WO1999030812A1 - Dispositif et procede d'aeration de fluides - Google Patents

Dispositif et procede d'aeration de fluides Download PDF

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Publication number
WO1999030812A1
WO1999030812A1 PCT/IB1998/002057 IB9802057W WO9930812A1 WO 1999030812 A1 WO1999030812 A1 WO 1999030812A1 IB 9802057 W IB9802057 W IB 9802057W WO 9930812 A1 WO9930812 A1 WO 9930812A1
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WO
WIPO (PCT)
Prior art keywords
gas
liquid
bubbles
fluid
diameter
Prior art date
Application number
PCT/IB1998/002057
Other languages
English (en)
Inventor
Alfonso Ganan Calvo
Original Assignee
Universidad De Sevilla
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from ES9702654A external-priority patent/ES2158741B1/es
Priority claimed from US09/191,756 external-priority patent/US6196525B1/en
Application filed by Universidad De Sevilla filed Critical Universidad De Sevilla
Priority to EP98960050A priority Critical patent/EP1039965A1/fr
Priority to CA002314919A priority patent/CA2314919A1/fr
Priority to JP2000538781A priority patent/JP2002508238A/ja
Priority to AU15732/99A priority patent/AU745698B2/en
Publication of WO1999030812A1 publication Critical patent/WO1999030812A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M15/00—Inhalators
    • A61M15/02—Inhalators with activated or ionised fluids, e.g. electrohydrodynamic [EHD] or electrostatic devices; Ozone-inhalators with radioactive tagged particles
    • A61M15/025—Bubble jet droplet ejection devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/04—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge
    • B05B7/0416—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid
    • B05B7/0441—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid with one inner conduit of liquid surrounded by an external conduit of gas upstream the mixing chamber
    • B05B7/0475—Spray pistols; Apparatus for discharge with arrangements for mixing liquids or other fluent materials before discharge with arrangements for mixing one gas and one liquid with one inner conduit of liquid surrounded by an external conduit of gas upstream the mixing chamber with means for deflecting the peripheral gas flow towards the central liquid flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/06—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane
    • B05B7/061—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with several liquid outlets discharging one or several liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/06—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane
    • B05B7/062—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with only one liquid outlet and at least one gas outlet
    • B05B7/065—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with only one liquid outlet and at least one gas outlet an inner gas outlet being surrounded by an annular adjacent liquid outlet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/06—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane
    • B05B7/062—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with only one liquid outlet and at least one gas outlet
    • B05B7/066—Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with only one liquid outlet and at least one gas outlet with an inner liquid outlet surrounded by at least one annular gas outlet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02—Spray pistols; Apparatus for discharge
    • B05B7/08—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • B05B7/0884—Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point the outlet orifices for jets constituted by a liquid or a mixture containing a liquid being aligned
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M43/00—Fuel-injection apparatus operating simultaneously on two or more fuels, or on a liquid fuel and another liquid, e.g. the other liquid being an anti-knock additive
    • F02M43/04—Injectors peculiar thereto
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M67/00—Apparatus in which fuel-injection is effected by means of high-pressure gas, the gas carrying the fuel into working cylinders of the engine, e.g. air-injection type
    • F02M67/10—Injectors peculiar thereto, e.g. valve less type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M69/00—Low-pressure fuel-injection apparatus ; Apparatus with both continuous and intermittent injection; Apparatus injecting different types of fuel
    • F02M69/04—Injectors peculiar thereto
    • F02M69/047—Injectors peculiar thereto injectors with air chambers, e.g. communicating with atmosphere for aerating the nozzles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23D—BURNERS
    • F23D11/00—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space
    • F23D11/10—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour
    • F23D11/106—Burners using a direct spraying action of liquid droplets or vaporised liquid into the combustion space the spraying being induced by a gaseous medium, e.g. water vapour medium and fuel meeting at the burner outlet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00351—Means for dispensing and evacuation of reagents
    • B01J2219/00378—Piezo-electric or ink jet dispensers
    • C—CHEMISTRY; METALLURGY
    • C40—COMBINATORIAL TECHNOLOGY
    • C40B—COMBINATORIAL CHEMISTRY; LIBRARIES, e.g. CHEMICAL LIBRARIES
    • C40B60/00—Apparatus specially adapted for use in combinatorial chemistry or with libraries
    • C40B60/14—Apparatus specially adapted for use in combinatorial chemistry or with libraries for creating libraries
    • G01N15/1409—
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/10—Investigating individual particles
    • G01N15/14—Electro-optical investigation, e.g. flow cytometers
    • G01N15/1404—Fluid conditioning in flow cytometers, e.g. flow cells; Supply; Control of flow
    • G01N2015/1406—Control of droplet point

Definitions

  • the invention relates generally to the field of small particle formation and more specifically to fields where it is important to create gas bubbles which are very small and uniform in size.
  • Monodispersed sprays of droplets of micrometric size have attracted the interest of scientist and engineers because of their potential applications in many fields of science and technology.
  • Classifying a polydispersed aerosol for example, by using a differential mobility analyzer, B.Y. Liu et al. (1974), "A Submicron Standard and the Primary Absolute Calibration of the Condensation Nuclei Counter, " /. Coloid Interface Sci. 47: 155-171 or breakup process of Rayleigh's type of a capillary microjet Lord Rayleigh (1879), "On the instability of Jets, " Proc. London Math. Soc. 1Q:4-13, are the current methods to produce the monodispersed aerosols of micrometric droplets needed for such applications.
