which has a particularly pleasing sensation on contact with the skin of the wearer.
- the inner layer comprises a film and the other two layers comprise non-wovens.
- the non-woven layer or the non-woven layers comprised by the bag (11) may be hydrophobic or hydrophilic. If the bag (11) does not comprise a film layer, preferably at least one non-woven layer is hydrophobic. As a consequence, fluid penetration is resisted through the wearer facing portion (16) and the garment facing portion (17) of the human waste management device (10). If the bag comprises a film or a hydrophobic non-woven layer, further non-woven layers may be hydrophilic.
- the non-woven layer is treated with a surface active material, such as a fluorchemical or other hydrophobic finishings, to provide the requisite hydrophobicity.
- a surface active material such as a fluorchemical or other hydrophobic finishings
- the non-woven layer may equally be treated with coatings of liquid impervious materials such as hot-melt adhesives or coatings of silicone or other hydrophobic compounds such as rubbers and vegetable and mineral waxes or it may be physically treated using nano-particulates or plasma coating techniques, for example.
- the non-woven layer can also be treated with agents to improve the tactile perceivable softness of the wearer facing portion (16) and the garment facing portion (17).
- the agents include but are not limited to vegetable, animal or synthetic oils, siiicone oils and the like. The presence of these agents are known to impart a silky or flannel-like feel to the non-woven layer without rendering it greasy or oily to the tactile sense of the wearer.
- surfactant material including anionic, non-ionic, cationic and amphoteric surfactants, may be added to further enhance softness and surface smoothness.
- the non-woven layer may be impregnated with a lotion to provide desirable therapeutic or protective coating lotion benefits.
- the lotion coating on the wearer facing portion (16) and the garment facing portion (17) is transferable to the skin of the wearer by normal contact and wearer motion and/or body heat.
- mineral oil in the form of a lotion is recognised as being effective in imparting a soothing, protective coating to the skin of the wearer.
- the bag may contain absorbent material.
- the absorbent material may comprise any absorbent material which is capable of absorbing and retaining liquids.
- the absorbent material may comprise a wide variety of liquid-absorbent materials commonly used in disposable diapers and other absorbent articles such as comminuted wood pulp, which is generally referred to as airfelt.
- suitable absorbent materials include creped cellulose wadding; meltblown polymers, including coform; chemically stiffened, modified or cross-linked cellulosic fibers; tissue, including tissue wraps and tissue laminates; absorbent foams; absorbent sponges; superabsorbent polymers; absorbent gelling materials; or any other known absorbent material or combinations of materials.
- the absorbent material may be positioned in the bag (11) in any suitable manner.
- the absorbent material may be loosely arranged within the bag or may be secured to the inner layer of the bag (11). Any known techniques for securing absorbent material to nonwoven and film substrates may be used to secure the absorbent material to the inner layer of the bag.
- the absorbent material may also be arranged to have any desired shape or configuration (e.g., rectangular, oval, circular, etc.).
- the outer surface of bag (11) is provided with patches of adhesive (40) for securing the bag (11) to the body of the wearer.
- the patches of adhesive (40) are positioned on the outer surface of bag (11) such that they are secured to the abdomen of the wearer in use. Any number, size and shape of adhesive patches (40) may be used depending on the intended use of the device.
- the human waste management device in particular urine management devices according to the present invention also preferably comprise an additional acquisition layer.
- the acquisition layer is typically secured to the inner surface of bag. However, the acquisition layer may also be secured to the flange, or both the flange and the inner surface of bag.
- the acquisition layer is preferably positioned such that it separates the genitalia of the wearer from coming into direct contact with the absorbent material.
- the acquisition layer is fluid pervious allowing urine to readily pass through so that it may be absorbed by absorbent material.
- the acquisition layer may be manufactured from a wide range of materials, such as porous foams; reticulated foams; apertured plastic films; or woven or nonwoven webs of natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polyester or polypropylene fibers), or a combination of natural and synthetic fibers. If the acquisition, barrier layer includes fibers, the fibers may be spunbond, carded, wet-laid, meltblown, hydroentangled, or otherwise processed as is known in the art.
- the acquisition layer is designed to have a pore size such that the absorbent material is not allowed to pass through and contact the wearer's skin.
- the acquisition layer preferably has a pore size which is greater than the pore size of the absorbent material.
