WO1999055505A1 - Diffusable antisapstain method and compositions - Google Patents
Diffusable antisapstain method and compositions Download PDFInfo
- Publication number
- WO1999055505A1 WO1999055505A1 PCT/NZ1999/000050 NZ9900050W WO9955505A1 WO 1999055505 A1 WO1999055505 A1 WO 1999055505A1 NZ 9900050 W NZ9900050 W NZ 9900050W WO 9955505 A1 WO9955505 A1 WO 9955505A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- fungicide
- wood
- antisapstain
- surfactant
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/48—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —S—C≡N groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/36—Aliphatic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
Definitions
- a surface envelope for fungicide applied after the infection is in situ, which can occur within 24 hours, is ineffectual because it remains on the surface where it is unable to arrest internal sapstain fungi.
- the logistics of the majority of logging operations prevent antisapstain treatment before pre-treatment sapstain infection occurs. Therefore treatment with conventional antisapstain formulations that sit on the surface, is ineffectual under these circumstances.
- the present invention provides an improved or at least alternative method of protecting wet wood, especially logs, against sapstain. It is believed that the method of the invention provides protection for a longer term than obtained by currently available antisapstain treatments, without requiring water treatment or early drying.
- fungicides that moves into the log in a gaseous phase.
- Such fungicides have the advantage that they are less affected by log drying since gaseous fungicide can diffuse rapidly across wood of a wide range of moisture contents.
- MBT is an example of a fungicide which can diffuse in gaseous form.
- the antisapstain concentrate composition may comprise between about 10% and about 40% of a water barrier substance and between about 60% and about 90% of either an organic solvent, or water or a water based composition containing the mobile fungicide. Typically this is diluted up to 50 fold with water before application, but in some circumstances an organic solvent may be used.
- a hydrophobic substance selected from lanolin, petrolatum, paraffin oils, fish oils such as shark oil, animal oils, waxes, silicones, fatty acid esters, bitumen, vegetable fats and oils, or more preferably wool grease.
- a surfactant preferably a quaternary ammonium salt such as benzalkonium chloride 1- 10% methyl pyrrolidone
- Fungicides which may be present in addition to MBT include substituted benzimidazoles such as carbendazim (methyl benzimidazol-2-ylcarbamate), chemical precursors of benzimidazoles such as benomyl (methyl l-(butycarbony ⁇ ) ⁇ benzimidazol-2ylcarbamate or copper-8-hydroxyquinolinolate; triazoles such as hexaconazole ((RS)-2-(2,4-dichlorophenyl)- l-(lH- l,2,4-triazole- l-yl) hexan-2-ol); and quaternary ammonium compounds such as didecyldimethyl ammonium chloride, chlorothalonil (tetrachloroisophthalonitrile), fenpropimorph and isothiazolinones (eg 2-n-octyl isothiazolin-3-one).
- substituted benzimidazoles such as carb
- extra fungicides may usefully be present in other embodiments of the invention as well for their usefulness at the surface of the log.
- An advantage of embodiments of the invention where more than one fungicide is used is that this allows advantage to be taken of synergy between fungicides or to increase the spectrum of activity against wood degrading fungi.
- a water barrier hydrophobic substance is present into an amount of 1-40%.
- the concentrates, working compositions and methods of the invention are also useful with sawn timber.
- This composition is for SENTRYTM LX antisapstain composition as marketed by Chemcolour Industries (NZ) Limited, New Zealand.
- the antisapstain compositions described in Examples 1A and 2D are mixed with water in the ratio of 1:5.5 and 1: 10.7 respectively and sprayed onto logs.
- the antisapstain composition of Example 3 was used without dilution.
- the objective of this study was to determine the efficacy of the antisapstain formulations of Example 1A (C 1099) and Example 2D (C 1098) for protection of freshly felled radiata pine logs against fungal degrade.
- IPBC 3-iodo-2 propynylbutylcarbamate
- Treated logs were trucked to a sawmill and stacked in standing bolsters to form a single row which resembled a commercial stack, using NP- 1 sprayed pulp logs for bed logs and upright bolsters. The stack was aligned to the prevailing wind, so that the individual logs were at right angles to the wind.