  • Capillary microjets with diameters ranging from tens of nanometers to hundred of micrometers are successfully generated by employing high electrical fields (several kV) to form the well-known cone-jet electrospray.
  • Theoretical and experimental results and numerical calculations on electrosprays can be obtained from M. Cloupean et al. (1989), "Electrostatic Spraying of Liquids in Cone Jet Mode," /. Electrostat 22: 135-159, Fernandez de la Mora et al. (1994), "The Current Transmitted through an Electrified Conical Meniscus," /. Fluid Mech.T : 155-184 and Loscertales (1994), A.M. Ganan- Calvo et al.
  • the use of purely mechanical means to produce capillary microjets is limited in most of applications for several reasons: the high-pressure values required to inject a fluid through a very narrow tube (typical diameters of the order of few micrometers) and the easy clogging of such narrow tubes due to impurities in the liquid.
  • the present invention provides a new technique for producing uniform sized monodispersion of gas bubbles based on a mechanical means which does not present the above inconveniences and can compete advantageously with electrospray atomizers.
  • the jet diameters produced with this technique can be easily controlled and range from below one micrometer to several tens of micrometers.
  • the present invention provides aeration methods using spherical gas bubbles having a size on d e order of 0.1 to 100 microns in size.
  • a device of the invention for producing a monodispersion of bubbles includes a source of a stream of gas which is forced through a liquid held under pressure in a pressure chamber with an exit opening therein. The stream of gas surrounded by the liquid in the pressure chamber flows out of an exit orifice of the chamber into a liquid thereby creating a monodispersion of bubbles with substantially uniform diameter.
  • the bubbles are small in size and produced with a relatively small amount of energy relative to comparable systems.
  • Applications of the aeration technology range from oxygenating sewage with monodispersions of bubbles to oxygenation of water for fish maintenance.
  • Figure 1 is a schematic view showing the basic components of one embodiment of the invention with a cylindrical feeding needle as a source of formulation.
  • Figure 2 is a schematic view of another embodiment of the invention with two concentric tubes as a source of formulation.
  • Figure 3 is a schematic view of yet another embodiment showing a wedge-shaped planar source of formulation.
  • Figure 3a illustrates a cross-sectional side view of the planar feeding source and the interaction of the fluids.
  • Figure 3b show a frontal view of the openings in the pressure chamber, with the multiple openings through which the atomizate exits the device.
  • Figure 3c illustrates the channels that are optionally formed within the planar feeding member. The channels are aligned with the openings in the pressure chamber.
  • Figure 4 is a schematic view of a stable capillary microjet being formed and flowing through an exit opening to thereafter form a monodisperse aerosol.
  • Figure 5 is a graph of data where 350 measured values o ⁇ dJ- d 0 versus QIQ 0 are plotted.
  • Figure 6 is a micrograph showing the even dispersement and uniform size of air bubbles created using the method of the invention after expulsion into air.
  • Figure 7 is a schematic view of the critical area of a device of the type shown in Figure 1 showing gas surrounded by liquid expelled into a liquid to form bubbles.
  • Figure 8 is a schematic view as in Figure 7 but with the bubbles flowing into a gas.
  • Figure 9 is a schematic view as in Figure 7 but with two immiscible liquids flowing into a gas.
  • dates of publication provided may be different from the actual publication dates which may need to be independently confirmed.
  • bubble denotes small uniformly sized particles of a gas or gaseous formulation that has been dispersed using the device and method of the invention.
  • the particles are generally spherical, and may be comprised of one or more gases or layers of gases.
  • air "particle free air” and the like, are used interchangeably herein to describe a volume of air which is substantially free of other material and, in particular, free of particles intentionally added such as particles of formulation.
  • Air is a mixture of various gas components that may, of course vary, but usually the air will contain approximately 21 % oxygen by volume. Air may also contain gases or other air-borne particles.
  • air may be filtered or treated to remove all unwanted particulate or gaseous matter, or the air may be used in an unfiltered state.
  • Air is the preferred gas for use of the invention in oxygenation of aqueous fluids, e.g. water.
  • gas and gas formulation refer to any gas or gaseous mixture which is desired to be dispersed using the method of the invention.
  • the formulation may be comprised of air, either filtered or unfiltered. Gases such as air may be spiked with a particular gas, such as the spiking of air with additional 0 2 gas for use in oxygenation.
  • a gaseous formulation may also contain suspended particlulate matter dispersed within the gas.
  • the gas can be CO 2 to carry out the carbonation of beverages (e.g. water, colas) or a gas containing an unwanted contaminant, e.g. radioactivity or an environmental toxin.
  • aeration refers to the dispersion of a gaseous material into a flowable fluid, for example to provide a diffusion surface to introduce a molecule or compound from the gas into the flowable surface.
  • the term is not limited to me dispersion of air per se, although the use of air is preferred, but rather refers to the introduction of any gas to a flowable fluid, e.g. O 2 , CO 2 , hydrogen, nitrogen, and the like and mixtures thereof.
  • the aeration of a fluid is preferably to allow molecules and/or compounds to diffuse to the fluid through the fluid-bubble interface following expulsion of the bubbles from the device of the invention into the surrounding fluid.
  • a fluid may, however, also be aerated for aesthetic purposes, such as the addition of CO 2 to a beverage to provide carbonation.