- the acquisition layer is less hydrophilic than the absorbent material.
- the acquisition layer may be treated with a surfactant to increase its initial wettability. When treated with surfactant, however, the acquisition layer should still be less hydrophilic than the absorbent material. Suitable methods for treating the acquisition layer with a surfactant include spraying the acquisition layer with the surfactant and immersing the material into the surfactant. Alternatively, a surfactant may be incorporated into the acquisition layer.
- the disposable human waste management devices (10) of the present invention have been found to be particularly useful and beneficial when used in conjunction with a garment, or diaper (50), preferably a disposable diaper - refer to Figure 2.
- the human waste management device (10) is preferably first positioned in the perianal area of the wearer before the disposable diaper (50) is applied.
- the diaper (50) is positioned over the human waste management device (10) and fastened in a conventional manner around the body of the wearer. It has been found that, in addition, to providing excellent separation between urine and faecal material, the combined human waste management device (10) and diaper (50) system actually reduces skin irritation, which may at times occur, especially since the group of typical wearers includes the very old, the very young and the unhealthy wearers.
- the presence of the faecal management device (10) permits the formation of a separation layer between the skin of the wearer and the diaper (50), i.e. a part of the absorbent core (58) of the diaper (10).
- the diaper (50) can be of the conventional type (an embodiment of which is described below although not a limiting example by any means) or can be adapted to contain in an effective and comfortable manner the human waste management device (10) according to the teachings of the present invention.
- the term "disposable diapers” refers to articles which absorb and contain body extrudates; and more specifically, refers to articles which are placed against or in proximity to the body of the wearer to absorb and contain the various extrudates discharged from the body and which are intended to be discarded after a single use (i.e., they are not intended to be laundered or otherwise restored or reused) and, preferably, to be recycled, composted or otherwise disposed of in an environmentally compatible manner.
- the term “diaper” refers to a garment generally worn by infants or incontinence sufferers that is drawn up between the legs and fastened about the waist of the wearer.
- FIG 3 is a partially cut-away perspective view of a diaper (50) embodying the present invention prior to it being placed on the wearer over the faecal management device (10).
- a preferred diaper (50) comprises a body portion (52) and a refastenable mechanical fastening device (54).
- a preferred body portion (52) comprises a liquid pervious topsheet (56), and absorbent core (58), a liquid impervious backsheet (60), and eiasticaily contractible leg cuffs (62); each leg cuff (62) preferably comprising a side flap (64) and one or more elastic members (66). For simplicity purposes, only one elastic member (66) is shown in the side flap (64).
- topsheet (56), the absorbent core (58), the backsheet (60), the side flaps (64), and the elastic members (66) may be assembled in a variety of well-known configurations.
- a preferred disposable diaper configuration is shown and generally described in US 3,860,003, an even more preferred disposable diaper configuration is shown and generally described in WO 93/16669.
- the backsheet (60) is joined to the topsheet (56); the absorbent core (58) is positioned between the topsheet (56) and the backsheet (60); the side flaps (64) extend outwardly from and along each side edge of the absorbent core (58); and the elastic member (66) is operatively associated with each side flap (64).
- Figure 3 shows the body portion (52) in which the topsheet (56) and the backsheet (60) are coextensive and have length and width dimensions generally larger than those of the absorbent core (58).
- the topsheet (56) is superposed on the backsheet (60) thereby forming the periphery (68) of the body portion (52).
- the body portion (52) has an inside surface (74) and an outside surface (76). When a backsheet (60) is used, it typically forms the outside surface (76) of the body portion (52).
- the inside surface (74) is that surface of the diaper (50) opposite the outside surface (76) and in the embodiment shown is typically formed by the topsheet (56).
- the inside surface (74) of the diaper (50) is that surface coextensive with the outside surface (76) and which is for the greater part in contact with the wearer when the diaper (50) is worn.
- the absorbent core (58) of the body portion (52) may be any absorbent means which is generally compressible, conformable, non-irritating to the skin of the wearer, and capable of absorbing and retaining liquids such as urine and other certain bodily discharges.
- the absorbent core (58) may be manufactured in a variety of sizes and shapes (for example, rectangular, hour-glass, "T-shaped, asymmetric, etc.) and from a wide variety of liquid absorbent materials commonly used in disposable diapers and other absorbent articles such as comminuted wood pulp which is generally referred to as airfelt.