- Logs were assessed after 12 and 16 weeks. Seven logs from each treatment were selected from the stack, taking care to include a representation of top, middle and bottom logs. The selected logs were laid out on bearers, and 3 from each treatment had a 30 cm disc removed from one end, and were assessed for decay using a pH colour indicator (methyl orange) . This indicator changes from orange- to red in the presence of decay fungi due to a lowering of the wood pH caused by incipient decay. These three logs were also given an external rating using the following rating scale:
- the objective of this study was to determine the efficacy of the antisapstain formulations of Examples 1A (C 1099) and 2D (C 1098) for protection of freshly felled radiata pine logs against fungal degrade.
- Discs were sawn from freshly cut radiata pine branches approximately 50 mm in diameter. Discs were frozen, gamma irradiated and then kept at -20°C until use.
- Fungicide concentrations are shown in Table 10. A water control was included in the trial.
- Trichoderma viride O. piceae (27) Poria vaillantii Chaetomium globosum O. ⁇ occosum (925) Phlebiopsis gigantea Cladosporium herbarum Diplodia pinea (4) Schizophyllum commune Penicillium sp. (x 2) Graphium (822) Leptographium ( 1790) 0. piliferum (4/97)
- Table 12 shows the fungal growth ratings for each of three replicate disks dipped in the three spore suspensions for each fungicide treatment.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU39613/99A AU764584B2 (en) | 1998-04-29 | 1999-04-29 | Diffusable antisapstain method and compositions |
NZ504749A NZ504749A (en) | 1998-04-29 | 1999-04-29 | Antisapstain compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ33032198 | 1998-04-29 | ||
NZ330321 | 1998-04-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999055505A1 true WO1999055505A1 (en) | 1999-11-04 |
Family
ID=19926689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NZ1999/000050 WO1999055505A1 (en) | 1998-04-29 | 1999-04-29 | Diffusable antisapstain method and compositions |
Country Status (3)
Country | Link |
---|---|
AR (1) | AR019119A1 (en) |
AU (1) | AU764584B2 (en) |
WO (1) | WO1999055505A1 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6197098B1 (en) * | 1999-12-16 | 2001-03-06 | Isp Investments Inc. | Fast drying biocidal preservative composition |
WO2001028332A1 (en) * | 1999-10-20 | 2001-04-26 | Air Liquide Sante (International) | Low-temperature-stable preservatives |
WO2006044218A2 (en) | 2004-10-14 | 2006-04-27 | Osmose, Inc. | Micronized wood preservative formulations in organic carriers |
EP1767093A2 (en) * | 2005-09-21 | 2007-03-28 | Clariant Produkte (Deutschland) GmbH | Biocidal compositions comprising an isothiazoline biocide and N-methyl-2-pyrrolidone |
EP2033520A1 (en) * | 2007-09-07 | 2009-03-11 | Cognis IP Management GmbH | Use of biocide compositions for wood preservation |
WO2010148450A1 (en) * | 2009-06-23 | 2010-12-29 | Danip Pty Ltd | Composition and method for treating wood |
WO2012091891A2 (en) * | 2010-12-29 | 2012-07-05 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
US8871277B2 (en) | 2003-06-17 | 2014-10-28 | Osmose, Inc. | Particulate wood preservative and method for producing the same |
US9079328B2 (en) | 2003-04-09 | 2015-07-14 | Koppers Performance Chemicals Inc. | Micronized wood preservative formulations |
US9314030B2 (en) | 2004-05-17 | 2016-04-19 | Koppers Performance Chemicals Inc. | Particulate wood preservative and method for producing same |
EP3387905A1 (en) * | 2017-04-12 | 2018-10-17 | ARS Holding Kolding A/S | Water-based anti-algae liquid |