  • a basic device comprises (1) a means for supplying a first fluid, preferably a gas, and (2) a pressure chamber supplied with a second fluid which flows out of an exit opening in the pressure chamber, preferably a liquid.
  • the exit opening of the pressure chamber is aligned with the flow path of the means for supplying the first fluid.
  • the means for supplying a first fluid is often referred to as a cylindrical tube (see Figure 1) and the first fluid is generally referred to as a gas.
  • the gas can be any gas depending on the desired use of the device, although it is preferably air.
  • the gas could be air used to create small bubbles for aeration of a liquid to provide a gaseous medium through which components may diffuse into a liquid.
  • the second fluid is generally described herein as being a liquid, e.g. water.
  • the invention is also generally described with a gas formulation being expelled from the supply means and forming a stable microjet due to interaction with surrounding water flow, which focuses the gas microjet to flow out of an exit of the pressure chamber.
  • Formation of the microjet and its acceleration and ultimate particle formation are based on the abrupt pressure drop associated with the steep acceleration experienced by the gas on passing through an exit orifice of the pressure chamber which holds the second fluid (i.e. the liquid).
  • the flow undergoes a certain pressure difference between the liquid and the gas, which in turn produces a highly curved zone on the liquid surface near the exit port of the pressure chamber and in the formation of a cuspidal point from which a steady microjet flows, provided the amount of the gas drawn through the exit port of the pressure chamber is replenished.
  • the flow of the liquid surrounds and focuses the gas into a stable microjet.
  • the focusing effect of the surrounding flow of liquid creates a stream of gas which is substantially smaller in diameter than the diameter of the exit orifice of the pressure chamber. This allows the gas to flow out of the pressure ch.amber orifice without touching the orifice, providing advantages including the feature that the diameter of the stream and the resulting particles are smaller than the diameter of the exit orifice of the chamber. This is particularly desirable because it is difficult to precisely engineer holes which are very small in diameter. Further, in the absence of the focusing effect (and formation of a stable interface cusp) flow of gas out of an opening will result in particles which have a diameter greater than the diameter of the exit opening.
  • the description provided here generally indicates that the gas leaves the pressure chamber through an exit orifice surrounded by the liquid and thereafter enters into a liquid surrounding environment which may be either a hydrophobic or hydrophilic liquid.
  • a liquid surrounding environment which may be either a hydrophobic or hydrophilic liquid.
  • This configuration is particularly useful when it is necessary to create very small highly uniform bubbles which are moved into a liquid surrounding exit opening of the pressure chamber.
  • the need for the formation of very small highly uniform bubbles into a gas occurs in a variety of different industrial applications. For example, water needs to be oxygenated in a variety of situations including small fish tanks for home use and large volume fisheries for industrial use. The additional oxygen can aid the rate of growth of the fish and thereby improve production for the fishery.
  • oxygen or air bubbles can be forced into liquid sewage in order to aid in treatment.
  • contaminated gases such as a gas contaminated with a radioactive material can be formed into small uniformed bubbles and blown into a liquid, where the contamination in the gas will diffuse into the liquid, thereby cleaning the gas.
  • the liquid will, of course, occupy substantially less volume and therefore be substantially easier to dispose of than contaminated toxic gas.
  • FIGURE 1 A first embodiment of the invention where the supply means is a cylindrical feeding needle supplying gas into a pressurized chamber of liquid is described below with reference to Figure 1.
  • Feeding needle - also referred to generally as a fluid source and a tube.
  • Atomizate (spray) also referred to as aerosol.
  • Dj diameter of the feeding needle
  • D 0 diameter of the orifice through which the microjet is passed
  • e axial length of the orifice through which withdrawal takes place
  • H distance from the feeding needle to the microjet outlet
  • P 0 pressure inside the chamber
  • P a atmospheric pressure.
  • a device of the invention will be comprised of at least one source of a first fluid (e.g., a feeding needle with an opening 2) into which a first fluid such as a gas formulation can be fed and an exit opening 5 from which the gas can be expelled.
  • the feeding needle 1, or at least its exit opening 5, is encompassed by a pressure chamber 3.
  • the chamber 3 has inlet opening 4 which is used to feed a second fluid (e.g. a liquid) into the chamber 3 and an exit opening 6 through which liquid from the pressure chamber and gas from the feeding needle 3 are expelled.
  • a second fluid e.g. a liquid
  • the first fluid is a gas it is preferably expelled into a liquid to create bubbles.
  • the feeding needle and pressure chamber are configured to obtain a desired result of producing bubbles wherein the particles are small and uniform in size.
  • the bubbles have a size which is in a range of 0J to 100 microns.
  • the particles of any given bubbles will all have about the same diameter with a relative standard deviation of +0.01 % to +30% or more preferably +0.01 % to + 10% .
  • Stating that bubbles will have a diameter in a range of 1 to 5 microns does not mean that different bubbles will have different diameters and that some will have a diameter of 1 micron while others of 5 microns.
  • the bubbles in a given dispersion will all (preferably about 90% or more) have the same diameter +0.01 % to +30%.
  • the bubbles of a given dispersion will have a diameter of 2 microns +0.01 % to +10%.
  • Such a uniform bubble monodispersion is created using the components and configuration as described above. However, other components and configurations will occur to those skilled in the art.
  • the object of each design will be to supply fluid so that it creates a stable capillary microjet which is accelerated and stabilized by pressure stress exerted by the second fluid on the first fluid surface.