- absorbent materials examples include creped cellulose wadding, meltblown polymers including coform, crosslinked cellulosic fibers, tissue including tissue wraps, absorbent foams, absorbent sponges, superabsorbent polymers, absorbent gelling materials, or any equivalent materials or combinations of materials.
- the configuration and construction of the absorbent core (58) may also be varied (for example, the absorbent core (58) may have varying caliper zones, hydrophilic gradients, superabsorbent gradients, or lower average density and lower average basis weight acquisition zones; or may comprise one or more layers or structures). Further, the size and absorbent capacity of the absorbent core (58) may be varied to accommodate wearers ranging from infants to adults.
- the backsheet (60) is impervious to liquids (for example, urine) and is preferably manufactured from a thin plastic film, preferably a thermoplastic film, although other flexible liquid impervious materials may also be used.
- the term "flexible” refers to materials which are compliant and which will readily conform to the general shape and contours of the human body.
- the backsheet (60) prevents the exudates absorbed and contained in the absorbent core (58) from soiling articles which are in contact with the diaper (50) such as undergarments and bedding.
- the backsheet (60) may thus comprise polymeric films such as thermoplastic films of polyethylene or polypropylene, or composite materials such as film-coated non-woven material. Exemplary films are manufactured by Tredegar Industries, Inc. of Terre Haute, Ind., USA or BP- Chemical PlasTec, Rotbuchenstrasse 1 , D-8000 M ⁇ nchen, Germany.
- the backsheet (60) is preferably textured to provide a more clothlike appearance. Further, the backsheet (60) may also permit vapours to escape from the absorbent core (58) while still preventing exudates from passing through the backsheet (60) by, for example, being supplied with microapertures.
- the size of the backsheet (60) is dictated by the size of the absorbent core (58) and the exact diaper design selected.
- the topsheet (56) of the diaper is compliant, soft feeling and non-irritating to the skin of the wearer. Further, the topsheet (56) is liquid pervious permitting liquids (for example, urine) to readily penetrate through its thickness.
- a suitable topsheet (56) may be manufactured from a wide range of materials, such as porous foams, reticulated foams, apertured films; or woven or non-woven webs of natural fibres (for example, wood or cotton fibres) or from a combination of natural and synthetic fibres. Preferably, it is made of a material that isolates the skin of the wearer from liquids retained in the absorbent core (58).
- the topsheet (56) may be a non- woven web of fibres.
- An exemplary topsheet (56) is carded and thermally bonded by means well-known to those skilled in the fabric art.
- a suitable topsheet (56) is manufactured by, for example, Veratec Inc., a division of International Paper Company, of Walpole, Mass., USA.
- a topsheet (56) particularly preferred for incontinence garments comprises a formed thermoplastic film.
- test method is utilized to determine the flexibility or stiffness of samples of the skin attachment means when the sample is compressed in the MD.
- test method measures the average force required to compress/fold the sample in MD at a force range of 0.001 to 0.3 Newtons.
- Test samples are prepared by cutting using scissors 3 samples of dimensions (6x2 cm in the MDxCD direction).
- test sample needs to bend during the test so as a form a C like fold in the centre of the sample. Tests in which the sample does not fold in this manner but adopt other configurations such as S-like folds are to be ignored and the test repeated.
- the following test method is utilized to determine the elongation of samples of the skin attachment means when the sample is stretched in the MD.
- test method measures the average force required to stretch the sample by 50%, 100% and to break the sample.
- Test samples are prepared by cutting using scissors 3 samples of dimensions (6x2.54 cm). 2. If present release paper is removed from the samples.