US10829505B2 (en) | 2016-04-20 | 2020-11-10 | Dow Silicones Corporation | Lithium alkylsiliconate composition, coating, and method of making same |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1025362A (en) * | 1961-11-11 | 1966-04-06 | Sumitomo Chemical Co | Improvements in or relating to fungicides |
EP0069573A1 (en) * | 1981-07-06 | 1983-01-12 | Merck & Co. Inc. | Improved aqueous dispersion microbiocide composition containing methylene bis(thiocyanate) |
GB2118160A (en) * | 1982-03-19 | 1983-10-26 | Houseman | Methylene bisthiocyanate compositions |
AU4681985A (en) * | 1984-08-28 | 1986-04-10 | Hickson International Plc | Improvements in compositions and methods for antisapstain treatment of timber and timber products |
CA1207952A (en) * | 1983-12-01 | 1986-07-22 | Stuart A. Eaton | Wood preservative composition |
US5607727A (en) * | 1995-03-14 | 1997-03-04 | Isk Biosciences Corporation | Composition and method for controlling brown stain in wood |
WO1997027034A1 (en) * | 1996-01-23 | 1997-07-31 | New Zealand Forest Research Institute Limited | Method of inhibiting sapstain in wood |
US5728730A (en) * | 1994-01-27 | 1998-03-17 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing methylene-bis(thiocyanate) and an organic acid |
-
1999
- 1999-04-29 AR ARP990101994 patent/AR019119A1/en active IP Right Grant
- 1999-04-29 AU AU39613/99A patent/AU764584B2/en not_active Expired
- 1999-04-29 WO PCT/NZ1999/000050 patent/WO1999055505A1/en active IP Right Grant
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1025362A (en) * | 1961-11-11 | 1966-04-06 | Sumitomo Chemical Co | Improvements in or relating to fungicides |
EP0069573A1 (en) * | 1981-07-06 | 1983-01-12 | Merck & Co. Inc. | Improved aqueous dispersion microbiocide composition containing methylene bis(thiocyanate) |
GB2118160A (en) * | 1982-03-19 | 1983-10-26 | Houseman | Methylene bisthiocyanate compositions |
CA1207952A (en) * | 1983-12-01 | 1986-07-22 | Stuart A. Eaton | Wood preservative composition |
AU4681985A (en) * | 1984-08-28 | 1986-04-10 | Hickson International Plc | Improvements in compositions and methods for antisapstain treatment of timber and timber products |
US5728730A (en) * | 1994-01-27 | 1998-03-17 | Buckman Laboratories International, Inc. | Synergistic antimicrobial compositions containing methylene-bis(thiocyanate) and an organic acid |
US5607727A (en) * | 1995-03-14 | 1997-03-04 | Isk Biosciences Corporation | Composition and method for controlling brown stain in wood |
WO1997027034A1 (en) * | 1996-01-23 | 1997-07-31 | New Zealand Forest Research Institute Limited | Method of inhibiting sapstain in wood |
Non-Patent Citations (1)
Title |
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DERWENT ABSTRACTS, Accession No. 86-097070/15, Class P63; & JP 61041501 A (KATAYAMA KAGAKU KOGYO KENKYUSHO KK) 27 February 1986. * |
Cited By (34)
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US7368466B2 (en) | 1999-10-20 | 2008-05-06 | Air Liquide Sante (International) | Low-temperature-stable preservatives |
WO2001028332A1 (en) * | 1999-10-20 | 2001-04-26 | Air Liquide Sante (International) | Low-temperature-stable preservatives |
JP2003511471A (en) * | 1999-10-20 | 2003-03-25 | エール・リキード・サンテ(アンテルナスィオナル) | Low temperature stable preservative |
US7045542B1 (en) | 1999-10-20 | 2006-05-16 | Air Liquide Sante (International) | Low-temperature-stable preservatives |
US6197098B1 (en) * | 1999-12-16 | 2001-03-06 | Isp Investments Inc. | Fast drying biocidal preservative composition |
US9079328B2 (en) | 2003-04-09 | 2015-07-14 | Koppers Performance Chemicals Inc. | Micronized wood preservative formulations |
US8871277B2 (en) | 2003-06-17 | 2014-10-28 | Osmose, Inc. | Particulate wood preservative and method for producing the same |