  • the stable microjet created by the second fluid leaves the pressurized area (e.g., leaves the pressure chamber and exits the pressure chamber orifice) and splits into particles or bubbles which have the desired size and uniformity.
  • the parameter window used i. e.
  • the set of special values for the properties of the liquid used, flow-rate used, feeding needle diameter, orifice diameter, pressure ratio, etc. should be large enough to be compatible with virtually any liquid (dynamic viscosities in the range from 10 "5 to 1 kg m ' V 1 ); in this way, the capillary microjet that emerges from the end of the feeding needle is absolutely stable and perturbations produced by breakage of the jet cannot travel upstream. Downstream, the microjet splits into evenly shaped bubbles simply by effect of capillary instability (see, for example, Rayleigh, "On the instability of jets", Proc. London Math. Soc, 4-13, 1878), similar in a manner to a laminar capillary jet falling from a half-open tap.
  • the capillary jet that emerges from the end of the bubble attached at the outlet of the feeding point is concentrically withdrawn into the nozzle.
  • the gas jet emerges from the attached bubble, the gas is accelerated by pressure forces exerted by the liquid stream, which gradually decreases the jet cross-section.
  • the liquid flow acts as a lens and focuses and stabilizes the gas microjet as it moves toward and into the exit orifice of the pressure chamber.
  • the first fluid of the invention is a gas
  • the second fluid is a liquid
  • d e inertia of the first fluid is low
  • the gas abruptly decelerates very soon after it issues from the cusp of the attached bubble.
  • the microjet is so short that it is almost indistinguishable from the stable cusp of the gas-liquid interface.
  • the first fluid of the invention is a gas and the second fluid is a liquid
  • the two fluid stream is expelled into a gaseous atmosphere
  • a liquid jet with a regularly spaced gaseous formation of bubbles is formed.
  • the regularity of the bubbles is such that the liquid jet is deformed in a very regular manner, resulting in a highly monodisperse stream of hollow droplets.
  • the gas inside these hollow droplets may be manipulated by appropriate chemical, thermal or mechanical means to expand further upon expulsion from the device, causing the hollow bubbles to break into even finer droplets.
  • the hollow droplets may be cured to a hollow, solid form.
  • the forces exerted by the second fluid flow on the first fluid surface should be steady enough to prevent irregular surface oscillations. Therefore, any turbulence in the gas and liquid motion should be avoided; even if the gas velocity is high, the characteristic size of the orifice should ensure that the fluid motion is laminar (similar to the boundary layers formed on the jet and on the inner surface of the nozzle or hole).
  • FIG 4 illustrates the interaction of a gas and a liquid to form bubbles using the method of the invention.
  • the feeding needle 60 has a circular exit opening 61 with an internal radius R which feeds a gas 62 out of the end, forming a drop with a radius in the range of R 1 to R., plus the thickness of the wall of the needle. Thereafter the drop narrows in circumference to a much smaller circumference as is shown in the expanded view of the tube (i.e. feeding needle) 5 as shown in Figures 1 and 4.
  • the exiting gas flow comprises an infinite amount of streamlines 63 that after interaction of the gas with the surrounding liquid narrows to form a stable cusp at the interface 64 of the two fluids.
  • the surrounding liquid also forms an infinite number of liquid streamlines 65, which interact with the solid surfaces and the exiting gas to create the effect of a virtual focusing funnel 66.
  • the exiting gas is focused by the focusing funnel 66 resulting in a stable capillary microjet 67, which remains stable until it exits the opening 68 of the pressure chamber 69.
  • the microjet After exiting the pressure chamber, the microjet begins to break-up, forming monodispersed particles 70.
  • the liquid flow which affects the gas withdrawal and its subsequent deceleration after the jet is formed, should be very rapid but also uniform in order to avoid perturbing the fragile capillary interface (the surface of the drop that emerges from the jet).
  • the exit opening 61 of the capillary tube 60 is positioned close to an exit opening 68 in a planar surface of a pressure chamber 69.
  • the exit opening 68 has a minimum diameter D 0 and is in a planar member with a thickness e.
  • the di.ameter D 0 is referred to as a minimum diameter because the opening may have a conical configuration with the n.arrower end of the cone positioned closer to the source of liquid flow.
  • the exit opening may be a funnel-shaped nozzle although other opening configurations are also possible, e.g. an hour glass configuration.
  • Liquid in the pressure chamber continuously flows out of the exit opening. The flow of the liquid causes the gas drop expelled from the tube to decrease in circumference as the gas moves away from the end of the tube in a direction toward the exit opening of the pressure chamber.
  • the opening shape which provokes m.aximum liquid acceleration is a conically shaped opening in the pressure chamber.
  • the conical opening is positioned with its narrower end toward the source of gas flow.
  • the distance between the end 61 of the tube 60 .and the beginning of the exit opening 68 is H.
  • R,, D 0 , H and e are all preferably on the order of hundreds of microns.
  • Ri 400 ⁇ m
  • D 0 150 ⁇ m
  • H 1mm
  • e 300 m.
  • the end of the gas stream develops a cusp-like shape at a critical distance from the exit opening 68 in the pressure chamber 69 when the applied pressure drop ⁇ P] across the exit opening 68 overcomes the liquid-gas surface tension stresses ⁇ /R * appearing at the point of maximum curvature — e.g. 1 R * from the exit opening.