- Test operation 1. Tensile tester setting
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- Health & Medical Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Nursing (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- External Artificial Organs (AREA)
- Materials For Medical Uses (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU45572/99A AU755748B2 (en) | 1998-06-26 | 1999-06-11 | Faecal collector with flexible skin attachment means |
JP2000556719A JP2002528145A (en) | 1998-06-26 | 1999-06-11 | Fecal collection and attachment with flexible skin attachment means |
DE69906735T DE69906735T2 (en) | 1998-06-26 | 1999-06-11 | FECAL STORAGE CONTAINER WITH A FLEXIBLE LASH FOR FASTENING TO THE SKIN |
EP99928522A EP1089694B1 (en) | 1998-06-26 | 1999-06-11 | Faecal collector with flexible skin attachment means |
CA002335367A CA2335367C (en) | 1998-06-26 | 1999-06-11 | Faecal collector with flexible skin attachment means |
BR9912220-0A BR9912220A (en) | 1998-06-26 | 1999-06-11 | Fecal collector with flexible device for fixation on the skin |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
USPCT/US98/13286 | 1998-06-26 | ||
PCT/US1998/013286 WO2000000122A1 (en) | 1998-06-26 | 1998-06-26 | Faecal collector with flexible skin attachment means |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000000133A1 true WO2000000133A1 (en) | 2000-01-06 |
Family
ID=22267372
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/013286 WO2000000122A1 (en) | 1998-06-26 | 1998-06-26 | Faecal collector with flexible skin attachment means |
PCT/US1999/013001 WO2000000133A1 (en) | 1998-06-26 | 1999-06-11 | Faecal collector with flexible skin attachment means |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/013286 WO2000000122A1 (en) | 1998-06-26 | 1998-06-26 | Faecal collector with flexible skin attachment means |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1089694B1 (en) |
JP (1) | JP2002528145A (en) |
KR (1) | KR100455238B1 (en) |
CN (2) | CN1145461C (en) |
AU (2) | AU8266998A (en) |
BR (1) | BR9912220A (en) |
CA (1) | CA2335367C (en) |
DE (1) | DE69906735T2 (en) |
ES (1) | ES2192387T3 (en) |
PE (1) | PE20000647A1 (en) |
TW (1) | TW529933B (en) |
WO (2) | WO2000000122A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000061040A1 (en) * | 1999-04-12 | 2000-10-19 | The Procter & Gamble Company | Faecal collector with a convenient release sheet |
DE102007001079B4 (en) * | 2007-01-04 | 2009-07-23 | Sylvia Vitale | Panties diaper with a absorbent core |
WO2008154930A2 (en) * | 2007-06-19 | 2008-12-24 | Coloplast A/S | Multi-layered adhesive appliance |
BRPI0813285B8 (en) * | 2007-06-25 | 2021-06-22 | Coloplast As | ostomy device for coupling to the body stoma |
US8277427B2 (en) | 2007-08-10 | 2012-10-02 | Coloplast A/S | Faecal management device |
JP5794970B2 (en) * | 2012-11-08 | 2015-10-14 | 株式会社ユニケア | Diaper unit and diaper exterior |
CN106955208A (en) * | 2016-01-08 | 2017-07-18 | 常铁钢 | A kind of urine collecting |
CN108338773A (en) * | 2018-04-23 | 2018-07-31 | 中国人民解放军总医院 | A kind of endoscopy excreta barrier cover of buttocks |
GB201814501D0 (en) * | 2018-09-06 | 2018-10-24 | Concepts For Success C4S | Faeces separation sheet |
CN109464233A (en) * | 2018-12-11 | 2019-03-15 | 振德医疗用品股份有限公司 | Incontinence of faces ostomy bag and its manufacturing method |
CN110811999A (en) * | 2019-11-18 | 2020-02-21 | 陆广俊 | Multifunctional diaper |
Citations (9)
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GB1078588A (en) * | 1965-05-25 | 1967-08-09 | Hollister Inc | Urine collector |
GB1092274A (en) * | 1965-03-11 | 1967-11-22 | Bard Inc C R | Improvements in or relating to a pediatric urine collector |
US3577989A (en) | 1968-10-31 | 1971-05-11 | Jean O Anderson | Disposable plastic, elimination-trapping bag for incontinent patients |
