WO1999067251A3 - Ethoxylated allyloligoglycosides and the polymers thereof - Google Patents

Ethoxylated allyloligoglycosides and the polymers thereof Download PDF

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Publication number
WO1999067251A3
WO1999067251A3 PCT/EP1999/003986 EP9903986W WO9967251A3 WO 1999067251 A3 WO1999067251 A3 WO 1999067251A3 EP 9903986 W EP9903986 W EP 9903986W WO 9967251 A3 WO9967251 A3 WO 9967251A3
Authority
WO
WIPO (PCT)
Prior art keywords
ethoxylated
allyloligoglycosides
polymers
radical
allyl
Prior art date
Application number
PCT/EP1999/003986
Other languages
German (de)
French (fr)
Other versions
WO1999067251A2 (en
Inventor
Joerg Kahre
Oliver Rhode
Rainer Eskuchen
Original Assignee
Cognis Deutschland Gmbh
Joerg Kahre
Oliver Rhode
Rainer Eskuchen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland Gmbh, Joerg Kahre, Oliver Rhode, Rainer Eskuchen filed Critical Cognis Deutschland Gmbh
Publication of WO1999067251A2 publication Critical patent/WO1999067251A2/en
Publication of WO1999067251A3 publication Critical patent/WO1999067251A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
    • C07H15/02—Acyclic radicals, not substituted by cyclic structures
    • C07H15/04—Acyclic radicals, not substituted by cyclic structures attached to an oxygen atom of the saccharide radical
    • C07H15/10—Acyclic radicals, not substituted by cyclic structures attached to an oxygen atom of the saccharide radical containing unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Saccharide Compounds (AREA)
  • Detergent Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)

Abstract

The invention relates to ethoxylated allyloligoglycosides of the formula (I): R1O(CH2CH2O)n[G]p, wherein R1 represents an allyl radical, G represents a sugar radical with 5-6 carbon atoms an n and independently represent 1-10. The substances are obtained by acetalating glucose in the presence of basic catalysts with a molar surplus of ethoxylated allyl alcohol, the catalyst is subsequently neutralised and the unreacted allylalcoholpolyglycolether is removed by distillation. The glycosides can be optionally polymerised with comonomers and are thus suitable as co-builders for detergents or thickening agents for aqueous surfactant solutions.
PCT/EP1999/003986 1998-06-19 1999-06-10 Ethoxylated allyloligoglycosides and the polymers thereof WO1999067251A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19827305.3 1998-06-19
DE1998127305 DE19827305A1 (en) 1998-06-19 1998-06-19 Preparation of ethoxylated allyloligoglycosides, useful as polymerisable (co)monomers to form polymers useful as co-builders in washing agents

Publications (2)

Publication Number Publication Date
WO1999067251A2 WO1999067251A2 (en) 1999-12-29
WO1999067251A3 true WO1999067251A3 (en) 2000-06-22

Family

ID=7871371

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/003986 WO1999067251A2 (en) 1998-06-19 1999-06-10 Ethoxylated allyloligoglycosides and the polymers thereof

Country Status (2)

Country Link
DE (1) DE19827305A1 (en)
WO (1) WO1999067251A2 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4713436A (en) * 1986-04-04 1987-12-15 A. E. Staley Manufacturing Company Glycoside-containing polyester preparation process
EP0394496A1 (en) * 1988-10-27 1990-10-31 Nippon Fine Chemical Co., Ltd. Glycoside derivatives, polymers containing glycoside derivatives, process for their preparation, and use of said polymers
JPH05140294A (en) * 1991-11-22 1993-06-08 Kao Corp Polymer having sugar residue and its production
DE19603629A1 (en) * 1995-02-01 1996-08-08 Kao Corp Alkyl glycoside prodn. for use as surfactants and intermediates

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2152381A1 (en) * 1992-12-23 1994-07-07 Denis G. Fauteux Ion-conductive polymer and electrolyte additives

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4713436A (en) * 1986-04-04 1987-12-15 A. E. Staley Manufacturing Company Glycoside-containing polyester preparation process
EP0394496A1 (en) * 1988-10-27 1990-10-31 Nippon Fine Chemical Co., Ltd. Glycoside derivatives, polymers containing glycoside derivatives, process for their preparation, and use of said polymers
JPH05140294A (en) * 1991-11-22 1993-06-08 Kao Corp Polymer having sugar residue and its production
DE19603629A1 (en) * 1995-02-01 1996-08-08 Kao Corp Alkyl glycoside prodn. for use as surfactants and intermediates

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199327, Derwent World Patents Index; Class A25, AN 1993-216893, XP002134183 *
FERNANDEZ-SANTANA V. ET AL.: "Glycosides of monoallyl diethylene glycol. A new type of spacer group for synthetic oligosaccharides", J. CARBOHYDRATE CHEMISTRY, vol. 8, no. 3, 1989, pages 531 - 537, XP000892469 *
SZURMAI Z. ET AL.: "Diethylene and triethylene glycol spacers for the preparation of neoglycoproteins", ACTA CHIMICA HUNGARICA, vol. 126, no. 2, 1989, pages 259 - 269, XP000892399 *

Also Published As

Publication number Publication date
WO1999067251A2 (en) 1999-12-29
DE19827305A1 (en) 1999-12-23

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