  • a steady state is then established if the gas flow rate Q ejected from the drop cusp is steadily supplied from the capillary tube.
  • This is the stable capillary cusp which is an essential characteristic of the invention needed to form the stable microjet. More particularly, a steady, thin gas jet with a typical diameter d j is smoothly emitted from the stable cusp-like drop shape and this thin gaseous jet extends over a distance in the range of microns to millimeters. The length of the stable microjet will vary from very short (e.g. 1 micron) to very long (e.g.
  • the gas jet is the stable capillary microjet obtained when supercritical flow is reached.
  • the microjet may be so small as to be almost indistinguishable from the stable cusp.
  • This jet demonstrates a robust behavior provided that the pressure drop ⁇ P., applied to the liquid is sufficiently large compared to the maximum surface tension stress (on the order of ⁇ /d j ) that act at the liquid-gas interface.
  • the stable microjet is formed without the need for other forces, i.e. without adding force such as electrical forces on a charged fluid.
  • the microjet eventually destabilizes due to the effect of surface tension forces. Destabilization results from small natural perturbations moving downstream, with the fastest growing perturbations being those which govern the break up of the microjet, eventually creating a uniform sized monodispersion of bubbles 70 as shown in Figure 4.
  • the microjet even as it initially destabilizes, passes out of the exit orifice of the pressure chamber without touching the peripheral surface of the exit opening.
  • MATHEMATICS OF A STABLE MICROJET Cylindrical coordinates (r,z) are chosen for analyzing the shape of a stable microjet, i.e. a liquid jet undergoing "supercritical flow.”
  • the cusp-like meniscus formed by the fluid coming out of the tube is pulled toward the exit of the pressure chamber by a pressure gradient created by the flow of a second, immiscible fluid.
  • the proposed system obviously requires delivery of the gas to be atomized and the liquid to be used in the resulting drop production. Both should be fed at a rate ensuring that the system lies within the stable parameter window. Multiplexing is effective when the flow- rates needed exceed those on an individual cell. More specifically, a plurality of feeding sources or feeding needles may be used to increase the rate at which aerosols are created. The flow-rates used should also ensure the mass ratio between the flows is compatible with the specifications of each application.
  • the gas and liquid can be dispensed by any type of continuous delivery system (e.g. a compressor or a pressurized tank the former and a volumetric pump or a pressurized bottle the latter). If multiplexing is needed, the liquid flow-rate should be as uniform as possible among cells; this may entail propulsion through several capillary needles, porous media or any other medium capable of distributing a uniform flow among different feeding points.
  • a compressor or a pressurized tank the former and a volumetric pump or a pressurized bottle the latter e.g. a compressor or a pressurized tank the former and a volumetric pump or a pressurized bottle the latter.
  • Each individual device should consist of a feeding point (a capillary needle, a point with an open microchannel, a microprotuberance on a continuous edge, etc.) 0.002-2 mm (but, preferentially 0.01-0.4 mm) in diameter, where the drop emerging from the microjet can be anchored, and a small orifice 0.002-2 mm (preferentially 0.01-0.25 mm) in diameter facing the drop and separated 0.01-2 mm (preferentially 0J-0.5 mm) from the feeding point.
  • the orifice communicates the withdrawal liquid around the drop, at an increased pressure, with the zone where the atomizate is produced, at a decreased pressure.
  • the device can be made from a variety of materials (metal, polymers, ceramics, glass).
  • Figure 1 depicts a tested prototype where the gas to be atomized is inserted through one end of the system 2 and the liquid in introduced via the special inlet 4 in the pressure chamber 3.
  • the prototype was tested at gas feeding rates from 10 to 2000 mBar above the atmospheric pressure P a at which the atomized gas was discharged.
  • the whole enclosure around the feeding needle 1 was at a pressure P 0 > P a .
  • the gas feeding pressure, Pj should always be slightly higher than the liquid propelling pressure, P 0 .
  • the pressure difference (P, - P 0 > 0) and the flow-rate of the gas to be atomized, Q are linearly related provided the flow is laminar - which is indeed the case with this prototype.
  • the critical dimensions are the distance from the needle to the plate (H), the needle diameter (D 0 ), the diameter of the orifice through which the microjet 6 is discharged (d 0 ) and the axial length, e, of the orifice (t ' .e. the thickness of the plate where the orifice is made).
  • the quality of the resulting spray 7 did not vary appreciably with changes in H provided the operating regime (i.e. stationary drop and microjet) was maintained. However, the system stability suffered at the longer H distances (about 0.1 mm).
  • the other atomizer dimensions had no effect on the spray or the prototype functioning provided the zone around the needle (its diameter) was large enough relative to the feeding needle.
  • WEBER NUMBER Adjusting parameters to obtain a stable capillary microjet and control its breakup into monodisperse particle is governed by the Weber number and the liquid-to-gas velocity ratio or ⁇ which equal VJV % .
  • the Weber number or "We" is defined by the following equation:
  • p is the density of the gas
  • d is the diameter of the stable microjet
  • ⁇ is the liquid-gas surface tension
  • Vf is the velocity of the liquid squared.
  • Weber number is greater than 1 in order to produce a stable capillary microjet.
  • the parameters should be adjusted so that the Weber number is less than about 40.
  • the monodisperse aerosol is obtained with a Weber number in a range of about 1 to about 40
  • OHNESORGE NUMBER A measure of the relative importance of viscosity on the jet breakup can be estimated from the Ohnesorge number defined as the ratio between two characteristic times: the viscous time t v and the breaking time t b .