GB2116849A (en) * | 1982-03-16 | 1983-10-05 | Hollister Inc | Fecal incontinence device |
US4699146A (en) | 1982-02-25 | 1987-10-13 | Valleylab, Inc. | Hydrophilic, elastomeric, pressure-sensitive adhesive |
EP0245064A2 (en) | 1986-05-09 | 1987-11-11 | E.R. Squibb & Sons, Inc. | Faecal incontinence bag |
US4784656A (en) | 1985-05-02 | 1988-11-15 | Christian Delores J | Fecal incontinence receptacle and methods of use |
JPH08117261A (en) * | 1994-10-24 | 1996-05-14 | Yoshio Beppu | Diaper |
EP0753290A2 (en) * | 1995-07-13 | 1997-01-15 | Hollister Incorporated | Fecal collector with elastic attachment patch |
-
1998
- 1998-06-26 WO PCT/US1998/013286 patent/WO2000000122A1/en active Application Filing
- 1998-06-26 CN CNB988141930A patent/CN1145461C/en not_active Expired - Fee Related
- 1998-06-26 AU AU82669/98A patent/AU8266998A/en not_active Abandoned
-
1999
- 1999-06-11 KR KR10-2000-7014784A patent/KR100455238B1/en not_active IP Right Cessation
- 1999-06-11 BR BR9912220-0A patent/BR9912220A/en not_active Application Discontinuation
- 1999-06-11 JP JP2000556719A patent/JP2002528145A/en not_active Withdrawn
- 1999-06-11 CN CNB998093149A patent/CN1158056C/en not_active Expired - Fee Related
- 1999-06-11 CA CA002335367A patent/CA2335367C/en not_active Expired - Fee Related
- 1999-06-11 AU AU45572/99A patent/AU755748B2/en not_active Ceased
- 1999-06-11 EP EP99928522A patent/EP1089694B1/en not_active Expired - Lifetime
- 1999-06-11 DE DE69906735T patent/DE69906735T2/en not_active Expired - Fee Related
- 1999-06-11 ES ES99928522T patent/ES2192387T3/en not_active Expired - Lifetime
- 1999-06-11 WO PCT/US1999/013001 patent/WO2000000133A1/en active IP Right Grant
- 1999-06-25 PE PE1999000574A patent/PE20000647A1/en not_active Application Discontinuation
- 1999-09-07 TW TW088115410A patent/TW529933B/en active
Patent Citations (10)
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GB1092274A (en) * | 1965-03-11 | 1967-11-22 | Bard Inc C R | Improvements in or relating to a pediatric urine collector |
GB1078588A (en) * | 1965-05-25 | 1967-08-09 | Hollister Inc | Urine collector |
US3577989A (en) | 1968-10-31 | 1971-05-11 | Jean O Anderson | Disposable plastic, elimination-trapping bag for incontinent patients |
US4699146A (en) | 1982-02-25 | 1987-10-13 | Valleylab, Inc. | Hydrophilic, elastomeric, pressure-sensitive adhesive |
GB2116849A (en) * | 1982-03-16 | 1983-10-05 | Hollister Inc | Fecal incontinence device |
GB2152387A (en) | 1982-03-16 | 1985-08-07 | Hollister Inc | Fecal collector |
US4784656A (en) | 1985-05-02 | 1988-11-15 | Christian Delores J | Fecal incontinence receptacle and methods of use |
EP0245064A2 (en) | 1986-05-09 | 1987-11-11 | E.R. Squibb & Sons, Inc. | Faecal incontinence bag |
JPH08117261A (en) * | 1994-10-24 | 1996-05-14 | Yoshio Beppu | Diaper |
EP0753290A2 (en) * | 1995-07-13 | 1997-01-15 | Hollister Incorporated | Fecal collector with elastic attachment patch |
Non-Patent Citations (1)
Title |
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PATENT ABSTRACTS OF JAPAN vol. 096, no. 009 30 September 1996 (1996-09-30) * |
Also Published As
Publication number | Publication date |
---|---|
KR100455238B1 (en) | 2004-11-08 |
AU755748B2 (en) | 2002-12-19 |
KR20010053194A (en) | 2001-06-25 |
CN1303254A (en) | 2001-07-11 |
CN1311652A (en) | 2001-09-05 |
BR9912220A (en) | 2001-05-02 |
CN1158056C (en) | 2004-07-21 |
JP2002528145A (en) | 2002-09-03 |
EP1089694A1 (en) | 2001-04-11 |
CA2335367A1 (en) | 2000-01-06 |
CN1145461C (en) | 2004-04-14 |
PE20000647A1 (en) | 2000-09-22 |
EP1089694B1 (en) | 2003-04-09 |
DE69906735T2 (en) | 2003-11-06 |
TW529933B (en) | 2003-05-01 |
AU8266998A (en) | 2000-01-17 |
AU4557299A (en) | 2000-01-17 |
DE69906735D1 (en) | 2003-05-15 |
WO2000000122A1 (en) | 2000-01-06 |
CA2335367C (en) | 2005-04-05 |
ES2192387T3 (en) | 2003-10-01 |
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