US9314030B2 (en) | 2004-05-17 | 2016-04-19 | Koppers Performance Chemicals Inc. | Particulate wood preservative and method for producing same |
EP2431430A1 (en) * | 2004-10-14 | 2012-03-21 | Osmose, Inc. | Micronized wood preservative formulations in organic carriers |
EP1799776A2 (en) * | 2004-10-14 | 2007-06-27 | Osmose, Inc. | Micronized wood preservative formulations in organic carriers |
EP1799776A4 (en) * | 2004-10-14 | 2009-05-06 | Osmose Inc | Micronized wood preservative formulations in organic carriers |
AU2005296077B2 (en) * | 2004-10-14 | 2010-12-23 | Koppers Performance Chemicals Inc. | Micronized wood preservative formulations in organic carriers |
WO2006044218A2 (en) | 2004-10-14 | 2006-04-27 | Osmose, Inc. | Micronized wood preservative formulations in organic carriers |
US9775350B2 (en) | 2004-10-14 | 2017-10-03 | Koppers Performance Chemicals Inc. | Micronized wood preservative formulations in organic carriers |
EP1767093A3 (en) * | 2005-09-21 | 2007-07-25 | Clariant Produkte (Deutschland) GmbH | Biocidal compositions comprising an isothiazoline biocide and N-methyl-2-pyrrolidone |
EP1767093A2 (en) * | 2005-09-21 | 2007-03-28 | Clariant Produkte (Deutschland) GmbH | Biocidal compositions comprising an isothiazoline biocide and N-methyl-2-pyrrolidone |
EP2033520A1 (en) * | 2007-09-07 | 2009-03-11 | Cognis IP Management GmbH | Use of biocide compositions for wood preservation |
US7959723B2 (en) | 2007-09-07 | 2011-06-14 | Cognis Ip Management Gmbh | Use of biocide compositions for wood preservation |
WO2009030433A3 (en) * | 2007-09-07 | 2009-12-17 | Cognis Ip Management Gmbh | Use of biocide compositions for wood preservation |
WO2009030433A2 (en) * | 2007-09-07 | 2009-03-12 | Cognis Ip Management Gmbh | Use of biocide compositions for wood preservation |
US20120148859A1 (en) * | 2009-06-23 | 2012-06-14 | Danip Pty Ltd. | Composition and method for treating wood |
AU2010265790C1 (en) * | 2009-06-23 | 2016-12-08 | Hyne & Son Pty. Limited | Composition and method for treating wood |
WO2010148450A1 (en) * | 2009-06-23 | 2010-12-29 | Danip Pty Ltd | Composition and method for treating wood |
US8765267B2 (en) | 2009-06-23 | 2014-07-01 | Danip Pty Ltd | Composition and method for treating wood |
AU2010265790B2 (en) * | 2009-06-23 | 2014-12-04 | Hyne & Son Pty. Limited | Composition and method for treating wood |
US8747534B2 (en) | 2010-12-29 | 2014-06-10 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
CN103260403B (en) * | 2010-12-29 | 2015-08-19 | 美国石膏公司 | Antimicrobial sizing emulsions and the gypsum panels manufactured by it |
AU2011352988B2 (en) * | 2010-12-29 | 2015-12-03 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
CN103260403A (en) * | 2010-12-29 | 2013-08-21 | 美国石膏公司 | Antimicrobial size emulsion and gypsum panel made therewith |
WO2012091891A3 (en) * | 2010-12-29 | 2012-08-23 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
US9518363B2 (en) | 2010-12-29 | 2016-12-13 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
WO2012091891A2 (en) * | 2010-12-29 | 2012-07-05 | United States Gypsum Company | Antimicrobial size emulsion and gypsum panel made therewith |
US10829505B2 (en) | 2016-04-20 | 2020-11-10 | Dow Silicones Corporation | Lithium alkylsiliconate composition, coating, and method of making same |
EP3387905A1 (en) * | 2017-04-12 | 2018-10-17 | ARS Holding Kolding A/S | Water-based anti-algae liquid |
Also Published As
Publication number | Publication date |
---|---|
AU764584B2 (en) | 2003-08-21 |
AU3961399A (en) | 1999-11-16 |
AR019119A1 (en) | 2001-12-26 |
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