  • the breaking time t b is given by [see Rayleigh (1878)]
  • EMBODIMENT OF FIGURE 2 A variety of configurations of components and types of fluids will become apparent to those skilled in the art upon reading this disclosure. These configurations and fluids are encompassed by the present invention provided they can produce a stable capillary microjet of a first fluid from a source to an exit port of a pressure chamber containing a second fluid.
  • the stable microjet is formed by the first fluid flowing from the feeding source to the exit port of the pressure chamber being accelerated and stabilized by pressure stress exerted by the second fluid in the pressure chamber on the surface of the first fluid forming the microjet.
  • the second fluid forms a focusing funnel when a variety of parameters are correctly tuned or adjusted.
  • the speed, pressure, viscosity and miscibility of the first and second fluids are chosen to obtain the desired results of a stable microjet of the first fluid focused into the center of a funnel formed with the second fluid.
  • These results are also obtained by adjusting or tuning physical parameters of the device, including the size of the opening from which the first fluid flows, the size of the opening from which both fluids exit, and the distance between these two openings.
  • the embodiment of Figure 1 can, itself, be arranged in a variety of configurations. Further, as indicated above, the embodiment may include a plurality of feeding needles. A plurality of feeding needles may be configured concentrically in a single construct, as shown in Figure 2.
  • Second fluid to be atomized (outer coating of particle).
  • the embodiment of Figure 2 is preferably used when attempting to form a spherical particle of one substance surrounded by another substance.
  • the device of Figure 2 is comprised ofthe same basic component as per the device of Figure 1 and further includes a second feeding source 32 which is positioned concentrically around the first cylindrical feeding source 31.
  • the second feeding source may be surrounded by one or more additional feeding sources with each concentrically positioned around the preceding source.
  • the process is based on the microsuction which the liquid-gas or liquid-liquid interphase undergoes (if both are immiscible), when said interphase approaches a point beginning from which one ofthe fluids is suctioned off while the combined suction ofthe two fluids is produced.
  • the interaction causes the fluid physically surrounded by the other to form a capillary microjet which finally breaks into spherical drops.
  • a capillary jet composed of two or more layers of different fluids is formed which, when it breaks, gives rise to the formation of spheres composed of several approximately concentric spherical layers of different fluids.
  • the size of the outer sphere (its thickness) and the size ofthe inner sphere (its volume) can be precisely adjusted. This can allow the manufacture of layered bubbles for a variety of end uses.
  • the method is based on the breaking of a capillary microjet composed of a nucleus of a gas and surrounded by other liquids and gases which are in a concentric manner injected by a special injection head, in such a way that they form a stable capillary microjet and that they do not mix by diffusion during the time between when the microjet is formed and when it is broken.
  • a capillary microjet composed of a nucleus of a gas and surrounded by other liquids and gases which are in a concentric manner injected by a special injection head, in such a way that they form a stable capillary microjet and that they do not mix by diffusion during the time between when the microjet is formed and when it is broken.
  • the injection head 25 consists of two concentric tubes with an external diameter on the order of one millimeter.
  • the material that will constitute the nucleus ofthe microsphere while between the internal tube 31 and the external tube 32 the coating is injected.
  • the fluid ofthe external tube 32 joins with the fluid of tube 31 as the fluids exit the feeding needle, and the fluids thus injected are accelerated by a stream of gas tor liquid hat passes through a small orifice 24 facing the end of the injection tubes.
  • the drop in pressure across the orifice 24 is sufficient, the fluids form a completely stationary capillary microjet, if the quantities of liquids that are injected are stationary.
  • This microjet does not touch the walls ofthe orifice, but passes through it wrapped in the stream of gas or funnel formed by gas from the tube 32. Because the funnel of fluid focuses the exiting fluid, the size ofthe exit orifice 26 does not dictate the size ofthe particles formed.
  • FIG. 2 shows a simplified diagram ofthe feeding needle 21, which is comprised ofthe concentric tubes 30, 31 through the internal and external flows ofthe fluids 28, 29 that are going to compose the microspheres comprised of two immiscible fluids.
  • the difference in pressures P 0 - F a (P 0 > P tf ) through the orifice 26 establishes a flow of liquid present in the chamber 23 and which is going to surround the microjet at its exit.
  • the same pressure gradient that moves the liquid is the one that moves the microjet in an axial direction through the hole 26, provided that the difference in pressures P 0 - F a is sufficiently great in comparison with the forces of surface tension, which create an adverse gradient in the direction ofthe movement.
  • the distance between the plane ofthe internal tube 31 (the one that will normally project more) and the plane ofthe orifice may vary between zero and three outside diameters ofthe external tube 32, depending on the surface tensions between the fluids and with the liquid, and on their viscosity values. Typically, the optimal distance is found experimentally for each particular configuration and each set of liquids used.
  • Multiplexing i.e. several sets of concentric tubes may be used, if me flows required are greater than those of an individual cell.
  • any means for continuous supply of gas compressors, pressure deposits, etc.
  • liquid volumetric pumps, pressure bottles, etc.
  • the flow of gas must be as homogeneous as possible between the various cells, which may require impulse through multiple capillary needles, porous media, or any other medium capable of distributing a homogeneous flow among different feeding points.
  • Each dispersion device will consist of concentric tubes 31, 32 with a diameter ranging between 0.05 and 2 mm, preferably between 0J and 0.4 mm, on which the drop from which the microjet emanates can be anchored, and a small orifice (between 0.001 and 2 mm in diameter, preferably between 0.1 and 0.25 mm), facing the drop and separated from the point of feeding by a distance between 0.001 and 2 mm, preferably between 0.2 and 0.5 mm.
  • the orifice puts the liquid that surrounds the drop, at higher pressure, in touch with the area in which the dispersion is to be attained, at lower pressure.
  • FIGURE 3 The embodiments of Figures 1 and 2 are similar in a number of ways. Both have a feeding piece which is preferably in the form of a feeding needle with a circular exit opening. Further, both have an exit port in the pressure chamber which is positioned directly in front ofthe flow path of fluid out ofthe feeding source. Precisely maintaining the alignment ofthe flow path ofthe feeding source with the exit port ofthe pressure chamber can present an engineering challenge particularly when the device includes a number of feeding needles.
  • the embodiment of Figure 3 is designed to simplify the manner in which components are aligned.
  • the embodiment of Figure 3 uses a planar feeding piece, which by virtue ofthe withdrawal effect produced by the pressure difference across a small opening through which fluid is passed permits multiple microjets to be expelled through multiple exit ports of a pressure chamber thereby obtaining multiple aerosol streams.
  • each planar feeding member feeds fluid to a linear array of outlet orifices in the surrounding pressure chamber.
  • the feeding member need not be strictly planar, and may be a curved feeding device comprised of two surfaces that maintain approximately the same spatial distance between the two pieces ofthe feeding source.
  • Such curved devices may have any level of curvature, e.g. circular, semicircular, elliptical, hemi-elliptical, etc.
  • the components ofthe embodiment of Figure 3 are as follows: 41. Feeding piece. 42. End of the feeding piece used to insert the gas to be dispersed.
  • the proposed dispersion device consists of a feeding piece 41 which creates a planar feeding channel through which a where a first fluid 48 flows.
  • the flow is preferably directed through one or more channels of uniform bores that are constructed on the planar surface of the feeding piece 41.
  • a pressure chamber 43 that holds the propelling flow of a second liquid 49 houses the feeding piece 41 and is under a pressure above maintained outside the chamber wall 50.
  • One or more orifices, openings or slots (outlets) 46 made in the wall 52 of the propulsion chamber face the edge of the feeding piece.
  • each bore or channel of the feeding piece 41 has its flow path substantially aligned with an outlet 46.
  • the second fluid 49 is a liquid and the first fluid 48 is a gas
  • the facts that the liquid is much more viscous and that the gas is much less dense virtually equalize the fluid and gas velocities.
  • the gas microthread formed is much shorter; however, because its rupture zone is almost invariably located in a laminar flowing stream, dispersion in the size of the microbubbles formed is almost always small.
  • the diameter of the gas microjet is given by
  • a continuous healthy minimum of oxygen is approximately a 6 parts per million (ppm) oxyge water ratio, which is approximately 24 grams of dissolved oxygen per 1000 gallons of water. Fish consume on average 18 grams of oxygen per hour for every ten pounds of fish. Low level stress and poor feeding response can be seen at oxygen levels of 4-5 ppm.
  • Acute stress, no feeding and inactivity can be seen at oxygen levels of 2-4 ppm, and oxygen levels of approximately 1-2 ppm generally result in death.
  • These numbers are merely a guideline since a number of variable (e.g., water temperature, water quality, condition of fish, level of other gasses, etc.) all may impact on actual oxygen needs. Proper aeration depends primarily on two factors: the gentleness and direction of water flow and d e size and amount of me air bubbles. With respect to the latter, smaller air bubbles are preferable because they (1) increase the surface are between me air and die water, providing a larger area for oxygen diffusion and (2) smaller bubbles stay suspended in water longer, providing a greater time period over which me oxygen may diffuse into the water.
  • the technology of the invention provides a method for aerating water for me proper growth and maintenance of fish.
  • a device of me invention for such a use would provide an oxygenated gas, preferably air, as die first fluid, and a liquid, preferably water, as the second fluid.
  • the air provided in a feeding source will be focused by d e flow of the surrounding water, creating a stable cusp at the interface of the two fluids.
  • the p.articles containing the gas nucleus, and preferably air nucleus, are expelled into the liquid medium where aeration is desired.
  • Figures 7 and 8 are useful in showing how bubbles may be formed in either a liquid ( Figure 7) or a gas ( Figure 8).
  • a tubular feeding source 71 is continually supplied with a flow of gas which forms a stable cusp 72 which is surrounded by the flow of liquid 73 in the pressure chamber 74 which is continually supplied with a flow of liquid 73.
  • the liquid 73 flows out ofthe chamber 74 into a liquid 75 which may be the same as or different from the liquid 73.
  • the cusp 72 of gas narrows to a capillary supercritical flow 76 and then enter the exit opening 77 ofthe chamber 74.
  • the supercritical flow 76 begins to destabilize but remains as a critical capillary flow until leaving the exit opening 77.
  • the gas stream breaks apart and forms bubbles 79 each of which are substantially identical to the others in shape and size.
  • the uniformity of bubbles is such that one bubble differs from another (in terms of measured physical diameter) in an amount in a range of standard deviation of ⁇ 0.01% to ⁇ 30% witii a preferred deviation being less than 1%.
  • the uniformity in size ofthe bubbles is greater than the uniformity ofthe particles formed as described above in connection with Figure 1 when liquid particles are formed.
  • Gas in the bubbles 79 will diffuse into the liquid 75. Smaller bubbles provide for greater surface area contact with the liquid 75. Smaller bubbles provide for greater surface area contact with the liquid 75 thereby allowing for a faster rate of diffusion men would occur if the same volume of gas were present in a smaller number of bubbles. For example, ten bubbles each containing 1 cubic mm of gas would diffuse gas into the liquid much more rapidly than one bubble containing 10 cubic mm of gas. Further, smaller bubbles rise to the liquid surface more slowly than larger bubbles. A slower rate of ascent in the liquid means that the gas bubbles are in contact with the liquid for a longer period of time thereby increasing the amount of diffusion of gas into the liquid.
  • FIG. 8 shows the same components as shown in Figure 7 except that the liquid 75 is replaced with a gas 80.
  • the stream of bubbles 79 disassociate the liquid 73 forms an outer spherical cover thereby providing hollow droplets 81 which will float in the gas 80.
  • the hollow droplets 81 have a large physical or actual diameter relative to tiieir aerodynamic diameter. Hollow droplets fall in air at a much slower rate compared to liquid droplets ofthe same diameter. Because the hollow droplets 81 do not settle or fall quickly in air they can evaporate and diffuse the evaporated liquid into surrounding air. Eventually the hollow droplets 81 will burst and form many smaller particles which diffuse these particles into the surrounding air. Thus, it is understood that the aerodynamic diameter of the hollow droplets is very small compared to their actual physical diameter. The creation of hollow droplets 81 which burst and form very small particles is applicable in a wide range of different applications including the creation of mists of water for cooling systems.
  • the feeding source 71 provides a stream of liquid 82 which may be miscible but is preferably immiscible in the liquid 73. Further the liquid 73 may be the same as or different from the liquid 75 but is preferably immiscible in the liquid 75.
  • the creation of emulsions using such a configuration of liquids has applicability in a variety of fields particularly because the liquid particles formed can have a size in the range of from about 1 to about 200 microns with a standard deviation in size of one particle to another being as little as 0.01%. The size deviation of one particle to another can vary up to about 30% and is preferably less than ⁇ 5% and more preferably less man ⁇ 1%.
  • the system operates to expel the liquid 82 out ofthe exit orifice 77 to form spheres 83 of liquid 82.
  • Each sphere 83 has an actual physical diameter which deviates from other spheres 83 by a standard deviation of ⁇ 0.01% to ⁇ 30%, preferably 10% or less and more preferably 1% or less.
  • the size ofthe spheres 83 and flow rate of liquid 82 is controlled so that each sphere 83 contain a single particle (e.g. a single cell) to be examined.
  • the stream of spheres 83 is caused to flow past a sensor and/or energy source of any desired type tiiereby allowing for sphere-by-sphere analysis ofthe sample of liquid 82.
  • the liquid 75 can be a gas (e.g., air).
  • the liquid 82 could be water which is surrounded by a second liquid 73 which is a compound for creating a desired odor e.g., a perfume.
  • the system then forms particles 83 which have a water center and an outer coating of fuel. Such water/perfume particles will rapidly disperse the perfume at a low cost.

Abstract

La présente invention concerne des procédés d'aération utilisant des bulles de gaz sphériques d'une grosseur comprise entre 0,1 et 100 microns. Un dispositif de l'invention permettant de produire une monodispersion de bulles comprend une source de flux gazeux que l'on force à passer à travers un liquide maintenu sous pression dans une chambre de pression pourvue d'une ouverture de sortie. Le flux gazeux entouré du liquide dans la chambre de pression s'écoule dans un liquide à travers un orifice de sortie de la chambre, créant ainsi une monodispersion de bulles de diamètre sensiblement uniforme. Les bulles sont de petite taille et leur production ne nécessite que relativement peu d'énergie par rapport à des systèmes comparables. Les applications de la technique d'aération vont de l'oxygénation des eaux d'égout à l'aide de monodispersions de bulles à l'oxygénation de l'eau dans laquelle vivent des poissons.
PCT/IB1998/002057 1997-12-17 1998-12-16 Dispositif et procede d'aeration de fluides WO1999030812A1 (fr)

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EP98960050A EP1039965A1 (fr) 1997-12-17 1998-12-16 Dispositif et procede d'aeration de fluides
CA002314919A CA2314919A1 (fr) 1997-12-17 1998-12-16 Dispositif et procede d'aeration de fluides
JP2000538781A JP2002508238A (ja) 1997-12-17 1998-12-16 流体のエアレーションのためのデバイスおよび方法
AU15732/99A AU745698B2 (en) 1997-12-17 1998-12-16 Device and method for aeration of fluids

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ES9702654A ES2158741B1 (es) 1997-12-17 1997-12-17 Dispositivo de sipersion de un fluido en otro inmiscible en forma de microgotas o microburbujas de tamaño uniforme.
ESP9702654 1997-12-17
US09/191,756 1998-11-13
US09/191,756 US6196525B1 (en) 1996-05-13 1998-11-13 Device and method for fluid aeration via gas forced through a liquid within an orifice of a pressure chamber

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US10369579B1 (en) 2018-09-04 2019-08-06 Zyxogen, Llc Multi-orifice nozzle for droplet atomization
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AU745698B2 (en) 2002-03-28

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